CN114531820A - Composite radiator and application thereof - Google Patents
Composite radiator and application thereof Download PDFInfo
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- CN114531820A CN114531820A CN202011321588.2A CN202011321588A CN114531820A CN 114531820 A CN114531820 A CN 114531820A CN 202011321588 A CN202011321588 A CN 202011321588A CN 114531820 A CN114531820 A CN 114531820A
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/02—Constructions of heat-exchange apparatus characterised by the selection of particular materials of carbon, e.g. graphite
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/367—Cooling facilitated by shape of device
- H01L23/3672—Foil-like cooling fins or heat sinks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0028—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for cooling heat generating elements, e.g. for cooling electronic components or electric devices
- F28D2021/0029—Heat sinks
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Abstract
Description
技术领域technical field
本发明涉及散热器件领域,特别涉及一种复合散热器及其应用。The invention relates to the field of radiator components, in particular to a composite radiator and its application.
背景技术Background technique
随高科技的蓬勃发展,电子元件的体积趋于微小化,而且单位面积上的密集度也愈来愈高,其效能不能增强,在这些因素之下,电子元件的总发热量则几乎逐年升高。为了确保电子元件的正常运行,需要安装散热器来进行散热,防止某些电子元件在高温工作中工作而缩短使用寿命。With the vigorous development of high technology, the volume of electronic components tends to be miniaturized, and the density per unit area is getting higher and higher, and its performance cannot be enhanced. Under these factors, the total calorific value of electronic components increases almost year by year. high. In order to ensure the normal operation of electronic components, it is necessary to install a radiator to dissipate heat to prevent some electronic components from working at high temperatures and shortening their service life.
现有技术中,散热器一般分为两个部分,即散热器的底板和散热鳍片,散热器的底板是与电子元件接触并聚集热量的地方,而散热鳍片则是热量传导的终点,最终将热量散失到空气中。这种结构的散热器的散热原理主要是依靠热传导的方式,因此需要较大表面积及较高的导热系数。散热器的性能不仅与散热器的结构相关,更决定于散热器的材质选择,散热器材质是指散热器本体所使用的具体材料。In the prior art, the heat sink is generally divided into two parts, namely the base plate of the heat sink and the heat dissipation fins. The base plate of the heat sink is the place where the heat is in contact with the electronic components and the heat is collected, and the heat dissipation fin is the end point of heat conduction. Eventually the heat is dissipated into the air. The heat dissipation principle of the radiator of this structure mainly relies on the way of heat conduction, so it needs a larger surface area and a higher thermal conductivity. The performance of the radiator is not only related to the structure of the radiator, but also depends on the material selection of the radiator. The radiator material refers to the specific material used in the body of the radiator.
目前常用的散热器材质主要有三类:(1)纯铝散热器:散热器的底板和散热鳍片均采用纯铝或6063合金来制造,这两种材质都有很好的导热性,然而工业可达到导热系数约为200W/m·K;(2)纯铜散热器:散热器的底板和散热鳍片均采用纯铜来制造,铜换热系数可达400W/m·K,可显著提升换热效率;(3)铜铝复合散热器:散热器的底板采用纯铜制造,散热鳍片采用铝合金制造。There are three main types of radiator materials commonly used at present: (1) Pure aluminum radiator: The bottom plate and fins of the radiator are made of pure aluminum or 6063 alloy, both of which have good thermal conductivity, but industrial The thermal conductivity can reach about 200W/m·K; (2) Pure copper radiator: the bottom plate and cooling fins of the radiator are made of pure copper, and the copper heat transfer coefficient can reach 400W/m·K, which can be significantly improved Heat exchange efficiency; (3) Copper-aluminum composite radiator: the bottom plate of the radiator is made of pure copper, and the heat dissipation fins are made of aluminum alloy.
但本申请的发明人在实现本申请实施例的过程中,发现上述技术至少存在如下技术问题:在发热量不断升高的电子元件上,纯铝散热器不能满足散热需求,且实现散热功能体积较大;纯铜散热器重量重,价格高,不利于推广应用;铜铝复合换热器铜底板与铝鳍片之间连接不好会产生很大接触热阻,影响散热效果。However, in the process of implementing the embodiments of the present application, the inventor of the present application found that the above-mentioned technology has at least the following technical problems: on the electronic components with continuously increasing calorific value, the pure aluminum radiator cannot meet the heat dissipation requirements, and the volume of the heat dissipation function can be realized. Large; pure copper radiator is heavy and expensive, which is not conducive to popularization and application; poor connection between the copper bottom plate and the aluminum fins of the copper-aluminum composite heat exchanger will cause a large contact thermal resistance and affect the heat dissipation effect.
因此,提供一种散热效果好,而且重量轻、热阻小、生产成本低的散热器已经成为本领域亟待解决的技术问题。Therefore, it has become an urgent technical problem to be solved in the art to provide a heat sink with good heat dissipation effect, light weight, low thermal resistance and low production cost.
发明内容SUMMARY OF THE INVENTION
本发明的主要目的是提出一种复合散热器及其应用,解决了现有技术中的散热器难以同时兼顾散热效果好、重量轻、热阻小、生产成本低的技术问题。The main purpose of the present invention is to propose a composite radiator and its application, which solves the technical problem that the radiator in the prior art is difficult to take into account good heat dissipation effect, light weight, low thermal resistance and low production cost at the same time.
为本发明所要解决的技术问题通过以下技术方案予以实现:The technical problem to be solved by the present invention is realized through the following technical solutions:
在本发明的一方面,本发明提供了一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板和散热鳍片均是由铝基复合材料制作而成的,所述铝基复合材料包括铝基体和石墨。In one aspect of the present invention, the present invention provides a composite heat sink, comprising a base plate and heat dissipation fins disposed on the base plate, wherein the base plate and the heat dissipation fins are both made of aluminum-based composite materials, The aluminum-based composite material includes an aluminum matrix and graphite.
可选地,所述铝基体为铝或铝合金;所述铝基体的原材料为铝基体粉末。Optionally, the aluminum matrix is aluminum or an aluminum alloy; the raw material of the aluminum matrix is aluminum matrix powder.
可选地,所述铝基体粉末的平均粒度为1-100μm。Optionally, the average particle size of the aluminum matrix powder is 1-100 μm.
可选地,所述铝基体粉末采用气体雾化法制备而成。Optionally, the aluminum matrix powder is prepared by a gas atomization method.
可选地,所述铝基体粉末表面氧化膜的厚度小于4nm。Optionally, the thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
可选地,所述石墨表面覆盖有镀层,所述镀层的材料为硅材料或金属材料;所述镀层的厚度为100-200μm。Optionally, the graphite surface is covered with a plating layer, and the material of the plating layer is silicon material or metal material; the thickness of the plating layer is 100-200 μm.
可选地,所述石墨为片状石墨。Optionally, the graphite is flake graphite.
可选地,所述片状石墨的直径为150-1000μm,厚度为10-50μm。Optionally, the diameter of the flake graphite is 150-1000 μm, and the thickness is 10-50 μm.
可选地,所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。Optionally, the flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fin is parallel to the direction of the flake graphite flowing through the heat dissipation fin. The heat flow directions of the sheets are parallel.
可选地,所述铝基复合材料的制备方法,包括如下步骤:Optionally, the preparation method of the aluminum matrix composite material includes the following steps:
提供铝基体粉末;Provide aluminum matrix powder;
将所述铝基体粉末与石墨混合均匀,得到混合物;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
可选地,所述混合物中,所述石墨的体积分数为20-75vol%,其余为铝基体粉末。Optionally, in the mixture, the volume fraction of the graphite is 20-75 vol%, and the rest is aluminum matrix powder.
可选地,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。Optionally, a groove is formed on one side of the bottom plate, and one end of the heat dissipation fin is embedded in the groove and connected to the bottom plate by welding.
在本发明的又一方面,本发明提供了上述复合散热器在高功率发热电子设备中的应用。In yet another aspect of the present invention, the present invention provides the application of the above-mentioned composite heat sink in a high-power heat-generating electronic device.
本发明具有如下有益效果:The present invention has the following beneficial effects:
本发明提供的复合散热器由铝基复合材料制作而成,所述铝基复合材料由铝基体和石墨复合而成,所得的散热器面内导热系数可达300W/m·K,密度低于2.5g/cm3,可以同时兼顾散热效果好、重量轻、热阻小、生产成本低。The composite radiator provided by the invention is made of an aluminum-based composite material, and the aluminum-based composite material is composed of an aluminum matrix and graphite. 2.5g/cm 3 , which can take into account good heat dissipation effect, light weight, low thermal resistance and low production cost at the same time.
石墨与铝基体二者密度相差非常大,石墨与铝基体界面润湿性差,导致石墨不能很好分散于铝基体中,石墨与铝基体相容性差;此外石墨与铝基体界面反应难以控制,易形成界面金属间化合物,在界面处产生较大的热阻,致使石墨的高导热性能无法充分发挥,影响导热效果。为了解决上述问题,本发明中,通过控制述铝基体粉末表面氧化膜的厚度小于4nm,以及在所述石墨表面覆盖镀层,相互配合,可以改善石墨与铝基体之间润湿性,增强石墨与铝基体之间的相容性,防止了碳铝间的不良界面反应,降低界面热阻,进而提高铝基复合材料的导热系数。The density difference between the graphite and the aluminum matrix is very large, and the interface between the graphite and the aluminum matrix has poor wettability, so that the graphite cannot be well dispersed in the aluminum matrix, and the compatibility between the graphite and the aluminum matrix is poor; The formation of intermetallic compounds at the interface produces a large thermal resistance at the interface, so that the high thermal conductivity of graphite cannot be fully exerted, and the thermal conductivity effect is affected. In order to solve the above problems, in the present invention, by controlling the thickness of the oxide film on the surface of the aluminum matrix powder to be less than 4 nm, and covering the graphite surface with a coating layer, the wettability between the graphite and the aluminum matrix can be improved, and the graphite and the aluminum matrix can be enhanced. The compatibility between the aluminum matrix prevents the adverse interface reaction between carbon and aluminum, reduces the interface thermal resistance, and further improves the thermal conductivity of the aluminum matrix composite material.
人工合成的片状石墨,沿片状平面方向上导热系数可达1200-1800W/m·K,已成功实现量产。但片状石墨在垂直该片状平面方向上的导热系数极低,仅为10-20W/m·K,极大的影响散热效果。为了解决上述问题,本发明中,所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。本发明通过控制底板和散热鳍片中片状石墨的取向,使得片状石墨的取向方向与热流方向一致,可以充分利用片状石墨平面方向导热系数高的特性,形成良好的散热效果。The artificially synthesized flake graphite has a thermal conductivity of 1200-1800W/m·K along the flake plane, and has been successfully mass-produced. However, the thermal conductivity of flake graphite in the direction perpendicular to the flake plane is extremely low, only 10-20W/m·K, which greatly affects the heat dissipation effect. In order to solve the above problems, in the present invention, the sheet-like plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; The direction of heat flow through the heat dissipation fins is parallel. The invention controls the orientation of the flake graphite in the bottom plate and the heat dissipation fins, so that the orientation direction of the flake graphite is consistent with the heat flow direction, and can make full use of the high thermal conductivity of the flake graphite in the plane direction to form a good heat dissipation effect.
本发明的复合散热器能应用在各类电子元器件上,可以提高对电子元件的散热效率,提高电子元件的可靠性,有利于延长电子元件的使用寿命。The composite radiator of the invention can be applied to various electronic components, can improve the heat dissipation efficiency of the electronic components, improve the reliability of the electronic components, and is beneficial to prolong the service life of the electronic components.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图示出的结构获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments of the present invention, and for those of ordinary skill in the art, other drawings can also be obtained according to the structures shown in these drawings without creative efforts.
图1为本发明实施例1的复合散热器的结构示意图;1 is a schematic structural diagram of a composite heat sink according to
图2为本发明实施例3的复合散热器的结构示意图。FIG. 2 is a schematic structural diagram of a composite heat sink according to
附图标号说明:Description of reference numbers:
具体实施方式Detailed ways
本发明中所用原料、设备,若无特别说明,均为本领域的常用原料、设备;本发明中所用方法,若无特别说明,均为本领域的常规方法。The raw materials and equipment used in the present invention, unless otherwise specified, are the common raw materials and equipment in the art; the methods used in the present invention, unless otherwise specified, are the conventional methods in the art.
如无特殊说明,本说明书中的术语的含义与本领域技术人员一般理解的含义相同,但如有冲突,则以本说明书中的定义为准。Unless otherwise specified, the meanings of the terms in this specification are the same as those generally understood by those skilled in the art, but in case of conflict, the definitions in this specification shall prevail.
本文中“包括”、“包含”、“含”、“含有”、“具有”或其它变体意在涵盖非封闭式包括,这些术语之间不作区分。术语“包含”是指可加入不影响最终结果的其它步骤和成分。术语“包含”还包括术语“由…组成”和“基本上由…组成”。本发明的组合物和方法/工艺包含、由其组成和基本上由本文描述的必要元素和限制项以及本文描述的任一的附加的或任选的成分、组分、步骤或限制项组成。"Comprising," "comprising," "including," "containing," "having," or other variations herein are intended to encompass non-closed includes, and no distinction is made between these terms. The term "comprising" means that other steps and ingredients may be added that do not affect the final result. The term "comprising" also includes the terms "consisting of" and "consisting essentially of." The compositions and methods/processes of the present invention comprise, consist of, and consist essentially of the essential elements and limitations described herein and any additional or optional ingredients, components, steps or limitations described herein.
在说明书和权利要求书中使用的涉及组分量、工艺条件等的所有数值或表述在所有情形中均应理解被“约”修饰。涉及相同组分或性质的所有范围均包括端点,该端点可独立地组合。由于这些范围是连续的,因此它们包括在最小值与最大值之间的每一数值。还应理解的是,本申请引用的任何数值范围预期包括该范围内的所有子范围。All numerical values or expressions used in the specification and claims referring to component amounts, process conditions, etc., should be understood to be modified by "about" in all instances. All ranges referring to the same component or property are inclusive of the endpoints, which endpoints are independently combinable. Since these ranges are continuous, they include every value between the minimum and maximum values. It is also to be understood that any numerical range recited herein is intended to include all subranges within that range.
正如背景技术所描述的,现有技术中存在散热器难以同时兼顾散热效果好、重量轻、热阻小、生产成本低的技术问题。为了解决上述技术问题,本发明提供了一种复合散热器及其应用。As described in the background art, there are technical problems in the prior art that the heat sink is difficult to take into account good heat dissipation effect, light weight, low thermal resistance and low production cost at the same time. In order to solve the above technical problems, the present invention provides a composite heat sink and its application.
第一方面,一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板和散热鳍片均是由铝基复合材料制作而成的,所述铝基复合材料包括铝基体和石墨。In a first aspect, a composite heat sink includes a base plate and heat dissipation fins disposed on the base plate, wherein the base plate and the heat dissipation fins are both made of an aluminum-based composite material, and the aluminum-based composite material includes Aluminum matrix and graphite.
本发明中,所述铝基体为铝或铝合金。对于铝合金,本发明对其具体组成不作特别限定,作为优选,所述铝合金为3003或6063。In the present invention, the aluminum substrate is aluminum or aluminum alloy. For the aluminum alloy, the specific composition of the aluminum alloy is not particularly limited in the present invention. Preferably, the aluminum alloy is 3003 or 6063.
铝基复合材料中的铝基体,一方面作为导热基体,另一方面起着粘结及固定石墨的作用。铝基体作为传统的导热材料,具有良好的导热系数和较高的强度,将之与高导热的石墨复合,可进一步提高铝基复合材料的导热系数。The aluminum matrix in the aluminum matrix composite material acts as a thermal conductive matrix on the one hand, and plays the role of bonding and fixing graphite on the other hand. As a traditional thermal conductive material, aluminum matrix has good thermal conductivity and high strength. Combining it with graphite with high thermal conductivity can further improve the thermal conductivity of aluminum matrix composites.
本发明的复合散热器无需使用风扇强制对流,而可通过空气自然对流方式散热,因此具有无噪音,无灰尘等特点。The composite radiator of the present invention does not require forced convection by a fan, but can dissipate heat through natural convection, so it has the characteristics of no noise and no dust.
本发明的复合散热器的面内导热系数可达300W/m·K,能应用在各类电子元器件上,可以提高对电子元件的散热效率,提高电子元件的可靠性,有利于延长电子元件的使用寿命。The in-plane thermal conductivity of the composite radiator of the invention can reach 300W/m·K, can be applied to various electronic components, can improve the heat dissipation efficiency of the electronic components, improve the reliability of the electronic components, and is conducive to extending the electronic components. service life.
本发明中,所述铝基体的原材料为铝基体粉末。In the present invention, the raw material of the aluminum matrix is aluminum matrix powder.
本发明中,所述铝基体粉末的平均粒度为1-100μm,例如1μm、3μm、5μm、8μm、10μm、20μm、30μm、40μm、50μm、60μm、70μm、80μm、90μm、100μm以及它们之间的任意值。In the present invention, the average particle size of the aluminum matrix powder is 1-100 μm, such as 1 μm, 3 μm, 5 μm, 8 μm, 10 μm, 20 μm, 30 μm, 40 μm, 50 μm, 60 μm, 70 μm, 80 μm, 90 μm, 100 μm and the range between them. any value.
本发明中,所述铝基体粉末采用气体雾化法制备而成。In the present invention, the aluminum matrix powder is prepared by a gas atomization method.
本发明对所述气体雾化法制备铝基体粉末的具体工艺过程和条件没有特别限制,以本领域技术人员熟知的气体雾化法的常规上述处理过程即可,本领域技术人员可以根据实际生产情况、产品要求及质量要求进行选择和调整。作为优选,所述铝基体粉末的制备方法为:采用高压气体作为雾化介质来破碎熔融铝基体细流,获得铝基体粉末,所述铝基体粉末为光滑圆球形,冷却速度为100℃/s,其中,所述高压气体包括纯度99.9%以上的氮气和氧气,其中所述氧气的体积含量为0.05-1.5%。The present invention has no particular limitations on the specific process and conditions for preparing the aluminum matrix powder by the gas atomization method. Select and adjust according to the situation, product requirements and quality requirements. Preferably, the preparation method of the aluminum matrix powder is as follows: using high-pressure gas as an atomization medium to break the molten aluminum matrix fine flow to obtain the aluminum matrix powder, the aluminum matrix powder is smooth and spherical, and the cooling rate is 100 ℃/s , wherein the high-pressure gas includes nitrogen and oxygen with a purity of more than 99.9%, wherein the volume content of the oxygen is 0.05-1.5%.
本发明中,所述铝基体粉末表面氧化膜的厚度小于4nm。由此可以避免影响烧结效果而产生微小孔洞降低换热性能及强度。In the present invention, the thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm. In this way, it can avoid the generation of tiny pores that affect the sintering effect and reduce the heat transfer performance and strength.
本发明中,所述石墨表面覆盖有镀层。由此,可以降低两相之间表面能,降低孔隙率,避免在加热熔炼过程生成Al-C化合物而产生热阻降低导热效果。In the present invention, the surface of the graphite is covered with a plating layer. In this way, the surface energy between the two phases can be reduced, the porosity can be reduced, and the Al-C compound generated during the heating and smelting process can be avoided to generate thermal resistance and reduce thermal conductivity.
本发明中,对所述镀层的材料不作特别限定,只要能实现上述功能即可,作为优选,所述镀层的材料为硅材料或金属材料,更优选地,所述镀层的材料为硅。In the present invention, the material of the plating layer is not particularly limited, as long as the above functions can be achieved. Preferably, the material of the plating layer is silicon material or metal material, more preferably, the material of the plating layer is silicon.
本发明中,所述镀层的厚度为100-200μm,例如100μm、110μm、120μm、130μm、140μm、150μm、160μm、170μm、180μm、190μm、200μm以及它们之间的任意值。In the present invention, the thickness of the plating layer is 100-200 μm, such as 100 μm, 110 μm, 120 μm, 130 μm, 140 μm, 150 μm, 160 μm, 170 μm, 180 μm, 190 μm, 200 μm and any value therebetween.
本发明中,所述石墨表面覆盖有镀层的制备方法没有特别限制,以本领域技术人员熟知的镀层的常规制备过程即可,本领域技术人员可以根据实际生产情况、产品要求及质量要求进行选择和调整。以石墨表面覆盖有硅层为例,其制备方法为:将清洗干燥后的石墨同无水氯化钙粉末、硅粉体混合均匀后放置在坩埚中,然后在真空碳管炉中加热,按照设定好的升温程序升温到1200℃,保温2小时,等待碳管炉升温保温程序完成后,炉体自然冷却到室温后,将共混粉体取出;用热水清洗所述共混粉体,溶解氯化钙;其中,石墨与无水氯化钙粉末的质量比为1:1,所述石墨与硅粉体的质量比为6-8:1,所述硅粉体的直径在20μm以内。In the present invention, the preparation method of the graphite surface covered with the coating is not particularly limited, and the conventional preparation process of the coating well known to those skilled in the art can be used, and those skilled in the art can select according to the actual production situation, product requirements and quality requirements and adjustment. Taking the graphite surface covered with a silicon layer as an example, the preparation method is as follows: the cleaned and dried graphite is evenly mixed with anhydrous calcium chloride powder and silicon powder, and then placed in a crucible, and then heated in a vacuum carbon tube furnace. The set heating program is heated to 1200°C, and kept for 2 hours. After the heating and heating program of the carbon tube furnace is completed, the furnace body is naturally cooled to room temperature, and then the blended powder is taken out; the blended powder is washed with hot water. , dissolve calcium chloride; wherein, the mass ratio of graphite and anhydrous calcium chloride powder is 1:1, the mass ratio of graphite and silicon powder is 6-8:1, and the diameter of the silicon powder is 20 μm within.
发明人在实践中发现,石墨与铝基体二者密度相差非常大,石墨与铝基体界面润湿性差,导致石墨不能很好分散于铝基体中,石墨与铝基体相容性差;此外石墨与铝基体界面反应难以控制,易形成界面金属间化合物,在界面处产生较大的热阻,致使石墨的高导热性能无法充分发挥,影响导热效果。为了解决上述问题,本发明中,通过控制述铝基体粉末表面氧化膜的厚度小于4nm,以及在所述石墨表面覆盖镀层,相互配合,可以改善石墨与铝基体之间润湿性,增强石墨与铝基体之间的相容性,防止了碳铝间的不良界面反应,降低界面热阻,进而提高铝基复合材料的导热系数。In practice, the inventor found that the density difference between graphite and aluminum matrix is very large, and the interface between graphite and aluminum matrix has poor wettability, resulting in graphite not being well dispersed in aluminum matrix, and poor compatibility between graphite and aluminum matrix; in addition, graphite and aluminum matrix have poor compatibility. The interface reaction of the matrix is difficult to control, and it is easy to form interfacial intermetallic compounds, resulting in a large thermal resistance at the interface, so that the high thermal conductivity of graphite cannot be fully exerted, and the thermal conductivity effect is affected. In order to solve the above problems, in the present invention, by controlling the thickness of the oxide film on the surface of the aluminum matrix powder to be less than 4 nm, and covering the graphite surface with a coating layer, the wettability between the graphite and the aluminum matrix can be improved, and the graphite and the aluminum matrix can be enhanced. The compatibility between the aluminum matrix prevents the adverse interface reaction between carbon and aluminum, reduces the interface thermal resistance, and further improves the thermal conductivity of the aluminum matrix composite material.
石墨的形态可分为四大类,即片状石墨、球状石墨、蠕虫状石墨和团絮状石墨。本发明中,所述石墨优选为片状石墨。其中,所述片状石墨的直径为150-1000μm,厚度为10-50μm。The morphology of graphite can be divided into four categories, namely flake graphite, spherical graphite, vermicular graphite and flocculent graphite. In the present invention, the graphite is preferably flake graphite. Wherein, the diameter of the flake graphite is 150-1000 μm, and the thickness is 10-50 μm.
本发明中,所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。In the present invention, the flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the direction of the flake graphite flowing through the heat dissipation fins The heat flow directions of the sheets are parallel.
需要说明的是,在本发明中,电子元件与底板接触,电子元件设于底板中心,热流路径为:电子元件产生的热流通过底板向电子元件左右两侧传导,底板再将热流传导至散热鳍片上散热。It should be noted that, in the present invention, the electronic components are in contact with the bottom plate, and the electronic components are arranged in the center of the bottom plate. On-chip heat dissipation.
石墨,作为一种国内资源丰富、成本低廉的材料,石墨是碳的一种同素异形体,属于六方晶系,片层内每个碳原子与另外三个碳原子以共价键连接,呈蜂巢式的多个六边形排列,片层间以范德华力连接,使其表现出很多性能的各向异性。同时,石墨还具有轻质(密度~2.26g·cm-3)、良好的耐高温、耐热冲击、抗腐蚀性能。人工合成的片状石墨,沿片状平面方向上导热系数可达1200-1800W/m·K,已成功实现量产。但片状石墨在垂直该片状平面方向上的导热系数极低,仅为10-20W/m·K,极大的影响散热效果。为了解决上述问题,本发明中,所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。本发明通过控制底板和散热鳍片中片状石墨的取向,使得片状石墨的取向方向与热流方向一致,可以充分利用片状石墨平面方向导热系数高的特性,形成良好的散热效果。Graphite, as a material with abundant domestic resources and low cost, is an allotrope of carbon and belongs to the hexagonal crystal system. Each carbon atom in the lamella is connected with three other carbon atoms by covalent bonds. The honeycomb-like arrangement of multiple hexagons is connected by van der Waals force between the sheets, which makes it exhibit a lot of anisotropy of properties. At the same time, graphite also has light weight (density ~ 2.26g·cm-3), good high temperature resistance, thermal shock resistance, and corrosion resistance. The artificially synthesized flake graphite has a thermal conductivity of 1200-1800W/m·K along the flake plane, and has been successfully mass-produced. However, the thermal conductivity of flake graphite in the direction perpendicular to the flake plane is extremely low, only 10-20W/m·K, which greatly affects the heat dissipation effect. In order to solve the above problems, in the present invention, the sheet-like plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; The direction of heat flow through the heat dissipation fins is parallel. The invention controls the orientation of the flake graphite in the bottom plate and the heat dissipation fins, so that the orientation direction of the flake graphite is consistent with the heat flow direction, and can make full use of the high thermal conductivity of the flake graphite in the plane direction to form a good heat dissipation effect.
本发明中,所述铝基复合材料的制备方法,包括如下步骤:In the present invention, the preparation method of the aluminum-based composite material includes the following steps:
提供铝基体粉末;Provide aluminum matrix powder;
将所述铝基体粉末与石墨混合均匀,得到混合物;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述混合物中,所述石墨的体积分数为20-75vol%,例如为20vol%、25vol%、32vol%、48vol%、50vol%、55vol%、60vol%、65vol%、70vol%、75vol%,其余为铝基体粉末。Wherein, in the mixture, the volume fraction of the graphite is 20-75vol%, such as 20vol%, 25vol%, 32vol%, 48vol%, 50vol%, 55vol%, 60vol%, 65vol%, 70vol%, 75vol% , and the rest are aluminum matrix powder.
本发明的铝基复合材料的制备中,将所述混合物装入模具中进行反复的震荡,保证石墨取向的一致性,同时采用了真空热压法粉末冶金工艺,石墨实现沿平行于热流方向取向,实现了石墨的定向排列,具有高取向性,实现热量在指定方向上的高效传导。In the preparation of the aluminum-based composite material of the present invention, the mixture is loaded into a mold for repeated oscillations to ensure the consistency of graphite orientation, and a vacuum hot pressing powder metallurgy process is adopted at the same time, and the graphite is oriented parallel to the direction of heat flow. , realizes the directional arrangement of graphite, has high orientation, and realizes the efficient conduction of heat in the specified direction.
本发明中铝基复合材料的制备中,整个过程步骤少、操作简单,便于产业化生产;本发明不引入任何化学试剂以及有毒、有污染的气体,具有环境友好的优势。In the preparation of the aluminum-based composite material in the present invention, the whole process has few steps, simple operation, and is convenient for industrial production; the present invention does not introduce any chemical reagents and toxic and polluting gases, and has the advantage of being environmentally friendly.
本发明的散热器中,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。In the heat sink of the present invention, a groove is formed on one side of the bottom plate, and one end of the heat dissipation fin is embedded in the groove and connected to the bottom plate by welding.
本发明中,对所述散热鳍片的形状不作特别限定,所述散热鳍片的纵向截面可以是长方形、梯形、三角形。作为优选,所述所述散热鳍片的纵向截面可以是长方形。In the present invention, the shape of the heat dissipation fin is not particularly limited, and the longitudinal section of the heat dissipation fin may be a rectangle, a trapezoid, or a triangle. Preferably, the longitudinal section of the heat dissipation fins may be rectangular.
本发明中,所述散热鳍片的数量为多个,所述散热鳍片之间设有间隙,如此,既不浪费所述底板的表面积,且能够保证所述散热鳍片与较低温的空气接触,保证所述散热鳍片具有较好的散热能力。In the present invention, the number of the heat dissipation fins is multiple, and there are gaps between the heat dissipation fins. In this way, the surface area of the bottom plate is not wasted, and the heat dissipation fins and the lower temperature air can be ensured. contact to ensure that the heat dissipation fins have better heat dissipation capacity.
为了更好的理解上述技术方案,下面将结合具体的实施例对上述技术方案进行详细的说明,实施例仅是本发明的优选实施方式,不是对本发明的限定。In order to better understand the above technical solutions, the above technical solutions will be described in detail below with reference to specific examples, which are only preferred embodiments of the present invention, and are not intended to limit the present invention.
实施例1Example 1
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite heat sink comprises a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为20vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 20 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为5μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 5 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述铝基体粉末表面氧化膜的厚度小于4nm。The thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
所述石墨为片状石墨;所述片状石墨的直径为200μm,厚度为20μm。The graphite is flake graphite; the flake graphite has a diameter of 200 μm and a thickness of 20 μm.
所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。The flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the heat flow direction flowing through the heat dissipation fins parallel.
实施例2Example 2
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite heat sink comprises a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为20vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 20 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为5μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 5 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述石墨表面覆盖有镀层,所述镀层的材料为硅;所述镀层的厚度为150μm。The surface of the graphite is covered with a plating layer, and the material of the plating layer is silicon; the thickness of the plating layer is 150 μm.
所述铝基体粉末表面氧化膜的厚度大于4nm。The thickness of the oxide film on the surface of the aluminum base powder is greater than 4 nm.
所述石墨为片状石墨;所述片状石墨的直径为200μm,厚度为20μm。The graphite is flake graphite; the flake graphite has a diameter of 200 μm and a thickness of 20 μm.
所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。The flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the heat flow direction flowing through the heat dissipation fins parallel.
实施例3Example 3
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite heat sink comprises a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为20vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 20 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为5μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 5 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述石墨表面覆盖有镀层,所述镀层的材料为硅;所述镀层的厚度为150μm。The surface of the graphite is covered with a plating layer, and the material of the plating layer is silicon; the thickness of the plating layer is 150 μm.
所述铝基体粉末表面氧化膜的厚度小于4nm。The thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
所述石墨为片状石墨;所述片状石墨的直径为200μm,厚度为20μm。The graphite is flake graphite; the flake graphite has a diameter of 200 μm and a thickness of 20 μm.
实施例4Example 4
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite heat sink comprises a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为32vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 32 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为20μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 20 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述铝基体粉末表面氧化膜的厚度小于4nm。The thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
所述石墨表面覆盖有镀层,所述镀层的材料为硅;所述镀层的厚度为150μm。The graphite surface is covered with a plating layer, and the material of the plating layer is silicon; the thickness of the plating layer is 150 μm.
所述石墨为片状石墨;所述片状石墨的直径为500μm,厚度为10μm。The graphite is flake graphite; the flake graphite has a diameter of 500 μm and a thickness of 10 μm.
所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。The flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the heat flow direction flowing through the heat dissipation fins parallel.
实施例5Example 5
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite radiator, comprising a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为48vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 48 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为100μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 100 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述铝基体粉末表面氧化膜的厚度小于4nm。The thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
所述石墨表面覆盖有镀层,所述镀层的材料为碳化硅;所述镀层的厚度为100μm。The surface of the graphite is covered with a plating layer, and the material of the plating layer is silicon carbide; the thickness of the plating layer is 100 μm.
所述石墨为片状石墨;述片状石墨的直径为1000μm,厚度为50μm。The graphite is flake graphite; the flake graphite has a diameter of 1000 μm and a thickness of 50 μm.
所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。The flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the heat flow direction flowing through the heat dissipation fins parallel.
实施例6Example 6
一种复合散热器,包括底板和设置于所述底板上的散热鳍片,所述底板一侧开有凹槽,所述散热鳍片的一端嵌入所述凹槽内并与所述底板焊接连接。A composite radiator, comprising a base plate and a heat dissipation fin arranged on the base plate, a groove is formed on one side of the base plate, and one end of the heat dissipation fin is embedded in the groove and connected to the base plate by welding .
所述底板和散热鳍片均是由铝基复合材料制作而成的。The bottom plate and the heat dissipation fins are all made of aluminum-based composite materials.
所述铝基复合材料的制备方法,包括如下步骤:The preparation method of the aluminum matrix composite material comprises the following steps:
提供铝基体粉末;其中,所述铝基体为铝合金3003;Provide aluminum matrix powder; wherein, the aluminum matrix is aluminum alloy 3003;
将所述铝基体粉末与石墨混合均匀,得到混合物;其中,所述混合物中,所述石墨的体积分数为75vol%,其余为铝基体粉末;Mixing the aluminum matrix powder and graphite uniformly to obtain a mixture; wherein, in the mixture, the volume fraction of the graphite is 75 vol%, and the rest is the aluminum matrix powder;
将所述混合物装入模具中进行反复的震荡;The mixture is loaded into a mold for repeated shaking;
将震荡后的装有所述混合物的模具放入真空热压炉中,首先抽真空至10-3Pa以下,然后逐步加热待温度升到800℃,开始给所述模具慢慢施加压力,直到达到40MPa的压力,保压10-30min,冷却,脱模。Put the shaken mold containing the mixture into a vacuum hot-pressing furnace, first vacuumize to below 10 -3 Pa, then gradually heat until the temperature rises to 800°C, and slowly apply pressure to the mold until Reach the pressure of 40MPa, keep the pressure for 10-30min, cool and demould.
其中,所述铝基体粉末的平均粒度为1μm;所述铝基体粉末采用气体雾化法制备而成。Wherein, the average particle size of the aluminum matrix powder is 1 μm; the aluminum matrix powder is prepared by a gas atomization method.
所述铝基体粉末表面氧化膜的厚度小于4nm。The thickness of the oxide film on the surface of the aluminum base powder is less than 4 nm.
所述石墨表面覆盖有镀层,所述镀层的材料为硅材料或金属材料;所述镀层的厚度为200μm。The graphite surface is covered with a plating layer, and the material of the plating layer is silicon material or metal material; the thickness of the plating layer is 200 μm.
所述石墨为片状石墨;所述片状石墨的直径为150μm,厚度为30μm。The graphite is flake graphite; the flake graphite has a diameter of 150 μm and a thickness of 30 μm.
所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。The flake plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; the flake plane direction of the flake graphite in the heat dissipation fins is parallel to the heat flow direction flowing through the heat dissipation fins parallel.
对比例1Comparative Example 1
基于实施例1,不同之处仅在于,所述底板和散热鳍片均是由铝合金3003制作而成的。Based on
测试例test case
为验证本发明产品性能,对实施例1-6和对比例1所制得散热器的导热系数分别进行了相关测试,具体结果如下:In order to verify the performance of the product of the present invention, the thermal conductivity of the radiators prepared in Examples 1-6 and Comparative Example 1 were tested respectively, and the specific results are as follows:
通过上述测试可知,通过控制述铝基体粉末表面氧化膜的厚度小于4nm,以及在所述石墨表面覆盖镀层,相互配合,可以提高散热器的导热系数,提高散热器的散热效果。It can be seen from the above test that by controlling the thickness of the oxide film on the surface of the aluminum base powder to be less than 4 nm, and covering the graphite surface with a coating layer, the thermal conductivity of the radiator can be improved and the heat dissipation effect of the radiator can be improved.
通过上述测试可知,所述底板中的片状石墨的片状平面方向与流经所述底板的热流方向平行;所述散热鳍片中的片状石墨的片状平面方向与流经所述散热鳍片的热流方向平行。本发明通过控制底板和散热鳍片中片状石墨的取向,使得片状石墨的取向方向与热流方向一致,可以充分利用片状石墨平面方向导热系数高的特性,形成良好的散热效果。It can be seen from the above test that the sheet-like plane direction of the flake graphite in the bottom plate is parallel to the direction of heat flow through the bottom plate; The heat flow directions of the fins are parallel. The invention controls the orientation of the flake graphite in the bottom plate and the heat dissipation fins, so that the orientation direction of the flake graphite is consistent with the heat flow direction, and can make full use of the high thermal conductivity of the flake graphite in the plane direction to form a good heat dissipation effect.
以上所述实施例仅表达了本发明的实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制,但凡采用等同替换或等效变换的形式所获得的技术方案,均应落在本发明的保护范围之内。The above-mentioned embodiment only expresses the embodiment of the present invention, and its description is more specific and detailed, but it should not be construed as a limitation on the scope of the present invention, but all technical solutions obtained in the form of equivalent replacement or equivalent transformation , should fall within the protection scope of the present invention.
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