CN115400561B - A desulfurization tower used in calcium oxide production - Google Patents
A desulfurization tower used in calcium oxide production Download PDFInfo
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- CN115400561B CN115400561B CN202211013057.6A CN202211013057A CN115400561B CN 115400561 B CN115400561 B CN 115400561B CN 202211013057 A CN202211013057 A CN 202211013057A CN 115400561 B CN115400561 B CN 115400561B
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- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 98
- 230000023556 desulfurization Effects 0.000 title claims abstract description 96
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000000292 calcium oxide Substances 0.000 title claims abstract description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000007921 spray Substances 0.000 claims abstract description 32
- 239000002002 slurry Substances 0.000 claims abstract description 28
- 239000000779 smoke Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims description 8
- 238000009423 ventilation Methods 0.000 claims description 3
- 230000006698 induction Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005507 spraying Methods 0.000 abstract description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- 239000003546 flue gas Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- 235000019738 Limestone Nutrition 0.000 description 4
- 239000006028 limestone Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/96—Regeneration, reactivation or recycling of reactants
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- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Treating Waste Gases (AREA)
Abstract
本发明公开了一种应用于氧化钙生产的脱硫塔,包括塔体,塔体内的底部设有脱硫浆液池,塔体一侧设有位于脱硫浆液池上方的进烟口,塔体顶部设有出气口,塔体内还设有位于进烟口和出气口之间的引风罩,引风罩上设有脱硫喷淋管,脱硫喷淋管连接有与脱硫浆液池相连的循环管;所述引风罩包括固定于塔体内且上小下大的底部锥形罩,底部锥形罩的前后两侧设有出液口,底部锥形罩上方设有导风管,导风管上方设有上大下小的锥形固定件,锥形固定件与塔体之间设有环形出烟口,脱硫喷淋管固定于锥形固定件的侧壁面;所述导风管侧壁面上设有出风口。本发明具有能够有效改善喷淋效果的特点。
The invention discloses a desulfurization tower used in calcium oxide production, which includes a tower body. A desulfurization slurry pool is provided at the bottom of the tower body. A smoke inlet located above the desulfurization slurry pool is provided on one side of the tower body. The top of the tower body is provided with a desulfurization slurry pool. At the air outlet, the tower body is also provided with a draft hood located between the smoke inlet and the gas outlet. The draft hood is provided with a desulfurization spray pipe, and the desulfurization spray pipe is connected to a circulation pipe connected to the desulfurization slurry pool; The draft hood includes a bottom cone-shaped hood that is fixed in the tower body and is small at the top and large at the bottom. There are liquid outlets on the front and rear sides of the bottom cone-shaped hood. There is an air guide duct above the bottom cone-shaped hood, and there is an air guide duct above it. The upper and lower cone-shaped fixing parts are large and small. There is an annular smoke outlet between the conical fixing part and the tower body. The desulfurization spray pipe is fixed on the side wall of the conical fixing part; the side wall of the air guide pipe is provided with Air outlet. The invention has the characteristics of effectively improving the spraying effect.
Description
技术领域Technical field
本发明涉及一种脱硫塔,特别是一种应用于氧化钙生产的脱硫塔。The invention relates to a desulfurization tower, in particular to a desulfurization tower used in calcium oxide production.
背景技术Background technique
采用煅烧法将石灰石制备成氧化钙的工艺一般包括以下工序:先将石灰石粗碎至150mm,并筛除30-50mm以下的细渣;然后将经筛选的石灰石及燃料定时、定量由窑顶加入窑内,于900-1200℃煅烧,再经冷却即得成品。在煅烧工序中,石灰石会产生二氧化碳,煤或者焦炭燃烧会产生含硫含硝的烟气(窑气),烟气需要经过脱硫脱硝处理后才能排放至空气中。现有的脱硫塔,一般是采用湿式脱硫法,即采用在喷淋塔内喷淋脱硫浆液的方式对烟气进行脱硫处理,该种方式的喷淋角度有限,使得部分烟气未经喷淋处理就排至大气中,导致最终的脱硫效果不理想,造成环境污染。因此,现有的技术存在着脱硫效果不理想的问题。The process of preparing limestone into calcium oxide by calcining method generally includes the following steps: first coarsely crush the limestone to 150mm, and screen out the fine residue below 30-50mm; then add the screened limestone and fuel from the top of the kiln in a regular and quantitative manner. In the kiln, it is calcined at 900-1200℃, and then cooled to obtain the finished product. During the calcination process, limestone will produce carbon dioxide, and the combustion of coal or coke will produce flue gas (kiln gas) containing sulfur and nitrate. The flue gas needs to be desulfurized and denitrified before it can be discharged into the air. Existing desulfurization towers generally use the wet desulfurization method, that is, the flue gas is desulfurized by spraying desulfurization slurry in the spray tower. The spray angle of this method is limited, so that part of the flue gas is not sprayed. After treatment, it will be discharged into the atmosphere, resulting in unsatisfactory final desulfurization effect and causing environmental pollution. Therefore, the existing technology has the problem of unsatisfactory desulfurization effect.
发明内容Contents of the invention
本发明的目的在于,提供一种应用于氧化钙生产的脱硫塔。本发明具有能够有效改善喷淋效果的特点。The object of the present invention is to provide a desulfurization tower used in calcium oxide production. The invention has the characteristics of effectively improving the spraying effect.
本发明的技术方案:一种应用于氧化钙生产的脱硫塔,包括塔体,塔体内的底部设有脱硫浆液池,塔体一侧设有位于脱硫浆液池上方的进烟口,塔体顶部设有出气口,塔体内还设有位于进烟口和出气口之间的引风罩,引风罩上设有脱硫喷淋管,脱硫喷淋管连接有与脱硫浆液池相连的循环管;所述引风罩包括固定于塔体内且上小下大的底部锥形罩,底部锥形罩的前后两侧设有出液口,底部锥形罩上方设有导风管,导风管上方设有上大下小的锥形固定件,锥形固定件与塔体之间设有环形出烟口,脱硫喷淋管固定于锥形固定件的侧壁面;所述导风管侧壁面上设有出风口。The technical solution of the present invention: a desulfurization tower used in calcium oxide production, including a tower body. A desulfurization slurry pool is provided at the bottom of the tower body. A smoke inlet is located above the desulfurization slurry pool on one side of the tower body. The top of the tower body It is equipped with an air outlet, and the tower body is also equipped with a draft hood located between the smoke inlet and the gas outlet. The draft hood is equipped with a desulfurization spray pipe, and the desulfurization spray pipe is connected to a circulation pipe connected to the desulfurization slurry pool; The draft hood includes a bottom cone-shaped hood that is fixed in the tower body and is small at the top and large at the bottom. Liquid outlets are provided on the front and rear sides of the bottom cone-shaped hood. An air guide duct is provided above the bottom cone-shaped hood. There is a cone-shaped fixing piece with a large upper part and a small one at the bottom. An annular smoke outlet is provided between the cone-shaped fixing part and the tower body. The desulfurization spray pipe is fixed on the side wall surface of the cone-shaped fixing part; the side wall surface of the air guide pipe Equipped with air outlet.
前述的一种应用于氧化钙生产的脱硫塔中,所述脱硫喷淋管包括多组呈阶梯分布的环形喷淋管,环形喷淋管上均布有喷嘴。In the aforementioned desulfurization tower used in calcium oxide production, the desulfurization spray pipes include multiple groups of annular spray pipes distributed in a stepped manner, and the annular spray pipes are evenly distributed with nozzles.
前述的一种应用于氧化钙生产的脱硫塔中,所述引风罩上方设有向下倾斜分布且与环形出烟口位置相对应的环形脱硫置物件,环形脱硫置物件内填充有脱硫颗粒,且环形脱硫置物件表面设有通风孔;所述锥形固定件上端还设有与环形脱硫置物件相平行的环形导风板。In the aforementioned desulfurization tower used in calcium oxide production, there is an annular desulfurization object distributed downwardly inclined and corresponding to the position of the annular smoke outlet above the draft hood, and the annular desulfurization object is filled with desulfurization particles. , and the surface of the annular desulfurization device is provided with ventilation holes; the upper end of the tapered fixing member is also provided with an annular air guide plate parallel to the annular desulfurization device.
前述的一种应用于氧化钙生产的脱硫塔中,所述引风罩上方的中部设有旋转杆,旋转杆上设有一组环形分布的旋转式脱硫盒,旋转式脱硫盒内设有脱硫颗粒,旋转式脱硫盒表面设有交换通孔;所述旋转杆外端连接有驱动电机。In the aforementioned desulfurization tower used in calcium oxide production, a rotating rod is provided in the middle above the draft hood. A set of annularly distributed rotating desulfurization boxes are provided on the rotating rod, and desulfurization particles are provided in the rotating desulfurization box. , the surface of the rotary desulfurization box is provided with exchange through holes; the outer end of the rotating rod is connected to a drive motor.
前述的一种应用于氧化钙生产的脱硫塔中,脱硫浆液池的中部设有过滤网,过滤网上方一侧的塔体上设有循环管;所述塔体的前后两侧壁面设有引流腔,引流腔的底部出口位于过滤网的下方。In the aforementioned desulfurization tower used in calcium oxide production, a filter is provided in the middle of the desulfurization slurry pool, and a circulation pipe is provided on the tower body above the filter net; drainage is provided on the front and rear walls of the tower. cavity, the bottom outlet of the drainage cavity is located below the filter.
前述的一种应用于氧化钙生产的脱硫塔中,引流腔与出液口相对应。In the aforementioned desulfurization tower used in calcium oxide production, the drainage cavity corresponds to the liquid outlet.
与现有技术相比,本发明通过在塔体内设置由底部锥形罩、导风管、锥形固定件构成的引风罩,并将由多组呈阶梯分布的环形喷淋管所构成的脱硫喷淋管设置在引风罩的锥形固定件的外壁面上,从而可以有效的扩大喷淋角度,实现全方位的喷淋,进而可以有效改善喷淋效果。与此同时,本发明还在引风罩的上方设置与环形出烟口相配合的环形脱硫置物件和可以旋转的旋转式脱硫盒,对烟气进一步的进行脱硫处理,进而可以有效的改善脱硫效果;而且,旋转式脱硫盒的转动,还可以对烟气产生扰动,进而进一步的改善脱硫的均匀性。综上所述,本发明具有能够有效改善喷淋效果的特点。Compared with the prior art, the present invention sets an air induction hood composed of a bottom conical hood, an air guide duct, and a conical fixing piece in the tower body, and uses a desulfurization system composed of multiple sets of annular spray pipes distributed in a stepped manner. The spray pipe is arranged on the outer wall surface of the cone-shaped fixing member of the draft hood, which can effectively expand the spray angle and achieve all-round spray, thereby effectively improving the spray effect. At the same time, the present invention also provides an annular desulfurization device that matches the annular smoke outlet and a rotatable desulfurization box above the draft hood to further desulfurize the flue gas, thereby effectively improving desulfurization. Effect; Moreover, the rotation of the rotary desulfurization box can also disturb the flue gas, thereby further improving the uniformity of desulfurization. To sum up, the present invention has the characteristics of effectively improving the spraying effect.
另外,本发明通过将底部锥形罩与出液口之间的相互配合,可以将喷淋后的脱硫浆液回收至脱硫浆液池的过滤网下方,从而可以对浆液进行过滤,提高循环效果;而且也能有效减少烟气携带浆液排放,减少浆液的损耗。In addition, the present invention can recover the sprayed desulfurization slurry below the filter screen of the desulfurization slurry tank by cooperating between the bottom conical cover and the liquid outlet, so that the slurry can be filtered and the circulation effect can be improved; and It can also effectively reduce the emission of slurry carried by flue gas and reduce the loss of slurry.
附图说明Description of drawings
图1是本发明的结构示意图;Figure 1 is a schematic structural diagram of the present invention;
图2是引风罩的结构视图;Figure 2 is a structural view of the draft hood;
图3是底部锥形罩的俯视图。Figure 3 is a top view of the bottom conical cover.
附图中的标记为:1-塔体,2-脱硫浆液池,3-进烟口,4-出气口,5-引风罩,6-脱硫喷淋管,7-循环管,501-底部锥形罩,502-出液口,503-导风管,504-锥形固定件,505-环形出烟口,506-出风口,507-环形脱硫置物件,508-环形导风板,8-旋转杆,9-旋转式脱硫盒,10-过滤网,11-引流腔。The marks in the drawings are: 1-tower body, 2-desulfurization slurry pool, 3-smoke inlet, 4-air outlet, 5-draft hood, 6-desulfurization spray pipe, 7-circulation pipe, 501-bottom Conical cover, 502-liquid outlet, 503-air guide duct, 504-conical fixing piece, 505-annular smoke outlet, 506-air outlet, 507-annular desulfurization storage object, 508-annular air guide plate, 8 -Rotating rod, 9-rotating desulfurization box, 10-filter, 11-drainage chamber.
具体实施方式Detailed ways
下面结合附图和实施例对本发明作进一步的说明,但并不作为对本发明限制的依据。The present invention will be further described below in conjunction with the accompanying drawings and examples, but this does not serve as a basis for limiting the present invention.
实施例。一种应用于氧化钙生产的脱硫塔,构成如图1至图3所示,包括塔体1,塔体1内的底部设有脱硫浆液池2,塔体1一侧设有位于脱硫浆液池2上方的进烟口3,塔体1顶部设有出气口4,塔体1内还设有位于进烟口3和出气口4之间的引风罩5,引风罩5上设有脱硫喷淋管6,脱硫喷淋管6连接有与脱硫浆液池2相连的循环管7;所述引风罩5包括固定于塔体1内且上小下大的底部锥形罩501,底部锥形罩501的前后两侧设有出液口502,底部锥形罩501上方设有导风管503,导风管503上方设有上大下小的锥形固定件504,锥形固定件504与塔体1之间设有环形出烟口505,脱硫喷淋管6固定于锥形固定件504的侧壁面;所述导风管503侧壁面上设有出风口506。Example. A desulfurization tower used in calcium oxide production is composed as shown in Figures 1 to 3. It includes a tower body 1. A desulfurization slurry pool 2 is provided at the bottom of the tower body 1. A desulfurization slurry pool is located on one side of the tower body 1. There is a smoke inlet 3 above 2, and an air outlet 4 is provided on the top of the tower body 1. The tower body 1 is also provided with a draft hood 5 located between the smoke inlet 3 and the air outlet 4. The draft hood 5 is provided with a desulfurization Spray pipe 6, the desulfurization spray pipe 6 is connected to the circulation pipe 7 connected to the desulfurization slurry pool 2; the draft hood 5 includes a bottom conical hood 501 fixed in the tower body 1 and with a small top and a large bottom. Liquid outlets 502 are provided on the front and rear sides of the cone-shaped cover 501. An air guide duct 503 is provided above the bottom cone-shaped cover 501. An upper and lower conical fixing piece 504 is disposed above the air duct 503. The conical fixing piece 504 An annular smoke outlet 505 is provided between the tower 1 and the desulfurization spray pipe 6. The desulfurization spray pipe 6 is fixed on the side wall of the cone-shaped fixture 504; the air guide 503 is provided with an air outlet 506 on the side wall.
所述脱硫喷淋管6包括多组呈阶梯分布的环形喷淋管,环形喷淋管上均布有喷嘴。The desulfurization spray pipe 6 includes multiple groups of annular spray pipes distributed in a stepped manner, and nozzles are evenly distributed on the annular spray pipes.
所述引风罩5上方设有向下倾斜分布且与环形出烟口505位置相对应的环形脱硫置物件507,环形脱硫置物件507内填充有脱硫颗粒,且环形脱硫置物件507表面设有通风孔;所述锥形固定件504上端还设有与环形脱硫置物件507相平行的环形导风板508。An annular desulfurization device 507 is provided above the draft hood 5 and is distributed obliquely downward and corresponding to the position of the annular smoke outlet 505. The annular desulfurization device 507 is filled with desulfurization particles, and the surface of the annular desulfurization device 507 is provided with Ventilation holes; the upper end of the tapered fixing member 504 is also provided with an annular air guide plate 508 parallel to the annular desulfurization device 507.
所述引风罩5上方的中部设有旋转杆8,旋转杆8上设有一组环形分布的旋转式脱硫盒9,旋转式脱硫盒9内设有脱硫颗粒,旋转式脱硫盒9表面设有交换通孔;所述旋转杆8外端连接有驱动电机。There is a rotating rod 8 in the middle above the draft hood 5, and a set of annularly distributed rotating desulfurization boxes 9 are arranged on the rotating rod 8. The rotating desulfurization boxes 9 are equipped with desulfurization particles, and the surface of the rotating desulfurization box 9 is provided with Exchange through holes; the outer end of the rotating rod 8 is connected to a drive motor.
脱硫浆液池2的中部设有过滤网10,过滤网10上方一侧的塔体1上设有循环管7;所述塔体1的前后两侧壁面设有引流腔11,引流腔11的底部出口位于过滤网10的下方。A filter 10 is provided in the middle of the desulfurization slurry tank 2, and a circulation pipe 7 is provided on the tower 1 above the filter 10; a drainage chamber 11 is provided on the front and rear side walls of the tower 1, and the bottom of the drainage chamber 11 The outlet is located below the filter 10.
引流腔11与出液口502相对应。The drainage cavity 11 corresponds to the liquid outlet 502 .
脱硫浆液池还连接有脱硫浆液补充管和废液回收管。The desulfurization slurry tank is also connected to a desulfurization slurry replenishment pipe and a waste liquid recovery pipe.
本发明的工作过程:烟气经进烟口进入塔体内,随后进入底部锥形罩内,从导风管的出风口流出至底部锥形罩和锥形固定件之间的喷淋腔体,依次经过阶梯分布的环形喷淋管的喷淋后,烟气从环形出烟口处流出,一部分烟气经过环形脱硫置物件内的脱硫颗粒的脱硫处理后,从出气口排放至外部环境或者进入下一处理工序,另一部分烟气在环形导风板的引导下,与旋转式脱硫盒内的脱硫颗粒接触后,从出气口排放。喷淋后的脱硫浆液经出液口和引流腔,回流至脱硫浆液池的过滤网下方,经过过滤后,经循环管重新循环使用。The working process of the present invention: flue gas enters the tower body through the smoke inlet, then enters the bottom conical cover, flows out from the air outlet of the air guide duct to the spray cavity between the bottom conical cover and the conical fixing piece, After being sprayed by the stepped annular spray pipes in sequence, the flue gas flows out from the annular smoke outlet. After a part of the flue gas is desulfurized by the desulfurization particles in the annular desulfurization device, it is discharged from the outlet to the external environment or enters the In the next treatment process, another part of the flue gas is guided by the annular air guide plate, contacts the desulfurization particles in the rotary desulfurization box, and is discharged from the air outlet. The sprayed desulfurization slurry flows back to the bottom of the filter screen of the desulfurization slurry pool through the liquid outlet and the drainage cavity. After being filtered, it is recirculated through the circulation pipe.
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Denomination of invention: A desulfurization tower applied to the production of calcium oxide Granted publication date: 20231124 Pledgee: China Postal Savings Bank Co.,Ltd. Jiande City Branch Pledgor: Zhejiang Jianing Environmental Protection New Material Technology Co.,Ltd. Registration number: Y2024330002633 |