CN113527772A - Aerogel latex foam as well as preparation method and application thereof - Google Patents
Aerogel latex foam as well as preparation method and application thereof Download PDFInfo
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- CN113527772A CN113527772A CN202110636700.XA CN202110636700A CN113527772A CN 113527772 A CN113527772 A CN 113527772A CN 202110636700 A CN202110636700 A CN 202110636700A CN 113527772 A CN113527772 A CN 113527772A
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- 239000004964 aerogel Substances 0.000 title claims abstract description 50
- 229920001821 foam rubber Polymers 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 51
- 229920000126 latex Polymers 0.000 claims abstract description 32
- 239000004816 latex Substances 0.000 claims abstract description 31
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 20
- 230000003213 activating effect Effects 0.000 claims abstract description 13
- 239000004088 foaming agent Substances 0.000 claims abstract description 13
- 239000003349 gelling agent Substances 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 11
- 238000005187 foaming Methods 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003242 anti bacterial agent Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 229940074391 gallic acid Drugs 0.000 claims description 3
- 235000004515 gallic acid Nutrition 0.000 claims description 3
- 229940096992 potassium oleate Drugs 0.000 claims description 3
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 claims description 3
- PGNWIWKMXVDXHP-UHFFFAOYSA-L zinc;1,3-benzothiazole-2-thiolate Chemical compound [Zn+2].C1=CC=C2SC([S-])=NC2=C1.C1=CC=C2SC([S-])=NC2=C1 PGNWIWKMXVDXHP-UHFFFAOYSA-L 0.000 claims description 3
- KMNUDJAXRXUZQS-UHFFFAOYSA-L zinc;n-ethyl-n-phenylcarbamodithioate Chemical compound [Zn+2].CCN(C([S-])=S)C1=CC=CC=C1.CCN(C([S-])=S)C1=CC=CC=C1 KMNUDJAXRXUZQS-UHFFFAOYSA-L 0.000 claims description 3
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 2
- 235000015424 sodium Nutrition 0.000 claims description 2
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 2
- 230000006835 compression Effects 0.000 abstract description 5
- 238000007906 compression Methods 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 239000007787 solid Substances 0.000 description 9
- 229910052681 coesite Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 5
- 239000004599 antimicrobial Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 244000061408 Eugenia caryophyllata Species 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 240000002657 Thymus vulgaris Species 0.000 description 1
- 235000007303 Thymus vulgaris Nutrition 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000007783 nanoporous material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
- C08J2307/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
- C08J2321/02—Latex
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of latex foam, and particularly relates to aerogel latex foam as well as a preparation method and application thereof. The aerogel latex foam comprises the following components in parts by weight: 54-70 parts of latex, 3-20 parts of aerogel filler, 1-2 parts of accelerator, 1-3 parts of activating agent, 1-3 parts of vulcanizing agent, 1-2 parts of anti-aging agent, 3-5 parts of foaming agent, 1-3 parts of gelling agent and 1-5 parts of water. Compared with the traditional latex foam, the aerogel latex foam provided by the invention has better compression rebound rate and oxidation resistance.
Description
Technical Field
The invention belongs to the technical field of latex foam, and particularly relates to aerogel latex foam as well as a preparation method and application thereof.
Background
Since the 20 th 19 th century latex products were made directly from natural latex, the production of latex products has evolved as an important part of the rubber industry. The consumption of the rubber latex in the world in the 80 s accounts for about 10 percent of the total consumption of the rubber.
The production process of the latex product is completely different from the processing of the dry rubber, and does notLarge heavy machinery and a plurality of working procedures are needed, and conditions are provided for large-scale popularization and application of the composite material. Latex products are increasingly favored for their natural, highly breathable, ultra-silent, highly resilient properties, and the like, and are used in many applications such as mattresses, pillows, shoe soles, gloves, toys, hoses, and the like. The natural latex emulsion product has the defects of easy oxidation, high price, sensitization and the like after being contacted with ultraviolet rays. The synthesized latex emulsion product contains butadiene and styrene, can release benzene and formaldehyde gas at a certain temperature, and has great influence on human health. SiO 22The aerogel is an inorganic nano porous material, and is applied to the foaming process of the natural latex, so that the prepared latex product has the characteristics of oxidation resistance, low price and no harm to human bodies, and meanwhile, the price of the natural latex product can be greatly reduced, and the popularization of the natural latex product in daily life is promoted.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides aerogel latex foam as well as a preparation method and application thereof.
The technical scheme provided by the invention is as follows:
the aerogel latex foam comprises the following components in parts by weight: 54-70 parts of latex, 3-20 parts of aerogel filler, 1-2 parts of accelerator, 1-3 parts of activating agent, 1-3 parts of vulcanizing agent, 1-2 parts of anti-aging agent, 3-5 parts of foaming agent, 1-3 parts of gelling agent and 1-5 parts of water.
Compared with the traditional latex foam cotton, the aerogel latex foam cotton provided by the invention has better compression rebound rate and oxidation resistance.
Specifically, the accelerator is selected from any one or combination of several of 2-mercaptobenzothiazole zinc salt, zinc diethyldithiocarbamate, zinc N-ethyl-N-phenyldithiocarbamate or 2-mercaptobenzothiazole.
Specifically, the activating agent is zinc oxide.
Specifically, the vulcanizing agent is sulfur.
Specifically, the anti-aging agent is an anti-aging agent 2246 or an anti-aging agent 264.
Specifically, the foaming agent is any one or a combination of a plurality of gallic acid, potassium oleate, ammonium oleate and triethanolamine oleate.
Specifically, the gelling agent is any one or a combination of ammonium sulfate, ammonium chloride and sodium silicofluoride.
Further, the antibacterial agent also comprises 5-8 parts by weight of an antibacterial agent. The antimicrobial agent is selected from KP-F25, clove essential oil, lavender essential oil, rosemary essential oil, sage essential oil, thyme essential oil, silver ion antimicrobial agent, copper ion antimicrobial agent or zinc ion antimicrobial agent.
The invention also provides a preparation method of the aerogel latex foam, which comprises the following steps:
1) uniformly stirring 90-100 parts by weight of concentrated latex solution and 3-20 parts by weight of aerogel filler, and then sequentially adding 1-2 parts by weight of accelerator, 1-3 parts by weight of vulcanizing agent, 1-2 parts by weight of anti-aging agent and 3-5 parts by weight of foaming agent under uniform stirring, or further adding an antibacterial agent, wherein the concentrated latex solution is concentrated natural latex solution or concentrated synthetic latex solution, the amount of the latex is 54-70 parts by weight, namely, the solid content of the concentrated latex solution is 60-70 wt%;
2) adding 1-3 parts by weight of an activating agent under uniform stirring, and foaming at 140-160 ℃;
3) adding 1-3 parts by weight of gelling agent and 1-3 parts by weight of vulcanizing agent after foaming, and solidifying and vulcanizing;
4) and dehydrating and drying to obtain the aerogel latex foam. 1-5 parts by weight of residual water after dehydration and drying.
The aerogel filler is SiO2Aerogel or SiO with solid content of 5-20 wt%2Aerogel slurry is used as a raw material, and SiO in the aerogel slurry2The aerogel accounts for 3-20 parts by weight.
Specifically, the weight part of the concentrated latex is 90-95 parts, and the solid content of the concentrated latex is 63-65 wt%.
The invention also provides application of the aerogel latex foam for manufacturing: mattress, pillow core, sole, gloves, toy or rubber tube. The invention has the beneficial effects that:
1、SiO2the aerogel has low heat conductivity coefficient and low density, and can improve the heat preservation and insulation performance of the latex foam when being added into the latex foam. Therefore, it is especially suitable for making mattress, pillow core, sole, gloves and hose.
2、SiO2The aerogel belongs to an inorganic material, is non-combustible in the air, and can be added into the latex foam to improve the fireproof performance of the latex foam. Thus being particularly suitable for manufacturing mattresses, pillow cores, shoe soles, gloves, toys or rubber tubes.
3. Adding SiO into latex foam2The aerogel has enhanced tensile strength and improved compression rebound rate. And the bubbles in the latex foam become more uniform due to the nucleation effect of the aerogel, the surface wrinkles and the mesoporous structure to form slits, and the energy barrier required by the nucleation of the bubbles on the surface is reduced, so that the average pore diameter of the foam is reduced. Therefore, it is especially suitable for making mattress, pillow core and sole.
4. The antioxidant is added into the natural latex, so that the production cost of the natural latex product can be reduced, the oxidation resistance of the natural latex product under ultraviolet irradiation can be improved, and the service life of the natural latex product can be prolonged. Thus being particularly suitable for manufacturing rubber hoses.
Detailed Description
The principles and features of this invention are described below in conjunction with examples which are set forth to illustrate, but are not to be construed to limit the scope of the invention.
Example 1
1) Uniformly stirring 90 parts by weight of concentrated latex solution and 10 parts by weight of aerogel filler, and then sequentially adding 1 part by weight of accelerator, 1 part by weight of vulcanizing agent, 1 part by weight of anti-aging agent and 3 parts by weight of foaming agent under uniform stirring, wherein the solid content of the concentrated latex solution is 65 wt%;
2) then adding 1 weight part of activating agent under uniform stirring, and foaming at 150 ℃;
3) adding 1 weight part of gelling agent and 1 weight part of vulcanizing agent after foaming, and solidifying and vulcanizing;
4) and dehydrating and drying to obtain the aerogel latex foam.
The solid content of the concentrated latex solution is 65 percent;
the aerogel filler is SiO2An aerogel;
the accelerator is 2-mercaptobenzothiazole zinc salt;
the activating agent is zinc oxide;
the vulcanizing agent is sulfur;
the anti-aging agent is an anti-aging agent 2246;
the foaming agent is gallic acid;
the gelling agent is ammonium sulfate.
Example 2
1) Uniformly stirring 90 parts by weight of concentrated latex solution and 15 parts by weight of aerogel filler, and then sequentially adding 1 part by weight of accelerator, 1 part by weight of vulcanizing agent, 1 part by weight of anti-aging agent and 3 parts by weight of foaming agent under uniform stirring, wherein the solid content of the concentrated latex solution is 65%;
2) then adding 1 weight part of activating agent under uniform stirring, and foaming at 150 ℃;
3) adding 1 weight part of gelling agent and 1 weight part of vulcanizing agent after foaming, and solidifying and vulcanizing;
4) and dehydrating and drying to obtain the aerogel latex foam.
The solid content of the concentrated latex solution is 65 percent;
the aerogel filler is SiO2An aerogel;
the accelerant is zinc diethyl dithiocarbamate;
the activating agent is zinc oxide;
the vulcanizing agent is sulfur;
the anti-aging agent is an anti-aging agent 2246;
the foaming agent is potassium oleate;
the gelling agent is ammonium chloride.
Example 3
1) Uniformly stirring 95 parts by weight of concentrated latex solution and 15 parts by weight of aerogel filler, and then sequentially adding 1.5 parts by weight of accelerator, 1.5 parts by weight of vulcanizing agent, 1 part by weight of anti-aging agent and 4 parts by weight of foaming agent under uniform stirring, wherein the solid content of the concentrated latex solution is 63 wt%;
2) then adding 1 weight part of activating agent under uniform stirring, and foaming at 150 ℃;
3) after foaming, adding 2 parts by weight of gelling agent and 2 parts by weight of vulcanizing agent, and solidifying and vulcanizing;
4) and dehydrating and drying to obtain the aerogel latex foam.
The solid content of the concentrated latex solution is 63 wt%;
the aerogel filler is SiO2An aerogel;
the accelerator is zinc N-ethyl-N-phenyl dithiocarbamate;
the activating agent is zinc oxide;
the vulcanizing agent is sulfur;
the anti-aging agent is an anti-aging agent 264;
the foaming agent is ammonium oleate;
the gelling agent is sodium silicofluoride.
Comparative example 1
The test object was latex foam purchased from south ton idefu latex products, inc.
Comparison test of important properties
Compression rebound resilience: the test method is a compression permanent deformation method, GB/T6669-2001;
weather resistance: the test method is a method for measuring the change of color, appearance and physical properties of the rubber material after the rubber material is exposed to natural or artificial climate, GB/T3511-;
coefficient of thermal conductivity: the test method is a heat flow meter method, GB/T10295-;
fire rating: the test method is a combustion method, GB/T8624-;
the above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (10)
1. The aerogel latex foam is characterized by comprising the following components in parts by weight: 54-70 parts of latex, 3-20 parts of aerogel filler, 1-2 parts of accelerator, 1-3 parts of activating agent, 1-3 parts of vulcanizing agent, 1-2 parts of anti-aging agent, 3-5 parts of foaming agent, 1-3 parts of gelling agent and 1-5 parts of water.
2. The aerogel latex foam of claim 1, wherein: the accelerator is selected from any one or combination of 2-mercaptobenzothiazole zinc salt, zinc diethyl dithiocarbamate, zinc N-ethyl-N-phenyl dithiocarbamate or 2-mercaptobenzothiazole.
3. The aerogel latex foam of claim 1, wherein: the activating agent is zinc oxide.
4. The aerogel latex foam of claim 1, wherein: the vulcanizing agent is sulfur.
5. The aerogel latex foam of claim 1, wherein: the anti-aging agent is an anti-aging agent 2246 or an anti-aging agent 264.
6. The aerogel latex foam of claim 1, wherein: the foaming agent is one or a combination of more of gallic acid, potassium oleate, ammonium oleate or triethanolamine oleate.
7. The aerogel latex foam of claim 1, wherein: the gelling agent is any one or combination of ammonium sulfate, ammonium chloride or sodium silicofluoride.
8. The aerogel latex foam as claimed in any one of claims 1 to 7, wherein: and 5-8 parts of an antibacterial agent.
9. A method for preparing aerogel latex foam according to any one of claims 1 to 7, comprising the steps of:
1) uniformly stirring 90-100 parts by weight of concentrated latex solution and 3-20 parts by weight of aerogel filler, and sequentially adding 1-2 parts by weight of accelerator, 1-3 parts by weight of vulcanizing agent, 1-2 parts by weight of anti-aging agent and 3-5 parts by weight of foaming agent under uniform stirring, wherein the concentrated latex solution is concentrated natural latex solution or concentrated synthetic latex solution, and the amount of the latex solution is 54-70 parts by weight;
2) adding 1-3 parts by weight of an activating agent under uniform stirring, and foaming at 140-160 ℃;
3) adding 1-3 parts by weight of gelling agent and 1-3 parts by weight of vulcanizing agent after foaming, and solidifying and vulcanizing;
4) and dehydrating and drying to obtain the aerogel latex foam.
10. Use of aerogel latex foam according to any one of claims 1 to 8, for the production of: mattress, pillow core, sole, gloves, toy or rubber tube.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110636700.XA CN113527772B (en) | 2021-06-08 | 2021-06-08 | Aerogel latex foam and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110636700.XA CN113527772B (en) | 2021-06-08 | 2021-06-08 | Aerogel latex foam and preparation method and application thereof |
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| Publication Number | Publication Date |
|---|---|
| CN113527772A true CN113527772A (en) | 2021-10-22 |
| CN113527772B CN113527772B (en) | 2023-08-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110636700.XA Active CN113527772B (en) | 2021-06-08 | 2021-06-08 | Aerogel latex foam and preparation method and application thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119119598A (en) * | 2024-07-23 | 2024-12-13 | 佛山尚尚雅纺织品有限公司 | Antibacterial sleep-aiding latex pillow and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120326071A1 (en) * | 2010-02-03 | 2012-12-27 | Saint-Gobain Isover | High-performance thermal insulation materials |
| CN109337154A (en) * | 2018-10-17 | 2019-02-15 | 长沙小如信息科技有限公司 | A kind of high-strength mattress material and preparation method thereof |
| JP2020019925A (en) * | 2018-07-18 | 2020-02-06 | 株式会社イノアック技術研究所 | Aerogel composite and manufacturing method therefor |
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| CN119119598A (en) * | 2024-07-23 | 2024-12-13 | 佛山尚尚雅纺织品有限公司 | Antibacterial sleep-aiding latex pillow and preparation method thereof |
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| CN113527772B (en) | 2023-08-22 |
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