CN115313155A - Multi-junction vertical cavity surface emitting laser of heterogeneous tunnel junction and preparation method thereof - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及半导体激光器领域,具体为一种异质隧道结的多结垂直腔面发射激光器。The invention relates to the field of semiconductor lasers, in particular to a heterogeneous tunnel junction multi-junction vertical cavity surface emitting laser.
背景技术Background technique
垂直腔面发射激光器(VCSEL)具有体积小、发散角小、光束质量高、成本低、易于二维集成等独特优势,近年来在半导体激光器领域引起了广泛的研究兴趣,并且也在应用端市场上迅速扩展,其中包括:3D面部识别、激光医美、气体探测、智能家居、激光雷达等应用。Vertical cavity surface emitting lasers (VCSEL) have unique advantages such as small size, small divergence angle, high beam quality, low cost, and easy two-dimensional integration. Rapidly expanding on the Internet, including: 3D facial recognition, laser medical beauty, gas detection, smart home, laser radar and other applications.
目前主流的VCSEL芯片,主要采用单有源区大孔径(5-10μm)结构,这种做法增加了光学设计难度,同时降低了出光功率密度,难以满足高集成度、高功率密度的需求。通过高掺杂的隧道结连接多个有源区是目前提高功率密度、量子效率和斜效率的一种行之有效的途径。然而,在多结VCSEL中,较高的隧穿几率和减小隧道结引入的吸收损耗是矛盾的。选择宽带隙材料、降低掺杂浓度虽然有利于减小隧道结引入的内部损耗,但是同时会影响隧道结的隧穿几率,导致由隧道结引入的压降和电阻升高,严重时会造成无隧穿效应。反之,如果只追求高隧穿几率,选择窄带隙材料,会使隧道结的吸收损耗很大,同样也会影响VCSEL激光器各方面的特性,而且导致激光器难以实现基模激射。The current mainstream VCSEL chip mainly adopts a single active area large aperture (5-10μm) structure, which increases the difficulty of optical design and reduces the optical power density, making it difficult to meet the requirements of high integration and high power density. Connecting multiple active regions through highly doped tunnel junctions is currently an effective way to increase power density, quantum efficiency, and slope efficiency. However, in multi-junction VCSELs, higher tunneling probability is contradictory to reducing absorption losses introduced by tunnel junctions. Although the selection of wide bandgap materials and the reduction of doping concentration are beneficial to reduce the internal loss introduced by the tunnel junction, it will also affect the tunneling probability of the tunnel junction, resulting in an increase in the voltage drop and resistance introduced by the tunnel junction. In severe cases, it will cause no tunneling effect. Conversely, if you only pursue a high tunneling probability and choose a narrow bandgap material, the absorption loss of the tunnel junction will be very large, which will also affect the characteristics of the VCSEL laser in all aspects, and make it difficult for the laser to achieve fundamental mode lasing.
本发明针对上述问题,设计了一种基于Ⅱ型异质隧道结的高性能多结垂直腔面发射激光器。Aiming at the above problems, the present invention designs a high-performance multi-junction vertical cavity surface-emitting laser based on type II heterogeneous tunnel junctions.
发明内容Contents of the invention
本发明的目的在于:为了解决现有垂直腔面发射激光器功率密度、量子效率和斜效率低、且吸收损耗较高的问题,本发明提供一种异质隧道结的多结垂直腔面发射激光器及其制备方法,在确保较低的激光器阈值和大功率的同时,减小了串联电阻和隧道结处的价带间吸收,电阻比同质隧道结小40%左右,实现了提供一种高性能的多结垂直腔面发射激光器。The object of the present invention is to provide a multi-junction vertical cavity surface emitting laser with a heterogeneous tunnel junction in order to solve the problems of low power density, quantum efficiency and slope efficiency, and high absorption loss of the existing vertical cavity surface emitting laser and its preparation method, while ensuring a lower laser threshold and high power, it reduces the series resistance and the absorption between the valence bands at the tunnel junction, and the resistance is about 40% smaller than that of the homogeneous tunnel junction, realizing providing a high Performance of multi-junction vertical-cavity surface-emitting lasers.
本发明为了实现上述目的具体采用以下技术方案:The present invention specifically adopts the following technical solutions in order to achieve the above object:
一种异质隧道结的多结垂直腔面发射激光器,所述激光器自上而下依次为P电极、P型布拉格反射镜组、第一氧化层、第一有源区、Ⅱ型异质隧道结、第二氧化层、第二有源区、N型布拉格反射镜组、衬底、N电极。A multi-junction vertical cavity surface-emitting laser with a heterogeneous tunnel junction, the laser includes a P electrode, a P-type Bragg mirror group, a first oxide layer, a first active region, and a type II heterogeneous tunnel in sequence from top to bottom A junction, a second oxide layer, a second active region, an N-type Bragg mirror group, a substrate, and an N electrode.
可选的,所述Ⅱ型异质隧道结包括:相邻的p型重掺杂的AlxGa1-xAsySb1-y及n型重掺杂AlxGa1-xAs,相邻的p型重掺杂的AlxGa1-xAsySb1-y及n型重掺杂AlxGa1-xAs的两侧分别为p型轻掺杂AlxGa1-xAs及n型轻掺杂AlxGa1-xAs。Optionally, the type II heterogeneous tunnel junction includes: adjacent p-type heavily doped Al x Ga 1-x As y Sb 1-y and n-type heavily doped Al x Ga 1-x As, in phase The two sides of adjacent p-type heavily doped Al x Ga 1-x As y Sb 1-y and n-type heavily doped Al x Ga 1-x As are respectively p-type lightly doped Al x Ga 1-x As And n-type lightly doped Al x Ga 1-x As.
可选的,其中所述p型轻掺杂及n型轻掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围为:x=0.2-0.4。Optionally, the variation range of the AlxGa1 - xAs composition of the p-type lightly doped and n-type lightly doped AlxGa1 - xAs is: x=0.2-0.4.
可选的,其中所述p型重掺杂的AlxGa1-xAsySb1-y的AlxGa1-xAsySb1-y组分变化范围为:x=0-0.2,y=0.8-1。Optionally, the variation range of the Al x Ga 1-x As y Sb 1-y composition of the p-type heavily doped Al x Ga 1-x As y Sb 1-y is: x=0-0.2, y=0.8-1.
可选的,其中所述n型重掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围为:x=0-0.1。Optionally, the variation range of the AlxGa1 - xAs composition of the n-type heavily doped AlxGa1 - xAs is: x=0-0.1.
可选的,所述p型轻掺杂及n型轻掺杂AlxGa1-xAs掺杂浓度范围为5×1017cm-3—2×1018cm-3,厚度为20-100nm。Optionally, the p-type lightly doped and n-type lightly doped Al x Ga 1-x As doping concentration ranges from 5×10 17 cm -3 to 2×10 18 cm -3 , and the thickness is 20-100nm .
可选的,所述p型重掺杂的AlxGa1-xAsySb1-y的掺杂浓度范围为5×1019cm-3—1×1020cm-3,厚度为5-10nm。Optionally, the doping concentration of the p-type heavily doped Al x Ga 1-x As y Sb 1-y ranges from 5×10 19 cm -3 to 1×10 20 cm -3 , and the thickness is 5- 10nm.
可选的,所述n型重掺杂AlxGa1-xAs的掺杂浓度范围为8×1018cm-3—3×1019cm-3,厚度为10-20nm。Optionally, the doping concentration of the n-type heavily doped AlxGa1 - xAs ranges from 8×10 18 cm -3 to 3×10 19 cm -3 , and the thickness is 10-20 nm.
本发明还提供一种异质隧道结的多结垂直腔面发射激光器的制备方法,包括以下步骤:The present invention also provides a method for preparing a heterogeneous tunnel junction multi-junction vertical cavity surface emitting laser, comprising the following steps:
S1、在衬底上依次外延N型布拉格反射镜组、第二有源区、第二氧化层、Ⅱ型异质隧道结、第一有源区、第一氧化层、P型布拉格反射镜组,得到第一预制件;S1. Epitaxial N-type Bragg mirror group, second active region, second oxide layer, II-type heterogeneous tunnel junction, first active region, first oxide layer, and P-type Bragg mirror group on the substrate in sequence , get the first prefab;
S2、在第一预制件的所述P型布拉格反射镜组远离第一有源区的一侧制作P电极,在所述衬底远离所述N型布拉格反射镜组的一侧制作N电极,得到目标激光器。S2. Fabricate a P electrode on the side of the P-type Bragg mirror group of the first preform away from the first active region, and fabricate an N electrode on the side of the substrate away from the N-type Bragg mirror group, Get the target laser.
与现有技术相比,本发明的优点在于:Compared with the prior art, the present invention has the advantages of:
1.本发明所涉及的一种异质隧道结垂直腔面发射激光器及其制备方法,通过在激光器中引入异质隧道结,确保较低的激光器阈值和大功率的同时,减小了串联电阻和隧道结处的价带间吸收,使得本发明的隧道结的电阻比同质隧道结小40%左右,实现了高性能的多结垂直腔面发射激光器,解决了现有垂直腔面发射激光器功率密度、量子效率和斜效率低、且吸收损耗较高的问题。1. A heterogeneous tunnel junction vertical cavity surface emitting laser and its preparation method involved in the present invention, by introducing a heterogeneous tunnel junction into the laser, while ensuring a lower laser threshold and high power, the series resistance is reduced and the absorption between the valence bands at the tunnel junction, so that the resistance of the tunnel junction of the present invention is about 40% smaller than that of the homogeneous tunnel junction, and a high-performance multi-junction vertical cavity surface emitting laser is realized, which solves the problem of the existing vertical cavity surface emitting laser Problems with low power density, quantum efficiency and slope efficiency, and high absorption losses.
附图说明Description of drawings
图1为一种异质隧道结垂直腔面发射激光器的结构示意图。Fig. 1 is a schematic structural diagram of a heterogeneous tunnel junction vertical cavity surface emitting laser.
图2为一种异质隧道结垂直腔面发射激光器的隧道结能带结构示意图。Fig. 2 is a schematic diagram of the tunnel junction energy band structure of a heterogeneous tunnel junction vertical cavity surface emitting laser.
图3为试验1中光学与电学性能测试示意图。FIG. 3 is a schematic diagram of optical and electrical performance testing in
附图标记:1-P电极,2-P型布拉格反射镜组,3-第一氧化层,4-第一有源区,5-Ⅱ型异质隧道结,6-第二氧化层,7-第二有源区,8-N型布拉格反射镜组,9-衬底,10-N电极Reference signs: 1-P electrode, 2-P-type Bragg mirror group, 3-first oxide layer, 4-first active region, 5-II-type heterogeneous tunnel junction, 6-second oxide layer, 7 -Second active region, 8-N-type Bragg mirror group, 9-substrate, 10-N electrodes
为使本发明实施例的目的、技术方案和优点更加清楚,下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. Obviously, the described embodiments are part of the embodiments of the present invention, not all of them. the embodiment.
因此,以下对提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Accordingly, the following detailed description of the embodiments of the invention provided is not intended to limit the scope of the claimed invention, but represents only selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
具体实施方式Detailed ways
参见图1所示,一种异质隧道结的多结垂直腔面发射激光器,所述激光器自上而下依次为P电极1、P型布拉格反射镜组2、第一氧化层3、第一有源区4、Ⅱ型异质隧道结5、第二氧化层6、第二有源区7、N型布拉格反射镜组8、衬底9、N电极10。Referring to Fig. 1, a multi-junction vertical cavity surface-emitting laser with a heterogeneous tunnel junction, the laser is sequentially composed of a
可以理解的,本发明所涉及的一种异质隧道结垂直腔面发射激光器,通过在激光器中引入Ⅱ型异质隧道结5,确保较低的激光器阈值和大功率的同时,减小了串联电阻和隧道结处的价带间吸收,使得本发明的Ⅱ型异质隧道结5的电阻比同质隧道结小40%左右,实现了高性能的多结垂直腔面发射激光器,解决了现有垂直腔面发射激光器功率密度、量子效率和斜效率低、且吸收损耗较高的问题。It can be understood that, for a heterogeneous tunnel junction vertical cavity surface emitting laser involved in the present invention, by introducing a type II
应理解的是,在隧道结中,一方面,为了避免光吸收,隧道结材料必须由比激光波长能量更大的带隙半导体组成;另一方面,隧穿概率随着构成隧穿结的半导体带隙减小而增加,短波长垂直腔面发射激光器很难实现低电阻隧道结,因此,很难同时实现低电阻和低光吸收。It should be understood that in a tunnel junction, on the one hand, in order to avoid light absorption, the tunnel junction material must be composed of a semiconductor with a band gap larger than the energy of the laser wavelength; Therefore, it is difficult to achieve low resistance and low light absorption at the same time.
传统的近红外多结垂直腔面发射激光器(如905、940和980nm)隧道结材料一般采用GaAs同质结。然而,对于905nm多结垂直腔面发射激光器,室温下有源区材料的荧光峰在890nm附近,对应的光子能量为1.393eV,而本征GaAs材料在室温时的禁带宽度为1.424eV,两者仅相差31meV。考虑到重掺杂带尾效应和载流子屏蔽作用引起的带隙收缩以及电弗朗兹一凯尔迪什效应导致的本征吸收边红移,GaAs同质结对该波段的光子存在本征吸收的可能性。因此异质结的隧道结更具有优越性。Traditional near-infrared multi-junction vertical cavity surface emitting lasers (such as 905, 940 and 980nm) tunnel junction materials generally use GaAs homojunction. However, for a 905nm multi-junction vertical cavity surface emitting laser, the fluorescence peak of the active region material is around 890nm at room temperature, and the corresponding photon energy is 1.393eV, while the intrinsic GaAs material has a forbidden band width of 1.424eV at room temperature. The difference between them is only 31meV. Considering the bandgap shrinkage caused by heavy doping band tail effect and carrier shielding effect, and the intrinsic absorption edge redshift caused by the electric Franz-Keldish effect, the GaAs homojunction has intrinsic properties for photons in this band. possibility of absorption. Therefore, the tunnel junction of the heterojunction is more advantageous.
具体的,参考Ⅱ型结隧穿概率公式:Egeff≡Egp-ΔEc=Egn-ΔEv(1)在公式(1)中,Egp和Egn表示p侧半导体和n侧半导体的带隙能,Egeff表示异质界面p侧的价带边和n侧的导带边之间的能隙。由于Egeff小于Egp和Egn,Ⅱ型异质隧道结的隧穿概率远大于同质结或Ⅰ型隧道结。Specifically, refer to the type II junction tunneling probability formula: E geff ≡E gp -ΔE c =E gn -ΔE v (1) In formula (1), E gp and E gn represent the band gap energy of p-side semiconductor and n-side semiconductor, and E geff represents the p-side of heterointerface The energy gap between the valence band edge on the n side and the conduction band edge on the n side. Since E geff is smaller than E gp and E gn , the tunneling probability of type II heterojunction is much higher than that of homojunction or type I tunnel junction.
进一步的,在Ⅱ型隧道结材料中,由于Egp和Egn大于激光波长能量,而Egeff小于激光波长能量,因此,光吸收可以发生在异质结附近。然而,从异质界面p侧的价带边到n侧的导带边的转变需要载波函数穿透带隙,因此,其穿透概率不高。此外,在垂直腔面发射激光器中,Ⅱ型异质隧道结一般放在驻波节点,因此,采用Ⅱ型异质隧道结的光吸收很小,这样的设置确保较低的激光器阈值和大功率的同时,Ⅱ型异质隧道结的电阻比同质隧道结小40%左右,大大降低了垂直腔面发射激光器的电阻。Furthermore, in type II tunnel junction materials, since E gp and E gn are greater than the energy of the laser wavelength, and E geff is less than the energy of the laser wavelength, light absorption can occur near the heterojunction. However, the transition from the valence band edge on the p-side of the heterointerface to the conduction band edge on the n-side requires the carrier function to penetrate the band gap, so its penetration probability is not high. In addition, in the vertical cavity surface emitting laser, the type II heterostructure tunnel junction is generally placed at the standing wave node, so the light absorption of the type II heterostructure tunnel junction is very small, and this setting ensures a lower laser threshold and high power At the same time, the resistance of the type II heterogeneous tunnel junction is about 40% smaller than that of the homogeneous tunnel junction, which greatly reduces the resistance of the vertical cavity surface emitting laser.
进一步的,本发明所涉及的一种异质隧道结的多结垂直腔面发射激光器,在每个有源区的p区一侧都设置了氧化层,氧化层的作用除了限制发光区孔径之外,还可以有效抑制电子的泄漏,进一步提升器件内量子效率。Furthermore, in the multi-junction vertical cavity surface-emitting laser with heterogeneous tunnel junctions involved in the present invention, an oxide layer is provided on the p-region side of each active region, and the function of the oxide layer is to limit the aperture of the light-emitting region. In addition, it can effectively suppress the leakage of electrons and further improve the quantum efficiency of the device.
本发明中的所述Ⅱ型异质隧道结包括:相邻的p型重掺杂的AlxGa1-xAsySb1-y及n型重掺杂AlxGa1-xAs,相邻的p型重掺杂的AlxGa1-xAsySb1-y及n型重掺杂AlxGa1-xAs的两侧分别为p型轻掺杂AlxGa1-xAs及n型轻掺杂AlxGa1-xAs。需要说明的是,在隧道结中引入AlxGa1- xAsySb1-y与AlxGa1-xAs两种材料,使得隧道结具有异质结构,此处的光吸收很小,因此使得此处能够实现较低的激光器阈值、较小的电阻、较大的输出功率,光电性能优越。The type II heterogeneous tunnel junction in the present invention includes: adjacent p-type heavily doped Al x Ga 1-x As y Sb 1-y and n-type heavily doped Al x Ga 1-x As, phase The two sides of adjacent p-type heavily doped Al x Ga 1-x As y Sb 1-y and n-type heavily doped Al x Ga 1-x As are respectively p-type lightly doped Al x Ga 1-x As And n-type lightly doped Al x Ga 1-x As. It should be noted that two materials, Al x Ga 1- x As y Sb 1-y and Al x Ga 1-x As, are introduced into the tunnel junction, so that the tunnel junction has a heterogeneous structure, and the light absorption here is very small. Therefore, a lower laser threshold, a smaller resistance, and a larger output power can be realized here, and the photoelectric performance is superior.
在本发明的一些实施例中,上述的p型轻掺杂及n型轻掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围为:x=0.2-0.4。In some embodiments of the present invention, the Al x Ga 1-x As composition range of the aforementioned lightly p-type doped and lightly n-doped Al x Ga 1-x As is: x=0.2-0.4.
其中,上述的p型轻掺杂及n型轻掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围优选为x=0.3。Wherein, the change range of AlxGa1 - xAs composition of above-mentioned lightly p-type doped and lightly n-doped AlxGa1 - xAs is preferably x=0.3.
在本发明的一些实施例中,上述的p型重掺杂的AlxGa1-xAsySb1-y的AlxGa1-xAsySb1-y组分变化范围为:x=0-0.2,y=0.8-1。In some embodiments of the present invention, the Al x Ga 1-x As y Sb 1-y composition range of the aforementioned p-type heavily doped Al x Ga 1-x As y Sb 1-y is: x= 0-0.2, y=0.8-1.
其中,上述的p型重掺杂的AlxGa1-xAsySb1-y的AlxGa1-xAsySb1-y组分变化范围优选为x=0.1,y=0.9。Wherein, the change range of AlxGa1 - xAsySb1 -y composition of the above-mentioned p-type heavily doped AlxGa1 - xAsySb1 - y is preferably x =0.1, y=0.9.
在本发明的一些实施例中,上述的n型重掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围为:x=0-0.1。In some embodiments of the present invention, the Al x Ga 1-x As composition of the above n-type heavily doped Al x Ga 1- x As varies in the range: x=0-0.1.
其中,上述的n型重掺杂AlxGa1-xAs的AlxGa1-xAs组分变化范围优选为x=0.05。Wherein, the variation range of the AlxGa1 - xAs composition of the above-mentioned n-type heavily doped AlxGa1 - xAs is preferably x=0.05.
在本发明的一些实施例中,上述的p型轻掺杂及n型轻掺杂AlxGa1-xAs掺杂浓度范围为5×1017cm-3—2×1018cm-3,厚度为20-100nm。In some embodiments of the present invention, the above-mentioned lightly doped p-type and lightly n-doped Al x Ga 1-x As doping concentrations range from 5×10 17 cm -3 to 2×10 18 cm -3 , The thickness is 20-100nm.
其中,上述的p型轻掺杂及n型轻掺杂AlxGa1-xAs掺杂浓度范围为1×1018cm-3,厚度为60nm。Wherein, the aforementioned p-type lightly doped and n-type lightly doped Al x Ga 1-x As doping concentrations range from 1×10 18 cm -3 , and the thickness is 60 nm.
在本发明的一些实施例中,上述的p型重掺杂的AlxGa1-xAsySb1-y的掺杂浓度范围为5×1019cm-3—1×1020cm-3,厚度为5-10nm。In some embodiments of the present invention, the above-mentioned p-type heavily doped Al x Ga 1-x As y Sb 1-y has a doping concentration ranging from 5×10 19 cm -3 to 1×10 20 cm -3 , with a thickness of 5-10nm.
其中,上述的p型重掺杂的AlxGa1-xAsySb1-y的掺杂浓度范围优选为1×1020cm-3,厚度为8nm。Wherein, the above-mentioned p-type heavily doped Al x Ga 1-x As y Sb 1-y preferably has a doping concentration range of 1×10 20 cm -3 and a thickness of 8 nm.
在本发明的一些实施例中,上述的n型重掺杂AlxGa1-xAs的掺杂浓度范围为8×1018cm-3—3×1019cm-3,厚度为10-20nm。In some embodiments of the present invention, the above-mentioned n-type heavily doped Al x Ga 1-x As has a doping concentration ranging from 8×10 18 cm -3 to 3×10 19 cm -3 , and a thickness of 10-20 nm. .
其中,上述的n型重掺杂AlxGa1-xAs的掺杂浓度范围优选为8×1018、1×1019、3×1019cm-3,厚度为10、12、15、20nm。Among them, the doping concentration range of the above-mentioned n-type heavily doped Al x Ga 1-x As is preferably 8×10 18 , 1×10 19 , 3×10 19 cm -3 , and the thickness is 10, 12, 15, 20 nm .
本发明还提供一种异质隧道结垂直腔面发射激光器的制备方法,包括以下步骤:The present invention also provides a method for preparing a heterogeneous tunnel junction vertical cavity surface emitting laser, comprising the following steps:
S1、在衬底9上依次外延N型布拉格反射镜组8、第二有源区7、第二氧化层6、Ⅱ型异质隧道结5、第一有源区4、第一氧化层3、P型布拉格反射镜组2,得到第一预制件;S1. Epitaxial N-type
S2、在第一预制件的所述P型布拉格反射镜组2远离第一有源区4的一侧制作P电极1,在所述衬底9远离所述N型布拉格反射镜组8的一侧制作N电极10,得到目标激光器。S2. Fabricate a
本发明中优选GaAs衬底。A GaAs substrate is preferred in the present invention.
本发明的P电极1、N电极10为金、铜、石墨、银或锡中的任一种。The
需要说明的是,在具体的外延过程中,在已经涉及的P型布拉格反射镜组2、第一氧化层3、第一有源区4、Ⅱ型异质隧道结5、第二氧化层6、第二有源区7、N型布拉格反射镜组8等各层之间还存在缓冲层,根据实际的制备需求调整参数对各缓冲层进行外延,以满足实际的需求。It should be noted that in the specific epitaxial process, in the already involved P-type
在本发明的一些实施例中,外延的方法可以选择金属有机化学气相沉积法(MOCVD)或分子束外延法(MBE)对各层进行外延。In some embodiments of the present invention, metal organic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE) can be selected as the epitaxy method to epitaxy each layer.
实施例1Example 1
一种异质隧道结的多结垂直腔面发射激光器,所述激光器自上而下依次为P电极、P型布拉格反射镜组、第一氧化层、第一有源区、Ⅱ型异质隧道结、第二氧化层、第二有源区、N型布拉格反射镜组、衬底、N电极。A multi-junction vertical cavity surface-emitting laser with a heterogeneous tunnel junction, the laser includes a P electrode, a P-type Bragg mirror group, a first oxide layer, a first active region, and a type II heterogeneous tunnel in sequence from top to bottom A junction, a second oxide layer, a second active region, an N-type Bragg mirror group, a substrate, and an N electrode.
本实施例中,所述Ⅱ型异质隧道结包括:相邻的p型重掺杂的Al0.15Ga0.85As0.95Sb0.05及n型重掺杂Al0.1Ga0.9As,相邻的p型重掺杂的Al0.15Ga0.85As0.95Sb0.05及n型重掺杂Al0.1Ga0.9As的两侧分别为p型轻掺杂Al0.3Ga0.7As及n型轻掺杂Al0.2Ga0.7As。In this embodiment, the type II heterogeneous tunnel junction includes: adjacent p-type heavily doped Al 0.15 Ga 0.85 As 0.95 Sb 0.05 and n-type heavily doped Al 0.1 Ga 0.9 As, adjacent p-type heavily The two sides of doped Al 0.15 Ga 0.85 As 0.95 Sb 0.05 and n-type heavily doped Al 0.1 Ga 0.9 As are respectively p-type lightly doped Al 0.3 Ga 0.7 As and n-type lightly doped Al 0.2 Ga 0.7 As.
其中,p型轻掺杂Al0.3Ga0.7As及n型轻掺杂Al0.2Ga0.7As的掺杂浓度范围为5×1017cm-3,厚度为20nm;p型重掺杂的Al0.15Ga0.85As0.95Sb0.05的掺杂浓度范围为5×1019cm-3,厚度为6nm;n型重掺杂Al0.1Ga0.9As的掺杂浓度范围为8×1018cm-3,厚度为11nm。Among them, the doping concentration range of p-type lightly doped Al 0.3 Ga 0.7 As and n-type lightly doped Al 0.2 Ga 0.7 As is 5×10 17 cm -3 , and the thickness is 20nm; p-type heavily doped Al 0.15 Ga The doping concentration range of 0.85 As 0.95 Sb 0.05 is 5×10 19 cm -3 and the thickness is 6nm; the doping concentration range of n-type heavily doped Al 0.1 Ga 0.9 As is 8×10 18 cm -3 and the thickness is 11nm .
实施例2Example 2
一种异质隧道结的多结垂直腔面发射激光器,所述激光器自上而下依次为P电极、P型布拉格反射镜组、第一氧化层、第一有源区、Ⅱ型异质隧道结、第二氧化层、第二有源区、N型布拉格反射镜组、衬底、N电极。A multi-junction vertical cavity surface-emitting laser with a heterogeneous tunnel junction, the laser includes a P electrode, a P-type Bragg mirror group, a first oxide layer, a first active region, and a type II heterogeneous tunnel in sequence from top to bottom A junction, a second oxide layer, a second active region, an N-type Bragg mirror group, a substrate, and an N electrode.
本实施例中,所述Ⅱ型异质隧道结包括:相邻的p型重掺杂的Al0.2Ga0.8As0.9Sb0.1及n型重掺杂Al0.1Ga0.9As,相邻的p型重掺杂的Al0.15Ga0.85As0.95Sb0.05及n型重掺杂Al0.1Ga0.9As的两侧分别为p型轻掺杂Al0.2Ga0.8As及n型轻掺杂Al0.2Ga0.8As。In this embodiment, the type II heterogeneous tunnel junction includes: adjacent p-type heavily doped Al 0.2 Ga 0.8 As 0.9 Sb 0.1 and n-type heavily doped Al 0.1 Ga 0.9 As, adjacent p-type heavily doped The two sides of doped Al 0.15 Ga 0.85 As 0.95 Sb 0.05 and n-type heavily doped Al 0.1 Ga 0.9 As are respectively p-type lightly doped Al 0.2 Ga 0.8 As and n-type lightly doped Al 0.2 Ga 0.8 As.
其中,p型轻掺杂Al0.2Ga0.8As及n型轻掺杂Al0.2Ga0.8As掺杂浓度范围为1×1018cm-3,厚度为60nm;p型重掺杂的Al0.2Ga0.8As0.9Sb0.1的掺杂浓度范围为0.5×1020cm-3,厚度为8nm;及n型重掺杂Al0.1Ga0.9As的掺杂浓度范围为2×1019cm-3,厚度为15nm。Among them, p-type lightly doped Al 0.2 Ga 0.8 As and n-type lightly doped Al 0.2 Ga 0.8 As have a doping concentration range of 1×10 18 cm -3 and a thickness of 60nm; p-type heavily doped Al 0.2 Ga 0.8 The doping concentration range of As 0.9 Sb 0.1 is 0.5×10 20 cm -3 and the thickness is 8nm; and the doping concentration range of n-type heavily doped Al 0.1 Ga 0.9 As is 2×10 19 cm -3 and the thickness is 15nm .
实施例3Example 3
一种异质隧道结的多结垂直腔面发射激光器,所述激光器自上而下依次为P电极、P型布拉格反射镜组、第一氧化层、第一有源区、Ⅱ型异质隧道结、第二氧化层、第二有源区、N型布拉格反射镜组、衬底、N电极。A multi-junction vertical cavity surface-emitting laser with a heterogeneous tunnel junction, the laser includes a P electrode, a P-type Bragg mirror group, a first oxide layer, a first active region, and a type II heterogeneous tunnel in sequence from top to bottom A junction, a second oxide layer, a second active region, an N-type Bragg mirror group, a substrate, and an N electrode.
本实施例中,所述Ⅱ型异质隧道结包括:相邻的p型重掺杂的Al0.15Ga0.85As0.95Sb0.05及n型重掺杂Al0.1Ga0.9As,相邻的p型重掺杂的Al0.2Ga0.8As0.9Sb0.1及n型重掺杂Al0.1Ga0.9As的两侧分别为p型轻掺杂Al0.2Ga0.8As及n型轻掺杂Al0.2Ga0.8As。In this embodiment, the type II heterogeneous tunnel junction includes: adjacent p-type heavily doped Al 0.15 Ga 0.85 As 0.95 Sb 0.05 and n-type heavily doped Al 0.1 Ga 0.9 As, adjacent p-type heavily The two sides of doped Al 0.2 Ga 0.8 As 0.9 Sb 0.1 and n-type heavily doped Al 0.1 Ga 0.9 As are respectively p-type lightly doped Al 0.2 Ga 0.8 As and n-type lightly doped Al 0.2 Ga 0.8 As.
其中,p型轻掺杂Al0.2Ga0.8As及n型轻掺杂Al0.2Ga0.8As掺杂浓度范围为2×1018cm-3,厚度为100nm;p型重掺杂的Al0.15Ga0.85As0.95Sb0.05的掺杂浓度范围为1×1020cm-3,厚度为10nm;及n型重掺杂Al0.1Ga0.9As的掺杂浓度范围为3×1019cm-3,厚度为20nm。Among them, p-type lightly doped Al 0.2 Ga 0.8 As and n-type lightly doped Al 0.2 Ga 0.8 As have a doping concentration range of 2×10 18 cm -3 and a thickness of 100nm; p-type heavily doped Al 0.15 Ga 0.85 The doping concentration range of As 0.95 Sb 0.05 is 1×10 20 cm -3 and the thickness is 10nm; and the doping concentration range of n-type heavily doped Al 0.1 Ga 0.9 As is 3×10 19 cm -3 and the thickness is 20nm .
进一步的,为了验证本发明所涉及的发射激光器的光学与电学性能,进行以下的试验例。Furthermore, in order to verify the optical and electrical properties of the laser emitting device of the present invention, the following test examples were carried out.
试验例.检验发射激光器的光学与电学性能Test example. Check the optical and electrical performance of the emitting laser
1.1试验设计1.1 Experimental design
试验设置两个处理组,实验组为实施例1的所涉及的Al0.1Ga0.9As/Al0.15Ga0.85As0.95Sb0.05Ⅱ型异质隧道结的三结垂直腔面发射激光器,对照组为采用普通同质隧道结的垂直腔面发射激光器,在相同的试验条件下,对其进行光学与电学的性能测试。Two treatment groups were set up in the experiment, the experimental group was the triple-junction vertical cavity surface-emitting laser of the Al 0.1 Ga 0.9 As/Al 0.15 Ga 0.85 As 0.95 Sb 0.05 type II heterogeneous tunnel junction involved in Example 1, and the control group was the Ordinary homogeneous tunnel junction vertical cavity surface emitting lasers are tested for their optical and electrical performance under the same test conditions.
测试结果见图3,其中,点划线代表对照组(普通GaAs同质隧道结的垂直腔面发射激光器),实线代表实验组(Al0.1Ga0.9As/Al0.15Ga0.85As0.95Sb0.05Ⅱ型异质隧道结垂直腔面发射激光器)。The test results are shown in Figure 3, where the dotted line represents the control group (vertical cavity surface emitting laser with ordinary GaAs homogeneous tunnel junction), and the solid line represents the experimental group (Al 0.1 Ga 0.9 As/Al 0.15 Ga 0.85 As 0.95 Sb 0.05 Ⅱ type hetero-tunnel junction vertical-cavity surface-emitting laser).
检验后,分别得出表征光学性能的电流—功率曲线,表征电学性能的电流—电压曲线。After the inspection, the current-power curve representing the optical performance and the current-voltage curve representing the electrical performance are obtained respectively.
1.2结果分析1.2 Analysis of results
参见图3的参见电流—功率曲线可知,可见在光学性能方面,实验组的电流激射阈值为1.1mA,而对照组的电流激射阈值1.2mA,可见两者的电流激射阈值相差不大,这是因为采用Ⅱ型异质隧道结AlxGa1-xAs/AlxGa1-xAsySb1-y没有增加吸收损耗。可见实验组与对照组相比,保证激射阈值不变的情况下,实验组的微分电阻和斜线效率表现更好,因此,实施例1的异质隧道结垂直腔面发射激光器具有更高的光电转换效率。Referring to the current-power curve in Figure 3, it can be seen that in terms of optical performance, the current lasing threshold of the experimental group is 1.1mA, while the current lasing threshold of the control group is 1.2mA. It can be seen that the current lasing threshold of the two is not much different , this is because the use of type II heterogeneous tunnel junction Al x Ga 1-x As/Al x Ga 1-x As y Sb 1-y does not increase the absorption loss. It can be seen that compared with the control group, when the lasing threshold is kept constant, the differential resistance and slope efficiency of the experimental group are better. Therefore, the heterogeneous tunnel junction vertical cavity surface emitting laser of Example 1 has a higher photoelectric conversion efficiency.
参见电流—电压曲线,在电学性能方面,实验组的曲线更陡峭,即实验组的微分电阻相较于对照组更小。可见,Ⅱ型隧道结AlxGa1-xAs/AlxGa1-xAsySb1-y具有更短的隧穿距离,增大了电子的隧穿概率,从而减小了微分电阻。Referring to the current-voltage curve, in terms of electrical properties, the curve of the experimental group is steeper, that is, the differential resistance of the experimental group is smaller than that of the control group. It can be seen that the type II tunnel junction Al x Ga 1-x As/Al x Ga 1-x As y Sb 1-y has a shorter tunneling distance, which increases the tunneling probability of electrons, thereby reducing the differential resistance.
结合两组曲线,实验组与对照组相比,保证激射阈值不变的情况下,微分电阻和斜线效率表现更好,具有更高的光电转换效率。Combining the two sets of curves, compared with the control group, when the lasing threshold is kept constant, the experimental group has better differential resistance and slope efficiency, and has higher photoelectric conversion efficiency.
综上所述,本发明所涉及的一种异质隧道结的多结垂直腔面发射激光器,通过在激光器中引入异质隧道结,确保较低的激光器阈值和大功率的同时,减小了串联电阻和隧道结处的价带间吸收,使得本发明的隧道结的电阻比同质隧道结小40%左右,实现了高性能的多结垂直腔面发射激光器,解决了现有垂直腔面发射激光器功率密度、量子效率和斜效率低、且吸收损耗较高的问题。In summary, a heterogeneous tunnel junction multi-junction vertical cavity surface emitting laser involved in the present invention, by introducing a heterogeneous tunnel junction into the laser, ensures a lower laser threshold and high power while reducing the The series resistance and the absorption between the valence bands at the tunnel junction make the resistance of the tunnel junction of the present invention about 40% smaller than that of the homogeneous tunnel junction, realizing a high-performance multi-junction vertical cavity surface emitting laser and solving the problem of existing vertical cavity surface emitting lasers. Issues of low power density, quantum efficiency, and slope efficiency of emitting lasers, and high absorption losses.
以上实施例仅为本发明其中的一种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above embodiment is only one implementation mode of the present invention, and its description is relatively specific and detailed, but it should not be construed as limiting the patent scope of the present invention. It should be pointed out that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention should be based on the appended claims.
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