Disclosure of Invention
The invention aims to provide a chip anti-irradiation packaging material and an anti-irradiation packaging process, and the wide-bandgap semiconductor material is doped into plastic as particles, so that the integral anti-irradiation performance of the chip and the reliability of the chip in a space environment are improved.
The basic scheme provided by the invention is as follows: a chip radiation-resistant packaging material is characterized in that: the plastic packaging material is doped with wide bandgap semiconductor particles, and the weight percentage of the wide bandgap semiconductor particles is between 10 and 75 percent.
The principle and the advantages of the invention are as follows: according to the invention, the wide bandgap semiconductor particles are doped in the plastic packaging material, and the radiation resistance of the wide bandgap semiconductor material is utilized, so that the radiation resistance of the plastic packaging material can be effectively improved, and the integral radiation resistance of the chip and the reliability of the chip in a space environment are improved. Therefore, the invention has the advantages that the wide bandgap semiconductor material is doped into the plastic as particles, so that the radiation resistance of the whole chip and the reliability of the chip in the space environment are improved.
Further, the plastic package material is an epoxy plastic package material.
Has the advantages that: the epoxy plastic packaging material has the advantages of low cost, high production efficiency and reasonable reliability, and is a common packaging material.
Further, the wide bandgap semiconductor particles are one of silicon carbide wide bandgap semiconductor particles or gallium nitride wide bandgap semiconductor particles.
Has the advantages that: the silicon carbide wide bandgap semiconductor and the gallium nitride wide bandgap semiconductor have anti-irradiation capability, and meanwhile, the silicon carbide and the gallium nitride are also used as high-thermal-conductivity-coefficient materials and doped into plastic package, so that the overall heat dissipation capability of the chip can be effectively improved.
Furthermore, the particle size of the wide bandgap semiconductor particles is 10nm-50 um.
Has the advantages that: the particle size of the wide bandgap semiconductor particles is controlled to be 10nm-50um, and the overall weight and the shape of the plastic packaging material doped with the wide bandgap semiconductor particles are not obviously influenced.
A chip irradiation-resistant packaging process is characterized in that: the method comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate;
s2: weighing the plastic packaging material and the doping particles, putting the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over;
s3: and (3) carrying out injection molding and press sealing on the chip copper substrate with the anti-radiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and carrying out pin electroplating and burr and flash removal on the chip after plastic packaging.
Principle and advantages: according to the invention, the wide bandgap semiconductor particles are doped in the plastic packaging material, and the radiation resistance of the wide bandgap semiconductor material is utilized, so that the radiation resistance of the plastic packaging material can be effectively improved, and the integral radiation resistance of the chip and the reliability of the chip in a space environment are improved. Meanwhile, an anti-irradiation layer grows on the back of the chip on the surface of the copper substrate, so that the anti-irradiation capability of the back of a chip device can be improved. Therefore, the invention has the advantages that the wide bandgap semiconductor material is doped into the plastic as particles, so that the integral anti-irradiation performance of the chip and the reliability of the chip in the space environment are improved, and meanwhile, the back of the chip device is extended to grow an anti-irradiation layer, so that the anti-irradiation capability of the back of the chip device is improved.
Further, in S1, the irradiation-resistant layer is made of one of metal oxide, metal simple substance or wide bandgap semiconductor material, the thickness of the irradiation-resistant layer is 1um-1mm, and the area of the irradiation-resistant layer is between the area of the chip and the area of the copper substrate.
Has the advantages that: the metal oxide or the metal simple substance or the wide bandgap semiconductor material can improve the radiation resistance of the back of the chip device.
Further, in S2, the molding compound is an epoxy molding compound, the stirring temperature in the mold is 150-220 ℃, and the stirring time is 5-30 min.
Has the advantages that: the epoxy molding compound has the advantages of low cost, high production efficiency and reasonable reliability, is a common packaging material, and can be uniformly stirred by stirring at the temperature of 150-220 ℃ for 5-30 minutes.
Further, the doped particles are one of silicon carbide wide bandgap semiconductor particles or gallium nitride wide bandgap semiconductor particles, the doped particles account for 10% -75% of the total mass, and the particle size of the doped particles is 10nm-50 um.
Has the advantages that: the silicon carbide wide bandgap semiconductor and the gallium nitride wide bandgap semiconductor have anti-irradiation capability, and meanwhile, the silicon carbide and the gallium nitride are also used as high-thermal-conductivity-coefficient materials and doped into plastic package, so that the overall heat dissipation capability of the chip can be effectively improved.
Detailed Description
The following is further detailed by way of specific embodiments:
as shown in figure 1, the chip anti-irradiation packaging material is prepared by weighing a plastic packaging material and wide bandgap semiconductor particles, doping the wide bandgap semiconductor particles in the plastic packaging material, wherein the plastic packaging material is an epoxy plastic packaging material, the wide bandgap semiconductor particles are silicon carbide wide bandgap semiconductor particles or gallium nitride wide bandgap semiconductor particles, the weight percentage of the wide bandgap semiconductor particles is between 1% and 30%, and the particle size of the wide bandgap semiconductor particles is between 10nm and 50 um.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; the irradiation-resistant layer is made of one of metal oxide, metal simple substance or wide bandgap semiconductor material, the thickness of the irradiation-resistant layer is 1um-1mm, and the area of the irradiation-resistant layer is between the area of the chip and the area of the copper substrate;
s2: weighing the plastic packaging material and the doping particles, putting the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 150-220 ℃, and the stirring time is 5-30 min; the doped particles are one of silicon carbide wide bandgap semiconductor particles or gallium nitride wide bandgap semiconductor particles, the doped particles account for 10-75% of the total mass, and the particle size of the doped particles is 10nm-50 um;
s3: and (3) carrying out injection molding and press sealing on the chip copper substrate with the anti-radiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and carrying out pin electroplating and burr and flash removal on the chip after plastic packaging.
The first embodiment is as follows:
2g of plastic packaging material and wide bandgap semiconductor particles are weighed, the wide bandgap semiconductor particles are doped in the plastic packaging material, the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are silicon carbide wide bandgap semiconductor particles, the weight proportion of the silicon carbide wide bandgap semiconductor particles is 20%, namely the weight of the silicon carbide wide bandgap semiconductor particles is 0.4g, and the particle size of the silicon carbide wide bandgap semiconductor particles is 10 nm.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; wherein, the material of the anti-irradiation layer is zirconia, the thickness of the anti-irradiation layer is 1um, and the area of the anti-irradiation layer is the area of the copper substrate;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 150 ℃, and the stirring time is 5 min; the doping particles are silicon carbide wide bandgap semiconductor particles, the weight of the silicon carbide wide bandgap semiconductor particles accounts for 20% of the total weight, namely the weight of the silicon carbide wide bandgap semiconductor particles is 0.4g, and the particle size of the silicon carbide wide bandgap semiconductor particles is 10 nm;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1M rad dose on the device subjected to plastic packaging in S3, wherein the electrical performance of the device is 88% of that of an undoped device.
Example two:
2g of plastic packaging material and wide bandgap semiconductor particles are weighed, the wide bandgap semiconductor particles are doped in the plastic packaging material, the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are silicon carbide wide bandgap semiconductor particles, the weight ratio of the silicon carbide wide bandgap semiconductor particles is 10%, and the particle size of the wide bandgap semiconductor particles is 200 nm.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; wherein, the material of the anti-irradiation layer is zirconia, the thickness of the anti-irradiation layer is 100um, and the area of the anti-irradiation layer is the area of the copper substrate;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 200 ℃, and the stirring time is 20 min; the doping particles are silicon carbide wide bandgap semiconductor particles, the weight of the silicon carbide wide bandgap semiconductor particles accounts for 10% of the total weight, and the particle size of the silicon carbide wide bandgap semiconductor particles is 200 nm;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1M rad dose on the device subjected to plastic packaging in S3, wherein the electrical performance of the device is 95% of that of an undoped device.
Example three:
a chip anti-irradiation packaging material is prepared by weighing 2g of plastic packaging material and wide bandgap semiconductor particles, doping the wide bandgap semiconductor particles in the plastic packaging material, wherein the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are silicon carbide wide bandgap semiconductor particles, the weight ratio of the silicon carbide wide bandgap semiconductor particles is 35%, and the particle size of the wide bandgap semiconductor particles is 5 um.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; wherein the material of the anti-irradiation layer is zirconium oxide, the thickness of the anti-irradiation layer is 1mm, and the area of the anti-irradiation layer is the area of the copper substrate;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 220 ℃, and the stirring time is 30 min; the doping particles are silicon carbide wide bandgap semiconductor particles, the weight of the silicon carbide wide bandgap semiconductor particles accounts for 35% of the total weight, and the particle size of the silicon carbide wide bandgap semiconductor particles is 5 um;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1M rad dose on the device subjected to plastic packaging in S3, wherein the electrical performance of the device is 69% of that of an undoped device.
Example four:
2g of plastic packaging material and wide bandgap semiconductor particles are weighed, the wide bandgap semiconductor particles are doped in the plastic packaging material, the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are gallium nitride wide bandgap semiconductor particles, the weight proportion of the gallium nitride wide bandgap semiconductor particles is 35%, and the particle size of the wide bandgap semiconductor particles is 10 nm.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; the irradiation-resistant layer is made of gallium nitride, the thickness of the irradiation-resistant layer is 1um, and the area of the irradiation-resistant layer is the area of the chip;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 150 ℃, and the stirring time is 5 min; the doped particles are gallium nitride wide bandgap semiconductor particles, the weight of the gallium nitride wide bandgap semiconductor particles accounts for 35% of the total weight, and the particle size of the gallium nitride wide bandgap semiconductor particles is 10 nm;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1M rad dose on the device subjected to plastic packaging in S3, wherein the electrical performance of the device is 67.8% of that of an undoped device, and the degradation amplitude of the device is the latter.
Example five:
2g of plastic packaging material and wide bandgap semiconductor particles are weighed, the wide bandgap semiconductor particles are doped in the plastic packaging material, the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are gallium nitride wide bandgap semiconductor particles, the weight ratio of the gallium nitride wide bandgap semiconductor particles is 15%, and the particle size of the wide bandgap semiconductor particles is 500 nm.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; the irradiation-resistant layer is made of gallium nitride, the thickness of the irradiation-resistant layer is 500um, and the area of the irradiation-resistant layer is the area of the chip;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 200 ℃, and the stirring time is 20 min; the doped particles are gallium nitride wide bandgap semiconductor particles, the weight of the gallium nitride wide bandgap semiconductor particles accounts for 15% of the total weight, and the particle size of the gallium nitride wide bandgap semiconductor particles is 500 nm;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1 Mrad dose on the device subjected to plastic packaging in S3, wherein the degradation amplitude of the electrical performance of the device is 91% of that of an undoped device.
Example six:
2g of plastic packaging material and wide bandgap semiconductor particles are weighed, the wide bandgap semiconductor particles are doped in the plastic packaging material, the plastic packaging material is epoxy plastic packaging material, the wide bandgap semiconductor particles are gallium nitride wide bandgap semiconductor particles, the weight proportion of the gallium nitride wide bandgap semiconductor particles is 30%, and the particle size of the wide bandgap semiconductor particles is 50 nm.
A chip radiation-resistant packaging process comprises the following steps:
s1: growing an anti-irradiation layer on the back of the copper substrate, welding a chip on the front of the copper substrate, and bonding the chip and a pin of the copper substrate; the irradiation-resistant layer is made of gallium nitride, the thickness of the irradiation-resistant layer is 1mm, and the area of the irradiation-resistant layer is the area of the chip;
s2: weighing 2g of plastic packaging material and doping particles, placing the plastic packaging material and the doping particles into a die with a preset stirring temperature, uniformly stirring, and obtaining a plastic packaging material composite material after the stirring time is over; wherein the plastic package material is epoxy plastic package material, the stirring temperature in the die is 220 ℃, and the stirring time is 30 min; the doped particles are gallium nitride wide bandgap semiconductor particles, the weight of the gallium nitride wide bandgap semiconductor particles accounts for 30% of the total weight, and the particle size of the gallium nitride wide bandgap semiconductor particles is 50 um;
s3: performing injection molding and press sealing on the chip copper substrate with the anti-irradiation layer in S1 by using the uniformly stirred plastic packaging material composite material, and performing pin electroplating and burr and flash removal on the chip after plastic packaging;
s4, carrying out irradiation test of 1M rad dose on the device subjected to plastic packaging in S3, wherein the electrical performance of the device is 76.6% of that of an undoped device.
The foregoing are merely exemplary embodiments of the present invention, and no attempt is made to show structural details of the invention in more detail than is necessary for the fundamental understanding of the art, the description taken with the drawings making apparent to those skilled in the art how the several forms of the invention may be embodied in practice with the teachings of the invention. It should be noted that, for those skilled in the art, without departing from the structure of the present invention, several changes and modifications can be made, which should also be regarded as the protection scope of the present invention, and these will not affect the effect of the implementation of the present invention and the practicability of the patent. The scope of the claims of the present application shall be determined by the contents of the claims, and the description of the embodiments and the like in the specification shall be used to explain the contents of the claims.