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CN1151724C - Composite herbicide for rice field - Google Patents

Composite herbicide for rice field Download PDF

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Publication number
CN1151724C
CN1151724C CNB011199059A CN01119905A CN1151724C CN 1151724 C CN1151724 C CN 1151724C CN B011199059 A CNB011199059 A CN B011199059A CN 01119905 A CN01119905 A CN 01119905A CN 1151724 C CN1151724 C CN 1151724C
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China
Prior art keywords
fields
rice
present
weed killer
barnyard grass
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Expired - Fee Related
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CNB011199059A
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Chinese (zh)
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CN1393132A (en
Inventor
吴元林
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National Federation of Agricultural Cooperative Associations
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ZHEJIANG LEJI CHEMICAL CO Ltd
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Abstract

The present invention relates to a composite weed killer for rice fields. The present invention has the characteristics of broad weeding spectrum, good weeding effect, safety to rice, safety to environment, convenient use, etc. The main components comprise oxaziclomefone and a sulfonylurea weed killer (arbitrary one of bensulfuron-methyl, pyrazosulfuron-ethyl or cinosulfuron), and the weight ratio of the effective components of the oxaziclomefone to sulfonylurea weed killer by mixture is (0.1 to 10): 1.According to differently selected auxiliary agents, the practical dosage form can be prepared into the dosage forms such as water suspension agents, wettable powders, tablets, water dispersion granules. The present invention is suitable for various rice fields and can once prevent and kill gramineae, sedge family and broadleaf weeds. The present invention has a broad popularization and use prospect in rice light-duty cultivation fields such as seedling fields, direct seeding fields, seedling throwing fields, etc. with the characteristics of various weeds, early germination, long emergence period and great generation capacity.

Description

The composite herbicide that is used for the rice field
The invention belongs to chemical pesticide, be specifically related to the weed killer herbicide of paddy field.
Active ingredient mainly contains two kinds: a kind of is that effective ingredient is pacified for going barnyard grass, and another kind is sulfonylurea herbicide (any in bensulfuron-methyl, pyrazosulfuron or the cinosulfuron).
Go barnyard grass peace (0xaziclomefone), its structural formula is
Bensulfuron-methyl (bensulfuron methyl) chemical name is 2-{[(4,6-dimethoxypyridin-2-yl) amino carbonyl amino] the sulfonyl methyl } methyl benzoate, its molecular formula is: ester is C 16H 18N 4O 7S, acid is C 15H 16N 4O 7S.Its structural formula is
Pyrazosulfuron (pyrazosulfuron-ethyl) chemical name is: 5-(4,6-dimethoxypyridin base 2-carbamyl sulfonamides)-1-methylpyrazole base-4-ethyl ester; Its molecular formula is: C 14H 18N 6O 7S; Its structural formula is:
Yellow grand (cinosulfuron) chemical name of ether is 1-(4,6-dimethoxy-1,3,5-triazines 2-yl)-3-[2 (2-methoxy ethoxy) phenyl sulphonyl] urea; Chemical formula is:
C 15H 19N 5O 7S; Its structural formula is:
Figure C0111990500041
Going barnyard grass peace is to absorb translocated herbicide, is mainly absorbed by weeds root and cauline leaf base portion, weeds leaves and stems chlorosis, stops growing, until withered.Chemical test is the result prove, with inhibition DNA, protein, amino acid, the lipogenesis of existing weed killer herbicide, suppresses mitotic mechanism of action difference, and this weed killer herbicide has new mechanism of action.In addition; Find that in the wheat water culture experiment activity of weeding that goes barnyard grass to pacify can be along with adding plant hormone GA 3And disappear, therefore infer the mechanism of action and the plant endogenesis GA of this weed killer herbicide 3Metabolic activity hinder relevant.In addition, because the absorption conduction in paddy rice, weeds and the difference of accretion rate make and go the barnyard grass peace to have high selectivity, to rice safety.Go barnyard grass peace efficient, Monochoria vaginalis, short arrowhead are had certain effect paddy field barnyard grass grass, moleplant seed, mexicana, difformed galingale herb, but to anti-heterodynes such as flat bar Fischer grass, needle spikesedge herb, Procumbent Falsepimpernel, false loosestrife, convexutricle sedge herb, firefly Lin, sweet wine intestines.
Sulfonylurea herbicide (in bensulfuron-methyl, pyrazosulfuron or the cinosulfuron any) is a kind of selectivity inner sucting conduction type weed killer herbicide, can be absorbed by root of weeds and blade, and transfer to the weeds complete stool very soon, can hinder the amino acid whose biosynthesis of weeds, thereby stop cell division and growth, but as safe as a house to paddy rice, be suitable for different soil properties, various types of paddy field weeding.Before bud or the bud post processing, annual and perennial broad leaved weed and sedge weed all there is good preventive effect, as four leaf duckweeds, pondweed, Monochoria vaginalis, short arrowhead, flat bar Fischer grass, needle spikesedge herb, Procumbent Falsepimpernel, false loosestrife, convexutricle sedge herb, lustrous and transparent Lin, sweet wine intestines etc., but poor to the preventive effect of grassy weeds such as barnyard grass grass, moleplant seed.
On producing, go barnyard grass peace and bensulfuron-methyl (or pyrazosulfuron, or cinosulfuron) all to can be used for rice seedling bed, live field, seedling throwing field, transplant field weeding.Under one situation, go the barnyard grass peace to use separately, consumption is about 2.7~3.3 gram effective ingredient/mus.Bensulfuron-methyl uses separately, and consumption is about 1.5~2 gram effective ingredient/mus.Pyrazosulfuron uses separately, and consumption is about 1.0~1.5 gram effective ingredient/mus, and cinosulfuron uses separately, and consumption is about 1.3~2.0 gram effective ingredient/mus.Singly under actual conditions, malignant weeds such as barnyard grass grass, moleplant seed, short arrowhead, mexicana all take place simultaneously, but spend the harm that barnyard grass peace or bensulfuron-methyl (or pyrazosulfuron, or cinosulfuron) all can not reach disposable control weeds.
In sum, the problem one of going barnyard grass peace and bensulfuron-methyl (or pyrazosulfuron, or cinosulfuron) to exist is to kill grass to compose extensively inadequately, and every kind of weed killer herbicide list usefulness all has the part weeds effectively not remove; The 2nd, remove the peaceful product cost of barnyard grass height, by independent using dosage, farming is originally at 15~16 yuan/mu; The 3rd, the peasant uses two kinds of weed killer herbicides with in use, and then for using method, key points for operation etc. are difficult to again grasp when using with, actual being difficult to promotes.
The present invention seeks to shortcoming, a kind of composite herbicide is provided, can enlarge and kill the grass spectrum, herbicidal effect is good, safe in utilization and can effectively reduces farming originally at prior art.For achieving the above object, through test in a large number, obtained this Herbicidal composition.Its centre point is to go barnyard grass peace to be re-dubbed preparation with a kind of sulfonylurea herbicide (in bensulfuron-methyl, pyrazosulfuron or the cinosulfuron any), and the two effective ingredient weight ratio is: 0.1~10: 1.After containing above two kinds of active ingredients, add proper assistant, can be processed into the extensive stock preparation, as aqueous suspension agent, wetting powder, tablet, water dispersible granules, granule etc.
Advantage of the present invention and remarkable result:
1, activity of weeding height
Just can bring into play good herbicidal effect with low consumption, to the preventive effect of moleplant seed, barnyard grass grass, needle spikesedge herb, Monochoria vaginalis all greater than 85%.
2, fool proof to paddy rice
Can in all types of paddy fields such as live field, rice seedling bed, seedling throwing field, transplant field, use.
3, fool proof to environment
This medicament is extremely low to people and animals, fish, shellfish toxicity, and because usage amount is few, is insoluble in water, and adsorption by soil power is strong, and is seldom residual in environment.Even, can not exert an influence to second stubble crop, surrounding environment with 5 times of consumptions yet.
4, killing grass composes wider
This medicament has remedied the careless defective of killing of single agent separately, complements one another, and a drug just can remove most weeds in the paddy field.A drug just can be removed the crop smothering problem in all types of paddy fields.Particularly has fabulous preventive effect for the difficult moleplant seed of preventing and kill off of other medicaments.
5, it is very stable to kill careless effect
This medicament can be owing to temperature height, soil condition, spilling water, problem such as leak influence activity of weeding, and it is very stable to kill careless effect.
6, reduce dosage, effectively reduce farming originally
This medicament is after composite, and its dosage significantly reduces than each single agent dosage.As go the barnyard grass peace to reduce to 2.0 gram effective ingredient/mus from 2.7~3.3 gram effective ingredient/mus of single usefulness, bensulfuron-methyl is reduced to 1.0 gram effective ingredient/mus from 1.5~2.0 gram effective ingredient/mus of single usefulness, pyrazosulfuron is from 1.0~1.5 gram effective ingredient/mus of single usefulness, reduce to 0.8 gram effective ingredient/mu, cinosulfuron is reduced to 1.0 gram effective ingredient/mus from 1.3~2.0 gram effective ingredient/mus of single usefulness.Make every mu of total drug cost descend about 20~30%.
Dosage and herbicidal effect that attached 2000 years are singly used and use with separately about above-mentioned several medicaments.
Medicament Mu consumption/gram (effective ingredient) Herbicidal effect (behind the medicine 30 days, fresh weight preventive effect): %
Grass family Broadleaved herb Sedge family Total grass
Go the barnyard grass peace 2.7 92.3 15.8 16.2 50.2
3.3 99 25.2 26.1 60.1
Bensulfuron-methyl 1.5 16.3 90.4 92.0 48.5
2.0 22.9 98.4 98.6 62.4
Pyrazosulfuron 1.0 18.7 92.5 91.6 57.5
1.5 23.6 99.1 98.5 65.7
Cinosulfuron 1.3 22.3 91.8 94.6 53.9
2.0 25.6 98.5 100 59.8
Remove barnyard grass peace+bensulfuron-methyl 2.0+1.0 93.2 95.4 97.6 96.5
Remove barnyard grass peace+pyrazosulfuron 2.0+0.8 94.2 94.5 98.0 97.0
Remove barnyard grass peace+cinosulfuron 2.0+1.0 94.3 95.0 98.6 96.5
Under the situation of light cultivation technology fast developments such as live, rice transplanting in recent years, this medicament since its use wide model, broad weed-killing spectrum, herbicidal effect good, to characteristics such as rice safeties, will receive much concern, have the vast market popularizing application prospect.
The present invention program's embodiment:
1, each component percentage by weight of the present invention, practical formulation embodiment are: (annotate: sulfonylurea herbicide: in bensulfuron-methyl, pyrazosulfuron or the cinosulfuron any)
Embodiment one (aqueous suspension agent) embodiment two (wetting powders)
Go barnyard grass peace 1.0% to go barnyard grass peace 5.0%
Sulfonylurea herbicide 0.8% sulfonylurea herbicide 10.0%
KP-1436 4.0% Negel formaldehyde condensation products 3.5%
Amtifoam-E20 2.0% alkylphenol-polyethenoxy ichthyodin 6.0%
Polyvinyl alcohol 2.0% neopelex 2.0%
Proxel Gxl 0.5% white carbon 20%
Propane diols 10.0% diatomite supplies 100%
Deionized water supplies 100%
Embodiment three (tablet) embodiment four (water dispersible granules)
Go barnyard grass peace 1.0% to go barnyard grass peace 10%
Sulfonylurea herbicide 10.0% sulfonylurea herbicide 5.0%
Sodium lignin sulfonate 2% Lactis Anhydrous 30.%
Citric acid 9% sodium lignin sulfonate 20.%
Sodium carbonate 11.5% naphthalene sulfonic acid-formaldehyde condensation product 3.0%
Dolomol 3% sodium alkyl benzene sulfonate 2.5%
Lactose is supplied 100% bentonite and is supplied 100%
Embodiment five (granula)
Go barnyard grass peace 10.0%
Sulfonylurea herbicide 1.0%
Carclazyte powder No. 1 30%
Potter's clay powder 30%
JX glue 0.5%
Paraffin 9.0%
Dispersing agent NNO 5.0%
White carbon supplies 100%
2, effective ingredient using dosage scope (unit: gram/hectare)
Go the barnyard grass peace to be: 20~75
Bensulfuron-methyl is: 15~45
(or pyrazosulfuron is: 10~40)
(cinosulfuron is: 12~45)
Embodiment is as follows:
1 2 3 4 5
Go barnyard grass to pacify 20.0 30.0 40.0 50.0 60.0
Bensulfuron-methyl 40.0 35.0 30.0 25.0 20.0
(or pyrazosulfuron 35.0 30.0 25.0 20.0 15.0)
(or cinosulfuron 40.0 35.0 30.0 25.0 20.0)

Claims (1)

1, the composite herbicide that is used for the rice field, it is characterized in that comprising two kinds of active ingredients, promptly remove barnyard grass peace and a kind of sulfonylurea herbicide, wherein sulfonylurea herbicide is any in bensulfuron-methyl, pyrazosulfuron or the cinosulfuron, and it is 0.1~10: 1 that active ingredient goes the barnyard grass peace and the weight ratio of sulfonylurea herbicide.
CNB011199059A 2001-06-29 2001-06-29 Composite herbicide for rice field Expired - Fee Related CN1151724C (en)

Priority Applications (1)

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102369922B (en) * 2011-10-19 2013-08-14 广东中迅农科股份有限公司 Pyrazosulfuron water dispersible granule and preparation method thereof
CN102524278A (en) * 2011-12-13 2012-07-04 济南科赛基农化工有限公司 Oxaziclomefone, pyrazosulfuron, pretilachlor ternary effervescent herbicide for paddy fields and preparation method thereof
CN103329917B (en) * 2013-06-04 2016-04-27 广东中迅农科股份有限公司 The Herbicidal combinations of a kind of Han You oxaziclomefone and bensulfuron-methyl
CN103329909B (en) * 2013-06-04 2016-05-11 广东中迅农科股份有限公司 The Herbicidal combinations of a kind of Han You oxazine humulone and mesotrione
CN103329910A (en) * 2013-06-04 2013-10-02 广东中迅农科股份有限公司 Weeding composition containing oxaziclomefone and pyribenzoxim
CN103340208B (en) * 2013-06-04 2016-04-27 广东中迅农科股份有限公司 The Herbicidal combinations of a kind of Han You oxaziclomefone and pyrazosulfuron
CN103461365B (en) * 2013-08-20 2016-04-06 湖南农大海特农化有限公司 A kind of composition pesticide preventing and kill off paddy field weed
CN103430955A (en) * 2013-08-29 2013-12-11 江苏省农用激素工程技术研究中心有限公司 Weeding composition containing halosulfuron-methyl and oxaziclomefone
CN106857625A (en) * 2017-04-07 2017-06-20 安徽蓝田农业开发有限公司 Herbicidal composition and its application of a kind of Han oxaziclomefones and cafenstrole
CN112753702A (en) * 2021-01-08 2021-05-07 黑龙江巨卓作物科学有限公司 Weeding composition containing oxaziclomefone, clomazone and pyrazosulfuron-ethyl

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