CN115339772B - Bidirectional humidity control bag for article preservation and application thereof - Google Patents
Bidirectional humidity control bag for article preservation and application thereof Download PDFInfo
- Publication number
- CN115339772B CN115339772B CN202111648406.7A CN202111648406A CN115339772B CN 115339772 B CN115339772 B CN 115339772B CN 202111648406 A CN202111648406 A CN 202111648406A CN 115339772 B CN115339772 B CN 115339772B
- Authority
- CN
- China
- Prior art keywords
- humidity
- layer
- humidity control
- bag
- moisture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000002457 bidirectional effect Effects 0.000 title abstract description 8
- 238000004321 preservation Methods 0.000 title abstract description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 34
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 34
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 31
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019506 cigar Nutrition 0.000 claims abstract description 17
- 239000001103 potassium chloride Substances 0.000 claims abstract description 17
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 17
- 239000011780 sodium chloride Substances 0.000 claims abstract description 17
- 235000002639 sodium chloride Nutrition 0.000 claims abstract description 17
- 239000001540 sodium lactate Substances 0.000 claims abstract description 17
- 235000011088 sodium lactate Nutrition 0.000 claims abstract description 17
- 229940005581 sodium lactate Drugs 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 30
- 239000005022 packaging material Substances 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229920000609 methyl cellulose Polymers 0.000 claims description 20
- 239000001923 methylcellulose Substances 0.000 claims description 20
- 235000010981 methylcellulose Nutrition 0.000 claims description 20
- 244000215068 Acacia senegal Species 0.000 claims description 19
- 108010010803 Gelatin Proteins 0.000 claims description 19
- 229920000084 Gum arabic Polymers 0.000 claims description 19
- 235000010489 acacia gum Nutrition 0.000 claims description 19
- 239000000205 acacia gum Substances 0.000 claims description 19
- 239000008273 gelatin Substances 0.000 claims description 19
- 229920000159 gelatin Polymers 0.000 claims description 19
- 235000019322 gelatine Nutrition 0.000 claims description 19
- 235000011852 gelatine desserts Nutrition 0.000 claims description 19
- 239000000665 guar gum Substances 0.000 claims description 18
- 235000010417 guar gum Nutrition 0.000 claims description 18
- 229960002154 guar gum Drugs 0.000 claims description 18
- 239000004745 nonwoven fabric Substances 0.000 claims description 18
- 229920002907 Guar gum Polymers 0.000 claims description 17
- 239000000123 paper Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000011111 cardboard Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 5
- 238000007731 hot pressing Methods 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 238000003860 storage Methods 0.000 abstract description 13
- 230000001105 regulatory effect Effects 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 239000002699 waste material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000012528 membrane Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 2
- 239000011086 glassine Substances 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 235000019823 konjac gum Nutrition 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
- B65D81/22—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient in moist conditions or immersed in liquids
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Packages (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及B01D53/28领域，具体为一种物品保存用双向调湿包及其应用。The invention relates to the field of B01D53/28, and in particular to a two-way humidity-control bag for storing articles and application thereof.
背景技术Background technique
干花、雪茄、吉他等物品的保存对保存环境的相对湿度要求较高，需要有一个相对稳定的湿度值。当前，环境相对湿度调节方式按是否消耗人工能源可以分为主动式方法和被动式方法。主动式方法主要是现有的暖通技术，它主要用于调节货物仓库室内环境的湿度，该方法需要消耗大量能源，且控制的平稳性和精度受设备的工作原理、通风管路的布置等因素的影响。而被动式方法则是利用某些材料的吸放湿特性来调控环境的湿度，这种方式具有节能、控制平稳、安全等优点，特别适用于对相对密闭小环境中湿度的平稳控制。The preservation of dried flowers, cigars, guitars and other items requires a high relative humidity of the preservation environment, and a relatively stable humidity value is required. At present, the relative humidity adjustment methods of the environment can be divided into active methods and passive methods according to whether artificial energy is consumed. The active method is mainly the existing HVAC technology, which is mainly used to adjust the humidity of the indoor environment of the cargo warehouse. This method consumes a lot of energy, and the stability and accuracy of the control are affected by factors such as the working principle of the equipment and the layout of the ventilation ducts. The passive method uses the moisture absorption and release characteristics of certain materials to regulate the humidity of the environment. This method has the advantages of energy saving, stable control, and safety. It is particularly suitable for the stable control of humidity in a relatively closed small environment.
现有技术中的环境湿度调节物品需将调湿成分涂覆于纸板载体上，制备工艺复杂，成本较高，使用不便，效率较低，而且容易造成资源浪费，不适合大规模推广生产及使用；同时涂覆型环境湿度调节物品的稳定性有待提升，在日常使用过程中可能会由于调湿成分脱落造成调湿性能失效，不能长期有效使用；而硅胶基调湿物品不环保，易产生大量废水，而且调湿功能单一。Environmental humidity regulating articles in the prior art require the humidity regulating components to be coated on a cardboard carrier, which has a complex preparation process, high cost, inconvenient use, low efficiency, and easy waste of resources, and is not suitable for large-scale production and use; at the same time, the stability of coated environmental humidity regulating articles needs to be improved, and the humidity regulating performance may fail due to the shedding of humidity regulating components during daily use, and cannot be effectively used for a long time; and silica gel-based humidity regulating articles are not environmentally friendly, easily generate a large amount of wastewater, and have a single humidity regulating function.
因此提供一种物品保存用双向调湿包，可根据物品所处环境有效快速调节湿度在特定的范围内，可根据物品保存需要对双向调湿包的大小进行调整，满足不同物品的实际使用需求，湿度调节范围宽(30-95％)，成本低、使用方便，可长期有效使用，满足干花、雪茄和吉他等对保存环境的相对湿度要求较高的物品的保存，这具有重要的研究意义和极高的实际应用价值。Therefore, a two-way humidity control bag for storing items is provided, which can effectively and quickly adjust the humidity within a specific range according to the environment in which the items are located. The size of the two-way humidity control bag can be adjusted according to the storage needs of the items to meet the actual use needs of different items. The humidity adjustment range is wide (30-95%), the cost is low, and it is easy to use. It can be effectively used for a long time and can meet the storage requirements of items such as dried flowers, cigars and guitars that have high relative humidity requirements for the storage environment. This has important research significance and extremely high practical application value.
发明内容Summary of the invention
为了解决上述问题，本发明一方面提供一种物品保存用双向调湿包，由透湿包材和调湿剂组成，所述双向调湿包通过透湿包材包裹调节剂制备得到。In order to solve the above problems, the present invention provides a two-way humidity-regulating bag for storing articles, which is composed of a moisture-permeable packaging material and a humidity-regulating agent. The two-way humidity-regulating bag is prepared by wrapping the humidity-permeable packaging material with the humidity-regulating agent.
作为一种优选的技术方案，按重量百分计，所述调湿剂包括亲水性高分子化合物0.5-5％，调湿成分8-50％，水50-90％。As a preferred technical solution, the humidity control agent includes 0.5-5% of a hydrophilic polymer compound, 8-50% of a humidity control component, and 50-90% of water, by weight percentage.
作为一种优选的技术方案，所述水选自自来水，纯净水，蒸馏水，过滤水，去离子水中的任意一种；优选的，所述水为去离子水；As a preferred technical solution, the water is selected from any one of tap water, purified water, distilled water, filtered water, and deionized water; preferably, the water is deionized water;
为了尽可能降低调湿剂中水分对透湿包材的压力，本申请人经过大量的探究性试验发现，当体系中的亲水性高分子化合物与调湿成分的质量比为(1-4)：(20-50)时，调湿剂呈凝胶粘稠状，亲水性高分子化合物的存在，可以有效的缓解水分对透湿包材的作用力，配合特定材质的层状结构透湿包材，防止水分泄漏影响使用效果。作为一种优选的技术方案，所述亲水性高分子化合物选自壳聚糖、卡拉胶，明胶，魔芋胶，黄原胶，甲基纤维素，羟丙基甲基纤维素，瓜尔豆胶，阿拉伯胶中的一种或几种的组合；优选的，所述亲水性高分子化合物为明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合；优选的，所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为(1.5-2)：(0.8-1.5)：(1.2-1.8)：(0.5-1)；本申请人在探究过程中发现，当采用明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合作为亲水性高分子化合物，尤其是当明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为(1.5-2)：(0.8-1.5)：(1.2-1.8)：(0.5-1)时，与体系中的调湿成分具有很好的匹配性，在不影响调湿成分调湿作用的条件下，使调湿成分均匀分散在亲水性高分子化合物形成的物理网状结构中，对调湿成分协同调节湿度具有促进作用，体系稳定性提高，有助于延长调湿包的有效使用时长。In order to reduce the pressure of water in the humidity control agent on the moisture permeable packaging material as much as possible, the applicant has found through a large number of exploratory tests that when the mass ratio of the hydrophilic polymer compound to the humidity control component in the system is (1-4): (20-50), the humidity control agent is in a gel-like viscous state. The presence of the hydrophilic polymer compound can effectively alleviate the force of water on the moisture permeable packaging material, and cooperate with the layered structure moisture permeable packaging material of a specific material to prevent moisture leakage from affecting the use effect. As a preferred technical solution, the hydrophilic polymer compound is selected from one or more of chitosan, carrageenan, gelatin, konjac gum, xanthan gum, methylcellulose, hydroxypropyl methylcellulose, guar gum, and gum arabic; preferably, the hydrophilic polymer compound is a combination of gelatin, gum arabic, methylcellulose and guar gum; preferably, the mass ratio of gelatin, gum arabic, methylcellulose and guar gum is (1.5-2): (0.8-1.5): (1.2-1.8): (0.5-1); The applicant found in the process of exploration that when gelatin, The combination of gum arabic, methyl cellulose and guar gum as a hydrophilic polymer compound, especially when the mass ratio of gelatin, gum arabic, methyl cellulose and guar gum is (1.5-2): (0.8-1.5): (1.2-1.8): (0.5-1), has a good match with the humidity-controlling components in the system. Under the condition of not affecting the humidity-controlling effect of the humidity-controlling components, the humidity-controlling components are evenly dispersed in the physical network structure formed by the hydrophilic polymer compound, which has a promoting effect on the synergistic humidity control of the humidity-controlling components, improves the stability of the system, and helps to extend the effective use time of the humidity-controlling bag.
所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶均购买自西格玛奥德里奇(上海)贸易有限公司。The gelatin, gum arabic, methyl cellulose and guar gum were all purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.
作为一种优选的技术方案，所述调湿成分选自氯化钠，氯化钾，氯化锂，乳酸钠，柠檬酸钾，溴化钠，苯甲酸钠，硫酸钾，硝酸钠，溴化锂中至少三种的组合；优选的，所述调湿成分包括钠盐、锂盐、钾盐；本申请通过配方的调整，可根据物品所处环境有效快速调节湿度在特定的范围内，湿度调节范围宽达30％-95％，满足对保存环境的相对湿度要求较高的物品的保存需求。作为一种优选的技术方案，所述调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，优选的，所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为(6-10)：(2-4)：(3-7)：(5-8)；本申请经过大量的试验探究发现，当调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，尤其是当所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为(6-10)：(2-4)：(3-7)：(5-8)时，配合亲水性高分子化合物和特定材质的透湿包材，可将环境湿度有效调节控制在65％-80％，效率高，不需要进行额外的后处理，避免资源浪费，尤其适用于干花、雪茄和吉他的保存。As a preferred technical solution, the humidity-adjusting component is selected from a combination of at least three of sodium chloride, potassium chloride, lithium chloride, sodium lactate, potassium citrate, sodium bromide, sodium benzoate, potassium sulfate, sodium nitrate, and lithium bromide; preferably, the humidity-adjusting component includes sodium salt, lithium salt, and potassium salt; the present application can effectively and quickly adjust the humidity within a specific range according to the environment in which the article is located through the adjustment of the formula, and the humidity adjustment range is as wide as 30%-95%, which meets the storage needs of articles with higher requirements on the relative humidity of the storage environment. As a preferred technical solution, the humidity-controlling component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide. Preferably, the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is (6-10): (2-4): (3-7): (5-8). After a large number of experimental investigations, the present application found that when the humidity-controlling component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide, especially when the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is (6-10): (2-4): (3-7): (5-8), in combination with a hydrophilic polymer compound and a moisture-permeable packaging material of a specific material, the ambient humidity can be effectively regulated and controlled at 65%-80%, with high efficiency, no need for additional post-processing, and avoidance of resource waste. The invention is particularly suitable for the preservation of dried flowers, cigars and guitars.
作为一种优选的技术方案，所述调湿剂的制备方法为：控制温度为30-40℃，按重量百分比将水、调湿成分加入容器中搅拌3-5min后，升温至55-70℃，加入亲水性高分子化合物，搅拌15-25min即得。As a preferred technical solution, the preparation method of the humidity control agent is: control the temperature to 30-40°C, add water and humidity control ingredients according to weight percentage into a container and stir for 3-5 minutes, then heat to 55-70°C, add a hydrophilic polymer compound, and stir for 15-25 minutes.
为了方便应用和推广，满足实际使用需求，通过透湿包材将调湿剂包覆后进行实际应用；为了满足调节剂调节环境湿度的需要，作为一种优选的技术方案，所述透湿包材为2-5层层状结构；优选的，所述透湿包材为二层结构或三层结构，所述二层结构或三层结构通过淋膜，涂布，复合，热压制备得到；In order to facilitate application and promotion and meet the actual use needs, the humidity regulator is coated with a moisture permeable packaging material for practical application; in order to meet the need of the regulator to adjust the ambient humidity, as a preferred technical solution, the moisture permeable packaging material is a 2-5 layer structure; preferably, the moisture permeable packaging material is a two-layer structure or a three-layer structure, and the two-layer structure or the three-layer structure is prepared by lamination, coating, compounding, and hot pressing;
作为一种优选的技术方案，所述透湿包材为二层结构；优选的，所述二层结构包括内层和外层；优选的，所述内层为防水透湿透气膜层，所述防水透湿透气膜层为低密度聚乙烯膜、线性低密度聚乙烯膜、聚乙烯透气膜、TPU透湿膜中的任意一种；所述外层为普通纸张、牛皮纸、包装纸、双胶纸、铜板纸、白卡纸、玻璃纸、羊皮纸、无纺布中的任意一种；优选的，所述防水透湿透气膜层为TPU透湿膜，优选的，所述TPU透湿膜采用美标ASTM E96BW2000测定的透湿度为2500-8000g/m2.24h，优选的，所述TPU透湿膜选自XG2090-09、TH-105WE、TH-105FE、TM-103WSE、TM-103FE中的任意一种；优选的，所述TPU透湿膜为TM-103WSE。所述外层为铜板纸。当所述透湿包材为二层结构时，通过设计内层采用透湿度为2500-8000g/m2.24h的TPU透湿膜作为防水透湿透气膜层，尤其是当TPU透湿膜为TM-103WSE时，配合外层为铜版纸，保证调湿剂可以有效调节控制环境湿度为30％-95％的同时，防止水分的泄漏，制备工艺简单，成本较低，使用方便，可根据物品保存需要对双向调湿包的大小进行调整，满足不同物品的实际使用需求，适合大规模推广生产及使用。As a preferred technical solution, the moisture permeable packaging material is a two-layer structure; preferably, the two-layer structure includes an inner layer and an outer layer; preferably, the inner layer is a waterproof, moisture permeable, breathable film layer, and the waterproof, moisture permeable, breathable film layer is any one of a low-density polyethylene film, a linear low-density polyethylene film, a polyethylene breathable film, and a TPU breathable film; the outer layer is any one of ordinary paper, kraft paper, wrapping paper, offset paper, coated paper, white cardboard, glassine, parchment, and non-woven fabric; preferably, the waterproof, moisture permeable, breathable film layer is a TPU breathable film, preferably, the moisture permeability of the TPU breathable film measured by the American standard ASTM E96BW2000 is 2500-8000g/ m2.24h , preferably, the TPU breathable film is selected from any one of XG2090-09, TH-105WE, TH-105FE, TM-103WSE, and TM-103FE; preferably, the TPU breathable film is TM-103WSE. The outer layer is coated paper. When the moisture permeable packaging material is a two-layer structure, the inner layer is designed to use a TPU moisture permeable membrane with a moisture permeability of 2500-8000g/ m2.24h as a waterproof, moisture permeable and breathable membrane layer, especially when the TPU moisture permeable membrane is TM-103WSE, and the outer layer is coated paper, it is ensured that the humidity control agent can effectively adjust and control the environmental humidity to 30%-95% while preventing water leakage. The preparation process is simple, the cost is low, and it is easy to use. The size of the two-way humidity control bag can be adjusted according to the storage needs of the items to meet the actual use needs of different items, and it is suitable for large-scale promotion, production and use.
所述TM-103WSE型TPU透湿膜购买自嘉兴南雄高分子有限公司；The TM-103WSE TPU moisture permeable membrane was purchased from Jiaxing Nanxiong Polymer Co., Ltd.
作为一种优选的技术方案，所述透湿包材为三层结构；优选的，所述三层结构包括里层、中间层和无纺布层；优选的，所述内层选自聚乙烯透气膜、高透湿TPU膜、中透湿TPU膜中的任意一种；所述中间层为低透湿TPU膜、双胶纸、铜板纸、白卡纸、玻璃纸中的任意一种；所述无纺布层为PP无纺布、PET无纺布、淋膜无纺布中的任意一种；优选的，所述内层为聚乙烯透气膜，所述中间层为白卡纸，所述无纺布层为淋膜无纺布。当所述透湿包材为三层结构时，通过设计内层为聚乙烯透气膜，中间层为白卡纸，配合无纺布层为淋膜无纺布，在不影响调湿剂与外界环境进行水分传递以调节控制环境湿度为30％-95％的同时，提高使用安全性，制备工艺简单，成本较低，使用方便，可根据物品保存需要对双向调湿包的大小进行调整，满足不同物品的实际使用需求，适合大规模推广生产及使用。As a preferred technical solution, the moisture permeable packaging material is a three-layer structure; preferably, the three-layer structure includes an inner layer, a middle layer and a non-woven fabric layer; preferably, the inner layer is selected from any one of a polyethylene breathable film, a high moisture permeability TPU film, and a medium moisture permeability TPU film; the middle layer is any one of a low moisture permeability TPU film, offset paper, coated paper, white cardboard, and glassine paper; the non-woven fabric layer is any one of PP non-woven fabric, PET non-woven fabric, and laminated non-woven fabric; preferably, the inner layer is a polyethylene breathable film, the middle layer is white cardboard, and the non-woven fabric layer is a laminated non-woven fabric. When the moisture permeable packaging material has a three-layer structure, the inner layer is designed to be a polyethylene breathable film, the middle layer is white cardboard, and the non-woven fabric layer is a coated non-woven fabric. While not affecting the moisture transfer between the humidity control agent and the external environment to adjust and control the environmental humidity to 30%-95%, the safety of use is improved, the preparation process is simple, the cost is low, and it is easy to use. The size of the two-way humidity control bag can be adjusted according to the storage needs of the items to meet the actual use needs of different items. It is suitable for large-scale production and use.
所述聚乙烯透气膜购买自新乐华宝塑料薄膜有限公司；所述淋膜无纺布购买自东莞市恒达布业有限公司。The polyethylene breathable film was purchased from Xinle Huabao Plastic Film Co., Ltd.; the coated non-woven fabric was purchased from Dongguan Hengda Fabric Co., Ltd.
本发明另一方面提供了一种物品保存用双向调湿包的应用，适用于对保存环境的相对湿度要求较高的干花、雪茄、吉他物品的保存。On the other hand, the present invention provides an application of a two-way humidity-control bag for storing articles, which is suitable for storing dried flowers, cigars, and guitars that require a relatively high relative humidity in the storage environment.
有益效果：Beneficial effects:
1、本发明提供了一种高效、稳定的物品保存用双向调湿包，通过透湿包材包裹调节剂制备得到，制备工艺简单，成本较低，使用方便，安全性高，可调节控制环境湿度为30％-95％，可根据物品保存需要对双向调湿包的大小进行调整，满足不同物品的实际使用需求，适合大规模推广生产及使用。1. The present invention provides an efficient and stable two-way humidity-regulating bag for storing articles, which is prepared by wrapping a regulator with a moisture-permeable packaging material. The preparation process is simple, the cost is low, the use is convenient, and the safety is high. The environmental humidity can be adjusted to 30%-95%. The size of the two-way humidity-regulating bag can be adjusted according to the needs of article storage to meet the actual use needs of different articles. It is suitable for large-scale promotion, production and use.
2、采用明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合作为亲水性高分子化合物，尤其是当明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为(1.5-2)：(0.8-1.5)：(1.2-1.8)：(0.5-1)时，与体系中的调湿成分具有很好的匹配性，在不影响调湿成分调湿作用的条件下，使调湿成分均匀分散在亲水性高分子化合物形成的物理网状结构中，对调湿成分协同调节湿度具有促进作用，体系稳定性提高，有助于延长调湿包的有效使用时长。2. A combination of gelatin, gum arabic, methyl cellulose and guar gum is used as the hydrophilic polymer compound, especially when the mass ratio of gelatin, gum arabic, methyl cellulose and guar gum is (1.5-2): (0.8-1.5): (1.2-1.8): (0.5-1), which has a good match with the humidity-controlling components in the system. Under the condition of not affecting the humidity-controlling effect of the humidity-controlling components, the humidity-controlling components are evenly dispersed in the physical network structure formed by the hydrophilic polymer compound, which has a promoting effect on the synergistic humidity regulation of the humidity-controlling components, improves the stability of the system, and helps to extend the effective use time of the humidity-controlling bag.
3、本申请可以通过配方的调整，可根据物品所处环境有效快速调节湿度在特定的范围内，湿度调节范围宽达30％-95％，满足对保存环境的相对湿度要求较高的物品的保存需求。3. The present application can adjust the humidity within a specific range effectively and quickly according to the environment in which the article is located by adjusting the formula. The humidity adjustment range is as wide as 30%-95%, which can meet the storage needs of articles with high requirements on the relative humidity of the storage environment.
4、当调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，尤其是当所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为(6-10)：(2-4)：(3-7)：(5-8)时，配合亲水性高分子化合物和特定材质的透湿包材，可将环境湿度有效调节控制在65％-80％，效率高，不需要进行额外的后处理，避免资源浪费，尤其适用于干花、雪茄和吉他的保存。4. When the humidity-regulating component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide, especially when the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is (6-10):(2-4):(3-7):(5-8), in combination with a hydrophilic polymer compound and a moisture-permeable packaging material of a specific material, the ambient humidity can be effectively regulated and controlled at 65%-80%, with high efficiency, no need for additional post-processing, and avoidance of waste of resources. It is particularly suitable for the preservation of dried flowers, cigars and guitars.
具体实施方式Detailed ways
实施例1Example 1
本发明的实施例1一方面提供一种物品保存用双向调湿包，由透湿包材和调湿剂组成，所述双向调湿包通过透湿包材包裹调节剂制备得到。Embodiment 1 of the present invention provides a two-way humidity-regulating bag for storing articles, which is composed of a moisture-permeable packaging material and a humidity-regulating agent. The two-way humidity-regulating bag is prepared by wrapping the humidity-permeable packaging material with the humidity-regulating agent.
按重量百分计，所述调湿剂包括亲水性高分子化合物3％，调湿成分35％，水62％。In terms of weight percentage, the humidity control agent includes 3% of a hydrophilic polymer compound, 35% of a humidity control component, and 62% of water.
所述水为去离子水；The water is deionized water;
所述亲水性高分子化合物与调湿成分的质量比为3：35；The mass ratio of the hydrophilic polymer compound to the humidity-controlling component is 3:35;
所述亲水性高分子化合物为明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合；，所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为1.8：1.2：1.5：0.8。The hydrophilic polymer compound is a combination of gelatin, gum arabic, methyl cellulose and guar gum; the mass ratio of the gelatin, gum arabic, methyl cellulose and guar gum is 1.8:1.2:1.5:0.8.
所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶均购买自西格玛奥德里奇(上海)贸易有限公司。The gelatin, gum arabic, methyl cellulose and guar gum were all purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.
所述调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为8：3：5：6。The humidity-adjusting component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide, and the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is 8:3:5:6.
所述调湿剂的制备方法为：控制温度为35℃，按重量百分比将水、调湿成分加入容器中搅拌5min后，升温至60℃，加入亲水性高分子化合物，搅拌20min即得。The preparation method of the humidity control agent is as follows: controlling the temperature to 35° C., adding water and humidity control components according to weight percentage into a container and stirring for 5 minutes, raising the temperature to 60° C., adding a hydrophilic polymer compound, and stirring for 20 minutes to obtain the humidity control agent.
所述透湿包材为二层结构，所述二层结构通过淋膜，涂布，复合，热压制备得到；The moisture permeable packaging material is a two-layer structure, and the two-layer structure is prepared by lamination, coating, compounding, and hot pressing;
所述二层结构包括内层和外层；所述内层为防水透湿透气膜层，所述防水透湿透气膜层为TPU透湿膜，所述TPU透湿膜为TM-103WSE。所述外层为铜板纸；所述TM-103WSE型TPU透湿膜购买自嘉兴南雄高分子有限公司。The two-layer structure includes an inner layer and an outer layer; the inner layer is a waterproof, moisture-permeable and breathable membrane layer, the waterproof, moisture-permeable and breathable membrane layer is a TPU breathable membrane, and the TPU breathable membrane is TM-103WSE. The outer layer is coated paper; the TM-103WSE TPU breathable membrane is purchased from Jiaxing Nanxiong Polymer Co., Ltd.
实施例2Example 2
本发明的实施例2一方面提供一种物品保存用双向调湿包，由透湿包材和调湿剂组成，所述双向调湿包通过透湿包材包裹调节剂制备得到。Embodiment 2 of the present invention provides a two-way humidity-regulating bag for storing articles, which is composed of a moisture-permeable packaging material and a humidity-regulating agent. The two-way humidity-regulating bag is prepared by wrapping the humidity-permeable packaging material with the humidity-regulating agent.
按重量百分计，所述调湿剂包括亲水性高分子化合物3％，调湿成分35％，水62％。In terms of weight percentage, the humidity control agent includes 3% of a hydrophilic polymer compound, 35% of a humidity control component, and 62% of water.
所述水为去离子水；The water is deionized water;
所述亲水性高分子化合物与调湿成分的质量比为3：35；The mass ratio of the hydrophilic polymer compound to the humidity-controlling component is 3:35;
所述亲水性高分子化合物为明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合；，所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为1.8：1.2：1.5：0.8。The hydrophilic polymer compound is a combination of gelatin, gum arabic, methyl cellulose and guar gum; the mass ratio of the gelatin, gum arabic, methyl cellulose and guar gum is 1.8:1.2:1.5:0.8.
所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶均购买自西格玛奥德里奇(上海)贸易有限公司。The gelatin, gum arabic, methyl cellulose and guar gum were all purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.
所述调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为8：3：5：6。所述调湿剂的制备方法为：控制温度为35℃，按重量百分比将水、调湿成分加入容器中搅拌5min后，升温至60℃，加入亲水性高分子化合物，搅拌20min即得。The humidity control component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide, and the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is 8:3:5:6. The preparation method of the humidity control agent is: control the temperature to 35°C, add water and humidity control components according to weight percentage into a container and stir for 5 minutes, then heat to 60°C, add a hydrophilic polymer compound, and stir for 20 minutes to obtain the humidity control agent.
所述透湿包材为三层结构，所述三层结构通过淋膜，涂布，复合，热压制备得到；所述三层结构包括里层、中间层和无纺布层；所述内层为聚乙烯透气膜，所述中间层为白卡纸，所述无纺布层为淋膜无纺布。所述聚乙烯透气膜购买自新乐华宝塑料薄膜有限公司；所述淋膜无纺布购买自东莞市恒达布业有限公司。The moisture permeable packaging material is a three-layer structure, which is prepared by laminating, coating, compounding, and hot pressing; the three-layer structure includes an inner layer, an intermediate layer, and a non-woven fabric layer; the inner layer is a polyethylene breathable film, the intermediate layer is white cardboard, and the non-woven fabric layer is a laminated non-woven fabric. The polyethylene breathable film was purchased from Xinle Huabao Plastic Film Co., Ltd.; the laminated non-woven fabric was purchased from Dongguan Hengda Fabric Co., Ltd.
实施例3Example 3
本发明的实施例3一方面提供一种物品保存用双向调湿包，由透湿包材和调湿剂组成，所述双向调湿包通过透湿包材包裹调节剂制备得到。Embodiment 3 of the present invention provides a two-way humidity-regulating bag for storing articles, which is composed of a moisture-permeable packaging material and a humidity-regulating agent. The two-way humidity-regulating bag is prepared by wrapping the humidity-permeable packaging material with the humidity-regulating agent.
按重量百分计，所述调湿剂包括亲水性高分子化合物3％，调湿成分30％，水67％。In terms of weight percentage, the humidity control agent includes 3% of a hydrophilic polymer compound, 30% of a humidity control component, and 67% of water.
所述水为去离子水；The water is deionized water;
所述亲水性高分子化合物与调湿成分的质量比为3：30；The mass ratio of the hydrophilic polymer compound to the humidity-controlling component is 3:30;
所述亲水性高分子化合物为明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的组合；，所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶的质量比为2：1.5：1.8：1。The hydrophilic polymer compound is a combination of gelatin, gum arabic, methyl cellulose and guar gum; the mass ratio of the gelatin, gum arabic, methyl cellulose and guar gum is 2:1.5:1.8:1.
所述明胶、阿拉伯胶、甲基纤维素和瓜尔豆胶均购买自西格玛奥德里奇(上海)贸易有限公司。The gelatin, gum arabic, methyl cellulose and guar gum were all purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.
所述调湿成分为氯化钠、乳酸钠、氯化钾、溴化锂的组合，所述氯化钠、乳酸钠、氯化钾、溴化锂的质量比为6：4：5：5。The humidity-adjusting component is a combination of sodium chloride, sodium lactate, potassium chloride and lithium bromide, and the mass ratio of the sodium chloride, sodium lactate, potassium chloride and lithium bromide is 6:4:5:5.
所述调湿剂的制备方法为：控制温度为35℃，按重量百分比将水、调湿成分加入容器中搅拌5min后，升温至60℃，加入亲水性高分子化合物，搅拌20min即得。The preparation method of the humidity control agent is as follows: controlling the temperature to 35° C., adding water and humidity control components according to weight percentage into a container and stirring for 5 minutes, raising the temperature to 60° C., adding a hydrophilic polymer compound, and stirring for 20 minutes to obtain the humidity control agent.
所述透湿包材为二层结构，所述二层结构通过淋膜，涂布，复合，热压制备得到；The moisture permeable packaging material is a two-layer structure, and the two-layer structure is prepared by lamination, coating, compounding, and hot pressing;
所述二层结构包括内层和外层；所述内层为防水透湿透气膜层，所述防水透湿透气膜层为TPU透湿膜，所述TPU透湿膜为TM-103WSE。所述外层为铜板纸；所述TM-103WSE型TPU透湿膜购买自嘉兴南雄高分子有限公司。The two-layer structure includes an inner layer and an outer layer; the inner layer is a waterproof, moisture-permeable and breathable membrane layer, the waterproof, moisture-permeable and breathable membrane layer is a TPU breathable membrane, and the TPU breathable membrane is TM-103WSE. The outer layer is coated paper; the TM-103WSE TPU breathable membrane is purchased from Jiaxing Nanxiong Polymer Co., Ltd.
对比例1Comparative Example 1
本发明的对比例1提供了一种物品保存用双向调湿包，其具体实施方式同实施例1，不同之处在于，所述亲水性高分子化合物与调湿成分的质量比为0.5：50。Comparative Example 1 of the present invention provides a two-way humidity-conditioning bag for storing articles, and its specific implementation is the same as that of Example 1, except that the mass ratio of the hydrophilic polymer compound to the humidity-conditioning component is 0.5:50.
对比例2Comparative Example 2
本发明的对比例2提供了一种物品保存用双向调湿包，其具体实施方式同实施例2，不同之处在于，所述亲水性高分子化合物不包含甲基纤维素。Comparative Example 2 of the present invention provides a two-way humidity-conditioning bag for storing articles, and its specific implementation is the same as that of Example 2, except that the hydrophilic polymer compound does not contain methyl cellulose.
对比例3Comparative Example 3
本发明的对比例3提供了一种物品保存用双向调湿包，其具体实施方式同实施例1，不同之处在于，所述防水透湿透气膜层为低透湿TPU膜。Comparative Example 3 of the present invention provides a two-way humidity-regulating bag for storing articles, and its specific implementation is the same as that of Example 1, except that the waterproof, moisture-permeable, and breathable membrane layer is a low moisture-permeable TPU membrane.
性能测试方法Performance Testing Methods
1、双向调湿性能：(1)将实施例和对比例制备得到的双向调湿包(8g)置于湿度为65％的装有3只雪茄的雪茄盒中，记录雪茄盒中湿度调节至标准湿度为75％时所需时间t1，结果见表1。1. Bidirectional humidity control performance: (1) The bidirectional humidity control packs (8 g) prepared in the examples and comparative examples were placed in a cigar box containing 3 cigars at a humidity of 65%. The time t 1 required for the humidity in the cigar box to be adjusted to a standard humidity of 75% was recorded. The results are shown in Table 1.
(2)将实施例和对比例制备得到的双向调湿包(8g)置于湿度为80％的装有3只雪茄的雪茄盒中，记录雪茄盒中湿度调节至标准湿度为75％时所需时间t2，结果见表1。(2) The two-way humidity control packs (8 g) prepared in the examples and comparative examples were placed in a cigar box containing 3 cigars at a humidity of 80%. The time t 2 required for the humidity in the cigar box to be adjusted to a standard humidity of 75% was recorded. The results are shown in Table 1.
2、长效调湿性能：将实施例和对比例制备得到的双向调湿包(120g)置于湿度为65-85％的装有50只雪茄的雪茄盒中，记录雪茄盒中湿度调节至标准湿度为75％时所需时间t3；采用湿度计测定雪茄盒贮存4个月后的湿度，结果见表1。2. Long-term humidity control performance: The two-way humidity control bags (120 g) prepared in the examples and comparative examples were placed in a cigar box containing 50 cigars at a humidity of 65-85%, and the time t 3 required for the humidity in the cigar box to be adjusted to the standard humidity of 75% was recorded. The humidity of the cigar box after storage for 4 months was measured with a hygrometer. The results are shown in Table 1.
表1实施例1-3、对比例1-3制备的双向调湿包的性能测试结果。Table 1 Performance test results of the bidirectional humidity control packs prepared in Examples 1-3 and Comparative Examples 1-3.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111648406.7A CN115339772B (en) | 2021-12-30 | 2021-12-30 | Bidirectional humidity control bag for article preservation and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111648406.7A CN115339772B (en) | 2021-12-30 | 2021-12-30 | Bidirectional humidity control bag for article preservation and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115339772A CN115339772A (en) | 2022-11-15 |
| CN115339772B true CN115339772B (en) | 2024-06-04 |
Family
ID=83947003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111648406.7A Active CN115339772B (en) | 2021-12-30 | 2021-12-30 | Bidirectional humidity control bag for article preservation and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115339772B (en) |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0657277A2 (en) * | 1993-12-07 | 1995-06-14 | Mitsubishi Gas Chemical Company, Inc. | Sheet shaped oxygen absorbing member and method for manufacture thereof |
| US5936178A (en) * | 1997-06-10 | 1999-08-10 | Humidi-Pak, Inc. | Humidity control device |
| CN201010188Y (en) * | 2007-03-15 | 2008-01-23 | 沈跃华 | Ventilating anti-leaking back package material construction |
| CN203427406U (en) * | 2013-08-15 | 2014-02-12 | 上海衡元高分子材料有限公司 | Breathable anti-reverse osmosis packaging material structure |
| CN203510867U (en) * | 2013-08-22 | 2014-04-02 | 杭州帝凡建筑节能科技有限公司 | Novel waterproof vapor-penetrating film |
| CN105246579A (en) * | 2013-03-14 | 2016-01-13 | 波凡达股份有限公司 | Humidity control system for wood products |
| CN106273705A (en) * | 2015-05-21 | 2017-01-04 | 东莞市冰谷塑胶科技有限公司 | A technology to realize waterproof, moisture-permeable and breathable |
| CN108824075A (en) * | 2018-06-29 | 2018-11-16 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article manufacturing method |
| CN108842509A (en) * | 2018-06-29 | 2018-11-20 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article manufacturing method |
| CN109051340A (en) * | 2018-06-29 | 2018-12-21 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article |
| WO2019098684A1 (en) * | 2017-11-17 | 2019-05-23 | 주식회사 데시존 | Humidity indicator composition |
| CN111332595A (en) * | 2020-03-16 | 2020-06-26 | 湘潭宏达防潮保鲜技术开发有限公司 | Processing and manufacturing method of bidirectional humidity control bag for cigar preservation |
| CN215152667U (en) * | 2021-01-20 | 2021-12-14 | 嘉兴星越包装材料有限公司 | High-moisture-permeability cover film for dehumidification box and dehumidification box with same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6921026B2 (en) * | 2002-02-05 | 2005-07-26 | Albert L. Saari | Preservation of intermediate moisture foods by controlling humidity and inhibition of mold growth |
| US20070023939A1 (en) * | 2005-07-27 | 2007-02-01 | David Hepple | Humidifier |
| US20150201673A1 (en) * | 2014-01-23 | 2015-07-23 | Ismail Houmani | Humidity Controlled Cigar Package |
| US9750811B2 (en) * | 2015-09-15 | 2017-09-05 | Boveda, Inc. | Devices and methods for controlling headspace humidity and oxygen levels |
| WO2018071670A1 (en) * | 2016-10-12 | 2018-04-19 | Boveda Inc. | Device for controlling headspace humidity and methods for making the same |
-
2021
- 2021-12-30 CN CN202111648406.7A patent/CN115339772B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0657277A2 (en) * | 1993-12-07 | 1995-06-14 | Mitsubishi Gas Chemical Company, Inc. | Sheet shaped oxygen absorbing member and method for manufacture thereof |
| US5936178A (en) * | 1997-06-10 | 1999-08-10 | Humidi-Pak, Inc. | Humidity control device |
| CN201010188Y (en) * | 2007-03-15 | 2008-01-23 | 沈跃华 | Ventilating anti-leaking back package material construction |
| CN105246579A (en) * | 2013-03-14 | 2016-01-13 | 波凡达股份有限公司 | Humidity control system for wood products |
| JP2016520410A (en) * | 2013-03-14 | 2016-07-14 | ボベダ、インコーポレイテッド | Humidity control system for wood products |
| CN203427406U (en) * | 2013-08-15 | 2014-02-12 | 上海衡元高分子材料有限公司 | Breathable anti-reverse osmosis packaging material structure |
| CN203510867U (en) * | 2013-08-22 | 2014-04-02 | 杭州帝凡建筑节能科技有限公司 | Novel waterproof vapor-penetrating film |
| CN106273705A (en) * | 2015-05-21 | 2017-01-04 | 东莞市冰谷塑胶科技有限公司 | A technology to realize waterproof, moisture-permeable and breathable |
| WO2019098684A1 (en) * | 2017-11-17 | 2019-05-23 | 주식회사 데시존 | Humidity indicator composition |
| CN108824075A (en) * | 2018-06-29 | 2018-11-16 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article manufacturing method |
| CN108842509A (en) * | 2018-06-29 | 2018-11-20 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article manufacturing method |
| CN109051340A (en) * | 2018-06-29 | 2018-12-21 | 上海衡元高分子材料有限公司 | Ambient humidity adjusts article |
| CN111332595A (en) * | 2020-03-16 | 2020-06-26 | 湘潭宏达防潮保鲜技术开发有限公司 | Processing and manufacturing method of bidirectional humidity control bag for cigar preservation |
| CN215152667U (en) * | 2021-01-20 | 2021-12-14 | 嘉兴星越包装材料有限公司 | High-moisture-permeability cover film for dehumidification box and dehumidification box with same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115339772A (en) | 2022-11-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Shao et al. | Electrospun poly (vinyl alcohol)/permutite fibrous film loaded with cinnamaldehyde for active food packaging | |
| CN110055820A (en) | A kind of preparation method of the compound fresh-keeping paper base material of functionality for reinforcing sustained release | |
| JP6443246B2 (en) | Base paper for total heat exchanger element and manufacturing method thereof | |
| RU2011129466A (en) | METHOD FOR REGULATING DISPERSIBILITY AND BARRIER PROPERTIES OF DRIED NANOCRYSTALLINE CELLULOSE IN SOLUTIONS WITH VARIOUS pH AND IONIC POWER | |
| CN107663813A (en) | A kind of damp-prrof packing paper and compound glue application solution and their preparation method | |
| CN115339772B (en) | Bidirectional humidity control bag for article preservation and application thereof | |
| CN102783707A (en) | Air curing agent used in tobacco leaf storing and alcoholizing processes and preparation method thereof | |
| CN107814967B (en) | Mildew-proof preservative film and preparation method thereof | |
| CN109162146A (en) | A kind of corrugated paper with durable antibiotic fungicidal properties | |
| CN107129224A (en) | A kind of functional material with latent heat temperature adjustment and passive damping and its preparation method and application | |
| CN103144845A (en) | Special paper-plastic composite film for keeping freshness of fruits and vegetables at room temperature | |
| CN108824075B (en) | Manufacturing method of environmental humidity control article | |
| CN104432407B (en) | A kind of moisture film oxygen absorbent and preparation method thereof | |
| CN109098308A (en) | A kind of phase transformation damping outer wall structure of building body | |
| WO2025051147A1 (en) | Aluminum-free moisture-regulating lining paper for cigarette and preparation method therefor | |
| CN105602446B (en) | A kind of phase-change coating and preparation method and application | |
| CN102433797A (en) | Moisture-proof coating for paper products | |
| CN105266190B (en) | Humectant and preparation method thereof for improving expanded cut tobacco physics humid keeping performance | |
| CN102966005B (en) | Preparation method of high-efficiency compound humidity-controlling paperboard | |
| CN113201160B (en) | Humidity-control barrier composite film and preparation method and application thereof | |
| CN206079020U (en) | Special wet sheets that transfers of cigar | |
| CN108402380A (en) | A kind of preparation method of food desiccant | |
| CN111719339A (en) | A kind of food antibacterial wrapping paper that can be controlled by humidity and preparation method thereof | |
| CN205238911U (en) | Children for books virgin's milk glue of cardboard scribble layer structure | |
| CN101168937B (en) | Hygroscopic paper coated with guar gum-acrylic acid water-absorbing resin and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: No. 129, Xingpu North Road, Suqian, Luoshan, Jinjiang City, Quanzhou City, Fujian Province 362200 Patentee after: Fujian Huaying Technology Co.,Ltd. Country or region after: China Address before: No. 45, Suqian Industrial Zone, Luoshan, Jinjiang City, Quanzhou City, Fujian Province, 362200 Patentee before: Fujian Hua Sheng Chemical Co.,Ltd. Country or region before: China |