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CN115315055A - A microwave cold plasma jet device - Google Patents

A microwave cold plasma jet device Download PDF

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CN115315055A
CN115315055A CN202210842203.XA CN202210842203A CN115315055A CN 115315055 A CN115315055 A CN 115315055A CN 202210842203 A CN202210842203 A CN 202210842203A CN 115315055 A CN115315055 A CN 115315055A
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microwave
cold plasma
plasma jet
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CN115315055B (en
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于丙文
金伟
柏怡文
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Huzhou Institute of Zhejiang University
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Abstract

本发明公开一种微波冷等离子体射流装置,包括腔体部分,微波耦合部分,调谐部分,电场调制部分;腔体部分为一端开放的双谐振腔结构,微波传输模式为TEM模式;微波耦合部分可以电导耦合、电容耦合、磁耦合等方式将微波能量耦合到腔体部分;电场调制部分由施加纳秒脉冲(或DC电压)的由绝缘层包裹的内电极实现。本发明基于微波冷等离子体臭氧生成量少、等离子体浓度更高、激发态粒子更丰富,以及纳秒脉冲(或DC)更易形成长直冷等离子体的特点,提出的一种微波冷等离子体射流方法,即在微波冷等离子体上施加辅助电场,利用辅助电场牵引带电粒子加速运动,延长射流的长度。

Figure 202210842203

The invention discloses a microwave cold plasma jet device, comprising a cavity part, a microwave coupling part, a tuning part and an electric field modulation part; the cavity part is a double resonant cavity structure with one end open, and the microwave transmission mode is a TEM mode; the microwave coupling part The microwave energy can be coupled to the cavity part by means of conductance coupling, capacitive coupling, magnetic coupling, etc. The electric field modulation part is realized by the inner electrode wrapped by the insulating layer applying nanosecond pulse (or DC voltage). The invention proposes a microwave cold plasma based on the characteristics of less ozone generation, higher plasma concentration, more excited particles, and easier formation of long direct cold plasma by nanosecond pulse (or DC) in the microwave cold plasma. The jet method is to apply an auxiliary electric field to the microwave cold plasma, and use the auxiliary electric field to drag the charged particles to accelerate the movement, so as to prolong the length of the jet.

Figure 202210842203

Description

一种微波冷等离子体射流装置A microwave cold plasma jet device

技术领域technical field

本发明属于材料处理、材料检测、等离子体生物医学、临床医学等领域,具体的,涉及一种具有辅助电场的微波冷等离子体射流装置,可获得稳定的常压长直微波冷等离子体射流。The invention belongs to the fields of material processing, material detection, plasma biomedicine, clinical medicine, etc., and specifically relates to a microwave cold plasma jet device with an auxiliary electric field, which can obtain a stable normal-pressure long straight microwave cold plasma jet.

背景技术Background technique

等离子体由电子、离子、中性粒子等组成,当重粒子温度远低于电子温度时被称为冷等离子体。目前,大气压冷等离子体被广泛应用于废气处理、辅助燃烧、表面改性、医用灭菌、临床医学等领域。其中,大气压冷等离子体射流在开放空间中产生,其在输送活性物质和带电粒子的同时还实现了放电区域和工作区域分离,具有更高的安全性,因此在生物、临床医学等领域具有较好的应用前景。在实际应用中,射流长度是首要考虑的关键参数,其在很大程度上影响和制约了常压冷等离子体射流的应用。同时,等离子体成分也是需考虑的关键因素,其限制了等离子体射流的应用场景。Plasma is composed of electrons, ions, neutral particles, etc. When the temperature of heavy particles is much lower than that of electrons, it is called cold plasma. At present, atmospheric pressure-cooled plasma is widely used in waste gas treatment, auxiliary combustion, surface modification, medical sterilization, clinical medicine and other fields. Among them, the atmospheric pressure-cooled plasma jet is generated in an open space. While transporting active substances and charged particles, it also realizes the separation of the discharge area and the working area, which has higher safety. Therefore, it has great potential in the fields of biology and clinical medicine. Good application prospects. In practical applications, the jet length is the key parameter to be considered first, which largely affects and restricts the application of atmospheric pressure cold plasma jets. At the same time, the plasma composition is also a key factor to be considered, which limits the application scenarios of plasma jets.

冷等离子体可以通过高压、微波、射频等途径驱动相应装置生成,驱动方式及装置结构对射流长度及成分有重要影响。其中,微波冷等离子体射流具有电子密度大、电离度高、可控性强、臭氧生成量少等优势,可以高效应用于病菌灭活、伤口治疗、人体手术等各种场景。Cold plasma can be generated by driving corresponding devices through high pressure, microwave, radio frequency, etc. The driving method and device structure have an important impact on the length and composition of the jet. Among them, the microwave cold plasma jet has the advantages of high electron density, high degree of ionization, strong controllability, and low ozone generation, and can be efficiently used in various scenarios such as germ inactivation, wound treatment, and human surgery.

冷等离子体射流生成于开放空间中,空气的汇入导致射流长度较短,为解决该问题,目前通过三条途径延长射流长度。The cold plasma jet is generated in an open space, and the influx of air leads to a short jet length. To solve this problem, three methods are currently used to extend the jet length.

一者是使用大流量的惰性气体(氦气、氩气、氖气等)为工作气体,使得射流喷口处于击穿场强阈值相对较低的惰性气体环境利于等离子体形成,同时高流量的气体能牵引等离子体向外喷出;(如卢新培课题组于2008年提出的长达11cm的氦气等离子体射流,由正弦高压驱动包裹石英管的中心电极生成)One is to use a large flow rate of inert gas (helium, argon, neon, etc.) It can pull the plasma out; (such as the 11cm-long helium plasma jet proposed by Lu Xinpei’s research group in 2008, which is generated by a central electrode wrapped in a quartz tube driven by a sinusoidal high voltage)

二者是通过高压纳秒脉冲驱动,在极高且极快的能量输入下等离子体射流长度被观察到显著增长;The two are driven by high-voltage nanosecond pulses, and the length of the plasma jet is observed to increase significantly under extremely high and extremely fast energy input;

三者是通过复合式同轴双线的结构,以双谐振腔配合双气流约束的方式调控等离子体射流形状(对应专利号CN201910658894.6)。The three are to control the shape of the plasma jet by means of dual resonant cavities and dual airflow constraints through a composite coaxial double-wire structure (corresponding to patent number CN201910658894.6).

1)使用惰性气体为工作气体时,需配备大型气瓶,携带不便,不适用于户外、接地取材等工作环境,并且该等离子体射流不适合应用于一些特殊环境(如肺部处理等);1) When using inert gas as the working gas, it needs to be equipped with a large gas cylinder, which is inconvenient to carry, and is not suitable for working environments such as outdoors and grounding materials, and the plasma jet is not suitable for some special environments (such as lung treatment, etc.);

2)在常用的工作气体中,空气因其无需配备气瓶、便携易操作等优势而具有更广的应用前景,但也有击穿场强阈值远大于惰性气体、使用高压驱动介质阻挡放电等方式激发放电时生成大量臭氧等问题,在应用于临床医学时不利于处理对象的健康;2) Among the commonly used working gases, air has wider application prospects because it does not need to be equipped with gas cylinders, is portable and easy to operate, but there are also methods such as the breakdown field strength threshold is much higher than that of inert gases, and the use of high voltage to drive dielectric barrier discharge. A large amount of ozone is generated when the discharge is excited, which is not conducive to the health of the treated object when it is used in clinical medicine;

3)由气流主导牵引等离子体射流喷出时,被处理的病原体等医学对象可能会在气流的扰动下脱离所处位置,有引起生化污染的潜在问题;3) When the plasma jet is ejected by the leading traction of the air flow, the treated pathogens and other medical objects may leave their positions under the disturbance of the air flow, which may cause potential problems of biochemical pollution;

4)通过复合式同轴双线及双气流的方式生成微波冷等离子体射流时,由于其开口端均为直管结构,电场强度未进一步增强,较难达到空气微波冷等离子体的激发场强,这制约了其在空气为工作气体时的应用。4) When the microwave cold plasma jet is generated by means of composite coaxial double wires and double air flow, since its opening ends are all straight tube structures, the electric field strength is not further enhanced, and it is difficult to achieve the excitation field strength of air microwave cold plasma , which restricts its application when air is the working gas.

发明内容Contents of the invention

为解决以上现有技术存在的问题,本发明提出一种微波冷等离子体射流装置。In order to solve the above problems in the prior art, the present invention proposes a microwave cold plasma jet device.

本发明可通过以下技术方案予以实现:The present invention can be realized through the following technical solutions:

一种微波冷等离子体射流装置,由腔体部分、微波耦合部分、调谐部分和电场调制部分组成;A microwave cold plasma jet device, which consists of a cavity part, a microwave coupling part, a tuning part and an electric field modulation part;

所述腔体部分为一端开放的外管、两端开放的中管、内电极同轴谐振腔结构,外管上设有微波馈入端口、切向流屏蔽气入口,中管上设有气体入口;The cavity part is an outer tube with one end open, a middle tube with both ends open, and an inner electrode coaxial resonant cavity structure. The outer tube is provided with a microwave feeding port and a tangential flow shielding gas inlet, and the middle tube is provided with a gas Entrance;

所述微波耦合部分包括耦合环,将微波能量耦合到所述腔体部分;The microwave coupling portion includes a coupling ring to couple microwave energy to the cavity portion;

所述调谐部分为调谐端对谐振腔长度进行调节的结构,以调节开口端场强,调谐端上端为反射端面;所述调谐端调整至腔体部分的深度为Yλ/4,其中λ为所述微波频率下的波长,Y为正奇数;The tuning part is a structure in which the tuning end adjusts the length of the resonant cavity to adjust the field strength at the opening end. The wavelength under the microwave frequency, Y is a positive odd number;

所述电场调制部分为施加纳秒脉冲/DC电压与内电极相连,内电极由同轴绝缘层包裹。The electric field modulation part is connected to the internal electrode for applying nanosecond pulse/DC voltage, and the internal electrode is wrapped by a coaxial insulating layer.

进一步地,所述外管、中管、内电极均为金属材质,外管与中管之间、中管与内电极之间的微波传输模式均为TEM模式。Further, the outer tube, the middle tube, and the inner electrode are all made of metal, and the microwave transmission modes between the outer tube and the middle tube, and between the middle tube and the inner electrode are all TEM modes.

进一步地,所述外管的轴向长度为Nλ/4,其中,λ为所述微波频率下的波长,N为正奇数。Further, the axial length of the outer tube is Nλ/4, where λ is the wavelength at the microwave frequency, and N is a positive odd number.

进一步地,所述外管、中管上端口为渐变收口结构,所述外管收口为0~60°,所述中管收口为0~30°。Further, the upper ports of the outer tube and the middle tube have a gradual closing structure, the closing of the outer tube is 0-60°, and the closing of the middle tube is 0-30°.

进一步地,所述中管、同轴绝缘层之间有上表面为金属材质的多孔同轴垫圈,该多孔同轴垫圈的上表面距所述腔体部分开口端端口的距离范围为

Figure BDA0003750745870000021
其中λ为所述微波频率下的波长,M为正奇数。Further, between the middle tube and the coaxial insulating layer, there is a porous coaxial gasket whose upper surface is made of metal, and the distance between the upper surface of the porous coaxial gasket and the port at the opening end of the cavity part is in the range of
Figure BDA0003750745870000021
Wherein λ is the wavelength at the microwave frequency, and M is a positive odd number.

进一步地,所述内电极插入同轴绝缘层的容腔,同轴绝缘层内层包覆在内电极的外侧。Further, the inner electrode is inserted into the cavity of the coaxial insulating layer, and the inner layer of the coaxial insulating layer covers the outer side of the inner electrode.

进一步地,所述中管上端口不高于外管,所述内电极及同轴绝缘层上端可高/低于中管。Further, the upper port of the middle tube is not higher than the outer tube, and the upper end of the inner electrode and the coaxial insulating layer can be higher/lower than the middle tube.

进一步地,所述外管、中管通过屏蔽气入口处或气体入口引入气体。Further, the outer tube and the middle tube introduce gas through the shielding gas inlet or the gas inlet.

进一步地,所述屏蔽气入口处以切向流的方式引入;所述的屏蔽气入口、气体入口的气体流速控制在0~20L/min。Further, the shielding gas inlet is introduced in a tangential flow; the gas flow rate of the shielding gas inlet and the gas inlet is controlled at 0-20 L/min.

进一步地,所述耦合环与外管上端口间距可调;所述微波等离子体射流装置适用电磁波频率范围为几MHz~几GHz。Further, the distance between the coupling ring and the upper port of the outer tube is adjustable; the microwave plasma jet device is suitable for electromagnetic wave frequencies ranging from several MHz to several GHz.

进一步地,所述纳秒脉冲电源的输出脉宽为10~900ns,上升沿为1~200ns,振幅为3~220kV,频率为1~20kHz,占空比为1~99%;所述DC电源的输出电压为0~60kV或0~-60kV。Further, the output pulse width of the nanosecond pulse power supply is 10-900ns, the rising edge is 1-200ns, the amplitude is 3-220kV, the frequency is 1-20kHz, and the duty cycle is 1-99%; the DC power supply The output voltage is 0~60kV or 0~-60kV.

有益效果Beneficial effect

本发明使用微波源驱动双谐振腔结构生成温度低、易调节、可手持操作的常压微波冷等离子体射流,并在此基础上引入有高压形成的辅助电场,牵引微波等离子体中极大密度的带电粒子向喷口外运动,以此延长射流长度。本发明以电场主导牵引带电粒子运动,有效避免了由气流扰动而可能造成的生化污染。同时,高压可驱动生成冷等离子体,能在炬管端口处辅助点火,利于微波等离子体射流的形成并提高其稳定性。其中,因于纳秒脉冲/DC高压与微波的工作频率差异较大,在等离子体谐振器中直流电场与微波场可实现场解耦。此外,微波冷等离子体生成装置基于微波等离子体炬(MPT)变形,于外管及中管上端加入渐变收口结构,用于调控开口端电场。而中心电极外的绝缘层可防止鞘层电压过高促使带电粒子产生对放电电极的轰击作用,提高了电极使用寿命,并使得射流装置整体可接触,提高了安全性。The invention uses a microwave source to drive a double-resonant cavity structure to generate a low-temperature, easy-to-adjust, and handheld-operated normal-pressure microwave cold plasma jet, and on this basis, introduces an auxiliary electric field formed by a high voltage to pull the maximum density in the microwave plasma. The charged particles move out of the nozzle, thereby extending the length of the jet. The invention uses the electric field to guide the movement of the charged particles, effectively avoiding the possible biochemical pollution caused by the disturbance of the air flow. At the same time, the high pressure can drive the generation of cold plasma, which can assist ignition at the port of the torch tube, which is beneficial to the formation of microwave plasma jet and improves its stability. Among them, due to the large difference in operating frequency between nanosecond pulse/DC high voltage and microwave, the DC electric field and microwave field can realize field decoupling in the plasma resonator. In addition, the microwave cold plasma generation device is based on the deformation of the microwave plasma torch (MPT), and a gradual closing structure is added to the upper end of the outer tube and the middle tube to control the electric field at the opening end. The insulating layer outside the center electrode can prevent the charged particles from bombarding the discharge electrode due to the high voltage of the sheath layer, which improves the service life of the electrode, and makes the jet device as a whole accessible, improving safety.

附图说明Description of drawings

图1是根据本发明专利的结构示意图;Fig. 1 is a structural schematic diagram according to the patent of the present invention;

图2是根据本发明专利的另一种结构示意图。Fig. 2 is another structural schematic diagram according to the patent of the present invention.

具体实施方式Detailed ways

以下通过特定的具体实施例说明本发明的实施方式,本领域的技术人员可由本说明书所揭示的内容轻易地了解本发明的其他优点及功效。The implementation of the present invention is described below through specific specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification.

具体实施例1Specific embodiment 1

具体实施例1给出本发明专利的复合调制微波冷等离子体射流装置,并结合图1给出其中一种典型结构示意图。Specific embodiment 1 presents the composite modulation microwave cold plasma jet device of the patent of the present invention, and a typical structural diagram thereof is provided in conjunction with FIG. 1 .

所述复合场调制微波冷等离子体射流装置由腔体部分、微波耦合部分、调谐部分和电场调制部分组成;The composite field modulated microwave cold plasma jet device is composed of a cavity part, a microwave coupling part, a tuning part and an electric field modulation part;

参见图1,本发明的微波冷等离子体射流装置,包括微波馈入端口1、外管2、调谐端3、中管4、中心内电极5、耦合环6、多孔同轴垫圈7、同轴绝缘层8、切向流屏蔽气入口9、纳秒脉冲/DC高压输入端10、气体入口11;Referring to Fig. 1, the microwave cold plasma jet device of the present invention includes a microwave feed port 1, an outer tube 2, a tuning end 3, a middle tube 4, a central inner electrode 5, a coupling ring 6, a porous coaxial gasket 7, a coaxial Insulation layer 8, tangential flow shielding gas inlet 9, nanosecond pulse/DC high voltage input terminal 10, gas inlet 11;

所述腔体部分为一端开放的外管2、两端开放的中管4、中心内电极5同轴谐振腔结构;The cavity part is an outer tube 2 with one end open, a middle tube 4 with both ends open, and a coaxial resonant cavity structure with a central inner electrode 5;

所述外管2、中管4、内电极5均为金属材质,外管2与中管4之间、中管4与内电极5之间的微波传输模式均为TEM模式,内电极5与辅助电源(DC或纳秒脉冲调制源)连接;The outer tube 2, the middle tube 4, and the inner electrode 5 are all made of metal, and the microwave transmission modes between the outer tube 2 and the middle tube 4, and between the middle tube 4 and the inner electrode 5 are all TEM modes, and the inner electrode 5 and the inner electrode 5 are all in the TEM mode. Auxiliary power supply (DC or nanosecond pulse modulation source) connection;

所述外管2的轴向长度为Nλ/4(λ为所述微波频率下的波长,N为正奇数);The axial length of the outer tube 2 is Nλ/4 (λ is the wavelength at the microwave frequency, and N is a positive odd number);

所述外管2、中管4上端口为渐变收口结构,所述外管2收口为0~60°,所述中管4收口为0~30°,该设计用于调整端口处电场;The upper ports of the outer tube 2 and the middle tube 4 have a gradual closing structure, the closing of the outer tube 2 is 0-60°, and the closing of the middle tube 4 is 0-30°, which is designed to adjust the electric field at the ports;

所述中管4、同轴绝缘层8之间有上表面为金属材质的多孔同轴垫圈7,多孔同轴垫圈7的上表面距腔体部分开口端端口的距离范围为

Figure BDA0003750745870000031
(λ为所述微波频率下的波长,M为正奇数);Between the middle tube 4 and the coaxial insulating layer 8, there is a porous coaxial gasket 7 whose upper surface is made of metal, and the distance between the upper surface of the porous coaxial gasket 7 and the opening port of the cavity part is
Figure BDA0003750745870000031
(λ is the wavelength under the microwave frequency, and M is a positive odd number);

所述中心内电极插入同轴绝缘层8的容腔,绝缘层内层包覆在中心内电极的外侧;所述同轴绝缘层8上端封闭,优选的,使用上端封闭的石英管;The central inner electrode is inserted into the cavity of the coaxial insulating layer 8, and the inner layer of the insulating layer is coated on the outside of the central inner electrode; the upper end of the coaxial insulating layer 8 is closed, preferably, a quartz tube with an upper end closed;

所述中管4上端口不高于外管,所述内电极5及绝缘层上端可高/低于中管,优选的,中管4上端低于外管上端口0~2mm,内电极5上端位于中管上端口-5~5mm;图1中包裹绝缘层的内电极上端与中管4上端口齐平;The upper port of the middle tube 4 is not higher than the outer tube, and the upper end of the inner electrode 5 and the insulating layer can be higher/lower than the middle tube. Preferably, the upper end of the middle tube 4 is 0-2mm lower than the upper port of the outer tube, and the inner electrode 5 The upper end is located at the upper port of the middle tube -5 ~ 5mm; the upper end of the inner electrode wrapped with the insulating layer in Figure 1 is flush with the upper port of the middle tube 4;

所述外管2、中管4可引入气体,优选的,屏蔽气入口9处以切向流的方式引入;所述的屏蔽气入口9、气体入口11的气体流速控制在0~20L/min;The outer pipe 2 and the middle pipe 4 can introduce gas, preferably, the shielding gas inlet 9 is introduced in a tangential flow; the gas flow rate of the shielding gas inlet 9 and the gas inlet 11 is controlled at 0-20L/min;

微波耦合部分可选的以电导耦合、电容耦合等方式将微波能量耦合到腔体部分;图1中给出以电导耦合将微波能量引入谐振腔的结构示意图;所述耦合环6与外管2上端口间距可调;所述微波等离子体射流装置适用电磁波频率范围为几MHz~几GHz,优选的,使用2.45GHz频率下产生5~40mm长度的稳定常压微波冷等离子体射流,微波功率转化效率大于80%。The microwave coupling part can optionally couple microwave energy to the cavity part by means of conductance coupling, capacitive coupling, etc.; Figure 1 shows a schematic structural diagram of introducing microwave energy into the resonator cavity by conductance coupling; the coupling ring 6 and the outer tube 2 The distance between the upper ports is adjustable; the microwave plasma jet device is suitable for electromagnetic wave frequency ranges from several MHz to several GHz. Preferably, a stable atmospheric pressure microwave cold plasma jet with a length of 5 to 40 mm is generated at a frequency of 2.45 GHz, and the microwave power is converted into The efficiency is greater than 80%.

所述调谐部分为调谐端3对谐振腔长度进行调节的结构,以调节开口端场强,调谐端上端为反射端面,其材质为金属材质;所述调谐端调整至腔体部分的深度为Yλ/4(λ为所述微波频率下的波长,Y为正奇数);The tuning part is a structure in which the tuning end 3 adjusts the length of the resonant cavity to adjust the field strength at the opening end. The upper end of the tuning end is a reflective end surface, and its material is a metal material; the depth of the tuning end adjusted to the cavity part is Yλ /4 (λ is the wavelength under the microwave frequency, Y is a positive odd number);

所述电场调制部分为辅助电源(纳秒脉冲或DC电压)与内电极5相连;所述纳秒脉冲电源的输出脉宽为10~900ns,上升沿为1~200ns,振幅为3~220kV,频率为1~20kHz,占空比为1~99%;所述DC电源的输出电压为0~60kV或0~-60kV;In the electric field modulation part, an auxiliary power supply (nanosecond pulse or DC voltage) is connected to the inner electrode 5; the output pulse width of the nanosecond pulse power supply is 10-900 ns, the rising edge is 1-200 ns, and the amplitude is 3-220 kV. The frequency is 1-20kHz, and the duty cycle is 1-99%; the output voltage of the DC power supply is 0-60kV or 0-60kV;

所述的微波等离子体射流装置可以下述18种方法进行工作:The described microwave plasma jet device can work in the following 18 ways:

1)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,纳秒脉冲电源连接至包裹同轴绝缘管的中心内电极,等离子体在谐振腔上端口轴线位置形成,并由脉冲电场驱动下向外喷出;1) The microwave is coupled into the resonant cavity through the microwave coupling part, and a TEM standing wave is formed in the resonant cavity. The nanosecond pulse power supply is connected to the central inner electrode wrapped in the coaxial insulating tube, and the plasma is formed at the axial position of the upper port of the resonant cavity, and Driven by a pulsed electric field, it is ejected outward;

2)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,高压(正/负)2) The microwave is coupled into the resonant cavity through the microwave coupling part, and a TEM standing wave is formed in the resonant cavity, and the high voltage (positive/negative)

电源连接至包裹同轴绝缘管的中心内电极,等离子体在谐振腔上端口轴线位置形成,并由高压电场驱动下向外喷出;The power supply is connected to the central inner electrode wrapped in the coaxial insulating tube, and the plasma is formed at the axial position of the upper port of the resonant cavity, and is ejected outwards driven by a high-voltage electric field;

3)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,等离子体在谐振腔上端口轴线位置形成并向外喷出;3) The microwave is coupled into the resonant cavity through the microwave coupling part, forming a TEM standing wave in the resonant cavity, and the plasma is formed at the axial position of the upper port of the resonant cavity and ejected outward;

4)纳秒脉冲电源连接至包裹同轴绝缘管的中心内电极,等离子体在内电极上端形成并向外喷出;4) The nanosecond pulse power supply is connected to the central inner electrode wrapped in the coaxial insulating tube, and the plasma is formed on the upper end of the inner electrode and ejected outward;

5)DC高压(正/负)电源连接至包裹同轴绝缘管的中心内电极,等离子体在内电极上端形成并向外喷出;5) The DC high-voltage (positive/negative) power supply is connected to the central inner electrode wrapped in the coaxial insulating tube, and the plasma is formed on the upper end of the inner electrode and ejected outward;

6)基于方法1),外管不与地线相连,以无穷远端为地线;6) Based on method 1), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

7)基于方法2),外管不与地线相连,以无穷远端为地线;7) Based on method 2), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

8)基于方法4),外管不与地线相连,以无穷远端为地线;8) Based on method 4), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

9)基于方法5),外管不与地线相连,以无穷远端为地线;9) Based on method 5), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

10)基于方法1),气体(单一/混合)由入口9、入口11输入,协同脉冲电场驱动微波等离子体射流喷出,并调整等离子体成分;10) Based on method 1), the gas (single/mixed) is input from the inlet 9 and the inlet 11, and the microwave plasma jet is driven by the pulsed electric field to eject, and the plasma composition is adjusted;

11)基于方法2),气体(单一/混合)由入口9、入口11输入,协同高压电场驱动微波等离子体射流喷出,并调整等离子体成分;11) Based on method 2), the gas (single/mixed) is input from the inlet 9 and the inlet 11, and the high-voltage electric field is used to drive the microwave plasma jet to eject and adjust the plasma composition;

12)基于方法3),气体(单一/混合)由入口9、入口11输入,牵引微波等离子体射流喷出,并调整等离子体成分;12) Based on method 3), the gas (single/mixed) is input from the inlet 9 and the inlet 11, and the microwave plasma jet is pulled to be ejected, and the plasma composition is adjusted;

13)基于方法4),气体(单一/混合)由入口9、入口11输入,牵引纳秒脉冲驱动的冷等离子体射流喷出,并调整等离子体成分;13) Based on method 4), the gas (single/mixed) is input from the inlet 9 and the inlet 11, and the cold plasma jet driven by nanosecond pulse is drawn to eject, and the plasma composition is adjusted;

14)基于方法5),气体(单一/混合)由入口9、入口11输入,牵引纳秒脉冲驱动的冷等离子体射流喷出,并调整等离子体成分;14) Based on method 5), the gas (single/mixed) is input from the inlet 9 and the inlet 11, and the cold plasma jet driven by the nanosecond pulse is pulled out, and the plasma composition is adjusted;

15)基于方法1),同轴绝缘层为绝缘涂层;15) Based on method 1), the coaxial insulating layer is an insulating coating;

16)基于方法2),同轴绝缘层为绝缘涂层;16) Based on method 2), the coaxial insulating layer is an insulating coating;

17)基于方法4),同轴绝缘层为绝缘涂层;17) Based on method 4), the coaxial insulating layer is an insulating coating;

18)基于方法5),同轴绝缘层为绝缘涂层;18) Based on method 5), the coaxial insulating layer is an insulating coating;

具体实施例2Specific embodiment 2

图2给出了根据本发明专利的另一种结构示意图,该结构支持双谐振腔、辅助电场及三气流协同调制微波冷等离子体射流长度;Figure 2 shows another structural schematic diagram according to the patent of the present invention, which supports dual resonant cavities, auxiliary electric field and three airflows to coordinately modulate the length of the microwave cold plasma jet;

所述复合场调制微波冷等离子体射流装置由腔体部分、微波耦合部分、调谐部分和电场调制部分组成;The composite field modulated microwave cold plasma jet device is composed of a cavity part, a microwave coupling part, a tuning part and an electric field modulation part;

参见图2,本发明的复合场调制微波冷等离子体射流装置,包括微波馈入端口1、外管2、调谐端3、中管4、耦合环6、多孔同轴垫圈7、切向流屏蔽气入口9、纳秒脉冲/DC高压输入端、中管进气口11、毛细管进气口12、毛细管内电极13、同轴绝缘管14;Referring to Fig. 2, the composite field modulated microwave cold plasma jet device of the present invention includes a microwave feed port 1, an outer tube 2, a tuning end 3, a middle tube 4, a coupling ring 6, a porous coaxial gasket 7, and a tangential flow shield Gas inlet 9, nanosecond pulse/DC high voltage input end, middle tube air inlet 11, capillary air inlet 12, capillary inner electrode 13, coaxial insulating tube 14;

所述腔体部分为外管2、中管4、毛细管内电极13同轴谐振腔结构;The cavity part is a coaxial resonant cavity structure of the outer tube 2, the middle tube 4, and the capillary inner electrode 13;

所述外管、中管、毛细管内电极均为金属材质,外管、中管、反射端形成一端开放的同轴谐振腔1,中管、毛细管内电极、反射端形成一端开放的同轴谐振腔2,二处均在内部形成TEM驻波场;The outer tube, the middle tube, and the inner electrode of the capillary are all made of metal, and the outer tube, the middle tube, and the reflective end form a coaxial resonant cavity 1 with one end open, and the middle tube, the capillary inner electrode, and the reflective end form a coaxial resonant cavity with one end open. Cavity 2, both of which form TEM standing wave fields inside;

毛细管内电极与辅助电源(DC或纳秒脉冲调制源)连接;The electrode in the capillary is connected to the auxiliary power supply (DC or nanosecond pulse modulation source);

所述外管的轴向长度为

Figure BDA0003750745870000051
(λ为所述微波频率下的波长,N为正奇数);The axial length of the outer tube is
Figure BDA0003750745870000051
(λ is the wavelength under the microwave frequency, and N is a positive odd number);

所述外管、中管上端口为渐变收口结构,所述外管收口为0~60°,所述中管收口为0~30°,该设计用于调整端口处电场;The upper ports of the outer tube and the middle tube have a gradual closing structure, the closing of the outer tube is 0-60°, and the closing of the middle tube is 0-30°, which is designed to adjust the electric field at the ports;

所述中管、同轴绝缘管14之间有上表面为金属材质的多孔同轴垫圈,多孔垫圈的上表面距腔体部分开口端端口的距离范围为

Figure BDA0003750745870000052
(λ为所述微波频率下的波长,M为正奇数);There is a porous coaxial gasket with an upper surface made of metal between the middle pipe and the coaxial insulating pipe 14, and the distance range between the upper surface of the porous gasket and the opening port of the cavity part is
Figure BDA0003750745870000052
(λ is the wavelength under the microwave frequency, and M is a positive odd number);

所述同轴绝缘管14内表面包裹于毛细管内电极外表面,其轴向长度与毛细管内电极一致,内径与毛细管内电极外径一致,优选的,使用石英绝缘管包裹毛细管内电极外表面;The inner surface of the coaxial insulating tube 14 is wrapped around the outer surface of the capillary inner electrode, its axial length is consistent with the capillary inner electrode, and its inner diameter is consistent with the outer diameter of the capillary inner electrode. Preferably, a quartz insulating tube is used to wrap the outer surface of the capillary inner electrode;

所述中管上端口不高于外管,所述毛细管内电极上端可高/低于中管,优选的,中管上端低于外管上端口0~2mm,毛细管内电极上端位于中管上端口-5~5mm;图2中毛细管内电极上端口与中管上端口齐平;The upper port of the middle tube is not higher than the outer tube, and the upper end of the inner electrode of the capillary can be higher/lower than the middle tube. Preferably, the upper end of the middle tube is 0-2mm lower than the upper port of the outer tube, and the upper end of the inner electrode of the capillary is located on the middle tube Port - 5 ~ 5mm; in Figure 2, the upper port of the inner electrode of the capillary is flush with the upper port of the middle tube;

所述外管、中管、毛细管内电极可引入气体,优选的,屏蔽气入口9处以切向流的方式引入;所述的进气口9、进气口11的气体流速控制在0~20L/min,进气口12的气体流速控制在0~1L/min;The outer tube, the middle tube, and the inner electrode of the capillary can introduce gas. Preferably, the shielding gas inlet 9 is introduced in a tangential flow; the gas flow rate of the gas inlet 9 and gas inlet 11 is controlled at 0-20L /min, the gas flow rate at the air inlet 12 is controlled at 0-1L/min;

微波耦合部分可选的以电导耦合、电容耦合等方式将微波能量耦合到腔体部分;图2中给出以电导耦合将微波能量引入谐振腔的结构示意图;所述耦合环6与外管上端口间距可调;所述微波等离子体射流装置适用电磁波频率范围为几MHz~几GHz,优选的,使用2.45GHz频率下产生5~40mm长度的稳定常压微波冷等离子体射流,微波功率转化效率大于80%。The microwave coupling part can optionally couple microwave energy to the cavity part by means of conductance coupling, capacitive coupling, etc.; Figure 2 shows a schematic structural diagram of introducing microwave energy into the resonator cavity by conductance coupling; the coupling ring 6 is connected to the outer tube The port spacing is adjustable; the microwave plasma jet device is suitable for electromagnetic wave frequency ranges from several MHz to several GHz. Preferably, a stable atmospheric pressure microwave cold plasma jet with a length of 5 to 40 mm is generated at a frequency of 2.45 GHz, and the microwave power conversion efficiency is Greater than 80%.

所述调谐部分为调谐端3对谐振腔长度进行调节的结构,以调节开口端场强,调谐端上端为反射端面,其材质为金属材质;所述调谐端调整至腔体部分的深度为Yλ/4(λ为所述微波频率下的波长,Y为正奇数);The tuning part is a structure in which the tuning end 3 adjusts the length of the resonant cavity to adjust the field strength at the opening end. The upper end of the tuning end is a reflective end surface, and its material is a metal material; the depth of the tuning end adjusted to the cavity part is Yλ /4 (λ is the wavelength under the microwave frequency, Y is a positive odd number);

所述电场调制部分为辅助电源(纳秒脉冲或DC电压)与毛细管内电极13相连;所述纳秒脉冲电源的输出脉宽为10~900ns,上升沿为1~200ns,振幅为3~220kV,频率为1~20kHz,占空比为1~99%;所述DC电源的输出电压为0~60kV或0~-60kV;The electric field modulation part is that the auxiliary power supply (nanosecond pulse or DC voltage) is connected to the inner electrode 13 of the capillary; the output pulse width of the nanosecond pulse power supply is 10-900ns, the rising edge is 1-200ns, and the amplitude is 3-220kV , the frequency is 1-20kHz, the duty cycle is 1-99%; the output voltage of the DC power supply is 0-60kV or 0-60kV;

所述的微波等离子体射流装置可以下述18种方法进行工作:The described microwave plasma jet device can work in the following 18 ways:

1)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,纳秒脉冲电源连接至毛细管内电极,等离子体在谐振腔上端口轴线位置形成,并由脉冲电场驱动下向外喷出;1) The microwave is coupled into the resonant cavity through the microwave coupling part, and a TEM standing wave is formed in the resonant cavity. The nanosecond pulse power supply is connected to the inner electrode of the capillary, and the plasma is formed at the axial position of the upper port of the resonant cavity, and is driven downward by the pulse electric field. Outer spray;

2)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,高压(正/负)电源连接至毛细管内电极,等离子体在谐振腔上端口轴线位置形成,并由高压电场驱动下向外喷出;2) The microwave is coupled into the resonant cavity through the microwave coupling part, and a TEM standing wave is formed in the resonant cavity. The high-voltage (positive/negative) power supply is connected to the inner electrode of the capillary, and the plasma is formed at the axial position of the upper port of the resonant cavity, and is controlled by the high-voltage electric field Driven to spray out;

3)微波通过微波耦合部分耦合至谐振腔中,在谐振腔中形成TEM驻波,等离子体在谐振腔上端口轴线位置形成并向外喷出;3) The microwave is coupled into the resonant cavity through the microwave coupling part, forming a TEM standing wave in the resonant cavity, and the plasma is formed at the axial position of the upper port of the resonant cavity and ejected outward;

4)纳秒脉冲电源连接至毛细管内电极,等离子体在内电极上端形成并向外喷出;4) The nanosecond pulse power supply is connected to the inner electrode of the capillary, and the plasma is formed on the upper end of the inner electrode and ejected outward;

5)DC高压(正/负)电源连接至毛细管内电极,等离子体在内电极上端形成并向外喷出;5) The DC high-voltage (positive/negative) power supply is connected to the inner electrode of the capillary, and the plasma is formed on the upper end of the inner electrode and ejected outward;

6)基于方法1),外管不与地线相连,以无穷远端为地线;6) Based on method 1), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

7)基于方法2),外管不与地线相连,以无穷远端为地线;7) Based on method 2), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

8)基于方法4),外管不与地线相连,以无穷远端为地线;8) Based on method 4), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

9)基于方法5),外管不与地线相连,以无穷远端为地线;9) Based on method 5), the outer tube is not connected to the ground wire, and the infinity end is used as the ground wire;

10)基于方法1),气体(单一/混合)由入口9、入口11、入口12输入,协同脉冲电场驱动微波等离子体射流喷出,并调整等离子体成分;10) Based on method 1), the gas (single/mixed) is input from the inlet 9, the inlet 11, and the inlet 12, and the microwave plasma jet is driven by the pulsed electric field to eject, and the plasma composition is adjusted;

11)基于方法2),气体(单一/混合)由入口9、入口11、入口12输入,协同高压电场驱动微波等离子体射流喷出,并调整等离子体成分;11) Based on method 2), the gas (single/mixed) is input from the inlet 9, the inlet 11, and the inlet 12, and the high-voltage electric field drives the microwave plasma jet to eject, and adjusts the plasma composition;

12)基于方法3),气体(单一/混合)由入口9、入口11、入口12输入,牵引微波等离子体射流喷出,并调整等离子体成分;12) Based on method 3), the gas (single/mixed) is input from the inlet 9, the inlet 11, and the inlet 12, and the microwave plasma jet is pulled to be ejected, and the plasma composition is adjusted;

13)基于方法4),气体(单一/混合)由入口9、入口11、入口12输入,牵引纳秒脉冲驱动的冷等离子体射流喷出,并调整等离子体成分;13) Based on method 4), the gas (single/mixed) is input from the inlet 9, the inlet 11, and the inlet 12, and the cold plasma jet driven by the nanosecond pulse is drawn to eject, and the plasma composition is adjusted;

14)基于方法5),气体(单一/混合)由入口9、入口11、入口12输入,牵引纳秒脉冲驱动的冷等离子体射流喷出,并调整等离子体成分;14) Based on method 5), the gas (single/mixed) is input from the inlet 9, the inlet 11, and the inlet 12, and the cold plasma jet driven by the nanosecond pulse is drawn to eject, and the plasma composition is adjusted;

15)基于方法1),毛细管内电极可为与同轴绝缘管上端口平齐的环形内电极,环形电极外表面被绝缘管内表面包裹,所述环形电极外径与同轴绝缘管内径一致;15) Based on method 1), the capillary inner electrode can be a ring-shaped inner electrode flush with the upper port of the coaxial insulating tube, the outer surface of the ring electrode is wrapped by the inner surface of the insulating tube, and the outer diameter of the ring electrode is consistent with the inner diameter of the coaxial insulating tube;

16)基于方法2),毛细管内电极可为与同轴绝缘管上端口平齐的环形内电极,环形电极外表面被绝缘管内表面包裹,所述环形电极外径与同轴绝缘管内径一致;16) Based on method 2), the capillary inner electrode may be a ring-shaped inner electrode flush with the upper port of the coaxial insulating tube, the outer surface of the ring electrode is wrapped by the inner surface of the insulating tube, and the outer diameter of the ring electrode is consistent with the inner diameter of the coaxial insulating tube;

17)基于方法4),毛细管内电极可为与同轴绝缘管上端口平齐的环形内电极,环形电极外表面被绝缘管内表面包裹,所述环形电极外径与同轴绝缘管内径一致;17) Based on method 4), the inner electrode of the capillary can be a ring-shaped inner electrode flush with the upper port of the coaxial insulating tube, the outer surface of the ring electrode is wrapped by the inner surface of the insulating tube, and the outer diameter of the ring electrode is consistent with the inner diameter of the coaxial insulating tube;

18)基于方法5),毛细管内电极可为与同轴绝缘管上端口平齐的环形内电极,环形电极外表面被绝缘管内表面包裹,所述环形电极外径与同轴绝缘管内径一致;18) Based on method 5), the inner electrode of the capillary can be a ring-shaped inner electrode flush with the upper port of the coaxial insulating tube, the outer surface of the ring electrode is wrapped by the inner surface of the insulating tube, and the outer diameter of the ring electrode is consistent with the inner diameter of the coaxial insulating tube;

本发明延长了微波冷等离子体射流的长度,配合不同驱动参数、气体参数可智能化生成特异性冷等离子体,提高了其在临床医院等领域的可操作性和实用性。The invention prolongs the length of the microwave cold plasma jet, can intelligently generate specific cold plasma in combination with different driving parameters and gas parameters, and improves its operability and practicability in clinical hospitals and other fields.

以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.

Claims (11)

1.一种微波冷等离子体射流装置,其特征在于,由腔体部分、微波耦合部分、调谐部分和电场调制部分组成;1. A microwave cold plasma jet device, characterized in that, consists of a cavity part, a microwave coupling part, a tuning part and an electric field modulation part; 所述腔体部分为一端开放的外管、两端开放的中管、内电极同轴谐振腔结构,外管上设有微波馈入端口、切向流屏蔽气入口,中管设有气体入口;The cavity part is an outer tube with one end open, a middle tube with both ends open, and an inner electrode coaxial resonant cavity structure. The outer tube is provided with a microwave feeding port and a tangential flow shielding gas inlet, and the middle tube is provided with a gas inlet. ; 所述微波耦合部分包括耦合环,将微波能量耦合到所述腔体部分;The microwave coupling portion includes a coupling ring to couple microwave energy to the cavity portion; 所述调谐部分为调谐端对谐振腔长度进行调节的结构,以调节开口端场强,调谐端上端为反射端面;所述调谐端调整至腔体部分的深度为Yλ/4,其中λ为所述微波频率下的波长,Y为正奇数;The tuning part is a structure in which the tuning end adjusts the length of the resonant cavity to adjust the field strength at the opening end. The wavelength under the microwave frequency, Y is a positive odd number; 所述电场调制部分为施加纳秒脉冲/DC电压与内电极相连,内电极由同轴绝缘层包裹。The electric field modulation part is connected to the internal electrode for applying nanosecond pulse/DC voltage, and the internal electrode is wrapped by a coaxial insulating layer. 2.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述外管、中管、内电极均为金属材质,外管与中管之间、中管与内电极之间的微波传输模式均为TEM模式。2. a kind of microwave cold plasma jet device according to claim 1, is characterized in that, described outer pipe, middle pipe, inner electrode are all metal materials, between outer pipe and middle pipe, middle pipe and inner electrode The microwave transmission modes among them are all TEM modes. 3.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述外管的轴向长度为Nλ/4,其中,λ为所述微波频率下的波长,N为正奇数。3. a kind of microwave cold plasma jet device according to claim 1, is characterized in that, the axial length of described outer tube is Nλ/4, and wherein, λ is the wavelength under described microwave frequency, and N is positive odd number. 4.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述外管、中管上端口为渐变收口结构,所述外管收口为0~60°,所述中管收口为0~30°。4. A microwave cold plasma jet device according to claim 1, characterized in that, the upper port of the outer tube and the middle tube is a gradual closing structure, the closing of the outer tube is 0-60°, the middle tube The closing of the tube is 0-30°. 5.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述中管、同轴绝缘层之间有上表面为金属材质的多孔同轴垫圈7,该多孔同轴垫圈7的上表面距所述腔体部分开口端端口的距离范围为
Figure FDA0003750745860000011
其中λ为所述微波频率下的波长,M为正奇数。
5. A kind of microwave cold plasma jet device according to claim 1, characterized in that, there is a porous coaxial washer 7 whose upper surface is a metal material between the middle tube and the coaxial insulating layer, and the porous coaxial The distance range of the upper surface of the gasket 7 from the open end port of the cavity part is
Figure FDA0003750745860000011
Wherein λ is the wavelength at the microwave frequency, and M is a positive odd number.
6.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述内电极插入同轴绝缘层的容腔,同轴绝缘层内层包覆在内电极的外侧。6 . The microwave cold plasma jet device according to claim 1 , wherein the inner electrode is inserted into the cavity of the coaxial insulating layer, and the inner layer of the coaxial insulating layer covers the outer side of the inner electrode. 7.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述中管上端口不高于外管,所述内电极及同轴绝缘层上端可高/低于中管。7. A microwave cold plasma jet device according to claim 1, characterized in that the upper port of the middle tube is not higher than the outer tube, and the upper end of the inner electrode and the coaxial insulating layer can be higher/lower than the middle Tube. 8.根据权利要求1所述的一种微波冷等离子体射流装置,其特征在于,所述外管、中管通过屏蔽气入口处或气体入口引入气体。8. A microwave cold plasma jet device according to claim 1, characterized in that, the outer tube and the middle tube introduce gas through the shielding gas inlet or the gas inlet. 9.根据权利要求8所述的一种微波冷等离子体射流装置,其特征在于,所述屏蔽气入口处以切向流的方式引入;所述的屏蔽气入口、气体入口的气体流速控制在0~20L/min。9. a kind of microwave cold plasma jet device according to claim 8, is characterized in that, described shielding gas entrance place is introduced with the mode of tangential flow; The gas velocity of described shielding gas entrance, gas inlet is controlled at 0 ~20L/min. 10.根据权利要求8所述的一种微波冷等离子体射流装置,其特征在于,所述耦合环与外管上端口间距可调;所述微波等离子体射流装置适用电磁波频率范围为几MHz~几GHz。10. A microwave cold plasma jet device according to claim 8, characterized in that the distance between the coupling ring and the upper port of the outer tube is adjustable; the microwave plasma jet device is applicable to electromagnetic wave frequency ranges from several MHz to several GHz. 11.根据权利要求8所述的一种微波冷等离子体射流装置,其特征在于,所述纳秒脉冲电源的输出脉宽为10~900ns,上升沿为1~200ns,振幅为3~220kV,频率为1~20kHz,占空比为1~99%;所述DC电源的输出电压为0~60kV或0~-60kV。11. A microwave cold plasma jet device according to claim 8, characterized in that the output pulse width of the nanosecond pulse power supply is 10-900 ns, the rising edge is 1-200 ns, and the amplitude is 3-220 kV, The frequency is 1-20kHz, and the duty ratio is 1-99%. The output voltage of the DC power supply is 0-60kV or 0-60kV.
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