[go: up one dir, main page]

CN115125420A - A kind of cast aluminum alloy for high-performance structural parts without heat treatment and preparation method thereof - Google Patents

A kind of cast aluminum alloy for high-performance structural parts without heat treatment and preparation method thereof Download PDF

Info

Publication number
CN115125420A
CN115125420A CN202210800086.0A CN202210800086A CN115125420A CN 115125420 A CN115125420 A CN 115125420A CN 202210800086 A CN202210800086 A CN 202210800086A CN 115125420 A CN115125420 A CN 115125420A
Authority
CN
China
Prior art keywords
aluminum alloy
pure
structural parts
heat treatment
performance structural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202210800086.0A
Other languages
Chinese (zh)
Other versions
CN115125420B (en
Inventor
叶珍
曹学锋
郑长清
苗赛男
周亚伟
张少文
徐连弟
梁振洲
李泉
安磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baoding Lizhong Wheel Manufacturing Co ltd
Original Assignee
Baoding Lizhong Wheel Manufacturing Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baoding Lizhong Wheel Manufacturing Co ltd filed Critical Baoding Lizhong Wheel Manufacturing Co ltd
Priority to CN202210800086.0A priority Critical patent/CN115125420B/en
Publication of CN115125420A publication Critical patent/CN115125420A/en
Application granted granted Critical
Publication of CN115125420B publication Critical patent/CN115125420B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0075Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Continuous Casting (AREA)
  • Forging (AREA)

Abstract

The invention relates to the technical field of alloy materials, and particularly discloses a heat-treatment-free high-performance structural member cast aluminum alloy and a preparation method thereof. The aluminum alloy comprises the following components in percentage by mass: si: 6.0-8.5%, Mg: 0.05-0.40%, Cu: 0.50-0.85%, Cr: 0.20-0.60%, Er: 0.01-0.10%, Mn: 0.45-0.75%, Zn: 0.1% -3.0%, V: 0.04-0.14%, Ni: 0.01 to 0.1 percent of Ba, less than or equal to 0.1 percent of Y, less than or equal to 0.16 percent of Fe, and the balance of Al. The preparation method provided by the invention can enable the aluminum alloy to have excellent mechanical properties under the condition of no solid solution heat treatment, meet the use requirements, and can also avoid the problem that large parts are easy to deform in the high-temperature solid solution treatment process.

Description

一种可免热处理高性能结构件铸造铝合金及其制备方法A kind of cast aluminum alloy for high-performance structural parts without heat treatment and preparation method thereof

技术领域technical field

本发明涉及铝合金材料术领域,尤其涉及一种可免热处理高性能结构件铸造铝合金及其制备方法。The invention relates to the field of aluminum alloy material technology, in particular to a heat-treatment-free high-performance structural component cast aluminum alloy and a preparation method thereof.

背景技术Background technique

目前汽车轻量化是新能源汽车产业的发展的迫切需求,而结构件压铸工艺及结构件用材料制造技术是汽车轻量化发展的关键,因此,汽车行业对于一体化压铸技术的需求也日益增长。一体化压铸能够大大减轻结构件的重量,降低生产成本,还能进一步提高汽车的安全性能。传统的铝合金汽车的结构受力件为满足力学性能的使用要求,往往需要进行固溶热处理和时效热处理进行强化,以提高其力学性能。At present, the lightweight of automobiles is an urgent need for the development of the new energy automobile industry, and the die-casting process of structural parts and the manufacturing technology of materials for structural parts are the key to the development of lightweight automobiles. Therefore, the demand for integrated die-casting technology in the automobile industry is also increasing. Integrated die casting can greatly reduce the weight of structural parts, reduce production costs, and further improve the safety performance of automobiles. In order to meet the requirements of mechanical properties, the structural stress-bearing parts of traditional aluminum alloy vehicles often need to be strengthened by solution heat treatment and aging heat treatment to improve their mechanical properties.

但是固溶热处理阶段的温度较高,温度至少大于500℃,时间一般大于2h,导致结构件在长时间高温加热和淬火工艺中,极易引起变形,大型部件变形尤其严重,例如电动车电池托架和副车架等。随着集成化应用领域的进一步扩大,集成后的结构件尺寸更大、形状更复杂,不适合再经固溶热处理进行强化。而传统的铝合金材料在未经固溶热处理的条件下,力学性能基本达不到标准要求,此外,固溶热处理还需要额外消耗大量的能源、精力和时间,无形中增加了生产成本,因此,开展免固溶热处理或低温固溶热处理的铝合金材料的研究成为行业发展发展的必然需求。However, the temperature in the solution heat treatment stage is relatively high, the temperature is at least greater than 500 °C, and the time is generally greater than 2 hours, which leads to the deformation of the structural parts during the long-term high-temperature heating and quenching process, and the deformation of large parts is especially serious. frame and subframe, etc. With the further expansion of the integrated application field, the integrated structural parts are larger in size and more complex in shape, and are not suitable for further strengthening by solution heat treatment. However, the mechanical properties of traditional aluminum alloy materials without solution heat treatment basically do not meet the standard requirements. In addition, solution heat treatment requires additional consumption of a lot of energy, energy and time, which virtually increases production costs. Therefore, , the research on aluminum alloy materials without solution heat treatment or low temperature solution heat treatment has become an inevitable demand for the development of the industry.

发明内容SUMMARY OF THE INVENTION

针对现有大型部件在高温固溶处理过程中容易变形等问题,本发明提供一种可免热处理高性能结构件铸造铝合金。Aiming at the problems that the existing large parts are easily deformed during the high-temperature solution treatment, the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment.

以及,本发明还提供一种可免热处理高性能结构件铸造铝合金的制备方法。And, the present invention also provides a preparation method of cast aluminum alloy for high-performance structural parts without heat treatment.

为达到上述发明目的,本发明实施例采用了如下的技术方案:In order to achieve the above-mentioned purpose of the invention, the embodiment of the present invention adopts the following technical scheme:

一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:6.0%~8.5%、Mg:0.05%~0.40%、Cu:0.50%~0.85%、Cr:0.20%~0.60%、Er:0.01%~0.10%、Mn:0.45%~0.75%、Zn:0.1%~3.0%、V:0.04%~0.14%、Ni:0.01%~0.1%、Ba≤0.1%、Y≤0.1%、Fe≤0.16%,其他杂质元素含量总和≤0.25%,余量为Al。A heat treatment-free high-performance structural casting aluminum alloy, comprising the following components by mass percentage: Si: 6.0%-8.5%, Mg: 0.05%-0.40%, Cu: 0.50%-0.85%, Cr: 0.20% ~0.60%, Er: 0.01%~0.10%, Mn: 0.45%~0.75%, Zn: 0.1%~3.0%, V: 0.04%~0.14%, Ni: 0.01%~0.1%, Ba≤0.1%, Y ≤0.1%, Fe≤0.16%, the total content of other impurity elements is ≤0.25%, and the balance is Al.

相对于现有技术,本申请提供的可免热处理高性能结构件铸造铝合金,具有以下优势:Compared with the prior art, the cast aluminum alloy for heat treatment-free high-performance structural parts provided by the present application has the following advantages:

本申请通过加入特定含量的Cu、Mg、Si元素,在铝液凝固过程中,使得其能够在枝晶间生成Al2Cu、Mg2Si、Al-Si-Cu-Mg等强化相,通过该强化相与位错间的交互作用,阻碍了位错运动,显著提高了合金的变形抗力和力学强度;此外,合金基体中存在的Cu、Mg、Si元素,在快速冷却过程中,更多的保留在基体中,这部分强化元素会在后期时效热处理过程中在基体中形成强化相,从而提升基体强度,实现在不需进行额外固溶热处理的条件下,得到综合性能俱佳的铝合金材料;本发明还通过加入含量较高的Si元素,能够提升铝液的铸造性能,抵消冷速较快带来的不利影响。In the present application, by adding specific content of Cu, Mg, Si elements, during the solidification process of the molten aluminum, it can generate Al 2 Cu, Mg 2 Si, Al-Si-Cu-Mg and other strengthening phases between the dendrites. The interaction between the strengthening phase and dislocations hinders the movement of dislocations and significantly improves the deformation resistance and mechanical strength of the alloy; in addition, the elements of Cu, Mg, and Si in the alloy matrix, during the rapid cooling process, more Retained in the matrix, this part of the strengthening elements will form a strengthening phase in the matrix during the later aging heat treatment process, thereby improving the strength of the matrix, and achieving an aluminum alloy material with excellent comprehensive properties without additional solution heat treatment. In the present invention, the casting performance of the molten aluminum can be improved by adding Si element with a relatively high content, and the adverse effects caused by the faster cooling rate can be offset.

因Fe元素在凝固过程中,与Al、Si等元素会共同形成针片状β-Fe相,在受力过程中容易产生应力集中,从而割裂基体,使合金材料性能降低;本发明通过加入特定含量的Mn、Cr、V、Ni元素,可使合金中的针片状含Fe相变为颗粒状,不仅降低其割裂作用,还能作为强化相阻碍位错移动,使合金在无需热处理的情况下提升强度;此外,若是任意改变Mn、Cr、V、Ni之间的配比,会造成含Fe相尺寸急剧增加,导致对铸造铝合金材料的性能极为不利。During the solidification process of Fe element, together with Al, Si and other elements, a needle-like β-Fe phase is formed, and stress concentration is easily generated during the stress process, thereby splitting the matrix and reducing the performance of the alloy material. The content of Mn, Cr, V, and Ni elements can make the needle-like Fe-containing phase in the alloy into particles, which not only reduces its splitting effect, but also acts as a strengthening phase to hinder the movement of dislocations, so that the alloy does not need heat treatment. In addition, if the ratio between Mn, Cr, V, and Ni is arbitrarily changed, the size of the Fe-containing phase will increase sharply, which is extremely unfavorable to the performance of the cast aluminum alloy material.

本申请加入的Er、Y具有细化晶粒的作用,Ba元素能将共晶硅从层片状转为珊瑚状或颗粒状,降低应力集中,Y能够使共晶硅尺寸减小,够使得合金材料在免热处理的情况下,显著提升其强度和塑性,以满足使用要求。Er and Y added in this application have the effect of refining grains. Ba element can convert eutectic silicon from lamellar to coral or granular shape, reducing stress concentration. Y can reduce the size of eutectic silicon, which can make eutectic silicon smaller. The strength and plasticity of the alloy material can be significantly improved without heat treatment to meet the application requirements.

本申请加入的Zn元素,在凝固过程中能富集在Al-Si-Cu-Mg相及含Fe相表面,抑制其生长,使得Al-Si-Cu-Mg相及含Fe相的尺寸减小,还能显著提升铝合金材料的铸态性能,且时效过程中因Zn元素在α-Al相中的固溶度增加,将Zn元素固溶进α-Al内,有固溶强化作用,进而增加铝合金材料的强度。The Zn element added in this application can be enriched on the surface of the Al-Si-Cu-Mg phase and the Fe-containing phase during the solidification process, inhibiting their growth and reducing the size of the Al-Si-Cu-Mg phase and the Fe-containing phase , can also significantly improve the as-cast properties of aluminum alloy materials, and due to the increase in the solid solubility of Zn in the α-Al phase during the aging process, the Zn element is dissolved into α-Al, which has a solid solution strengthening effect, and then Increase the strength of aluminum alloy materials.

进一步地,本发明还提供一种可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:Further, the present invention also provides a preparation method of cast aluminum alloy for high-performance structural parts without heat treatment, comprising the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行预处理,然后按照如权利要求1所述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is pretreated respectively, then each component is weighed according to the raw material proportioning as claimed in claim 1;

步骤二、将预处理后的所述中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg完全熔化,得铝液;Step 2: The pretreated master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al- Y, pure Al and pure Mg are completely melted to obtain molten aluminum;

步骤三、于700℃~720℃条件下,向所述铝液中通入氩气,得精炼铝液;Step 3, under the condition of 700℃~720℃, pass argon gas into the molten aluminum to obtain the molten aluminum;

步骤四、当所述精炼铝液的温度为650℃~690℃时,将所述精炼铝液浇铸至温度为130℃~170℃的模具中,得试棒;Step 4. When the temperature of the refined aluminum liquid is 650°C to 690°C, the refined aluminum liquid is cast into a mold with a temperature of 130°C to 170°C to obtain a test bar;

步骤五、将所述试棒进行时效热处理,得可免热处理高性能结构件铸造铝合金。Step 5, subjecting the test bar to aging heat treatment, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

相对于现有技术,本申请提供的可免热处理高性能结构件铸造铝合金的制备方法,具有以下优势:Compared with the prior art, the preparation method of the cast aluminum alloy for heat treatment-free high-performance structural parts provided by the present application has the following advantages:

本申请在浇铸过程中,采用模具温度较低,使得铝液冷却速度较快,能够细化强化相,从而进一步提升合金强度,使合金不需进行固溶热处理的前提下,还具优异的力学性能,满足使用要求;同时控制模具的预热温度为130℃~170℃,还能降低冷却速度,防止冷速较快,产生裂纹等缺陷。In the casting process of the present application, the mold temperature is relatively low, so that the cooling rate of the aluminum liquid is faster, and the strengthening phase can be refined, thereby further improving the strength of the alloy, so that the alloy does not need to undergo solution heat treatment, and also has excellent mechanical properties. At the same time, the preheating temperature of the mold is controlled to be 130 ° C ~ 170 ° C, and the cooling speed can be reduced to prevent the cooling speed from being fast and the occurrence of cracks and other defects.

本申请提供的制备方法能够将铝合金材料在免固溶热处理的情况下,还具有优异的力学性能,满足使用要求,并能够避免大型部件在高温固溶处理过程中容易变形的问题,提高了成材率。The preparation method provided by the present application can make the aluminum alloy material have excellent mechanical properties without solid solution heat treatment, meet the requirements of use, and can avoid the problem that large parts are easily deformed during the high temperature solution treatment process, and improve the yield.

可选的,所述时效热处理的条件为:温度为150℃~230℃,时间为1h~3h。Optionally, the conditions of the aging heat treatment are as follows: the temperature is 150°C to 230°C, and the time is 1 hour to 3 hours.

优选的时效热处理条件能够使得Cu、Mg、Si元素在基体中形成强化相,提高铝合金基体的强度;并能够增加Zn元素在α-Al中的固溶度,将Zn元素固溶进α-Al内,进而增加铝合金材料的强度。The preferred aging heat treatment conditions can make Cu, Mg, Si elements form strengthening phases in the matrix, and improve the strength of the aluminum alloy matrix; and can increase the solid solubility of Zn element in α-Al, and solid solution of Zn element into α-Al Al, thereby increasing the strength of the aluminum alloy material.

可选的,所述氩气的流速为3-5L/min.Optionally, the flow rate of the argon is 3-5L/min.

可选的,所述氩气的通入时间为8min~12min。Optionally, the introduction time of the argon gas is 8 min to 12 min.

可选的,所述氩气的通气管口位于所述铝液的底部。Optionally, the vent of the argon gas is located at the bottom of the molten aluminum.

优选的氩气的通入条件,使得铝液处于氩气气氛中,避免铝液固化过程中产生氧化物,降低铝合金材料的力学性能;还能够将铝液中的杂质通过氮气上浮,将铝液中的有害元素以及杂质分离干净。The preferred argon inflow conditions make the molten aluminum in an argon atmosphere to avoid the generation of oxides during the solidification process of the molten aluminum and reduce the mechanical properties of the aluminum alloy material; it can also float the impurities in the molten aluminum through nitrogen to remove the aluminum The harmful elements and impurities in the liquid are separated cleanly.

可选的,步骤二中,在730℃~755℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置10min~20min,于700℃~720℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后得铝液。Optionally, in step 2, under the condition of 730 ℃ ~ 755 ℃, first place the master alloy Al-Si, Al-Cu and pure Al in a furnace for melting, and after complete melting, add the master alloy Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 10min-20min, and the master alloys Al-Er, Al-Ba, Al- Y, when all components are completely melted, the molten aluminum is obtained.

优选的加入顺序能够使得各元素在熔炼过程中生成特定的强化相如Al2Cu、Mg2Si、Al-Si-Cu-Mg等,提高铝合金材料的力学性能。The preferred order of addition enables each element to generate specific strengthening phases such as Al 2 Cu, Mg 2 Si, Al-Si-Cu-Mg, etc. during the smelting process, thereby improving the mechanical properties of the aluminum alloy material.

可选的,所述浇铸的铸造周期为35s~55s。Optionally, the casting cycle of the casting is 35s˜55s.

可选的,所述预处理的过程为:将所述中间合金、纯Al、纯Mg和纯Zn分别进行打磨、抛光、清洗和烘干。Optionally, the pretreatment process is as follows: grinding, polishing, cleaning and drying the master alloy, pure Al, pure Mg and pure Zn, respectively.

本申请通过打磨、抛光,将中间合金、纯Al、纯Mg和纯Zn表面的氧化皮除去,再通过清洗、烘干后即可进行称量,该预处理方法能尽力避免引入杂质元素。In the present application, the oxide scale on the surface of the master alloy, pure Al, pure Mg and pure Zn is removed by grinding and polishing, and then it can be weighed after cleaning and drying. This pretreatment method can try to avoid the introduction of impurity elements.

附图说明Description of drawings

为了更清楚地说明本发明实施例中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the technical solutions in the embodiments of the present invention more clearly, the following briefly introduces the drawings required in the embodiments. Obviously, the drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained from these drawings without any creative effort.

图1是本发明实施例1提供的微观组织图;Fig. 1 is the microstructure diagram provided in Example 1 of the present invention;

图2是本发明实施例1提供的局部放大微观组织图;2 is a partially enlarged microstructure diagram provided in Example 1 of the present invention;

图3是本发明对比例1提供的微观组织图;Fig. 3 is the microstructure diagram provided by comparative example 1 of the present invention;

图4是本发明对比例1提供的局部放大微观组织图。FIG. 4 is a partial enlarged microstructure diagram provided by Comparative Example 1 of the present invention.

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the objectives, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.

实施例1Example 1

本发明实施例1提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:7.0%、Mg:0.4%、Cu:0.70%、Cr:0.20%、Er:0.08%、Mn:0.60%、Zn:2.0%、V:0.04%、Ni:0.1%、Ba:0.06%、Y:0.02%,余量为Al。Embodiment 1 of the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 7.0%, Mg: 0.4%, Cu: 0.70%, Cr: 0.20%, Er: 0.08%, Mn: 0.60%, Zn: 2.0%, V: 0.04%, Ni: 0.1%, Ba: 0.06%, Y: 0.02%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行打磨、抛光以除去表面的氧化皮,之后进行清洗、烘干,然后按照上述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is polished and polished to remove the oxide scale on the surface, then cleaned and dried, and then each component is weighed according to the above-mentioned raw material ratio;

步骤二、在740℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置10min,于710℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后,得铝液;Step 2: Under the condition of 740°C, first place the master alloys Al-Si, Al-Cu and pure Al in a melting furnace for melting, and then add master alloys Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 10 minutes. The master alloys Al-Er, Al-Ba, and Al-Y were added at 710 °C. When all components were completely melted, aluminum was obtained. liquid;

步骤三、于710℃条件下,向所述铝液中通入氩气,得精炼铝液,氩气的流速为4L/min,通入时间为10min,且所述氩气的通气管口位于所述铝液的底部;Step 3. Under the condition of 710°C, pass argon gas into the molten aluminum to obtain the molten aluminum, the flow rate of argon gas is 4L/min, the feeding time is 10min, and the vent pipe opening of the argon gas is located at the bottom of the molten aluminum;

步骤四、当所述精炼铝液的温度为670℃时,将所述精炼铝液浇铸至温度为150℃的模具中,得试棒,铸造周期为50s;Step 4. When the temperature of the refined aluminum liquid is 670°C, the refined aluminum liquid is cast into a mold with a temperature of 150°C to obtain a test rod, and the casting cycle is 50s;

步骤五、将所述试棒于190℃条件下进行时效热处理3h,得可免热处理高性能结构件铸造铝合金。Step 5. The test rod is subjected to an aging heat treatment at 190° C. for 3 hours, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

实施例2Example 2

本发明实施例1提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:8.5%、Mg:0.3%、Cu:0.5%、Cr:0.2%、Er:0.01%、Mn:0.75%、Zn:0.1%、V:0.1%、Ni:0.08%、Ba:0.1%、Y:0.1%,余量为Al。Embodiment 1 of the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 8.5%, Mg: 0.3%, Cu: 0.5%, Cr: 0.2%, Er: 0.01%, Mn: 0.75%, Zn: 0.1%, V: 0.1%, Ni: 0.08%, Ba: 0.1%, Y: 0.1%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行打磨、抛光以除去表面的氧化皮,之后进行清洗、烘干,然后按照上述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is polished and polished to remove the oxide scale on the surface, then cleaned and dried, and then each component is weighed according to the above-mentioned raw material ratio;

步骤二、在730℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置15min,于720℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后,得铝液;Step 2: Under the condition of 730°C, first place the master alloy Al-Si, Al-Cu and pure Al in a furnace for smelting, and after complete melting, add the master alloy Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 15 minutes. The master alloys Al-Er, Al-Ba, and Al-Y were added at 720 °C. When all components were completely melted, aluminum was obtained. liquid;

步骤三、于720℃条件下,向所述铝液中通入氩气,得精炼铝液,氩气的流速为3L/min,通入时间为10min,且所述氩气的通气管口位于所述铝液的底部;Step 3. Under the condition of 720°C, argon gas is introduced into the aluminum liquid to obtain the refined aluminum liquid. The flow rate of argon gas is 3L/min, the introduction time is 10min, and the vent pipe opening of the argon gas is located at the bottom of the molten aluminum;

步骤四、当所述精炼铝液的温度为650℃时,将所述精炼铝液浇铸至温度为130℃的模具中,得试棒,铸造周期为35s;Step 4. When the temperature of the refined aluminum liquid is 650°C, the refined aluminum liquid is cast into a mold with a temperature of 130°C to obtain a test rod, and the casting cycle is 35s;

步骤五、将所述试棒于200℃条件下进行时效热处理1.5h,得可免热处理高性能结构件铸造铝合金。Step 5. The test rod is subjected to an aging heat treatment at 200° C. for 1.5 hours, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

实施例3Example 3

本发明实施例1提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:7.5%、Mg:0.2%、Cu:0.6%、Cr:0.6%、Er:0.1%、Mn:0.5%、Zn:1.0%、V:0.08%、Ni:0.01%、Ba:0.08%、Y:0.02%,余量为Al。Embodiment 1 of the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 7.5%, Mg: 0.2%, Cu: 0.6%, Cr: 0.6%, Er: 0.1%, Mn: 0.5%, Zn: 1.0%, V: 0.08%, Ni: 0.01%, Ba: 0.08%, Y: 0.02%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行打磨、抛光以除去表面的氧化皮,之后进行清洗、烘干,然后按照上述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is polished and polished to remove the oxide scale on the surface, then cleaned and dried, and then each component is weighed according to the above-mentioned raw material ratio;

步骤二、在755℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置20min,于700℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后,得铝液;Step 2: Under the condition of 755°C, first place the master alloys Al-Si, Al-Cu and pure Al in a furnace for smelting, and after complete melting, add master alloys Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 20 minutes. The master alloys Al-Er, Al-Ba, and Al-Y were added at 700 °C. When all components were completely melted, aluminum was obtained. liquid;

步骤三、于700℃条件下,向所述铝液中通入氩气,得精炼铝液,氩气的流速为5L/min,通入时间为8min,且所述氩气的通气管口位于所述铝液的底部;Step 3. Under the condition of 700 ℃, pass argon gas into the aluminum liquid to obtain the refined aluminum liquid, the flow rate of the argon gas is 5L/min, the feeding time is 8min, and the vent pipe port of the argon gas is located at the bottom of the molten aluminum;

步骤四、当所述精炼铝液的温度为690℃时,将所述精炼铝液浇铸至温度为170℃的模具中,得试棒,铸造周期为55s;Step 4. When the temperature of the refined aluminum liquid is 690°C, the refined aluminum liquid is cast into a mold with a temperature of 170°C to obtain a test rod, and the casting cycle is 55s;

步骤五、将所述试棒于150℃条件下进行时效热处理3h,得可免热处理高性能结构件铸造铝合金。Step 5. The test bar is subjected to an aging heat treatment at 150° C. for 3 hours, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

实施例4Example 4

本发明实施例1提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:6.0%、Mg:0.05%、Cu:0.85%、Cr:0.6%、Er:0.08%、Mn:0.45%、Zn:0.1%、V:0.14%、Ni:0.08%、Ba:0.02%、Y:0.04%,余量为Al。Embodiment 1 of the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 6.0%, Mg: 0.05%, Cu: 0.85%, Cr: 0.6%, Er: 0.08%, Mn: 0.45%, Zn: 0.1%, V: 0.14%, Ni: 0.08%, Ba: 0.02%, Y: 0.04%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行打磨、抛光以除去表面的氧化皮,之后进行清洗、烘干,然后按照上述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is polished and polished to remove the oxide scale on the surface, then cleaned and dried, and then each component is weighed according to the above-mentioned raw material ratio;

步骤二、在745℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置12min,于715℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后,得铝液;Step 2: Under the condition of 745°C, first place the master alloy Al-Si, Al-Cu and pure Al in a furnace for smelting, and after complete melting, add the master alloy Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 12 minutes. The master alloys Al-Er, Al-Ba, and Al-Y were added at 715 °C. When all components were completely melted, aluminum was obtained. liquid;

步骤三、于715℃条件下,向所述铝液中通入氩气,得精炼铝液,氩气的流速为4.5L/min,通入时间为12min,且所述氩气的通气管口位于所述铝液的底部;Step 3. Under the condition of 715°C, argon gas is introduced into the aluminum liquid to obtain the refined aluminum liquid. The flow rate of the argon gas is 4.5L/min, the introduction time is 12min, and the argon gas vent pipe mouth at the bottom of the molten aluminum;

步骤四、当所述精炼铝液的温度为680℃时,将所述精炼铝液浇铸至温度为160℃的模具中,得试棒,铸造周期为40s;Step 4. When the temperature of the refined aluminum liquid is 680°C, the refined aluminum liquid is cast into a mold with a temperature of 160°C to obtain a test rod, and the casting cycle is 40s;

步骤五、将所述试棒于230℃条件下进行时效热处理1h,得可免热处理高性能结构件铸造铝合金。Step 5. The test bar is subjected to an aging heat treatment at 230° C. for 1 hour, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

实施例5Example 5

本发明实施例1提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:6.5%、Mg:0.1%、Cu:0.8%、Cr:0.4%、Er:0.08%、Mn:0.5%、Zn:3%、V:0.08%、Ni:0.08%、Ba:0.04%、Y:0.04%,余量为Al。Embodiment 1 of the present invention provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 6.5%, Mg: 0.1%, Cu: 0.8%, Cr: 0.4%, Er: 0.08%, Mn: 0.5%, Zn: 3%, V: 0.08%, Ni: 0.08%, Ba: 0.04%, Y: 0.04%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备方法,包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行打磨、抛光以除去表面的氧化皮,之后进行清洗、烘干,然后按照上述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is polished and polished to remove the oxide scale on the surface, then cleaned and dried, and then each component is weighed according to the above-mentioned raw material ratio;

步骤二、在735℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置16min,于720℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后,得铝液;Step 2: Under the condition of 735°C, first place the master alloy Al-Si, Al-Cu and pure Al in a furnace for smelting, and after complete melting, add the master alloy Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg were completely melted, and then allowed to stand for 16 minutes. The master alloys Al-Er, Al-Ba, and Al-Y were added at 720 °C. When all components were completely melted, aluminum was obtained. liquid;

步骤三、于720℃条件下,向所述铝液中通入氩气,得精炼铝液,氩气的流速为3.5L/min,通入时间为11min,且所述氩气的通气管口位于所述铝液的底部;Step 3. Under the condition of 720°C, argon gas is introduced into the molten aluminum to obtain the molten aluminum. The flow rate of the argon gas is 3.5L/min, the introduction time is 11min, and the vent pipe of the argon gas is at the bottom of the molten aluminum;

步骤四、当所述精炼铝液的温度为660℃时,将所述精炼铝液浇铸至温度为140℃的模具中,得试棒,铸造周期为45s;Step 4. When the temperature of the refined aluminum liquid is 660°C, the refined aluminum liquid is cast into a mold with a temperature of 140°C to obtain a test rod, and the casting cycle is 45s;

步骤五、将所述试棒于210℃条件下进行时效热处理2h,得可免热处理高性能结构件铸造铝合金。Step 5. The test rod is subjected to an aging heat treatment at 210° C. for 2 hours, so that the high-performance structural parts can be cast aluminum alloy without heat treatment.

为了更好的说明本发明的技术方案,下面还通过对比例和本发明的实施例做进一步的对比。In order to better illustrate the technical solutions of the present invention, further comparisons are made below with the examples of the present invention through comparative examples.

对比例1Comparative Example 1

本对比例提供一种可免热处理高性能结构件铸造铝合金,包括如下质量百分比的各组分:Si:7.0%、Mg:0.4%、Cu:0.70%、Cr:0.02%、Er:0.08%、Mn:0.8%、Zn:2.0%、V:0.04%、Ni:0.1%、Ba:0.06%、Y:0.02%,余量为Al。This comparative example provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, including the following components by mass percentage: Si: 7.0%, Mg: 0.4%, Cu: 0.70%, Cr: 0.02%, Er: 0.08% , Mn: 0.8%, Zn: 2.0%, V: 0.04%, Ni: 0.1%, Ba: 0.06%, Y: 0.02%, and the balance is Al.

上述可免热处理高性能结构件铸造铝合金的制备过程如实施例1所述,不再赘述。The above-mentioned preparation process of the cast aluminum alloy for the heat treatment-free high-performance structural parts is as described in Example 1, and will not be repeated here.

对比例2Comparative Example 2

本对比例提供一种可免热处理高性能结构件铸造铝合金,其原料组分与实施例1一致不再赘述。This comparative example provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment.

上述可免热处理高性能结构件铸造铝合金的制备方法包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

将步骤四中所述精炼铝液的温度替换为720℃,其余制备工艺步骤与实施例1一致,不再赘述。The temperature of the molten aluminum refining described in step 4 was replaced with 720° C., and the remaining preparation process steps were the same as those in Example 1, and will not be repeated here.

对比例3Comparative Example 3

本对比例提供一种可免热处理高性能结构件铸造铝合金,其原料组分与实施例1一致不再赘述。This comparative example provides a cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment.

上述可免热处理高性能结构件铸造铝合金的制备方法包括以下步骤:The above-mentioned preparation method of cast aluminum alloy for heat-free high-performance structural parts comprises the following steps:

将步骤五中模具的温度替换为200℃,其余制备工艺步骤与实施例1一致,不再赘述。The temperature of the mold in step 5 was replaced with 200° C., and the rest of the preparation process steps were the same as those in Example 1, and will not be repeated here.

为了更好的说明本发明实施例提供的可免热处理高性能结构件铸造铝合金的特性,下面将实施例1以及对比例1制备的铝合金材料进行分析。In order to better illustrate the characteristics of the cast aluminum alloy for heat-treatment-free high-performance structural parts provided by the embodiments of the present invention, the aluminum alloy materials prepared in Example 1 and Comparative Example 1 are analyzed below.

试验例1微观结构Test Example 1 Microstructure

实施例1制备的铝合金材料的微观组织如图1所示,然后进行局部放大如图2所示。The microstructure of the aluminum alloy material prepared in Example 1 is shown in FIG. 1 , and then partially enlarged as shown in FIG. 2 .

对比例1制备的铝合金材料的微观组织如图3所示,然后进行局部放大如图4所示。The microstructure of the aluminum alloy material prepared in Comparative Example 1 is shown in FIG. 3 , and then partially enlarged as shown in FIG. 4 .

从图1和图3中可以看出,实施例1制备的铝合金材料二次枝晶间距比对比例1的小,且晶粒整体尺寸也较小;从图2和图4中能更加明显的看出,实施例1制备的铝合金材料的枝晶间颗粒尺寸较小且分布较均匀,能够促进合金强韧性的增加,而对比例1制备的铝合金材料中生成的相整体尺寸较大,且大部分呈针状,会导致合金在受力过程中产生应力集中,从而大大降低合金的性能。It can be seen from Figures 1 and 3 that the secondary dendrite spacing of the aluminum alloy material prepared in Example 1 is smaller than that of Comparative Example 1, and the overall size of the grains is also smaller; it can be more obvious from Figures 2 and 4 It can be seen that the interdendritic particle size of the aluminum alloy material prepared in Example 1 is smaller and the distribution is more uniform, which can promote the increase of the strength and toughness of the alloy, while the overall size of the phase generated in the aluminum alloy material prepared in Comparative Example 1 is larger. , and most of them are needle-shaped, which will cause stress concentration in the alloy during the stress process, thereby greatly reducing the performance of the alloy.

试验例2能谱分析Test Example 2 Energy Spectrum Analysis

将图2中标记的位置1、2、3、4、5分别进行能谱分析,结果如下表1~5所示,从表1~5中可以看出,枝晶间存在Al2Cu、Al-Si-Cu-Mg、Mg2Si强化相,且图2中的标记1和标记3还证明了因本申请中各合金元素的联合作用,能显著改善含Fe相形貌。The positions 1, 2, 3, 4, and 5 marked in Figure 2 were analyzed by energy spectrum, and the results were shown in Tables 1 to 5 below. It can be seen from Tables 1 to 5 that there are Al 2 Cu and Al between dendrites. -Si-Cu-Mg, Mg 2 Si strengthening phase, and the marks 1 and 3 in Figure 2 also prove that the morphology of the Fe-containing phase can be significantly improved due to the combined action of the alloying elements in the present application.

表1Table 1

Figure BDA0003733679820000111
Figure BDA0003733679820000111

表2Table 2

Figure BDA0003733679820000112
Figure BDA0003733679820000112

表3table 3

Figure BDA0003733679820000113
Figure BDA0003733679820000113

Figure BDA0003733679820000121
Figure BDA0003733679820000121

表4Table 4

Figure BDA0003733679820000122
Figure BDA0003733679820000122

表5table 5

Figure BDA0003733679820000123
Figure BDA0003733679820000123

试验例3力学性能Test Example 3 Mechanical Properties

将实施例1~5以及对比例1~3制备的可免热处理高性能结构件铸造铝合金进行室温拉伸力学性能测试,测试结果如表6所示。The room temperature tensile mechanical properties of the cast aluminum alloys prepared in Examples 1 to 5 and Comparative Examples 1 to 3 for high-performance structural parts that can be exempted from heat treatment were tested, and the test results are shown in Table 6.

表6测试结果Table 6 Test results

Figure BDA0003733679820000124
Figure BDA0003733679820000124

Figure BDA0003733679820000131
Figure BDA0003733679820000131

从表6中可以看出,本发明实施例提供的可免热处理高性能结构件铸造铝合金,在免固溶热处理的情况下,还具有优异的力学性能,满足使用要求。It can be seen from Table 6 that the cast aluminum alloy for high-performance structural parts that can be free from heat treatment provided by the embodiment of the present invention also has excellent mechanical properties without solid solution heat treatment, and meets the requirements for use.

以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换或改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements or improvements made within the spirit and principles of the present invention shall be included in the protection of the present invention. within the range.

Claims (9)

1.一种可免热处理高性能结构件铸造铝合金,其特征在于:包括如下质量百分比的各组分:Si:6.0%~8.5%、Mg:0.05%~0.40%、Cu:0.50%~0.85%、Cr:0.20%~0.60%、Er:0.01%~0.10%、Mn:0.45%~0.75%、Zn:0.1%~3.0%、V:0.04%~0.14%、Ni:0.01%~0.1%、Ba≤0.1%、Y≤0.1%、Fe≤0.16%,其他杂质元素含量总和≤0.25%,余量为Al。1. A cast aluminum alloy for high-performance structural parts that can be exempted from heat treatment, characterized in that: each component comprises the following mass percentages: Si: 6.0% to 8.5%, Mg: 0.05% to 0.40%, Cu: 0.50% to 0.85% %, Cr: 0.20% to 0.60%, Er: 0.01% to 0.10%, Mn: 0.45% to 0.75%, Zn: 0.1% to 3.0%, V: 0.04% to 0.14%, Ni: 0.01% to 0.1%, Ba≤0.1%, Y≤0.1%, Fe≤0.16%, the total content of other impurity elements is ≤0.25%, and the balance is Al. 2.一种可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:包括以下步骤:2. a preparation method of cast aluminum alloy for heat-free high-performance structural parts is characterized in that: comprise the following steps: 步骤一、将中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg分别进行预处理,然后按照如权利要求1所述的原料配比称取各组分;Step 1. Combine the master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al-Y and pure Al and pure Al Mg is pretreated respectively, then each component is weighed according to the raw material proportioning as claimed in claim 1; 步骤二、将预处理后的所述中间合金Al-Si、Al-Cu、Al-Cr、Al-Er、Al-Mn、Al-Zn、Al-V、Al-Ni、Al-Ba、Al-Y以及纯Al和纯Mg完全熔化,得铝液;Step 2: The pretreated master alloys Al-Si, Al-Cu, Al-Cr, Al-Er, Al-Mn, Al-Zn, Al-V, Al-Ni, Al-Ba, Al- Y, pure Al and pure Mg are completely melted to obtain molten aluminum; 步骤三、于700℃~720℃条件下,向所述铝液中通入氩气,得精炼铝液;Step 3, under the condition of 700℃~720℃, pass argon gas into the molten aluminum to obtain the molten aluminum; 步骤四、当所述精炼铝液的温度为650℃~690℃时,将所述精炼铝液浇铸至温度为130℃~170℃的模具中,得试棒;Step 4. When the temperature of the refined aluminum liquid is 650°C to 690°C, the refined aluminum liquid is cast into a mold with a temperature of 130°C to 170°C to obtain a test bar; 步骤五、将所述试棒进行时效热处理,得可免热处理高性能结构件铸造铝合金。Step 5, subjecting the test bar to aging heat treatment, so that the high-performance structural parts can be cast aluminum alloy without heat treatment. 3.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述时效热处理的条件为:温度为150℃~230℃,时间为1h~3h。3 . The method for preparing a heat-treated high-performance cast aluminum alloy for high-performance structural parts as claimed in claim 2 , wherein the conditions of the aging heat treatment are as follows: the temperature is 150° C. to 230° C. and the time is 1 hour to 3 hours. 4 . 4.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述氩气的流速为3-5L/min。4 . The method for preparing a cast aluminum alloy for heat-free high-performance structural parts according to claim 2 , wherein the flow rate of the argon gas is 3-5 L/min. 5 . 5.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述氩气的通入时间为8min~12min。5 . The method for preparing cast aluminum alloy for heat-treated high-performance structural parts as claimed in claim 2 , wherein the argon gas is introduced for a time of 8 min to 12 min. 6 . 6.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述氩气的通气管口位于所述铝液的底部。6 . The method for preparing cast aluminum alloy for heat-free high-performance structural parts according to claim 2 , wherein the argon gas vent pipe is located at the bottom of the molten aluminum. 7 . 7.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:步骤二中,在730℃~755℃条件下,先将所述中间合金Al-Si、Al-Cu和纯Al置于熔炉中进行熔炼,完全熔化后加入中间合金Al-Cr、Al-Mn、Al-Zn、Al-V、Al-Ni和纯Mg,完全熔化后,静置10min~20min,于700℃~720℃条件下加入中间合金Al-Er、Al-Ba、Al-Y,当所有组分均完全熔化后得铝液。7 . The method for preparing a cast aluminum alloy for a heat-treated high-performance structural part as claimed in claim 2 , wherein in the second step, under the condition of 730° C. to 755° C., the intermediate alloy Al-Si, Al-Cu and pure Al are placed in a furnace for smelting. After complete melting, the intermediate alloys Al-Cr, Al-Mn, Al-Zn, Al-V, Al-Ni and pure Mg are added. After complete melting, let stand for 10 min~ 20min, add the master alloy Al-Er, Al-Ba, Al-Y at 700 ℃~720 ℃, when all the components are completely melted, the aluminum liquid is obtained. 8.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述浇铸的铸造周期为35s~55s。8 . The method for preparing an aluminum alloy cast for a heat-treatment-free high-performance structural part according to claim 2 , wherein the casting cycle of the casting is 35s˜55s. 9 . 9.如权利要求2所述的可免热处理高性能结构件铸造铝合金的制备方法,其特征在于:所述预处理的过程为:将所述中间合金、纯Al、纯Mg和纯Zn分别进行打磨、抛光、清洗和烘干。9 . The method for preparing a cast aluminum alloy for a heat-treated high-performance structural part as claimed in claim 2 , wherein the process of the pretreatment is: separate the master alloy, pure Al, pure Mg and pure Zn respectively. 10 . Sand, polish, wash and dry.
CN202210800086.0A 2022-07-06 2022-07-06 High-performance structural member casting aluminum alloy capable of avoiding heat treatment and preparation method thereof Active CN115125420B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210800086.0A CN115125420B (en) 2022-07-06 2022-07-06 High-performance structural member casting aluminum alloy capable of avoiding heat treatment and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210800086.0A CN115125420B (en) 2022-07-06 2022-07-06 High-performance structural member casting aluminum alloy capable of avoiding heat treatment and preparation method thereof

Publications (2)

Publication Number Publication Date
CN115125420A true CN115125420A (en) 2022-09-30
CN115125420B CN115125420B (en) 2023-05-12

Family

ID=83381041

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210800086.0A Active CN115125420B (en) 2022-07-06 2022-07-06 High-performance structural member casting aluminum alloy capable of avoiding heat treatment and preparation method thereof

Country Status (1)

Country Link
CN (1) CN115125420B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115679162A (en) * 2022-11-18 2023-02-03 江西万泰铝业有限公司 A new energy vehicle heat-free aluminum alloy material and low-carbon preparation method
CN115852212A (en) * 2022-11-30 2023-03-28 浙江万安科技股份有限公司 Aluminum alloy material for integral low-pressure casting hollow auxiliary frame and preparation method
CN116179903A (en) * 2023-02-07 2023-05-30 帅翼驰新材料集团有限公司 Low-carbon heat-free high-pressure cast aluminum alloy
CN116200635A (en) * 2023-02-07 2023-06-02 帅翼驰新材料集团有限公司 Manufacturing method of low-carbon heat-treatment-free high-pressure casting aluminum alloy
CN116287891A (en) * 2023-05-25 2023-06-23 小米汽车科技有限公司 Heat-treatment-free die-casting aluminum alloy and preparation method and application thereof
CN118563177A (en) * 2024-03-26 2024-08-30 肇庆市大正铝业有限公司 A kind of AlSiNi high-strength aluminum alloy without heat treatment and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102312135A (en) * 2010-06-30 2012-01-11 通用汽车环球科技运作有限责任公司 Improved y alloy y
US20140376352A1 (en) * 2013-06-24 2014-12-25 Seagate Technology Llc Materials for near field transducers, near field tranducers containing same, and methods of forming
CN111197132A (en) * 2020-01-09 2020-05-26 张煜琰 Non-heat treatment type high-strength die-casting aluminum alloy and preparation method thereof
CN113930645A (en) * 2021-09-29 2022-01-14 玉林师范学院 Aluminum alloy/aluminum alloy-ceramic combined brake disc for vehicle and preparation method thereof
CN114411020A (en) * 2022-01-13 2022-04-29 上海交通大学 Non-heat treatment reinforced high-strength high-toughness die-casting aluminum-silicon alloy and preparation method thereof
CN114438378A (en) * 2022-01-14 2022-05-06 大连理工大学宁波研究院 A kind of new energy vehicle integrated forming aluminum-silicon alloy and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102312135A (en) * 2010-06-30 2012-01-11 通用汽车环球科技运作有限责任公司 Improved y alloy y
US20140376352A1 (en) * 2013-06-24 2014-12-25 Seagate Technology Llc Materials for near field transducers, near field tranducers containing same, and methods of forming
CN111197132A (en) * 2020-01-09 2020-05-26 张煜琰 Non-heat treatment type high-strength die-casting aluminum alloy and preparation method thereof
CN113930645A (en) * 2021-09-29 2022-01-14 玉林师范学院 Aluminum alloy/aluminum alloy-ceramic combined brake disc for vehicle and preparation method thereof
CN114411020A (en) * 2022-01-13 2022-04-29 上海交通大学 Non-heat treatment reinforced high-strength high-toughness die-casting aluminum-silicon alloy and preparation method thereof
CN114438378A (en) * 2022-01-14 2022-05-06 大连理工大学宁波研究院 A kind of new energy vehicle integrated forming aluminum-silicon alloy and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115679162A (en) * 2022-11-18 2023-02-03 江西万泰铝业有限公司 A new energy vehicle heat-free aluminum alloy material and low-carbon preparation method
CN115852212A (en) * 2022-11-30 2023-03-28 浙江万安科技股份有限公司 Aluminum alloy material for integral low-pressure casting hollow auxiliary frame and preparation method
CN115852212B (en) * 2022-11-30 2024-06-11 浙江万安科技股份有限公司 Aluminum alloy material for integral low-pressure casting hollow auxiliary frame and preparation method thereof
CN116179903A (en) * 2023-02-07 2023-05-30 帅翼驰新材料集团有限公司 Low-carbon heat-free high-pressure cast aluminum alloy
CN116200635A (en) * 2023-02-07 2023-06-02 帅翼驰新材料集团有限公司 Manufacturing method of low-carbon heat-treatment-free high-pressure casting aluminum alloy
CN116287891A (en) * 2023-05-25 2023-06-23 小米汽车科技有限公司 Heat-treatment-free die-casting aluminum alloy and preparation method and application thereof
CN116287891B (en) * 2023-05-25 2023-08-08 小米汽车科技有限公司 Heat-treatment-free die-casting aluminum alloy and preparation method and application thereof
CN118563177A (en) * 2024-03-26 2024-08-30 肇庆市大正铝业有限公司 A kind of AlSiNi high-strength aluminum alloy without heat treatment and preparation method thereof
CN118563177B (en) * 2024-03-26 2024-12-31 肇庆市大正铝业有限公司 A kind of AlSiNi high-strength aluminum alloy without heat treatment and preparation method thereof

Also Published As

Publication number Publication date
CN115125420B (en) 2023-05-12

Similar Documents

Publication Publication Date Title
CN115125420B (en) High-performance structural member casting aluminum alloy capable of avoiding heat treatment and preparation method thereof
CN111411247B (en) Composite treatment method for regenerated wrought aluminum alloy melt
CN109439976B (en) A compound modification method of cast aluminum-silicon alloy
CN108396204B (en) Hypoeutectic aluminum-silicon alloy casting and process method for improving performance thereof
CN108193096B (en) A kind of high-strength and high-toughness hypoeutectic aluminum-silicon casting alloy and preparation method thereof
CN104561702B (en) A kind of Al-Zn-Mg-Cu alloy with trace addition of Er and Zr and its preparation process
CN106521378B (en) A kind of alsimay die casting efficient energy-saving heat treatment method
CN111690844B (en) Eutectic Al-Fe-Mn-Si-Mg die casting alloy and preparation method and application thereof
CN108517446A (en) A kind of preparation method of high toughness Al-alloy for evacuated die-casting process and products thereof
CN112941377B (en) Er-containing cast heat-resistant Al-Si-Cu-Mg alloy
CN108118225A (en) A kind of low cost high-voltage contracting strength and deformation magnesium alloy and preparation method thereof
CN108588513A (en) A kind of modified A356 aluminium alloys and its multiple ageing hot processing method
CN113862531A (en) Aluminum alloy and preparation method thereof
CN116574944A (en) A kind of heat-free aluminum alloy for new energy automobile battery pack and preparation method thereof
CN111945040B (en) A kind of Al-Si-Cu-Mg-Zr aluminum alloy and its short flow heat treatment process
CN114855036B (en) High-strength high-thermal-conductivity cast aluminum alloy, preparation method thereof and aluminum alloy product
CN107699747A (en) A kind of high Cu contents Al Si Li Cu casting alloys and preparation method thereof
CN117821813B (en) Aluminum alloy material for auxiliary frame of automobile and preparation method
CN117845105B (en) A high-strength and tough cast aluminum alloy and its preparation method and application
CN115323225B (en) Corrosion-resistant high-toughness cast aluminum-silicon alloy and preparation method thereof
CN114752822B (en) Die-casting aluminum alloy and preparation method thereof
CN106011507A (en) Al-Mg-Si-Y rare earth aluminum alloy and preparation method thereof
CN111705248A (en) A kind of Al-4.5Cu aluminum copper alloy material and preparation method thereof
CN111996419A (en) Iron-containing hypoeutectic aluminum-silicon alloy and preparation method thereof
CN116657005B (en) A kind of recycled aluminum alloy material and its preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A high-performance structural component cast aluminum alloy without heat treatment and its preparation method

Granted publication date: 20230512

Pledgee: Bank of Communications Ltd Baoding branch

Pledgor: BAODING LIZHONG WHEEL MANUFACTURING Co.,Ltd.

Registration number: Y2024980057302

PE01 Entry into force of the registration of the contract for pledge of patent right