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CN114213972B - Coating applied to deicing of rotating wind turbine blades and method for making the same - Google Patents

Coating applied to deicing of rotating wind turbine blades and method for making the same Download PDF

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CN114213972B
CN114213972B CN202111466644.6A CN202111466644A CN114213972B CN 114213972 B CN114213972 B CN 114213972B CN 202111466644 A CN202111466644 A CN 202111466644A CN 114213972 B CN114213972 B CN 114213972B
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deicing
elastic layer
coating
rigid substrate
blades
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CN114213972A (en
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顾军民
周永刚
顾光成
薛志亮
应宇翔
李珂
金崇会
刘俊豪
钟雲濠
叶锋
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Guodian Ningbo Wind Power Development Co ltd
Zhejiang University ZJU
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Guodian Ningbo Wind Power Development Co ltd
Zhejiang University ZJU
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D1/00Wind motors with rotation axis substantially parallel to the air flow entering the rotor 
    • F03D1/06Rotors
    • F03D1/065Rotors characterised by their construction elements
    • F03D1/0675Rotors characterised by their construction elements of the blades
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D80/00Details, components or accessories not provided for in groups F03D1/00 - F03D17/00
    • F03D80/40Ice detection; De-icing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2530/00Rubber or the like
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05BINDEXING SCHEME RELATING TO WIND, SPRING, WEIGHT, INERTIA OR LIKE MOTORS, TO MACHINES OR ENGINES FOR LIQUIDS COVERED BY SUBCLASSES F03B, F03D AND F03G
    • F05B2230/00Manufacture
    • F05B2230/90Coating; Surface treatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05BINDEXING SCHEME RELATING TO WIND, SPRING, WEIGHT, INERTIA OR LIKE MOTORS, TO MACHINES OR ENGINES FOR LIQUIDS COVERED BY SUBCLASSES F03B, F03D AND F03G
    • F05B2280/00Materials; Properties thereof
    • F05B2280/60Properties or characteristics given to material by treatment or manufacturing
    • F05B2280/6011Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wind Motors (AREA)

Abstract

The invention provides a coating applied to deicing of blades of a rotary wind turbine and a manufacturing method thereof, wherein the coating consists of a rigid substrate with the thickness of 0.3-0.5 mm and the surface roughness of 0.2-0.4 mm and a micro-deformation elastic layer with the thickness of 0.3-0.5 mm and the elastic modulus of 5 kPa-20 kPa; the rigid substrate is solidified after being thermally fused and adhered with the surface of the wind turbine blade to form a porous surface structure; the elastic layer is adhered on the rigid substrate and mutually hooked with the rigid substrate. Because the surface roughness of the rigid substrate is high, the thicknesses of different positions of the elastic layer are different, and the deformation under stress is different, an air gap is generated between the ice layer and the elastic layer, the adhesion force of the ice layer is reduced, and the ice layer falls off. The coating applied to deicing of the blades of the rotating wind turbine is simple to prepare, low in cost and easy to popularize.

Description

一种应用于旋转风力机叶片除冰的涂层及其制作方法Coating for deicing blades of rotating wind turbines and method for making the same

技术领域technical field

本发明涉及风力发电机除冰技术领域,特别涉及一种应用于旋转风力机叶片除冰的涂层及其制作方法。The invention relates to the technical field of wind power generator deicing, in particular to a coating applied to the deicing of rotating wind power blades and a manufacturing method thereof.

背景技术Background technique

我国约有40%的机组容量工作在高寒高湿地区。当风力发电机工作在高寒高湿地带时,叶片表面容易结冰,结冰太厚会迫使机组停机,降低发电功率,否则会引起机组倒塌,叶片上的冰块掉落还会威胁人身安全。风机叶片上的结冰主要有明冰、霜冰、混合冰三种。明冰是在微寒有雨风速大的条件下形成的透明坚硬冰块,密度在900kg/m3以上;霜冰是在极寒风速小的条件下形成的白色不透明晶状碎冰,密度在600kg/m3以下;混合冰的形成条件和形态介于明冰和霜冰之间,密度为600-900kg/m3。其中明冰和混合冰的密度大,对风机的危害较大。叶片上不同位置的结冰情况也不相同,占叶片总长1/3的叶尖部位线速度大,和过冷水滴碰撞频繁,结冰厚度最大。About 40% of the unit capacity in our country works in high cold and high humidity areas. When wind turbines work in high-cold and high-humidity areas, the surface of the blades is prone to icing. If the icing is too thick, the unit will be shut down and the power generation will be reduced. Otherwise, the unit will collapse, and the falling ice on the blades will threaten personal safety. There are three types of icing on fan blades: clear ice, frost ice, and mixed ice. Bright ice is transparent and hard ice formed under the conditions of mild cold, rain and high wind speed, with a density of more than 900kg/m3; frost ice is white opaque crystalline crushed ice formed under extremely cold and low wind speed, with a density of Below 600kg/m3; the formation conditions and form of mixed ice are between clear ice and frost ice, and the density is 600-900kg/m3. Among them, the density of clear ice and mixed ice is high, which is more harmful to the fan. The icing conditions at different positions on the blade are also different. The blade tip, which accounts for 1/3 of the total length of the blade, has a high linear velocity and frequent collisions with supercooled water droplets, resulting in the largest icing thickness.

目前已有的风机除冰技术可分为两种:At present, the existing fan deicing technology can be divided into two types:

主动除冰:从外界输入能量对叶片表面进行加热,使接触面上的冰块融化,降低冰块在表面上的黏附力,利用离心力将冰甩脱。主动除冰包括电热除冰、微波除冰、气流除冰等。电热除冰在叶片上敷设一层电阻加热元件(如:碳布),通过外接电源供热;微波除冰将微波能导到叶片表面,利用微波能提高叶片表面的温度;气流除冰在叶片型腔内形成一股循环的暖流,使热量从叶片内表面传递到外表面。如公开号为CN107939620A的中国专利文献公开了一种风机叶片防冰除冰系统,包括气热防冰装置、膨胀管除冰装置、电加热除冰装置、层除冰装置及监测控制装置,电加热除冰装置包括多个布设在风机叶片上的相互并联的电阻丝。Active deicing: Energy is input from the outside to heat the surface of the blade to melt the ice on the contact surface, reduce the adhesion of the ice on the surface, and use centrifugal force to shake off the ice. Active deicing includes electric deicing, microwave deicing, airflow deicing, etc. Electrothermal deicing lays a layer of resistance heating elements (such as carbon cloth) on the blade, and supplies heat through an external power supply; microwave deicing guides microwave energy to the surface of the blade, and uses microwave energy to increase the temperature of the blade surface; airflow deicing is performed on the blade A circulating warm current is formed in the cavity to transfer heat from the inner surface of the blade to the outer surface. For example, the Chinese patent document whose publication number is CN107939620A discloses a fan blade anti-icing and de-icing system, including an air-heat anti-icing device, an expansion tube de-icing device, an electric heating de-icing device, a layer de-icing device and a monitoring and control device. The heating and deicing device includes a plurality of parallel resistance wires arranged on the fan blades.

虽然主动除冰技术加热效率高,升温快,能够快速除冰,但是主要缺点有:(1)加热的能耗大;(2)加热元件容易遭到雷击;(3)设备复杂,不易维修。Although the active deicing technology has high heating efficiency, fast temperature rise, and quick deicing, the main disadvantages are: (1) high energy consumption for heating; (2) the heating element is easily struck by lightning; (3) the equipment is complicated and difficult to maintain.

被动除冰:在叶片表面涂覆化学涂层,改变接触面特性,使冰块难以在叶片上形成或形成后可以被轻松甩脱,与主动除冰相比不耗能、使用简单。被动除冰包括化学药品、超疏水涂层、超光滑涂层等。Passive deicing: Coating chemical coatings on the surface of the blades can change the characteristics of the contact surface, making it difficult for ice to form on the blades or can be easily thrown off after forming. Compared with active deicing, it consumes less energy and is easier to use. Passive deicing includes chemicals, superhydrophobic coatings, ultrasmooth coatings, etc.

然而,在叶片表面喷洒异丙醇、乙烯乙二醇、乙醇等化学药品,降低冰点防止结冰,这种方法作用时间短且有污染;超疏水涂层通过降低表面接触角,防止水珠的凝结,这种方法除冰效果差且不耐用;超光滑涂层在接触面形成一层润滑水膜,降低冰的附着,这种方法效果好,但制备复杂、成本昂贵。However, spraying isopropanol, ethylene glycol, ethanol and other chemicals on the surface of the blade to lower the freezing point and prevent freezing, this method has a short action time and is polluting; Condensation, this method has poor deicing effect and is not durable; the ultra-smooth coating forms a lubricating water film on the contact surface to reduce the adhesion of ice. This method is effective, but the preparation is complicated and expensive.

发明内容Contents of the invention

本发明提供了一种应用于旋转风力机叶片除冰的涂层及其制作方法,通过在风力机叶片表面喷涂除冰涂层,利用离心力的作用使冰块与涂层间产生空气间隙,降低冰块的粘附力,达到除冰的技术效果。The invention provides a coating applied to deicing blades of a rotating wind turbine and a manufacturing method thereof. By spraying a deicing coating on the surface of a wind turbine blade, an air gap is generated between the ice cube and the coating by the action of centrifugal force, thereby reducing the The adhesion of ice cubes achieves the technical effect of deicing.

一种应用于旋转风力机叶片除冰的涂层,由厚度为0.3mm~0.5mm表面粗糙度为0.2mm~0.4mm的刚性基底和厚度为0.3mm~0.5mm弹性模量为5kPa~20kPa的微变形弹性层组成。A coating applied to the deicing of rotating wind turbine blades, consisting of a rigid substrate with a thickness of 0.3mm to 0.5mm and a surface roughness of 0.2mm to 0.4mm and a coating with a thickness of 0.3mm to 0.5mm and an elastic modulus of 5kPa to 20kPa Composed of micro-deformation elastic layer.

其中,所述的刚性基底用于与风力机叶片表面热熔粘合后固化,形成多孔性的表面结构;所述的弹性层粘附在刚性基底上,与刚性基底相互勾联。Wherein, the rigid base is used for hot-melt bonding with the surface of the wind turbine blade and then solidified to form a porous surface structure; the elastic layer is adhered to the rigid base and interlinked with the rigid base.

由于刚性基底表面粗糙度高,弹性层不同位置厚度不同,受力下的变形量不同。Due to the high surface roughness of the rigid base, the thickness of the elastic layer is different at different positions, and the deformation under force is different.

针对旋转风力机叶片的工作环境,为了提高除冰涂层的使用寿命,优选的刚性基底是一种固体可熔性聚合物树脂,其表面粗糙度高,弹性层与刚性基底相互勾联,使弹性层与刚性基底紧密固定。For the working environment of rotating wind turbine blades, in order to improve the service life of the deicing coating, the preferred rigid substrate is a solid meltable polymer resin with high surface roughness, and the elastic layer is connected with the rigid substrate to make The elastic layer is firmly fixed to the rigid base.

为了提高除冰涂层的使用效果,优选的,所述的弹性层是硅酮橡胶与硅胶按照质量比9:1的组合。In order to improve the application effect of the deicing coating, preferably, the elastic layer is a combination of silicone rubber and silica gel at a mass ratio of 9:1.

为了便于涂层的制作,优选的,弹性层是硅酮橡胶和硅胶组合后,再用有机溶剂稀释后均匀的喷涂到刚性基底上,进一步优选的,有机溶剂为无水乙醇或六甲基二硅氧烷In order to facilitate the production of the coating, preferably, the elastic layer is a combination of silicone rubber and silica gel, and then diluted with an organic solvent and sprayed uniformly on the rigid substrate. More preferably, the organic solvent is absolute ethanol or hexamethyl di Silicone

为了进一步提高除冰涂层的使用效果,优选的,弹性层是一种疏水的光滑表面,接触角115°~125°。In order to further improve the application effect of the deicing coating, preferably, the elastic layer is a hydrophobic smooth surface with a contact angle of 115°-125°.

为了保证除冰涂层的除冰效果,提高使用寿命,降低使用成本,涂层的总厚度为0.8mm~1mm。涂层太薄,不能起到很好的除冰效果;涂层太厚,会影响涂层的使用寿命,还会破坏风力机叶片的气动特性,而且使用成本增加。In order to ensure the deicing effect of the deicing coating, increase the service life, and reduce the cost of use, the total thickness of the coating is 0.8 mm to 1 mm. If the coating is too thin, it cannot achieve a good deicing effect; if the coating is too thick, the service life of the coating will be affected, and the aerodynamic characteristics of the wind turbine blades will be damaged, and the use cost will increase.

所述的涂层上覆冰后,在离心力和周期性重力的作用下,涂层上的弹性层发生形变,弹性层与冰层间产生气穴,冰层的粘附力减少,在离心力的作用下脱落。After the coating is covered with ice, under the action of centrifugal force and periodic gravity, the elastic layer on the coating is deformed, air pockets are generated between the elastic layer and the ice layer, and the adhesion of the ice layer is reduced. fall off under action.

具体的,在风机运行过程中,弹性层在切向力的作用下发生变形,由于弹性层不同位置厚度不同,受力下的变形量不同,在局部区域,冰层与弹性层分离产生空气间隙,在离心力和周期性重力的作用下,空气间隙增大,冰层的粘附力减少,同时随着结冰厚度的增加,冰块受到的离心力增大,最终冰层在离心力的作用下脱落。Specifically, during the operation of the fan, the elastic layer deforms under the action of the tangential force. Since the thickness of the elastic layer is different at different positions, the amount of deformation under the force is different. In some areas, the separation of the ice layer and the elastic layer creates an air gap. , under the action of centrifugal force and periodic gravity, the air gap increases and the adhesion of the ice layer decreases. At the same time, as the thickness of the ice increases, the centrifugal force on the ice increases, and finally the ice layer falls off under the action of centrifugal force .

本发明还提供了一种应用于旋转风力机叶片除冰涂层的制作方法,包括以下步骤:The present invention also provides a method for making a deicing coating applied to a rotating wind turbine blade, comprising the following steps:

(1)对风力机叶片表面进行清洁;(1) Clean the surface of the wind turbine blade;

(2)在风力机叶片表面喷涂加热后的固体可熔性聚合物树脂,形成具有多孔性表面结构的刚性基底;(2) Spray the heated solid meltable polymer resin on the surface of the wind turbine blade to form a rigid substrate with a porous surface structure;

(3)按照质量比9:1混合硅酮橡胶与硅胶;(3) Mix silicone rubber and silica gel according to the mass ratio of 9:1;

(4)按质量比3:2用有机溶剂稀释混合后的硅酮橡胶与硅胶,并搅拌均匀;(4) Dilute the mixed silicone rubber and silica gel with an organic solvent in a mass ratio of 3:2, and stir evenly;

(5)在刚性基底上喷涂形成弹性层;(5) Spray coating on a rigid substrate to form an elastic layer;

(6)待弹性层晾干后形成除冰涂层。(6) After the elastic layer is dried, a deicing coating is formed.

进一步地,步骤(2)中,多孔性表面结构的刚性基底厚度为0.3mm~0.5mm;步骤(5)中,弹性层厚度为0.3mm~0.5mm。Further, in step (2), the thickness of the rigid substrate of the porous surface structure is 0.3mm-0.5mm; in step (5), the thickness of the elastic layer is 0.3mm-0.5mm.

进一步地,步骤(6)中,晾干后的除冰涂层刚性基底和弹性层相互勾连,防止弹性层脱落,从而提高弹性层的寿命。Further, in step (6), the dried rigid base of the deicing coating and the elastic layer are interlocked to prevent the elastic layer from falling off, thereby increasing the life of the elastic layer.

与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

本发明通过刚性基底和弹性层的组合,降低冰层的粘附力,使冰层在厚度很薄时就能在风力机叶片旋转的离心力作用下脱落,避免了风力发电机因结冰而停机的情况,提高风机的发电量。涂层制备简单,成本低,易推广。The present invention reduces the adhesive force of the ice layer through the combination of the rigid base and the elastic layer, so that the ice layer can fall off under the centrifugal force of the blade rotation of the wind turbine when the thickness is very thin, avoiding the shutdown of the wind turbine due to icing In the case of wind turbines, the power generation capacity of the wind turbines is increased. The coating is simple to prepare, low in cost and easy to popularize.

附图说明Description of drawings

图1为本发明一种应用于旋转风力机叶片除冰的涂层结构的示意图;Fig. 1 is the schematic diagram of a kind of coating structure that is applied to the deicing of rotary wind turbine blade of the present invention;

图2为本发明实施例中试验叶片结冰厚度随时间变化图;Fig. 2 is the time-varying diagram of the icing thickness of the test blade in the embodiment of the present invention;

图3为本发明实施例中试验风力机叶片结冰情况。Fig. 3 is the icing situation of the test wind turbine blade in the embodiment of the present invention.

图中:1-风力机叶片表面;2-刚性基底;3-弹性层;4-冰层;5-空气间隙。In the figure: 1-wind turbine blade surface; 2-rigid base; 3-elastic layer; 4-ice layer; 5-air gap.

具体实施方式detailed description

下面结合附图和实施例对本发明做进一步详细描述,需要指出的是,以下所述实施例旨在便于对本发明的理解,而对其不起任何限定作用。The present invention will be further described in detail below with reference to the accompanying drawings and embodiments. It should be noted that the following embodiments are intended to facilitate the understanding of the present invention, but do not limit it in any way.

如图1所示,一种应用于旋转风力机叶片除冰的涂层,由厚度0.4mm表面粗糙度0.3mm的刚性基底2和厚度0.4mm弹性模量10kPa的微变形弹性层3组成。As shown in Figure 1, a coating applied to the deicing of rotating wind turbine blades consists of a rigid substrate 2 with a thickness of 0.4 mm and a surface roughness of 0.3 mm, and a slightly deformed elastic layer 3 with a thickness of 0.4 mm and an elastic modulus of 10 kPa.

其中,刚性基底2与风力机叶片表面1热熔粘合后固化,形成多孔性的表面结构;弹性层3粘附在刚性基底2上,与刚性基底2相互勾联。由于刚性基底2表面粗糙度高,弹性层3不同位置厚度不同,受力下的变形量不同。Wherein, the rigid base 2 is thermally bonded to the wind turbine blade surface 1 and solidified to form a porous surface structure; the elastic layer 3 is adhered to the rigid base 2 and interlinked with the rigid base 2 . Due to the high surface roughness of the rigid base 2, the thickness of the elastic layer 3 is different at different positions, and the deformation amount under stress is different.

针对旋转风力机叶片的工作环境,为了提高除冰涂层的使用寿命,刚性基底2是一种固体可熔性聚合物树脂,其表面粗糙度高,弹性层3与刚性基底2相互勾联,使弹性层3与刚性基底2紧密固定。For the working environment of rotating wind turbine blades, in order to improve the service life of the deicing coating, the rigid base 2 is a solid meltable polymer resin with high surface roughness, and the elastic layer 3 is connected to the rigid base 2, Make the elastic layer 3 and the rigid base 2 tightly fixed.

为了提高除冰涂层的使用效果,弹性层3是硅酮橡胶与硅胶按照质量比9:1的组合。In order to improve the use effect of the deicing coating, the elastic layer 3 is a combination of silicone rubber and silica gel at a mass ratio of 9:1.

为了便于涂层的制作,弹性层3是硅酮橡胶和硅胶组合后,再用有机溶剂稀释后均匀的喷涂到刚性基底2上,有机溶剂为无水乙醇。In order to facilitate the coating, the elastic layer 3 is a combination of silicone rubber and silica gel, and then diluted with an organic solvent and evenly sprayed on the rigid substrate 2. The organic solvent is absolute ethanol.

为了进一步提高除冰涂层的使用效果,弹性层3是一种疏水的光滑表面,接触角115°~125°。In order to further improve the application effect of the deicing coating, the elastic layer 3 is a hydrophobic and smooth surface with a contact angle of 115°-125°.

为了保证除冰涂层的除冰效果,提高使用寿命,降低使用成本,涂层的厚度为0.8~1mm。涂层太薄,不能起到很好的除冰效果;涂层太厚,会影响涂层的使用寿命,还会破坏风力机叶片的气动特性,而且使用成本增加。In order to ensure the deicing effect of the deicing coating, improve the service life and reduce the use cost, the thickness of the coating is 0.8-1 mm. If the coating is too thin, it cannot achieve a good deicing effect; if the coating is too thick, the service life of the coating will be affected, and the aerodynamic characteristics of the wind turbine blades will be damaged, and the use cost will increase.

为了提高除冰涂层的使用效果,弹性层3在切向力的作用下发生变形,由于弹性层3不同位置厚度不同,受力下的变形量不同。In order to improve the application effect of the deicing coating, the elastic layer 3 is deformed under the action of the tangential force. Since the thickness of the elastic layer 3 is different at different positions, the amount of deformation under the force is different.

如图1所示,在局部区域,冰层4与弹性层3分离产生空气间隙5,在离心力和周期性重力的作用下,空气间隙5增大,冰层4的粘附力减少,同时随着结冰厚度的增加,冰块受到的离心力增大,最终冰层4在离心力的作用下脱落。As shown in Figure 1, in a local area, the ice layer 4 is separated from the elastic layer 3 to form an air gap 5, and under the action of centrifugal force and periodic gravity, the air gap 5 increases, and the adhesion force of the ice layer 4 decreases. With the increase of freezing thickness, the centrifugal force suffered by the ice cube increases, and finally the ice layer 4 falls off under the effect of centrifugal force.

为验证本发明的效果,在某试验小风机上涂覆局部应力涂层,将小风力机的三个叶片标号为一、二、三,其中叶片一不涂涂层,作为空白对照;叶片二和叶片三的叶尖处涂覆涂层。In order to verify the effect of the present invention, a local stress coating was applied on a certain experimental small wind machine, and the three blades of the small wind machine were labeled as one, two, and three, wherein blade one was not coated, as a blank control; blade two Coating is applied to the tip of blade three.

将涂有涂层的叶片装配到风力机上,在结冰气象条件下每隔一小时对叶片进行观测,记录风力机叶片的结冰厚度,叶片结冰厚度随时间变化如图2所示。The coated blades were assembled to the wind turbine, and the blades were observed every hour under icing weather conditions, and the icing thickness of the wind turbine blades was recorded. The change of the icing thickness of the blades with time is shown in Figure 2.

随着时间的增加,无涂层的叶片结冰厚度随时间增加,而有涂层的叶片结冰厚度变化不大。试验5h后风力机叶片结冰情况如图3所示,图中,(a)为叶片一的结冰情况,(b)为叶片二的结冰情况,(c)为叶片三的结冰情况。经过测量,叶片一无涂层,5h结冰厚度为57.0mm,叶片二和叶片三有涂层,5h结冰厚度分别为2.5mm和3.0mm,结冰厚度远小于叶片一。With the increase of time, the icing thickness of the uncoated blade increased with time, while the icing thickness of the coated blade did not change much. The icing condition of the blades of the wind turbine after 5 hours of the test is shown in Figure 3. In the figure, (a) is the icing condition of blade 1, (b) is the icing condition of blade 2, and (c) is the icing condition of blade 3 . After measurement, blade 1 has no coating, and the icing thickness is 57.0mm in 5h. Blade 2 and blade 3 have coating, and 5h icing thickness is 2.5mm and 3.0mm respectively, and the icing thickness is much smaller than blade 1.

上述实验的结果说明:本发明的除冰涂层可以明显减少叶片表面的冰块积累,可以让叶片更快地将冰块旋转甩脱,能够达到除冰的效果。The results of the above experiments show that the deicing coating of the present invention can significantly reduce the accumulation of ice cubes on the surface of the blades, allow the blades to rotate and shake off the ice cubes faster, and achieve the effect of deicing.

以上所述的实施例对本发明的技术方案和有益效果进行了详细说明,应理解的是以上所述仅为本发明的具体实施例,并不用于限制本发明,凡在本发明的原则范围内所做的任何修改、补充和等同替换,均应包含在本发明的保护范围之内。The embodiments described above have described the technical solutions and beneficial effects of the present invention in detail. It should be understood that the above descriptions are only specific embodiments of the present invention, and are not intended to limit the present invention. All within the scope of the principles of the present invention Any modifications, supplements and equivalent replacements should be included within the protection scope of the present invention.

Claims (7)

1. A coating applied to deicing of blades of a rotary wind turbine is characterized by comprising a rigid substrate with the thickness of 0.3-0.5 mm and the surface roughness of 0.2-0.4 mm and a micro-deformation elastic layer with the thickness of 0.3-0.5 mm and the elastic modulus of 5-20 kPa; the rigid substrate is used for being solidified after being hot-melted and bonded with the surface of the wind turbine blade to form a porous surface structure; the elastic layer is adhered to the rigid substrate and is mutually hooked with the rigid substrate;
after the coating is coated with ice, under the action of centrifugal force and periodic gravity, the elastic layer on the coating deforms, air pockets are generated between the elastic layer and the ice layer, the adhesion force of the ice layer is reduced, and the ice layer falls off under the action of the centrifugal force.
2. The coating as claimed in claim 1, wherein the rigid substrate is a solid meltable polymer resin.
3. The coating applied to deicing blades of rotating wind turbines as claimed in claim 1, wherein said elastomeric layer is a combination of silicone rubber and silicone rubber in a mass ratio of 9.
4. The coating applied to deicing blades of rotating wind turbines as claimed in claim 1, wherein the elastic layer is formed by combining silicone rubber and silica gel, and then uniformly spraying the silicone rubber and silica gel onto a rigid substrate after being diluted by an organic solvent.
5. The coating applied to deicing blades of rotating wind turbines as claimed in claim 1, wherein said elastomeric layer is a hydrophobic smooth surface having a contact angle of 115 ° to 125 °.
6. The coating applied to deicing blades of rotating wind turbines as claimed in claim 1, wherein the total thickness of the coating is 0.8mm to 1mm.
7. The manufacturing method of the deicing coating applied to the blades of the rotary wind turbines according to any one of claims 1 to 6, characterized by comprising the following steps of:
(1) Cleaning the surface of the wind turbine blade;
(2) Spraying heated solid meltable polymer resin on the surface of the wind turbine blade to form a rigid substrate with a porous surface structure; the thickness of the rigid substrate is 0.3mm to 0.5mm, and the surface roughness is 0.2mm to 0.4 mm;
(3) Mixing silicone rubber and silica gel according to a mass ratio of 9;
(4) Diluting the mixed silicone rubber and silica gel with an organic solvent according to a mass ratio of 3;
(5) Spraying an elastic layer on the rigid substrate; the thickness of the elastic layer is 0.3mm to 0.5mm, and the elastic modulus is 5-20 kPa;
(6) And forming a deicing coating after the elastic layer is aired, and mutually hooking the rigid substrate of the aired deicing coating and the elastic layer to prevent the elastic layer from falling off.
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Citations (1)

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Publication number Priority date Publication date Assignee Title
CN106769632A (en) * 2017-01-22 2017-05-31 哈尔滨工业大学 A kind of device and method of Fast Evaluation low freezing point elastic coating anti-ice cover ability

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WO2017196870A1 (en) * 2016-05-09 2017-11-16 Eric Loth Methods and systems for self-lubricating icephobic elastomer coatings
IL254269B (en) * 2017-08-31 2021-08-31 Rafael Advanced Defense Systems Ltd Non-icing surfaces

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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