CN114409999B - A polypropylene composition and preparation method thereof - Google Patents
A polypropylene composition and preparation method thereof Download PDFInfo
- Publication number
- CN114409999B CN114409999B CN202111677705.3A CN202111677705A CN114409999B CN 114409999 B CN114409999 B CN 114409999B CN 202111677705 A CN202111677705 A CN 202111677705A CN 114409999 B CN114409999 B CN 114409999B
- Authority
- CN
- China
- Prior art keywords
- polypropylene composition
- polypropylene
- parts
- antioxidant
- hyperbranched polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 64
- -1 polypropylene Polymers 0.000 title claims abstract description 60
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 60
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920000587 hyperbranched polymer Polymers 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 239000012745 toughening agent Substances 0.000 claims abstract description 16
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 9
- 238000001125 extrusion Methods 0.000 claims description 21
- 238000005469 granulation Methods 0.000 claims description 12
- 230000003179 granulation Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 10
- 238000012360 testing method Methods 0.000 claims description 8
- 229920006150 hyperbranched polyester Polymers 0.000 claims description 7
- 230000020477 pH reduction Effects 0.000 claims description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 29
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 238000000465 moulding Methods 0.000 abstract description 4
- 239000000945 filler Substances 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a polypropylene composition and a preparation method thereof. The polypropylene composition comprises, by weight, 55-90 parts of polypropylene resin, 1-5 parts of hyperbranched polymer, 5-10 parts of toughening agent, 5-10 parts of compatilizer, 0-30 parts of modified montmorillonite and 0.5-1 part of antioxidant. The polypropylene composition has better adhesive property by utilizing the hyperbranched polymer, can improve the adhesive property of materials on one hand, can be directly adhered with metal in molding without additionally adding a layer of tackifier materials, simplifies the process, saves the cost, and can improve the compatibility of filler and matrix resin and improve the toughness and the rigidity of the materials on the other hand. In addition, the invention adopts modified montmorillonite, improves the compatibility of montmorillonite and resin, further improves the mechanical property of the polypropylene composition, and improves the bonding property with metal.
Description
Technical Field
The invention belongs to the technical field of high polymer materials, and particularly relates to a polypropylene composition and a preparation method thereof.
Background
With the development of industries such as building, automobiles, decoration and fitment, furniture, information industry technology and the like and the improvement of the requirements of people on living space environment, functional processed products such as safety glass, energy-saving hollow glass and the like are widely applied. Compared with single-layer glass, the hollow glass has better heat insulation and heat preservation effects and is increasingly used. The main materials of the hollow glass include glass, a spacing bar, a drying agent and the like. The traditional spacing bars are mostly aluminum bars, and the novel warm-edge spacing bars are generated due to the defects of easy condensation, frosting, poor heat preservation effect and the like caused by low metal heat conductivity coefficient. At present, most of the materials are PVC or PP, related documents and patents are consulted, and enterprises for producing warm edge strips feed back that most of the materials are imported at present, so that the materials are easy to deform, poor in temperature resistance and high in price, and can not be directly bonded with metal aluminum strips, and can be bonded with metal only by being matched with an adhesive, but the process is complex and high in cost. Therefore, there is a need to develop a material which can be bonded to a metal aluminum strip, is easy to process, has excellent heat resistance, and is dimensionally stable.
Disclosure of Invention
The present invention aims to provide a polypropylene composition and a method for preparing the same, which aims to overcome the defects of the prior art. The polypropylene composition provided by the invention has good toughness, flexural modulus and adhesive property.
The polypropylene composition comprises, by weight, 55-90 parts of polypropylene resin, 1-5 parts of hyperbranched polymer, 5-10 parts of toughening agent, 5-10 parts of compatilizer, 0-30 parts of modified montmorillonite and 0.5-1 part of antioxidant.
The hyperbranched polymer is a star-shaped or dendritic polymer, contains a large amount of active groups and has good bonding performance, and the polypropylene composition can improve the bonding performance of materials on one hand, can be directly bonded with metals in molding without additionally adding a layer of tackifier materials, can simplify the process and save the cost, and can improve the compatibility of montmorillonite and matrix resin and improve the toughness and rigidity of the materials on the other hand. In addition, as the hyperbranched polymer content increases, the toughness and peel strength of the material increases.
As a preferred embodiment of the present invention, the hyperbranched polymer is at least one of hyperbranched polyethyleneimine, hyperbranched polyester, hyperbranched unsaturated resin, and hyperbranched epoxy resin.
The hyperbranched polymer contains more polar functional groups such as amino groups, amide groups, ester groups, unsaturated groups or epoxy groups on the molecular chain, has better compatibility with resin and filler, and improves the performance of the whole material such as mechanical performance, processability, adhesiveness and the like.
As a preferred embodiment of the invention, the hyperbranched polymer has a degree of branching of from 0.5 to 0.7.
The degree of branching of the hyperbranched polymer influences the mechanical properties and the adhesive properties of the polypropylene composition. With increasing branching of the hyperbranched polymer, the impact strength and the adhesive properties of the polypropylene composition are enhanced and the flexural modulus is slightly reduced. However, the branching degree of the hyperbranched polymer is too high, the compatibility of the hyperbranched polymer and polypropylene is poor, and the mechanical property and the adhesive property of the material are reduced.
As a preferred embodiment of the invention, the modified montmorillonite is montmorillonite with the surface being modified by acidification and/or modified by quaternary ammonium salt, the D50 particle size of the modified montmorillonite is 2-5 mu m, and more preferably, the modified montmorillonite is montmorillonite with the surface being modified by acidification and modified by quaternary ammonium salt.
The montmorillonite is a lamellar silicate with stronger polarity, and after radial acid treatment, the polar bond is passivated, the specific surface area is increased, the aperture is increased, and meanwhile, after quaternary ammonium salt treatment, the adsorption property and the bonding performance of the montmorillonite are enhanced, and the compatibility with resin can be improved. Compared with unmodified montmorillonite, the mechanical property and the bonding property with metal of the polypropylene composition prepared by the modified montmorillonite are obviously enhanced.
As a preferred embodiment of the present invention, the polypropylene resin has a melt flow rate of 1 to 5g/10min under test conditions of 230℃and 2.16kg according to test standard ISO 1133-1-2011.
The invention selects the polypropylene resin with low melt flow rate, which is beneficial to material extrusion molding, and can avoid unstable molding due to low viscosity and high melt flow property of polypropylene.
As a preferred embodiment of the invention, the toughening agent is at least one of POE, EVA, an acrylic elastomer and EPDM, and the melt flow rate of the toughening agent is 0.5-5g/10min under the test condition of 190 ℃ and 2.16kg according to the test standard ISO 1133-1-2011.
As a preferred embodiment of the invention, the compatibilizer is polypropylene grafted maleic anhydride.
According to the invention, the antioxidant is a mixture of the antioxidant 1010 and the antioxidant 168, and the mass ratio of the antioxidant 1010 to the antioxidant 168 is 1 (1-2).
In addition, the invention also claims a preparation method of the polypropylene composition, which comprises the following steps:
(1) Uniformly mixing a hyperbranched polymer, modified montmorillonite and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) And mixing the mixture, the polypropylene resin, the toughening agent and the antioxidant, and carrying out melt extrusion and granulation to obtain the polypropylene composition.
As a preferred embodiment of the invention, in the step (2), the device for melt extrusion and granulation is a twin-screw extruder, the extrusion temperature of the twin-screw extruder is 180-210 ℃, the length-diameter ratio is (38-42): 1, and the rotating speed is 300-500rpm.
Compared with the prior art, the invention has the beneficial effects that:
(1) The hyperbranched polymer has better adhesive property, and the hyperbranched polymer is added into the polypropylene composition, so that on one hand, the adhesive property of the material can be improved, the material can be directly adhered to metal in molding, a layer of tackifier material is not required to be additionally added, the process is simplified, the cost is saved, and on the other hand, the compatibility of the filler and matrix resin can be improved, and the toughness and rigidity of the material are improved.
(2) In addition, the invention adopts modified montmorillonite, improves the compatibility of montmorillonite and resin, further improves the mechanical property of the polypropylene composition, and improves the bonding property with metal.
Detailed Description
For a better description of the objects, technical solutions and advantages of the present invention, the present invention will be further described with reference to the following specific examples.
Unless specifically stated otherwise, the reagents, methods and apparatus employed in the present invention are those conventional in the art. The reagents and materials used in the present invention are commercially available unless otherwise specified.
The following raw materials are adopted in the examples and comparative examples of the invention:
polypropylene A, with a melt flow rate of 3g/10min at 230 ℃,2.16kg, brand PP K8003, available from the Mao Ming petrochemical industry;
the polypropylene B has a melt flow rate of 1g/10min at 230 ℃ and 2.16kg, and is sold under the brand name PP EPS30R and purchased from the name Mao petrochemical industry;
polypropylene C has a melt flow rate of 5g/10min at 230℃and 2.16kg, and is available from Yanshan petrochemical industry under the brand PP K1005;
The toughening agent A is POE, the melt flow rate measured at 190 ℃ and 2.16kg is 5g/10min, and the brand is POE 7447, which is purchased from DOW;
The toughening agent B is POE, the melt flow rate measured at 190 ℃ and 2.16kg is 0.5g/10min, and the brand is POE 8150, which is purchased from DOW;
the toughening agent C is POE, the melt flow rate measured at 190 ℃ and 2.16kg is 6g/10min, and the brand is POE LC610, which is purchased from LG;
Hyperbranched polymer A, hyperbranched polyester, with a branching degree of 0.5, brand name Hyper H102, purchased from Wuhan hyperbranched;
hyperbranched polymer B, hyperbranched polyester, with a branching degree of 0.6, brand name Hyper H103, purchased from Wuhan hyperbranched;
hyperbranched polymer C, hyperbranched polyester, with a branching degree of 0.7, and a brand of Hyper H104, purchased from Wuhan hyperbranched;
Hyperbranched polymer D, hyperbranched polyester, with a branching degree of 0.4, brand name Hyper H101, purchased from Wuhan hyperbranched;
Hyperbranched polymer E, hyperbranched polyester, with a branching degree of 0.75 and a trade name of Hyper H105, purchased from Wuhan hyperbranched;
Modified montmorillonite A, montmorillonite with surface modified by acidification and quaternary ammonium salt modification, D50 of 3um, DK4-D, purchased from Zhejiang Feng hong;
Modified montmorillonite B, surface modified montmorillonite with acid, D50 of 3um, DK4-S, purchased from Zhejiang Feng hong;
Modified montmorillonite C, montmorillonite with surface modified by quaternary ammonium salt, D50 of 3um, DK4-Y, purchased from Zhejiang Feng hong;
montmorillonite D, which is not modified, D50 is 3um, and the brand is DK4-1, purchased from Zhejiang Feng hong;
the compatilizer is polypropylene grafted maleic anhydride and is commercially available, and the same compatilizer is used in the examples and the comparative examples of the invention;
antioxidant 1010 and antioxidant 168 in the mass ratio of 1 to 1, and the same antioxidant was used in the examples and comparative examples.
Examples 1 to 14 and comparative examples 1 to 5
The components of the polypropylene compositions of examples 1 to 14 of the present invention are shown in Table 1, and the components of the polypropylene compositions of comparative examples 1 to 5 are shown in Table 2.
The preparation methods of the polypropylene composition disclosed by the embodiments 1-9, 11-14 and the comparative examples 2-4 comprise the following steps:
(1) Uniformly mixing a hyperbranched polymer, modified montmorillonite and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) Adding the mixture, the polypropylene resin, the toughening agent and the antioxidant into a double screw for mixing, carrying out melt extrusion and pelleting to obtain the polypropylene composition, wherein the extrusion temperature of a double screw extruder is 180-210 ℃, the length-diameter ratio is 40:1, and the rotating speed is 300-500rpm.
The preparation method of the polypropylene composition of the embodiment 10 of the invention comprises the following steps:
(1) Uniformly mixing a hyperbranched polymer and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) Adding the mixture, the polypropylene resin, the toughening agent and the antioxidant into a double screw for mixing, and carrying out melt extrusion and granulation to obtain the polypropylene composition, wherein the extrusion temperature of a double screw extruder is 180-210 ℃.
The preparation method of the polypropylene composition of the comparative example 1 comprises the following steps:
(1) Uniformly mixing the modified montmorillonite and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) Adding the mixture, the polypropylene resin, the toughening agent and the antioxidant into a double screw for mixing, and carrying out melt extrusion and granulation to obtain the polypropylene composition, wherein the extrusion temperature of a double screw extruder is 180-210 ℃.
The preparation method of the polypropylene composition of the comparative example 5 comprises the following steps:
(1) Uniformly mixing a hyperbranched polymer, unmodified montmorillonite and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) Adding the mixture, the polypropylene resin, the toughening agent and the antioxidant into a double screw for mixing, and carrying out melt extrusion and granulation to obtain the polypropylene composition, wherein the extrusion temperature of a double screw extruder is 180-210 ℃.
TABLE 1
TABLE 2
Effect example
The polypropylene compositions prepared in examples and comparative examples were tested for properties, and specific test items and test methods are as follows:
(1) The impact strength of the cantilever beam is tested according to GB/T1843-2008;
(2) Flexural modulus tested according to standard GB/T9341-2008;
(3) Peel strength test standard GB/T2792-2014 test.
The results of the performance test of the polypropylene compositions described in examples 1 to 14 and comparative examples 1 to 5 are shown in Table 3.
TABLE 3 Table 3
According to the data of Table 3, the polypropylene compositions of examples 1-14 were far superior in Izod impact strength and peel strength to the polypropylene compositions prepared in comparative examples 1-5. According to examples 1-3, the cantilever impact strength, flexural modulus and adhesive property of the material increased with the addition of the hyperbranched polymer, but according to comparative examples 1-3 and examples 1-3, the addition of the hyperbranched polymer according to the present invention can enhance the cantilever impact strength, flexural modulus and adhesive property of the material, but when the addition of the hyperbranched polymer is out of the range defined by the present invention, the cantilever impact strength, flexural modulus and adhesive property of the material decrease. From the data of examples 2, 4-7, it is seen that as the branching degree of the hyperbranched polymer increases, the cantilever impact strength, flexural modulus and adhesion properties of the material increase and then decrease, and that the properties of the material are optimal in the range of 0.5-0.7 branching degree. From the data of examples 2, 8-9 and comparative example 5, it is evident that the modified montmorillonite can significantly enhance the mechanical properties and adhesion properties of the material as compared with the unmodified montmorillonite, and that the montmorillonite subjected to surface acidification modification and quaternary ammonium salt modification has the most significant improvement in the properties of the material. From the data of examples 2 and 10 to 12, it is understood that the cantilever impact strength, flexural modulus and bonding property of the material increase with increasing addition of the modified montmorillonite, but the cantilever impact strength and bonding property of the material significantly decrease with increasing addition beyond the limit of the present invention.
Finally, it should be noted that the above embodiments are only for illustrating the technical solution of the present invention and not for limiting the scope of the present invention, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that the technical solution of the present invention may be modified or substituted equally without departing from the spirit and scope of the technical solution of the present invention.
Claims (7)
1. The polypropylene composition is characterized by comprising, by weight, 55-90 parts of polypropylene resin, 1-5 parts of hyperbranched polymer, 5-10 parts of toughening agent, 5-10 parts of compatilizer, 10-30 parts of modified montmorillonite and 0.5-1 part of antioxidant;
the hyperbranched polymer is hyperbranched polyester, and the branching degree of the hyperbranched polymer is 0.5-0.7;
the modified montmorillonite is montmorillonite with the surface modified by acidification, and the D50 particle size of the modified montmorillonite is 2-5 mu m.
2. The polypropylene composition according to claim 1, wherein the polypropylene resin has a melt flow rate of 1 to 5g/10min at 230 ℃ under test conditions of 2.16 kg.
3. The polypropylene composition of claim 1, wherein the toughening agent is at least one of POE, EVA, an acrylic elastomer, and EPDM, and wherein the toughening agent has a melt flow rate of 0.5 to 5g/10min under test conditions of 190 ℃ and 2.16 kg.
4. The polypropylene composition according to claim 1, wherein the compatibilizer is polypropylene grafted maleic anhydride.
5. The polypropylene composition according to claim 1, wherein the antioxidant is a mixture of antioxidant 1010 and antioxidant 168.
6. A process for the preparation of a polypropylene composition according to any one of claims 1 to 5, comprising the steps of:
(1) Uniformly mixing a hyperbranched polymer, modified montmorillonite and a compatilizer, and then carrying out melt extrusion granulation to obtain a mixture;
(2) And mixing the mixture, the polypropylene resin, the toughening agent and the antioxidant, and carrying out melt extrusion and granulation to obtain the polypropylene composition.
7. The method of producing a polypropylene composition according to claim 6, wherein in the step (2), the means for melt extrusion and pelletization is a twin-screw extruder, and the extrusion temperature of the twin-screw extruder is 180 to 210 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111677705.3A CN114409999B (en) | 2021-12-31 | 2021-12-31 | A polypropylene composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111677705.3A CN114409999B (en) | 2021-12-31 | 2021-12-31 | A polypropylene composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114409999A CN114409999A (en) | 2022-04-29 |
| CN114409999B true CN114409999B (en) | 2024-12-06 |
Family
ID=81271122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111677705.3A Active CN114409999B (en) | 2021-12-31 | 2021-12-31 | A polypropylene composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114409999B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116178840B (en) * | 2023-02-13 | 2024-06-04 | 金发科技股份有限公司 | Polypropylene composite material and preparation method and application thereof |
| CN117004135B (en) * | 2023-07-27 | 2025-03-25 | 金发科技股份有限公司 | A polypropylene composition and its preparation method and application |
| CN119141990A (en) * | 2024-08-26 | 2024-12-17 | 江苏利特尔绿色包装股份有限公司 | Ultrahigh-barrier homogeneous composite packaging film and preparation process thereof |
| CN119283400A (en) * | 2024-10-18 | 2025-01-10 | 宿迁市鲁班科技股份有限公司 | A high-strength polypropylene hollow plastic plate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101712779A (en) * | 2009-08-25 | 2010-05-26 | 上海普利特复合材料股份有限公司 | Polypropylene nano composite material and preparation method thereof |
| CN110885433A (en) * | 2019-05-24 | 2020-03-17 | 武汉金发科技有限公司 | Hyperbranched polyester and synthesis method thereof, and thermoplastic resin composition and preparation method thereof |
| CN113845720A (en) * | 2021-08-25 | 2021-12-28 | 武汉金发科技有限公司 | Polypropylene composite material with high tinting strength and low shrinkage rate as well as preparation method and application thereof |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125125C (en) * | 1998-09-08 | 2003-10-22 | 中国科学院化学研究所 | Polypropylene/montmorillonite laminated compound material and its preparing process |
| CN1182192C (en) * | 2000-03-17 | 2004-12-29 | 中国石油天然气股份有限公司兰州石化分公司 | Composite nanometer-level polypropylene/montmorillonoid material and its preparation |
| CN1137198C (en) * | 2001-03-21 | 2004-02-04 | 中科纳米技术工程中心有限公司 | Nano composite polymer-montmorillonoid material and its prepn. |
| CN1344759A (en) * | 2001-10-26 | 2002-04-17 | 中国科学院长春应用化学研究所 | Composite nano polypropylene mixture/montmorillonoid nano-material and its prepn |
| US6673870B2 (en) * | 2002-05-13 | 2004-01-06 | The Procter & Gamble Company | Compositions of polyolefins and hyperbranched polymers with improved tensile properties |
| CN1272373C (en) * | 2004-09-16 | 2006-08-30 | 上海交通大学 | Preparation of polypropylene / organic montmorillonite nanometer composite material |
| CN100368472C (en) * | 2005-10-18 | 2008-02-13 | 东华大学 | A method for improving the fluidity of polypropylene melt |
| ATE546413T1 (en) * | 2008-06-30 | 2012-03-15 | Union Carbide Chem Plastic | METHOD FOR EXHAUSTING ORGANIC CLAY TO PRODUCE A NANOCOMPOSITE |
| CN108276682A (en) * | 2017-12-26 | 2018-07-13 | 上海普利特复合材料股份有限公司 | A kind of high fluidity polypropylene composite material with high strength and toughness and preparation method thereof |
| CN108034138B (en) * | 2017-12-26 | 2021-01-01 | 金发科技股份有限公司 | Polypropylene composition and preparation method and application thereof |
| CN109370041B (en) * | 2018-08-09 | 2021-04-09 | 河南工程学院 | Polypropylene modified material with good rigidity and high elongation at break and preparation method thereof |
| CN109867922B (en) * | 2018-12-28 | 2022-01-18 | 聚石化学(苏州)有限公司 | Halogen-free flame-retardant reinforced PBT (polybutylene terephthalate) composite material with excellent adhesion with epoxy resin and preparation method thereof |
| CN110256660A (en) * | 2019-05-27 | 2019-09-20 | 武汉金发科技有限公司 | A kind of hyper-branched polyester and its synthetic method and a kind of thermoplastic resin composition and preparation method thereof |
| CN110452469B (en) * | 2019-09-25 | 2022-01-28 | 河南城建学院 | Modified polypropylene material and preparation method thereof |
| CN110684282A (en) * | 2019-10-30 | 2020-01-14 | 南京聚隆科技股份有限公司 | 3D hollow blow molding micro-foaming polyolefin material and preparation method thereof |
| CN111662507B (en) * | 2020-06-30 | 2022-04-22 | 万华化学(四川)有限公司 | Polypropylene material with high weld mark strength and preparation method thereof |
| CN112646274B (en) * | 2020-12-22 | 2022-10-18 | 武汉金发科技有限公司 | Polypropylene composite material and preparation method thereof |
-
2021
- 2021-12-31 CN CN202111677705.3A patent/CN114409999B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101712779A (en) * | 2009-08-25 | 2010-05-26 | 上海普利特复合材料股份有限公司 | Polypropylene nano composite material and preparation method thereof |
| CN110885433A (en) * | 2019-05-24 | 2020-03-17 | 武汉金发科技有限公司 | Hyperbranched polyester and synthesis method thereof, and thermoplastic resin composition and preparation method thereof |
| CN113845720A (en) * | 2021-08-25 | 2021-12-28 | 武汉金发科技有限公司 | Polypropylene composite material with high tinting strength and low shrinkage rate as well as preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 蒙脱土的有机化及其对小本体聚丙烯的改性研究;赵彦生等;第九届全国化学工艺年会;1506-1510 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114409999A (en) | 2022-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114409999B (en) | A polypropylene composition and preparation method thereof | |
| CN109337312B (en) | Polylactic acid composite material and preparation method thereof | |
| CN105331055B (en) | PBT composite material used for NMT forming and preparation method thereof | |
| CN113388194B (en) | Glass fiber reinforced polypropylene composition and preparation method and application thereof | |
| CN107312327B (en) | High-heat-resistance high-impact-resistance nylon alloy resin composition | |
| CN105860316B (en) | Improve the ASA resin composition and preparation method thereof of low-temperature impact toughness | |
| CN110372988A (en) | A kind of ABS/POK composite material and preparation method | |
| CN104804398A (en) | High heat resistance and high transparency polycarbonate composition for automotive lamp and preparation method of composition | |
| CN100549087C (en) | PC terpolymer resin/polybutylene terephthalate alloy material | |
| CN104177719B (en) | Special material for cross-flow fan reinforced AS with high heat resistance and preparation method of material | |
| CN109721969A (en) | A kind of ultra-toughness low-temperature impact-resistant PBT material and preparation method thereof | |
| CN105885320A (en) | PMMA resin with ultrahigh toughness | |
| CN113045876A (en) | PET/ABS plastic alloy and preparation method thereof | |
| CN108276746A (en) | A kind of liquid crystal polyester/nylon alloy material and preparation method thereof | |
| CN106987102A (en) | Low floating fine short fiber enhanced PBT/ABS alloy material of a kind of heat-resisting impact resistance available for electric appliance casing and preparation method thereof | |
| CN113912992B (en) | Weather-resistant acid rain-resistant ASA/PBT composite material, and preparation method and application thereof | |
| CN106905650B (en) | High impact polymethyl methacrylate alloy resin composition and preparation method thereof | |
| CN105647104B (en) | A kind of polyoxymethylene alloy and preparation method thereof | |
| CN106893250B (en) | A kind of ABS resin composition being blow molded with high fondant-strength, good appearance | |
| CN109401102B (en) | Cold-resistant ASA resin and preparation method thereof | |
| CN108690341B (en) | Compatilizer for PC/ABS alloy and PC/ABS alloy | |
| CN109320898B (en) | Nano montmorillonite modified PA6/ABS alloy and preparation method thereof | |
| CN107365470B (en) | A kind of high heat resistance HI high impact PMMA resin and preparation method thereof | |
| CN105419143A (en) | Heat-resistant ASA resin composition with tiger wrinkle defect eliminated and preparation method thereof | |
| CN111793315A (en) | Polyolefin toughening modifier and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20241024 Address after: 510663 Guangzhou science and Technology Development Zone, Guangdong, China, 33 Applicant after: KINGFA SCI. & TECH. Co.,Ltd. Country or region after: China Applicant after: CHENGDU KINGFA SCI. & TECH. ADVANCED MATERIALS Co.,Ltd. Applicant after: Jiangsu Jinfa renewable resources Co.,Ltd. Address before: 510663 Guangzhou science and Technology Development Zone, Guangdong, China, 33 Applicant before: KINGFA SCI. & TECH. Co.,Ltd. Country or region before: China Applicant before: CHENGDU KINGFA SCI. & TECH. ADVANCED MATERIALS Co.,Ltd. Applicant before: Jiangsu golden hair Environmental Protection Technology Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |