CN115028902A - Environment-friendly recyclable tableware with vegetable protein as raw material and preparation method thereof - Google Patents
Environment-friendly recyclable tableware with vegetable protein as raw material and preparation method thereof Download PDFInfo
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Abstract
本发明公开了一种以植物蛋白为原料的环保可回收餐具及其制备方法,属于环保餐具领域。按照原料份量配比:玉米黄粉7~10份,大豆蛋白3~4份,淀粉4~6份,羧甲基纤维素钠1~3份,食用明胶1~2份,加入桑叶提取液和水适量。采用微波功率200~1000W,微波时间1~5min处理后,放入磨具中,加压成型后取出干燥,在餐具表面涂抹5%~10%玉米醇溶蛋白和乙基纤维素防水涂层,将餐具置于紫外线消毒箱内杀菌即可。此餐具不含任何塑料物,由天然物质的提取物或农产品加工副产物的提取物作为主要原料,属良性循环。回收后的产品经粉碎后能为动物提供高含量的蛋白和多糖,更加有利于其作为动物饲料进行利用。The invention discloses an environment-friendly recyclable tableware using vegetable protein as a raw material and a preparation method thereof, belonging to the field of environment-friendly tableware. According to the proportion of raw materials: 7-10 parts of corn yellow powder, 3-4 parts of soybean protein, 4-6 parts of starch, 1-3 parts of sodium carboxymethyl cellulose, 1-2 parts of edible gelatin, add mulberry leaf extract and Appropriate amount of water. The microwave power is 200-1000W, and the microwave time is 1-5min. After treatment, put it in the abrasive tool, press and shape, take it out and dry, and apply 5%-10% zein and ethyl cellulose waterproof coating on the surface of the tableware. Put the tableware in the ultraviolet disinfection box to sterilize. This tableware does not contain any plastics, and uses the extracts of natural substances or the by-products of agricultural product processing as the main raw materials, which is a virtuous circle. The recovered product can provide animals with high content of protein and polysaccharide after being crushed, which is more conducive to its utilization as animal feed.
Description
技术领域technical field
本发明属于环保餐具领域,特别涉及一种以植物蛋白为原料的环保可回收餐具及其制备方法。The invention belongs to the field of environment-friendly tableware, in particular to an environment-friendly recyclable tableware using vegetable protein as a raw material and a preparation method thereof.
背景技术Background technique
随着快餐饮食习惯的普及,一次性餐具应时而生,带来方便快捷的同时也存在严重的生态污染、卫生安全隐患等弊端。一次性餐具的主要材料为聚苯乙烯,回收后难以再利用,通常使用焚烧处理,这将产生大量有害气体,形成大气污染,或直接或间接地对生物造成不可逆的急性、慢性危害。也有使用深埋地下的处理方式,将其难以为微生物降解、危害农作物生长,损害泥土结构、给环境带来极大压力。并且一次性餐具在高温使用的条件下会释放出有毒有害物质,长期使用此类餐具会对人类健康产生不良的影响。因此对身体健康无害的新型环保可降解餐具应运而生。With the popularization of fast food eating habits, disposable tableware has emerged from time to time, which brings convenience and efficiency, but also has serious ecological pollution, hidden dangers of health and safety and other disadvantages. The main material of disposable tableware is polystyrene, which is difficult to reuse after recycling. It is usually treated by incineration, which will generate a large amount of harmful gases, form air pollution, or directly or indirectly cause irreversible acute and chronic harm to organisms. There are also treatment methods that use deep burial, which is difficult to be degraded by microorganisms, harms the growth of crops, damages the soil structure, and brings great pressure to the environment. Moreover, the disposable tableware will release toxic and harmful substances under the condition of high temperature use, and the long-term use of such tableware will have adverse effects on human health. Therefore, a new type of environmentally friendly degradable tableware that is harmless to health came into being.
目前市场上出现的一些环保餐具,包括PE复膜纸板、纸浆模塑、植物秸杆果壳类模压、降解塑料、淀粉生物全降解等餐具材料或产品,都几乎是顾此失彼,不能同时满足安全、卫生、方便、环保等优点。特别是随着环保呼声的日益高涨,具有环保意义餐具产品的研制开发应用可谓是迫在眉捷。因此,急需开发一种新型环保可回收做动物饲料的一次性餐具、食品包装材料,用后可有效回收用作动物的营养饲料,实现资源的最大程度利用。利用玉米黄粉、大豆蛋白、土豆淀粉、桑叶提取物等固有的特性,把它们和其它可食性助剂按一定的比例组合,经搅拌加热加压定型后,涂抹疏水性涂层精制而成,此疏水性涂层利用玉米醇溶蛋白的疏水性质达到隔离的效果,同时在涂层中加入可作为动物饲料添加剂的乙基纤维素,更加提高了疏水涂层的机械性能和阻隔性能。此餐具不含任何塑料物,由天然物质的提取物或农产品加工副产物的提取物作为主要原料,属良性循环。回收后的产品因具有丰富的营养价值,可粉碎后可直接用作各种动物饲料,其社会价值较高,可兼顾环保和健康两大重要问题。At present, some environmentally friendly tableware on the market, including PE laminated paperboard, pulp molding, plant straw husk molding, degradable plastic, starch biodegradable and other tableware materials or products, are almost neglecting the other and cannot meet the requirements of safety, Hygiene, convenience, environmental protection and other advantages. Especially with the increasing voice of environmental protection, the development and application of tableware products with environmental protection significance can be described as urgent. Therefore, there is an urgent need to develop a new type of environmentally friendly disposable tableware and food packaging materials that can be recycled as animal feed. Using the inherent characteristics of corn yellow powder, soybean protein, potato starch, mulberry leaf extract, etc., they are combined with other edible additives in a certain proportion, and after stirring, heating and pressure setting, they are refined by applying a hydrophobic coating. The hydrophobic coating utilizes the hydrophobic properties of zein to achieve the effect of isolation, and at the same time, ethyl cellulose, which can be used as an animal feed additive, is added to the coating to further improve the mechanical properties and barrier properties of the hydrophobic coating. This tableware does not contain any plastics, and uses the extracts of natural substances or the by-products of agricultural product processing as the main raw materials, which is a virtuous circle. Due to its rich nutritional value, the recovered product can be directly used as animal feed after being crushed. It has high social value and can take into account the two important issues of environmental protection and health.
发明内容SUMMARY OF THE INVENTION
本发明的目的是提供了一种以植物蛋白为原料的环保可回收餐具及其制备方法,本发明提供的以植物蛋白为原料的环保餐具,原料主要来源于农产品加工副产物(玉米黄粉和大豆蛋白),其来源广泛,成本较低,对人身体无害,并且其中加入的桑叶提取物具有较高的营养价值,采用的涂层为玉米醇溶蛋白与乙基纤维素的结合,提高了涂层的防水效果,使用过后可回收做动物饲料。此餐具的制作及使用不仅降低了生产成本,在高温下还能防止有毒有害物质的产生,用后可回收作为动物饲料利用,实现绿色循环。The purpose of the present invention is to provide a kind of environmentally friendly recyclable tableware with vegetable protein as raw material and preparation method thereof, the environmental protection tableware with vegetable protein as raw material provided by the present invention, the raw material mainly comes from agricultural product processing by-products (corn yellow powder and soybean meal) protein), which has a wide range of sources, low cost, and is harmless to the human body, and the mulberry leaf extract added has high nutritional value, and the coating used is the combination of zein and ethyl cellulose to improve The waterproof effect of the coating is achieved, and it can be recycled as animal feed after use. The production and use of the tableware not only reduces the production cost, but also prevents the production of toxic and harmful substances under high temperature, and can be recycled as animal feed after use to realize green circulation.
为了实现上述发明目的,本发明一种以植物蛋白为原料的环保可回收餐具,其原料份量配比为:玉米黄粉7~10份,大豆蛋白3~4份,淀粉4~6份,羧甲基纤维素钠1~3份,食用明胶1~2份,加入桑叶提取液和水适量。In order to achieve the above purpose of the invention, the present invention is an environmentally friendly and recyclable tableware using vegetable protein as a raw material. 1-3 parts of sodium cellulose, 1-2 parts of edible gelatin, add mulberry leaf extract and appropriate amount of water.
优选地,所述桑叶提取液为采用水提法提取,其添加量按上述原料质量的 400~850mL/kg添加,其余用水补齐至850mL/kg。Preferably, the mulberry leaf extract is extracted by water extraction, and the addition amount is 400-850 mL/kg of the quality of the above-mentioned raw materials, and the rest is supplemented to 850 mL/kg with water.
上述一种以植物蛋白为原料的环保可回收餐具的制备方法,按照下述步骤进行:(1)先将原料中的玉米黄粉、大豆蛋白粉碎,过120目筛,将其余原料按照上述份量依次放入容器中,搅拌,加入桑叶提取液和水,搅拌均匀。(2)在微波功率200~1000W,微波时间1~5min处理后,放入磨具中,加压成型后取出干燥。(3)在餐具表面涂抹5%~10%(质量百分比计)的玉米醇溶蛋白和乙基纤维素(二者配比为9:1~5:5)防水涂层。(4)将餐具置于紫外线消毒箱内杀菌即可。The above-mentioned preparation method of the environmentally-friendly recyclable tableware with vegetable protein as raw material is carried out according to the following steps: (1) firstly, pulverize the corn yellow powder and soybean protein in the raw material, pass through a 120 mesh sieve, and sequentially order the remaining raw materials according to the above-mentioned weights. Put into a container, stir, add mulberry leaf extract and water, stir well. (2) After the microwave power is 200-1000W and the microwave time is 1-5min, it is put into an abrasive tool, and it is taken out and dried after being pressed and formed. (3) Apply a waterproof coating of 5% to 10% (mass percentage) of zein and ethyl cellulose (the ratio of the two is 9:1 to 5:5) on the surface of the tableware. (4) Put the tableware in the ultraviolet disinfection box to sterilize.
本发明的有益效果:使用原料环保健康,原料成本较低,加工制作方法科学、简单、并且作为饲料回收以后,其丰富的蛋白质,尤其是玉米蛋白与大豆蛋白的配比实现了蛋白质的互补作用,并且添加了一定量的淀粉,使得其中多糖和蛋白的含量均较高,其中多糖含量为42.38%~45.11%,蛋白含量为38.21%~41.80%。添加桑叶提取物后还提供了少量的活性物质黄酮和多酚,更加有利于其作为动物饲料提高动物的生产和生长性能,其社会价值较高。The beneficial effects of the invention are as follows: the use of raw materials is environmentally friendly and healthy, the cost of raw materials is low, the processing method is scientific and simple, and after being recovered as feed, the rich protein, especially the ratio of corn protein and soybean protein, realizes the complementary effect of protein , and a certain amount of starch is added, so that the content of polysaccharide and protein is high, wherein the content of polysaccharide is 42.38%-45.11%, and the content of protein is 38.21%-41.80%. The addition of the mulberry leaf extract also provides a small amount of active substances flavonoids and polyphenols, which is more conducive to improving the production and growth performance of animals as animal feed, and has high social value.
下面通过实施例,对本发明的技术方案做进一步的详细描述。The technical solutions of the present invention will be described in further detail below through examples.
具体实施方式Detailed ways
在本发明中所使用的术语,除非有另外说明,一般具有本领域普通技术人员通常理解的含义。下面结合具体的实施例,并参照数据进一步详细地描述本发明。应理解,这些实施例只是,对本发明进行进一步说明,不能理解为对本发明保护范围的限定,该领域的技术工程师可根据上述发明的内容对本发明作出一些非本质的改进和调整。Terms used in the present invention generally have the meanings commonly understood by those of ordinary skill in the art unless otherwise specified. The present invention will be described in further detail below in conjunction with specific embodiments and with reference to data. It should be understood that these embodiments are only to further illustrate the present invention, and should not be construed as limiting the protection scope of the present invention, and technical engineers in this field can make some non-essential improvements and adjustments to the present invention according to the content of the above invention.
在以下的实施例中,未详细描述的各种过程和方法是本领域中公知的常规方法。所用试剂的来源、商品名以及有必要列出其组成成分者,均在首次出现时标明,其后所用相同试剂如无特殊说明,均以首次标明的内容相同。本发明所作的举例,而并非对实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动,这里无需也无法对所有的实施方式予以穷举,而由此所引申出的显而易见的变化或变动仍处于本发明的保护范围中。In the following examples, various procedures and methods not described in detail are conventional methods well known in the art. The source and trade name of the reagents used, as well as those necessary to list their components, are indicated when they appear for the first time, and the same reagents used thereafter will be the same as those indicated for the first time unless otherwise specified. The present invention is an example, not a limitation to the embodiment. For those of ordinary skill in the art, changes or modifications in other different forms can also be made on the basis of the above description, and it is not necessary and impossible to list all the implementations here, and it is obvious that it is derived from this. Variations or modifications are still within the scope of the present invention.
本实施例中的微波设备型号为:NN-DS59JB,购于上海松下微波炉有限公司。The model of the microwave equipment in this embodiment is: NN-DS59JB, which was purchased from Shanghai Panasonic Microwave Oven Co., Ltd.
本实施例中的桑叶提取液的制备工艺为:称取一定桑叶粉(过60目)配制物料浓度为50g/L,加入5%纤维素酶(酶底比),提取3h后,12000r/min离心,取上清液,得到桑叶提取液。The preparation process of the mulberry leaf extract in this embodiment is as follows: take a certain amount of mulberry leaf powder (over 60 meshes) to prepare the material concentration of 50g/L, add 5% cellulase (enzyme-to-base ratio), and extract after 3h, 12000r /min centrifugation, take the supernatant to obtain the mulberry leaf extract.
实施例1Example 1
一种以植物蛋白为原料的环保可回收餐具及其制备方法,原料份量配比为:玉米黄粉7份,大豆蛋白3份,淀粉4份,羧甲基纤维素钠1份,食用明胶1 份。桑叶提取液的添加量按上述原料质量的700mL/kg添加,加水150mL/kg。An environmentally friendly recyclable tableware using vegetable protein as a raw material and a preparation method thereof. The proportions of the raw materials are: 7 parts of corn yellow powder, 3 parts of soybean protein, 4 parts of starch, 1 part of sodium carboxymethyl cellulose, and 1 part of edible gelatin . The addition amount of the mulberry leaf extract is added at 700 mL/kg of the above-mentioned raw material quality, and 150 mL/kg of water is added.
先将原料中的玉米黄粉、大豆蛋白粉碎,过120目筛,将其余原料按照上述份量依次放入容器中,搅拌,加入桑叶提取液和水,搅拌均匀。在微波功率200 W,微波时间5min处理后,放入磨具中,加压成型后取出干燥。在餐具表面涂抹5%(质量百分比计)玉米醇溶蛋白和乙基纤维素(配比9:1)防水涂层。将餐具置于紫外线消毒箱内杀菌即可。First, crush the corn yellow powder and soybean protein in the raw materials, pass through a 120-mesh sieve, put the rest of the raw materials into a container in sequence according to the above weight, stir, add mulberry leaf extract and water, and stir evenly. After the microwave power was 200 W and the microwave time was 5 min, it was put into an abrasive tool, pressed and formed, and then taken out and dried. Apply 5% (mass percent) zein and ethyl cellulose (9:1) waterproof coating on the tableware surface. Put the tableware in the ultraviolet disinfection box to sterilize.
所得到的餐具表面光滑,能够成型,且粉碎后测定干物质中营养成分:多糖含量为44.42%,蛋白质含量为41.80%,且添加桑叶提取物除提高了多糖和蛋白含量以外,还提供了一定含量的多酚(1.04%)和黄酮(0.4%),能够提高其抗氧化等生物学功能,这些营养成分有利于此餐具回收后作为高蛋白的营养饲料进行利用。The surface of the obtained tableware is smooth and can be formed, and the nutrients in the dry matter are determined after crushing: the polysaccharide content is 44.42%, the protein content is 41.80%, and the addition of the mulberry leaf extract not only improves the polysaccharide and protein content, but also provides A certain content of polyphenols (1.04%) and flavonoids (0.4%) can improve its biological functions such as anti-oxidation, and these nutrients are beneficial to the recycling of the tableware as a high-protein nutritional feed.
实施例2Example 2
一种以植物蛋白为原料的环保可回收餐具及其制备方法,原料份量配比为:玉米黄粉10份,大豆蛋白4份,淀粉6份,羧甲基纤维素钠3份,食用明胶2 份。桑叶提取液的添加量按上述原料质量的850mL/kg添加。An environmentally friendly recyclable tableware using vegetable protein as a raw material and a preparation method thereof. The proportions of the raw materials are: 10 parts of corn yellow powder, 4 parts of soybean protein, 6 parts of starch, 3 parts of sodium carboxymethyl cellulose, and 2 parts of edible gelatin . The addition amount of the mulberry leaf extract is added at 850 mL/kg of the above-mentioned raw material quality.
先将原料中的玉米黄粉、大豆蛋白粉碎,过120目筛,将其余原料按照上述份量依次放入容器中,搅拌,加入桑叶提取液和水,搅拌均匀。在微波功率1000 W,微波时间1min处理后,放入磨具中,加压成型后取出干燥。在餐具表面涂抹10%(质量百分比计)玉米醇溶蛋白和乙基纤维素(配比5:5)防水涂层。将餐具置于紫外线消毒箱内杀菌即可。First, crush the corn yellow powder and soybean protein in the raw materials, pass through a 120-mesh sieve, put the rest of the raw materials into a container in sequence according to the above weight, stir, add mulberry leaf extract and water, and stir evenly. After the microwave power was 1000 W and the microwave time was 1 min, it was put into an abrasive tool, pressed and formed, and then taken out to dry. Apply 10% (mass percent) zein and ethyl cellulose (5:5) waterproof coating on the tableware surface. Put the tableware in the ultraviolet disinfection box to sterilize.
所得到的餐具表面光滑,能够成型,且粉碎后测定干物质中营养成分:多糖含量为45.11%,蛋白质含量为39.16%,且添加桑叶提取物除提高了多糖和蛋白含量以外,还提供了一定含量的多酚(1.26%)和黄酮(0.48%),能够提高其抗氧化等生物学功能,这些营养成分有利于此餐具回收后作为高蛋白的营养饲料进行利用。The surface of the obtained tableware is smooth and can be formed, and the nutrients in the dry matter are determined after crushing: the polysaccharide content is 45.11%, the protein content is 39.16%, and the addition of the mulberry leaf extract not only improves the polysaccharide and protein content, but also provides. A certain content of polyphenols (1.26%) and flavonoids (0.48%) can improve its biological functions such as antioxidants, and these nutrients are beneficial to the recycling of the tableware as a high-protein nutritional feed.
实施例3Example 3
一种以植物蛋白为原料的环保可回收餐具及其制备方法,原料份量配比为:玉米黄粉8.5份,大豆蛋白3.5份,淀粉5份,羧甲基纤维素钠2份,食用明胶 1份。桑叶提取液的添加量按上述原料质量的400mL/kg添加,加水450mL/kg。An environmentally friendly recyclable tableware using vegetable protein as a raw material and a preparation method thereof. The proportions of the raw materials are: 8.5 parts of corn yellow powder, 3.5 parts of soybean protein, 5 parts of starch, 2 parts of sodium carboxymethyl cellulose, and 1 part of edible gelatin . The addition amount of the mulberry leaf extract is added at 400 mL/kg of the above-mentioned raw material quality, and 450 mL/kg of water is added.
先将原料中的玉米黄粉、大豆蛋白粉碎,过120目筛,将其余原料按照上述份量依次放入容器中,搅拌,加入桑叶提取液和水,搅拌均匀。在微波功率500 W,微波时间2min处理后,放入磨具中,加压成型后取出干燥。在餐具表面涂抹7%(质量百分比计)玉米醇溶蛋白和乙基纤维素(配比7:3)防水涂层。将餐具置于紫外线消毒箱内杀菌即可。First, crush the corn yellow powder and soybean protein in the raw materials, pass through a 120-mesh sieve, put the rest of the raw materials into a container in sequence according to the above weight, stir, add mulberry leaf extract and water, and stir evenly. After the microwave power is 500 W and the microwave time is 2 min, it is put into the mold, and then taken out and dried after being pressed and formed. Apply 7% (mass percent) zein and ethyl cellulose (ratio 7:3) waterproof coating on the tableware surface. Put the tableware in the ultraviolet disinfection box to sterilize.
所得到的餐具表面光滑,能够成型,且粉碎后测定干物质中营养成分:多糖含量为42.38%,蛋白质含量为38.21%,且添加桑叶提取物除提高了多糖和蛋白含量以外,还提供了一定含量的多酚(0.5%)和黄酮(0.22%),能够提高其抗氧化等生物学功能,这些营养成分有利于此餐具回收后作为高蛋白的营养饲料进行利用。The surface of the obtained tableware is smooth and can be formed, and the nutrients in the dry matter are determined after crushing: the polysaccharide content is 42.38%, the protein content is 38.21%, and the addition of the mulberry leaf extract not only improves the polysaccharide and protein content, but also provides A certain content of polyphenols (0.5%) and flavonoids (0.22%) can improve its biological functions such as antioxidants, and these nutrients are beneficial to the recycling of the tableware as a high-protein nutritional feed.
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