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CN114878505A - A Chip-Type Micro Air Cell Based on Plane Bending Optical Waveguide - Google Patents

A Chip-Type Micro Air Cell Based on Plane Bending Optical Waveguide Download PDF

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CN114878505A
CN114878505A CN202210809842.6A CN202210809842A CN114878505A CN 114878505 A CN114878505 A CN 114878505A CN 202210809842 A CN202210809842 A CN 202210809842A CN 114878505 A CN114878505 A CN 114878505A
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梁磊
贾鹏
秦莉
王立军
宋悦
王玉冰
陈泳屹
雷宇鑫
邱橙
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Changchun Institute of Optics Fine Mechanics and Physics of CAS
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Abstract

本发明实施例中提供的基于平面弯曲光波导的芯片式微型气室,硅基衬底,设置于硅基衬底上的光波导下包层,设置在光波导下包层上的芯层,芯层为脊形光波导结构,包括宽口激光入射波导、波导模式转化器、直波导、弯曲波导和宽口激光输出波导,设置在芯层上的气室互作用腔体,气室互作用腔体设有进气口和出气口,气室互作用腔体与芯层围成密闭空间。通过采用直波导和弯曲波导结合的方式构成延时线型弯曲波导,增加待测气体与倏逝场相互作用,提高其光功率限制因子,在不增加光波导长度的前提下,增加了等效光程长度,在光波导传感芯片上集成微型气室互作用腔体,提高系统集成化水平。

Figure 202210809842

The chip-type micro gas cell based on the plane-curved optical waveguide provided in the embodiment of the present invention, a silicon-based substrate, an optical waveguide lower cladding layer arranged on the silicon-based substrate, a core layer arranged on the optical waveguide lower cladding layer, The core layer is a ridge-shaped optical waveguide structure, including a wide-mouth laser incident waveguide, a waveguide mode converter, a straight waveguide, a curved waveguide and a wide-mouth laser output waveguide, and an air-chamber interaction cavity arranged on the core layer. The cavity is provided with an air inlet and an air outlet, and the air chamber interacts with the cavity and the core layer to form a closed space. By adopting a combination of straight waveguide and curved waveguide to form a time-delay line curved waveguide, the interaction between the gas to be tested and the evanescent field is increased, and the optical power limiting factor is improved. On the premise of not increasing the length of the optical waveguide, the equivalent The optical path length is improved by integrating a micro-air chamber interaction cavity on the optical waveguide sensor chip to improve the level of system integration.

Figure 202210809842

Description

一种基于平面弯曲光波导的芯片式微型气室A chip-type micro gas cell based on a plane-curved optical waveguide

技术领域technical field

本发明涉及气体检测领域,特别涉及一种基于平面弯曲光波导的芯片式微型气室及红外气体检测装置。The invention relates to the field of gas detection, in particular to a chip-type micro gas chamber and an infrared gas detection device based on a plane-curved optical waveguide.

背景技术Background technique

红外气体检测是利用待测气体在近红外或中红外的吸收谱特性,实现对待测气体浓度的测定,具有检测灵敏度高、响应快、稳定性好等特点,在外星探测、深海探测、大气环境检测、工业气体检测等领域应用十分广泛。红外气体检测系统传感部分主要包括红外激光发射模块、气室以及光电转换模块,气室的设计直接关乎检测系统检测精度、检测灵敏度、体积重量和成本。传统气室多采用离散光学元件,体积大,集成度差,与之相比,平面光波导式传感气室体积非常小,还可以和激光光源、探测器实现片上集成。Infrared gas detection is to use the absorption spectrum characteristics of the gas to be measured in the near-infrared or mid-infrared to realize the determination of the concentration of the gas to be measured. It has the characteristics of high detection sensitivity, fast response, and good stability. It is widely used in detection, industrial gas detection and other fields. The sensing part of the infrared gas detection system mainly includes the infrared laser emission module, the gas chamber and the photoelectric conversion module. The design of the gas chamber is directly related to the detection accuracy, detection sensitivity, volume weight and cost of the detection system. Traditional gas cells mostly use discrete optical components, which are large in size and poor in integration. Compared with the planar optical waveguide sensing gas cell, the volume is very small, and it can also be integrated with laser light sources and detectors on-chip.

基于此,人们提出了几种基于平面光波导气室来检测气体浓度方法,可大致分为两类:折射率传感和光吸收传感。折射率传感是基于待测气体折射率的变化,导致输出光的频率或相位的变化。与折射率传感相比,基于激光吸收光谱的波导传感器具有选择性,因为每种待测气体都有独特的吸收光谱,通过检测特定波长激光通过待测气体时的光衰减,可以计算出待测气体的浓度。Based on this, several methods for detecting gas concentration based on planar optical waveguide gas cells have been proposed, which can be roughly divided into two categories: refractive index sensing and optical absorption sensing. Refractive index sensing is based on changes in the refractive index of the gas being measured, resulting in changes in the frequency or phase of the output light. Compared with refractive index sensing, the waveguide sensor based on laser absorption spectrum is selective, because each gas to be tested has a unique absorption spectrum. measure the gas concentration.

现有的技术为了降低检测下限,根据比尔-兰伯特定律,需要增加光路长度,即光与待测气体相互作用的长度,这又会带来很大的传输损耗。在光波导气体传感器,待测气体作为波导的包层,并与波导的倏逝场相互作用,只要提高待测气体光功率限制因子意味着光能够与待测气体充分相互作用,增加等效光程长度,降低系统噪声和检测下限。In order to reduce the lower limit of detection in the existing technology, according to the Beer-Lambert law, it is necessary to increase the optical path length, that is, the length of the interaction between the light and the gas to be measured, which will bring about a large transmission loss. In the optical waveguide gas sensor, the gas to be tested acts as the cladding of the waveguide and interacts with the evanescent field of the waveguide. As long as the optical power limit factor of the gas to be tested is increased, it means that the light can fully interact with the gas to be tested, increasing the equivalent light length, reduce system noise and lower detection limit.

发明内容SUMMARY OF THE INVENTION

有鉴于此,本发明实施例中提供一种基于平面弯曲光波导的芯片式微型气室及红外气体检测装置。In view of this, embodiments of the present invention provide a chip-type micro gas cell and an infrared gas detection device based on a plane-curved optical waveguide.

第一方面,本发明提供一种基于平面弯曲光波导的芯片式微型气室,包括:In a first aspect, the present invention provides a chip-type micro gas cell based on a plane-curved optical waveguide, comprising:

硅基衬底;silicon-based substrate;

设置于所述硅基衬底上的光波导下包层;an optical waveguide lower cladding layer disposed on the silicon-based substrate;

设置在所述光波导下包层上的芯层,所述芯层为脊形光波导结构,包括宽口激光入射波导、波导模式转化器、直波导、弯曲波导和宽口激光输出波导;a core layer arranged on the lower cladding layer of the optical waveguide, the core layer is a ridge-shaped optical waveguide structure, including a wide-mouth laser incident waveguide, a waveguide mode converter, a straight waveguide, a curved waveguide and a wide-mouth laser output waveguide;

设置在所述芯层上的气室互作用腔体,所述气室互作用腔体设有进气口和出气口,所述气室互作用腔体与所述芯层围成密闭空间。An air-chamber interaction cavity is provided on the core layer, the air-chamber interaction cavity is provided with an air inlet and an air outlet, and the air-chamber interaction cavity and the core layer form a closed space.

作为一种可选的方案,所述光波导下包层为在所述硅基衬底上生成的均匀厚度的低折射率、低损耗无机材料或聚合物薄膜材料。As an optional solution, the optical waveguide lower cladding layer is a low-refractive-index, low-loss inorganic material or a polymer thin film material with a uniform thickness formed on the silicon-based substrate.

作为一种可选的方案,所述光波导下包层采用SiO2材料。As an optional solution, the lower cladding layer of the optical waveguide is made of SiO 2 material.

作为一种可选的方案,所述芯层采用无机材料制成,制备工艺为化学气相沉积、电子束蒸发或溅射工艺。As an optional solution, the core layer is made of inorganic material, and the preparation process is chemical vapor deposition, electron beam evaporation or sputtering process.

作为一种可选的方案,所述芯层为聚合物薄膜材料制成,制备工艺为旋涂和烘烤。As an optional solution, the core layer is made of polymer film material, and the preparation process is spin coating and baking.

作为一种可选的方案,所述直波导和所述弯曲波导构成的形状是延时线波导。As an optional solution, the shape formed by the straight waveguide and the curved waveguide is a delay line waveguide.

作为一种可选的方案,所述气室互作用腔体为方形、圆形或椭圆形。As an optional solution, the air-chamber interaction cavity is square, circular or oval.

作为一种可选的方案,所述气室互作用腔体的材料为聚合物材料或玻璃。As an optional solution, the material of the air-chamber interaction cavity is a polymer material or glass.

作为一种可选的方案,所述气室互作用腔体采用聚二甲基硅氧烷PDMS材料制成。As an optional solution, the air chamber interaction cavity is made of polydimethylsiloxane PDMS material.

作为一种可选的方案,所述芯层为脊形光波导结构,所述脊形光波导结构为倒梯形结构设计,所述波导模式转化器包括第一波导模式转化器和第二波导模式转化器,所述宽口激光入射波导与所述第一波导模式转化器连接,所述第一波导模式转化器与所述直波导连接,所述弯曲波导为半圆型波导,所述直波导与所述弯曲波导连接构成串联S型延时线结构,所述直波导与所述第二波导模式转化器连接,所述第二波导模式转化器与所述宽口激光输出波导连接,所述第一波导模式转化器与所述第二波导模式转化器结构相同但通光方向相反,所述宽口激光入射波导与所述宽口激光输出波导结构相同。As an optional solution, the core layer is a ridge optical waveguide structure, the ridge optical waveguide structure is an inverted trapezoidal structure design, and the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode converter, the wide-mouth laser incident waveguide is connected to the first waveguide mode converter, the first waveguide mode converter is connected to the straight waveguide, the curved waveguide is a semicircular waveguide, and the straight waveguide is connected to the straight waveguide. The curved waveguides are connected to form a series S-shaped delay line structure, the straight waveguides are connected to the second waveguide mode converter, the second waveguide mode converter is connected to the wide-mouth laser output waveguide, and the first waveguide mode converter is connected to the wide-mouth laser output waveguide. A waveguide mode converter has the same structure as the second waveguide mode converter but the light passing directions are opposite, and the wide-mouth laser input waveguide has the same structure as the wide-mouth laser output waveguide.

作为一种可选的方案,所述芯层为脊形光波导结构,所述脊形光波导结构为倒梯形结构设计,所述波导模式转化器包括第一波导模式转化器和第二波导模式转化器,所述宽口激光入射波导与所述第一波导模式转化器连接,所述第一波导模式转化器与所述直波导连接,所述弯曲波导为多个半径不同的半圆型波导组成,所述直波导与所述弯曲波导连接构成太极式螺旋型延时线结构,所述直波导与所述第二波导模式转化器连接,所述第二波导模式转化器与所述宽口激光输出波导连接,所述第一波导模式转化器与所述第二波导模式转化器结构相同但通光方向相反,所述宽口激光入射波导与所述宽口激光输出波导结构相同。As an optional solution, the core layer is a ridge optical waveguide structure, the ridge optical waveguide structure is an inverted trapezoidal structure design, and the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode a converter, the wide-mouth laser incident waveguide is connected to the first waveguide mode converter, the first waveguide mode converter is connected to the straight waveguide, and the curved waveguide is composed of a plurality of semicircular waveguides with different radii , the straight waveguide is connected with the curved waveguide to form a Taichi type helical delay line structure, the straight waveguide is connected with the second waveguide mode converter, and the second waveguide mode converter is connected with the wide-mouth laser The output waveguide is connected, the first waveguide mode converter and the second waveguide mode converter have the same structure but opposite light passing directions, and the wide-mouth laser incident waveguide has the same structure as the wide-mouth laser output waveguide.

作为一种可选的方案,所述芯层为脊形光波导结构和狭缝光波导结构,所述狭缝光波导结构设置在所述直波导和弯曲波导上,所述波导模式转化器包括第一波导模式转化器和第二波导模式转化器,所述宽口激光入射波导与所述第一波导模式转化器连接,所述第一波导模式转化器与所述直波导连接,所述弯曲波导为半圆型波导,所述直波导与所述弯曲波导连接构成串联S型延时线结构,所述直波导与所述第二波导模式转化器连接,所述第二波导模式转化器与所述宽口激光输出波导连接,所述第一波导模式转化器与所述第二波导模式转化器结构相同但通光方向相反,所述宽口激光入射波导与所述宽口激光输出波导结构相同。As an optional solution, the core layer is a ridge optical waveguide structure and a slit optical waveguide structure, the slit optical waveguide structure is arranged on the straight waveguide and the curved waveguide, and the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode converter, the wide-mouth laser incident waveguide is connected with the first waveguide mode converter, the first waveguide mode converter is connected with the straight waveguide, the curved The waveguide is a semicircular waveguide, the straight waveguide is connected to the curved waveguide to form a series S-shaped delay line structure, the straight waveguide is connected to the second waveguide mode converter, and the second waveguide mode converter is connected to the second waveguide mode converter. The wide-mouth laser output waveguide is connected, the first waveguide mode converter and the second waveguide mode converter have the same structure but opposite light passing directions, and the wide-mouth laser incident waveguide has the same structure as the wide-mouth laser output waveguide .

第二方面,本发明提供一种红外气体检测装置,具有如上述的基于平面弯曲光波导的芯片式微型气室。In a second aspect, the present invention provides an infrared gas detection device having the above-mentioned chip-type micro gas cell based on a plane-curved optical waveguide.

本发明实施例中提供的基于平面弯曲光波导的芯片式微型气室及红外检测装置,包括硅基衬底,设置于所述硅基衬底上的光波导下包层,设置在所述光波导下包层上的芯层,所述芯层为脊形光波导结构,包括宽口激光入射波导、波导模式转化器、直波导、弯曲波导和宽口激光输出波导,设置在所述芯层上的气室互作用腔体,所述气室互作用腔体设有进气口和出气口,所述气室互作用腔体与所述芯层围成密闭空间。通过采用直波导和弯曲波导结合的方式构成延时线型弯曲波导,增加待测气体与倏逝场相互作用,提高其光功率限制因子,在不增加光波导长度的前提下,增加了等效光程长度,在光波导传感芯片上集成微型气室互作用腔体,将红外气体检测气室做到芯片化、集成化,为后续激光光源、气室、探测器和控制电路一体化微型设计提供了解决方案。The chip-type micro gas cell and the infrared detection device based on the plane-curved optical waveguide provided in the embodiment of the present invention include a silicon-based substrate, an optical waveguide lower cladding layer disposed on the silicon-based substrate, and disposed on the optical waveguide. The core layer on the lower cladding layer of the waveguide, the core layer is a ridge-shaped optical waveguide structure, including a wide-mouth laser incident waveguide, a waveguide mode converter, a straight waveguide, a curved waveguide and a wide-mouth laser output waveguide, arranged on the core layer The air-chamber interaction cavity above the air-chamber interaction cavity is provided with an air inlet and an air outlet, and the air-chamber interaction cavity and the core layer form a closed space. By adopting the combination of straight waveguide and curved waveguide to form a time delay line curved waveguide, the interaction between the gas to be tested and the evanescent field is increased, the optical power limiting factor is improved, and the equivalent optical waveguide length is increased without increasing the length of the optical waveguide. Optical path length, integrated miniature gas chamber interaction cavity on the optical waveguide sensor chip, the infrared gas detection gas chamber can be chipped and integrated, and the subsequent laser light source, gas chamber, detector and control circuit can be integrated miniature Design provides the solution.

附图说明Description of drawings

图1为本发明实施例中提供一种基于平面弯曲光波导的芯片式微型气室的结构示意图;FIG. 1 is a schematic structural diagram of a chip-type micro gas cell based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图2为本发明实施例中提供一种基于平面弯曲光波导的芯片式微型气室中光波导结构的结构示意图;2 is a schematic structural diagram of an optical waveguide structure in a chip-type micro gas cell based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图3为本发明实施例中提供一种基于平面弯曲光波导的芯片式微型气室的传感区脊形光波导结构模拟光场分布图;FIG. 3 is a simulated optical field distribution diagram of a ridge-shaped optical waveguide structure in a sensing region of a chip-type micro-air chamber based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图4为本发明实施例中提供另一种基于平面弯曲光波导的芯片式微型气室的传感区脊形光波导结构SEM照片示意图;FIG. 4 is a schematic SEM photograph of a ridge-shaped optical waveguide structure in the sensing region of another chip-type micro air cell based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图5为本发明实施例中提供一种基于平面弯曲光波导的芯片式微型气室的结构示意图;5 is a schematic structural diagram of a chip-type micro gas cell based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图6为本发明实施例中提供另一种基于平面弯曲光波导的芯片式微型气室中光波导结构的结构示意图;FIG. 6 is a schematic structural diagram of an optical waveguide structure in another chip-type micro-air chamber based on a plane-curved optical waveguide according to an embodiment of the present invention;

图7为本发明实施例中提供又一种基于平面弯曲光波导的芯片式微型气室的结构示意图;FIG. 7 is a schematic structural diagram of another chip-type micro air cell based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图8为本发明实施例中提供又一种基于平面弯曲光波导的芯片式微型气室中光波导结构的结构示意图;8 is a schematic structural diagram of an optical waveguide structure in a chip-type micro-air chamber based on a plane-curved optical waveguide provided in an embodiment of the present invention;

图9为本发明实施例中提供又一种基于平面弯曲光波导的芯片式微型气室中光波导结构的俯视图。FIG. 9 is a top view of another optical waveguide structure in a chip-type micro gas cell based on a plane-curved optical waveguide provided in an embodiment of the present invention.

具体实施方式Detailed ways

为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to make those skilled in the art better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only Embodiments are part of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

本发明的说明书和权利要求书及上述附图中的术语“第一”、“第二”、“第三”、“第四”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的实施例能够以除了在这里图示或描述的内容以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。The terms "first", "second", "third", "fourth", etc. in the description and claims of the present invention and the above-mentioned drawings are used to distinguish similar objects and are not necessarily used to describe a specific order or sequence. It is to be understood that data so used may be interchanged under appropriate circumstances so that the embodiments described herein can be practiced in sequences other than those illustrated or described herein. Furthermore, the terms "comprising" and "having" and any variations thereof, are intended to cover non-exclusive inclusion, for example, a process, method, system, product or device comprising a series of steps or units is not necessarily limited to those expressly listed Rather, those steps or units may include other steps or units not expressly listed or inherent to these processes, methods, products or devices.

结合图1和2所示,本发明提供一种基于平面弯曲光波导的芯片式微型气室,包括:1 and 2, the present invention provides a chip-type micro gas cell based on a plane-curved optical waveguide, including:

硅基衬底1;Silicon-based substrate 1;

设置于所述硅基衬底上的光波导下包层2;an optical waveguide lower cladding layer 2 disposed on the silicon-based substrate;

设置在所述光波导下包层2上的芯层3,所述芯层3为脊形光波导结构,包括宽口激光入射波导301、波导模式转化器、直波导303、弯曲波导304和宽口激光输出波导306;The core layer 3 arranged on the lower cladding layer 2 of the optical waveguide, the core layer 3 is a ridge-shaped optical waveguide structure, including a wide-mouth laser incident waveguide 301, a waveguide mode converter, a straight waveguide 303, a curved waveguide 304 and a wide-mouth laser incident waveguide 301. A laser output waveguide 306;

设置在所述芯层上的气室互作用腔体4,所述气室互作用腔体4设有进气口5和出气口6,进气口5用于输入待测气体,出气口6用于排出待测气体,所述气室互作用腔体4与所述芯层3围成密闭空间。The air chamber interaction cavity 4 arranged on the core layer, the air chamber interaction cavity 4 is provided with an air inlet 5 and an air outlet 6, the air inlet 5 is used to input the gas to be measured, and the air outlet 6 For discharging the gas to be tested, the gas chamber interaction cavity 4 and the core layer 3 form a closed space.

作为一种可选的方案,所述光波导下包层2为在所述硅基衬底1上生成的均匀厚度的低折射率、低损耗无机材料或聚合物薄膜材料,介质膜或聚合物薄膜最低厚度是不让光波导的光场泄露到衬底层,本实施例中,光波导下包层2可以采用SiO2材料,厚度可以为2μm,对此不做限定。As an optional solution, the optical waveguide lower cladding layer 2 is a low-refractive index, low-loss inorganic material or a polymer thin film material, a dielectric film or a polymer film with a uniform thickness formed on the silicon-based substrate 1 The minimum thickness of the film is to prevent the optical field of the optical waveguide from leaking to the substrate layer. In this embodiment, the lower cladding layer 2 of the optical waveguide can be made of SiO 2 material, and the thickness can be 2 μm, which is not limited.

对于芯层3的材料,可以采用无机材料或聚合物材料制成,在芯层3采用无机材料制成,制备工艺为化学气相沉积、电子束蒸发或溅射工艺。在芯层3采用聚合物薄膜材料制成,制备工艺为旋涂和烘烤,对于相关制备工艺,本领域普通技术人员应当了解,对此不做赘述。The material of the core layer 3 can be made of inorganic material or polymer material, and the core layer 3 is made of inorganic material, and the preparation process is chemical vapor deposition, electron beam evaporation or sputtering process. The core layer 3 is made of a polymer film material, and the preparation process is spin coating and baking. Those of ordinary skill in the art should understand the relevant preparation process, and will not be repeated here.

本发明实施例中,所述直波导303和所述弯曲波导304构成的形状是延时线波导,采用延时线型弯曲波导结构,增加待测气体与倏逝场相互作用,提高其光功率限制因子,在不增加光波导长度的前提下,增加了等效光程长度,在光波导传感芯片上集成微型气室互作用腔体,真正将红外气体检测气室做到芯片化、集成化,为后续激光光源、气室、探测器和控制电路一体化微型设计提供了解决方案。In the embodiment of the present invention, the shape formed by the straight waveguide 303 and the curved waveguide 304 is a delay line waveguide, and a delay line curved waveguide structure is adopted to increase the interaction between the gas to be measured and the evanescent field, and improve its optical power The limiting factor is to increase the equivalent optical path length without increasing the length of the optical waveguide, and integrate the micro-chamber interaction cavity on the optical waveguide sensor chip, which truly makes the infrared gas detection gas chamber chip-like and integrated. It provides a solution for the integrated miniature design of the subsequent laser light source, gas chamber, detector and control circuit.

所述气室互作用腔体4为方形、圆形或椭圆形,能覆盖上述直波导303和弯曲波导304组成的气体传感区域。气室互作用腔体4材料可以是聚合物材料、玻璃等不影响激光在光波导传播的材料,可以根据需要选择,对此不做限定The gas-chamber interaction cavity 4 is square, circular or elliptical, and can cover the gas sensing area formed by the straight waveguide 303 and the curved waveguide 304 . The material of the gas-chamber interaction cavity 4 can be a polymer material, glass or other material that does not affect the propagation of the laser light in the optical waveguide, and can be selected according to the needs, which is not limited

本实施例中,所述气室互作用腔体4采用聚二甲基硅氧烷PDMS材料制成。In this embodiment, the air chamber interaction cavity 4 is made of polydimethylsiloxane PDMS material.

在一些实施例中,所述芯层3为脊形光波导结构,所述脊形光波导结构为倒梯形结构设计,所述波导模式转化器包括第一波导模式转化器302和第二波导模式转化器305,所述宽口激光入射波导301与所述第一波导模式转化器302连接,所述第一波导模式转化器302与所述直波导303连接,所述弯曲波导304为半圆型波导,所述直波导303具有多条且平行间隔设置,所述直波导303与所述弯曲波导304连接构成串联S型延时线结构,所述直波导303与所述第二波导模式转化器305连接,所述第二波导模式转化器305与所述宽口激光输出波导306连接,所述第一波导模式转化器302与所述第二波导模式转化器305结构相同但通光方向相反,所述宽口激光入射波导301与所述宽口激光输出波导306结构相同。In some embodiments, the core layer 3 is a ridge optical waveguide structure, the ridge optical waveguide structure is an inverted trapezoidal structure design, and the waveguide mode converter includes a first waveguide mode converter 302 and a second waveguide mode Converter 305, the wide-mouth laser incident waveguide 301 is connected to the first waveguide mode converter 302, the first waveguide mode converter 302 is connected to the straight waveguide 303, and the curved waveguide 304 is a semicircular waveguide , the straight waveguides 303 are arranged in parallel and spaced apart, the straight waveguides 303 and the curved waveguides 304 are connected to form a series S-shaped delay line structure, the straight waveguides 303 and the second waveguide mode converter 305 connected, the second waveguide mode converter 305 is connected to the wide-mouth laser output waveguide 306, the first waveguide mode converter 302 and the second waveguide mode converter 305 have the same structure but opposite light passing directions, so The wide-mouth laser incident waveguide 301 has the same structure as the wide-mouth laser output waveguide 306 .

结合图1所示,具体地,脊形光波导为SOI光波导,具体为从下至上依次包括硅基衬底1;置于硅基衬底上的光波导下包层2,采用SiO2材料,厚度为2μm;置于光波导下包层2上的芯层3,采用Si材料,厚度为500nm;置于所述芯层3上的气室互作用腔体4,采用聚二甲基硅氧烷(PDMS)材料制成,置于所述气室互作用腔体上的进气口5和出气口6,均由PDMS材料制备。1, specifically, the ridge-shaped optical waveguide is an SOI optical waveguide, which includes a silicon-based substrate 1 in order from bottom to top; the optical waveguide lower cladding layer 2 placed on the silicon-based substrate is made of SiO2 material , the thickness is 2 μm; the core layer 3 placed on the lower cladding layer 2 of the optical waveguide is made of Si material, and the thickness is 500 nm; the gas chamber interaction cavity 4 placed on the core layer 3 is made of polydimethylsilicon Oxane (PDMS) material, the air inlet 5 and the air outlet 6 placed on the air chamber interaction cavity are made of PDMS material.

结合图2所示,芯层3为脊形光波导结构,构成串联S型延时线结构,刻蚀深度为220nm,包括宽口激光入射波导301,宽度15μm,第一波导模式转化器302,长度300μm,波导宽度从15μm过渡到1.5μm,多条直波导303,长度1718μm,波导宽度1.5μm,多条弯曲波导304为半圆型波导,弯曲半径50μm,波导宽度1.5μm,直波导303与弯曲波导304首尾连接构成串联S型延时线结构,第二波导模式转化器305与第一波导模式转化器302结构相同,通光方向相反;宽口激光输出波导306结构与宽口激光入射波导301结构相同。As shown in FIG. 2 , the core layer 3 is a ridge-shaped optical waveguide structure, forming a series S-type delay line structure, the etching depth is 220 nm, and includes a wide-mouth laser incident waveguide 301 with a width of 15 μm, a first waveguide mode converter 302, The length is 300 μm, the waveguide width is transitioned from 15 μm to 1.5 μm, the plurality of straight waveguides 303, the length is 1718 μm, the waveguide width is 1.5 μm, the plurality of curved waveguides 304 are semi-circular waveguides, the bending radius is 50 μm, the waveguide width is 1.5 μm, the straight waveguides 303 and the bending The waveguides 304 are connected end to end to form a series S-shaped delay line structure. The second waveguide mode converter 305 has the same structure as the first waveguide mode converter 302, and the light passing direction is opposite; the structure of the wide-mouth laser output waveguide 306 is the same as that of the wide-mouth laser incident waveguide 301 The structure is the same.

图3所示是模拟的传感区脊形光波导结构模拟光场分布图,脊形为倒梯形结构,上边宽1.5μm,下边宽1.65μm。图4所示是模拟的传感区脊形光波导结构SEM照片。在此基础上已经成功研制芯片式微型气室,并用于甲烷气体检测,试验证明效果可行。Figure 3 shows the simulated light field distribution diagram of the simulated ridge-shaped optical waveguide structure in the sensing area. The ridge shape is an inverted trapezoid structure with a width of 1.5 μm on the upper side and a width of 1.65 μm on the lower side. Figure 4 shows the SEM photo of the simulated ridge-shaped optical waveguide structure in the sensing region. On this basis, a chip-type micro gas chamber has been successfully developed and used for methane gas detection, and the test proves that the effect is feasible.

结合图5所示,在另一些实施例中,所述芯层为脊形光波导结构,所述脊形光波导结构为倒梯形结构设计,所述波导模式转化器包括第一波导模式转化器302和第二波导模式转化器305,所述宽口激光入射波导301与所述第一波导模式转化器302连接,所述第一波导模式转化器302与所述直波导303连接,所述弯曲波导304为多个半径不同的半圆型波导组成,所述直波导303与所述弯曲波导304连接构成太极式螺旋型延时线结构,所述直波导303与所述第二波导模式转化器305连接,所述第二波导模式转化器305与所述宽口激光输出波导306连接,所述第一波导模式转化器302与所述第二波导模式转化器305相同但通光方向相反,所述宽口激光入射波导301与所述宽口激光输出波导306结构相同。With reference to FIG. 5 , in other embodiments, the core layer is a ridge optical waveguide structure, the ridge optical waveguide structure is an inverted trapezoidal structure design, and the waveguide mode converter includes a first waveguide mode converter 302 and a second waveguide mode converter 305, the wide-mouth laser incident waveguide 301 is connected with the first waveguide mode converter 302, the first waveguide mode converter 302 is connected with the straight waveguide 303, the curved The waveguide 304 is composed of a plurality of semi-circular waveguides with different radii. The straight waveguide 303 and the curved waveguide 304 are connected to form a Taichi spiral delay line structure. The straight waveguide 303 and the second waveguide mode converter 305 connected, the second waveguide mode converter 305 is connected to the wide-mouth laser output waveguide 306, the first waveguide mode converter 302 is the same as the second waveguide mode converter 305 but the light passing direction is opposite, the The wide-mouth laser incident waveguide 301 has the same structure as the wide-mouth laser output waveguide 306 .

结合图5所示,具体地,脊形光波导为SU-8光波导,具体为从下至上依次包括硅基衬底1;置于硅基衬底上的光波导下包层2,采用SiO2材料,厚度为2μm;置于所述光波导下包层2上的芯层3,采用SU-8材料,厚度为3μm;置于所述芯层3上的气室互作用腔体4,采用聚二甲基硅氧烷(PDMS)材料制成,置于所述气室互作用腔体4左右两侧的进气口5和出气口6,均由PDMS材料制备。As shown in FIG. 5 , specifically, the ridge-shaped optical waveguide is an SU-8 optical waveguide, which includes a silicon-based substrate 1 in order from bottom to top; the optical waveguide lower cladding layer 2 placed on the silicon-based substrate is made of SiO 2 material, with a thickness of 2 μm; the core layer 3 placed on the lower cladding layer 2 of the optical waveguide is made of SU-8 material, with a thickness of 3 μm; the gas chamber interaction cavity 4 placed on the core layer 3, It is made of polydimethylsiloxane (PDMS) material, and the air inlet 5 and the air outlet 6 placed on the left and right sides of the air chamber interaction cavity 4 are all made of PDMS material.

结合图6所示,芯层3为脊形光波导结构,构成太极式螺旋型延时线结构,刻蚀深度为1μm,包括宽口激光入射波导301,宽度15μm;第一波导模式转化器302,长度300μm,波导宽度从15μm过渡到2.5μm,多条直波导303,长度1718μm,波导宽度2.5μm,多条弯曲波导304为多个半径不同的半圆型波导组成,弯曲半径分别为50μm、75μm和100μm,波导宽度2.5μm;直波导303与弯曲波导304首尾连接构成太极式螺旋型延时线结构,第二波导模式转化器305与第一波导模式转化器302结构相同,通光方向相反;宽口激光输出波导306结构与宽口激光入射波导301结构相同。As shown in FIG. 6 , the core layer 3 is a ridge-shaped optical waveguide structure, which constitutes a Taichi-type helical delay line structure with an etching depth of 1 μm, including a wide-mouth laser incident waveguide 301 with a width of 15 μm; a first waveguide mode converter 302 , the length is 300 μm, the waveguide width transitions from 15 μm to 2.5 μm, the multiple straight waveguides 303 are 1718 μm in length and the waveguide width is 2.5 μm, and the multiple curved waveguides 304 are composed of multiple semi-circular waveguides with different radii, and the bending radii are 50 μm and 75 μm respectively. and 100 μm, and the waveguide width is 2.5 μm; the straight waveguide 303 and the curved waveguide 304 are connected end to end to form a Taichi spiral delay line structure, the second waveguide mode converter 305 has the same structure as the first waveguide mode converter 302, and the light passing direction is opposite; The structure of the wide-mouth laser output waveguide 306 is the same as that of the wide-mouth laser input waveguide 301 .

在又一些实施例中,所述芯层为脊形光波导结构和狭缝光波导结构,所述狭缝光波导结构设置在所述直波导303和弯曲波304导上,所述波导模式转化器包括第一波导模式转化器302和第二波导模式转化器305,所述宽口激光入射波导301与所述第一波导模式转化器302连接,所述第一波导模式转化器302与所述直波导303连接,所述弯曲波导304为半圆型波导,所述直波导303与所述弯曲波导304连接构成串联S型延时线结构,所述直波导303与所述第二波导模式转化器305连接,所述第二波导模式转化器305与所述宽口激光输出波导306连接,所述第一波导模式转化器302与所述第二波导模式转化器305结构相同但通光方向相反,所述宽口激光入射波导301与所述宽口激光输出波导306结构相同。In still other embodiments, the core layer is a ridge optical waveguide structure and a slit optical waveguide structure, the slit optical waveguide structure is arranged on the straight waveguide 303 and the bending wave 304, and the waveguide mode is converted The device includes a first waveguide mode converter 302 and a second waveguide mode converter 305, the wide-mouth laser incident waveguide 301 is connected to the first waveguide mode converter 302, and the first waveguide mode converter 302 is connected to the The straight waveguide 303 is connected, the curved waveguide 304 is a semi-circular waveguide, the straight waveguide 303 and the curved waveguide 304 are connected to form a series S-type delay line structure, the straight waveguide 303 and the second waveguide mode converter 305 is connected, the second waveguide mode converter 305 is connected with the wide-mouth laser output waveguide 306, the first waveguide mode converter 302 and the second waveguide mode converter 305 have the same structure but the light passing direction is opposite, The wide-mouth laser incident waveguide 301 has the same structure as the wide-mouth laser output waveguide 306 .

结合图7所示,光波导为SOI光波导,具体为从下至上依次包括硅基衬底1;置于硅基衬底上的光波导下包层2,采用SiO2材料,厚度为2μm;置于光波导下包层2上的芯层3,采用Si材料,厚度为220nm;置于所述芯层3上的气室互作用腔体4,采用聚二甲基硅氧烷(PDMS)材料制成,置于所述气室互作用腔体4上的进气口5和出气口6,均由PDMS材料制备。As shown in FIG. 7 , the optical waveguide is an SOI optical waveguide, which specifically includes a silicon-based substrate 1 from bottom to top; the optical waveguide lower cladding layer 2 placed on the silicon-based substrate is made of SiO 2 material and has a thickness of 2 μm; The core layer 3 placed on the lower cladding layer 2 of the optical waveguide is made of Si material with a thickness of 220 nm; the gas chamber interaction cavity 4 placed on the core layer 3 is made of polydimethylsiloxane (PDMS) The air inlet 5 and the air outlet 6 placed on the air chamber interaction cavity 4 are made of PDMS material.

结合图8和图9所示,芯层3采用脊形光波导和狭缝光波导结构,构成串联S型延时线结构,刻蚀深度为220nm,包括宽口激光入射波导301,脊形光波导结构,宽度8μm;第一波导模式转化器302,长度300μm,脊形光波导结构,波导宽度从8μm过渡到1.1μm;多条直波导303,狭缝波导结构,长度1718μm,波导总宽度1.1μm,两边高折射率区宽度为500nm,中间狭缝宽100nm,多条弯曲波导304为半圆型波导,弯曲半径50μm,波导宽度1.1μm,两边高折射率区宽度为500nm,中间狭缝宽100nm;直波导303与弯曲波导304首尾连接构成串联S型延时线结构,第二波导模式转化器305与第一波导模式转化器302结构相同,通光方向相反;宽口激光输出波导306结构与宽口激光入射波导301结构相同。8 and 9, the core layer 3 adopts a ridge optical waveguide and a slit optical waveguide structure to form a series S-type delay line structure, and the etching depth is 220 nm, including the wide-mouth laser incident waveguide 301, the ridge light Waveguide structure, width 8μm; first waveguide mode converter 302, length 300μm, ridge optical waveguide structure, waveguide width transition from 8μm to 1.1μm; multiple straight waveguides 303, slit waveguide structure, length 1718μm, total waveguide width 1.1 μm, the width of the high refractive index region on both sides is 500 nm, the width of the middle slit is 100 nm, the plurality of curved waveguides 304 are semi-circular waveguides, the bending radius is 50 μm, the width of the waveguide is 1.1 μm, the width of the high refractive index region on both sides is 500 nm, and the width of the middle slit is 100 nm The straight waveguide 303 and the curved waveguide 304 are connected end to end to form a series S-type delay line structure, the second waveguide mode converter 305 has the same structure as the first waveguide mode converter 302, and the light passing direction is opposite; the wide-mouth laser output waveguide 306 has the same structure as The structure of the wide-mouth laser incident waveguide 301 is the same.

本发明实施例中提供的基于平面弯曲光波导的芯片式微型气室,通过采用直波导和弯曲波导结合的方式构成延时线型弯曲波导,增加待测气体与倏逝场相互作用,提高其光功率限制因子,在不增加光波导长度的前提下,增加了等效光程长度,在光波导传感芯片上集成微型气室互作用腔体,将红外气体检测气室做到芯片化、集成化,为后续激光光源、气室、探测器和控制电路一体化微型设计提供了解决方案。The chip-type micro gas cell based on the plane-curved optical waveguide provided in the embodiment of the present invention forms a time-delay line-type curved waveguide by combining a straight waveguide and a curved waveguide, thereby increasing the interaction between the gas to be measured and the evanescent field, and improving its performance. The optical power limiting factor increases the equivalent optical path length without increasing the length of the optical waveguide, and integrates the micro-gas chamber interaction cavity on the optical waveguide sensing chip, so that the infrared gas detection gas chamber can be chipped, Integration provides a solution for the subsequent integrated miniature design of laser light source, gas chamber, detector and control circuit.

相应地,本发明提供一种红外气体检测装置,具有如上述的基于平面弯曲光波导的芯片式微型气室,可以将红外气体检测气室做到芯片化、集成化,为后续激光光源、气室、探测器和控制电路一体化微型设计提供了解决方案。Correspondingly, the present invention provides an infrared gas detection device, which has the above-mentioned chip-type micro gas chamber based on a plane-curved optical waveguide, which can realize the chip-based and integrated infrared gas detection gas chamber, which can be used for subsequent laser light sources, gas The integrated miniature design of chamber, detector and control circuit provides the solution.

上述具体实施方式,并不构成对本发明保护范围的限制。本领域技术人员应该明白的是,根据设计要求和其他因素,可以进行各种修改、组合、子组合和替代。任何在本发明的精神和原则之内所作的修改、等同替换和改进等,均应包含在本发明保护范围之内。The above-mentioned specific embodiments do not constitute a limitation on the protection scope of the present invention. It should be understood by those skilled in the art that various modifications, combinations, sub-combinations and substitutions may occur depending on design requirements and other factors. Any modifications, equivalent replacements and improvements made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (13)

1. A chip type micro air chamber based on a planar bending optical waveguide is characterized by comprising:
a silicon-based substrate;
an optical waveguide lower cladding disposed on the silicon-based substrate;
the core layer is arranged on the optical waveguide lower cladding layer and is of a ridge optical waveguide structure and comprises a wide-mouth laser incident waveguide, a waveguide mode converter, a straight waveguide, a bent waveguide and a wide-mouth laser output waveguide;
the air chamber interaction cavity is arranged on the core layer, an air inlet and an air outlet are formed in the air chamber interaction cavity, and the air chamber interaction cavity and the core layer form a closed space in a surrounding mode.
2. The chip-type micro gas cell based on planar bending optical waveguide of claim 1, wherein the optical waveguide lower cladding layer is a low refractive index, low loss inorganic material or polymer thin film material of uniform thickness generated on the silicon-based substrate.
3. The chip-type micro gas cell based on planar bending optical waveguide as claimed in claim 1 or 2, wherein the optical waveguide lower cladding layer is made of SiO 2 A material.
4. The chip type micro gas cell based on the planar bending optical waveguide as claimed in claim 1, wherein the core layer is made of inorganic material and is prepared by chemical vapor deposition, electron beam evaporation or sputtering.
5. The chip-type micro air cell based on the planar bending optical waveguide as claimed in claim 1, wherein the core layer is made of polymer film material and is prepared by spin coating and baking.
6. The chip-type micro gas cell based on planar curved optical waveguide as claimed in claim 1, wherein the straight waveguide and the curved waveguide are formed in the shape of a delay line waveguide.
7. The chip-type micro gas cell based on planar bending optical waveguide of claim 1, wherein the gas cell interaction cavity is square, circular or elliptical.
8. The chip-type micro gas cell based on planar bending optical waveguide of claim 1 or 7, wherein the material of the gas cell interaction cavity is polymer material or glass.
9. The chip-type micro gas cell based on planar bending optical waveguide of claim 1 or 7, wherein the gas cell interaction cavity is made of PDMS material.
10. The chip-type micro gas cell based on planar curved optical waveguide as claimed in claim 1, wherein the core layer is a ridge optical waveguide structure, the ridge optical waveguide structure is designed as an inverted trapezoid structure, the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode converter, the wide laser incident waveguide is connected to the first waveguide mode converter, the first waveguide mode converter is connected to the straight waveguide, the curved waveguide is a semicircular waveguide, the straight waveguide is connected to the curved waveguide to form a serial S-type delay line structure, the straight waveguide is connected to the second waveguide mode converter, the second waveguide mode converter is connected to the wide laser output waveguide, the first waveguide mode converter and the second waveguide mode converter are identical in structure but opposite in light passing direction, the wide-mouth laser incident waveguide and the wide-mouth laser output waveguide have the same structure.
11. The chip-type micro gas cell based on planar curved optical waveguide as claimed in claim 1, wherein the core layer is a ridge optical waveguide structure, the ridge optical waveguide structure is designed as an inverted trapezoid structure, the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode converter, the wide laser incident waveguide is connected to the first waveguide mode converter, the first waveguide mode converter is connected to the straight waveguide, the curved waveguide is composed of a plurality of semicircular waveguides with different radii, the straight waveguide is connected to the curved waveguide to form a tai-chi helical delay line structure, the straight waveguide is connected to the second waveguide mode converter, the second waveguide mode converter is connected to the wide laser output waveguide, the first waveguide mode converter and the second waveguide mode converter are identical in structure but opposite in light transmission direction, the wide-mouth laser incident waveguide and the wide-mouth laser output waveguide have the same structure.
12. The chip-type micro gas cell based on planar curved optical waveguide as claimed in claim 1, wherein the core layer is a ridge optical waveguide structure and a slit optical waveguide structure, the slit optical waveguide structure is disposed on the straight waveguide and the curved waveguide, the waveguide mode converter includes a first waveguide mode converter and a second waveguide mode converter, the wide laser incident waveguide is connected to the first waveguide mode converter, the first waveguide mode converter is connected to the straight waveguide, the curved waveguide is a semicircular waveguide, the straight waveguide is connected to the curved waveguide to form a serial S-type delay line structure, the straight waveguide is connected to the second waveguide mode converter, the second waveguide mode converter is connected to the wide laser output waveguide, the first waveguide mode converter is identical to the second waveguide mode converter in structure but opposite to the light transmission direction, the wide-mouth laser incident waveguide and the wide-mouth laser output waveguide have the same structure.
13. An infrared gas detection device, characterized in that, the chip-type micro gas cell based on the planar bending optical waveguide of any one of claims 1 to 12 is provided.
CN202210809842.6A 2022-07-11 2022-07-11 A Chip-Type Micro Air Cell Based on Plane Bending Optical Waveguide Pending CN114878505A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150147038A1 (en) * 2013-11-28 2015-05-28 Ngk Insulators, Ltd. Optical Waveguide Devices
CN110726689A (en) * 2019-09-26 2020-01-24 宁波大学 A miniature spectral absorption optical waveguide type mid-infrared gas sensor and its application
CN112285825A (en) * 2020-10-19 2021-01-29 东南大学 Optical coupling chip and preparation method thereof
CN114296177A (en) * 2022-01-25 2022-04-08 吉林大学 Racetrack-type microring optical switch based on silica/polymer hybrid waveguide and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150147038A1 (en) * 2013-11-28 2015-05-28 Ngk Insulators, Ltd. Optical Waveguide Devices
CN110726689A (en) * 2019-09-26 2020-01-24 宁波大学 A miniature spectral absorption optical waveguide type mid-infrared gas sensor and its application
CN112285825A (en) * 2020-10-19 2021-01-29 东南大学 Optical coupling chip and preparation method thereof
CN114296177A (en) * 2022-01-25 2022-04-08 吉林大学 Racetrack-type microring optical switch based on silica/polymer hybrid waveguide and preparation method thereof

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Application publication date: 20220809