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CN114171584A - Ga2O3 based heterojunction field effect transistor and preparation method - Google Patents

Ga2O3 based heterojunction field effect transistor and preparation method Download PDF

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CN114171584A
CN114171584A CN202111498547.5A CN202111498547A CN114171584A CN 114171584 A CN114171584 A CN 114171584A CN 202111498547 A CN202111498547 A CN 202111498547A CN 114171584 A CN114171584 A CN 114171584A
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周弘
王晨璐
燕庆龙
张进成
郝跃
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Xidian University
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/102Constructional design considerations for preventing surface leakage or controlling electric field concentration
    • H10D62/112Constructional design considerations for preventing surface leakage or controlling electric field concentration for preventing surface leakage due to surface inversion layers, e.g. by using channel stoppers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/80FETs having rectifying junction gate electrodes
    • H10D30/801FETs having heterojunction gate electrodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/102Constructional design considerations for preventing surface leakage or controlling electric field concentration
    • H10D62/103Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices
    • H10D62/105Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE] 
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/80Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
    • H10D62/82Heterojunctions
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Abstract

本发明公开了一种基于Ga2O3的异质结场效应晶体管,主要解决现有氧化镓基器件实际功率优值较低、功率损耗大的问题。其自下而上包括:源电极S、衬底层,漂移层和漏、栅电极,其中,衬底层采用厚度为500um~700um,浓度为1×1018~5×1018cm‑3的N型高掺β‑Ga2O3材料;漂移层采用厚度为5um~7um,浓度为1.5×1016~1×1017cm‑3的N型低掺β‑Ga2O3材料;该N型低掺β‑Ga2O3漂移层的两端分别设有P型NiO层,其与N型低掺β‑Ga2O3漂移层构成异质PN结。本发明提升了器件的击穿电压,增加器件功率优值,降低器件的功率损耗,可用于制备大功率增强型氧化镓器件。

Figure 202111498547

The invention discloses a Ga 2 O 3 -based heterojunction field effect transistor, which mainly solves the problems of low actual power figure of merit and large power loss of the existing gallium oxide-based device. It includes from bottom to top: source electrode S, substrate layer, drift layer, drain and gate electrodes, wherein the substrate layer adopts N-type with a thickness of 500um~700um and a concentration of 1×10 18 ~5×10 18 cm ‑3 Highly doped β-Ga 2 O 3 material; the drift layer is an N-type low-doped β-Ga 2 O 3 material with a thickness of 5um to 7um and a concentration of 1.5×10 16 to 1×10 17 cm 3 ; The two ends of the β-Ga 2 O 3 -doped drift layer are respectively provided with a P-type NiO layer, which forms a hetero PN junction with the N-type low-doped β-Ga 2 O 3 drift layer. The invention improves the breakdown voltage of the device, increases the power figure of merit of the device, reduces the power loss of the device, and can be used for preparing a high-power enhanced gallium oxide device.

Figure 202111498547

Description

Based on Ga2O3Heterojunction field effect transistor and preparation method thereof
Technical Field
The invention belongs to the technical field of semiconductor devices, and particularly relates to Ga2O3The heterojunction field effect transistor can be used for preparing a vertical enhancement mode gallium oxide device.
Technical Field
Ga2O3Is an ultra-wide band gap semiconductor material with 4.6-4.9eV, has a theoretical breakdown electric field strength of about 8MV/cm and is close to 250cm2Electron mobility of/Vs and Baliga figure of merit of more than 3000, and high breakdown voltage and high conversion efficiency can be obtained at the same time. While Ga2O3The material can also be obtained by mature and low cost melting method to obtain high quality bulk substrate, thus Ga2O3The base device is regarded as a powerful competitor in the power device market and becomes a hot spot of research in recent years.
Since Ga is2O3The material has a size of as small as 0.28-0.33meAnd an electron affinity of up to 4.0eV, Ga2O3The material can realize N-type doping with ideal conductivity and electron mobility, and Ga is used at present2O310 can be achieved by doping atoms of Si, Ge, Sn, F, Cl, etc15-1019Effective N-type semiconductor of power, but Ga2O3P-type doping of materials is difficult to achieve and remains a focus of research. Ga2O3Ga of the material is due to its very large effective hole mass and the valence band at deep levels2O3It is very difficult to realize P-type doping with high mobility, and the absence of P-type doping limits Ga to a great extent2O3Development of devices. To alleviate this deficiency, research has found that P-type NiO material and N-type Ga can be used2O3The material forms a heterogeneous PN junction to improve the power merit value of the device, but the current heterogeneous PN junction Ga2O3The base device is basically a horizontal structure which reduces the reliability of the device due to the existence of interface states and does not have the characteristics of low cost, high reliability and low costCan fully exert Ga2O3The advantage of a power figure of merit of greater than 3000 increases the useless power loss of the device. While Ga is absent due to the absence of P-type material2O3The basic device mainly works in a depletion mode, the subsequent circuit design is complex, and the device cannot be ensured to be in a safe working mode.
Disclosure of Invention
The present invention aims to overcome the defects of the prior art and provide a Ga-based material2O3The heterojunction field effect transistor and the preparation method thereof are used for increasing the power figure of merit of the device and reducing the power loss of the device.
In order to achieve the purpose, the technical scheme of the invention is as follows:
1. based on Ga2O3The heterojunction field effect transistor and the preparation method thereof comprise the following steps from bottom to top: source electrode S, substrate layer, drift layer and drain, gate electrode, its characterized in that:
the substrate layer is 500-700 um thick and 1 × 1018~5×1018cm-3N-type highly doped beta-Ga of2O3A material;
the drift layer adopts a thickness of 5 um-7 um and a concentration of 1.5 multiplied by 1016~1×1017cm-3N-type low doped beta-Ga of2O3A material;
the N-type low-doped beta-Ga2O3The two ends of the drift layer are respectively provided with a P-type NiO layer which is low-doped with the N-type beta-Ga2O3The drift layer forms a heterogeneous PN junction so as to increase the power figure of merit of the device and reduce the power loss of the device.
Further, the thickness of the NiO layer is 1-1.5 um, and the concentration is 2 x 1017~5×1018cm-3
Further, the gate electrode G is positioned at the upper part of the P-type NiO layer, and the drain electrode D is positioned between the gate electrodes G and is N-type low-doped beta-Ga2O3The upper part of (a).
2. Based on Ga2O3The method for manufacturing a Heterojunction Field Effect Transistor (HFET) comprises:
1) the thickness of the substrate is 500 um-700 um, the doping is 1 x 1018~5×1018cm-3The thickness of the drift layer is 5 um-7 um, and the concentration is 1.5 multiplied by 1016~1×1017cm-3Ga of (2)2O3Sequentially placing the epitaxial wafer into an acetone solution, an isopropanol solution and deionized water, respectively ultrasonically cleaning for 5min, and then blowing by using a nitrogen gun;
2) ga after washing2O3The back of the epitaxial wafer faces upwards, titanium with the thickness of 40 nm-70 nm and gold with the thickness of 80 nm-150 nm are sequentially deposited in an electron beam evaporation E-beam system, then the epitaxial wafer after electron beam evaporation is placed in an annealing furnace, and rapid annealing is carried out for 1min under the condition that the nitrogen flow rate is 3-5L/min and the temperature is 460-480 ℃, so that ohmic contact of a source electrode is formed;
3) annealing the Ga2O3Sequentially placing the epitaxial wafer into an acetone solution, an isopropanol solution and deionized water, respectively ultrasonically cleaning for 5min, and then blowing by using a nitrogen gun; then Ga is added2O3Photoetching the surface of the epitaxial wafer to form a drain electrode pattern;
4) post-lithographic Ga in E-beam evaporation2O3Depositing titanium with the thickness of 40 nm-70 nm and gold with the thickness of 80 nm-150 nm on the surface of the epitaxial wafer in sequence, performing ultrasonic cleaning in an acetone solution, an isopropanol solution and deionized water for 5min respectively to strip the drain metal, placing the drain metal into an annealing furnace, and performing rapid annealing for 1min under the conditions that the nitrogen flow rate is 3-5L/min and the temperature is 460-480 ℃ to form the ohmic contact of the drain.
5) In forming drain ohmic contact Ga2O3The surface of the epitaxial wafer is subjected to secondary photoetching to form a pattern to be etched, and the pattern is placed into an Inductively Coupled Plasma (ICP) system and BCl is utilized3Etching with Ar gas to a depth of 1-1.5 μm;
6) placing the etched epitaxial wafer into a magnetron sputtering sputter system, and carrying out Ar and O treatment at the radio frequency power of 150W2Bombarding the NiO target to form a P-type NiO coating on the etched surface of the NiO target in the atmosphere;
7) putting the epitaxial wafer with the P-type NiO coating film into an electron beam evaporation E-beam system to sequentially deposit nickel with the thickness of 40-80 nm and gold with the thickness of 80-150 nm so as to form a grid electrode;
8) depositing NiO and Ga after the grid metal2O3And respectively putting the epitaxial wafer into an acetone solution, an isopropanol solution and deionized water, and respectively carrying out ultrasonic cleaning for 15min for stripping to finish the manufacture of the device.
Compared with the prior art, the invention has the following advantages:
1. the invention adopts N-type Ga2O3The materials are used as a substrate and a drift layer, and the N-type Ga can be doped by introducing a P-type NiO material2O3A heterogeneous PN junction is formed, reverse electric leakage can be effectively restrained through the depletion effect of the PN junction, and therefore the breakdown voltage of the device is improved, the power excellent value of the device is greatly increased, and the power loss of the device is reduced.
2. The invention constructs a Ga-based2O3The enhancement mode is realized by the enhancement type field effect transistor made of the material and by turning off the device without bias voltage through a heterogeneous PN junction, and the subsequent circuit design is simplified.
3. In the invention, Ga is added in the preparation process2O3The three process steps of etching, NiO coating and grid metal deposition are placed after one-time photoetching, compared with the experimental process of the traditional one-time photoetching process, the experimental efficiency is greatly improved, meanwhile, the photoetching times are reduced, the exposure time of the device is shortened, the quantity of introduced impurities is reduced, and the reliability of the device is effectively improved.
Drawings
FIG. 1 is a schematic diagram of a heterojunction field effect transistor structure according to the present invention.
FIG. 2 is a schematic diagram of an implementation process for fabricating a heterojunction field effect transistor according to the present invention.
Detailed Description
The heterojunction field effect transistor structure and the preparation process of the present invention are further described in detail below with reference to the accompanying drawings.
Referring to fig. 1, the heterojunction field effect transistor of the present invention comprises: a P-type NiO layer, a substrate layer, a drift layer,A source electrode S, a drain electrode D, and a gate electrode G. Wherein, the substrate layer is 500 um-700 um thick and 1 × 1018~5×1018cm-3N-type highly doped beta-Ga of2O3A material; the drift layer is 5-7 um thick and 1.5 × 1016~1×1017cm-3N-type low doped beta-Ga of2O3Material of N-type highly doped beta-Ga2O3A layer above; the thickness of the P-type NiO layer is 1 um-1.5 um, and the concentration is 2 multiplied by 1017~5×1018cm-3Which is located in N-type low doped beta-Ga2O3Both ends of the upper part of the drift layer, and beta-Ga2O3The drift layer forms a heterogeneous PN junction so as to improve the breakdown voltage and increase the power optimal value; the gate electrode G is positioned on the upper part of the P-type NiO layer; n-type low-doped beta-Ga with drain electrode D positioned between gate electrodes G2O3An upper portion of the drift layer; the source electrode S is positioned in N type highly doped beta-Ga2O3A lower portion of the substrate layer.
Referring to fig. 2, the method of fabricating a heterojunction field effect transistor of the present invention gives the following three examples:
example 1 preparation of N-type beta-Ga2O3The substrate layer has a thickness of 500um and a doping of 5 × 1018cm-3N type beta-Ga2O3The drift layer has a thickness of 5 μm and a doping of 1.5X 1016cm-3And P-type NiO with the thickness of 1 μm and the doping of 2 × 1017cm-3A heterojunction field effect transistor of (1).
Step 1: cleaning of beta-Ga2O3And (c) an epitaxial wafer, as shown in fig. 2 (a).
The thickness of the substrate layer is 500um and the doping is 5 multiplied by 1018cm-3And a drift layer thickness of 5 μm and a doping concentration of 1.5X 1016cm-3Of beta-Ga2O3And (3) carrying out ultrasonic cleaning on the homoepitaxial wafer in an acetone solution, absolute ethyl alcohol and deionized water for 5min respectively in sequence, and then carrying out blow-drying by using nitrogen.
Step 2: and manufacturing a source ohmic electrode.
2.1) Ga after washing2O3Putting electron beams into the epitaxial wafer with the back side facing upwardsIn the evaporation E-beam system, the electron gun voltage is 7.5kV and the pressure is 1X 10-6Sequentially depositing Ti with the thickness of 60nm and Au with the thickness of 120nm under the condition of Pa;
2.2) putting the epitaxial wafer evaporated by the electron beam into an annealing furnace, and carrying out rapid annealing for 1min under the condition that the nitrogen flow rate is 3L/min and the temperature is 470 ℃ to form ohmic contact of a source electrode.
And step 3: cleaning of beta-Ga2O3And (c) an epitaxial wafer, as shown in fig. 2 (b).
Annealing the Ga2O3And ultrasonic cleaning the epitaxial wafer in an acetone solution, an isopropanol solution and deionized water for 5min respectively, and blow-drying by using a nitrogen gun.
And 4, step 4: and manufacturing a drain electrode ohmic electrode.
4.1) in Ga2O3Performing primary photoetching on the surface of the epitaxial wafer to form a drain electrode pattern, as shown in FIG. 2 (c);
4.2) etching the post-Ga2O3The epitaxial wafer was placed in an electron beam evaporation E-beam system at an electron gun voltage of 7.5kV and a pressure of 1X 10-6Sequentially depositing Ti with the thickness of 60nm and Au with the thickness of 120nm under the condition of Pa, wherein the growth rates of the Ti and the Au are respectively 0.3nm/s and 0.3nm/s, as shown in a figure 2 (d);
4.3) Ga grown with Ti and Au2O3Sequentially placing the epitaxial wafer in an acetone solution, an isopropanol solution and deionized water, and carrying out ultrasonic cleaning for 5min respectively to strip the drain metal;
4.4) placing the epitaxial wafer with the stripped drain metal into an annealing furnace, and carrying out rapid annealing for 1min under the condition that the nitrogen flow rate is 3L/min and the temperature is 470 ℃ to form a drain ohmic contact, as shown in figure 2 (e).
And 5: etching of beta-Ga2O3And (7) an epitaxial wafer.
5.1) Ga in forming ohmic contact of drain2O3Performing secondary photoetching on the surface of the epitaxial wafer to form a gate pattern, as shown in FIG. 2 (f);
5.2) Ga to be patterned into a gate electrode2O3Placing the epitaxial wafer into an Inductively Coupled Plasma (ICP) system, and setting the pressure of a reaction chamber to be 8mTorr and BCl3With Ar gasThe proportion is 2:1, the RF power is 150W, and the gate pattern is etched to a depth of 1 μm, as shown in FIG. 2 (g).
Step 6: NiO grows by sputtering.
Putting the etched sample wafer into a magnetron sputtering sputter system, and arranging Ar and O2The flow rate ratio is 5: 1. the pressure of the reaction chamber is 0.5Pa, the radio frequency power is 150W, and the NiO target is bombarded to carry out NiO coating, namely the NiO coating is carried out on the etched surface with the thickness of 1 mu m and the doping concentration of 2 multiplied by 1017cm-3FIG. 2(h) shows the P-type NiO plating film.
And 7: and manufacturing a grid electrode.
7.1) putting the coated sample wafer into an electron beam evaporation E-beam system, wherein the voltage of an electron gun is 7.5kV, and the pressure is 1 multiplied by 10-6Setting the growth rates of Ni and Au to be 0.3 and 0.3nm/s respectively under the condition of Pa, and sequentially depositing Ni with the thickness of 60nm and Au with the thickness of 120nm on the surface of the sample wafer after film plating, as shown in figure 2 (i);
7.2) placing the sample wafer deposited with Ni and Au in an acetone solution, an isopropanol solution and deionized water in sequence, and carrying out ultrasonic cleaning for 5min respectively to strip the gate metal, as shown in figure 2(j), thereby completing the preparation of the device.
Example 2 preparation of N-type beta-Ga2O3The substrate layer thickness is 600um and the doping is 2X 1018cm-3The drift layer thickness is 7 μm and the doping is 1.5X 1016cm-3And P-type NiO with a thickness of 1.5 μm and a doping of 5 × 1017cm-3A heterojunction field effect transistor of (1).
The method comprises the following steps: n-type beta-Ga2O3Homoepitaxial wafer cleaning
The substrate layer thickness was chosen to be 600um and the doping 2 x 1018cm-3And a drift layer thickness of 7 μm and a doping concentration of 1.5X 1016cm-3Of the N-type beta-Ga2O3The homoepitaxial wafer, as shown in fig. 2(a), was sequentially subjected to ultrasonic cleaning in acetone solution, absolute ethanol, and deionized water for 5min, and then blown dry with nitrogen.
Step two: and manufacturing a source ohmic electrode.
Ga after washing2O3The epitaxial wafer is placed into an electron beam evaporation E-beam system with the back side facing upwards, and the voltage of an electron gun is 7.5kV, and the pressure is 2 multiplied by 10-6Sequentially depositing Ti with the thickness of 40nm and Au with the thickness of 150nm under the condition of Pa; and then the silicon substrate is placed into an annealing furnace, and rapid annealing is carried out for 1min under the condition that the nitrogen flow rate is 4L/min and the temperature is 475 ℃, so that ohmic contact of a source electrode is formed.
Step three: cleaning of beta-Ga2O3And (c) an epitaxial wafer, as shown in fig. 2 (b).
This step is the same as step 3 of example 1.
Step four: and manufacturing a drain electrode ohmic electrode.
In Ga2O3Performing primary photoetching on the surface of the epitaxial wafer to form a drain electrode pattern, as shown in FIG. 2 (c);
then the photoetched epitaxial wafer is put into an electron beam evaporation E-beam system, and the voltage of an electron gun is set to be 7.5kV, and the pressure is set to be 2 multiplied by 10-6Pa, Ti and Au growth rate of 0.2 and 0.2nm/s, depositing Ti with thickness of 40nm and Au with thickness of 150nm on the drain electrode pattern in sequence, as shown in figure 2(d), and placing the drain electrode pattern in acetone solution, isopropanol solution and deionized water in sequence to perform ultrasonic cleaning for 5min respectively for stripping the drain electrode metal;
then the stripped epitaxial wafer is put into an annealing furnace, and rapid annealing is carried out for 1min under the condition that the nitrogen flow rate is 4L/min and the temperature is 475 ℃, so as to form the drain electrode ohmic contact, as shown in figure 2(e)
Step five: etching of beta-Ga2O3And (7) an epitaxial wafer.
In Ga2O3Performing secondary photoetching on the surface of the epitaxial wafer to form a gate pattern, as shown in FIG. 2 (f);
then putting the sample with the drain electrode pattern into an Inductively Coupled Plasma (ICP) system, wherein the pressure of the reaction chamber is 10mTorr, BCl3And Ar gas ratio 3: 1, etching the gate pattern with a depth of 1.5 μm under the condition of 150W of RF power, as shown in FIG. 2 (g).
Step six: NiO grows by sputtering.
Placing the etched epitaxial wafer into a magnetron sputtering sputter system, and arranging Ar and O2Is 5: 2. the technological conditions that the pressure of the reaction chamber is 0.6Pa and the radio frequency power is 150W are adopted, the NiO target material is bombarded, the thickness of the NiO target material is 1.5 mu m, the doping concentration is 5 multiplied by 1017cm-3FIG. 2(h) shows the P-type NiO plating film.
Step seven: and manufacturing a grid electrode.
7.1) putting the coated sample wafer into an electron beam evaporation E-beam system, wherein the voltage of an electron gun is 7.5kV, and the pressure is 2 multiplied by 10-6Sequentially depositing Ni with the thickness of 40nm and Au with the thickness of 150nm on the NiO layer under the condition of Pa, wherein the growth rates of the Ni and the Au are respectively 0.2 and 0.2nm/s, and shown in a figure 2 (i);
7.2) carrying out ultrasonic cleaning on the sample wafer subjected to metal evaporation in acetone solution, isopropanol solution and deionized water for 5min respectively to carry out grid metal stripping, as shown in figure 2(j), and finishing the preparation of the device.
Example 3 production of N-type beta-Ga2O3The substrate layer has a thickness of 700 μm and a doping of 1X 1018cm-3N type beta-Ga2O3The drift layer thickness is 5 μm and the doping is 1 × 1017cm-3And P-type NiO with a thickness of 1 μm and a doping of 5 × 1018cm-3A heterojunction field effect transistor of (1).
Step A: cleaning of beta-Ga2O3And (c) an epitaxial wafer, as shown in fig. 2 (a).
The substrate layer thickness was chosen to be 700 μm and the doping 1X 1018cm-3And a drift layer thickness of 5 μm and a doping concentration of 1 × 1017cm-3Of the N-type beta-Ga2O3And (3) carrying out ultrasonic cleaning on the homoepitaxial wafer in an acetone solution, absolute ethyl alcohol and deionized water for 5min respectively in sequence, and then carrying out blow-drying by using nitrogen.
And B: and manufacturing a source ohmic electrode.
B1) Ga after washing2O3The back of the epitaxial wafer faces upwards, and the epitaxial wafer is placed into an electron beam evaporation E-beam system, and the voltage of an electron gun is set to be 7.5kV, and the pressure is set to be 5 multiplied by 10-6Pa, sequentially depositing Ti with the thickness of 70nm and Au with the thickness of 80nm on the back of the epitaxial wafer;
B2) and (3) putting the sample wafer subjected to electron beam evaporation into an annealing furnace, and performing rapid annealing for 1min at the temperature of 480 ℃ under the condition of the nitrogen flow rate of 5L/min to form ohmic contact of the source electrode.
And C: cleaning of beta-Ga2O3Swatch, as in fig. 2 (b).
This step is the same as step 3 of example 1.
Step D: and manufacturing a drain electrode ohmic electrode.
D1) In Ga2O3Performing one-time photoetching on the surface of the sample wafer to form a drain electrode pattern, as shown in FIG. 2 (c);
D2) placing the sample wafer with the drain electrode pattern into an electron beam evaporation E-beam system, and controlling the electron gun voltage to be 7.5kV and the pressure to be 5 × 10-6Controlling the growth rates of Ti and Au to be 0.1 and 0.1nm/s respectively under the process condition of Pa, and sequentially depositing Ti with the thickness of 70nm and Au with the thickness of 80nm on the drain electrode pattern, as shown in figure 2 (d);
D3) sequentially placing the sample wafer subjected to electron beam evaporation into an acetone solution, an isopropanol solution and deionized water, and carrying out ultrasonic cleaning for 5min respectively to strip the drain metal;
D4) placing the stripped sample wafer into an annealing furnace, performing rapid annealing at 480 deg.C under nitrogen flow rate of 5L/min to form drain ohmic contact, as shown in FIG. 2(e)
Step E: etching of beta-Ga2O3And (7) an epitaxial wafer.
E1) Ga in forming drain ohmic contact2O3Carrying out secondary photoetching on the surface of the sample wafer to form a grid pattern, as shown in figure 2 (f);
E2) ga to be patterned into gate electrode2O3Placing the sample into inductively coupled plasma ICP system, and using BCl3Etching with Ar gas under 12mTorr, BCl pressure in the reaction chamber3And Ar gas ratio of 4:1, etching the gate pattern with a depth of 1 μm under the condition of 150W of RF power, as shown in FIG. 2 (g).
Step F: NiO grows by sputtering.
Putting the etched sample wafer into a magnetron sputtering sputter system, and arranging Ar and O2The flow rate ratio is 5: 4. the pressure of the reaction chamber is 0.8Pa, and the radio frequency power is 150WThe process conditions are that the thickness of the etched surface is 1 mu m, the doping concentration is 5 multiplied by 1018cm-3FIG. 2(h) shows the P-type NiO plating film.
Step G: and manufacturing a grid electrode.
G1) Putting the NiO-coated sample wafer into an electron beam evaporation E-beam system, wherein the voltage of an electron gun is 7.5kV, and the pressure is 5 multiplied by 10-6Controlling the growth rates of Ni and Au to be 0.1 and 0.1nm/s respectively under the condition of Pa, and sequentially depositing Ni with the thickness of 80nm and Au with the thickness of 80nm on the surface of the NiO plating film, as shown in figure 2 (i);
G2) and (5) sequentially placing the sample wafer subjected to metal evaporation into an acetone solution, an isopropanol solution and deionized water, and carrying out ultrasonic cleaning for 5min respectively to strip the gate metal, as shown in figure 2(j), thereby completing the preparation of the device.
The above are only three embodiments of the present invention, and do not limit the present invention in any way. It will be apparent to persons skilled in the relevant art that various modifications and changes in form and detail can be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (7)

1.一种基于Ga2O3的异质结场效应晶体管,自下而上包括:源电极S、衬底层,漂移层和漏、栅电极,其特征在于:1. a heterojunction field effect transistor based on Ga 2 O 3 , comprising from bottom to top: source electrode S, substrate layer, drift layer and drain, gate electrode, it is characterized in that: 所述衬底层,采用厚度为500um~700um,浓度为1×1018~5×1018cm-3的N型高掺β-Ga2O3材料;The substrate layer adopts an N-type highly doped β-Ga 2 O 3 material with a thickness of 500um to 700um and a concentration of 1×10 18 to 5×10 18 cm -3 ; 所述漂移层,采用厚度为5um~7um,浓度为1.5×1016~1×1017cm-3的N型低掺β-Ga2O3材料;The drift layer adopts N-type low-doped β-Ga 2 O 3 material with a thickness of 5um to 7um and a concentration of 1.5×10 16 to 1×10 17 cm -3 ; 所述N型低掺β-Ga2O3漂移层的两端分别设有P型NiO层,其与N型低掺β-Ga2O3漂移层构成异质PN结,以增加器件功率优值,降低器件的功率损耗。Both ends of the N-type low-doped β-Ga 2 O 3 drift layer are respectively provided with a P-type NiO layer, which forms a hetero-PN junction with the N-type low-doped β-Ga 2 O 3 drift layer to increase the power efficiency of the device. value, reducing the power loss of the device. 2.根据权利要求书1所述的场效应晶体管,其特征在于:所述NiO层的厚度为1~1.5um,浓度为2×1017~5×1018cm-32 . The field effect transistor according to claim 1 , wherein the thickness of the NiO layer is 1-1.5 μm, and the concentration is 2×10 17 ˜5×10 18 cm −3 . 3 . 3.根据权利要求书1所述的场效应晶体管,其特征在于:所述栅电极G位于P型NiO层的上部,漏电极D位于栅电极G之间的N型低掺β-Ga2O3的上部。3 . The field effect transistor according to claim 1 , wherein the gate electrode G is located on the upper part of the P-type NiO layer, and the drain electrode D is located between the gate electrodes G and N-type low-doped β-Ga 2 O. 4 . top of 3 . 4.一种基于Ga2O3的异质结场效应晶体管制作方法,其特征在于,包括:4. A method for making a heterojunction field effect transistor based on Ga 2 O 3 , comprising: 1)将衬底厚度为500um~700um,掺杂为1×1018~5×1018cm-3和漂移层厚度为5um~7um,浓度为1.5×1016~1×1017cm-3的Ga2O3外延片,依次放入丙酮溶液、异丙醇溶液和去离子水中各超声清洗5min,再利用氮气枪吹干;1) The thickness of the substrate is 500um~700um, the doping is 1×10 18 ~5×10 18 cm -3 and the thickness of the drift layer is 5um~7um and the concentration is 1.5×10 16 ~1×10 17 cm -3 The Ga 2 O 3 epitaxial wafer was sequentially placed in acetone solution, isopropanol solution and deionized water for ultrasonic cleaning for 5 min each, and then dried with a nitrogen gun; 2)将清洗后的Ga2O3外延片背面朝上,在电子束蒸发E-beam系统中依次淀积厚度为40nm~70nm的钛和厚度为80nm~150nm的金,再将电子束蒸发后的外延片放入退火炉内,在氮气流速为3~5L/min温度为470℃~480℃情况下进行1min快速退火,形成源极欧姆接触;2) With the back of the cleaned Ga 2 O 3 epitaxial wafer facing up, deposit titanium with a thickness of 40nm to 70nm and gold with a thickness of 80nm to 150nm in sequence in an electron beam evaporation E-beam system, and then evaporate the electron beam. The epitaxial wafer is put into the annealing furnace, and the nitrogen flow rate is 3~5L/min and the temperature is 470℃~480℃ for 1min rapid annealing to form the source ohmic contact; 3)将退火后的Ga2O3外延片依次在放入丙酮溶液、异丙醇溶液和去离子水中各超声清洗5min,再利用氮气枪吹干;再在该Ga2O3外延片表面进行光刻,形成漏极图形; 3 ) Put the annealed Ga 2 O 3 epitaxial wafer into acetone solution, isopropanol solution and deionized water for ultrasonic cleaning for 5min in turn, and then use a nitrogen gun to dry it ; Photolithography to form drain patterns; 4)在电子束蒸发E-beam系统中对光刻后的Ga2O3外延片表面依次淀积厚度为40nm~70nm的钛和厚度为80nm~150nm的金,再分别在丙酮溶液、异丙醇溶液和去离子水中各超声清洗5min进行漏极金属剥离,再将其放入退火炉内,在氮气流速为3~5L/min、温度为470℃~480℃条件下进行1min的快速退火,形成漏极欧姆接触。4) In the electron beam evaporation E-beam system, titanium with a thickness of 40nm-70nm and gold with a thickness of 80nm-150nm are sequentially deposited on the surface of the photolithographic Ga 2 O 3 epitaxial wafer, and then respectively in acetone solution, isopropyl The drain metal was stripped by ultrasonic cleaning in alcohol solution and deionized water for 5 min each, and then placed in an annealing furnace for 1 min of rapid annealing at a nitrogen flow rate of 3 to 5 L/min and a temperature of 470 °C to 480 °C. A drain ohmic contact is formed. 5)在形成漏极欧姆接触Ga2O3的外延片表面进行二次光刻,形成待刻蚀图形,再将其放入电感耦合等离子体ICP系统中,利用BCl3和Ar气体进行深度为1μm~1.5μm的刻蚀;5) Perform secondary photolithography on the surface of the epitaxial wafer where the drain ohmic contact Ga 2 O 3 is formed to form the pattern to be etched, and then put it into the inductively coupled plasma ICP system, and use BCl 3 and Ar gas to conduct a depth of 1μm~1.5μm etching; 6)将刻蚀后的外延片放入磁控溅射sputter系统中,在射频功率为150W的Ar和O2氛围下,通过对NiO靶材进行轰击以在其刻蚀表面形成P型NiO镀膜;6) Put the etched epitaxial wafer into a magnetron sputtering sputter system, and under the atmosphere of Ar and O 2 with a radio frequency power of 150W, the NiO target is bombarded to form a P-type NiO coating on its etched surface ; 7)将具有P型NiO镀膜的外延片放入电子束蒸发E-beam系统中依次淀积厚度为40nm~80nm的镍和80nm~150nm的金,以形成栅极电极;7) Putting the epitaxial wafer with the P-type NiO coating into the electron beam evaporation E-beam system and depositing nickel with a thickness of 40nm to 80nm and gold with a thickness of 80nm to 150nm in turn to form a gate electrode; 8)将淀积NiO、栅极金属后的Ga2O3外延片分别放入丙酮溶液、异丙醇溶液和去离子水中各超声清洗15min进行剥离,完成器件制作。8) Put the Ga 2 O 3 epitaxial wafer after deposition of NiO and gate metal into acetone solution, isopropanol solution and deionized water respectively for ultrasonic cleaning for 15 minutes to peel off to complete the device fabrication. 5.根据权利要求4所述的方法,其中(5)中采用电感耦合等离子体ICP系统进行Ga2O3刻蚀,其工艺条件如下:5. method according to claim 4, wherein adopt inductively coupled plasma ICP system to carry out Ga 2 O 3 etching in (5), its technological condition is as follows: 反应室压强为8mTorr~12mTorr;The pressure of the reaction chamber is 8mTorr~12mTorr; 反应室气体为BCl3和Ar;The reaction chamber gases are BCl 3 and Ar; BCl3与Ar的流速比例为2:1~4:1;The flow rate ratio of BCl 3 to Ar is 2:1~4:1; RF射频源功率为150W。The RF RF source power is 150W. 6.根据权利要求4所述的方法,其中(6)中在磁控溅射sputter系统中进行NiO镀膜,其工艺条件如下:6. method according to claim 4, wherein in (6), carry out NiO coating in magnetron sputtering sputter system, and its processing condition is as follows: 反应室压强为0.5Pa~0.8Pa;The pressure of the reaction chamber is 0.5Pa ~ 0.8Pa; 反应室气体为Ar、O2、CDA;The gas in the reaction chamber is Ar, O 2 , CDA; Ar与O2气体流速比例为5:1~5:4;The ratio of Ar to O 2 gas flow rate is 5:1~5:4; RF射频源功率为150W。The RF RF source power is 150W. 7.根据权利要求4所述的方法,其中(2)、(4)和(7)中在电子束蒸发E-beam系统中进行金属蒸发,其工艺条件如下:7. The method according to claim 4, wherein metal evaporation is carried out in an electron beam evaporation E-beam system in (2), (4) and (7), and its process conditions are as follows: 电子枪电压为7.5kV;The electron gun voltage is 7.5kV; 反应腔腔内压强为1×10-6~5×10-6Pa。The pressure in the reaction chamber is 1×10 -6 to 5×10 -6 Pa.
CN202111498547.5A 2021-12-09 2021-12-09 Ga2O3 based heterojunction field effect transistor and preparation method Pending CN114171584A (en)

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