CN115282070A - Cleaning composition with temperature sensation and preparation method and application thereof - Google Patents
Cleaning composition with temperature sensation and preparation method and application thereof Download PDFInfo
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Abstract
Description
技术领域technical field
本申请涉及化妆品生产技术领域,尤其涉及一种具有温感的清洁组合物及其制备方法和应用。The application relates to the technical field of cosmetic production, in particular to a warming cleaning composition and its preparation method and application.
背景技术Background technique
角质层位于肌肤的最外层,正常情况下,表皮以28天左右为一个周期进行自我更新,不需要人为干预老废角质就会自行脱落。但是皮肤代谢受老化、作息改变、天气变化等多种因素影响。皮肤角质更新较慢则容易造成皮肤暗沉粗糙,没有弹性,长期如此会导致毛孔堵塞、长痘、起鸡皮。因此,为了改善皮肤让皮肤处于健康状态,适度去角质是非常关键的。The stratum corneum is located in the outermost layer of the skin. Under normal circumstances, the epidermis renews itself in a cycle of about 28 days, and the old waste stratum corneum will fall off without human intervention. However, skin metabolism is affected by many factors such as aging, changes in work and rest, and weather changes. Slower skin cutin renewal can easily lead to dull, rough and inelastic skin. If this happens for a long time, it will lead to clogged pores, acne, and chicken skin. Therefore, in order to improve the skin and keep the skin in a healthy state, moderate exfoliation is very critical.
磨砂膏,一种颗粒均匀的皮肤清洁剂。主要作用为清除老化角质,间接辅助深层清洁。使用时将膏体在皮肤上适当按摩,在发挥制剂中油分、水分及表面活性剂清洁作用的同时,通过植物颗粒、化学颗粒等磨料的摩擦作用,可去除较难清除的污垢、堆积在皮肤表面老化的角质层细胞和老化的鳞状角质,使得皮肤柔软细腻。Scrub, a fine-grained skin cleanser. The main function is to remove aging cutin and indirectly assist deep cleansing. Massage the ointment on the skin properly when using it. While exerting the cleaning effect of oil, water and surfactant in the preparation, at the same time, through the friction of plant particles, chemical particles and other abrasives, it can remove dirt that is difficult to remove and accumulate on the skin. The aged stratum corneum cells and aged squamous cutin on the surface make the skin soft and delicate.
但是,当温度较低时,人体皮肤新陈代谢速度变缓,会导致老废角质堆积严重,在这种情况下普通磨砂膏清洁效果欠佳。因此,目前亟需一种在人体皮肤温度较低时也能够达到较好清洁效果的磨砂膏。However, when the temperature is low, the metabolism of human skin slows down, which will lead to serious accumulation of old dead skin cells. In this case, the cleaning effect of ordinary scrubs is not good. Therefore, need badly a kind of scrub that also can reach better cleaning effect when human body skin temperature is lower at present.
CN 113662893 A中公开了一种温感面膜,其中利用姜根油、胡椒籽提取物、吴茱萸提取物渗入皮肤,带来热感,诱导血管舒张。其安全性和加热效果均有待提高。目前未有采用硅酸铝钾盐作为加热成分的温感化妆品。CN 113662893 A discloses a warm-sensing facial mask, in which ginger root oil, pepper seed extract and Evodia rutaecarpa extract are used to penetrate into the skin to bring thermal sensation and induce vasodilation. Its safety and heating effect all need to be improved. At present, there is no warm-sensing cosmetic that uses potassium aluminum silicate as a heating component.
发明内容Contents of the invention
本发明的目的是提供一种含有硅酸铝钾盐的具有温感的清洁组合物,该清洁组合物能够遇水发热,有效提高皮肤表面温度,达到较好清洁效果,同时兼具优异的保湿性能,使清洗过后皮肤滋润不紧绷。The object of the present invention is to provide a cleansing composition containing potassium aluminum silicate with a sense of warmth, which can generate heat when exposed to water, effectively increase the surface temperature of the skin, achieve a better cleaning effect, and simultaneously have excellent moisturizing properties Its performance keeps the skin moisturized and not tight after washing.
一方面,本申请提供了一种具有温感的清洁组合物,以质量份数计,所述组合物包括25-35份硅酸铝钾盐、25-35份油脂、13-25份表面活性剂、11-25份增稠剂、3.1-7.5份磨砂剂。On the one hand, the present application provides a cleansing composition with a sense of warmth, the composition includes 25-35 parts of potassium aluminum silicate, 25-35 parts of grease, 13-25 parts of surface active agent, 11-25 parts of thickener, 3.1-7.5 parts of scrub agent.
进一步的,所述硅酸铝钾盐的粒径为0.4-0.5mm。Further, the particle size of the aluminum potassium salt is 0.4-0.5 mm.
本申请选用硅酸铝钾盐作为主要发热成分,获得一种具有温感的清洁组合物。硅酸铝钾盐是沸石族矿物的总称,是一种含水的碱或碱土金属铝硅酸盐矿物。硅酸铝钾盐是一种新兴材料,作为离子交换剂、吸附分离剂、干燥剂、催化剂、水泥混合材料,被广泛应用于工业、农业、国防等部门。硅酸铝钾盐具有多种的微孔结构,能够吸附水,且遇水吸附过程为放热过程。现有技术中未有将其用于磨砂膏中的先例。In this application, potassium aluminum silicate is selected as the main exothermic component to obtain a cleaning composition with a sense of warmth. Potassium aluminum silicate is a general term for zeolite minerals, which is a hydrous alkali or alkaline earth metal aluminosilicate mineral. Potassium aluminum silicate is a new kind of material, which is widely used in industry, agriculture, national defense and other departments as ion exchanger, adsorption separation agent, desiccant, catalyst and cement mixing material. Potassium aluminum silicate has a variety of microporous structures, which can absorb water, and the adsorption process when encountering water is an exothermic process. There is no precedent for using it in scrubs in the prior art.
本申请将其使用在磨砂膏中,一方面,使其遇水放热,有效提高皮肤表面真实温度,软化角质。另一方面,利用硅酸铝钾盐的吸附特性,同时提高磨砂膏的清洁力。This application uses it in the scrub cream. On the one hand, it releases heat when it meets water, which effectively increases the real temperature of the skin surface and softens the cutin. On the other hand, it utilizes the adsorption properties of potassium aluminum silicate while improving the cleaning power of the scrub.
进一步的,所述油脂选自棕榈酸乙基己酯、辛酸辛酸癸酸甘油三酯、牛油果树果脂提取物、鲸蜡基聚二甲基硅氧烷、碳酸二辛酯、油醇芥酸酯中的一种或多种;优选的,所述油脂为棕榈酸乙基己酯、辛酸癸酸甘油三酯或牛油果树果脂提取物。Further, the oil is selected from ethylhexyl palmitate, caprylic caprylic capric triglyceride, shea butter extract, cetyl polydimethylsiloxane, dioctyl carbonate, oleyl erucic acid One or more of the esters; preferably, the oil is ethylhexyl palmitate, caprylic triglyceride or shea butter extract.
在一种实施方式中,本申请选用了棕榈酸乙基己酯作为油脂成分,该油脂为极轻爽的润肤油脂,透气性好,铺展性佳,为干性透气油,是优异的皮肤柔润剂。本申请采用棕榈酸乙基己酯作为基础成分,棕榈酸乙基己酯的性质贴近于人体皮肤,更易被皮肤吸收,并可以达到油养肤的效果,能够有效改善使用者皮肤状态。In one embodiment, the present application selects ethylhexyl palmitate as the oil component. The oil is an extremely light emollient oil with good air permeability and good spreadability. It is a dry air-permeable oil and is an excellent skin emollient. This application uses ethylhexyl palmitate as the basic component. The nature of ethylhexyl palmitate is close to that of human skin, which is easier to be absorbed by the skin, and can achieve the effect of nourishing the skin with oil, and can effectively improve the skin condition of the user.
在一种实施方式中,本申请选用了辛酸癸酸甘油三酯作为油脂成分,辛酸癸酸甘油三酯是高清爽度无气味植物油脂,属棉籽油或椰油的化合物。它具有高度亲肤性能,且不油腻,有润滑肌肤的效果,并且它还具有良好的铺展性,使皮肤具有滑而不腻的感觉,容易被皮肤吸收。In one embodiment, the present application selects caprylic capric triglyceride as the oil component. Caprylic capric triglyceride is an odorless vegetable oil with high crispness and is a compound of cottonseed oil or coconut oil. It is highly skin-friendly, non-greasy, and has the effect of lubricating the skin. It also has good spreadability, making the skin feel smooth but not greasy, and is easily absorbed by the skin.
在一种实施方式中,本申请选用了牛油果树果脂提取物作为油脂成分。牛油果树果脂是从植物中萃取的纯天然物质,具有保湿滋润的功效,这是因为牛油果树果脂提取物富含多种不饱和脂肪酸等,易被皮肤吸收,滋润肤感。牛油果树果脂还可作为柔润剂,为皮肤提供额外的脂肪,减少皮肤水分蒸发,可恢复皮肤光泽、柔软和弹性。In one embodiment, the present application selects shea butter extract as the oil component. Shea butter is a pure natural substance extracted from plants, which has the effect of moisturizing. This is because the extract of shea butter is rich in a variety of unsaturated fatty acids, etc., which is easily absorbed by the skin and moisturizes the skin. Shea Butter also acts as an emollient, providing extra fat to the skin and reducing moisture evaporation from the skin, restoring radiance, suppleness and elasticity to the skin.
并且,棕榈酸乙基己酯、辛酸癸酸甘油三酯和牛油果树果脂提取物能够与硅酸铝钾盐能够组成稳定体系,适用于本申请组合物。In addition, ethylhexyl palmitate, caprylic capric triglyceride and shea butter extract can form a stable system with potassium aluminum silicate, which is suitable for the composition of this application.
进一步的,所述表面活性剂为脂肪醇聚氧乙烯醚和/或甘油三异硬脂酸酯;优选的,以质量份数计,所述表面活性剂为5-10份脂肪醇聚氧乙烯醚、8-15份甘油三异硬脂酸酯。Further, the surfactant is fatty alcohol polyoxyethylene ether and/or glycerol triisostearate; preferably, in parts by mass, the surfactant is 5-10 parts of fatty alcohol polyoxyethylene Ether, 8-15 parts of glycerol triisostearate.
其中,本申请表面活性剂选择使用脂肪醇聚氧乙烯醚和甘油三异硬脂酸酯(PEG-20)。脂肪醇聚氧乙烯醚为浅黄色黏稠液体,泡沫丰富,去污力强,乳化力和溶解性好,具较低的皮肤刺激性,生物降解性好,可与多种表面活性剂配伍。甘油三异硬脂酸酯(PEG-20),性质温和,对肌肤刺激性低,并且具有很好的清洁效果。Wherein, the surfactant of the present application is selected to use fatty alcohol polyoxyethylene ether and glycerol triisostearate (PEG-20). Fatty alcohol polyoxyethylene ether is a light yellow viscous liquid with rich foam, strong detergency, good emulsification and solubility, low skin irritation, good biodegradability, and can be compatible with various surfactants. Glyceryl triisostearate (PEG-20), mild in nature, low in irritation to the skin, and has a good cleaning effect.
进一步的,以质量份数计,所述增稠剂为5-10份MIGLYOL 840Gel B、1-5份聚乙烯、5-10份蜂蜡。Further, in parts by mass, the thickener is 5-10 parts of MIGLYOL 840Gel B, 1-5 parts of polyethylene, and 5-10 parts of beeswax.
其中,MIGLYOL 840Gel B为广州启嘉化工有限公司提供的840GelB,其主要成分为丙二醇二辛酸酯/二癸酸酯及司拉氯铵水辉石及碳酸丙二醇酯。Among them, MIGLYOL 840Gel B is provided by Guangzhou Qijia Chemical Co., Ltd. 840GelB, its main components are propylene glycol dicaprylate/dicaprate, steralnium chloride hectorite and propylene carbonate.
进一步的,以质量份数计,所述磨砂剂为3-7份水合硅石、0.1-0.5份橄榄壳颗粒。Further, in terms of parts by mass, the scrub agent is 3-7 parts of hydrated silica and 0.1-0.5 parts of olive shell particles.
在一种优选的实施例中,以质量份数计,上述组合物包括粒径为0.4-0.5mm的硅酸铝钾盐25-35份、棕榈酸乙基己酯或辛酸癸酸甘油三酯或牛油果树果脂提取物25-35份、脂肪醇聚氧乙烯醚5-10份、甘油三异硬脂酸酯8-15份、MIGLYOL 840Gel B 5-10份、聚乙烯1-5份、蜂蜡5-10份、水合硅石3-7份、橄榄壳颗粒0.1-0.5份。In a preferred embodiment, in terms of parts by mass, the composition includes 25-35 parts of potassium aluminum silicate with a particle size of 0.4-0.5 mm, ethylhexyl palmitate or caprylic triglyceride Or shea butter extract 25-35 parts, fatty alcohol polyoxyethylene ether 5-10 parts, glycerin triisostearate 8-15 parts, MIGLYOL 840Gel B 5-10 parts, polyethylene 1-5 parts, 5-10 parts of beeswax, 3-7 parts of hydrated silica, 0.1-0.5 parts of olive shell particles.
另一方面,本申请还提供了上述的具有温感的清洁组合物的制备方法,所述制备方法包括如下步骤:On the other hand, the present application also provides a preparation method of the above-mentioned warm-sensing cleaning composition, the preparation method comprising the following steps:
步骤一、将油脂、表面活性剂混合,均质至完全分散;Step 1. Mix the oil and surfactant, homogenize until completely dispersed;
步骤二、继续加入增稠剂,加热到88℃-90℃反应10-20min,以30-50r/min速度搅拌至完全溶解;优选的,反应15min;Step 2. Continue to add thickener, heat to 88°C-90°C for 10-20min, stir at 30-50r/min until completely dissolved; preferably, react for 15min;
步骤三、搅拌降温至60℃-70℃,加入硅酸铝钾盐,搅拌分散,加入磨砂剂继续搅拌均匀;优选的,降温至65℃。Step 3: Stir and cool down to 60°C-70°C, add potassium aluminum silicate, stir to disperse, add abrasive agent and continue stirring evenly; preferably, cool down to 65°C.
进一步的,所述方法还包括在40℃-50℃温度下进行灌装,常温放置10-24h;优选的,常温放置12h。Further, the method also includes filling at a temperature of 40°C-50°C, and standing at room temperature for 10-24 hours; preferably, standing at room temperature for 12 hours.
一种优选的实施例方式中,一种具有温感的磨砂膏的制作工艺,包括以下步骤:In a preferred embodiment, a manufacturing process of a warm scrub comprises the following steps:
步骤1、把油脂、脂肪醇聚氧乙烯醚和甘油三异硬脂酸酯(PEG-20)混合,均质至混合原料分散均匀,均质速度为600-800r/min;Step 1. Mix oil, fatty alcohol polyoxyethylene ether and glycerol triisostearate (PEG-20), homogenize until the mixed raw materials are evenly dispersed, and the homogenization speed is 600-800r/min;
步骤2、在上述混合原料中继续加入MIGLYOL 840Gel B、聚乙烯、蜂蜡,乳化锅中加热到88℃-90℃保温15分钟,以30-50r/min速度进行搅拌至完全溶解;Step 2. Continue to add MIGLYOL 840Gel B, polyethylene, and beeswax to the above mixed raw materials, heat in an emulsification pot to 88°C-90°C for 15 minutes, and stir at a speed of 30-50r/min until completely dissolved;
步骤3、搅拌至温度降至65℃,混合均匀后加入硅酸铝钾盐,搅拌分散,分散均匀后,加入水合硅石、橄榄壳颗粒继续搅拌均匀;Step 3. Stir until the temperature drops to 65°C. After mixing evenly, add potassium aluminum silicate, stir to disperse, and after dispersing evenly, add hydrated silica and olive shell particles and continue to stir evenly;
步骤4、在温度控制在40℃-50℃的情况下边搅拌边灌装,常温放置12小时后结成结实膏体。Step 4. Fill while stirring while the temperature is controlled at 40°C-50°C, and form a firm paste after standing at room temperature for 12 hours.
其中油脂可选择棕榈酸乙基己酯、辛酸癸酸甘油三酯或牛油果树果脂提取物,均能达到相同的技术效果。Among them, the oil can be selected from ethylhexyl palmitate, caprylic capric triglyceride or shea butter extract, all of which can achieve the same technical effect.
另一方面,本申请还提供了一种含有上述的具有温感的清洁组合物的化妆品,所述化妆品为磨砂膏、香皂、洁面霜和/或洁面剂。On the other hand, the present application also provides a cosmetic containing the above-mentioned warming cleansing composition, wherein the cosmetic is scrub, soap, cleansing cream and/or cleansing agent.
进一步的,所述化妆品为磨砂膏。Further, the cosmetic is a scrub.
本发明具有如下有益效果:The present invention has following beneficial effect:
1、本申请首次提供了一种含有的硅酸铝钾盐的具有温感的清洁组合物,其遇水可发生放热作用,可以提高皮肤表面温度,进而促进皮肤微循环和新陈代谢速度,能够有效软化角质,便于组合物去除皮肤表面较难清除的污垢、堆积在皮肤表面老化的角质层细胞和老化的鳞状角质,彻底清洁皮肤;1. For the first time, this application provides a warm-sensing cleaning composition containing potassium aluminum silicate, which can generate exothermic effect when it encounters water, which can increase the skin surface temperature, thereby promoting skin microcirculation and metabolism speed, and can Effectively softens cutin, which facilitates the composition to remove dirt that is difficult to remove on the surface of the skin, aged cutin cells and aged squamous cutin accumulated on the surface of the skin, and thoroughly cleans the skin;
2、本申请含有的硅酸铝钾盐的具有温感的清洁组合物可在升温放热的同时,利用硅酸铝钾盐的吸附作用,配合组合物其他成分,温和高效的吸附皮肤表面污垢,高效清洁皮肤;2. The temperature-sensitive cleaning composition of potassium aluminum silicate contained in this application can use the adsorption effect of potassium aluminum silicate and cooperate with other components of the composition to gently and efficiently adsorb dirt on the skin surface while heating up and releasing heat. , effectively cleans the skin;
3、本申请清洁组合物在具有强清洁力的同时兼具高保湿性能,使得清洗过后皮肤滋润不紧绷,避免了过度清洁对皮肤造成的损伤,安全温和,适用于多种肤质,能够广泛应用推广;3. The cleaning composition of this application has strong cleaning power and high moisturizing performance at the same time, so that the skin is moisturized and not tight after cleaning, and avoids damage to the skin caused by excessive cleaning. It is safe and gentle, suitable for various skin types, and can Wide application and promotion;
4、本申请中采用棕榈酸乙基己酯、辛酸癸酸甘油三酯或牛油果树果脂提取物作为基础油脂,与硅酸铝钾盐及其他成分共同组成清洁组合物稳定体系,能够达到以油养肤的效果,有效改善使用者皮肤状态。4. In this application, ethylhexyl palmitate, caprylic triglyceride or shea butter extract are used as the base oil, together with potassium aluminum silicate and other components to form a stable cleaning composition system, which can achieve the following The effect of oil nourishing skin can effectively improve the user's skin condition.
具体实施方式Detailed ways
为了更清楚的阐释本申请的整体构思,下面以实施例的方式进行详细说明。在下文的描述中,给出了大量具体的细节以便提供对本发明更为彻底的理解。然而,对于本领域技术人员来说显而易见的是,本发明可以无需一个或多个这些细节而得以实施。在其他的例子中,为了避免与本发明发生混淆,对于本领域公知的一些技术特征未进行描述。In order to illustrate the overall concept of the present application more clearly, the following will be described in detail in the form of examples. In the following description, numerous specific details are given in order to provide a more thorough understanding of the present invention. It will be apparent, however, to one skilled in the art that the present invention may be practiced without one or more of these details. In other examples, some technical features known in the art are not described in order to avoid confusion with the present invention.
实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。Those who do not indicate the specific conditions in the examples are carried out according to the conventional conditions or the conditions suggested by the manufacturer.
其中,椰油酰胺丙基甜菜碱、硅酸铝钾盐,由上海麦克林生化科技有限公司提供,其中硅酸铝钾盐粒径为0.4-0.5mm;棕榈酸乙基己酯、鲸蜡基聚二甲基硅氧烷、脂肪醇聚氧乙烯醚、水合硅石、甘油、山梨醇、月桂酰谷氨酸钠、氯化钠由上海阿拉丁生化科技股份有限公司提供;辛酸癸酸甘油三酯、牛油果树果脂提取物由北京灵宝科技有限公司提供;甘油三异硬脂酸酯由江苏省海安石油化工厂提供;聚乙烯由上海凯茵化工有限公司提供;碳酸丙二醇酯、MIGLYOL 840Gel B由广州启嘉化工有限公司提供,其中MIGLYOL 840Gel B为840Gel B,其主要成分为丙二醇二辛酸酯/二癸酸酯及司拉氯铵水辉石及碳酸丙二醇酯;蜂蜡由西亚化学试剂有限公司提供;橄榄壳颗粒,粒度为40-80目,由河南威邦环保科技有限公司提供;月桂醇磺基琥珀酸酯二钠由广州远达新材料有限公司提供;月桂酰羟乙磺酸钠由湖北科易佳化工有限公司提供;植物磨砂颗粒、细硅石磨砂颗粒由灵寿县圣邦矿产品加工厂提供;接枝淀粉为丙烯酸接枝淀粉300,由北京翌桧东方商贸有限公司提供;水溶霍霍巴酯蜡由广州市宝隆国际贸易有限公司提供;防腐剂为防腐剂EG5,由广州简恺生物科技有限公司提供;皮肤水分测试仪为MoistureMeter SC,由上海怡宽实业有限公司提供。Among them, cocamidopropyl betaine and potassium aluminum silicate are provided by Shanghai McLean Biochemical Technology Co., Ltd., wherein the potassium aluminum silicate has a particle size of 0.4-0.5mm; ethylhexyl palmitate, cetyl Polydimethylsiloxane, fatty alcohol polyoxyethylene ether, hydrated silica, glycerin, sorbitol, sodium lauroyl glutamate, and sodium chloride were provided by Shanghai Aladdin Biochemical Technology Co., Ltd.; caprylic capric triglyceride , Shea butter extract was provided by Beijing Lingbao Technology Co., Ltd.; glycerol triisostearate was provided by Jiangsu Haian Petrochemical Factory; polyethylene was provided by Shanghai Kaiyin Chemical Co., Ltd.; propylene carbonate, MIGLYOL 840Gel B Provided by Guangzhou Qijia Chemical Co., Ltd., of which MIGLYOL 840Gel B is 840Gel B, its main components are propylene glycol dicaprylate/dicaprate, steralnium chloride hectorite and propylene glycol carbonate; beeswax is provided by West Asia Chemical Reagent Co., Ltd.; olive shell particles, particle size is 40-80 mesh, Provided by Henan Weibang Environmental Protection Technology Co., Ltd.; disodium lauryl sulfosuccinate is provided by Guangzhou Yuanda New Material Co., Ltd.; sodium lauroyl isethionate is provided by Hubei Keyijia Chemical Co., Ltd.; plant scrub particles, The fine silica abrasive particles are provided by Lingshou County Shengbang Mineral Products Processing Factory; the grafted starch is acrylic acid grafted starch 300, provided by Beijing Yihui Dongfang Trading Co., Ltd.; the water-soluble jojoba ester wax is provided by Guangzhou Baolong International Trade Co., Ltd. Provided; the preservative is preservative EG5, provided by Guangzhou Jiankai Biotechnology Co., Ltd.; the skin moisture tester is MoistureMeter SC, provided by Shanghai Yikuan Industrial Co., Ltd.
如未特殊说明,在以下实施方式中,所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。Unless otherwise specified, in the following embodiments, the reagents or instruments used are not indicated by the manufacturer, but are all conventional products that can be purchased from the market.
实施例1组合物成分筛选实验Embodiment 1 composition component screening experiment
本实施例中针对硅酸铝钾盐进行悬浮实验,对其配合物进行筛选。In this example, a suspension experiment was carried out on potassium aluminum silicate, and its complexes were screened.
具体实验方法为:步骤1、把不同油脂、7份MIGLYOL 840Gel B、2份聚乙烯、8份蜂蜡,加入乳化锅中,加热到88℃-90℃保温15分钟,以30-50r/min速度进行搅拌至完全溶解;步骤2、搅拌至温度降至65℃,搅拌混合均匀后加入30份硅酸铝钾盐,搅拌分散均匀后,加入5份水合硅石、0.1份橄榄壳颗粒搅拌均匀;步骤3、在温度控制在40℃-50℃的情况下边搅拌边灌装,常温放置12小时后结成结实膏体。The specific experimental method is: Step 1. Add different oils, 7 parts of MIGLYOL 840Gel B, 2 parts of polyethylene, and 8 parts of beeswax into the emulsification pot, heat it to 88°C-90°C and keep it warm for 15 minutes at a speed of 30-50r/min Stir until completely dissolved; step 2, stir until the temperature drops to 65°C, stir and mix evenly, add 30 parts of aluminum silicate potassium salt, stir and disperse evenly, add 5 parts of hydrated silica, 0.1 part of olive shell particles and stir evenly; step 3. Fill while stirring while controlling the temperature at 40°C-50°C, and form a firm paste after standing at room temperature for 12 hours.
膏体制作完成后,观察其状态,判断酸铝钾盐是否在体系中均匀悬浮,观察结果如表1所示。After the paste is made, observe its state to judge whether the aluminum potassium salt is evenly suspended in the system. The observation results are shown in Table 1.
表1Table 1
油脂可选择棕榈酸乙基己酯、辛酸辛酸癸酸甘油三酯或牛油果树果脂提取物,但略有出水的现象,为进一步提高体系的长时间存放稳定性进一步采用不同表面活性剂与上述优选后的油脂进行复配。将优选后的油脂与不同表面活性剂混合均质,均质速度为600-800r/min,观察结果如表2所示。The oil can choose ethylhexyl palmitate, caprylic caprylic capric triglyceride or shea butter extract, but there is a slight water out phenomenon, in order to further improve the long-term storage stability of the system, different surfactants and the above-mentioned The optimized oil is compounded. The optimized grease was mixed with different surfactants for homogenization, and the homogenization speed was 600-800r/min. The observation results are shown in Table 2.
表2Table 2
如表2结果所示,经试验证明,组合物成分优选为硅酸铝钾盐25-35份、油脂25-35份、脂肪醇聚氧乙烯醚5-10份、甘油三异硬脂酸酯8-15份。其中各成分间具有配合作用,在本实施例质量比范围内,各成分共同组成稳定体系。As shown in the results in Table 2, it has been proved by experiments that the components of the composition are preferably 25-35 parts of potassium aluminum silicate, 25-35 parts of oil, 5-10 parts of fatty alcohol polyoxyethylene ether, glycerin triisostearate 8-15 servings. Each component has a synergistic effect, and within the mass ratio range of this embodiment, each component together forms a stable system.
实施例2Example 2
本实施例中提供了一种具有温感的磨砂膏,包括以下重量份组分:粒径为0.4-0.5mm的硅酸铝钾盐30份,棕榈酸乙基己酯32份,脂肪醇聚氧乙烯醚6份,甘油三异硬脂酸酯(PEG-20)10份,MIGLYOL 840Gel B 7份,聚乙烯2份,蜂蜡8份,水合硅石5份,橄榄壳颗粒0.1份。Provided in this embodiment is a scrub with a sense of warmth, including the following components in parts by weight: 30 parts of potassium aluminum silicate with a particle size of 0.4-0.5 mm, 32 parts of ethylhexyl palmitate, fatty alcohol poly 6 parts of oxyethylene ether, 10 parts of glycerol triisostearate (PEG-20), 7 parts of MIGLYOL 840Gel B, 2 parts of polyethylene, 8 parts of beeswax, 5 parts of hydrated silica, 0.1 part of olive shell particles.
本实施例中提供了一种具有温感的磨砂膏的制作工艺,包括以下步骤:Provided in this embodiment is a process for making a warm scrub, comprising the following steps:
步骤1、把棕榈酸乙基己酯、脂肪醇聚氧乙烯醚和甘油三异硬脂酸酯(PEG-20)混合,均质至混合原料分散均匀,均质速度为600-800r/min;Step 1. Mix ethylhexyl palmitate, fatty alcohol polyoxyethylene ether and glycerol triisostearate (PEG-20), homogenize until the mixed raw materials are evenly dispersed, and the homogenization speed is 600-800r/min;
步骤2、在上述混合原料中继续加入MIGLYOL 840Gel B、聚乙烯、蜂蜡,乳化锅中加热到88℃-90℃保温15分钟,以30-50r/min速度进行搅拌至完全溶解;Step 2. Continue to add MIGLYOL 840Gel B, polyethylene, and beeswax to the above mixed raw materials, heat in an emulsification pot to 88°C-90°C for 15 minutes, and stir at a speed of 30-50r/min until completely dissolved;
步骤3、搅拌至温度降至65℃,混合均匀后加入硅酸铝钾盐,搅拌分散,分散均匀后,加入水合硅石、橄榄壳颗粒继续搅拌均匀;Step 3. Stir until the temperature drops to 65°C. After mixing evenly, add potassium aluminum silicate, stir to disperse, and after dispersing evenly, add hydrated silica and olive shell particles and continue to stir evenly;
步骤4、在温度控制在40℃-50℃的情况下边搅拌边灌装,常温放置12小时后结成结实膏体。Step 4. Fill while stirring while the temperature is controlled at 40°C-50°C, and form a firm paste after standing at room temperature for 12 hours.
实施例3Example 3
本实施例中提供了一种具有温感的磨砂膏,包括以下重量份组分:粒径为0.4-0.5mm的硅酸铝钾盐30份,辛酸辛酸癸酸甘油三酯32份,脂肪醇聚氧乙烯醚6份,甘油三异硬脂酸酯(PEG-20)10份,MIGLYOL 840Gel B 7份,聚乙烯2份,蜂蜡8份,水合硅石5份,橄榄壳颗粒0.1份。Provided in this embodiment is a scrub with a sense of warmth, comprising the following components in parts by weight: 30 parts of potassium aluminum silicate with a particle diameter of 0.4-0.5 mm, 32 parts of caprylic caprylic capric triglycerides, fatty alcohol 6 parts of polyoxyethylene ether, 10 parts of glyceryl triisostearate (PEG-20), 7 parts of MIGLYOL 840Gel B, 2 parts of polyethylene, 8 parts of beeswax, 5 parts of hydrated silica, 0.1 part of olive shell particles.
本实施例中提供了一种具有温感的磨砂膏的制作工艺,包括以下步骤:Provided in this embodiment is a process for making a warm scrub, comprising the following steps:
步骤1、把辛酸辛酸癸酸甘油三酯、脂肪醇聚氧乙烯醚和甘油三异硬脂酸酯(PEG-20)混合,均质至混合原料分散均匀,均质速度为600-800r/min;Step 1. Mix caprylic caprylic capric triglyceride, fatty alcohol polyoxyethylene ether and glyceryl triisostearate (PEG-20), homogenize until the mixed raw materials are evenly dispersed, and the homogenization speed is 600-800r/min ;
步骤2、在上述混合原料中继续加入MIGLYOL 840Gel B、聚乙烯、蜂蜡,乳化锅中加热到88℃-90℃保温15分钟,以30-50r/min速度进行搅拌至完全溶解;Step 2. Continue to add MIGLYOL 840Gel B, polyethylene, and beeswax to the above mixed raw materials, heat in an emulsification pot to 88°C-90°C for 15 minutes, and stir at a speed of 30-50r/min until completely dissolved;
步骤3、搅拌至温度降至65℃,混合均匀后加入硅酸铝钾盐,搅拌分散,分散均匀后,加入水合硅石、橄榄壳颗粒继续搅拌均匀;Step 3. Stir until the temperature drops to 65°C. After mixing evenly, add potassium aluminum silicate, stir to disperse, and after dispersing evenly, add hydrated silica and olive shell particles and continue to stir evenly;
步骤4、在温度控制在40℃-50℃的情况下边搅拌边灌装,常温放置12小时后结成结实膏体。Step 4. Fill while stirring while the temperature is controlled at 40°C-50°C, and form a firm paste after standing at room temperature for 12 hours.
实施例4Example 4
本实施例中提供了一种具有温感的磨砂膏,包括以下重量份组分:粒径为0.4-0.5mm的硅酸铝钾盐30份,牛油果树果脂提取物32份,脂肪醇聚氧乙烯醚6份,甘油三异硬脂酸酯(PEG-20)10份,MIGLYOL 840Gel B 7份,聚乙烯2份,蜂蜡8份,水合硅石5份,橄榄壳颗粒0.1份。Provided in this embodiment is a warm-sensing scrub, comprising the following components in parts by weight: 30 parts of potassium aluminum silicate with a particle size of 0.4-0.5 mm, 32 parts of shea butter extract, fatty alcohol polysaccharide 6 parts of oxyethylene ether, 10 parts of glycerol triisostearate (PEG-20), 7 parts of MIGLYOL 840Gel B, 2 parts of polyethylene, 8 parts of beeswax, 5 parts of hydrated silica, 0.1 part of olive shell particles.
本实施例中提供了一种具有温感的磨砂膏的制作工艺,包括以下步骤:Provided in this embodiment is a process for making a warm scrub, comprising the following steps:
步骤1、把牛油果树果脂提取物、脂肪醇聚氧乙烯醚和甘油三异硬脂酸酯(PEG-20)混合,均质至混合原料分散均匀,均质速度为600-800r/min;Step 1. Mix shea butter extract, fatty alcohol polyoxyethylene ether and glyceryl triisostearate (PEG-20), and homogenize until the mixed raw materials are evenly dispersed, and the homogenization speed is 600-800r/min;
步骤2、在上述混合原料中继续加入MIGLYOL 840Gel B、聚乙烯、蜂蜡,乳化锅中加热到88℃-90℃保温15分钟,以30-50r/min速度进行搅拌至完全溶解;Step 2. Continue to add MIGLYOL 840Gel B, polyethylene, and beeswax to the above mixed raw materials, heat in an emulsification pot to 88°C-90°C for 15 minutes, and stir at a speed of 30-50r/min until completely dissolved;
步骤3、搅拌至温度降至65℃,混合均匀后加入硅酸铝钾盐,搅拌分散,分散均匀后,加入水合硅石、橄榄壳颗粒继续搅拌均匀;Step 3. Stir until the temperature drops to 65°C. After mixing evenly, add potassium aluminum silicate, stir to disperse, and after dispersing evenly, add hydrated silica and olive shell particles and continue to stir evenly;
步骤4、在温度控制在40℃-50℃的情况下边搅拌边灌装,常温放置12小时后结成结实膏体。Step 4. Fill while stirring while the temperature is controlled at 40°C-50°C, and form a firm paste after standing at room temperature for 12 hours.
实施例5Example 5
本实施例与实施例1的区别仅在于不含硅酸铝钾盐。The difference between this embodiment and embodiment 1 is that it does not contain potassium aluminum silicate.
对比例comparative example
本对比例中提供了一种全表活体系的磨砂膏,包括以下重量份组分:甘油15份,月桂醇磺基琥珀酸酯二钠30份,月桂酰羟乙磺酸钠10份,植物磨砂颗粒0.5份,细硅石磨砂颗粒5份,山梨醇4份,椰油酰胺丙基甜菜碱6份,接枝淀粉2.5份,月桂酰谷氨酸钠1份,氯化钠2份,水溶霍霍巴酯蜡0.5份,防腐剂1份,余量为水。Provided in this comparative example is a scrub cream with a full surface activity system, including the following components in parts by weight: 15 parts of glycerin, 30 parts of disodium lauryl sulfosuccinate, 10 parts of sodium lauroyl isethionate, plant 0.5 parts of scrub granules, 5 parts of fine silica scrub granules, 4 parts of sorbitol, 6 parts of cocamidopropyl betaine, 2.5 parts of grafted starch, 1 part of sodium lauroyl glutamate, 2 parts of sodium chloride, water soluble Huohuo 0.5 part of wax ester wax, 1 part of preservative, and the balance is water.
将以上组分按以下步骤制作:The above components are made according to the following steps:
步骤1、预备:将设备清洗干净备用,把甘油和接枝淀粉混合一起,分散均匀;Step 1. Preparation: Clean the equipment for later use, mix glycerin and grafted starch together, and disperse evenly;
步骤2、把月桂酰羟乙磺酸钠、月桂醇磺基琥珀酸酯二钠、月桂酰谷氨酸钠、山梨醇、水溶霍霍巴酯蜡、水,加入到主乳化锅中,加热到88-90℃保温15分钟,慢搅拌至完全溶解(可适当低速均质);Step 2. Add sodium lauroyl isethionate, disodium lauryl sulfosuccinate, sodium lauroyl glutamate, sorbitol, water-soluble jojoba ester wax, and water into the main emulsification pot and heat to 88 Incubate at -90°C for 15 minutes, stir slowly until completely dissolved (homogenize at a suitable low speed);
步骤3、取少量液体观察无颗粒后,再加入氯化钠,搅拌混合均匀后加入细硅石磨砂颗粒、植物磨砂颗粒搅拌分散均匀,搅拌分散均匀后,加入已经混合好的甘油、接枝淀粉及椰油酰胺丙基甜菜碱搅拌均匀,88-90℃保温10分钟,降温;Step 3. Take a small amount of liquid and observe that there are no particles, then add sodium chloride, stir and mix evenly, add fine silica frosting particles, plant frosting particles, stir and disperse evenly, after stirring and dispersing evenly, add glycerin, grafted starch and Stir cocamidopropyl betaine evenly, keep warm at 88-90°C for 10 minutes, and cool down;
步骤4、搅拌至温度降至65℃,加入防腐剂,搅拌均匀;Step 4. Stir until the temperature drops to 65°C, add preservatives, and stir evenly;
步骤5、报检合格后出料,在保温(温度控制在56-60℃)的情况下边搅拌边灌装,常温放置12小时后结成结实膏体,即为全表活体系磨砂膏。Step 5. After passing the inspection, discharge the material, fill it while stirring while keeping warm (the temperature is controlled at 56-60°C), and leave it at room temperature for 12 hours to form a firm paste, which is the full surface activity system scrub.
实施例6磨砂膏使用感调查Embodiment 6 Scrub use sense survey
本实施例中针对上述实施例2~5和对比例磨砂膏进行清洁力试验。In this embodiment, the cleaning power test is carried out for the above-mentioned examples 2 to 5 and the scrub cream of the comparative example.
具体实验方法为:随机选取年龄区间在18-30岁内50名消费者,性别随机确定,任意等分成五组,分别使用实施例2-5及对比例的磨砂膏进行沐浴,使用时间1个月,两天使用一次,调查消费者对于实施例2、3、4、5及对比例使用感受并对其结果进行评价,具体结果见表3所示。The specific experimental method is: randomly select 50 consumers in the age range of 18-30 years old, determine their sex at random, divide them into five groups at random, use the scrubs of Examples 2-5 and the comparative example to bathe, and use them for 1 month Month, use once every two days, survey consumer for embodiment 2,3,4,5 and comparative example use experience and evaluate its result, and concrete result is shown in table 3.
表3table 3
由表3可见,100%消费者认为本申请中实施例2-4产品具有很好的清洁力,100%消费者认为使用过程温和不刺激,100%消费者认为使用过程有热感,83.33%的消费者认为保湿性较好,洗后不紧绷。As can be seen from Table 3, 100% of consumers think that the products of Examples 2-4 in the present application have good cleaning power, 100% of consumers think that the use process is mild and not irritating, 100% of consumers think that the use process has a sense of heat, 83.33% of consumers think that the moisturizing effect is better, and the skin does not feel tight after washing.
本申请中硅酸铝钾盐为多孔结构,吸附能力强,在遇水发热同时可有效吸附皮肤上杂质,搭配PEG-20表活,故实施例2-4的磨砂膏与全表活体系的磨砂膏相比有较好的清洁效果。且本申请所述磨砂膏体系在保证清洁力高的同时,兼具温和性和保湿性,给消费者带来良好的使用感受。In this application, potassium aluminum silicate has a porous structure and strong adsorption capacity. It can effectively absorb impurities on the skin when exposed to water and generate heat. It is matched with PEG-20 surface activity, so the scrub cream of Examples 2-4 is compatible with the total surface activity system. Scrubs have a better cleaning effect than scrubs. Moreover, the scrub system described in the present application has both mildness and moisturizing properties while ensuring high cleaning power, and brings good use experience to consumers.
实施例7磨砂膏保湿力试验Embodiment 7 Scrub moisturizing power test
采用上述对比例和实施例2-4继续对磨砂膏进行保湿力测试。Using the above comparative examples and Examples 2-4 to continue to test the moisturizing power of the scrub.
具体实验方法为:随机选取年龄区间在18-60岁内40名消费者,性别随机确定,任意等分成四组,分别使用实施例2-4的磨砂膏和对比例按摩涂抹手臂,单次涂抹后清洗干净,涂抹量为4cm*5cm,约300mg。于恒温(21±1℃,50±10%湿度)条件下,清洗完成后0h、1h、2h为节点,使用皮肤水分测试仪进行手臂皮肤角质层水合含量CAP值测定,并以0h CAP值为基础计算CAP下降率,具体结果见表4所示。The specific experimental method is: randomly select 40 consumers in the age range of 18-60 years old, gender is randomly determined, and they are randomly divided into four groups, and the scrub cream of embodiment 2-4 and the comparative example are used to massage and smear the arms respectively, and the single smear After cleaning, the amount of application is 4cm*5cm, about 300mg. Under the condition of constant temperature (21±1°C, 50±10% humidity), 0h, 1h, and 2h after cleaning are taken as nodes, and the CAP value of the hydration content of the stratum corneum of the arm skin is measured with a skin moisture tester, and the 0h CAP value is Based on the calculation of the CAP decline rate, the specific results are shown in Table 4.
CAP下降率=(CAP0h-CAPx h)/CAP0h CAP descent rate = (CAP 0h -CAP xh )/CAP 0h
CAP0h为0h测得CAP值,X为对应的时间(1h或2h),CAPx h为X h测得CAP值。CAP 0h is the CAP value measured at 0h, X is the corresponding time (1h or 2h), and CAP xh is the CAP value measured at X h.
表4Table 4
由表4可见,磨砂膏保湿力试验中,实施例2-4中磨砂膏使用1h、2h后,手臂皮肤角质层水合含量CAP值较T0均有下降,但其CAP值下降率小于对比例,即本申请中实施例2-4中磨砂膏保湿性能优于对比例。It can be seen from Table 4 that in the scrub moisturizing power test, after using the scrub in Example 2-4 for 1 hour and 2 hours, the CAP value of the hydration content of the stratum corneum of the arm skin decreased compared with T0, but the rate of decline in the CAP value was lower than that of the comparative example. That is, the moisturizing performance of the scrub cream in Examples 2-4 of the present application is better than that of the comparative examples.
本申请中采用棕榈酸乙基己酯、辛酸癸酸甘油三酯或牛油果树果脂提取物作为基础油脂成分,起到呵护皮脂膜的作用,在使用产品之后,皮肤水分散失量少,故磨砂膏保湿效果相比于其他产品更好。In this application, ethylhexyl palmitate, caprylic triglyceride or shea butter extract are used as the basic oil components to protect the sebum membrane. The moisturizing effect of the cream is better than other products.
以上所述仅为本申请的实施例而已,并不用于限制本申请。对于本领域技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原理之内所作的任何修改、等同替换、改进等,均应包含在本申请的权利要求范围之内。The above descriptions are only examples of the present application, and are not intended to limit the present application. For those skilled in the art, various modifications and changes may occur in this application. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present application shall be included within the scope of the claims of the present application.
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