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CN108824075B - Manufacturing method of environmental humidity control article - Google Patents

Manufacturing method of environmental humidity control article Download PDF

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CN108824075B
CN108824075B CN201810697751.1A CN201810697751A CN108824075B CN 108824075 B CN108824075 B CN 108824075B CN 201810697751 A CN201810697751 A CN 201810697751A CN 108824075 B CN108824075 B CN 108824075B
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humidity
manufacturing
base material
conditioning
article
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CN108824075A (en
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沈跃华
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Shanghai Hengyuan polymer material Co.,Ltd.
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Shanghai Hengyuan Macromolecular Materials Co ltd
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Priority to PCT/CN2019/093699 priority patent/WO2020001620A1/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/365Coating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • D06M13/148Polyalcohols, e.g. glycerol or glucose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Drying Of Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

本发明提供了一种工艺简单,原材料便宜,调湿性能好,节约能源的环境湿度调节物品制造方法。本发明提供的环境湿度调节物品制造方法,用于将环境湿度调节控制在45~55%,包括以下步骤:步骤一,配置调湿组合物,将至少一种氯化盐和水在不低于40℃的情况下配置成调湿液;步骤二,在不低于40℃将所述基材在调湿液中以1~15m/s的速度涂布,使得每立方厘米基材中负载有0.64克所述调湿液,其中,有机酸盐为乳酸钠、乳酸钾和甲酸钠中的至少一种,多元醇中碳的数量不大于5,有机酸盐的质量分数范围是30.6~58.8%,多元醇的质量分数范围是9.3~26.7%。The invention provides a manufacturing method of environmental humidity regulating articles with simple process, cheap raw materials, good humidity regulation performance and energy saving. The manufacturing method of the environmental humidity adjustment article provided by the present invention is used for adjusting the environmental humidity to 45-55%, and includes the following steps: Step 1, configure a humidity-conditioning composition, mix at least one chloride salt and water at a temperature not lower than In the case of 40 ° C, it is configured as a humidity-conditioning liquid; in step 2, the substrate is coated in the humidity-conditioning solution at a speed of 1 to 15 m/s at a temperature not lower than 40 ° C, so that every cubic centimeter of the substrate is loaded with moisture. 0.64 g of the humidity-conditioning liquid, wherein the organic acid salt is at least one of sodium lactate, potassium lactate and sodium formate, the number of carbon in the polyol is not more than 5, the mass fraction of the organic acid salt is in the range of 30.6 to 58.8%, and the polyol The mass fraction of alcohol ranges from 9.3 to 26.7%.

Description

环境湿度调节物品制造方法Manufacturing method of environmental humidity control article

技术领域technical field

本发明具体涉及一种环境湿度调节物品制造方法。The invention particularly relates to a manufacturing method of an environmental humidity regulating article.

背景技术Background technique

“湿度”是影响各行各业的产品包装及储存保质期的重要因素。每个产品都需要一个合理的湿度范围来储存。例如,摄像镜头需要保存在45~55%的湿度范围,环境湿度低于该数值橡胶密封圈会老化;环境湿度高于该数值镜头会起雾。木质类乐器等产品的保存湿度是45~55%,环境湿度低于该数值会使得木质变形,从而影响音质;环境湿度高于该数值会使得木头发霉,或是因为木头吸收大量湿气发生木头的溶胀从而损坏木制品。"Humidity" is an important factor affecting product packaging and storage shelf life in all walks of life. Every product requires a reasonable humidity range for storage. For example, the camera lens needs to be stored in the humidity range of 45-55%. If the ambient humidity is lower than this value, the rubber sealing ring will age; if the ambient humidity is higher than this value, the lens will fog up. The storage humidity of wooden musical instruments and other products is 45-55%. If the ambient humidity is lower than this value, the wood will be deformed, which will affect the sound quality; swell and damage wood products.

为了将环境湿度控制45%~55%,常用的方式是采用调湿硅胶对环境进行调湿,但是调湿硅胶的使用不符合绿色环保产品。在生产调湿硅胶过程中产生大量的废水,为了环保很多硅胶原料工厂都关闭整顿。这导致各个行业把原来物料清单表中最不重要的干燥剂产品也开始列入重要物资的采购清单。In order to control the environmental humidity from 45% to 55%, the commonly used method is to use humidity-conditioning silica gel to adjust the humidity of the environment, but the use of humidity-conditioning silica gel is not in line with green environmental protection products. A large amount of waste water is generated in the process of producing humidity-adjusting silica gel. In order to protect the environment, many silica gel raw material factories have been closed for rectification. This has led to various industries to include the least important desiccant products in the original bill of materials list in the purchase list of important materials.

因而,目前急需一种调湿硅胶的替代品,而且该替代品的制造工艺必须符合绿色环保的主旨。Therefore, there is an urgent need for a substitute for humidity-adjusting silica gel, and the manufacturing process of the substitute must comply with the theme of green environmental protection.

发明内容SUMMARY OF THE INVENTION

本发明是为了解决上述问题而进行的,目的在于提供一种工艺简单,原材料便宜,调湿性能好,节约能源的环境湿度调节物品制造方法。The present invention is designed to solve the above problems, and aims to provide a method for manufacturing an environmental humidity-conditioning article with simple process, cheap raw materials, good humidity-conditioning performance and energy saving.

本发明提供了一种环境湿度调节物品制造方法,用于将环境湿度调节控制在45~55%,具有这样的特征,包括以下步骤:The present invention provides a manufacturing method of an environmental humidity regulation article, which is used to control the environmental humidity regulation at 45-55%, which has the characteristics of including the following steps:

步骤一,配置调湿液Step 1, configure the moisture conditioner

将至少一种氯化盐和水在不低于40℃的情况下配置成调湿液;At least one chloride salt and water are prepared into a moisturizing liquid at a temperature not lower than 40°C;

步骤二,在基材上涂布调湿液Step 2: Coat the moisture conditioner on the substrate

在不低于40℃将所述基材在调湿液中以1~15m/s的速度涂布,使得每立方厘米基材中负载有0.54~0.74克所述调湿液,其中,有机酸盐为乳酸钠、乳酸钾和甲酸钠中的至少一种,多元醇中碳的数量不大于5,在调湿液中,有机酸盐的质量分数范围是30.6~58.8%,多元醇的质量分数范围是9.3~26.7%。The substrate is coated in a humidity-conditioning liquid at a speed of 1-15 m/s at a temperature of not lower than 40°C, so that 0.54-0.74 grams of the humidity-conditioning liquid is loaded per cubic centimeter of the substrate, wherein the organic acid The salt is at least one of sodium lactate, potassium lactate and sodium formate, and the number of carbons in the polyol is not more than 5. In the humidity-conditioning liquid, the mass fraction of the organic acid salt ranges from 30.6 to 58.8%, and the mass fraction of the polyol ranges from 9.3 to 26.7%.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征:其中,有机酸盐的质量分数范围是44.4~46.2%,多元醇的质量分数范围是13.3~20.5%。In the manufacturing method of the environmental humidity conditioning article provided by the present invention, it may also have the following characteristics: wherein, the mass fraction range of the organic acid salt is 44.4-46.2%, and the mass fraction range of the polyol is 13.3-20.5%.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征:其中,有机酸盐为乳酸钠,多元醇为丙三醇。In the manufacturing method of the environmental humidity regulation article provided by the present invention, it may also have the following characteristics: wherein, the organic acid salt is sodium lactate, and the polyol is glycerol.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征:其中,有机酸盐为乳酸钠,多元醇为乙二醇。In the manufacturing method of the environmental humidity regulation article provided by the present invention, it can also have the following characteristics: wherein, the organic acid salt is sodium lactate, and the polyhydric alcohol is ethylene glycol.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征:其中,有机酸盐有两种,分别为乳酸钠和乳酸钾,多元醇为乙二醇,乳酸钠在调湿液中的质量分数范围是15.6~45%,所述乳酸钾在调湿液中的质量分数范围是10~30%,乳酸钠和所述乳酸钾的总质量分数在30.6~58.8%范围内。In the manufacturing method of the environmental humidity adjustment article provided by the present invention, it can also have the following characteristics: wherein, there are two kinds of organic acid salts, namely sodium lactate and potassium lactate, the polyol is ethylene glycol, and the sodium lactate in the humidity conditioning liquid is ethylene glycol. The mass fraction range is 15.6-45%, the mass fraction range of the potassium lactate in the humidity conditioning liquid is 10-30%, and the total mass fraction of the sodium lactate and the potassium lactate is within the range of 30.6-58.8%.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征,还包括:In the manufacturing method of the environmental humidity regulation article provided by the present invention, it can also have such features, and also include:

步骤三,裁切基材Step 3, cut the substrate

对基材进行裁切,使得基材达到预定的大小。The substrate is cut so that the substrate reaches a predetermined size.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征:其中,基材的材料为纸类材料、棉布、化纤类材料、无纺布、毛毡、多孔塑料、矿物基质中的任意一种。In the manufacturing method of the environmental humidity regulation article provided by the present invention, it may also have the following characteristics: wherein the material of the base material is paper material, cotton cloth, chemical fiber material, non-woven fabric, felt, porous plastic, mineral matrix any kind.

在本发明提供的环境湿度调节物品制造方法中,还可以具有这样的特征,还包括:In the manufacturing method of the environmental humidity regulation article provided by the present invention, it can also have such features, and also include:

步骤四,包装Step 4, Packaging

采用包裹袋对负载有调湿组合物的基材进行容纳包裹。The substrate loaded with the humidity-conditioning composition is contained and wrapped using a wrapping bag.

发明的作用与效果The role and effect of the invention

根据本发明所涉及的环境湿度调节物品制造方法,因为包括以下步骤:步骤一,配置调湿液;步骤二,在基材上涂布调湿液,其中,有机酸盐为乳酸钠、乳酸钾和甲酸钠中的至少一种,多元醇中碳的数量不大于5,在调湿液中,有机酸盐的质量分数范围是30.6~58.8%,多元醇的质量分数范围是9.3~26.7%,所以,本发明的环境湿度调节物品制造方法具有可以制造将环境湿度调节控制在45~55%的环境湿度调节物品,该环境湿度调节物品不需要对目标空间“预调”,吸放湿容量大,可以快速让目标环境达到预定湿度。According to the manufacturing method of the environmental humidity regulation article involved in the present invention, it includes the following steps: Step 1, configure a humidity-conditioning liquid; At least one of the sodium formate, the number of carbon in the polyol is not more than 5, in the humidity conditioning liquid, the mass fraction range of organic acid salt is 30.6-58.8%, and the mass fraction range of polyol is 9.3-26.7%, so, The manufacturing method of the environmental humidity regulating article of the present invention has the advantages of being able to manufacture the environmental humidity regulating article which can control the environmental humidity regulation at 45-55%, the environmental humidity regulating article does not need to "pre-adjust" the target space, has a large capacity for absorbing and releasing moisture, and can Quickly bring the target environment to the predetermined humidity.

不仅如此,本发明的环境湿度调节物品制造方法仅采用的是常见的乳酸钠、乳酸钾和甲酸钠,使用这些有机盐制备的组合物不仅成本低廉,而且在制造时对人体安全。当保护镜头或是木制乐器时,本发明的用于调节环境湿度的组合物完全不会腐蚀镜头或乐器,让使用者放心。而且,本发明的环境湿度调节物品制造方法制造出的环境湿度调节物品在废弃后对自然环境也依然友好,可被自然分解,不会造成二次污染。Not only that, the manufacturing method of the environmental humidity regulating article of the present invention only adopts the common sodium lactate, potassium lactate and sodium formate, and the composition prepared by using these organic salts is not only low in cost, but also safe for human body during manufacture. When protecting a lens or a wooden musical instrument, the composition for adjusting the environmental humidity of the present invention will not corrode the lens or the musical instrument at all, so that the user can be assured. Moreover, the environmental humidity regulating article manufactured by the method for manufacturing the environmental humidity regulating article of the present invention is still friendly to the natural environment after being discarded, and can be decomposed naturally without causing secondary pollution.

另外,本发明的环境湿度调节物品制造方法工艺简单,原材料便宜,调湿性能好,节约能源。在涂布步骤中基材上的调湿液涂布均匀。由于在制造和涂布调湿液时,温度都不低于40℃,所以在室温时有机酸盐在制备得到的环境湿度调节物品中处于过饱和的状态,从而可以调节环境湿度,进而保证物品处在适宜的湿度范围。In addition, the manufacturing method of the environmental humidity regulation article of the present invention has simple process, cheap raw materials, good humidity regulation performance and energy saving. In the coating step, the moisture-conditioning liquid on the substrate is uniformly coated. Since the temperature is not lower than 40°C during the manufacture and coating of the humidity-conditioning liquid, the organic acid salt is in a supersaturated state in the prepared ambient humidity conditioning article at room temperature, so that the ambient humidity can be adjusted, thereby ensuring the article in a suitable humidity range.

具体实施方式Detailed ways

为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解,以下实施例对本发明环境湿度调节物品制造方法作具体阐述。In order to make it easy to understand the technical means, creative features, achieved goals and effects of the present invention, the following embodiments specifically illustrate the manufacturing method of the environmental humidity regulation article of the present invention.

<实施例一><Example 1>

一种环境湿度调节物品制造方法,用于制造将环境湿度控制在45~55%的环境湿度调节物品,包括以下步骤:A method for manufacturing an environmental humidity regulating article, which is used for manufacturing an environmental humidity regulating article whose environmental humidity is controlled at 45-55%, comprises the following steps:

步骤一,配置调湿液Step 1, configure the moisture conditioner

将至少一种有机酸盐、至少一种多元醇和水在不低于40℃的情况下配置成调湿液。At least one organic acid salt, at least one polyol and water are prepared into a humidity conditioning liquid at a temperature of not lower than 40°C.

步骤二,在基材上涂布调湿液Step 2: Coat the moisture conditioner on the substrate

将基材在调湿液中以5~10m/s的速度涂布,涂布长度为3~10m,使得每立方厘米基材中负载有0.64克调湿液。The substrate is coated in the moisture-conditioning liquid at a speed of 5-10 m/s, and the coating length is 3-10 m, so that 0.64 grams of the moisture-conditioning liquid is loaded in the substrate per cubic centimeter.

步骤三,裁切基材Step 3, cut the substrate

对基材进行裁切,使得基材达到预定的大小,在本实施例中,该基材的厚度大于1mm,预定大小根据用户的需求进行设定,可从1cm×1cm~100cm×100cm。Cut the base material to make the base material reach a predetermined size. In this embodiment, the thickness of the base material is greater than 1 mm, and the predetermined size is set according to the user's needs, which can be from 1 cm × 1 cm to 100 cm × 100 cm.

基材具有一定的吸水性能,基材的吸水性能为每立方厘米基材吸水量不小于自身体积的100%。基材的材料为纸类材料、棉布、化纤类材料、无纺布、毛毡、多孔塑料中的任意一种。在本实施例一中,基材选用纸类材料中的棉木浆纸。该棉木浆纸的基材的吸水性能为每立方厘米基材吸水量不小于0.8克,保水性能为每立方厘米基材吸水量不小于1.2克。为了便于裁剪,该棉木浆纸的厚度为2mm。The base material has certain water absorption performance, and the water absorption performance of the base material is that the water absorption amount of the base material per cubic centimeter is not less than 100% of its own volume. The material of the base material is any one of paper material, cotton cloth, chemical fiber material, non-woven fabric, felt and porous plastic. In the first embodiment, the base material is cotton wood pulp paper among paper materials. The water absorption performance of the base material of the cotton wood pulp paper is that the water absorption capacity of the base material per cubic centimeter is not less than 0.8 grams, and the water retention performance is that the water absorption capacity of the base material per cubic centimeter is not less than 1.2 grams. In order to facilitate cutting, the thickness of the cotton-wood pulp paper is 2 mm.

在本实施例中,有机酸盐为乳酸钠。多元醇为丙三醇。In this embodiment, the organic acid salt is sodium lactate. The polyol is glycerol.

在调湿液中,乳酸钠的质量分数范围是30.6~58.8%。丙三醇的质量分数范围是9.3~26.7%。In the humidity-conditioning liquid, the mass fraction of sodium lactate ranges from 30.6 to 58.8%. The mass fraction of glycerol ranges from 9.3 to 26.7%.

乳酸钠的纯度为不小于99.9%。丙三醇的纯度为不小于99.9%。水为去离子水。The purity of sodium lactate is not less than 99.9%. The purity of glycerol is not less than 99.9%. The water is deionized water.

<实施例二><Example 2>

一种环境湿度调节物品制造方法,用于制造将环境湿度控制在45~55%的环境湿度调节物品,包括以下步骤:A method for manufacturing an environmental humidity regulating article, which is used for manufacturing an environmental humidity regulating article whose environmental humidity is controlled at 45-55%, comprises the following steps:

步骤一,配置调湿液Step 1, configure the moisture conditioner

将至少一种有机酸盐、至少一种多元醇和水在不低于40℃的情况下配置成调湿液。At least one organic acid salt, at least one polyol and water are prepared into a humidity conditioning liquid at a temperature of not lower than 40°C.

步骤二,在基材上涂布调湿液Step 2: Coat the moisture conditioner on the substrate

将基材在调湿液中以1~5m/s的速度涂布,涂布长度为2~6m,使得每立方厘米基材中负载有0.74克调湿液。The substrate is coated in the moisture-conditioning liquid at a speed of 1-5 m/s, and the coating length is 2-6 m, so that 0.74 grams of the moisture-conditioning liquid is loaded in the substrate per cubic centimeter.

步骤三,裁切基材Step 3, cut the substrate

对基材进行裁切,使得基材达到预定的大小,在本实施例中,该基材的厚度的范围在0.1~1mm,预定大小根据用户的需求进行设定,可从2cm×2cm~50cm×50cm。Cut the base material to make the base material reach a predetermined size. In this embodiment, the thickness of the base material is in the range of 0.1 to 1 mm, and the predetermined size is set according to the needs of the user, which can be from 2 cm × 2 cm to 50 cm. ×50cm.

在本实施例二中,有机酸盐为乳酸钠。多元醇为丙三醇。In the second embodiment, the organic acid salt is sodium lactate. The polyol is glycerol.

在调湿液中,乳酸钠的质量分数范围是44.4~46.2%。丙三醇的质量分数范围是13.3~20.5%。In the humidity conditioning liquid, the mass fraction of sodium lactate ranges from 44.4 to 46.2%. The mass fraction of glycerol ranges from 13.3 to 20.5%.

乳酸钠的纯度为不小于99.9%。丙三醇的纯度为不小于99.9%。水为去离子水。The purity of sodium lactate is not less than 99.9%. The purity of glycerol is not less than 99.9%. The water is deionized water.

当乳酸钠和丙三醇的质量分数大于分数范围时,组合物中容易产生结晶,需要高温才能将晶体溶解,损耗大,而且组合物的质量不稳定;当乳酸钠和丙三醇的质量分数小于分数范围时,基材上负载的调湿液中的调湿有效成分减少,调湿性能会发生降低。When the mass fraction of sodium lactate and glycerol is greater than the fraction range, crystallization is likely to occur in the composition, and high temperature is required to dissolve the crystals, the loss is large, and the quality of the composition is unstable; when the mass fraction of sodium lactate and glycerol is less than the fraction In the range, the humidity-conditioning active ingredient in the humidity-conditioning liquid supported on the substrate decreases, and the humidity-conditioning performance decreases.

<实施例三><Example 3>

一种环境湿度调节物品制造方法,用于制造将环境湿度控制在45~55%的环境湿度调节物品,包括以下步骤:A method for manufacturing an environmental humidity regulating article, which is used for manufacturing an environmental humidity regulating article whose environmental humidity is controlled at 45-55%, comprises the following steps:

步骤一,配置调湿液Step 1, configure the moisture conditioner

将至少一种有机酸盐、至少一种多元醇和水在不低于40℃的情况下配置成调湿液。At least one organic acid salt, at least one polyol and water are prepared into a humidity conditioning liquid at a temperature of not lower than 40°C.

步骤二,在基材上涂布调湿液Step 2: Coat the moisture conditioner on the substrate

在不低于40℃将基材在调湿液中以10~15m/s的速度涂布,使得每立方厘米基材中负载有0.54克调湿液。The substrate is coated in the moisture-conditioning liquid at a speed of 10-15 m/s at a temperature of not lower than 40° C., so that 0.54 grams of the moisture-conditioning liquid is loaded per cubic centimeter of the substrate.

步骤三,裁切基材Step 3, cut the substrate

对基材进行裁切,使得基材达到预定的大小,在本实施例中,该基材的厚度的范围在0.1~1mm,预定大小根据用户的需求进行设定,可从2cm×2cm~50cm×50cm。Cut the base material to make the base material reach a predetermined size. In this embodiment, the thickness of the base material is in the range of 0.1 to 1 mm, and the predetermined size is set according to the needs of the user, which can be from 2 cm × 2 cm to 50 cm. ×50cm.

步骤四,包装Step 4, Packaging

采用包裹袋对负载有调湿组合物的基材进行容纳包裹。The substrate loaded with the humidity-conditioning composition is contained and wrapped using a wrapping bag.

在本实施例三中,有机酸盐为乳酸钠。多元醇为乙二醇。In the third embodiment, the organic acid salt is sodium lactate. The polyol is ethylene glycol.

在调湿液中,乳酸钠的质量分数范围是44.4~46.2%。乙二醇的质量分数范围是13.3~20.5%。In the humidity conditioning liquid, the mass fraction of sodium lactate ranges from 44.4 to 46.2%. The mass fraction of ethylene glycol ranges from 13.3 to 20.5%.

乳酸钠的纯度为不小于99.9%。乙二醇的纯度为不小于99.9%。水为去离子水。The purity of sodium lactate is not less than 99.9%. The purity of ethylene glycol is not less than 99.9%. The water is deionized water.

包裹袋容纳负载有调湿层的基材。包裹袋由可渗透水蒸气但不渗透液态溶液的薄壁材料构成,例如无纺布、复合塑料袋、纸塑复合袋以及布袋中的任意一种。在本实施例三中,该材料为无纺布。The wrapping bag contains the substrate loaded with the moisture conditioning layer. The wrapping bag is composed of thin-walled materials that are permeable to water vapor but impermeable to liquid solutions, such as any one of non-woven fabrics, composite plastic bags, paper-plastic composite bags, and cloth bags. In the third embodiment, the material is non-woven fabric.

<实施例四><Example 4>

一种环境湿度调节物品制造方法,用于制造将环境湿度控制在45~55%的环境湿度调节物品,包括以下步骤:A method for manufacturing an environmental humidity regulating article, which is used for manufacturing an environmental humidity regulating article whose environmental humidity is controlled at 45-55%, comprises the following steps:

步骤一,配置调湿液Step 1, configure the moisture conditioner

将至少一种有机酸盐、至少一种多元醇和水在不低于40℃的情况下配置成调湿液。At least one organic acid salt, at least one polyol and water are prepared into a humidity conditioning liquid at a temperature of not lower than 40°C.

步骤二,在基材上涂布调湿液Step 2: Coat the moisture conditioner on the substrate

在不低于40℃将所述基材在调湿液中以1~15m/s的速度涂布,使得每立方厘米基材中负载有0.64克所述调湿液。The substrate is coated in the humidity conditioning liquid at a speed of 1-15 m/s at a temperature not lower than 40° C., so that 0.64 grams of the humidity conditioning liquid is loaded per cubic centimeter of the substrate.

步骤三,裁切基材Step 3, cut the substrate

对基材进行裁切,使得基材达到预定的大小,在本实施例中,该基材的厚度的范围在0.1~1mm,预定大小根据用户的需求进行设定,可从2cm×2cm~50cm×50cm。Cut the base material to make the base material reach a predetermined size. In this embodiment, the thickness of the base material is in the range of 0.1 to 1 mm, and the predetermined size is set according to the needs of the user, which can be from 2 cm × 2 cm to 50 cm. ×50cm.

在本实施例四中,有机酸盐为甲酸钠。多元醇为乙二醇。In the fourth embodiment, the organic acid salt is sodium formate. The polyol is ethylene glycol.

在调湿液中,甲酸钠的质量分数范围是44.4~46.2%。乙二醇的质量分数范围是13.3~20.5%。In the humidity conditioning liquid, the mass fraction of sodium formate ranges from 44.4 to 46.2%. The mass fraction of ethylene glycol ranges from 13.3 to 20.5%.

甲酸钠的纯度为不小于99.9%。乙二醇的纯度为不小于99.9%。水为去离子水。The purity of sodium formate is not less than 99.9%. The purity of ethylene glycol is not less than 99.9%. The water is deionized water.

包裹袋容纳负载有调湿层的基材。包裹袋由可渗透水蒸气但不渗透液态溶液的薄壁聚合物材料构成。在本实施例四中,该材料为聚酯。The wrapping bag contains the substrate loaded with the moisture conditioning layer. Wrappers are constructed of thin-walled polymeric materials that are permeable to water vapor but impermeable to liquid solutions. In the fourth embodiment, the material is polyester.

<实施例五><Example 5>

一种环境湿度调节物品制造方法,具体步骤同实施例一。A manufacturing method of an environmental humidity regulation article, the specific steps are the same as those of the first embodiment.

其中,有机酸盐为乳酸钾。多元醇为丙三醇。Among them, the organic acid salt is potassium lactate. The polyol is glycerol.

在调湿液中,乳酸钾的质量分数范围是44.4~46.2%。丙三醇的质量分数范围是13.3~20.5%。In the humidity-conditioning liquid, the mass fraction of potassium lactate ranges from 44.4 to 46.2%. The mass fraction of glycerol ranges from 13.3 to 20.5%.

乳酸钾的纯度为不小于99.9%。丙三醇的纯度为不小于99.9%。水为去离子水。The purity of potassium lactate is not less than 99.9%. The purity of glycerol is not less than 99.9%. The water is deionized water.

<实施例六><Example 6>

一种环境湿度调节物品制造方法,具体步骤同实施例一。A manufacturing method of an environmental humidity regulation article, the specific steps are the same as those of the first embodiment.

其中,有机酸盐为乳酸钾。多元醇为乙二醇。Among them, the organic acid salt is potassium lactate. The polyol is ethylene glycol.

在调湿液中,乳酸钾的质量分数范围是44.4~46.2%。乙二醇的质量分数范围是13.3~20.5%。In the humidity-conditioning liquid, the mass fraction of potassium lactate ranges from 44.4 to 46.2%. The mass fraction of ethylene glycol ranges from 13.3 to 20.5%.

乳酸钾的纯度为不小于99.9%。乙二醇的纯度为不小于99.9%。水为去离子水。The purity of potassium lactate is not less than 99.9%. The purity of ethylene glycol is not less than 99.9%. The water is deionized water.

<实施例七><Embodiment 7>

一种环境湿度调节物品制造方法,具体步骤同实施例一。A manufacturing method of an environmental humidity regulation article, the specific steps are the same as those of the first embodiment.

其中,有机酸盐为乳酸钠和乳酸钾。多元醇为乙二醇。Among them, the organic acid salts are sodium lactate and potassium lactate. The polyol is ethylene glycol.

在调湿液中,乳酸钠的质量分数范围是15.6~45%。乳酸钾的质量分数范围是10~30%。乳酸钠和乳酸钾的总质量分数在30.6~58.8%范围内。乙二醇的质量分数范围是13.3~20.5%。In the humidity conditioning liquid, the mass fraction of sodium lactate ranges from 15.6 to 45%. The mass fraction of potassium lactate ranges from 10 to 30%. The total mass fraction of sodium lactate and potassium lactate was in the range of 30.6-58.8%. The mass fraction of ethylene glycol ranges from 13.3 to 20.5%.

乳酸钠的纯度为不小于99.9%。乳酸钾的纯度为不小于99.9%。乙二醇的纯度为不小于99.9%。水为去离子水。The purity of sodium lactate is not less than 99.9%. The purity of potassium lactate is not less than 99.9%. The purity of ethylene glycol is not less than 99.9%. The water is deionized water.

以实施例二为例,调节不同湿度的乳酸钠、丙三醇和水的质量百分数为Taking embodiment two as an example, the mass percent of sodium lactate, glycerol and water regulating different humidity is

调节湿度(%)Regulated Humidity (%) 乳酸钠(%)Sodium lactate (%) 丙三醇(%)Glycerol(%) 水(%)water(%) 4545 45.545.5 20.520.5 34.034.0 5050 46.246.2 16.116.1 37.737.7 5555 44.444.4 13.313.3 42.342.3

采用本实施例二中的1千克的大小规格为0.42m2大小、0.3cm厚的环境湿度调节物品在25℃初始湿度范围在10~90%的情况下,对1立方米的密闭空间(无外界气体交换)进行调湿,在24小时内将环境湿度调节控制在45~55%内,调湿长期有效。如果该密闭空间中的气体长期与湿度范围为80%的外界气体进行交换,调湿有效时间为1个月。Using the 1 kilogram in the second embodiment with a size of 0.42 m 2 and a thickness of 0.3 cm for the environmental humidity conditioning article under the condition that the initial humidity range at 25 ° C is 10 to 90%, for a closed space of 1 cubic meter (without External air exchange) for humidity control, the environmental humidity is controlled within 45-55% within 24 hours, and the humidity control is effective for a long time. If the gas in the closed space is exchanged with the outside air with a humidity range of 80% for a long time, the effective time of humidity control is 1 month.

实施例的作用与效果Action and effect of the embodiment

根据本实施例所涉及的环境湿度调节物品制造方法,因为包括以下步骤:步骤一,配置调湿液;步骤二,在基材上涂布调湿液,其中,有机酸盐为乳酸钠、乳酸钾和甲酸钠中的至少一种,多元醇中碳的数量不大于5,在调湿液中,有机酸盐的质量分数范围是30.6~58.8%,多元醇的质量分数范围是9.3~26.7%,所以,本实施例的环境湿度调节物品制造方法具有可以制造将环境湿度调节控制在45~55%的环境湿度调节物品,该环境湿度调节物品不需要对目标空间“预调”,吸放湿容量大,可以快速让目标环境达到预定湿度。According to the method for manufacturing an environmental humidity conditioning article involved in this embodiment, it includes the following steps: step 1, configuring a humidity conditioning liquid; step 2, coating a humidity conditioning liquid on the substrate, wherein the organic acid salts are sodium lactate, potassium lactate and at least one of sodium formate, the number of carbon in the polyol is not more than 5, in the humidity conditioning liquid, the mass fraction range of organic acid salt is 30.6-58.8%, and the mass fraction range of polyol is 9.3-26.7%, so , the manufacturing method of the environmental humidity regulation article of this embodiment has the ability to manufacture the environmental humidity regulation article that can control the environmental humidity regulation at 45-55%, the environmental humidity regulation article does not need to "pre-adjust" the target space, and has a large moisture absorption and release capacity. , which can quickly make the target environment reach the predetermined humidity.

不仅如此,本实施例的环境湿度调节物品制造方法仅采用的是常见的乳酸钠、乳酸钾和甲酸钠,使用这些有机盐制备的组合物不仅成本低廉,而且在制造时对人体安全。当保护镜头或是木制乐器时,本实施例的用于调节环境湿度的组合物完全不会腐蚀镜头或乐器,让使用者放心。而且,本实施例的环境湿度调节物品制造方法制造出的环境湿度调节物品在废弃后对自然环境也依然友好,可被自然分解,不会造成二次污染。Not only that, the manufacturing method of the environmental humidity conditioning article of the present embodiment only adopts the common sodium lactate, potassium lactate and sodium formate, and the composition prepared by using these organic salts is not only low in cost, but also safe for human body during manufacture. When protecting a lens or a wooden musical instrument, the composition for adjusting the environmental humidity of this embodiment will not corrode the lens or the musical instrument at all, so that the user can be assured. Moreover, the environmental humidity regulating article manufactured by the method for manufacturing the environmental humidity regulating article of the present embodiment is still friendly to the natural environment after being discarded, and can be naturally decomposed without causing secondary pollution.

另外,本实施例的环境湿度调节物品制造方法工艺简单,原材料便宜,调湿性能好,节约能源。在涂布步骤中基材上的调湿液涂布均匀。由于在制造和涂布调湿液时,温度都不低于40℃,所以在室温时有机酸盐在制备得到的环境湿度调节物品中处于过饱和的状态,从而可以调节环境湿度,进而保证物品处在适宜的湿度范围。In addition, the manufacturing method of the environmental humidity regulation article of the present embodiment has simple process, cheap raw materials, good humidity regulation performance, and energy saving. In the coating step, the moisture-conditioning liquid on the substrate is uniformly coated. Since the temperature is not lower than 40°C during the manufacture and coating of the humidity-conditioning liquid, the organic acid salt is in a supersaturated state in the prepared ambient humidity conditioning article at room temperature, so that the ambient humidity can be adjusted, thereby ensuring the article in a suitable humidity range.

上述实施方式为本发明的优选案例,并不用来限制本发明的保护范围。The above embodiments are preferred cases of the present invention, and are not intended to limit the protection scope of the present invention.

在上述实施例中,本发明的环境湿度调节物品制造方法中的多元醇采用了丙三醇和乙二醇,但是作为本发明的环境湿度调节物品制造方法,碳的数量不大于5的多元醇均可以实现同样的效果。In the above-described embodiments, the polyols in the method for manufacturing an environmental humidity conditioning article of the present invention employ glycerol and ethylene glycol, but as the method for manufacturing an environmental humidity conditioning article of the present invention, polyols with a carbon number not greater than 5 are The same effect can be achieved.

Claims (3)

1. An ambient humidity conditioning article manufacturing method for manufacturing a cuttable ambient humidity conditioning article of a predetermined conditioning humidity which controls ambient humidity within a range of 45 to 55% without pre-conditioning a target space, comprising the steps of:
step one, preparing humidity adjusting liquid
Preparing sodium lactate, glycerol and water into a humidity-regulating liquid at the temperature of not lower than 40 ℃;
step two, coating the humidifying liquid on a base material capable of being cut
Coating the base material in a humidity-regulating solution at a speed of 1-5 m/s at a temperature of not less than 40 ℃, wherein the coating length is 2-6 m, so that 0.74 g of the humidity-regulating solution is loaded in each cubic centimeter of the base material, and the organic acid salt in the humidity-regulating article is in a supersaturated state at room temperature;
step three, cutting the base material
Cutting the base material to enable the base material to reach a preset size, wherein the preset size is 2cm multiplied by 2 cm-50 cm multiplied by 50cm,
wherein in the humidity-controlling liquid, the mass fraction range of the sodium lactate is 44.4-46.2%,
the mass fraction range of the glycerol is 13.3-20.5%,
the purity of the sodium lactate is not less than 99.9 percent, the purity of the glycerol is not less than 99.9 percent, the water is deionized water,
the thickness of the base material is 0.1-1 mm.
2. The ambient humidity adjustment article manufacturing method according to claim 1, characterized in that:
when the preset humidity is 45%, the mass fractions of sodium lactate, glycerol and water in the humidity adjusting liquid are 45.5%, 20.5% and 34.0% respectively;
when the preset humidity is 50%, the mass fractions of sodium lactate, glycerol and water in the humidity adjusting liquid are 46.2%, 16.1% and 37.7% respectively;
when the preset humidity is 55%, the mass fractions of sodium lactate, glycerol and water in the humidity adjusting liquid are 44.4%, 13.3% and 42.3%, respectively.
3. The method of manufacturing an ambient humidity conditioning article according to claim 1, further comprising:
step four, packaging
And adopting a wrapping bag to accommodate and wrap the base material loaded with the humidifying composition.
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