CN113963833B - Heat pump evaporation treatment system and method for radioactive waste liquid treatment - Google Patents
Heat pump evaporation treatment system and method for radioactive waste liquid treatment Download PDFInfo
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Abstract
Description
技术领域Technical field
本公开涉及废液处理技术领域,具体涉及一种用于放射性废液处理的热泵蒸发处理系统及方法。The present disclosure relates to the technical field of waste liquid treatment, and in particular to a heat pump evaporation treatment system and method for radioactive waste liquid treatment.
背景技术Background technique
随着科学技术的进步,核能作为极具推广价值的清洁能源,被广泛运用于诸多领域。在核能的生产过程中,核燃料循环过程中会产生放射性废液,放射性废液中含有少量的放射性核素以及不同浓度的盐分,对人体及环境有一定危害,因此在排放之前需要进行净化处理。With the advancement of science and technology, nuclear energy, as a clean energy with great promotion value, is widely used in many fields. In the production process of nuclear energy, radioactive waste liquid will be produced during the nuclear fuel cycle. The radioactive waste liquid contains a small amount of radionuclides and salts of different concentrations, which is harmful to the human body and the environment. Therefore, it needs to be purified before discharge.
目前用于放射性废液处理的方法主要是蒸发浓缩法,该方法将经过预热的放射性废液送入蒸发器,利用高温蒸汽对蒸发器进行加热,使得放射性废液分离为蒸汽和浓缩液,蒸汽经冷凝后直接排放,浓缩液作进一步处理。The current method used to treat radioactive waste liquid is mainly the evaporation concentration method. This method sends the preheated radioactive waste liquid into the evaporator, and uses high-temperature steam to heat the evaporator, so that the radioactive waste liquid is separated into steam and concentrated liquid. The steam is directly discharged after condensation, and the concentrated liquid is further processed.
中国专利CN204303367U公开了一种低水平放射性废液处理系统,该系统中设置了蒸汽压缩机和电蒸汽发生器,能够在无需外部蒸汽供给的情况下,通过消耗电能为发射性废液的蒸发过程提供加热蒸汽,因而具有较好的节能效果。Chinese patent CN204303367U discloses a low-level radioactive waste liquid treatment system. The system is equipped with a steam compressor and an electric steam generator, which can evaporate the radioactive waste liquid by consuming electrical energy without the need for external steam supply. Provides heating steam, thus having better energy saving effect.
然而,在实现本公开的过程中,发明人发现上述系统中的电蒸汽发生器存在空罐干烧或满罐溢出的问题。However, in the process of realizing the present disclosure, the inventor discovered that the electric steam generator in the above system has problems of dry burning of the empty tank or overflowing of the full tank.
发明内容Contents of the invention
本公开的目的是解决已有放射性废液处理系统中存在的电蒸汽发生器空罐干烧或满罐溢出的问题,提供一种用于放射性废液处理的热泵蒸发处理系统及方法。The purpose of this disclosure is to solve the problems of dry burning of empty electric steam generator tanks or overflowing of full tanks existing in existing radioactive waste liquid treatment systems, and to provide a heat pump evaporation treatment system and method for radioactive waste liquid treatment.
为了实现上述目的,本公开提供一种用于放射性废液处理的热泵蒸发处理系统,该系统包括第一预热器、第二预热器、蒸发器、蒸汽压缩机、电蒸汽发生器和冷凝液控制装置,所述第一预热器具有第一原液室和第一预热室,所述第二预热器具有第二原液室和第二预热室,所述蒸发器具有蒸发室和加热室;In order to achieve the above objects, the present disclosure provides a heat pump evaporation treatment system for radioactive waste liquid treatment, which system includes a first preheater, a second preheater, an evaporator, a steam compressor, an electric steam generator and a condensation unit. Liquid control device, the first preheater has a first raw liquid chamber and a first preheating chamber, the second preheater has a second raw liquid chamber and a second preheating chamber, the evaporator has an evaporation chamber and heating chamber;
所述第一原液室、所述第二原液室、所述蒸发室和所述蒸汽压缩机依次连通,所述蒸汽压缩机的出口以及所述电蒸汽发生器的补偿蒸汽出口分别与所述加热室的入口连通,所述加热室的蒸汽出口与所述第二预热室的入口连通,所述加热室的冷凝液出口以及所述第二预热室的出口分别与所述电蒸汽发生器的冷凝液入口连通,所述电蒸汽发生器的冷凝液出口与所述第一预热室的入口连通;The first raw liquid chamber, the second raw liquid chamber, the evaporation chamber and the steam compressor are connected in sequence, and the outlet of the steam compressor and the compensation steam outlet of the electric steam generator are respectively connected with the heating The inlet of the chamber is connected, the steam outlet of the heating chamber is connected with the inlet of the second preheating chamber, the condensate outlet of the heating chamber and the outlet of the second preheating chamber are connected with the electric steam generator respectively. The condensate inlet of the electric steam generator is connected with the inlet of the first preheating chamber;
其中,所述冷凝液控制装置包括:Wherein, the condensate control device includes:
冷凝液流量调节阀,设置于所述电蒸汽发生器的冷凝液出口与所述第一预热室的入口之间,用于对进入所述第一预热室中的所述蒸汽冷凝液的流量进行调节;A condensate flow regulating valve is provided between the condensate outlet of the electric steam generator and the inlet of the first preheating chamber, and is used to control the flow of the steam condensate entering the first preheating chamber. Flow is regulated;
液位传感器,设置于所述电蒸汽发生器中,用于测量对所述电蒸汽发生器中的液位;以及A liquid level sensor, disposed in the electric steam generator, for measuring the liquid level in the electric steam generator; and
控制器,分别与所述冷凝液流量调节阀和所述液位传感器连接,用于从所述液位传感器处获取所述电蒸汽发生器内的实际液位,并基于所述实际液位,对所述冷凝液流量调节阀的开度进行调节,以对进入所述第一预热室中的所述蒸汽冷凝液的流量进行调节。A controller, respectively connected to the condensate flow regulating valve and the liquid level sensor, for obtaining the actual liquid level in the electric steam generator from the liquid level sensor, and based on the actual liquid level, The opening of the condensate flow regulating valve is adjusted to adjust the flow of the steam condensate entering the first preheating chamber.
可选地,所述系统还包括供料槽、净化塔、热水泵和外排管道;Optionally, the system also includes a feed tank, a purification tower, a hot water pump and an external discharge pipe;
所述供料槽的出口与所述第一原液室的入口连通;The outlet of the feed tank is connected with the inlet of the first raw liquid chamber;
所述净化塔设置在所述蒸发室和所述蒸汽压缩机之间,所述净化塔的入口与所述蒸发室的出口连通,所述净化塔的出口与所述蒸汽压缩机的入口连通;The purification tower is arranged between the evaporation chamber and the steam compressor, the inlet of the purification tower is connected to the outlet of the evaporation chamber, and the outlet of the purification tower is connected to the inlet of the steam compressor;
所述热水泵设置在所述电蒸汽发生器和所述第一预热室之间,所述热水泵的入口与所述电蒸汽发生器的冷凝液出口连通,所述热水泵的出口与所述第一预热室的入口连通,用于将所述电蒸汽发生器中的蒸汽冷凝液送入所述第一预热室中;The hot water pump is disposed between the electric steam generator and the first preheating chamber, the inlet of the hot water pump is connected to the condensate outlet of the electric steam generator, and the outlet of the hot water pump is connected to the condensate outlet of the electric steam generator. The inlet of the first preheating chamber is connected for sending the steam condensate in the electric steam generator into the first preheating chamber;
所述外排管道与所述第一预热室的出口连通。The outer discharge pipe is connected with the outlet of the first preheating chamber.
本公开还提供采用上述任意一项所述的系统处理放射性废液的方法,该方法包括:The present disclosure also provides a method for treating radioactive waste liquid using any one of the systems described above, which method includes:
利用所述控制器从所述液位传感器处获取所述电蒸汽发生器内的实际液位;utilizing the controller to obtain the actual liquid level in the electric steam generator from the liquid level sensor;
将所述实际液位与预设液位进行比对;Compare the actual liquid level with the preset liquid level;
在所述实际液位低于所述预设液位的情况下,利用所述控制器控制所述冷凝液流量调节阀以减小所述冷凝液流量调节阀的开度;When the actual liquid level is lower than the preset liquid level, use the controller to control the condensate flow regulating valve to reduce the opening of the condensate flow regulating valve;
在所述实际液位高于所述预设液位的情况下,利用所述控制器控制所述冷凝液流量调节阀以增大所述冷凝液流量调节阀的开度。When the actual liquid level is higher than the preset liquid level, the controller is used to control the condensate flow regulating valve to increase the opening of the condensate flow regulating valve.
可选地,所述预设液位为所述电蒸汽发生器内部深度的50~65%,优选为55~60%。Optionally, the preset liquid level is 50-65% of the internal depth of the electric steam generator, preferably 55-60%.
可选地,在对所述冷凝液流量调节阀的开度进行调节时,调节幅度为所述冷凝液流量调节阀总开度为25~35%。Optionally, when adjusting the opening of the condensate flow regulating valve, the adjustment range is such that the total opening of the condensate flow regulating valve is 25% to 35%.
可选地,所述方法还包括:Optionally, the method also includes:
将待处理的放射性废液依次送入所述第一预热器的第一原液室和所述第二预热器的第二原液室中进行预热处理;Send the radioactive waste liquid to be treated sequentially into the first raw liquid chamber of the first preheater and the second raw liquid chamber of the second preheater for preheating treatment;
使预热后的所述放射性废液进入所述蒸发器的蒸发室中进行蒸发处理,得到二次蒸汽和浓缩废液;Let the preheated radioactive waste liquid enter the evaporation chamber of the evaporator for evaporation treatment to obtain secondary steam and concentrated waste liquid;
使所述二次蒸汽进入所述蒸汽压缩机中进行加压升温处理,得到高温蒸汽,并将所述高温蒸汽作为热源返回所述蒸发器的加热室中进行换热;Let the secondary steam enter the steam compressor for pressure and temperature raising treatment to obtain high-temperature steam, and return the high-temperature steam as a heat source to the heating chamber of the evaporator for heat exchange;
将所述加热室中部分未冷凝的所述高温蒸汽和不凝气作为热源送入所述第二预热器的第二预热室中进行换热;Send the partially uncondensed high-temperature steam and non-condensable gas in the heating chamber as a heat source into the second preheating chamber of the second preheater for heat exchange;
将所述加热室中换热产生的蒸汽冷凝液以及所述第二预热室中换热产生的蒸汽冷凝液分别送入所述电蒸汽发生器中;Send the steam condensate generated by heat exchange in the heating chamber and the steam condensate generated by heat exchange in the second preheating chamber to the electric steam generator respectively;
使所述电蒸汽发生器中的部分蒸汽冷凝液进行蒸发得到补偿蒸汽,使所述补偿蒸汽作为热源进入所述蒸发器的加热室中进行换热;Evaporate part of the steam condensate in the electric steam generator to obtain compensation steam, and use the compensation steam as a heat source to enter the heating chamber of the evaporator for heat exchange;
使所述电蒸汽发生器中的部分蒸汽冷凝液作为热源进入所述第一预热器的第一预热室中进行换热,换热后的蒸汽冷凝液从所述第一预热室的出口进行排放。Part of the steam condensate in the electric steam generator is used as a heat source to enter the first preheating chamber of the first preheater for heat exchange, and the heat-exchanged steam condensate is discharged from the first preheating chamber. Export for discharge.
可选地,经所述第一预热器预热后,所述放射性废液的温度升高至70℃~85℃,经所述第二预热器预热后,所述放射性废液的温度升高至90℃~98℃。Optionally, after being preheated by the first preheater, the temperature of the radioactive waste liquid rises to 70°C to 85°C, and after being preheated by the second preheater, the temperature of the radioactive waste liquid is The temperature rises to 90℃~98℃.
可选地,经所述蒸汽压缩机进行加压升温处理后,所述高温蒸汽的压力为50kPa~80kPa,温度为110℃~120℃。Optionally, after the steam compressor performs pressure and temperature raising treatment, the pressure of the high-temperature steam is 50kPa˜80kPa, and the temperature is 110°C˜120°C.
可选地,从所述电蒸汽发生器进入所述第一预热室的蒸汽冷凝液的温度为110℃~120℃;Optionally, the temperature of the steam condensate entering the first preheating chamber from the electric steam generator is 110°C to 120°C;
从所述第一预热室的出口进行排放的蒸汽冷凝液的温度为40℃~55℃。The temperature of the steam condensate discharged from the outlet of the first preheating chamber is 40°C to 55°C.
可选地,所述补偿蒸汽的温度为110℃~120℃。Optionally, the temperature of the compensation steam is 110°C to 120°C.
通过上述技术方案,本公开提供的热泵蒸发处理系统中设有冷凝液控制装置,能够实时监测电蒸汽发生器中的实际液位,并基于所述实际液位对流出电蒸汽发生器的蒸汽冷凝液的流量进行调节,这能够有效避免电蒸汽发生器空罐干烧或满罐溢出等问题的出现,有利于延长设备的使用寿命。Through the above technical solution, the heat pump evaporation processing system provided by the present disclosure is provided with a condensate control device, which can monitor the actual liquid level in the electric steam generator in real time, and condense the steam flowing out of the electric steam generator based on the actual liquid level. The flow of liquid is adjusted, which can effectively avoid problems such as dry burning of empty electric steam generator tanks or overflow of full tanks, and is beneficial to extending the service life of the equipment.
本公开的其他特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the present disclosure will be described in detail in the detailed description that follows.
附图说明Description of the drawings
附图是用来提供对本公开的进一步理解,并且构成说明书的一部分,与下面的具体实施方式一起用于解释本公开,但并不构成对本公开的限制。在附图中:The accompanying drawings are used to provide a further understanding of the present disclosure and constitute a part of the specification. They are used to explain the present disclosure together with the following specific embodiments, but do not constitute a limitation of the present disclosure. In the attached picture:
图1示意性示出了根据本公开实施例的一种用于放射性废液处理的热泵蒸发处理系统的结构示意图;Figure 1 schematically shows a structural diagram of a heat pump evaporation treatment system for radioactive waste liquid treatment according to an embodiment of the present disclosure;
图2示意性示出了根据本公开实施例的一种冷凝液处理流路的结构示意图。FIG. 2 schematically shows a structural diagram of a condensate treatment flow path according to an embodiment of the present disclosure.
附图标记说明Explanation of reference signs
1 第一预热器 2 第二预热器1 First preheater 2 Second preheater
3 蒸发器 4 净化塔3 Evaporator 4 Purification tower
5 蒸汽压缩机 6 电蒸汽发生器5 Steam compressor 6 Electric steam generator
7 冷凝液流量调节阀 8 外排管道7 Condensate flow regulating valve 8 External discharge pipe
9 供料槽 10 热水泵9 Feed trough 10 Hot water pump
11 液位传感器 12 控制器11 Level sensor 12 Controller
具体实施方式Detailed ways
以下结合附图对本公开的具体实施方式进行详细说明。应当理解的是,此处所描述的具体实施方式仅用于说明和解释本公开,并不用于限制本公开。Specific embodiments of the present disclosure will be described in detail below with reference to the accompanying drawings. It should be understood that the specific embodiments described here are only used to illustrate and explain the present disclosure, and are not intended to limit the present disclosure.
图1示意性示出了根据本公开实施例的一种用于放射性废液处理的热泵蒸发处理系统的结构示意图。Figure 1 schematically shows a structural diagram of a heat pump evaporation treatment system for radioactive waste liquid treatment according to an embodiment of the present disclosure.
如图1所示,该系统可以包括第一预热器1、第二预热器2、蒸发器3、蒸汽压缩机5、电蒸汽发生器6和冷凝液控制装置,所述第一预热器1具有第一原液室和第一预热室,所述第二预热器2具有第二原液室和第二预热室,所述蒸发器3具有蒸发室和加热室。As shown in Figure 1, the system may include a first preheater 1, a second preheater 2, an evaporator 3, a steam compressor 5, an electric steam generator 6 and a condensate control device. The first preheater The evaporator 1 has a first raw liquid chamber and a first preheating chamber, the second preheater 2 has a second raw liquid chamber and a second preheating chamber, and the evaporator 3 has an evaporation chamber and a heating chamber.
其中,所述第一原液室、所述第二原液室、所述蒸发室和所述蒸汽压缩机5依次连通,所述蒸汽压缩机5的出口以及所述电蒸汽发生器6的补偿蒸汽出口分别与所述加热室的入口连通,所述加热室的蒸汽出口与所述第二预热室的入口连通,所述加热室的冷凝液出口以及所述第二预热室的出口分别与所述电蒸汽发生器6的冷凝液入口连通,所述电蒸汽发生器6的冷凝液出口与所述第一预热室的入口连通。Wherein, the first raw liquid chamber, the second raw liquid chamber, the evaporation chamber and the steam compressor 5 are connected in sequence, and the outlet of the steam compressor 5 and the compensation steam outlet of the electric steam generator 6 are respectively connected with the inlet of the heating chamber, the steam outlet of the heating chamber is connected with the inlet of the second preheating chamber, the condensate outlet of the heating chamber and the outlet of the second preheating chamber are respectively connected with the The condensate inlet of the electric steam generator 6 is connected, and the condensate outlet of the electric steam generator 6 is connected with the inlet of the first preheating chamber.
在本公开中,具体地,第一原液室、第二原液室和蒸发室构成废液处理流路,用于对放射性废液进行预热处理和蒸发处理;蒸汽压缩机、加热室和第二预热室构成蒸汽处理流路,用于为放射性废液的预热和蒸发提供加热蒸汽;电蒸汽发生器和第一预热室构成冷凝液处理流路,用于为放射性废液的预设提供预热用水,并排放降温后的蒸汽冷凝液。In the present disclosure, specifically, the first raw liquid chamber, the second raw liquid chamber and the evaporation chamber constitute a waste liquid treatment flow path for preheating and evaporating radioactive waste liquid; the steam compressor, the heating chamber and the second The preheating chamber forms a steam treatment flow path, which is used to provide heating steam for preheating and evaporation of radioactive waste liquid; the electric steam generator and the first preheating chamber form a condensate treatment flow path, which is used for preheating and evaporating radioactive waste liquid. Provide preheating water and discharge the cooled steam condensate.
放射性废液从第一原液室入口进入,依次经第一原液室和第二原液室预热后,进入蒸发器的蒸发室,并在蒸发室中蒸发产生二次蒸汽;二次蒸汽进入蒸汽压缩机,并在蒸汽压缩机中经加压和升温,变成高温蒸汽;高温蒸汽进入蒸发器的加热室进行换热,为蒸发室中放射性废液的蒸发过程提供热量,换热后的高温蒸汽冷凝为蒸汽冷凝液进入电蒸汽发生器;蒸发室中部分未冷凝的高温蒸汽以及不凝气体进入第二预热室进行换热,为第二原液室中放射性废液的预热提供热量,换热产生的蒸汽冷凝液进入电蒸汽发生器,不凝气体从第二预热室直接排放;进入电蒸汽发生器的蒸汽冷凝液,一部分被加热沸腾产生补偿蒸汽,另一部分进入第一预热室中,为第一原液室中放射性废液的预热提供热量;电蒸汽发生器中产生的补偿蒸汽进入蒸发器的加热室中进行换热,第一预热室中的蒸汽冷凝液在换热后直接排放。The radioactive waste liquid enters from the entrance of the first raw liquid chamber, and after being preheated by the first raw liquid chamber and the second raw liquid chamber, enters the evaporation chamber of the evaporator, and evaporates in the evaporation chamber to generate secondary steam; the secondary steam enters the vapor compression chamber machine, and is pressurized and heated in the steam compressor to become high-temperature steam; the high-temperature steam enters the heating chamber of the evaporator for heat exchange, providing heat for the evaporation process of radioactive waste liquid in the evaporation chamber. The high-temperature steam after heat exchange The condensed steam condensate enters the electric steam generator; part of the uncondensed high-temperature steam and non-condensable gas in the evaporation chamber enters the second preheating chamber for heat exchange, providing heat for preheating the radioactive waste liquid in the second raw liquid chamber. The steam condensate generated by heat enters the electric steam generator, and the non-condensable gas is directly discharged from the second preheating chamber; part of the steam condensate entering the electric steam generator is heated and boiled to generate compensation steam, and the other part enters the first preheating chamber. , providing heat for preheating the radioactive waste liquid in the first liquid chamber; the compensation steam generated in the electric steam generator enters the heating chamber of the evaporator for heat exchange, and the steam condensate in the first preheating chamber is exchanging heat Then discharge directly.
图2示意性示出了根据本公开实施例的一种冷凝液处理流路的结构示意图。如图2所示,冷凝液处理流路由电蒸汽发生器5和第一预热器1的第一预热室构成,冷凝液处理流路设有冷凝液控制装置,包括:冷凝液流量调节阀7,设置于所述电蒸汽发生器6的冷凝液出口与所述第一预热室的入口之间,用于对进入所述第一预热室中的所述蒸汽冷凝液的流量进行调节;液位传感器11,设置于所述电蒸汽发生器6中,用于测量对所述电蒸汽发生器6中的液位;控制器12,分别与所述冷凝液流量调节阀7和所述液位传感器11连接,用于从所述液位传感器11处获取所述电蒸汽发生器6内的实际液位,并基于所述实际液位,对所述冷凝液流量调节阀7的开度进行调节,以对进入所述第一预热室中的所述蒸汽冷凝液的流量进行调节。FIG. 2 schematically shows a structural diagram of a condensate treatment flow path according to an embodiment of the present disclosure. As shown in Figure 2, the condensate treatment flow is composed of the electric steam generator 5 and the first preheating chamber of the first preheater 1. The condensate treatment flow is provided with a condensate control device, including: a condensate flow regulating valve. 7. Disposed between the condensate outlet of the electric steam generator 6 and the inlet of the first preheating chamber, used to adjust the flow rate of the steam condensate entering the first preheating chamber. ; Liquid level sensor 11 is provided in the electric steam generator 6 for measuring the liquid level in the electric steam generator 6; controller 12 is respectively connected with the condensate flow regulating valve 7 and the The liquid level sensor 11 is connected for obtaining the actual liquid level in the electric steam generator 6 from the liquid level sensor 11 and adjusting the opening of the condensate flow rate valve 7 based on the actual liquid level. Adjustment is performed to adjust the flow rate of the steam condensate entering the first preheating chamber.
通过上述技术方案,该热泵蒸发处理系统至少具有如下有益效果:Through the above technical solution, the heat pump evaporation treatment system has at least the following beneficial effects:
(1)该热泵蒸发处理系统将废液蒸发处理产生的二次蒸汽用作废液蒸发处理所需的加热蒸汽,加热蒸汽在为废液蒸发处理提供热量的过程中转化为可以直接排放的蒸汽冷凝液,因此,本公开可以无需设置蒸汽冷凝装置,而且实现了对蒸汽热量的再利用,具有低耗节能的优点;(1) The heat pump evaporation treatment system uses the secondary steam generated by the waste liquid evaporation treatment as the heating steam required for the waste liquid evaporation treatment. The heating steam is converted into condensed steam that can be directly discharged during the process of providing heat for the waste liquid evaporation treatment. liquid, therefore, the present disclosure eliminates the need to install a steam condensing device, and realizes the reuse of steam heat, which has the advantage of low consumption and energy saving;
(2)设置了用于监测电蒸汽发生器中液位高度的液位传感器,以及用于控制电蒸汽发生器中蒸汽冷凝液流出流量的冷凝液流量调节阀,并将液位传感器与冷凝液流量控制阀进行自动化关联,实现了根据电蒸汽发生器液位调控蒸汽冷凝液流出流量的控制方式,这能够有效避免蒸汽冷凝液流出流量偏大或偏小导致的电蒸汽发生器液位偏低或偏高的问题。(2) A liquid level sensor for monitoring the liquid level in the electric steam generator and a condensate flow regulating valve for controlling the outflow flow of steam condensate in the electric steam generator are provided, and the liquid level sensor is connected to the condensate The flow control valve is automatically associated to realize the control method of regulating the steam condensate outflow flow according to the electric steam generator liquid level. This can effectively avoid the low electric steam generator liquid level caused by the steam condensate outflow flow being too large or too small. Or a high problem.
具体地,所述第一预热器采用水水换热的方式对放射性废液进行预热,热源为第一预热室内的蒸汽冷凝液,第一预热室内的蒸汽冷凝液换热后可以直接排放。放射性废液在蒸发器的蒸发室中经过蒸发产生二次蒸汽,蒸汽又在蒸发器的蒸发室以及第二预热器的第二预热室中冷凝为蒸汽冷凝液,正常状态下,放射性废液的输入量与放射性废液的蒸发量相等,放射性废液的蒸发量与蒸汽冷凝液的回流量相等,蒸汽冷凝液的回流量与蒸汽冷凝液的输出量,也即在不考虑蒸发器中浓缩废液卸料的情况下,放射性废液的输入量与蒸汽冷凝液的输出量相等,因此,为了保证系统的平稳运行,通常需要将蒸汽冷凝液的输出量进行控制。Specifically, the first preheater uses water-water heat exchange to preheat the radioactive waste liquid. The heat source is the steam condensate in the first preheating chamber. After heat exchange, the steam condensate in the first preheating chamber can be Direct discharge. The radioactive waste liquid is evaporated in the evaporation chamber of the evaporator to produce secondary steam, and the steam is condensed into steam condensate in the evaporation chamber of the evaporator and the second preheating chamber of the second preheater. Under normal conditions, the radioactive waste liquid The input amount of liquid is equal to the evaporation amount of radioactive waste liquid, the evaporation amount of radioactive waste liquid is equal to the reflux amount of steam condensate, and the reflux amount of steam condensate is equal to the output amount of steam condensate, that is, without considering the evaporator When discharging concentrated waste liquid, the input volume of radioactive waste liquid is equal to the output volume of steam condensate. Therefore, in order to ensure the smooth operation of the system, it is usually necessary to control the output volume of steam condensate liquid.
然而,在系统运行过程中,放射性废液的蒸发量可能存在波动,当蒸发量偏低时,蒸汽冷凝液的回流量偏低,若蒸汽冷凝液依然按照之前的输出量进行输出,则会导致电蒸汽发生器的液位持续降低,最终导致电蒸汽发生器空罐,电热元件裸露干烧;当蒸发量偏高时,蒸汽冷凝液的回流量偏高,若蒸汽冷凝液依然按照之前的输出量进行输出,则会导致电蒸汽发生器的液位持续升高,最终导致电蒸汽发生器内的空间减小甚至消失,这会进一步导致电蒸汽发生器产生的补偿蒸汽减少,无法为电蒸汽加热室提供足够的加热蒸汽,从而影响系统的处理效果。本公开通过调节蒸汽冷凝液的输出量来保持电蒸汽发生器的液位不变,能够有效解决以上问题。However, during the operation of the system, the evaporation amount of the radioactive waste liquid may fluctuate. When the evaporation amount is low, the return flow rate of the steam condensate is low. If the steam condensate is still output according to the previous output volume, it will cause The liquid level of the electric steam generator continues to decrease, eventually causing the electric steam generator to be empty and the electric heating element to be exposed and dry. When the evaporation amount is high, the return flow of the steam condensate will be high. If the steam condensate still outputs according to the previous If the amount is output, the liquid level of the electric steam generator will continue to rise, and eventually the space inside the electric steam generator will be reduced or even disappear. This will further cause the compensation steam generated by the electric steam generator to be reduced, and it will not be able to provide electric steam. The heating chamber provides enough heating steam to affect the treatment effect of the system. The present disclosure can effectively solve the above problems by adjusting the output of steam condensate to keep the liquid level of the electric steam generator constant.
此外,第一预热器的预热能力是固定不变的,通常设置为第一预热室内蒸汽冷凝液的量与第一原液室内放射性废液的量相等时,第一预热器能够将放射性废液预热至预设温度,因此,本公开对蒸汽冷凝液的输出量进行控制,还能够保障第一预热器的稳定运行,确保第一预热器能将进入其中的放射性废液预热至预设温度。In addition, the preheating capacity of the first preheater is fixed and is usually set so that when the amount of steam condensate in the first preheating chamber is equal to the amount of radioactive waste liquid in the first raw liquid chamber, the first preheater can The radioactive waste liquid is preheated to a preset temperature. Therefore, the present disclosure controls the output of the steam condensate and can also ensure the stable operation of the first preheater and ensure that the first preheater can absorb the radioactive waste liquid entering it. Preheat to preset temperature.
根据本公开,所述系统还可以包括供料槽9、净化塔4、热水泵10和外排管道8;所述供料槽9的出口与所述第一原液室的入口连通;所述净化塔4设置在所述蒸发室和所述蒸汽压缩机5之间,所述净化塔4的入口与所述蒸发室的出口连通,所述净化塔4的出口与所述蒸汽压缩机5的入口连通;所述热水泵10设置在所述电蒸汽发生器6和所述第一预热室之间,所述热水泵10的入口与所述电蒸汽发生器6的冷凝液出口连通,所述热水泵10的出口与所述第一预热室的入口连通,用于将所述电蒸汽发生器6中的蒸汽冷凝液送入所述第一预热室中;所述外排管道8与所述第一预热室的出口连通。According to the present disclosure, the system may also include a feed tank 9, a purification tower 4, a hot water pump 10 and an external discharge pipe 8; the outlet of the feed tank 9 is connected to the inlet of the first raw liquid chamber; the purification The tower 4 is arranged between the evaporation chamber and the steam compressor 5. The inlet of the purification tower 4 is connected with the outlet of the evaporation chamber, and the outlet of the purification tower 4 is connected with the inlet of the steam compressor 5. Communicated; the hot water pump 10 is arranged between the electric steam generator 6 and the first preheating chamber, and the inlet of the hot water pump 10 is connected with the condensate outlet of the electric steam generator 6. The outlet of the hot water pump 10 is connected with the inlet of the first preheating chamber, and is used to send the steam condensate in the electric steam generator 6 into the first preheating chamber; the external discharge pipe 8 is connected with the inlet of the first preheating chamber. The outlet of the first preheating chamber is connected.
根据本公开,所述蒸发室的出口处可以设置有第一过滤网,所述净化塔4中可以设置有第二过滤网,来自所述蒸发室的二次蒸汽经所述第一过滤网和所述第二过滤网后,进入所述蒸汽压缩机5。According to the present disclosure, a first filter screen may be provided at the outlet of the evaporation chamber, a second filter screen may be provided in the purification tower 4, and the secondary steam from the evaporation chamber passes through the first filter screen and After the second filter, it enters the steam compressor 5 .
第一过滤网和第二过滤网能够有效去除蒸汽中夹带的未达排放标准的小水滴,避免其通过蒸汽处理流路和冷凝液处理流路排放到外界。The first filter and the second filter can effectively remove small water droplets entrained in the steam that do not meet the emission standard, and prevent them from being discharged to the outside through the steam treatment flow path and the condensate treatment flow path.
本公开还提供采用上述任意一项所述的系统处理放射性废液的方法,该方法可以包括:利用所述控制器从所述液位传感器处获取所述电蒸汽发生器内的实际液位;将所述实际液位与预设液位进行比对;在所述实际液位低于所述预设液位的情况下,利用所述控制器控制所述冷凝液流量调节阀以减小所述冷凝液流量调节阀的开度;在所述实际液位高于所述预设液位的情况下,利用所述控制器控制所述冷凝液流量调节阀以增大所述冷凝液流量调节阀的开度。The present disclosure also provides a method for treating radioactive waste liquid using any one of the systems described above. The method may include: using the controller to obtain the actual liquid level in the electric steam generator from the liquid level sensor; The actual liquid level is compared with the preset liquid level; when the actual liquid level is lower than the preset liquid level, the controller is used to control the condensate flow regulating valve to reduce the The opening of the condensate flow regulating valve; when the actual liquid level is higher than the preset liquid level, the controller is used to control the condensate flow regulating valve to increase the condensate flow regulating valve. valve opening.
在本公开中,具体地,可以采用领域内常用的控制器对冷凝液流量调节阀的开度进行自动调节,例如可编程逻辑控制器(PLC系统)。所述冷凝液流量调节阀开度的减小量或增大量可以根据实际需要进行确定,本公开不再赘述。In the present disclosure, specifically, a controller commonly used in the field can be used to automatically adjust the opening of the condensate flow regulating valve, such as a programmable logic controller (PLC system). The amount of decrease or increase in the opening of the condensate flow regulating valve can be determined according to actual needs, and will not be described in detail in this disclosure.
根据本公开,所述预设液位可以为所述电蒸汽发生器内部深度的50~65%,优选为55~60%。本公开将电蒸汽发生器内的液位设定为固定值,并根据电蒸汽发生器内的液位变化来调控蒸汽冷凝液的输出量,使蒸汽冷凝液的输出量逐步等于其回流量,从而使系统运行趋于稳定,这能够在保证电蒸汽发生器始终稳定运行的情况下,对系统的性能及运行稳定性进行调节,这有利于保障系统的长期稳定运行。According to the present disclosure, the preset liquid level may be 50-65% of the internal depth of the electric steam generator, preferably 55-60%. In this disclosure, the liquid level in the electric steam generator is set to a fixed value, and the output of the steam condensate is adjusted according to changes in the liquid level in the electric steam generator, so that the output of the steam condensate is gradually equal to its return flow. As a result, the system operation tends to be stable, which can adjust the performance and operational stability of the system while ensuring that the electric steam generator always operates stably, which is conducive to ensuring the long-term stable operation of the system.
根据本公开,在对所述冷凝液流量调节阀的开度进行调节时,调节幅度可以为所述冷凝液流量调节阀总开度为25~35%。According to the present disclosure, when adjusting the opening of the condensate flow regulating valve, the adjustment range may be such that the total opening of the condensate flow regulating valve is 25% to 35%.
可选地,所述方法还可以包括:将待处理的放射性废液依次送入所述第一预热器的第一原液室和所述第二预热器的第二原液室中进行预热处理;使预热后的所述放射性废液进入所述蒸发器的蒸发室中进行蒸发处理,得到二次蒸汽和浓缩废液;使所述二次蒸汽进入所述蒸汽压缩机中进行加压升温处理,得到高温蒸汽,并将所述高温蒸汽作为热源返回所述蒸发器的加热室中进行换热;将所述加热室中部分未冷凝的所述高温蒸汽和不凝气作为热源送入所述第二预热器的第二预热室中进行换热;将所述加热室中换热产生的蒸汽冷凝液以及所述第二预热室中换热产生的蒸汽冷凝液分别送入所述电蒸汽发生器中;使所述电蒸汽发生器中的部分蒸汽冷凝液进行蒸发得到补偿蒸汽,使所述补偿蒸汽作为热源进入所述蒸发器的加热室中进行换热;使所述电蒸汽发生器中的部分蒸汽冷凝液作为热源进入所述第一预热器的第一预热室中进行换热,换热后的蒸汽冷凝液从所述第一预热室的出口进行排放。Optionally, the method may further include: sequentially sending the radioactive waste liquid to be treated into the first raw liquid chamber of the first preheater and the second raw liquid chamber of the second preheater for preheating. Processing; causing the preheated radioactive waste liquid to enter the evaporation chamber of the evaporator for evaporation treatment to obtain secondary steam and concentrated waste liquid; causing the secondary steam to enter the steam compressor for pressurization The temperature is raised to obtain high-temperature steam, and the high-temperature steam is returned to the heating chamber of the evaporator as a heat source for heat exchange; part of the uncondensed high-temperature steam and non-condensable gas in the heating chamber are sent into the heating chamber as a heat source. Heat exchange is performed in the second preheating chamber of the second preheater; the steam condensate generated by heat exchange in the heating chamber and the steam condensate generated by heat exchange in the second preheating chamber are sent into In the electric steam generator; evaporate part of the steam condensate in the electric steam generator to obtain compensation steam, and use the compensation steam as a heat source to enter the heating chamber of the evaporator for heat exchange; Part of the steam condensate in the electric steam generator enters the first preheating chamber of the first preheater as a heat source for heat exchange, and the heat-exchanged steam condensate is discharged from the outlet of the first preheating chamber. .
根据本公开,经所述第一预热器预热后,所述放射性废液的温度升高至70℃~85℃,经所述第二预热器预热后,所述放射性废液的温度升高至90℃~98℃。According to the present disclosure, after being preheated by the first preheater, the temperature of the radioactive waste liquid rises to 70°C to 85°C, and after being preheated by the second preheater, the temperature of the radioactive waste liquid is The temperature rises to 90℃~98℃.
根据本公开,经所述蒸汽压缩机进行加压升温处理后,所述高温蒸汽的压力可以为50kPa~80kPa,温度可以为110℃~120℃。According to the present disclosure, after the steam compressor performs pressure and temperature raising treatment, the pressure of the high-temperature steam can be 50kPa˜80kPa, and the temperature can be 110°C˜120°C.
根据本公开,从所述电蒸汽发生器进入所述第一预热室的蒸汽冷凝液的温度可以为110℃~120℃;从所述第一预热室的出口进行排放的蒸汽冷凝液的温度可以为40℃~55℃。According to the present disclosure, the temperature of the steam condensate entering the first preheating chamber from the electric steam generator may be 110°C to 120°C; the temperature of the steam condensate discharged from the outlet of the first preheating chamber The temperature can be 40℃~55℃.
根据本公开,所述补偿蒸汽的温度可以为110℃~120℃。According to the present disclosure, the temperature of the compensation steam may be 110°C to 120°C.
以上结合附图详细描述了本公开的优选实施方式,但是,本公开并不限于上述实施方式中的具体细节,在本公开的技术构思范围内,可以对本公开的技术方案进行多种简单变型,这些简单变型均属于本公开的保护范围。The preferred embodiments of the present disclosure have been described in detail above with reference to the accompanying drawings. However, the present disclosure is not limited to the specific details of the above-mentioned embodiments. Within the scope of the technical concept of the present disclosure, various simple modifications can be made to the technical solutions of the present disclosure. These simple modifications all belong to the protection scope of the present disclosure.
另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本公开对各种可能的组合方式不再另行说明。In addition, it should be noted that each of the specific technical features described in the above-mentioned specific embodiments can be combined in any suitable manner without conflict. In order to avoid unnecessary repetition, this disclosure describes various possible combinations. The combination method will not be further explained.
此外,本公开的各种不同的实施方式之间也可以进行任意组合,只要其不违背本公开的思想,其同样应当视为本公开所公开的内容。In addition, any combination of various embodiments of the present disclosure can also be carried out, and as long as they do not violate the idea of the present disclosure, they should also be regarded as the contents disclosed in the present disclosure.
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CN116153551B (en) * | 2023-01-04 | 2024-05-14 | 中国原子能科学研究院 | Radioactive waste liquid treatment method and system |
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