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CN115077699A - High-resolution spectrometer - Google Patents

High-resolution spectrometer Download PDF

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CN115077699A
CN115077699A CN202210662529.4A CN202210662529A CN115077699A CN 115077699 A CN115077699 A CN 115077699A CN 202210662529 A CN202210662529 A CN 202210662529A CN 115077699 A CN115077699 A CN 115077699A
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胡九龙
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Shenzhen Ocder Light Control Technology Co ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J3/00Spectrometry; Spectrophotometry; Monochromators; Measuring colours
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
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    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/21Polarisation-affecting properties

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Abstract

The invention relates to a high-resolution spectrometer, which comprises a slit, a collimating objective lens, a light splitting element, an imaging objective lens and an area array detector which are sequentially arranged on a light path, wherein the array direction of the pixel array surface of the area array detector and the direction of the image of the slit on the focal plane of the imaging objective lens form a preset included angle, so that a plurality of pixels in the pixel array surface of the area array detector, which are nearly parallel to the direction of the image, in the array direction in a single row/line mode can respectively detect spectral lines with different wavelengths, and the defect that the spectral lines between adjacent single row/line pixels cannot be detected due to the fact that the spectral lines in the array direction in the pixel array surface of the area array detector, which are parallel to the direction of the image, in the existing spectrometer are effectively avoided; therefore, the resolution of the spectrograph is improved under the condition of not changing the resolution of the area array detector.

Description

一种高分辨率光谱仪A high-resolution spectrometer

技术领域technical field

本发明涉及光谱分析仪器技术领域,特别涉及一种高分辨率光谱仪。The invention relates to the technical field of spectral analysis instruments, in particular to a high-resolution spectrometer.

背景技术Background technique

光谱仪包括依次设置在光路上的狭缝、准直物镜、分光元件、成像物镜和探测器,从狭缝出射的光经过准直物镜后形成平行光,平行光经过分光元件分光,分光后的光束经过成像物镜成像到探测器的像素阵列面上。光谱仪成像的光谱长度是固定的,光谱仪的分辨率取决于探测器的分辨率,目前要提高光谱仪的分辨率即采用高分辨率的探测器,但高分辨率的探测器成本高,直接导致高分辨率的光谱仪价格高。The spectrometer includes a slit, a collimating objective lens, a spectroscopic element, an imaging objective lens and a detector arranged in sequence on the optical path. The light emitted from the slit passes through the collimating objective lens to form parallel light, and the parallel light is split by the spectroscopic element. It is imaged onto the pixel array surface of the detector through the imaging objective lens. The spectral length of the spectrometer imaging is fixed, and the resolution of the spectrometer depends on the resolution of the detector. At present, to improve the resolution of the spectrometer, a high-resolution detector is used, but the high-resolution detector costs high, which directly leads to high Spectrometers with high resolution are expensive.

发明内容SUMMARY OF THE INVENTION

本发明目的是提供一种高分辨率光谱仪,解决现有技术中存在的上述问题。The purpose of the present invention is to provide a high-resolution spectrometer to solve the above problems existing in the prior art.

本发明解决上述技术问题的技术方案如下:The technical scheme that the present invention solves the above-mentioned technical problems is as follows:

一种高分辨率光谱仪,其特征在于,包括依次设置在光路上的狭缝、准直物镜、分光元件、成像物镜和面阵探测器,从所述狭缝出射的光经过所述准直物镜后形成平行光,平行光经过所述分光元件分光,分光后的光束经过所述成像物镜成像到所述面阵探测器的像素阵列面上,所述像素阵列面设置在所述成像物镜的焦平面,且所述像素阵列面的阵列方向与所述狭缝在所述成像物镜的焦平面的像的方向成预设夹角。A high-resolution spectrometer, characterized in that it includes a slit, a collimating objective lens, a spectroscopic element, an imaging objective lens and an area array detector sequentially arranged on an optical path, and light emitted from the slit passes through the collimating objective lens Then, parallel light is formed, the parallel light is split by the spectroscopic element, and the split light beam is imaged on the pixel array surface of the area array detector through the imaging objective lens, and the pixel array surface is set at the focal point of the imaging objective lens. A plane, and the array direction of the pixel array plane and the direction of the image of the slit on the focal plane of the imaging objective lens form a preset angle.

本发明的有益效果是:像素阵列面的阵列方向与狭缝在成像物镜的焦平面的像的方向成预设夹角,使面阵探测器的像素阵列面中与像的方向接近平行的阵列方向单列/行的多个像素分别探测不同波长的谱线,有效避免现有光谱仪中面阵探测器的像素阵面中与像的方向平行的阵列方向单列/行多个像素仅探测一个波长的谱线,位于相邻单列/行像素之间的谱线不能被探测的弊端;从而实现在不改变面阵探测器分辨率的情况下,提高光谱仪的分辨率。The beneficial effects of the present invention are: the array direction of the pixel array surface and the image direction of the slit on the focal plane of the imaging objective lens form a preset angle, so that the pixel array surface of the area array detector is nearly parallel to the image direction. Multiple pixels in a single column/row in a single direction detect spectral lines of different wavelengths respectively, which effectively avoids the detection of only one wavelength by multiple pixels in a single column/row in an array direction parallel to the direction of the image in the pixel array of the area array detector in the existing spectrometer. Spectral lines, the disadvantage that the spectral lines located between adjacent single-column/row pixels cannot be detected; thus, the resolution of the spectrometer can be improved without changing the resolution of the area array detector.

在上述技术方案的基础上,本发明还可以做如下改进。On the basis of the above technical solutions, the present invention can also be improved as follows.

进一步,所述预设夹角为所述像素阵列面中与所述像的方向接近平行的阵列方向与所述像的方向的夹角,所述预设夹角小于arctan(a/((n-1)*b));Further, the preset angle is the angle between the pixel array plane and the direction of the image that is nearly parallel to the direction of the image and the direction of the image, and the preset angle is smaller than arctan(a/((n -1)*b));

其中,所述a为所述像素阵列面中与所述像的方向接近垂直的阵列方向相邻像素之间的间隔,所述b为所述像素阵列面中与所述像的方向接近平行的阵列方向相邻像素之间的间隔,所述n为所述像素阵列面中与所述像的方向接近平行的阵列方向像素的个数。Wherein, the a is the interval between adjacent pixels in the array direction that is nearly perpendicular to the image direction in the pixel array plane, and the b is the pixel array plane that is nearly parallel to the image direction. The interval between adjacent pixels in the array direction, where n is the number of pixels in the array direction that are nearly parallel to the image direction in the pixel array plane.

进一步,所述预设夹角为arctan(a/(n*b))。Further, the preset included angle is arctan(a/(n*b)).

进一步,所述分光元件为棱镜和/或光栅。Further, the light splitting element is a prism and/or a grating.

本发明的另一技术方案如下:Another technical scheme of the present invention is as follows:

一种膜厚仪,包括上述高分辨率光谱仪。A film thickness meter, comprising the above-mentioned high-resolution spectrometer.

本发明的另一技术方案如下:Another technical scheme of the present invention is as follows:

一种镀膜机,包括上述膜厚仪。A coating machine includes the above-mentioned film thickness gauge.

本发明的另一技术方案如下:Another technical scheme of the present invention is as follows:

一种椭偏仪,包括上述高分辨率光谱仪。An ellipsometer, comprising the above-mentioned high-resolution spectrometer.

本发明的另一技术方案如下:Another technical scheme of the present invention is as follows:

一种镀膜机,包括上述椭偏仪。A coating machine, comprising the above-mentioned ellipsometer.

附图说明Description of drawings

图1为本发明一种高分辨率光谱仪中像素阵列面与狭缝在成像物镜的焦平面的像的相对位置关系示意图。1 is a schematic diagram of the relative positional relationship between the pixel array surface and the image of the slit on the focal plane of the imaging objective lens in a high-resolution spectrometer of the present invention.

具体实施方式Detailed ways

以下结合附图对本发明的原理和特征进行描述,所举实例只用于解释本发明,并非用于限定本发明的范围。The principles and features of the present invention will be described below with reference to the accompanying drawings. The examples are only used to explain the present invention, but not to limit the scope of the present invention.

本发明实施例1一种高分辨率光谱仪,包括依次设置在光路上的狭缝、准直物镜、分光元件、成像物镜和面阵探测器,从狭缝出射的光经过准直物镜后形成平行光,平行光经过分光元件分光,分光后的光束经过成像物镜成像到面阵探测器的像素阵列面1上,像素阵列面1设置在成像物镜的焦平面,且像素阵列面1的阵列方向与狭缝在成像物镜的焦平面的像2的方向成预设夹角,如图1所示。Embodiment 1 of the present invention is a high-resolution spectrometer, comprising a slit, a collimating objective lens, a spectroscopic element, an imaging objective lens, and an area array detector sequentially arranged on an optical path, and the light emitted from the slit passes through the collimating objective lens to form a parallel Light, parallel light is split by the spectroscopic element, and the split beam is imaged on the pixel array surface 1 of the area array detector through the imaging objective lens. The pixel array surface 1 is set on the focal plane of the imaging objective lens, and the array direction of the pixel array surface 1 is the same as The slit forms a preset angle in the direction of the image 2 of the focal plane of the imaging objective, as shown in FIG. 1 .

像素阵列面1的阵列方向包括纵向方向单列像素的延伸方向,如图1所示的BA方向,和横向方向单行像素的延伸方向,如图1所示的AC方向,两个方向相互垂直,选取其中一个方向即可表征像素阵列面1的阵列方向,需要说明的是,其中纵向方向和横向方向是分别相对于竖直线和水平线更接近而言。狭缝在成像物镜的焦平面的像2的方向采用狭缝的像2中狭缝的延伸方向表征,如图1所示的DC方向。由于狭缝在成像物镜的焦平面的像2为一系列相互平行的像2,每个像2对应一个特定的波长,且波长连续,即像2为波长连续的光谱;像素阵列面1的阵列方向与狭缝在成像物镜的焦平面的像2的方向成预设夹角,使面阵探测器的像素阵列面1中与像2的方向接近平行的阵列方向单列/行的多个像素分别探测不同波长的谱线,如图1所示,像素阵列面1中与像的方向接近平行的阵列方向为纵向方向单列像素的延伸方向,单列多个像素分别探测不同的波长的谱线;有效避免现有光谱仪中面阵探测器的像素阵面中与像的方向平行的阵列方向单列/行多个像素仅探测一个波长的谱线,位于相邻单列/行像素之间的谱线不能被探测的弊端;从而实现在不改变面阵探测器分辨率的情况下,提高光谱仪的分辨率。The array direction of the pixel array surface 1 includes the extension direction of a single column of pixels in the longitudinal direction, such as the BA direction shown in Figure 1, and the extension direction of a single row of pixels in the lateral direction, such as the AC direction shown in Figure 1. The two directions are perpendicular to each other. One of the directions can represent the array direction of the pixel array surface 1. It should be noted that the longitudinal direction and the lateral direction are respectively closer to the vertical line and the horizontal line. The direction of the image 2 of the slit in the focal plane of the imaging objective lens is characterized by the extending direction of the slit in the image 2 of the slit, such as the DC direction shown in FIG. 1 . Because the image 2 of the slit in the focal plane of the imaging objective lens is a series of mutually parallel images 2, each image 2 corresponds to a specific wavelength, and the wavelengths are continuous, that is, the image 2 is a spectrum with continuous wavelengths; the array of the pixel array surface 1 The direction and the direction of the image 2 of the focal plane of the imaging objective lens form a preset angle, so that the pixels in the pixel array plane 1 of the area array detector are nearly parallel to the direction of the image 2 in a single column/row of the array direction, respectively. Detecting spectral lines of different wavelengths, as shown in Figure 1, the array direction in the pixel array surface 1 that is nearly parallel to the direction of the image is the extension direction of a single column of pixels in the longitudinal direction, and multiple pixels in a single column detect spectral lines of different wavelengths respectively; effective; It is avoided that in the pixel array of the area array detector in the existing spectrometer, the array direction parallel to the direction of the image in a single column/row of multiple pixels only detects the spectral line of one wavelength, and the spectral line between adjacent single column/row pixels cannot be detected. Therefore, the resolution of the spectrometer can be improved without changing the resolution of the area array detector.

本发明实施例2一种高分辨率光谱仪,在实施例1的基础上,预设夹角为像素阵列面1中与像2的方向接近平行的阵列方向与像2的方向的夹角,预设夹角小于arctan(a/((n-1)*b));Embodiment 2 of the present invention is a high-resolution spectrometer. On the basis of Embodiment 1, the preset angle is the angle between the array direction in the pixel array plane 1 that is nearly parallel to the direction of the image 2 and the direction of the image 2. Let the included angle be less than arctan(a/((n-1)*b));

其中,a为像素阵列面1中与像2的方向接近垂直的阵列方向相邻像素之间的间隔,如图1所示,像素阵列面1中与像2的方向接近垂直的阵列方向为横向方向单行像素的延伸方向,a为A、C两点之间的间隔;b为像素阵列面1中与像2的方向接近平行的阵列方向相邻像素之间的间隔,如图1所示,像素阵列面1中与像2的方向接近平行的阵列方向为纵向方向单列像素的延伸方向,b为A、E两点之间的间隔。Among them, a is the interval between adjacent pixels in the array direction of the pixel array surface 1 that is nearly perpendicular to the direction of the image 2. As shown in Figure 1, the array direction of the pixel array surface 1 that is nearly perpendicular to the direction of the image 2 is the horizontal direction The extension direction of a single row of pixels in the direction, a is the interval between points A and C; b is the interval between adjacent pixels in the array direction in the pixel array surface 1 that is nearly parallel to the direction of the image 2, as shown in Figure 1, In the pixel array plane 1, the array direction that is nearly parallel to the direction of the image 2 is the extension direction of a single row of pixels in the longitudinal direction, and b is the interval between points A and E.

需要说明的是接近垂直和接近平行均为相对而言,像素阵列面1的阵列方向包括纵向方向单列像素的延伸方向和横向方向单行像素的延伸方向,共两个方向,狭缝在成像物镜的焦平面的像2的方向是确定的,从像素阵列面1的两个阵列方向中选取与像2的方向更接近垂直的阵列方向,即为像素阵列面1中与像2的方向接近垂直的阵列方向,从像素阵列面1的两个阵列方向中选取与像2的方向更接近平行的阵列方向,即为像素阵列面1中与像2的方向接近平行的阵列方向。具体实施中,此预设夹角极小,从像素阵列面1的两个阵列方向中很容易选取与像2的方向更接近平行或更接近垂直的阵列方向。It should be noted that near-vertical and near-parallel are relative terms, and the array direction of the pixel array surface 1 includes the extension direction of a single column of pixels in the longitudinal direction and the extension direction of a single row of pixels in the lateral direction. There are two directions in total. The direction of the image 2 of the focal plane is determined. From the two array directions of the pixel array surface 1, the array direction that is closer to the direction of the image 2 is selected, that is, the direction of the pixel array surface 1 that is close to the perpendicular to the direction of the image 2. For the array direction, from the two array directions of the pixel array surface 1, the array direction that is more parallel to the direction of the image 2 is selected, that is, the array direction that is nearly parallel to the direction of the image 2 in the pixel array surface 1. In a specific implementation, the preset included angle is extremely small, and an array direction that is closer to parallel or closer to the perpendicular direction to the direction of the image 2 can be easily selected from the two array directions of the pixel array surface 1 .

n为像素阵列面(1)中与像的方向接近平行的阵列方向像素的个数,如图1所示即为纵向方向单列像素的个数,n=4。n is the number of pixels in the array direction nearly parallel to the direction of the image in the pixel array surface (1), as shown in FIG.

如图1所示,∠ABC=arctan(a/((n-1)*b)),当预设夹角小于arctan(a/((n-1)*b)),即B点像素探测的谱线位于∠ABC内,A、B、C三点像素探测的谱线按光谱方向依次分布,实现按光谱方向,依次使用像素阵列面第1纵列各个像素,第2纵列各个像素,第3纵列各个像素……第m纵列各个像素,且每列各个像素从上到下依次使用,实现光谱仪的分辨率为面阵探测器的分辨率mXn,且面阵探测器的各个像素的使用有序可循,其中,m为像素阵列面1横向方向单行像素的个数,如图1所示m=4;有效避免现有光谱仪中面阵探测器的像素阵列面中与像的方向平行的阵列方向单列/行多个像素仅探测一个波长的谱线,采用分辨率mXn的面阵探测器的光谱仪的分辨率仅为m或n的弊端。As shown in Figure 1, ∠ABC=arctan(a/((n-1)*b)), when the preset angle is less than arctan(a/(((n-1)*b)), that is, the pixel detection at point B The spectral lines of the pixel array are located within ∠ABC, and the spectral lines detected by the three-point pixels A, B, and C are distributed in sequence according to the spectral direction. Each pixel in the 3rd column ... each pixel in the mth column, and each pixel in each column is used in sequence from top to bottom, so that the resolution of the spectrometer is the resolution m×n of the area array detector, and each pixel of the area array detector is used. It can be used in an orderly manner, where m is the number of pixels in a single row of pixels in the lateral direction of the pixel array surface 1, as shown in Figure 1, m=4; effectively avoiding the interference between the pixel array surface of the existing spectrometer and the image in the area array detector. A single column/row of multiple pixels in a parallel array direction only detects spectral lines of one wavelength, and the resolution of a spectrometer using an area array detector with a resolution of mXn is only m or n.

本发明实施例3一种高分辨率光谱仪,在实施例2的基础上,预设夹角为arctan(a/(n*b))。Embodiment 3 of the present invention is a high-resolution spectrometer. On the basis of Embodiment 2, the preset included angle is arctan(a/(n*b)).

如图1所示,令BD=b,则∠ADC=arctan(a/(n*b)),当预设夹角为arctan(a/(n*b)),即C点像素探测的谱线过D点,又由于BD=b,即BD之间的间隔与纵向方向相邻像素之间的间隔相等,则B、C两点像素探测的谱线之间的光谱间隔与纵向方向相邻像素探测的谱线之间的光谱间隔相等,实现按光谱方向,依次使用的两个像素探测的谱线之间的光谱间隔相等;如图1所示,分辨率4X4的面阵探测器的像素阵列面1中16个像素探测的16个谱线中相邻谱线之间的光谱间隔相等。As shown in Figure 1, let BD=b, then ∠ADC=arctan(a/(n*b)), when the preset angle is arctan(a/(n*b)), that is, the spectrum detected by the C point pixel The line passes through point D, and since BD=b, that is, the interval between BD is equal to the interval between adjacent pixels in the longitudinal direction, the spectral interval between the spectral lines detected by the pixels at points B and C is adjacent to the longitudinal direction. The spectral interval between the spectral lines detected by the pixels is equal, so that the spectral interval between the spectral lines detected by the two pixels used in sequence according to the spectral direction is equal; as shown in Figure 1, the pixels of the area array detector with a resolution of 4X4 Among the 16 spectral lines detected by the 16 pixels in the array surface 1, the spectral intervals between adjacent spectral lines are equal.

本发明实施例4一种高分辨率光谱仪,在实施例1至3任一实施例的基础上,分光元件为棱镜和/或光栅。Embodiment 4 of the present invention is a high-resolution spectrometer. On the basis of any of Embodiments 1 to 3, the spectroscopic element is a prism and/or a grating.

本发明实施例5一种膜厚仪,包括实施例1至4任一实施例中的高分辨率光谱仪。Embodiment 5 of the present invention is a film thickness meter, including the high-resolution spectrometer in any of Embodiments 1 to 4.

本发明实施例6一种镀膜机,包括实施例5中的膜厚仪。Embodiment 6 of the present invention is a coating machine, including the film thickness gauge in Embodiment 5.

本发明实施例7一种椭偏仪,包括实施例1至4任一实施例中的高分辨率光谱仪。Embodiment 7 of the present invention is an ellipsometer, including the high-resolution spectrometer in any of Embodiments 1 to 4.

本发明实施例8一种镀膜机,包括实施例7中的椭偏仪。Embodiment 8 of the present invention is a coating machine, including the ellipsometer in Embodiment 7.

以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the protection of the present invention. within the range.

Claims (8)

1. The utility model provides a high resolution spectrometer, its characterized in that is including setting gradually slit, collimating objective, beam splitting component, formation of image objective and the area array detector on the light path, follows the light of slit outgoing passes through form the parallel light behind the collimating objective, the parallel light passes through beam splitting component beam splitting, light beam process after the beam splitting the formation of image objective is arrived on the pixel array face (1) of area array detector, pixel array face (1) sets up the focal plane of formation of image objective, just the array direction of pixel array face (1) with the slit is in the direction of formation of image (2) of the focal plane of formation of image objective becomes to predetermine the contained angle.
2. The high resolution spectrometer according to claim 1, wherein the predetermined angle is an angle between an array direction of the pixel array plane (1) approximately parallel to the direction of the image (2) and the direction of the image (2), the predetermined angle being smaller than arctan (a/((n-1) × b));
wherein a is an interval between adjacent pixels in an array direction approximately perpendicular to the direction of the image (2) in the pixel array surface (1), b is an interval between adjacent pixels in the array direction approximately parallel to the direction of the image (2) in the pixel array surface (1), and n is the number of pixels in the array direction approximately parallel to the direction of the image (2) in the pixel array surface (1).
3. The high resolution spectrometer according to claim 2, wherein the predetermined angle is arctan (a/(n × b)).
4. The high resolution spectrometer according to any of claims 1 to 3, wherein the beam splitting element is a prism and/or a grating.
5. A film thickness gauge comprising the high resolution spectrometer of any one of claims 1 to 4.
6. A coater comprising the film thickness measuring instrument according to claim 5.
7. An ellipsometer comprising the high resolution spectrometer of any one of claims 1 to 4.
8. A coater comprising the ellipsometer of claim 7.
CN202210662529.4A 2022-06-13 2022-06-13 High-resolution spectrometer Pending CN115077699A (en)

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US5473427A (en) * 1993-10-01 1995-12-05 Unicam Limited Spectrophotometer
WO2004036160A1 (en) * 2002-10-10 2004-04-29 Institut für Physikalische Hochtechnologie e.V. High resolution spectrometer
CN1587928A (en) * 2004-09-09 2005-03-02 中国科学院上海技术物理研究所 Image surface correcting structure for imaging spectrograph
CN103389159A (en) * 2013-07-23 2013-11-13 中国科学院长春光学精密机械与物理研究所 Prism and grating cascading dispersion two-channel and high-resolution spectrum imaging system
CN110736541A (en) * 2019-09-19 2020-01-31 杭州远方光电信息股份有限公司 spectrometers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5473427A (en) * 1993-10-01 1995-12-05 Unicam Limited Spectrophotometer
WO2004036160A1 (en) * 2002-10-10 2004-04-29 Institut für Physikalische Hochtechnologie e.V. High resolution spectrometer
CN1587928A (en) * 2004-09-09 2005-03-02 中国科学院上海技术物理研究所 Image surface correcting structure for imaging spectrograph
CN103389159A (en) * 2013-07-23 2013-11-13 中国科学院长春光学精密机械与物理研究所 Prism and grating cascading dispersion two-channel and high-resolution spectrum imaging system
CN110736541A (en) * 2019-09-19 2020-01-31 杭州远方光电信息股份有限公司 spectrometers

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