CN114736701B - A biomass pyrolysis furnace, a biomass pyrolysis system and a pyrolysis process - Google Patents
A biomass pyrolysis furnace, a biomass pyrolysis system and a pyrolysis process Download PDFInfo
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- 238000000197 pyrolysis Methods 0.000 title claims abstract description 149
- 239000002028 Biomass Substances 0.000 title claims abstract description 120
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000002485 combustion reaction Methods 0.000 claims abstract description 58
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 12
- 238000005192 partition Methods 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 104
- 238000002156 mixing Methods 0.000 claims description 38
- 238000000926 separation method Methods 0.000 claims description 38
- 238000000746 purification Methods 0.000 claims description 29
- 238000001035 drying Methods 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 19
- 239000000428 dust Substances 0.000 claims description 18
- 238000004062 sedimentation Methods 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 13
- 238000005469 granulation Methods 0.000 claims description 12
- 230000003179 granulation Effects 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002023 wood Substances 0.000 claims description 8
- 239000003610 charcoal Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims 8
- 238000007233 catalytic pyrolysis Methods 0.000 claims 3
- 238000004523 catalytic cracking Methods 0.000 abstract description 30
- 238000010438 heat treatment Methods 0.000 abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052799 carbon Inorganic materials 0.000 abstract description 12
- 238000003421 catalytic decomposition reaction Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 1
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000012075 bio-oil Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
- C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/18—Modifying the properties of the distillation gases in the oven
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
本发明涉及生物质热解设备技术领域,具体来说是一种生物质热解炉及生物质热解系统和热解工艺,生物质热解炉包括外壳体和供热体,供热体套设并连接于外壳体内,且二者之间预留有燃烧腔,燃烧腔内由隔板由上至下分隔为热解室和催化裂解室,催化裂解室上还贯通连接有热风机:供热体上开设有若干开口,开口上嵌设有若干稳焰体;外壳体上设置有全预混风机;供热体内设置有反应室,反应室由螺旋设置的燃烧管组成;燃烧管的顶端贯通设置有料仓,料仓上贯通连接有热氮气风管;燃烧管的底部贯通设置有接收仓。本发明提供了一种生物质热解炉,以及配合生物质热解炉使用的生物质热解系统,旨在通过生物质和焦油共同制备生物质碳,以及实现焦油的催化分解。
The present invention relates to the technical field of biomass pyrolysis equipment, specifically a biomass pyrolysis furnace and a biomass pyrolysis system and a pyrolysis process, wherein the biomass pyrolysis furnace comprises an outer shell and a heating body, the heating body is sleeved and connected in the outer shell, and a combustion chamber is reserved between the two, the combustion chamber is divided into a pyrolysis chamber and a catalytic cracking chamber from top to bottom by a partition, and a hot air blower is also connected to the catalytic cracking chamber: a plurality of openings are provided on the heating body, and a plurality of flame stabilizing bodies are embedded in the openings; a full premixing blower is provided on the outer shell; a reaction chamber is provided in the heating body, and the reaction chamber is composed of a spirally arranged combustion tube; a silo is provided at the top of the combustion tube, and a hot nitrogen air duct is connected to the silo; a receiving bin is provided at the bottom of the combustion tube. The present invention provides a biomass pyrolysis furnace and a biomass pyrolysis system used in conjunction with the biomass pyrolysis furnace, which is intended to prepare biomass carbon by biomass and tar, and to achieve catalytic decomposition of tar.
Description
技术领域Technical Field
本发明涉及生物质热解设备技术领域,具体来说是一种生物质热解炉及生物质热解系统和热解工艺。The invention relates to the technical field of biomass pyrolysis equipment, in particular to a biomass pyrolysis furnace and a biomass pyrolysis system and a pyrolysis process.
背景技术Background technique
煤炭、石油等不可再生的化石能源的过度开采和利用,使得地球上的能源与环境问题越来越严峻,寻求高效、洁净能源成为世界关注的热点,生物质资源是地球上第四大资源,其储量仅次于煤炭、石油和天然气,同时也是储量第一的清洁型可再生能源,是最适合的化石能源替代能源之一;生物质能源具有资源丰富、廉价、可再生、清洁等特点,因此生物质的开发与应用已经成为了广泛关注的热点。The excessive exploitation and utilization of non-renewable fossil energy such as coal and oil have made the energy and environmental problems on the earth more and more serious. The search for efficient and clean energy has become a hot topic of world concern. Biomass resources are the fourth largest resource on the earth, and its reserves are second only to coal, oil and natural gas. It is also the clean renewable energy with the largest reserves and is one of the most suitable alternative energy sources to fossil energy. Biomass energy has the characteristics of abundant resources, low cost, renewable and clean. Therefore, the development and application of biomass has become a hot topic of widespread concern.
生物质热解就是将生物质经过热解的过程转化成可燃气体和自然资源,生物质热解是在无氧或限氧条件下,对生物质原料进行加热,实现热解反应,得到生物炭、生物油、燃气的过程。目前生物质热解工艺和热洁炉的设计得到了广泛关注,但是目前的生物质热解工艺仍然存在诸多亟待解决的问题,其中的一个问题就是焦油的转化、脱除,焦油主要是由组成生物质的纤维素、木质素、半纤维素等成分的分子键断裂时产生的,断裂过程中产生CO、CO2、H2O、CH4等小的气态分子,焦炭、木醋酸、焦油等大的分子,焦油成分复杂,其含有上百种不同类型、性质的化合物,主要成分是多核芳香族成分,焦油成分中含有浓度较高的PAH物质,PAH物质具有较高的毒性,在凝结为细小液滴的焦油不完全燃烧后,会引起PAH物质和焦炭的产生,PAH物质具有致癌的危险性;若对焦油进行净化处理,产生的焦油废水中含有酚及酚类化合物、苯系物、杂环、芳香族化合物等有机物,其COD浓度高,还散发出强烈刺激性气味,对环境造成污染,危害人体健康。Biomass pyrolysis is the process of converting biomass into combustible gases and natural resources through pyrolysis. Biomass pyrolysis is the process of heating biomass raw materials under anaerobic or oxygen-limited conditions to achieve pyrolysis reaction and obtain biochar, bio-oil and gas. At present, the design of biomass pyrolysis process and thermal cleaning furnace has received extensive attention, but the current biomass pyrolysis process still has many problems to be solved. One of the problems is the conversion and removal of tar. Tar is mainly produced when the molecular bonds of cellulose, lignin, hemicellulose and other components of biomass are broken. During the breaking process, small gaseous molecules such as CO , CO2, H2O , CH4 , and large molecules such as coke, pyroacetic acid, and tar are produced. The composition of tar is complex, containing hundreds of compounds of different types and properties. The main component is polynuclear aromatic components. Tar contains high concentrations of PAH substances. PAH substances are highly toxic. After the tar condensed into fine droplets is incompletely burned, PAH substances and coke will be produced. PAH substances are carcinogenic. If the tar is purified, the tar wastewater produced contains phenol and phenolic compounds, benzene series, heterocyclic rings, aromatic compounds and other organic matter. Its COD concentration is high and it also emits a strong irritating odor, which pollutes the environment and endangers human health.
发明内容Summary of the invention
针对现有技术存在的不足,本发明的目的是提供一种生物质热解炉及生物质热解系统和热解工艺,本发明提供了一种生物质热解炉,以及配合生物质热解炉使用的生物质热解系统,旨在通过生物质和焦油共同制备生物质碳,以及实现焦油的催化分解。In view of the deficiencies in the prior art, the purpose of the present invention is to provide a biomass pyrolysis furnace, a biomass pyrolysis system and a pyrolysis process. The present invention provides a biomass pyrolysis furnace, and a biomass pyrolysis system used in conjunction with the biomass pyrolysis furnace, aiming to prepare biomass carbon from biomass and tar, and to achieve catalytic decomposition of tar.
为解决上述技术问题,本发明采用如下技术方案:In order to solve the above technical problems, the present invention adopts the following technical solutions:
一种生物质热解炉,其特征在于,包括外壳体和供热体,所述供热体套设并连接于所述外壳体内,且二者之间预留有燃烧腔,所述燃烧腔内由隔板由上至下分隔为热解室和催化裂解室,所述催化裂解室上还贯通连接有热风机:A biomass pyrolysis furnace, characterized in that it comprises an outer shell and a heating body, the heating body is sleeved and connected in the outer shell, and a combustion chamber is reserved between the two, the combustion chamber is divided into a pyrolysis chamber and a catalytic cracking chamber from top to bottom by a partition, and a hot air blower is also connected to the catalytic cracking chamber:
所述供热体上开设有若干开口,所述开口上嵌设有若干稳焰体;The heating body is provided with a plurality of openings, and the openings are provided with a plurality of flame stabilizing bodies;
所述外壳体上设置有全预混风机,所述全预混风机分别与所述热解室和所述催化裂解室通过连通管贯通连接;The outer shell is provided with a full premixing fan, and the full premixing fan is respectively connected with the pyrolysis chamber and the catalytic cracking chamber through a connecting pipe;
所述供热体内设置有反应室,所述反应室由螺旋设置的燃烧管组成;所述燃烧管的顶端贯通设置有料仓,所述料仓上贯通连接有热氮气风管;所述燃烧管的底部贯通设置有接收仓;A reaction chamber is arranged in the heating body, and the reaction chamber is composed of a spirally arranged combustion tube; a material bin is arranged through the top of the combustion tube, and a hot nitrogen air duct is connected to the material bin; a receiving bin is arranged through the bottom of the combustion tube;
所述燃烧管上还贯通连接有供气管。The combustion tube is also connected with an air supply tube.
优选的,所述料仓上还通过物料提升机连接有用于存储颗粒生物质的缓冲仓。Preferably, the silo is also connected to a buffer silo for storing granular biomass via a material elevator.
优选的,所述燃烧管与所述接收仓之间设置有排料管,所述排料管上贯通连接有热解气排管,所述排料管上还设置有启闭组件,所述启闭组件包括舵机和旋板,所述舵机的输出轴横向贯穿所述排料管侧壁,并在端部与所述旋板固接,所述旋板转动至水平方向将所述排料管的内部阻断。Preferably, a discharge pipe is provided between the combustion pipe and the receiving bin, and a pyrolysis gas discharge pipe is connected through the discharge pipe. An opening and closing assembly is also provided on the discharge pipe, and the opening and closing assembly includes a servo and a rotary plate. The output shaft of the servo transversely passes through the side wall of the discharge pipe and is fixedly connected to the rotary plate at the end. The rotary plate rotates to a horizontal direction to block the interior of the discharge pipe.
优选的,所述热氮气风管、所述供气管和所述连通管上分别设置有阀门。Preferably, valves are respectively provided on the hot nitrogen duct, the air supply pipe and the connecting pipe.
本发明还提供了基于生物质热解炉的生物质热解系统,包括:The present invention also provides a biomass pyrolysis system based on a biomass pyrolysis furnace, comprising:
干燥粉碎设备,用于对生物质进行干燥粉碎处理;Drying and crushing equipment, used for drying and crushing biomass;
混合造粒设备,用于将焦油和生物质混合并造粒,所述混合造粒设备与所述缓冲仓贯通连接;A mixing and granulating device, used for mixing and granulating tar and biomass, wherein the mixing and granulating device is connected to the buffer bin;
生物质热解炉,用于进行生物质炭的制备;Biomass pyrolysis furnace, used for preparing biomass charcoal;
沉淀池,用于收集热解产生的焦油蒸汽、热解气及粉尘的混合物,所述沉淀池与所述热解气排管贯通连接;A sedimentation tank, used to collect a mixture of tar vapor, pyrolysis gas and dust generated by pyrolysis, wherein the sedimentation tank is in continuous connection with the pyrolysis gas exhaust pipe;
旋风分离机,用于离心分离气体和粉尘;Cyclone separators, used for centrifugal separation of gas and dust;
一级脱焦油塔,用于将焦油蒸汽与热解气进行一次分离;The primary detarring tower is used to separate the tar vapor from the pyrolysis gas;
二级脱焦油塔,用于将焦油蒸汽进行二次分离,所述一级脱焦油塔和所述二级脱焦油塔分别与所述混合造粒设备贯通连接;A secondary detarring tower, used for secondary separation of tar vapor, wherein the primary detarring tower and the secondary detarring tower are respectively connected to the mixing granulation equipment;
气酸分离塔,用于将热解气中的木醋液进行分离;A gas-acid separation tower is used to separate wood vinegar from the pyrolysis gas;
净化装置,用于对热解气进行净化处理,并得到可燃气体;A purification device, used for purifying the pyrolysis gas and obtaining combustible gas;
所述干燥粉碎设备、所述混合造粒设备、所述生物质热解炉、所述沉淀池、所述旋风分离机、所述一级脱焦油塔、所述二级脱焦油塔、所述气酸分离塔、所述净化装置依次贯通连接;The drying and crushing equipment, the mixing and granulating equipment, the biomass pyrolysis furnace, the sedimentation tank, the cyclone separator, the primary detarring tower, the secondary detarring tower, the gas-acid separation tower, and the purification device are sequentially connected;
所述一级脱焦油塔、所述二级脱焦油塔共同与所述混合造粒设备贯通连接。The primary detarring tower and the secondary detarring tower are connected to the mixing granulation equipment.
优选的,所述生物质热解炉、所述干燥粉碎设备还分别与所述净化装置贯通连接,所述净化装置分别与所述全预混风机、所述供气管贯通连接。Preferably, the biomass pyrolysis furnace and the drying and crushing equipment are also connected to the purification device respectively, and the purification device is connected to the full premix blower and the air supply pipe respectively.
本发明还保护了利用生物质热解系统进行生物质热解的工艺,包括如下步骤:The present invention also protects a process for pyrolyzing biomass using a biomass pyrolysis system, comprising the following steps:
步骤1、利用所述干燥粉碎设备对生物质进行干燥粉碎,粉碎的长度为2-4cm,干燥至生物质含水率10%以下;Step 1, using the drying and pulverizing equipment to dry and pulverize the biomass, the pulverized length is 2-4 cm, and the biomass is dried to a moisture content of less than 10%;
步骤2、利用所述混合造粒设备将焦油和生物质混合并造粒,得到待处理物,焦油和生物质的质量比为1:7-10;Step 2: using the mixing and granulating equipment to mix and granulate the tar and biomass to obtain a material to be processed, wherein the mass ratio of the tar to the biomass is 1:7-10;
步骤3、利用所述生物质热解炉进行生物质热解制备生物质炭,所述生物质碳制备的条件为于250-400℃下热解1-1.5h;Step 3, using the biomass pyrolysis furnace to pyrolyze biomass to prepare biochar, wherein the biochar is prepared under the conditions of pyrolysis at 250-400° C. for 1-1.5 h;
步骤4、利用所述沉淀池进行焦油蒸汽、热解气及粉尘的混合物收集;Step 4: using the sedimentation tank to collect the mixture of tar vapor, pyrolysis gas and dust;
步骤5、利用所述旋风分离机离心分离,得到气体和粉尘;Step 5, using the cyclone separator for centrifugal separation to obtain gas and dust;
步骤6、利用所述一级脱焦油塔进行焦油蒸汽的分离;Step 6, using the primary detarring tower to separate tar vapor;
步骤7、利用所述二级脱焦油塔进行焦油蒸汽的再次分离;Step 7, using the secondary detarring tower to separate the tar vapor again;
步骤8、利用所述气酸分离塔分离热解气中的木醋酸;Step 8, using the gas-acid separation tower to separate the pyrolysis gas from the wood acetic acid;
步骤9、利用所述净化装置对热解气进行净化、收集处理,得到可燃气体。Step 9: purify, collect and process the pyrolysis gas using the purification device to obtain combustible gas.
优选的,所述生物质热解的具体方法为:Preferably, the specific method of biomass pyrolysis is:
生物质采用所述干燥粉碎设备处理后,于所述混合造粒设备内实现焦油与生物质的共混,得到待处理物,待处理物于所述缓冲仓内储存,并在所述物料提升机的作用下进入至所述料仓内,待处理物在所述热氮气风管排出气体的带动下进入至所述燃烧管内,并于所述燃烧管进行生物质碳的制备,制得的生物质碳于所述接收仓内收集;燃烧产生的焦油蒸汽、热解气及粉尘的混合物经由所述热解气排管先排入至所述沉淀池内,再排入至所述旋风分离机器内进行除尘操作,然后将混合气排入至所述一级脱焦油塔内,进行焦油蒸汽的一次分离操作,剩余热解气排入至所述二级脱焦油塔内,进行焦油蒸汽的二次分离操作,将分离后剩余的热解气排入至所述气酸分离塔,实现木醋酸与热解气的分离,最终分离后的热解气于净化装置内处理,得到可燃气体;After the biomass is processed by the drying and crushing equipment, tar and biomass are blended in the mixing and granulating equipment to obtain a material to be processed. The material to be processed is stored in the buffer bin and enters the silo under the action of the material elevator. The material to be processed enters the combustion tube driven by the exhaust gas of the hot nitrogen air duct, and biomass carbon is prepared in the combustion tube. The prepared biomass carbon is collected in the receiving bin; the mixture of tar vapor, pyrolysis gas and dust generated by combustion is first discharged into the sedimentation tank through the pyrolysis gas exhaust pipe, and then discharged into the cyclone separation machine for dust removal operation, and then the mixed gas is discharged into the primary detarring tower to perform a primary separation operation of tar vapor, and the remaining pyrolysis gas is discharged into the secondary detarring tower to perform a secondary separation operation of tar vapor, and the remaining pyrolysis gas after separation is discharged into the gas-acid separation tower to separate wood acetic acid from pyrolysis gas, and the pyrolysis gas after final separation is treated in a purification device to obtain combustible gas;
所述一级脱焦油塔、所述二级脱焦油塔分离出的焦油再排入至所述混合造粒设备内,实现焦油的利用;The tar separated by the primary detarring tower and the secondary detarring tower is then discharged into the mixing granulation equipment to realize the utilization of the tar;
所述净化装置与所述干燥粉碎设备贯通连接,可燃气体向所述干燥粉碎设备提供热环境;The purification device is connected to the drying and crushing equipment, and the combustible gas provides a thermal environment for the drying and crushing equipment;
所述净化装置与所述生物质热解炉贯通连接,所述净化装置与所述生物质热解炉上的全预混风机贯通连接,实现空气与可燃气体混合,向所述稳焰体提供可燃气体;The purification device is connected to the biomass pyrolysis furnace, and the purification device is connected to the full premixing fan on the biomass pyrolysis furnace to achieve mixing of air and combustible gas and provide combustible gas to the flame stabilizing body;
所述净化装置还与所述生物质热解炉上的所述供气管贯通连接,实现焦油于所述燃烧管内的催化裂解。The purification device is also connected to the gas supply pipe on the biomass pyrolysis furnace to achieve catalytic cracking of tar in the combustion pipe.
与现有技术相比,本发明具有的有益效果是:Compared with the prior art, the present invention has the following beneficial effects:
1、本发明设置了生物质热解炉,生物质热解炉由隔板分隔为热解室和催化裂解室,热解室和催化裂解室能够共同用于生物质的热解反应,并实现待处理物的高温碳化,得到的生物质碳经由接收仓收集;热解完成后可单独使用催化裂解室时,催化裂解室提供的高温用于实现燃烧管内焦油的最终催化裂解,此时将焦油和催化剂于混合造粒设备内混合,然排入至燃烧管内,并使得催化剂与焦油滑落在催化裂解室处,此时经由混合气管向燃烧管内排入含有水分的混合气,混合气包括了热解气和空气,于750-900℃下实现焦油的单独高温裂解;1. The present invention provides a biomass pyrolysis furnace, which is divided into a pyrolysis chamber and a catalytic cracking chamber by a partition. The pyrolysis chamber and the catalytic cracking chamber can be used together for the pyrolysis reaction of biomass, and realize the high-temperature carbonization of the material to be treated, and the obtained biomass carbon is collected through a receiving bin; when the catalytic cracking chamber can be used alone after the pyrolysis is completed, the high temperature provided by the catalytic cracking chamber is used to realize the final catalytic cracking of the tar in the combustion tube, at which time the tar and the catalyst are mixed in the mixing granulation device, and then discharged into the combustion tube, and the catalyst and the tar are made to slide down at the catalytic cracking chamber, at which time a mixed gas containing water is discharged into the combustion tube through the mixed gas pipe, and the mixed gas includes pyrolysis gas and air, and the tar is cracked at 750-900°C at a high temperature;
通过使用本申请的生物质热解炉,不仅实现了生物质碳的制备,而且实现了焦油的催化裂解,所以有效降低了生物质燃烧产焦油的量。By using the biomass pyrolysis furnace of the present application, not only the preparation of biomass carbon is achieved, but also the catalytic cracking of tar is achieved, so the amount of tar produced by biomass combustion is effectively reduced.
2、本发明中还在燃烧管上分别贯通连接有热氮气风管和供气管,供气管可流通氮气或热解气,当供气管流通氮气时,燃烧管的顶端和底端分别通入氮气,通过调节两个氮气的供风量来实现对燃烧管内物料位置的调控,并使得待处理物处于悬浮状态,便于实现更加优异的碳化操作;当供气管流通热解气时,向燃烧管内提供可燃气体,此时便于焦油的高温催化裂解。2. In the present invention, a hot nitrogen duct and an air supply pipe are respectively connected to the combustion tube. The air supply pipe can flow nitrogen or pyrolysis gas. When nitrogen is circulated in the air supply pipe, nitrogen is introduced into the top and bottom ends of the combustion tube respectively. The position of the material in the combustion tube is regulated by adjusting the air supply volume of the two nitrogen gases, and the material to be treated is placed in a suspended state, which is convenient for achieving a better carbonization operation. When pyrolysis gas is circulated in the air supply pipe, combustible gas is provided into the combustion tube, which is convenient for high-temperature catalytic cracking of tar.
3、本发明的生物质碳制备方法为:将生物质与焦油混合、粉碎、造粒后,经由生物质热解炉进行热解操作,在无氧环境或低氧环境下实现生物质碳的制备;本发明的焦油裂解操作为:将焦油和催化剂混合,经由生物质热解炉进行催化裂解操作,在热解气、氧气和水的条件下实现焦油的催化裂解。3. The biomass carbon preparation method of the present invention is: after mixing, crushing and granulating the biomass and tar, the pyrolysis operation is carried out in a biomass pyrolysis furnace to realize the preparation of biomass carbon in an oxygen-free environment or a low-oxygen environment; the tar cracking operation of the present invention is: mixing the tar and the catalyst, carrying out a catalytic cracking operation in a biomass pyrolysis furnace, and realizing the catalytic cracking of the tar under the conditions of pyrolysis gas, oxygen and water.
4、本发明还设计了配合生物质热解炉使用的生物质热解系统,通过利用生物质热解系统实现热解气、木醋酸、焦油、生物质炭的分离,且实现了焦油和热解气的循环利用,多余的热解气经净化处理后,便于作为燃气进行二次利用。4. The present invention also designs a biomass pyrolysis system for use with a biomass pyrolysis furnace. The biomass pyrolysis system is used to separate pyrolysis gas, wood acetic acid, tar, and biochar, and to recycle tar and pyrolysis gas. Excess pyrolysis gas can be purified and reused as fuel gas for secondary use.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明一种利用生物质热解炉进行生物质热解的系统图;FIG1 is a system diagram of a biomass pyrolysis furnace for pyrolysis of biomass according to the present invention;
图2为本发明一种生物质热解炉的内部结构示意图。FIG. 2 is a schematic diagram of the internal structure of a biomass pyrolysis furnace of the present invention.
附图标记说明:Description of reference numerals:
1、外壳体;2、供热体;3、净化装置;4、隔板;5、热解室;6、催化裂解室;7、热风机;8、稳焰体;9、全预混风机;10、连通管;11、燃烧管;12、料仓;13、热氮气风管;14、接收仓;15、供气管;16、一级脱焦油塔;17、二级脱焦油塔;18、气酸分离塔;19、阀门;20、物料提升机;21、缓冲仓;22、排料管;23、气排管;24、舵机;25、旋板;26、干燥粉碎设备;27、混合造粒设备;28、沉淀池;29、旋风分离机。1. Outer shell; 2. Heating body; 3. Purification device; 4. Partition; 5. Pyrolysis chamber; 6. Catalytic cracking chamber; 7. Hot air blower; 8. Flame stabilizing body; 9. Full premixing fan; 10. Connecting pipe; 11. Combustion pipe; 12. Silo; 13. Hot nitrogen air duct; 14. Receiving bin; 15. Air supply pipe; 16. Primary detarring tower; 17. Secondary detarring tower; 18. Gas-acid separation tower; 19. Valve; 20. Material elevator; 21. Buffer bin; 22. Discharge pipe; 23. Gas discharge pipe; 24. Steering gear; 25. Rotary plate; 26. Drying and crushing equipment; 27. Mixing and granulating equipment; 28. Sedimentation tank; 29. Cyclone separator.
具体实施方式Detailed ways
下面对本发明的具体实施方式进行详细描述,但应当理解本发明的保护范围并不受具体实施方式的限制。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。本发明各实施例中实验方法,如无特殊说明,均为常规方法。The specific embodiments of the present invention are described in detail below, but it should be understood that the protection scope of the present invention is not limited by the specific embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work belong to the protection scope of the present invention. The experimental methods in the embodiments of the present invention are conventional methods unless otherwise specified.
利用生物质热解炉进行生物质热解的设备,如图1-2所示,包括:The equipment for pyrolyzing biomass using a biomass pyrolysis furnace, as shown in Figure 1-2, includes:
干燥粉碎设备26,用于对生物质进行干燥粉碎处理;Drying and crushing equipment 26, used for drying and crushing biomass;
混合造粒设备27,用于将焦油和生物质混合并造粒,所述混合造粒设备27与所述缓冲仓21贯通连接;A mixing and granulating device 27, used for mixing and granulating tar and biomass, wherein the mixing and granulating device 27 is connected to the buffer bin 21;
生物质热解炉,用于生物质热解制备生物质炭,所述生物质碳制备的条件为于250-400℃下热解1-1.5h;A biomass pyrolysis furnace, used for pyrolysis of biomass to prepare biochar, wherein the biochar is prepared under the conditions of pyrolysis at 250-400°C for 1-1.5h;
沉淀池28,用于收集热解产生的焦油蒸汽、热解气及粉尘的混合物,所述沉淀池28与所述热解气排管23贯通连接;A sedimentation tank 28 is used to collect a mixture of tar vapor, pyrolysis gas and dust generated by pyrolysis, and the sedimentation tank 28 is connected to the pyrolysis gas exhaust pipe 23;
旋风分离机29,用于离心分离气体和粉尘;A cyclone separator 29, for centrifugally separating gas and dust;
一级脱焦油塔16,用于将焦油蒸汽与热解气进行一次分离;The primary detarring tower 16 is used to separate the tar vapor from the pyrolysis gas;
二级脱焦油塔17,用于将焦油蒸汽进行二次分离,所述一级脱焦油塔16和所述二级脱焦油塔17分别与所述混合造粒设备27贯通连接;The secondary detarring tower 17 is used for secondary separation of tar vapor, and the primary detarring tower 16 and the secondary detarring tower 17 are respectively connected to the mixing granulation equipment 27;
气酸分离塔18,用于将热解气中的木醋液进行分离;A gas-acid separation tower 18 is used to separate wood vinegar from the pyrolysis gas;
净化装置3,用于对热解气进行净化处理,并得到可燃气体;Purification device 3, used for purifying the pyrolysis gas and obtaining combustible gas;
所述干燥粉碎设备26、所述混合造粒设备27、所述生物质热解炉、所述沉淀池28、所述旋风分离机29、所述一级脱焦油塔16、所述二级脱焦油塔17、所述气酸分离塔18、所述净化装置3依次贯通连接;The drying and crushing equipment 26, the mixing and granulating equipment 27, the biomass pyrolysis furnace, the sedimentation tank 28, the cyclone separator 29, the primary detarring tower 16, the secondary detarring tower 17, the gas-acid separation tower 18, and the purification device 3 are sequentially connected;
所述一级脱焦油塔16、所述二级脱焦油塔17共同与所述混合造粒设备27贯通连接;The primary detarring tower 16 and the secondary detarring tower 17 are connected to the mixing granulation equipment 27;
所述生物质热解炉、所述干燥粉碎设备26还分别与所述净化装置3贯通连接,所述净化装置3分别与所述全预混风机9、所述供气管15贯通连接。The biomass pyrolysis furnace and the drying and crushing equipment 26 are also connected to the purification device 3 respectively, and the purification device 3 is connected to the full premixing fan 9 and the air supply pipe 15 respectively.
所述生物质热解炉的结构如图2所示,包括外壳体1和供热体2,所述供热体2套设并连接于所述外壳体1内,且二者之间预留有燃烧腔,燃烧腔用于可燃气体的流通,便于所有稳焰体8上火焰均能够持续燃烧,所述燃烧腔内由隔板4由上至下分隔为热解室5和催化裂解室6,于热解室5和催化裂解室6内共同实现生物质的热解反应,并实现待处理物的高温碳化得到的生物质碳,单独使用催化裂解室时,催化裂解室提供的高温用于实现燃烧管内焦油的最终催化裂解,所述催化裂解室6上还贯通连接有热风机7,热风机7便于向热风机7内提供热风,提升催化裂解室6上稳焰体8燃烧的温度:The structure of the biomass pyrolysis furnace is shown in FIG2 , and includes an outer shell 1 and a heating body 2. The heating body 2 is sleeved and connected in the outer shell 1, and a combustion chamber is reserved between the two. The combustion chamber is used for the circulation of combustible gas, so that the flames on all flame stabilizing bodies 8 can burn continuously. The combustion chamber is divided from top to bottom into a pyrolysis chamber 5 and a catalytic cracking chamber 6 by a partition 4. The pyrolysis reaction of biomass is jointly realized in the pyrolysis chamber 5 and the catalytic cracking chamber 6, and the high-temperature carbonization of the material to be treated is realized to obtain biomass carbon. When the catalytic cracking chamber is used alone, the high temperature provided by the catalytic cracking chamber is used to realize the final catalytic cracking of tar in the combustion tube. The catalytic cracking chamber 6 is also connected with a hot air blower 7, which is convenient for providing hot air into the hot air blower 7 to increase the combustion temperature of the flame stabilizing body 8 in the catalytic cracking chamber 6:
所述供热体2上开设有若干开口,所述开口上嵌设有若干稳焰体8;The heating body 2 is provided with a plurality of openings, and a plurality of flame stabilizing bodies 8 are embedded in the openings;
所述外壳体1上设置有全预混风机9,全预混风机9实现空气与可燃气体的混合,排入至燃烧腔内,向稳焰体8上火焰提供燃烧气体,所述全预混风机9分别与所述热解室5和所述催化裂解室6通过连通管10贯通连接,连通管10上设置有阀门,阀门控制气体的流向,继而根据热解反应、催化裂解反应的要求进行调控;The outer shell 1 is provided with a full premixing fan 9, which realizes the mixing of air and combustible gas, discharges the mixture into the combustion chamber, and provides combustion gas to the flame on the flame stabilizing body 8. The full premixing fan 9 is respectively connected with the pyrolysis chamber 5 and the catalytic cracking chamber 6 through a connecting pipe 10. The connecting pipe 10 is provided with a valve, which controls the flow direction of the gas, and then regulates and controls according to the requirements of the pyrolysis reaction and the catalytic cracking reaction.
所述供热体2内设置有反应室,所述反应室由螺旋设置的燃烧管11组成;所述燃烧管11的顶端贯通设置有料仓12,所述料仓12上贯通连接有热氮气风管13;所述燃烧管11的底部贯通设置有接收仓;热氮气风管13排出热的氮气,经由热氮气将燃烧管11内的空气排出,并于燃烧管11内进行待处理物的热解制生物质碳操作;A reaction chamber is arranged in the heating body 2, and the reaction chamber is composed of a spirally arranged combustion tube 11; a silo 12 is arranged through the top of the combustion tube 11, and a hot nitrogen air duct 13 is connected to the silo 12; a receiving bin is arranged through the bottom of the combustion tube 11; the hot nitrogen air duct 13 discharges hot nitrogen, and the air in the combustion tube 11 is discharged through the hot nitrogen, and the pyrolysis of the object to be treated to produce biomass carbon is performed in the combustion tube 11;
所述燃烧管11上还贯通连接有供气管15,所述供气管15可通入热解气或氮气,当连接热解气,便于实现焦油的催化裂解;当连接氮气,便于对燃烧管11内待处理物的位置调控。The combustion tube 11 is also connected with an air supply tube 15, and the air supply tube 15 can be fed with pyrolysis gas or nitrogen. When connected with pyrolysis gas, it is convenient to realize catalytic cracking of tar; when connected with nitrogen, it is convenient to control the position of the object to be treated in the combustion tube 11.
本发明的实施例均依托于利用生物质热解炉进行生物质热解的设备,具体如下所示:The embodiments of the present invention all rely on a device for pyrolyzing biomass using a biomass pyrolysis furnace, which is specifically as follows:
实施例1Example 1
利用所述设备进行生物质热解的工艺,具体方法为:The process of using the equipment to perform biomass pyrolysis is specifically as follows:
生物质采用所述干燥粉碎设备26处理后,于所述混合造粒设备27内实现焦油与生物质的共混,得到待处理物,待处理物于所述缓冲仓21内储存,并在所述物料提升机20的作用下进入至所述料仓12内,待处理物在所述热氮气风管13排出气体的带动下进入至所述燃烧管11内,并于所述燃烧管11进行生物质碳的制备,制得的生物质碳于所述接收仓内收集;燃烧产生的焦油蒸汽、热解气及粉尘的混合物经由所述热解气排管23先排入至所述沉淀池28内,再排入至所述旋风分离机器29内进行除尘操作,然后将混合气排入至所述一级脱焦油塔16内,进行焦油蒸汽的一次分离操作,剩余热解气排入至所述二级脱焦油塔17内,进行焦油蒸汽的二次分离操作,将分离后剩余的热解气排入至所述气酸分离塔18,实现木醋酸与热解气的分离,最终分离后的热解气于净化装置内处理,得到可燃气体;After the biomass is processed by the drying and crushing equipment 26, the tar and the biomass are mixed in the mixing and granulating equipment 27 to obtain the material to be processed, which is stored in the buffer bin 21 and enters the silo 12 under the action of the material elevator 20. The material to be processed enters the combustion tube 11 driven by the exhaust gas of the hot nitrogen air duct 13, and the biomass carbon is prepared in the combustion tube 11. The prepared biomass carbon is collected in the receiving bin; the tar vapor, pyrolysis gas and dust generated by the combustion are collected. The mixture is first discharged into the sedimentation tank 28 through the pyrolysis gas discharge pipe 23, and then discharged into the cyclone separation machine 29 for dust removal operation, and then the mixed gas is discharged into the primary detarring tower 16 to perform a primary separation operation of tar vapor, and the remaining pyrolysis gas is discharged into the secondary detarring tower 17 to perform a secondary separation operation of tar vapor, and the remaining pyrolysis gas after separation is discharged into the gas-acid separation tower 18 to achieve separation of wood acetic acid and pyrolysis gas, and finally the separated pyrolysis gas is treated in a purification device to obtain combustible gas;
所述一级脱焦油塔16、所述二级脱焦油塔17分离出的焦油再排入至所述混合造粒设备27内,实现焦油的利用;The tar separated by the primary detarring tower 16 and the secondary detarring tower 17 is then discharged into the mixing granulation device 27 to realize the utilization of the tar;
所述净化装置3与所述干燥粉碎设备26贯通连接,可燃气体向所述干燥粉碎设备26提供热环境;The purification device 3 is connected to the drying and crushing equipment 26, and the combustible gas provides a thermal environment for the drying and crushing equipment 26;
所述净化装置3与所述生物质热解炉贯通连接,所述净化装置3与所述生物质热解炉上的全预混风机9贯通连接,实现空气与可燃气体混合,向所述稳焰体8提供可燃气体;The purification device 3 is connected to the biomass pyrolysis furnace, and the purification device 3 is connected to the full premixing fan 9 on the biomass pyrolysis furnace to achieve mixing of air and combustible gas and provide combustible gas to the flame stabilizing body 8;
所述供气管15内通入的是氮气,通过上下氮气的流量来调控待处理物于燃烧管11内的位置。Nitrogen is introduced into the gas supply pipe 15 , and the position of the object to be processed in the combustion tube 11 is regulated by adjusting the flow rate of the nitrogen gas up and down.
实施例2Example 2
利用所述设备进行焦油催化裂解的工艺,具体方法为:The process of using the equipment to carry out catalytic cracking of tar is specifically as follows:
于所述混合造粒设备27内实现焦油与催化剂的共混,得到待处理物I,待处理物I于所述缓冲仓21内储存,并在所述物料提升机20的作用下进入至所述料仓12内,待处理物I进入至所述燃烧管11内,并使得所述热风机7运行,控制所述燃烧管11的温度,并于750-900℃下进行焦油的催化裂解,催化剂于所述接收仓内收集;燃烧产生的热解气及粉尘的混合物经由所述热解气排管23先排入至所述沉淀池28内,再排入至所述旋风分离机器29内进行除尘操作,然后将混合气排入至所述一级脱焦油塔16内,进行焦油蒸汽的一次分离操作,剩余热解气排入至所述二级脱焦油塔17内,进行焦油蒸汽的二次分离操作,将分离后剩余的热解气排入至所述气酸分离塔18,实现木醋酸与热解气的分离,最终分离后的热解气于净化装置内处理,得到可燃气体;The tar and the catalyst are mixed in the mixing and granulating device 27 to obtain the material to be processed I, which is stored in the buffer bin 21 and enters the material bin 12 under the action of the material elevator 20. The material to be processed I enters the combustion tube 11, and the hot air blower 7 is operated to control the temperature of the combustion tube 11, and the catalytic cracking of the tar is carried out at 750-900°C, and the catalyst is collected in the receiving bin; the mixture of pyrolysis gas and dust generated by the combustion is passed through the hot air blower 7 to the combustion tube 11. The degassing pipe 23 is first discharged into the sedimentation tank 28, and then discharged into the cyclone separation machine 29 for dust removal operation, and then the mixed gas is discharged into the primary detarring tower 16 to perform a primary separation operation of tar vapor, and the remaining pyrolysis gas is discharged into the secondary detarring tower 17 to perform a secondary separation operation of tar vapor, and the remaining pyrolysis gas after separation is discharged into the gas-acid separation tower 18 to achieve the separation of wood acetic acid and pyrolysis gas, and finally the separated pyrolysis gas is treated in a purification device to obtain combustible gas;
所述一级脱焦油塔16、所述二级脱焦油塔17分离出的焦油再排入至所述混合造粒设备27内,实现焦油的利用;The tar separated by the primary detarring tower 16 and the secondary detarring tower 17 is then discharged into the mixing granulation device 27 to realize the utilization of the tar;
所述净化装置3与所述生物质热解炉贯通连接,所述净化装置3与所述生物质热解炉上的全预混风机9贯通连接,实现空气与可燃气体混合,向所述稳焰体8提供可燃气体;The purification device 3 is connected to the biomass pyrolysis furnace, and the purification device 3 is connected to the full premixing fan 9 on the biomass pyrolysis furnace to achieve mixing of air and combustible gas and provide combustible gas to the flame stabilizing body 8;
所述净化装置3还与所述生物质热解炉上的所述供气管15贯通连接,实现焦油于所述燃烧管11内的催化裂解,此时的供气管15内通入的是热解气、空气和水的混合物,便于焦油的裂解。The purification device 3 is also connected to the gas supply pipe 15 on the biomass pyrolysis furnace to achieve catalytic cracking of tar in the combustion pipe 11. At this time, a mixture of pyrolysis gas, air and water is introduced into the gas supply pipe 15 to facilitate the cracking of tar.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include these modifications and variations.
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