CN113271777B - 包含氟氯吡啶酸和其他除草剂的组合物及其方法 - Google Patents
包含氟氯吡啶酸和其他除草剂的组合物及其方法 Download PDFInfo
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- CN113271777B CN113271777B CN201980087232.6A CN201980087232A CN113271777B CN 113271777 B CN113271777 B CN 113271777B CN 201980087232 A CN201980087232 A CN 201980087232A CN 113271777 B CN113271777 B CN 113271777B
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
- A01P13/02—Herbicides; Algicides selective
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- Environmental Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种除草组合物提供了防治不希望的植被，例如在直播稻、水播稻、移栽稻、谷物、小麦、大麦、燕麦、黑麦、高粱、玉米或玉蜀黍、甘蔗、向日葵、油菜、卡诺拉油菜、甜菜、大豆、棉花、菠萝、蔬菜、草地、草原、牧场、休耕地、草皮、树和藤蔓果园、水生物、种植作物、蔬菜、工业植被管理(IVM)或路域(ROW)中，所述除草组合物含有(a)式(I)的化合物：其中X代表CH或N，hal代表F、Cl或Br，R是甲基或乙基，并且R’是H、甲基或乙基，或其农业上可接受的盐或酯；(b)第二除草剂，所述第二除草剂包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺；和/或(c)第三除草剂，所述第三除草剂包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺。
Description
相关申请的交叉引用
本申请是要求2018年11月2日提交的标题为“包含氟氯吡啶酸和其他除草剂的组合物及其方法”的美国临时申请号62/755,069的优先权的国际申请，将其全部内容通过引用并入本文。
技术领域
本公开文本的方面提供了除草组合物，其包含至少一种除草吡啶或嘧啶羧酸、第二除草剂和/或第三除草剂或其农业上可接受的盐、酯和酰胺。本文还提供了防治不希望的植被的方法，其包括施用本文公开的组合物。
背景技术
保护作物免受抑制作物生长的杂草和其他植被的侵害是农业中不断出现的问题。为了帮助战胜这个问题，合成化学领域的研究人员已经生产出广泛多样的有效防治此类不需要的生长的化学品和化学配制品。在文献中已公开了许多类型的化学除草剂，并且大量已用于商业用途。然而，仍然需要有效控制不希望的植被的组合物和方法。
发明内容
本文提供的第一实施方案包括除草组合物，其包含除草有效量的(a)式(I)化合物：
其中X代表CH或N，hal代表F、Cl或Br，R代表甲基或乙基，并且R’代表H、甲基或乙基，或其农业上可接受的盐、酯或酰胺，(b)第二除草剂，所述第二除草剂包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺；和/或(c)第三除草剂，所述第三除草剂包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺。
第二实施方案包括根据第一实施方案所述的组合物，其中式(I)以以下形式中的至少一种存在：羧酸、羧酸盐、芳烷基、烷基酯、未经取代的苄基、经取代的苄基、C1-4烷基、和/或正丁酯。
第三个实施方案包括根据第一个或第二个实施方案所述的组合物，其中所述第二除草剂(b)包含选自以下的至少一种化合物：草丁膦(glufosinate)、甲基胺草磷(amiprofos-methyl)、莎稗磷、地散磷、双丙氨膦(bilanafos)、抑草磷、调节膦(fosamine)和哌草磷，或其农业上可接受的盐、酯和酰胺。
第四实施方案包括根据第一至第四实施方案中任一项所述的组合物，其中所述第三除草剂(c)包含选自以下的至少一种化合物：氯氟吡氧乙酸(fluroxypyr)、氯氨吡啶酸(aminopyralid)、cliodinate、二氯吡啶酸、氟硫草定、氟啶草、毒莠定和噻草啶，或其农业上可接受的盐、酯和酰胺。
第五实施方案包括根据第一至第四实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂是草丁膦或其农业上可接受的盐、酯和酰胺，其中以gae/ha(克酸当量/公顷)与gai/ha(克活性成分/公顷)或gae/ha与gae/ha为单位给出的式(I)的化合物与草丁膦或其农业上可接受的盐、酯和酰胺的重量比包括从约1:1000至约1:1、从约1:500至约1:1、从约1:400至约1:1、从约1:300至约1:1、从约1:200至约1:1、从约1:100至约1:1、从约1:90至约1:1、从约1:80至约1:1、从约1:70至约1:1、从约1:60至约1:1、从约1:50至约1:1、从约1:40至约1:1、从约1:30至约1:1、从约1:25至约1:1、从约1:20至约1:1、从约1:13至约1:1、从约1:12.5至约1:1、从约1:10至约1:1、从约1:9至约1:1、从约1:8至约1:1、从约1:7至约1:1、从约1:6至约1:1、从约1:5至约1:1、从约1:4至约1:1、从约1:3至约1:1、从约1:2至约1:1、从约1:1至约1:1、约1:1、约1:2、约1:4、约1:5、约1:10、约1:12.5、约1:25、约1:50、约1:100、约1:150、约1:200、约1:250、约1:300、约1:350、约1:400、约1:450、约1:500或其任何组合。
第六实施方案包括根据第一至第五实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂是草丁膦或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物与草丁膦或其农业上可接受的盐、酯和酰胺的重量比选自以下的组：包括从约1:400至约1:12.5、从约1:400至约1:25、从约1:400至约1:50、从约1:400至约1:100、从约1:400至约1:200、从约1:200至约1:12.5、从约1:200至约1:50、从约1:200至约1:100、从约1:100至约1:12.5、从约1:100至约1:50、从约1:50至约1:12.5、从约1:50至约1:25、从约1:25至约1:12.5或其任何组合的比率或比率范围。
第七实施方案包括根据第一至第六实施方案中任一项所述的组合物，其中所述组合物中的第三除草剂是氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括从约1:200至约1:1、从约1:100至约1:1、从约1:90至约1:1、从约1:80至约1:1、从约1:70至约1:1、从约1:60至约1:1、从约1:50至约1:1、从约1:40至约1:1、从约1:35至约1:1、从约1:30至约1:1、从约1:20至约1:1、从约1:10至约1:1、从约1:8.8至约1:1、从约1:8.75至约1:1、从约1:5至约1:1、从约1:4.5至约1:1、从约1:4.4至约1:1、从约1:4.3至约1:1、从约1:4至约1:1、从约1:3至约1:1、从约1:2.5至约1:1、从约1:2.2至约1:1、从约1:2至约1:1、从约1:1至约1:1、约1:70、约1:35、约1:17.5、约1:8.8、约1:8.75、约1:4.4、约1:4.38、1:4.3、约1:2.5、约1:2.2或其任何组合。
第八实施方案包括根据第一至第七实施方案中任一项所述的组合物，其中所述组合物中的第三除草剂是氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括从约1:70至约1:2.2、从约1:70至约1:2.2、从约1:70至约1:4.38、从约1:70至约1:4.4、从约1:70至约1:8.8、从约1:70至约1:8.75、从约1:70至约1:17.5、从约1:70至约1:35、从约1:35至约1:2.2、从约1:35至约1:4.38、从约1:35至约1:4.4、从约1:35至约1:8.8、从约1:35至约1:8.75、从约1:35至约1:17.5、从约1:17.5至约1:2.2、从约1:17.5至约1:4.4、从约1:17.5至约1:8.8、从约1:17.5至约1:8.75、从约1:8.8至约1:2.2、从约1:8.8至约1:4.4、从约1:8.8至约1:8.75或其任何组合。
第九实施方案包括根据第一至第八实施方案中任一项所述的组合物，其中所述组合物包含式(I)的化合物、第二除草剂、和第三除草剂。
第十实施方案包括根据第一至第九实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:100至约1:1:1、从约1:500:80至约1:1:1、从约1:400:70至约1:1:1、从约1:400:70至约1:12:2、从约1:400:70至约1:12.5:2.2、从约1:400:70至约1:25:4.4、从约1:400:70至约1:50:8.8、从约1:300:70至约1:1:1、从约1:200:70至约1:1:1、从约1:100:70至约1:1:1、从约1:90:70至约1:1:1、从约1:80:70至约1:1:1、从约1:70:70至约1:1:1、从约1:60:70至约1:1:1、从约1:50:70至约1:1:1、从约1:40:70至约1:1:1、从约1:30:70至约1:1:1、从约1:25:70至约1:1:1、从约1:20:70至约1:1:1、从约1:13:70至约1:1:1、从约1:12.5:70至约1:1:1、从约1:10:70至约1:1:1、从约1:9:70至约1:1:1、从约1:8:70至约1:1:1、从约1:7:70至约1:1:1、从约1:6:70至约1:1:1、从约1:5:70至约1:1:1、从约1:2:70至约1:1:1、从约1:1:1至约1:1:1、约1:1:1、约1:2:70、约1:4:70、约1:5:70、约1:10:70、约1:12.5:70、约1:25:70、约1:50:70、约1:100:70、约1:150:70、约1:200:70、约1:250:70、约1:300:70、约1:350:70、约1:400:70、约1:450:70、约1:500:70或其任何组合。
第十一实施方案包括根据第一至第十实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:35至约1:1:1、从约1:500:35至约1:1:1、从约1:400:35至约1:1:1、从约1:300:35至约1:1:1、从约1:200:35至约1:1:1、从约1:100:35至约1:1:1、从约1:90:35至约1:1:1、从约1:80:35至约1:1:1、从约1:70:35至约1:1:1、从约1:60:35至约1:1:1、从约1:50:35至约1:1:1、从约1:40:35至约1:1:1、从约1:30:35至约1:1:1、从约1:25:35至约1:1:1、从约1:20:35至约1:1:1、从约1:13:35至约1:1:1、从约1:12.5:35至约1:1:1、从约1:10:35至约1:1:1、从约1:9:35至约1:1:1、从约1:8:35至约1:1:1、从约1:7:35至约1:1:1、从约1:6:35至约1:1:1、从约1:5:35至约1:1:1、从约1:2:35至约1:1:1、约1:2:35、约1:4:35、约1:5:35、约1:10:35、约1:12.5:35、约1:25:35、约1:50:35、约1:100:35、约1:150:35、约1:200:35、约1:250:35、约1:300:35、约1:350:35、约1:400:35、约1:450:35、约1:500:35或其任何组合。
第十二实施方案包括根据第一至第十一实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:17.5至约1:1:1、从约1:500:17.5至约1:1:1、从约1:400:17.5至约1:1:1、从约1:300:17.5至约1:1:1、从约1:200:17.5至约1:1:1、从约1:100:17.5至约1:1:1、从约1:90:17.5至约1:1:1、从约1:80:17.5至约1:1:1、从约1:70:17.5至约1:1:1、从约1:60:17.5至约1:1:1、从约1:50:17.5至约1:1:1、从约1:40:17.5至约1:1:1、从约1:30:17.5至约1:1:1、从约1:25:17.5至约1:1:1、从约1:20:17.5至约1:1:1、从约1:13:17.5至约1:1:1、从约1:12.5:17.5至约1:1:1、从约1:10:17.5至约1:1:1、从约1:9:17.5至约1:1:1、从约1:8:17.5至约1:1:1、从约1:7:17.5至约1:1:1、从约1:6:17.5至约1:1:1、从约1:5:17.5至约1:1:1、从约1:2:17.5至约1:1:1、约1:2:17.5、约1:4:17.5、约1:5:17.5、约1:10:17.5、约1:12.5:17.5、约1:25:17.5、约1:50:17.5、约1:100:17.5、约1:150:17.5、约1:200:17.5、约1:250:17.5、约1:300:17.5、约1:350:17.5、约1:400:17.5、约1:450:17.5、约1:500:17.5、约1:2:18、约1:4:18、约1:5:18、约1:10:18、约1:12.5:18、约1:25:18、约1:50:18、约1:100:18、约1:150:18、约1:200:18、约1:250:18、约1:300:18、约1:350:18、约1:400:18、约1:450:18、约1:500:18或其任何组合。
第十三实施方案包括根据第一至第十二实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:8.8至约1:1:1、从约1:500:8.8至约1:1:1、从约1:400:8.8至约1:1:1、从约1:300:8.8至约1:1:1、从约1:200:8.8至约1:1:1、从约1:100:8.8至约1:1:1、从约1:90:8.8至约1:1:1、从约1:80:8.8至约1:1:1、从约1:70:8.8至约1:1:1、从约1:60:8.8至约1:1:1、从约1:50:8.8至约1:1:1、从约1:40:8.8至约1:1:1、从约1:30:8.8至约1:1:1、从约1:25:8.8至约1:1:1、从约1:20:8.8至约1:1:1、从约1:13:8.8至约1:1:1、从约1:12.5:8.8至约1:1:1、从约1:10:8.8至约1:1:1、从约1:9:8.8至约1:1:1、从约1:8:8.8至约1:1:1、从约1:7:8.8至约1:1:1、从约1:6:8.8至约1:1:1、从约1:5:8.8至约1:1:1、从约1:2:8.8至约1:1:1、约1:2:8.8、约1:4:8.8、约1:5:8.8、约1:10:8.8、约1:12.5:8.8、约1:25:8.8、约1:50:8.8、约1:100:8.8、约1:150:8.8、约1:200:8.8、约1:250:8.8、约1:300:8.8、约1:350:8.8、约1:400:8.8、约1:450:8.8、约1:500:8.8、约1:2:9、约1:4:9、约1:5:9、约1:10:9、约1:12.5:9、约1:25:9、约1:50:9、约1:100:9、约1:150:9、约1:200:9、约1:250:9、约1:300:9、约1:350:9、约1:400:9、约1:450:9、约1:500:9或其任何组合。
第十四实施方案包括根据第一至第十三实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:4.4至约1:1:1、从约1:500:4.4至约1:1:1、从约1:400:4.4至约1:1:1、从约1:300:4.4至约1:1:1、从约1:200:4.4至约1:1:1、从约1:100:4.4至约1:1:1、从约1:90:4.4至约1:1:1、从约1:80:4.4至约1:1:1、从约1:70:4.4至约1:1:1、从约1:60:4.4至约1:1:1、从约1:50:4.4至约1:1:1、从约1:40:4.4至约1:1:1、从约1:30:4.4至约1:1:1、从约1:25:4.4至约1:1:1、从约1:20:4.4至约1:1:1、从约1:13:4.4至约1:1:1、从约1:12.5:4.4至约1:1:1、从约1:10:4.4至约1:1:1、从约1:9:4.4至约1:1:1、从约1:8:4.4至约1:1:1、从约1:7:4.4至约1:1:1、从约1:6:4.4至约1:1:1、从约1:5:4.4至约1:1:1、从约1:2:4.4至约1:1:1、约1:2:4.4、约1:4:4.4、约1:5:4.4、约1:10:4.4、约1:12.5:4.4、约1:25:4.4、约1:50:4.4、约1:100:4.4、约1:150:4.4、约1:200:4.4、约1:250:4.4、约1:300:4.4、约1:350:4.4、约1:400:4.4、约1:450:4.4、约1:500:4.4、约1:2:5、约1:4:5、约1:5:5、约1:10:5、约1:12.5:5、约1:25:5、约1:50:5、约1:100:5、约1:150:5、约1:200:5、约1:250:5、约1:300:5、约1:350:5、约1:400:5、约1:450:5、约1:500:5或其任何组合。
第十五实施方案包括根据第一至第十四实施方案中任一项所述的组合物，其中所述组合物中的第二除草剂和第三除草剂是草丁膦或其农业上可接受的盐、酯和酰胺以及氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺，其中以gae/ha与gai/ha或gae/ha与gae/ha为单位给出的式(I)的化合物或其农业上可接受的盐、酯和酰胺与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比包括1:1000:2.2至约1:1:1、从约1:500:2.2至约1:1:1、从约1:400:2.2至约1:1:1、从约1:300:2.2至约1:1:1、从约1:200:2.2至约1:1:1、从约1:100:2.2至约1:1:1、从约1:90:2.2至约1:1:1、从约1:80:2.2至约1:1:1、从约1:70:2.2至约1:1:1、从约1:60:2.2至约1:1:1、从约1:50:2.2至约1:1:1、从约1:40:2.2至约1:1:1、从约1:30:2.2至约1:1:1、从约1:25:2.2至约1:1:1、从约1:20:2.2至约1:1:1、从约1:13:2.2至约1:1:1、从约1:12.5:2.2至约1:1:1、从约1:10:2.2至约1:1:1、从约1:9:2.2至约1:1:1、从约1:8:2.2至约1:1:1、从约1:7:2.2至约1:1:1、从约1:6:2.2至约1:1:1、从约1:5:2.2至约1:1:1、从约1:2:2.2至约1:1:1、约1:2:2.2、约1:4:2.2、约1:5:2.2、约1:10:2.2、约1:12.5:2.2、约1:25:2.2、约1:50:2.2、约1:100:2.2、约1:150:2.2、约1:200:2.2、约1:250:2.2、约1:300:2.2、约1:350:2.2、约1:400:2.2、约1:450:2.2、约1:500:2.2、约1:2:2、约1:4:2、约1:5:2、约1:10:2、约1:12.5:2、约1:25:2、约1:50:2、约1:100:2、约1:150:2、约1:200:2、约1:250:2、约1:300:2、约1:350:2、约1:400:2、约1:450:2、约1:500:2或其任何组合。
第十六实施方案包括根据第一至第十五实施方案中任一项所述的组合物，其中式(I)的化合物是氟氯吡啶酯(halauxifen-methyl)，草丁膦或其农业上可接受的盐、酯和酰胺是草铵膦，并且氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺是氯氟吡氧乙酸异辛酯。
第十七实施方案包括根据第一至第十六实施方案中任一项所述的组合物，其中所述组合物进一步包含至少一种农业上可接受的试剂，所述试剂包含佐剂、载体和/或安全剂。
第十八实施方案包括根据第一至第十七实施方案中任一项的组合物，所述组合物进一步包含至少一种另外的除草剂。
第十九实施方案包括一种防治不希望的植被的方法，其包括以下步骤：向植被和/或土壤和/或水中施用除草有效量的至少一种根据第一至第十七实施方案中任一项所述的组合物或以其他方式使植被和/或土壤和/或水与除草有效量的至少一种根据第一至第十七实施方案中任一项所述的组合物接触。
第二十实施方案包括根据第十九实施方案所述的方法，其中所述方法在由以下组成的组的至少一个成员中实践：直播、水播和/或移栽稻；谷物；小麦；大麦；燕麦；黑麦；高粱；玉米/玉蜀黍；甘蔗；向日葵；油菜；卡诺拉油菜；甜菜；大豆；棉花；菠萝；草地(pasture)；草原；牧场；休耕地；草皮；树和藤蔓果园；水生物；种植作物；蔬菜；工业植被管理(IVM)或路域(right-of-way，ROW)。
第二十一实施方案包括根据第十九和/或第二十实施方案所述的方法，其中除草有效量的将所述组合物在芽前或芽后施用于以下中的至少一种：作物、田地、ROW或稻田。
第二十二实施方案包括根据第十九至二十一实施方案中任一项所述的方法，其中可以在耐受以下的作物中防治所述不希望的植被：草甘膦、5-烯醇丙酮莽草酸-3-磷酸(EPSP)合酶抑制剂、草丁膦、谷氨酰胺合成酶抑制剂、麦草畏、苯氧基生长素、吡啶氧基生长素、合成生长素、生长素运输抑制剂、芳氧基苯氧基丙酸酯、环己二酮、苯基吡唑啉、乙酰辅酶A羧化酶(ACC酶)抑制剂、咪唑啉酮、磺酰脲、嘧啶基硫代苯甲酸酯、三唑并嘧啶、磺酰基氨基羰基三唑啉酮、乙酰乳酸合酶(ALS)或乙酰羟酸合酶(AHAS)抑制剂、4-羟苯基丙酮酸双加氧酶(HPPD)抑制剂、八氢番茄红素去饱和酶抑制剂、类胡萝卜素生物合成抑制剂、原卟啉原氧化酶(PPO)抑制剂、纤维素生物合成抑制剂、有丝分裂抑制剂、微管抑制剂、极长链脂肪酸抑制剂、脂肪酸和脂质生物合成抑制剂、光合系统I抑制剂、光合系统II抑制剂、原卟啉原氧化酶(PPO)抑制剂、三嗪、或溴草腈。
第二十三实施方案包括根据第十九至第二十二实施方案中任一项所述的方法，其中处理对至少一种除草剂具有抗性或耐受性的植物，并且在所述抗性耐受性作物具有赋予了对多种作用方式的多种除草剂或抑制剂的耐受性的多种或叠加性状的情况下，在一些实施方案中，对除草剂表达出抗性或耐受性的经处理的植物是本身不希望的植被。
第二十四实施方案包括根据第十九至二十三实施方案中任一项所述的方法，其中所述抗性或耐受性杂草是对多种除草剂作用方式的多种除草剂、多种化学类别、抑制剂具有抗性或耐受性或通过多种抗性机制而具有抗性或耐受性的生物型。
第二十五实施方案包括根据第十九至第二十四实施方案中任一项所述的方法，其中所述抗性或耐受性的不希望的植物是对由以下组成的至少一种或多种作用方式具有抗性或耐受性的生物型：乙酰乳酸合酶(ALS)抑制剂或乙酰羟酸合酶(AHAS)抑制剂、光合系统II抑制剂、乙酰辅酶A羧化酶(ACC酶)抑制剂、合成生长素、生长素运输抑制剂、光合系统I抑制剂、5-烯醇丙酮莽草酸-3-磷酸(EPSP)合酶抑制剂、微管组装抑制剂、脂肪酸和脂质合成抑制剂、原卟啉原氧化酶(PPO)抑制剂、类胡萝卜素生物合成抑制剂、极长链脂肪酸(VLCFA)抑制剂、八氢番茄红素去饱和酶(PDS)抑制剂、谷氨酰胺合成酶抑制剂、4-羟苯基-丙酮酸-双加氧酶(HPPD)抑制剂、有丝分裂抑制剂、纤维素生物合成抑制剂、具有多种作用方式的除草剂、二氯喹啉酸、芳基氨基丙酸、燕麦枯、草多索、或有机砷。
第二十五实施方案包括一种防治不希望的植被的方法，其包括以下步骤：施用除草有效量的至少一种根据第一至第十八实施方案中任一项所述的化合物，其中所述组合物的量按以gai/ha或gae/ha表述的比率的式(I)或其农业上可接受的盐、酯和酰胺来施用，所述比率包括约：1、2、3、4、5、6、7、8、9和10gai/ha或gae/ha或其任何组合。
第二十六实施方案包括根据第二十五实施方案所述的方法，其中所述组合物的量按以gai/ha或gae/ha表述的比率的草丁膦或其农业上可接受的盐、酯和酰胺来施用，所述比率包括约：1、5、10、25、50、100、150、200、250、300、350、400、450、500和1000gai/ha或gae/ha或其任何组合。
第二十六实施方案包括根据第二十五和/或第二十六实施方案所述的方法，其中所述组合物的量按以gai/ha或gae/ha表述的比率的氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺来施用，所述比率包括约：1、2、2.2、2.5、4、4.4、4.5、5、8、8.8、9、10、17.5、35、70、100和200gai/ha或gae/ha或其任何组合。
第二十七实施方案包括根据第十九至第二十六实施方案中任一项所述的方法，其中被防治的植物是至少一种植物，其包括：苘麻(Abutilon theophrasti Medik.)(绒毛叶，ABUTH)、西部苋(Amaranthus rudis Sauer)(普通水麻(common waterhemp)，AMATA)、藜(Chenopodium album L.)(普通藜(common lambsquarter)，CHEAL)、卷茎蓼(Polygonumconvolvulus L.)(野生荞麦，POLCO)、新疆白芥(Sinapis arvensis L.)(野芥(wildmustard)，SINAR)和/或至少一种白酒草属(Conyza)物种。与这些实施方案一致，所述至少一种白酒草属物种包括但不限于苏门白酒草(Conyza sumatrensis)(苏门达腊飞蓬(Sumatran fleabane)，ERISU)、加拿大白酒草(Conyza canadensis)(加拿大飞蓬(Canadian fleabane)，ERICA)、香丝草(Conyza bonariensis)(多毛飞蓬(hairyfleabane)，ERIBO)或其他相关的飞蓬物种(白酒草属物种，ERISS)。
第二十八实施方案包括一种防治不希望的植被的方法，其包括使植被或其场所与根据第一至第十八实施方案中任一项所述的组合物接触或向土壤或水中施用根据第一至第十八实施方案中任一项所述的组合物以防止植被的生长的出苗。
第二十九实施方案包括根据第十九至第二十八实施方案中任一项所述的方法，其中所述不希望的植被是未成熟的。
第三十实施方案包括根据第十九至第二十九实施方案中任一项所述的方法，其中将根据第一至第十八实施方案中任一项所述的组合物施用于水中。
第三十一实施方案包括根据第十九至第三十实施方案中任一项所述的方法，其中将根据第一至第十八实施方案中任一项所述的组合物在芽前施用于作物或生长区。
第三十二实施方案包括根据第十九至第三十一实施方案中任一项所述的方法，其中将根据第一至第十八实施方案中任一项所述的组合物在芽后施用于作物或生长区。
第三十三实施方案包括根据第十九至第三十二实施方案中任一项所述的方法，其中所述耐受性作物具有赋予了对多种除草剂或多种作用方式的耐受性的多种或叠加性状。
具体实施方式
尽管在本文的附图和描述中详细说明和描述了本公开文本的构思，但是附图和它们的描述中的结果在特征方面将被认为是示例性的而不是限制性的；应当理解，仅示出和描述了说明性实施例，并且希望保护落入本公开文本的精神内的所有改变和修改。
定义
除非另有定义，否则科学和技术术语具有与本公开文本相关的领域的普通技术人员通常理解的含义相同的含义。
如本文所用，除非另有明确说明或另有明确暗示，否则术语‘约’是指值加或减10％的范围，例如约1.0包含从0.9至1.1的值。
如本文所用，式(I)的化合物具有以下结构：
其中X代表CH或N，hal代表F、Cl或Br，R代表甲基或乙基，并且R’代表H、甲基或乙基，或其农业上可接受的盐、酯和酰胺。除非另有明确说明或另有明确暗示，否则式(I)的化合物可以包括但不限于氟氯吡啶酸或氟氯吡啶酯。
如本文所用，氟氯吡啶酯(4-氨基-3-氯-6-(4-氯-2-氟-3-甲氧基苯基)吡啶甲酸甲酯)具有以下结构：
它描述在美国专利7,314,849B2中，将所述专利通过引用以其整体并入本文。氟氯吡啶酯的示例性用途包括其防治阔叶杂草(例如在谷物作物中)的用途。氟氯吡啶酯可以作为其他形式来使用，例如氟氯吡啶酸K+(4-氨基-3-氯-6-(4-氯-2-氟-3-甲氧基苯基)吡啶甲酸钾)，其具有以下结构：
如本文所用，式(I)的吡啶或嘧啶羧酸可以包括4-氨基-3-氯-6-(4-氯-2-氟-3-甲氧基苯基)吡啶-2-甲酸和6-氨基-5-氯-2-(4-氯-2-氟-3-甲氧基苯基)-嘧啶-4-甲酸衍生物可以式(I)的吡啶或嘧啶羧酸。式(I)的化合物的示例性用途包括在多种非作物和作物情况下防治不希望的植被，包括但不限于禾草、阔叶和莎草杂草。
如本文所用，草丁膦是2-氨基-4-[羟基(甲基)膦酰基]丁酸。草丁膦的示例性形式是草铵膦，即草丁膦的铵盐。它可以被称为2-氨基-4-(羟甲基膦基)丁酸单铵盐，并且具有以下结构：
草丁膦(或膦丝菌素(phosphinothricin))的其他化学形式包括双丙氨磷(bialaphos)，其为2-氨基-4-(甲基膦基)丁酰基丙氨酰基丙氨酸并且具有以下结构：
双丙氨磷也可以以盐的形式使用，诸如双丙氨磷钠。示例性用途描述在Tomlin,C.和编辑A World Compendium The Pesticide Manual.第15版Alton:BCPC Publications,2009(下文为“The Pesticide Manual,第十五版,2009.”)中。示例性用途包括其防治一年生和多年生阔叶杂草和禾草的用途。其他化学形式包括草丁膦-P，即S-2-氨基-4-[羟基(甲基)膦酰基]丁酸。
如本文所用，氯氟吡氧乙酸是2-[(4-氨基-3,5-二氯-6-氟-2-吡啶基)氧基]乙酸并且具有以下结构：
氯氟吡氧乙酸的示例性用途描述在The Pesticide Manual,第十五版,2009中。氯氟吡氧乙酸的示例性用途包括其用于芽后叶面施用以防治阔叶杂草(例如在小粒谷类作物中)、防治草地中的酸模属物种(Rumex spp.)和异株荨麻(Urtilca dioica)以及防治消遣草原中的白三叶草(Trifolium repens)的用途。其他示例性用途包括其防治草本和木本阔叶杂草(例如，在果园和种植园作物中)以及阔叶灌木(例如在针叶林中)的用途。氯氟吡氧乙酸的示例性化学形式包括例如氯氟吡氧乙酸甲基庚酯(也称为氯氟吡氧乙酸异辛酯)，其为2-[(4-氨基-3,5-二氯-6-氟-2-吡啶基)氧基]乙酸1-甲基庚酯并且具有以下结构：
如本文所用，除草剂意指杀死、防治或以其他方式不利地改变植物的生长的化合物，例如活性成分。
如本文所用，除草有效量或植被防治量是活性成分的量，所述量引起对植物的不利改变作用，例如引起偏离自然发育、杀死、影响调节、引起干燥、引起迟缓等。
如本文所用，防治不希望的植被意指防止、减少、杀死或以其他方式不利地改变植物和植被的发育。本文描述了通过施用某些除草剂组合或组合物来防治不希望的植被的方法。施用方法包括但不限于施用于植物或其场所，例如施用于与植被相邻的区域，以及经由手、背包、机器、拖拉机或空中(飞机和直升机)施用方法的芽前、芽后、叶面(撒播、直播、带播、点播、机械、顶上、或挽救)和在水中施用(浮出和沉水植被、撒播、点播、机械、注水、颗粒播撒、颗粒点播、摇瓶或流喷雾)。
如本文所用，植物和植被包括但不限于发芽的种子、出苗的幼苗、从营养繁殖体中长出的植物、未成熟的植被和建立的植被。
如本文所用，农业上可接受的盐和酯是指展现出除草活性的盐和酯或在植物、水或土壤中转化或可以转化为提及的除草剂的盐和酯。示例性的农业上可接受的酯是水解、氧化、代谢或以其他方式转化或可以水解、氧化、代谢或以其他方式转化(例如在植物、水或土壤中)为对应的羧酸的那些，取决于pH，所述羧酸可以呈解离的或未解离的形式。
示例性盐包括衍生自碱金属或碱土金属的那些以及衍生自氨和胺的那些。示例性阳离子包括下式的钠、钾、镁和铵阳离子：
R1R2R3R4N+
其中R1、R2、R3和R4各自独立地代表氢或C1-C12烷基、C3-C12烯基或C-C12炔基，其中每个任选地被一个或多个羟基、C1-C4烷氧基、C1-C4烷硫基或苯基取代，条件是R1、R2、R3和R4是在空间上相容的。另外，R1、R2、R3和R4中的任何两个一起可以代表含有1至12个碳原子和最多两个氧或硫原子的脂族双官能部分。盐可以通过用金属氢氧化物(诸如氢氧化钠)、胺(诸如氨、三甲胺、二乙醇胺、2-甲硫基丙胺、双烯丙胺、2-丁氧基乙胺、吗啉、环十二胺或苄胺)或四烷基氢氧化铵(诸如四甲基氢氧化铵或氢氧化胆碱)处理来制备。
示例性酯包括衍生自C1-C12烷基、C3-C12烯基、C3-C12炔基或C7-C10芳基取代的烷基醇(诸如甲醇、异丙醇、1-丁醇、2-乙基己醇、丁氧基乙醇、甲氧基丙醇、烯丙醇、炔丙醇、环己醇或未经取代或经取代的苄醇)的那些。苄醇可以被从1-3个独立地选自卤素、C1-C4烷基或C1-C4烷氧基的取代基取代。酯可以通过使用任何数量的合适的活化剂(诸如用于肽偶联的那些，诸如二环己基碳二亚胺(DCC)或羰基二咪唑(CDI))将酸与醇偶联；通过在碱(诸如三乙胺或碳酸锂)的存在下使酸与烷基化剂(诸如烷基卤或烷基磺酸盐)反应；通过使酸的相应酰氯与适当的醇反应；通过在酸催化剂存在下使相应的酸与适当的醇反应或通过酯交换来制备。
组合物和方法
本文提供了除草组合物，其包含除草有效量的(a)式(I)的化合物：
其中X代表CH或N，hal代表F、Cl或Br，R代表甲基或乙基，并且R’代表H、甲基或乙基，或其农业上可接受的盐或酯，(b)第二除草剂，所述第二除草剂包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺；和/或(c)第三除草剂，所述第三除草剂包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺。
本文还提供了防治不希望的植被的方法，其包括使所述植被或其场所(即，与所述植被相邻的区域)与除草有效量的式(I)的化合物或其农业上可接受的盐或酯接触或向土壤或水中施用除草有效量的式(I)的化合物或其农业上可接受的盐或酯以防止植被的出苗或生长；(b)第二除草剂，所述第二除草剂包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺；和/或(c)第三除草剂，所述第三除草剂包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺。在某些实施方案中，所述方法使用本文所述的组合物。
此外，在一些实施方案中，式(I)的化合物或其农业上可接受的盐或酯；包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺的第二除草剂；和/或包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺的第三除草剂的组合在组合时比在单独施用时更有效。
在本文所述的组合物和方法的某些实施方案中，使用式(I)的化合物(即，氟氯吡啶酸酯)。在某些实施方案中，使用式(I)的化合物的羧酸盐。在某些实施方案中，使用芳烷基酯或烷基酯。在某些实施方案中，使用苄基、经取代的苄基或C1-4烷基(例如，正丁基)酯。在某些实施方案中，使用苄基酯。
在一些实施方案中，将式(I)的化合物或其盐或酯；包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺的第二除草剂；和/或包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺的第三除草剂配制在一种组合物中，罐混合，同时施用或顺序地施用。
当将所述化合物直接施用于处于生长的任何阶段的植物或植物的场所时，它们展现出除草活性。所观察到的作用取决于有待防治的植物物种、植物生长阶段、稀释度和喷雾滴尺寸的施用参数、固体组分的粒度、使用时的环境条件、所使用的具体化合物、所使用的具体佐剂和载体、土壤类型等以及所施用的化学品的量。可以调节这些和其他因素以促进非选择性或选择性除草作用。在一些实施方案中，将本文所述的组合物作为芽后施用、芽前施用、或在水中施用于淹水水稻或水体(例如，池塘、湖泊和流)而施用于相对未成熟的不希望的植被，以实现对杂草的最大防治。
在一些实施方案中，本文提供的组合物和方法用于防治作物中的杂草，所述作物包括但不限于直播、水播和/或移栽稻；谷物；小麦；大麦；燕麦；黑麦；高粱；玉米/玉蜀黍；甘蔗；向日葵；油菜；卡诺拉油菜；甜菜；大豆；棉花；菠萝；草地；草原；牧场；休耕地；草皮；树和藤蔓果园；水生物；种植作物；蔬菜；工业植被管理(IVM)和路域(ROW)。
本文所述的组合物和方法可以例如与草甘膦、EPSP合酶抑制剂、草丁膦、谷氨酰胺合酶抑制剂、麦草畏、苯氧基生长素、吡啶氧基生长素、合成生长素、生长素运输抑制剂、芳氧基苯氧基丙酸酯、环己二酮、苯基吡唑啉、ACC酶抑制剂、咪唑啉酮、磺酰脲、嘧啶基硫代苯甲酸酯、三唑并嘧啶、磺酰基氨基羰基三唑啉酮、ALS或AHAS抑制剂、HPPD抑制剂、八氢番茄红素去饱和酶抑制剂、类胡萝卜素生物合成抑制剂、PPO抑制剂、纤维素生物合成抑制剂、有丝分裂抑制剂、微管抑制剂、极长链脂肪酸抑制剂、脂肪酸和脂质生物合成抑制剂、光合系统I抑制剂、光合系统II抑制剂、三嗪、和溴草腈结合用于防治在草甘膦耐受性、5-烯醇丙酮莽草酸-3-磷酸(EPSP)合酶抑制剂耐受性、草丁膦耐受性、谷氨酰胺合成酶抑制剂耐受性、麦草畏耐受性、苯氧基生长素耐受性、吡啶氧基生长素耐受性、生长素耐受性、生长素运输抑制剂耐受性、芳氧基苯氧基丙酸酯耐受性、环己二酮耐受性、苯基吡唑啉耐受性、乙酰辅酶A羧化酶(ACC酶)抑制剂耐受性、咪唑啉酮耐受性、磺酰脲耐受性、嘧啶基硫代苯甲酸酯耐受性、三唑并嘧啶耐受性、磺酰基氨基羰基三唑啉酮耐受性、乙酰乳酸合酶(ALS)或乙酰羟酸合酶(AHAS)抑制剂耐受性、4-羟苯基丙酮酸双加氧酶(HPPD)抑制剂耐受性、八氢番茄红素去饱和酶抑制剂耐受性、类胡萝卜素生物合成抑制剂耐受性、原卟啉原氧化酶(PPO)抑制剂耐受性、纤维素生物合成抑制剂耐受性、有丝分裂抑制剂耐受性、微管抑制剂耐受性、极长链脂肪酸抑制剂耐受性、脂肪酸和脂质生物合成抑制剂耐受性、光合系统I抑制剂耐受性、光合系统II抑制剂耐受性、三嗪耐受性和溴草腈耐受性作物(诸如但不限于大豆、棉花、卡诺拉油菜/油菜、稻、谷物、玉米、高粱、向日葵、甜菜、甘蔗、草皮等)中的不希望的植被。所述组合物和方法可以用于防治在作物中的不希望的植被，所述作物具有赋予了对多种作用方式的多种化学品和/或抑制剂的耐受性的多种或叠加性状。在一些实施方案中，将式(I)的化合物或其盐或酯和互补的除草剂或其盐或酯与除草剂组合使用，所述除草剂对所处理的作物具有选择性，并且所述除草剂补充由这些化合物以所用的施用率防治的杂草谱。在一些实施方案中，同时、作为组合配制品、作为罐混合物或顺序地施用本文所述的组合物和其他互补除草剂。
所述组合物和方法可以用于防治在作物中的不希望的植被，所述作物具有农艺应激耐受性(包括但不限于干旱、冷、热、盐、水、营养物、肥力、pH)、有害生物耐受性(包括但不限于昆虫、真菌和病原体)和作物改善性状(包括但不限于产率；蛋白质、碳水化合物或油含量；蛋白质、碳水化合物或油组成；植物高度和植物结构)。
本文提供的组合物和方法用于防治不希望的植被。不希望的植被包括但不限于在稻、谷物、小麦、大麦、燕麦、黑麦、草地、草原、牧场、休耕地、行栽作物(例如，玉米或玉蜀黍、甘蔗、向日葵、油菜、卡诺拉油菜、甜菜、大豆、棉花)、草皮、树和藤蔓果园、种植作物、蔬菜、观赏物种、水生物或非作物环境(例如，路域、工业植被管理)中出现的不希望的植被。
在一些实施方案中，本文提供的方法用于防治在稻中的不希望的植被。在某些实施方案中，不希望的植被是阔叶臂形草(Brachiaria platyphylla(Groseb.)Nash)或阔叶尾稃草(Urochloa platyphylla(Nash)R.D.Webster)(阔叶信号草(broadleafsignalgrass)，BRAPP)、棉田马唐(Digitaria sanguinalis(L.)Scop.)(大马唐草(largecrabgrass)，DIGSA)、稗属物种(Echinochloa species)(ECHSS)、对稗草(Echinochloacrus-galli(L.)P.Beauv.)(稗草(barnyardgrass)，ECHCG)、孔雀稗(Echinochloa crus-pavonis(Kunth)Schult.)(孔雀稗(gulf cockspur)，ECHCV)、光头稗(Echinochloacolonum(L.)LINK)(光头稗(junglerice)，ECHCO)、水田稗(Echinochloa oryzoides(Ard.)Fritsch)(早熟水包禾(early watergrass)，ECHOR)、空心稗(Echinochloa oryzicola(Vasinger)Vasinger)(晚熟水包禾(late watergrass)，ECHPH)、水稗(Echinochloaphyllopogon(Stapf)Koso-Pol.)(稻稗草(rice barnyardgrass)，ECHPH)、多穗稗(Echinochloa polystachya(Kunth)Hitchc.)(匍匐河草(creeping river grass)，ECHPO)、田间鸭嘴草(Ischaemum rugosum Salisb.)(鸭嘴草(saramollagrass)，ISCRU)、中国千金子(Leptochloa chinensis(L.)Nees)(中国千金子(Chinese sprangletop)，LEFCH)、丛生千金子(Leptochloa fascicularis(Lam.)Gray)(有芒千金子(beardedsprangletop)，LEFFA)、类黍千金子(Leptochloa panicoides(Presl.)Hitchc.)(亚马逊千金子(Amazon sprangletop)，LEFPA)、稻属物种(Oryza species)(红色杂草稻(red andweedy rice)，ORYSS)、洋野黍(Panicum dichotomiflorum(L.)Michx.)(秋黍子(fallpanicum)，PANDI)、毛花雀稗(Paspalum dilatatum Poir.)(雀稗草(dallisgrass)，PASDI)、筒轴茅(Rottboellia cochinchinensis(Lour.)W.D.Clayton)(罗氏草(itchgrass)，ROOEX)、莎草属物种(Cyperus species)(CYPSS)、异型莎草(Cyperusdifformis L.)(小花莎草(smallflower flatsedge)，CYPDI)、Cyperus dubius Rottb.(MAPDU)、油莎草(Cyperus esculentus L.)(黄色香附子(yellow nutsedge)，CYPES)、碎米莎草(Cyperus iria L.)(稻莎草(rice flatsedge)，CYPIR)、金门莎草(Cyperus rotundusL.)(紫色香附子(purple nutsedge)，CYPRO)、水莎草(Cyperus serotinus Rottb./C.B.Clarke)(沙泽莎草(tidalmarsh flatsedge)，CYPSE)、荸荠属物种(Eleocharisspecies)(ELOSS)、刚飘拂草(Fimbristylis miliacea(L.)Vahl)(globe fringerush)，FIMMI)、拟莞属物种(Schoenoplectus species)(SCPSS)、萤蔺(Schoenoplectusjuncoides Roxb.)(日本香蒲(Japanese bulrush)，SCPJU)、海滨三棱草(Bolboschoenusmaritimus(L.)Palla)或海滨拟莞(Schoenoplectus maritimus L.Lye)(sea clubrush，SCPMA)、水毛花(Schoenoplectus mucronatus L.)(稻田香蒲(ricefield bulrush)，SCPMU)、合萌属物种(Aeschynomene species)(合萌(jointvetch)，AESSS)、喜旱莲子草(Alternanthera philoxeroides(Mart.)Griseb.)(鳄鱼草(alligatorweed)，ALRPH)、川泽泻(Alisma plantago-aquatica L.)(普通泽泻(common waterplantain)，ALSPA)、苋属物种(Amaranthus species)(藜(pigweed)和苋(amaranth)，AMASS)、长叶水苋菜(Ammanniacoccinea Rottb.)(红茎草(redstem)，AMMCO)、圆叶鸭跖草(Commelina benghalensis L.)(饭包草(Benghal dayflower)，COMBE)、旱莲草(Eclipta alba(L.)Hassk.)(美洲鳢肠(American false daisy)，ECLAL)、沼生异蕊花(Heteranthera limosa(SW.)Willd./Vahl)(ducksalad，HETLI)、肾形异蕊花(Heteranthera reniformis R.&P.)(圆叶异芯花(roundleaf mudplantain)，HETRE)、番薯属物种(Ipomoea species)(喇叭花(morningglory)，IPOSS)、裂叶牵牛(Ipomoea hederacea(L.)Jacq.)(常春藤叶牵牛(ivyleaf morningglory)，IPOHE)、美洲母草(Lindernia dubia(L.)Pennell)(low falsepimpernel，LIDDU)、丁香蓼属物种(Ludwigia species)(LUDSS)、亚麻叶丁香蓼(Ludwigialinifolia Poir.)(东南毛草龙(southeastern primrose-willow)，LUDLI)、水丁香(Ludwigia octovalvis(Jacq.)Raven)(长果毛草龙(longfruited primrose-willow)，LUDOC)、雨久花(Monochoria korsakowii Regel&Maack)(雨久花(monochoria)，MOOKA)、鸭舌草(Monochoria vaginalis(Burm.F.)C.Presl ex Kuhth)(雨久花(monochoria)，MOOVA)、裸花水竹叶(Murdannia nudiflora(L.)Brenan)(鸽草(doveweed)，MUDNU)、宾州蓼(Polygonum pensylvanicum L.)(宾州荨麻(Pennsylvania smartweed)，POLPY)、春蓼(Polygonum persicaria L.)(桃叶蓼(ladysthumb)，POLPE)、辣椒蓼(Polygonumhydropiperoides Michx.)(POLHP，中等蓼(mild smartweed))、节节菜(Rotala indica(Willd.)Koehne)(印度紫水苋菜(Indian toothcup)，ROTIN)、慈姑属物种(Sagittariaspecies)(慈菇(arrowhead)，SAGSS)、大麻田菁(Sesbania exaltata(Raf.)Cory/Rydb.ExHill)(大麻田菁(hemp sesbania)，SEBEX)、或尖瓣花(Sphenoclea zeylanica Gaertn.)(鹅草(gooseweed)，SPDZE)。
在一些实施方案中，本文提供的方法用于防治在谷物中的不希望的植被。在某些实施方案中，不希望的植被是鼠尾看麦娘(Alopecurus myosuroides Huds.)(黑草(blackgrass)，ALOMY)、阿披拉草(Apera spica-venti(L.)Beauv.)(风草(windgrass)，APESV)、野燕麦(Avena fatua L.)(野生燕麦(wild oat)，AVEFA)、旱雀麦(Bromustectorum L.)(绒毛雀麦草(downy brome)，BROTE)、多花黑麦草(Lolium multiflorumLam.)(意大利黑麦草(Italian ryegrass)，LOLMU)、细虉草(Phalaris minor Retz.)(小籽虉草(littleseed canarygrass)，PHAMI)、一年生早熟禾(Poa annua L.)(一年生蓝草(annual bluegrass)，POANN)、金色狗尾草(Setaria pumila(Poir.)Roemer&J.A.Schultes)(黄狐尾草(yellow foxtail)，SETLU)、狗尾草(Setaria viridis(L.)Beauv.)(绿狐尾草(green foxtail)，SETVI)、反枝苋(Amaranthus retroflexus L.)(红根苋(redroot pigweed)，AMARE)、芸苔属物种(Brassica species)(BRSSS)、藜(Chenopodiumalbum L.)(普通藜(common lambsquarter)，CHEAL)、丝路蓟(Cirsium arvense(L.)Scop.)(加拿大蓟(Canada thistle)，CIRAR)、拉拉藤(Galium aparine L.)(猪殃殃(catchweedbedstraw)，GALAP)、地肤(Kochia scoparia(L.)Schrad.)(地肤(kochia)，KCHSC)、紫花野芝麻(Lamium purpureum L.)(紫色枯荨麻(purple deadnettle)，LAMPU)、洋甘菊(Matricaria recutita L.)(野甘菊(wild chamomile)，MATCH)、同花母菊(Matricariamatricarioides(Less.)Porter)(香甘菊(pineappleweed)，MATMT)、虞美人(Papaverrhoeas L.)(普通罂粟(common poppy)，PAPRH)、卷茎蓼(Polygonum convolvulus L.)(野荞麦(wild buckwheat)，POLCO)、风滚草(Salsola tragus L.)(俄国蓟(Russianthistle)，SASKR)、白芥属物种(Sinapis species)(SINSS)、新疆白芥(Sinapis arvensisL.)(野芥(wild mustard)，SINAR)、繁缕(Stellaria media(L.)Vill.)(普通繁缕(commonchickweed)，STEME)、阿拉伯婆婆纳(Veronica persica Poir.)(波斯婆婆纳(Persianspeedwell)，VERPE)、野生堇菜(Viola arvensis Murr.)(田野堇菜(field violet)，VIOAR)、或三色堇(Viola tricolor L.)(野生堇菜(wild violet)，VIOTR)。
在一些实施方案中，本文提供的方法用于防治在范围和草地、休耕地、IVM和ROW中的不希望的植被。在某些实施方案中，不希望的植被是豚草(Ambrosia artemisiifoliaL.)(普通豚草(common ragweed)，AMBEL)、钝叶决明(Cassia obtusifolia)(镰果灯心草豆(sickle pod)，CASOB)、斑点矢车菊(Centaurea maculosa auct.non Lam.)(斑点矢车菊(spotted knapweed)，CENMA)、丝路蓟(Cirsium arvense(L.)Scop.)(加拿大蓟(Canadathistle)，CIRAR)、田旋花(Convolvulus arvensis L.)(田野旋花(field bindweed)，CONAR)、胡萝卜(Daucus carota L.)(野生胡萝卜(wild carrot)，DAUCA)、乳浆大戟(Euphorbia esula L.)(乳浆草(leafy spurge)，EPHES)、毒莴苣(Lactuca serriola L./Torn.)(多刺莴苣(prickly lettuce)，LACSE)、长叶车前(Plantago lanceolata L.)(鹿角车前草(buckhorn plantain)，PLALA)、钝叶酸模(Rumex obtusifolius L.)(苦酸模(broadleaf dock)，RUMOB)、刺金午时花(Sida spinosa L.)(多刺金午时花(pricklysida)，SIDSP)、新疆白芥(Sinapis arvensis L.)(野芥(wild mustard)，SINAR)、苦苣菜(Sonchus arvensis L.)(多年生苦苣菜(perennial sowthistle)，SONAR)、一枝黄花属物种(Solidago species)(秋麒麟草(goldenrod)，SOOSS)、西洋蒲公英(Taraxacumofficinale G.H.Weber ex Wiggers)(蒲公英(dandelion)，TAROF)、白三叶草(Trifoliumrepens L.)(白三叶草(white clover)，TRFRE)、或异株荨麻(Urtica dioica L.)(普通荨麻(common nettle)，URTDI)。
在一些实施方案中，本文提供的方法用于防治在行栽作物、树和藤蔓作物、和多年生作物中找到的不希望的植被。在某些实施方案中，不希望的植被是鼠尾看麦娘(Alopecurus myosuroides Huds.)(黑草(blackgrass)，ALOMY)、野燕麦(Avena fatua L.)(野生燕麦(wild oat)，AVEFA)、伏生臂形草(Brachiaria decumbens Stapf.)或倾伏尾稃草(Urochloa decumbens(Stapf)R.D.Webster)(苏里南草(Surinam grass)，BRADC)、珊状臂形草(Brachiaria brizantha(Hochst.ex A.Rich.)Stapf.)或珊状尾稃草(Urochloabrizantha(Hochst.ex A.Rich.)R.D.)(银须芒草(beard grass)，BRABR)、阔叶臂形草(Brachiaria platyphylla(Groseb.)Nash)或阔叶尾稃草(Urochloa platyphylla(Nash)R.D.Webster)(阔叶信号草(broadleaf signalgrass)，BRAPP)、车前臂形草(Brachiariaplantaginea(Link)Hitchc.)或Urochloa plantaginea(Link)R.D.Webster)(亚历山大草(alexandergrass)，BRAPL)、蒺藜草(Cenchrus echinatus L.)(棘蒺藜草(southernsandbur)，CENEC)、平枝马唐(Digitaria horizontalis Willd.)(牙买加马唐草(Jamaicancrabgrass)，DIGHO)、两耳草(Digitaria insularis(L.)Mez ex Ekman)(酸草(sourgrass)，TRCIN)、棉田马唐(Digitaria sanguinalis(L.)Scop.)(大马唐草(largecrabgrass)，DIGSA)、对稗草(Echinochloa crus-galli(L.)P.Beauv.)(稗草(barnyardgrass)，ECHCG)、光头稗(Echinochloa colonum(L.)Link)(光头稗(junglerice)，ECHCO)、牛筋草(Eleusine indica(L.)Gaertn.)(蟋蟀草(goosegrass)，ELEIN)、多花黑麦草(Lolium multiflorum Lam.)(意大利黑麦草(Italian ryegrass)，LOLMU)、洋野黍(Panicum dichotomiflorum Michx.)(秋黍子(fall panicum)，PANDI)、稷(Panicum miliaceum L.)(野黍(wild-proso millet)，PANMI)、大狗尾草(Setaria faberiHerrm.)(谷莠子(giant foxtail)，SETFA)、狗尾草(Setaria viridis(L.)Beauv.)(绿狐尾草(green foxtail)，SETVI)、石茅(Sorghum halepense(L.)Pers.)(约翰逊草(Johnsongrass)，SORHA)、双色高粱(Sorghum bicolor(L.)Moench ssp.Arundinaceum)(shattercane，SORVU)、油莎草(Cyperus esculentus L.)(黄色香附子(yellownutsedge)，CYPES)、金门莎草(Cyperus rotundus L.)(紫色香附子(purple nutsedge)，CYPRO)、苘麻(Abutilon theophrasti Medik.)(绒毛叶(velvetleaf)，ABUTH)、苋属物种(Amaranthus species)(藜(pigweed)和苋(amaranth)，AMASS)、豚草(Ambrosiaartemisiifolia L.)(普通豚草(common ragweed)，AMBEL)、多年生豚草(Ambrosiapsilostachya DC.)(西方豚草(western ragweed)，AMBPS)、三裂叶豚草(Ambrosiatrifida L.)(三裂叶豚草(giant ragweed)，AMBTR)、有距单花葵(Anoda cristata(L.)Schlecht.)(有距单花葵(spurred anoda)，ANVCR)、叙利亚马利筋(Asclepias syriacaL.)(普通乳草(common milkweed)，ASCSY)、三叶鬼针草(Bidens pilosa L.)(毛鬼针草(hairy beggarticks)，BIDPI)、丰花草属物种(Borreria species)(BOISS)、Borreriaalata(Aubl.)DC.或Spermacoce alata Aubl.(阔叶纽扣草(broadleaf buttonweed)，BOILF)、阔叶丰花草(Spermacose latifolia)(阔叶纽扣草(broadleaved button weed)，BOILF)、藜(Chenopodium album L.)(普通藜(common lambsquarter)，CHEAL)、丝路蓟(Cirsium arvense(L.)Scop.)(加拿大蓟(Canada thistle)，CIRAR)、圆叶鸭跖草(Commelina benghalensis L.)(热带紫露草(tropical spiderwort)，COMBE)、曼佗罗(Datura stramonium L.)(蔓陀罗(jimsonweed)，DATST)、胡萝卜(Daucus carota L.)(野生胡萝卜(wild carrot)，DAUCA)、白苞猩猩草(Euphorbia heterophylla L.)(野生一品红(wild poinsettia)，EPHHL)、大飞扬草(Euphorbia hirta L.)或飞扬草(Chamaesycehirta(L.)Millsp.)(花园大戟(garden spurge)，EPHHI)、齿裂大戟(Euphorbia dentataMichx.)(锯齿大戟(toothed spurge)，EPHDE)、野塘蒿(Erigeron bonariensis L.)或香丝草(Conyza bonariensis(L.)Cronq.)(多毛飞蓬(hairy fleabane)，ERIBO)、苏门飞蓬(Erigeron sumatrensis)或苏门白酒草(Conyza sumatrensis(苏门达腊飞蓬(Sumatranfleabane)，ERISU)、加拿大飞蓬(Erigeron canadensis L.)或加拿大白酒草(Conyzacanadensis)(加拿大飞蓬(Canadian fleabane)，ERICA)、或其他相关飞蓬物种(白酒草属物种(Conyza spp)，ERISS)、一年生向日葵(Helianthus annuus L.)(普通向日葵(commonsunflower)，HELAN)、头花小牵牛(Jacquemontia tamnifolia(L.)Griseb.)(小花牵牛(smallflower morningglory)，IAQTA)、裂叶牵牛(Ipomoea hederacea(L.)Jacq.)(常春藤叶牵牛(ivyleaf morningglory)，IPOHE)、瘤梗番薯(Ipomoea lacunosa L.)(白牵牛(white morningglory)，IPOLA)、毒莴苣(Lactuca serriola L./Torn.)(多刺莴苣(prickly lettuce)，LACSE)、马齿苋(Portulaca oleracea L.)(普通马齿苋(commonpurslane)，POROL)、墨苜蓿属物种(Richardia species)(马齿笕(pusley)，RCHSS)、金午时花属物种(Sida species)(金午时花(sida)，SIDSS)、刺金午时花(Sidaspinosa L.)(多刺金午时花(prickly sida)，SIDSP)、新疆白芥(Sinapis arvensis L.)(野芥(wildmustard)，SINAR)、Solanum ptychanthum Dunal(东方黑龙葵(eastern blacknightshade)，SOLPT)、羽芒菊(Tridax procumbens L.)(羽芒菊(coat button)，TRQPR)或苍耳(Xanthium strumarium L.)(普通苍耳(common cocklebur)，XANST)。
在一些实施方案中，本文提供的方法用于防治在草皮中的不希望的植被。在某些实施方案中，不希望的植被是雏菊(Bellis perennis L.)(英国雏菊(English daisy)，BELPE)、油莎草(Cyperus esculentus L.)(黄色香附子(yellow nutsedge)，CYPES)、莎草属物种(Cyperus species)(CYPSS)、棉田马唐(Digitaria sanguinalis(L.)Scop.)(大马唐草(large crabgrass)，DIGSA)、弗吉尼亚双角草(Diodia virginiana L.)(弗吉尼亚纽扣草(Virginia buttonweed)，DIQVI)、大戟属物种(Euphorbia species)(大戟(spurge)，EPHSS)、欧活血丹(Glechoma hederacea L.)(连钱草(ground ivy)，GLEHE)、伞花天胡荽(Hydrocotyle umbellata L.)(dollarweed，HYDUM)、水蜈蚣属物种(Kyllinga species)(水蜈蚣(kyllinga)，KYLSS)、宝盖草(Lamium amplexicaule L.)(宝盖草(henbit)，LAMAM)、裸花水竹叶(Murdannia nudiflora(L.)Brenan)(鸽草(doveweed)，MUDNU)、酢浆草属物种(Oxalis species)(酢浆草(woodsorrel)，OXASS)、宽叶车前(Plantago major L.)(宽叶车前(broadleaf plantain)，PLAMA)、长叶车前(Plantago lanceolata L.)(鹿角/窄叶车前(buckhorn/narrowleaf plantain)，PLALA)、叶下珠(Phyllanthus urinaria L.)(珍珠草(chamberbitter)，PYLTE)、钝叶酸模(Rumex obtusifolius L.)(苦酸模(broadleaf dock)，RUMOB)、银条(Stachys floridana Shuttlew.)(佛罗里达水苏(Florida betony)，STAFL)、繁缕(Stellaria media(L.)Vill.)(普通繁缕(commonchickweed)，STEME)、西洋蒲公英(Taraxacum officinale G.H.Weber ex Wiggers)(蒲公英(dandelion)，TAROF)、白三叶草(Trifolium repens L.)(白三叶草(white clover)，TRFRE)、或堇菜属物种(Viola species)(野生堇菜(wild violet)，VIOSS)。
在一些实施方案中，本文提供的组合物和方法用于防治不希望的植被，包括禾草、宽叶和莎草杂草。在某些实施方案中，本文提供的组合物和方法用于防治不希望的植被，包括但不限于看麦娘属(Alopecurus)、燕麦属(Avena)、矢车菊属(Centaurea)、莎草属(Cyperus)、马唐属(Digitaria)、稗属(Echinochloa)、番薯属物种(Ipomoea)、千金子属(Leptochloa)和苦苣菜属(Sonchus)。
在一些实施方案中，式(I)的化合物或其农业上可接受的盐或酯；包含至少一种有机磷除草剂或其农业上可接受的盐、酯和酰胺的第二除草剂；和/或包含至少一种吡啶除草剂或其农业上可接受的盐、酯和酰胺的第三除草剂的组合用于防治苘麻(Abutilontheophrasti Medik.)(绒毛叶，ABUTH)、西部苋(Amaranthus rudis Sauer)(普通水麻(common waterhemp)，AMATA)、藜(Chenopodium album L.)(普通藜(commonlambsquarter)，CHEAL)、卷茎蓼(Polygonum convolvulus L.)(野生荞麦，POLCO)、野芥(Sinapis arvensis L.)(野芥(wild mustard)，SINAR)和/或至少一种白酒草属(Conyza)物种，包括但不限于苏门白酒草(Conyza sumatrensis)(苏门达腊飞蓬(Sumatranfleabane)，ERISU)、加拿大白酒草(Conyza canadensis)(加拿大飞蓬(Canadianfleabane)，ERICA)、香丝草(Conyza bonariensis)(多毛飞蓬(hairy fleabane)，ERIBO)或其他相关的飞蓬物种(白酒草属物种，ERISS)。
式(I)的化合物或其农业上可接受的盐或酯可以用于防治除草剂抗性或耐受性杂草。使用式I的化合物或其农业上可接受的盐或酯和本文所述的组合物的组合的方法还可以用于防治除草剂抗性或耐受性杂草。示例性抗性或耐受性杂草包括但不限于对以下具有抗性或耐受性的生物型：乙酰乳酸合酶(ALS))或乙酰羟酸合酶(AHAS)抑制剂(例如，咪唑啉酮、磺酰脲、嘧啶基硫代苯甲酸酯、三唑并嘧啶、和磺酰基氨基羰基三唑啉酮)、光合系统II抑制剂(例如，苯基氨基甲酸酯、哒嗪酮、三嗪、三嗪酮、尿嘧啶、酰胺、脲、苯并噻二嗪酮、腈、苯基哒嗪)、乙酰辅酶A羧化酶(ACC酶)抑制剂(例如，芳氧基苯氧基丙酸酯、环己二酮、苯基吡唑啉)、合成生长素(例如，苯甲酸、苯氧基羧酸、吡啶羧酸、喹啉羧酸)、生长素运输抑制剂(例如，邻甲酰胺苯甲酸酯、半卡巴腙)、光合系统I抑制剂(例如，联吡啶鎓)、5-烯醇丙酮莽草酸-3-磷酸(EPSP)合酶抑制剂(例如，草甘膦)、谷氨酰胺合成酶抑制剂(例如，草丁膦、双丙氨酰膦(bialafos))、微管组装抑制剂(例如，苯甲酰胺、苯甲酸、二硝基苯胺、氨基磷酸酯、吡啶)、有丝分裂抑制剂(例如，氨基甲酸酯)、极长链脂肪酸(VLCFA)抑制剂(例如，乙酰胺、氯乙酰胺、氧基乙酰胺、四唑啉酮)、脂肪酸和脂质合成抑制剂(例如，二硫代磷酸酯、硫代氨基甲酸酯、苯并呋喃、氯碳酸)、原卟啉原氧化酶(PPO)抑制剂(例如，氟锁草醚、氟锁草醚-钠、唑啶草酮、苯卡巴腙、双苯嘧草酮、治草醚、氟丙嘧草酯、唑草酮(carfentrazone)、唑酮草酯(carfentrazone-ethyl)、甲氧除草醚、吲哚酮草酯(cinidon-ethyl)、异丙吡草酯、氟哒嗪草酸(flufenpyr)、氟哒嗪草酯(flufenpyr-ethyl)、氟烯草酸(flumiclorac)、氟亚胺草酯(flumiclorac-pentyl)、丙炔氟草胺、乙羧氟草醚(fluoroglycofen)、乙羧氟草醚-乙基、嗪草酸、嗪草酸甲酯、氟磺胺草醚、氟硝磺酰胺(halosafen)、三唑酰草胺、乳氟禾草灵、丙炔恶草酮、恶草酮、乙氧氟草醚、戊基恶唑酮、氟唑草胺(profluazol)、双唑草腈、吡草醚(pyraflufen)、吡氟苯草酯(pyraflufen-ethyl)、苯嘧磺草胺、甲磺草胺、噻二唑草胺、氟嘧硫草酯、三氟草嗪(trifludimoxazin)、[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯(CAS 353292-31-6；S-3100)、N-乙基-3-(2,6-二氯-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS452098-92-9)、N-四氢糠基-3-(2,6-二氯-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS 915396-43-9)、N-乙基-3-(2-氯-6-氟-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS 452099-05-7)、N-四氢糠基-3-(2-氯-6-氟-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS45100-03-7)和3-[7-氟-3-氧代-4-(丙-2-炔基)-3,4-二氢-2H-苯并[1,4]噁嗪-6-基]-1,5-二甲基-6-硫酮基-[1,3,5]三嗪烷-2,4-二酮；b5)，其来自漂白剂除草剂的组)、类胡萝卜素生物合成抑制剂(例如，广灭灵(clomazone)、杀草强(amitrole)、苯草醚)、八氢番茄红素去饱和酶(PDS)抑制剂(例如，酰胺、anilidex、呋喃酮、苯氧基丁酰胺、吡啶嗪酮(pyridiazinone)、吡啶)、4-羟苯基-丙酮酸-双加氧酶(HPPD)抑制剂(例如，callistemone、异噁唑、吡唑、三酮)、纤维素生物合成抑制剂(例如，腈、苯甲酰胺、二氯喹啉酸、三唑并酰胺)、具有多种作用方式的除草剂(诸如二氯喹啉酸)、以及未分类的除草剂(诸如芳基氨基丙酸、燕麦枯、草多索、和有机砷)。示例性抗性或耐受性杂草包括但不限于对多种除草剂具有抗性或耐受性的生物型、对多种化学类别具有抗性或耐受性的生物型、对多种除草剂作用方式具有抗性或耐受性的生物型以及具有多种抗性或耐受性机制(例如，靶位点抗性或代谢抗性)的生物型。
在本文所述的组合物和方法的某些实施方案中，将式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺组合使用。在一些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺的重量比在从约1:500至约1:1的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺的重量比在从约1:400至约1:12.5的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺的重量比在从约1:200至约1:25的范围内。在某些实施方案中，本文提供的组合物包含式(I)的化合物或其盐或酯和草丁膦或其铵盐。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯和草铵膦，其中式(I)的化合物或其盐或酯与草铵膦的重量比是从约1:400至约1:12.5或从约1:400至约1:25。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯和草铵膦，其中式(I)的化合物的苄基酯或其盐或酯与草铵膦的重量比是从约1:200至约1:12.5或从约1:200至约1:25。
关于所述方法，在某些实施方案中，所述方法包括使不希望的植被或其场所与本文所述的组合物接触或向土壤或水中施用本文所述的组合物以防止植被的出苗或生长。在一些实施方案中，所述组合物以基于组合物中活性成分的总量从约1克酸当量/公顷(gae/ha)至约400克活性成分/公顷(gai/ha)的施用率施用。在某些实施方案中，所述组合物以基于组合物中活性成分的总量从约4克酸当量/公顷(gae/ha)至约400gae/ha的施用率施用。在一些实施方案中，所述方法包括使不希望的植被或其场所与式(I)的化合物或其盐或酯和草丁膦或其农业上可接受的盐、酯和酰胺或其盐或酯接触或向土壤或水中施用式(I)的化合物或其盐或酯和草丁膦或其农业上可接受的盐、酯和酰胺或其盐或酯，例如顺序地或同时地，以防止植被的出苗或生长。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约50gai/ha至约400gai/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约100gai/ha至约400gai/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约200gai/ha至约400gai/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一个实施方案中，所述方法使用式(I)的化合物和草铵膦，其中式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用，并且草铵膦以约50gai/ha至约400gai/ha的比率施用。在某些实施方案中，使用式(I)的化合物或其盐或酯与草丁膦或其盐或酯的组合的方法和组合物用于防治苘麻(Abutilon theophrasti Medik.)(绒毛叶，ABUTH)、西部苋(Amaranthus rudis Sauer)(普通水麻(common waterhemp)，AMATA)、藜(Chenopodium album L.)(普通藜(common lambsquarter)，CHEAL)、卷茎蓼(Polygonumconvolvulus L.)(野生荞麦，POLCO)、野芥(Sinapis arvensis L.)(野芥(wildmustard)，SINAR)和/或至少一种白酒草属(Conyza)物种，包括但不限于苏门白酒草(Conyza sumatrensis)(苏门达腊飞蓬(Sumatran fleabane)，ERISU)、加拿大白酒草(Conyza canadensis)(加拿大飞蓬(Canadian fleabane)，ERICA)、香丝草(Conyzabonariensis)(多毛飞蓬(hairy fleabane)，ERIBO)或其他相关的飞蓬物种(白酒草属物种，ERISS)。
在本文所述的组合物和方法的某些实施方案中，将式(I)的化合物或其盐或酯与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺组合使用。在一些实施方案中，式(I)的化合物或其盐或酯与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:70至约1:1的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:70至约1:2.2的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:35至约1:8.8的范围内。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯和氯氟吡氧乙酸异辛酯，其中式(I)的化合物或其盐或酯与氯氟吡氧乙酸异辛酯的重量比是从约1:70至约1:1或从约1:70至约1:2.2。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯和氯氟吡氧乙酸异辛酯，其中式(I)的化合物的苄基酯或其盐或酯与氯氟吡氧乙酸异辛酯的重量比是从约1:35至约1:8.8或从约1:35至约1:4.4。
关于所述方法，在某些实施方案中，所述方法包括使不希望的植被或其场所与本文所述的组合物接触或向土壤或水中施用本文所述的组合物以防止植被的出苗或生长。在一些实施方案中，基于组合物中活性成分的总量，所述组合物以从约1克酸当量/公顷(gae/ha)至约70克gae/ha的施用率来施用。在某些实施方案中，所述组合物以基于组合物中活性成分的总量从约4克酸当量/公顷(gae/ha)至约70gae/ha的施用率施用。在一些实施方案中，所述方法包括使不希望的植被或其场所与式(I)的化合物或其盐或酯和氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺或其盐或酯接触或向土壤或水中施用式(I)的化合物或其盐或酯和氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺或其盐或酯，例如顺序地或同时地，以防止植被的出苗或生长。在一些实施方案中，氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约8.8gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约17.5gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约35gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一个实施方案中，所述方法使用式(I)的化合物和氯氟吡氧乙酸异辛酯，其中式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用，并且氯氟吡氧乙酸异辛酯以约8.8gae/ha至约70gai/ha的比率施用。在某些实施方案中，使用式(I)的化合物或其盐或酯与氯氟吡氧乙酸或其盐或酯的组合的方法和组合物用于防治苘麻(Abutilon theophrasti Medik.)(绒毛叶，ABUTH)、西部苋(Amaranthusrudis Sauer)(普通水麻(common waterhemp)，AMATA)、藜(Chenopodium album L.)(普通藜(common lambsquarter)，CHEAL)、卷茎蓼(Polygonum convolvulus L.)(野生荞麦，POLCO)、野芥(Sinapis arvensis L.)(野芥(wild mustard)，SINAR)和/或至少一种白酒草属(Conyza)物种，包括但不限于苏门白酒草(Conyza sumatrensis)(苏门达腊飞蓬(Sumatran fleabane)，ERISU)、加拿大白酒草(Conyza canadensis)(加拿大飞蓬(Canadian fleabane)，ERICA)、香丝草(Conyza bonariensis)(多毛飞蓬(hairyfleabane)，ERIBO)或其他相关的飞蓬物种(白酒草属物种，ERISS)。
在本文所述的组合物和方法的某些实施方案中，将式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺和氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺组合使用。在一些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:400:70至约1:1:1的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:400:70至约1:12.5:2.2的范围内。在某些实施方案中，式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺与氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺的重量比在从约1:200:35至约1:25:8.8的范围内。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯、草铵膦、和氯氟吡氧乙酸异辛酯，其中式(I)的化合物或其盐或酯与草铵膦与氯氟吡氧乙酸异辛酯的重量比是从约1:400:70至约1:1或从约1:400:70至约1:12.5:2.2。在一个实施方案中，所述组合物包含式(I)的化合物或其盐或酯、草铵膦、和氯氟吡氧乙酸异辛酯，其中式(I)的化合物的苄基酯或其盐或酯与草铵膦与氯氟吡氧乙酸异辛酯的重量比是从约1:200:35至约1:12.5:8.8或从约1:200:35至约1:25:4.4。
关于所述方法，在某些实施方案中，所述方法包括使不希望的植被或其场所与本文所述的组合物接触或向土壤或水中施用本文所述的组合物以防止植被的出苗或生长。在一些实施方案中，基于组合物中活性成分的总量，所述组合物以从约1克酸当量/公顷(gae/ha)至约400克gae/ha的施用率来施用。在某些实施方案中，所述组合物以基于组合物中活性成分的总量从约4克酸当量/公顷(gae/ha)至约400gae/ha的施用率施用。在一些实施方案中，所述方法包括使不希望的植被或其场所与式(I)的化合物或其盐或酯，草丁膦或其农业上可接受的盐、酯和酰胺，和氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺或其盐或酯接触或向土壤或水中施用式(I)的化合物或其盐或酯，草丁膦或其农业上可接受的盐、酯和酰胺，和氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺或其盐或酯，例如顺序地或同时地，以防止植被的出苗或生长。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约50gai/ha至约400gai/ha的比率施用，氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约8.8gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约100gae/ha至约400gae/ha的比率施用，氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约17.5gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一些实施方案中，草丁膦或其农业上可接受的盐、酯和酰胺以从约200gae/ha至约400gae/ha的比率施用，氯氟吡氧乙酸或其农业上可接受的盐、酯和酰胺以从约35gae/ha至约70gae/ha的比率施用，并且其盐或酯的式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用。在一个实施方案中，所述方法使用式(I)的化合物、草铵膦、和氯氟吡氧乙酸异辛酯，其中式(I)的化合物以从约1gae/ha至约4gae/ha的比率施用，草铵膦以约50gae/ha至约400gai/ha的比率施用，并且氯氟吡氧乙酸异辛酯以约8.8gae/ha至约70gai/ha的比率施用。在某些实施方案中，使用式(I)的化合物或其盐或酯与草丁膦或其农业上可接受的盐、酯和酰胺和氯氟吡氧乙酸或其盐或酯的组合的方法和组合物用于防治苘麻(Abutilon theophrasti Medik.)(绒毛叶，ABUTH)、西部苋(Amaranthusrudis Sauer)(普通水麻(common waterhemp)，AMATA)、藜(Chenopodium album L.)(普通藜(common lambsquarter)，CHEAL)、卷茎蓼(Polygonum convolvulus L.)(野生荞麦，POLCO)、野芥(Sinapis arvensis L.)(野芥(wild mustard)，SINAR)和/或至少一种白酒草属(Conyza)物种，包括但不限于苏门白酒草(Conyza sumatrensis)(苏门达腊飞蓬(Sumatran fleabane)，ERISU)、加拿大白酒草(Conyza canadensis)(加拿大飞蓬(Canadian fleabane)，ERICA)、香丝草(Conyza bonariensis)(多毛飞蓬(hairyfleabane)，ERIBO)或其他相关的飞蓬物种(白酒草属物种，ERISS)。
本文所述组合物的组分可以单独地施用或作为多部分除草系统的一部分施用。
本文所述的组合物可以与一种或多种另外的除草剂结合施用以防治多种多样的不希望的植被。当与其他除草剂结合使用时，可以将所述组合物与其他一种或多种除草剂一起配制，与其他一种或多种除草剂进行罐混合或与其他一种或多种除草剂顺序地施用。可以与本文所述的组合物和方法结合使用的一些除草剂包括但不限于：4-CPA；4-CPB；4-CPP；3,4-DA；3,4-DB；3,4-DP；2,3,6-TBA；2,4,5-T；2,4,5-TB；乙草胺、氟锁草醚、苯草醚、丙烯醛、甲草胺、二丙烯草胺、禾草灭、烯丙醇、alorac、胺嗪酮(ametridione)、莠灭净、amibuzin、氨唑草酮、酰嘧磺隆、氯丙嘧啶酸、氯氨吡啶酸、甲基胺草磷、杀草强、氨基磺酸铵、莎稗磷、anisuron、磺草灵、莠去通、莠去津、唑啶草酮、四唑嘧磺隆、叠氮津、燕麦灵、BCPC、氟丁酰草胺、草除灵、苯卡巴腙、氟草胺、呋草磺、苄嘧磺隆-甲基、地散磷、禾草丹、苯达松-钠(bentazon-sodium)、胺酸杀、双苯嘧草酮、苄草胺、双环磺草酮(benzobicyclon)、吡草酮、benzofluor、新燕灵(benzoylprop)、苯噻隆、双丙氨磷、氟吡草酮(bicyclopyrone)、治草醚、双丙氨膦、双草醚-钠(bispyribac-sodium)、硼砂、除草定、糠溴草腈(bromobonil)、溴丁酰草胺、溴杀烯、溴草腈、溴杀草敏、去草胺、氟丙嘧草酯、抑草磷、丁烯草胺、丁噻咪草酮(buthidazole)、丁噻隆、地乐胺、丁苯草酮、炔草隆、丁草特(butylate)、卡可基酸、唑草胺、氯酸钙、氰氨化钙、cambendichlor、威磺灵、长杀草、carboxazole chlorprocarb、唑酮草酯、CDEA、CEPC、甲氧除草醚、草灭平、地快乐、炔禾灵(chlorazifop)、可乐津、氯溴隆、氟炔灵、氯特龙(chloreturon)、伐草克(chlorfenac)、燕麦酯(chlorfenprop)、氟咪杀、氯甲丹、杀草敏、氯嘧磺隆、草枯醚(chlornitrofen)、三氯丙酸(chloropon)、绿麦隆、枯草隆、羟敌草腈、氯苯胺灵、氯磺隆、敌草索、氯硫酰草胺、吲哚酮草酯、环庚草醚、醚磺隆、落草胺、烯草酮、cliodinate、炔草酯-炔丙基(clodinafop-propargyl)、氯丁草(clofop)、广灭灵、氯甲酰草胺(clomeprop)、调果酸(cloprop)、cloproxydim、二氯吡啶酸、氯酯胺磺隆(cloransulam-methyl)、CMA、硫酸铜、CPMF、CPPC、醚草敏、甲酚、苄草隆、氰草净、草净津、草灭特、cyclopyrimorate、环丙嘧磺隆、草噻喃、环莠隆、氰氟草酯(cyhalofop-butyl)、苯草快(cyperquat)、环草津、三环噻草胺(cyprazole)、环酰草胺、杀草隆、茅草枯、棉隆、异丁草胺、甜菜安、敌草净、燕麦敌(di-allate)、麦草畏、敌草腈、氯双脲(dichloralurea)、苄胺灵、2,4-滴丙酸(dichlorprop)、精2,4-滴丙酸(dichlorprop-P)、禾草灵-甲基(diclofop-methyl)、双氯磺草胺、二乙除草双(diethamquat)、乙酰甲草胺(diethatyl)、戊味禾草灵(difenopenten)、枯莠隆、燕麦枯、吡氟酰草胺、氟吡草腙、恶唑隆、哌草丹、二甲草胺、异戊净、二甲酚草胺、精二甲酚草胺(dimethenamid-P)、草灭散、草哒酮(dimidazon)、敌乐胺、地乐特(dinofenate)、硝丙酚、二戊硝酚、地乐酚、特乐酚、草乃敌、杀草净、敌草快、赛松、氟硫草定、敌草隆(diuron)、DMPA、DNOC、DSMA、EBEP、甘草津、草多索(endothal)、三唑磺、EPTC、抑草蓬、戊草丹、丁氟消草、乙基水杨胺(ethbenzamide)、胺苯磺隆、磺噻隆、硫草敌、ethobenzamid、etobenzamid、乙氧呋草黄、氟乳醚、乙氧嘧磺隆、硝草酚、乙胺草醚(etnipromid)、乙氧苯草胺、EXD、酰苯磺威(fenasulam)、涕丙酸(fenoprop)、恶唑禾草灵(fenoxaprop)、精乙基恶唑禾草灵(fenoxaprop-P-ethyl)、精乙基恶唑禾草灵+双苯恶唑酸乙酯(isoxadifen-ethyl)、苯磺噁唑草(fenoxasulfone)、氯苯氧乙醇(fenteracol)、噻唑禾草灵(fenthiaprop)、四唑酰草胺、非草隆、硫酸亚铁、麦草伏(flamprop)、麦草伏-M、啶嘧磺隆、双氟磺草胺、吡氟禾草灵、精吡氟禾草灵-丁基(fluazifop-P-butyl)、异丙吡草酯、氟酮磺隆、氟吡磺隆、氟消草、氟噻草胺、吡氟草胺(flufenican)、氟哒嗪草酯、唑嘧磺草胺、flumezin、氟亚胺草酯、丙炔氟草胺、炔草胺(flumipropyn)、伏草隆、三氟硝草醚、乙羧氟草醚、唑啶草、氟除草醚、氟硫隆、氟胺草唑、flupropacil、四氟丙酸(flupropanate)、氟啶嘧磺隆、氟啶草酮、氟咯草酮、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、呋草酮、嗪草酸、氟磺胺草醚、甲酰胺磺隆、调节膦、fumiclorac、呋氧草醚、草甘膦盐和酯、氟硝磺酰胺、氟氯吡啶酸、氟氯吡啶酯、氯吡嘧磺隆-甲基、氟啶草、氟吡甲禾灵(haloxyfop-methyl)、精氟吡甲禾灵(haloxyfop-P-methyl)、六氯丙铜、六氟盐(hexaflurate)、环嗪酮、唑吡嘧磺隆、茚草酮、茚嗪氟草胺、碘草腈(iodobonil)、碘甲烷、碘甲磺隆(iodosulfuron)、乙基碘甲磺隆钠(iodosulfuron-ethyl-sodium)、iofensulfuron、碘草腈、抑草津、三唑酰草胺、丙草定(iprymidam)、草特灵(isocarbamid)、异草定、丁嗪草酮、异草完隆、isopolinate、异乐灵、异丙隆、异恶隆、异恶酰草胺、异噁氯草酮(isoxachlortole)、异噁唑草酮(isoxaflutole)、异恶草醚、隆草特、ketospiradox、乳氟禾草灵、环草定、利谷隆、MAA、MAMA、MCPA酯和胺、MCPA-硫乙基、MCPB、2甲4氯丙酸(mecoprop)、精2甲4氯丙酸(mecoprop-P)、地乐施、苯噻草胺、氟磺酰草胺、灭莠津、甲基二磺隆(mesosulfuron)、硝磺草酮、威百亩(metam)、恶唑酰草胺、苯嗪草酮、吡唑草胺、嗪吡嘧磺隆(metazosulfuron)、二甲哒草伏(metflurazon)、甲基苯噻隆(methabenzthiazuron)、methalpropalin、灭草唑(methazole)、methiobencarb、methiozolin、灭草恒(methiuron)、醚草通、格草净、甲基bromide、硫代异氰酸甲酯、甲基杀草隆、甲氧苯草隆、秀谷隆、异丙甲草胺、磺草唑胺、甲氧隆、赛克津、甲磺隆、甲磺隆-甲基、草达灭、庚酰草胺、monisouron、一氯醋酸、绿谷隆、灭草隆、伐草快、MSMA、萘丙胺、敌草胺、抑草生、草不隆、烟嘧磺隆、氟氯草胺、甲磺乐灵、除草醚、三氟甲草醚(nitrofluorfen)、达草灭、草完隆(noruron)、OCH、坪草丹、邻二氯苯、甲嘧啶磺隆、黄草消、丙炔恶草酮、恶草酮、草哒松(oxapyrazon)、环氧嘧磺隆(oxasulfuron)、恶嗪草酮、乙氧氟草醚、paraflufen-ethyl、对氟隆(parafluron)、克草猛、天竺葵酸、二甲戊乐灵、五氟磺草胺(penoxsulam)、五氯苯酚、甲氯酰草胺、戊基恶唑酮、黄草伏、烯草胺(pethoxamid)、棉胺宁、苯敌草、甜菜宁(phenmedipham-ethyl)、稀草隆、醋酸苯汞、毒莠定、氟吡酰草胺(picolinafen)、唑啉草酯、哌草磷、亚砷酸钾、叠氮化钾、氰酸钾、丙草胺、甲基氟嘧磺隆、环丙腈津(procyazine)、氨氟乐灵、氟唑草胺、环丙氟灵、环苯草酮、甘扑津、调环酸钙(prohexadione-calcium)、扑灭通、扑草净、拿草特、毒草安、敌稗、喔草酯、扑灭津、苯胺灵、异丙草胺、丙苯磺隆、丙嗪嘧磺隆、炔苯酞草胺、草硫亚胺、苄草丹、氟磺隆、扑灭生、丙炔草胺、pydanon、双唑草腈、吡氟苯草酯、磺酰草吡唑、双唑草腈(pyrazogyl)、吡唑特(pyrazolynate)、吡嘧磺隆-乙基(pyrazosulfuron-ethyl)、苄草唑、嘧啶肟草醚、稗草丹、氯草定、pyridafol、哒草特(pyridate)、环酯草醚、嘧草醚(pyriminobac-methyl)、吡丙醚(pyrimisulfan)、嘧草硫醚-钠(pyrithiobac-sodium)、罗克杀草砜(pyroxasulfone)、啶磺草胺、二氯喹啉酸、氯甲喹啉酸、灭藻醌、克藻胺(quinonamid)、喹禾灵、精喹禾灵-乙基(quizalofop-P-ethyl)、硫氰苯胺(rhodethanil)、砜嘧磺隆、精异丙甲草胺(S-metolachlor)、另丁津、仲丁通、烯禾啶、环草隆、西玛津、西玛通(simeton)、西草净、SMA、亚砷酸钠、叠氮化钠、氯酸钠、磺草酮、草克死、甲磺草胺、甲嘧磺隆(sulfometuron)、草硫膦(sulfosate)、磺酰磺隆、硫酸、sulglycapin、灭草灵(swep)、SYN-523、TCA、牧草胺(tebutam)、丁噻隆(tebuthiuron)、特糠酯酮(tefuryltrione)、环磺酮(tembotrione)、吡喃草酮(tepraloxydim)、特草定、芽根灵、特丁草胺、特丁通、特丁津、去草净、四氟隆(tetrafluron)、噻吩草胺(thenylchlor)、噻氟隆、噻草啶、噻二唑草胺、噻苯隆、甲基噻烯卡巴腙(thiencarbazone-methyl)、噻吩磺隆、thifensulfurn-methyl、禾草丹、氟嘧硫草酯、仲草丹、tioclorim、苯吡唑草酮、肟草酮(tralkoxydim)、氟酮磺草胺(triafamone)、野麦畏、醚苯磺隆、三嗪氟草胺、苯磺隆(tribenuron)、苯磺隆-甲基(tribenuron-methyl)、杀草畏(tricamba)、三氯吡氧乙酸胆碱盐(triclopyr choline salt)、三氯吡氧乙酸酯和胺、灭草环、草达津、三氟啶磺隆、氟乐灵、氟胺磺隆(triflusulfuron)、三氟苯氧丙酸(trifop)、三氟禾草肟(trifopsime)、三羟基三嗪、三甲隆(trimeturon)、tripropindan、草达克(tritac)三氟甲磺隆(tritosulfuron)、灭草猛(vernolate)、二甲苯草胺(xylachlor)及其盐、酯、光学活性异构体及混合物。
在一些实施方案中，可以将本文所述的组合物与一种或多种另外的除草剂结合施用以防治多种多样的不希望的植被。当与其他除草剂结合使用时，可以将所述组合物与其他一种或多种除草剂一起配制，与其他一种或多种除草剂进行罐混合或与其他一种或多种除草剂顺序地施用。可以与本文所述的组合物和方法结合使用的一些除草剂包括但不限于：氟锁草醚、氟锁草醚-钠、唑啶草酮、苯卡巴腙、双苯嘧草酮、治草醚、氟丙嘧草酯、唑草酮、唑酮草酯、甲氧除草醚、吲哚酮草酯、异丙吡草酯、氟哒嗪草酸、氟哒嗪草酯、氟烯草酸、氟亚胺草酯、丙炔氟草胺、乙羧氟草醚、乙羧氟草醚-乙基、嗪草酸、嗪草酸甲酯、氟磺胺草醚、氟硝磺酰胺、三唑酰草胺、乳氟禾草灵、丙炔恶草酮、恶草酮、乙氧氟草醚、戊基恶唑酮、氟唑草胺、双唑草腈、吡草醚、吡氟苯草酯、苯嘧磺草胺、甲磺草胺、噻二唑草胺、氟嘧硫草酯、三氟草嗪、[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯(CAS 353292-31-6；S-3100)、N-乙基-3-(2,6-二氯-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS452098-92-9)、N-四氢糠基-3-(2,6-二氯-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS 915396-43-9)、N-乙基-3-(2-氯-6-氟-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS 452099-05-7)、N-四氢糠基-3-(2-氯-6-氟-4-三氟甲基苯氧基)-5-甲基-1H-吡唑-1-甲酰胺(CAS 45100-03-7)和3-[7-氟-3-氧代-4-(丙-2-炔基)-3,4-二氢-2H-苯并[1,4]噁嗪-6-基]-1,5-二甲基-6-硫酮基-[1,3,5]三嗪烷-2,4-二酮；b5)，其来自漂白剂除草剂的组。
本文所述的组合物和方法可以进一步与草甘膦、5-烯醇丙酮莽草酸-3-磷酸(EPSP)合酶抑制剂、谷氨酰胺合成酶抑制剂、麦草畏、苯氧基生长素、吡啶氧基生长素、合成生长素、生长素运输抑制剂、芳氧基苯氧基丙酸酯、环己二酮、苯基吡唑啉、乙酰辅酶A羧化酶(ACC酶)抑制剂、咪唑啉酮、磺酰脲、嘧啶基硫代苯甲酸酯、三唑并嘧啶、磺酰基氨基羰基三唑啉酮、乙酰乳酸合酶(ALS)或乙酰羟酸合酶(AHAS)抑制剂、4-羟苯基丙酮酸双加氧酶(HPPD)抑制剂、八氢番茄红素去饱和酶抑制剂、类胡萝卜素生物合成抑制剂、原卟啉原氧化酶(PPO)抑制剂、纤维素生物合成抑制剂、有丝分裂抑制剂、微管抑制剂、极长链脂肪酸抑制剂、脂肪酸和脂质生物合成抑制剂、光合系统I抑制剂、光合系统II抑制剂、三嗪、和溴草腈结合用于草甘膦耐受性、EPSP合酶抑制剂耐受性、草丁膦耐受性、谷氨酰胺合成酶抑制剂耐受性、麦草畏耐受性、苯氧基生长素耐受性、吡啶氧基生长素耐受性、生长素耐受性、生长素运输抑制剂耐受性、芳氧基苯氧基丙酸酯耐受性、环己二酮耐受性、苯基吡唑啉耐受性、ACC酶耐受性、咪唑啉酮耐受性、磺酰脲耐受性、嘧啶基硫代苯甲酸酯耐受性、三唑并嘧啶耐受性、磺酰基氨基羰基三唑啉酮耐受性、ALS或AHAS耐受性、HPPD耐受性、八氢番茄红素去饱和酶抑制剂耐受性、类胡萝卜素生物合成抑制剂耐受性、PPO耐受性、纤维素生物合成抑制剂耐受性、有丝分裂抑制剂耐受性、微管抑制剂耐受性、极长链脂肪酸抑制剂耐受性、脂肪酸和脂质生物合成抑制剂耐受性、光合系统I抑制剂耐受性、光合系统II抑制剂耐受性、三嗪耐受性和溴草腈耐受性作物以及具有赋予了对多种化学和/或多种作用方式的耐受性(通过单一和/或多种抗性机制)的多种或叠加性状的作物。在一些实施方案中，将式(I)的化合物或其盐或酯和互补的除草剂或其盐或酯与除草剂组合使用，所述除草剂对所处理的作物具有选择性，并且所述除草剂补充由这些化合物以所用的施用率防治的杂草谱。在一些实施方案中，同时、作为组合配制品或作为罐混合物或作为顺序施用来施用本文所述的组合物和其他互补除草剂。
在一些实施方案中，将本文所述的组合物与一种或多种除草剂安全剂组合使用以增强其选择性，所述除草剂安全剂诸如AD-67(MON 4660)、解草酮(benoxacor)、禾草丹、芸苔素内酯、解毒喹(解草酯)(cloquintocet(mexyl))、解草胺腈、环丙磺酰胺(cyprosulfamide)、杀草隆、二氯丙烯胺(dichlormid)、dicyclonon、哌草丹、乙拌磷、解草唑-乙基(fenchlorazole-ethyl)、解草啶(fenclorim)、解草安(flurazole)、肟草安(fluxofenim)、解草噁唑(furilazole)、harpin蛋白、双苯恶唑酸乙酯、解草烷(jiecaowan)、解草烯(jiecaoxi)、吡唑解草酯(mefenpyr-diethyl)、甲酚盐(mephenate)、萘二甲酸酐(NA)、解草腈(oxabetrinil)、R29148和N-苯基-磺酰基苯甲酸酰胺。在一些实施方案中，安全剂用于稻、谷物、玉米或玉蜀黍环境。在一些实施方案中，安全剂是解毒喹酸或其酯或盐。在某些实施方案中，解毒喹用于拮抗组合物对稻和谷物的有害作用。在一些实施方案中，安全剂是解草酯。
在一些实施方案中，将本文所述的组合物与一种或多种植物生长调节剂组合使用，所述植物生长调节剂诸如2,3,5-三-碘苯甲酸、IAA、IBA、萘乙酰胺、α-萘乙酸、苄基腺嘌呤、4-羟基苯乙醇、激动素、玉米素、草多索、乙烯利、五氯苯酚、噻苯隆、脱叶磷(tribufos)、艾维激素(aviglycine)、乙烯利、马来酰肼、赤霉素、赤霉酸、脱落酸、嘧啶醇、调节膦、草甘二膦、异嘧醇(isopyrimol)、茉莉酸、马来酰肼、甲哌鎓(mepiquat)、2,3,5-三-碘苯甲酸、整形素、二氯芴素(dichlorflurenol)、呋嘧醇、氟磺酰草胺、多效唑、四环唑(tetcyclacis)、烯效唑(uniconazole)、芸苔素内酯、芸苔素内酯-乙基、环己酰亚胺、乙烯、磺菌威、调环酸、抑芽唑(triapenthenol)和抗倒酯(trinexapac)。
在一些实施方案中，植物生长调节剂用于一种或多种作物或环境，诸如稻、谷物作物、玉米、玉蜀黍、阔叶作物、油菜/卡诺拉油菜、草皮、菠萝、甘蔗、向日葵、草地、草原、牧场、休耕地、树和藤蔓果园、种植作物、蔬菜、和非作物(观赏植物)环境。在一些实施方案中，将植物生长调节剂与式(I)的化合物混合，或与式(I)的化合物和咪唑啉酮混合，以引起对植物的优先有利的作用。
在一些实施方案中，本文提供的组合物进一步包含至少一种农业上可接受的佐剂或载体。合适的佐剂或载体不应对有价值的作物具有植物毒性，特别是在将组合物用于在存在作物的情况下的选择性杂草防治时所采用的浓度下，并且不应与除草组分或其他组合物成分化学反应。此类混合物可以设计用于直接施用于杂草或其场所，或者可以是在施用前通常用另外的载体和佐剂稀释的浓缩物或配制品。它们可以是固体，诸如例如尘剂、颗粒剂、水可分散性颗粒剂、或可湿性粉剂；或液体，诸如例如可乳化性浓缩物、溶液、乳液或悬浮液。它们也可以作为预混物提供或进行罐混合。
合适的农业佐剂和载体包括但不限于作物油浓缩物；壬基酚乙氧基化物；苄基椰油烷基二甲基季铵盐；石油烃、烷基酯、有机酸和阴离子表面活性剂的共混物；C9-C11烷基多糖苷；磷酸化醇乙氧基化物；天然伯醇(C12-C16)乙氧基化物；二仲丁基苯酚EO-PO嵌段共聚物；聚硅氧烷-甲基帽；壬基酚乙氧基化物+尿素硝酸铵；乳化甲基化种子油；十三醇(合成)乙氧基化物(8EO)；牛脂胺乙氧基化物(15EO)；PEG(400)二油酸酯-99。
可以使用的液体载体包括水和有机溶剂。有机溶剂包括但不限于石油馏分或烃，诸如矿物油、芳族溶剂、石蜡油等；植物油，诸如大豆油、菜籽油、橄榄油、蓖麻油、葵花籽油、椰子油、玉米油、棉籽油、亚麻籽油、棕榈油、花生油、红花油、芝麻油、桐油等；以上植物油的酯；一元醇或二元、三元或其他低级多元醇(含4-6个羟基)的酯，诸如硬脂酸2-乙基己酯、油酸正丁酯、肉豆蔻酸异丙酯、二油酸丙二醇酯、琥珀酸二辛酯、己二酸二丁酯、邻苯二甲酸二辛酯等；一元、二元和多元羧酸的酯等。具体的有机溶剂包括但不限于甲苯、二甲苯、石脑油、作物油、丙酮、甲乙酮、环己酮、三氯乙烯、全氯乙烯、乙酸乙酯、乙酸戊酯、乙酸丁酯、丙二醇单甲醚和二乙二醇单甲醚、甲醇、乙醇、异丙醇、戊醇、乙二醇、丙二醇、甘油、N-甲基-2-吡咯烷酮、N,N-二甲基烷基酰胺、二甲基亚砜、液体肥料等。在某些实施方案中，水是用于稀释浓缩物的载体。
合适的固体载体包括但不限于滑石、叶腊石粘土、硅石、凹凸棒石粘土、高岭土、砂藻土(kieselguhr)、白垩、硅藻土(diatomaxeous earth)、石灰、碳酸钙、膨润土、漂白土、棉子壳、小麦粉、大豆粉、浮石、木粉、核桃壳粉、木质素、纤维素等。
在一些实施方案中，本文所述的组合物进一步包含一种或多种表面活性剂。在一些实施方案中，此类表面活性剂用于固体和液体组合物以及在某些实施方案中被设计为在施用前有待用载体稀释的那些。表面活性剂在性质上可以是阴离子型、阳离子型或非离子型，并且可以用作乳化剂、润湿剂、悬浮剂或用于其他目的。也可以用于本发明配制品的表面活性剂尤其描述于“McCutcheon’s Detergents and Emulsifiers Annual,”MCPublishing Corp.,里奇伍德,新泽西州,1998和“Encyclopedia of Surfactants,”第I-III卷,Chemical Publishing Co.,纽约,1980-81中。表面活性剂包括但不限于烷基硫酸盐，诸如月桂基硫酸二乙醇铵；烷基芳基磺酸盐，诸如十二烷基苯磺酸钙；烷基苯酚-氧化烯加成产物，诸如乙氧基化壬基苯酚-C18；醇-氧化烯加成产物，诸如乙氧基化十三烷醇-C16；皂，诸如硬脂酸钠；烷基萘磺酸盐，诸如二丁基萘磺酸钠；磺基琥珀酸盐的二烷基酯，诸如二(2-乙基己基)磺基琥珀酸钠；山梨醇酯，诸如油酸山梨醇酯；季胺，诸如月桂基三甲基氯化铵；脂肪酸的聚乙二醇酯，诸如聚硬脂酸乙二醇酯；环氧乙烷和环氧丙烷的嵌段共聚物；单和二烷基磷酸酯的盐；植物油或种子油，诸如大豆油、菜籽油/卡诺拉菜籽油、橄榄油、蓖麻油、葵花籽油、椰子油、玉米油、棉籽油、亚麻籽油、棕榈油、花生油、红花油、芝麻油、桐油等；以及以上植物油的酯，并且在某些实施方案中是甲酯。
在一些实施方案中，这些材料，诸如植物油或种子油及其酯，可以互换用作农业佐剂、液体载体或表面活性剂。
用于本文提供的组合物的其他示例性添加剂包括但不限于相容剂、消泡剂、螯合剂、中和剂和缓冲剂、腐蚀抑制剂、染料、气味剂、铺展剂、渗透助剂、粘着剂、分散剂、增稠剂、凝固点抑制剂、抗微生物剂等。所述组合物还可以含有其他相容的组分，例如其他除草剂、植物生长调节剂、杀真菌剂、杀昆虫剂等，并且可以与液体肥料或固体颗粒肥料载体(诸如硝酸铵、尿素等)一起配制。
在一些实施方案中，本文所述组合物中的活性成分的浓度是从约0.0005至98重量百分比。在一些实施方案中，所述浓度是从约0.0006至90重量百分比。在设计用作浓缩物的组合物中，在某些实施方案中，活性成分以从约0.1至98重量百分比并且在某些实施方案中约0.5至90重量百分比的浓度存在。在某些实施方案中，此类组合物在施用前用惰性载体(诸如水)稀释。在某些实施方案中，通常施用于杂草或杂草场所的经稀释的组合物含有约0.0006至3.0重量百分比的活性成分并且在某些实施方案中含有约0.01至1.0重量百分比。
可以通过使用常规的地面或空中喷粉器、喷雾器和颗粒施用器，通过添加到灌溉水或稻田水中，以及通过本领域技术人员已知的其他常规手段将本发明的组合物施用于杂草或杂草场所。
所描述的实施方案和以下实施例用于说明目的并且不旨在限制权利要求的范围。在不脱离所要求保护的主题的精神和范围的情况下，关于本文所述的组合物的其他修改、使用或组合对于本领域普通技术人员将是显而易见的。
实施例
实施例中的结果是温室试验结果。
将所希望的测试植物物种的种子或果仁种植在通过将壤土或砂壤土(例如，28.6百分比的淤泥、18.8百分比的粘土和52.6百分比的沙子，其pH为约5.8并且有机物含量为约1.8百分比)和钙质砂砾以80至20的比率混合而制备的土壤基质中。将土壤基质容纳在体积为1夸脱并且表面积为83.6cm2的塑料盆中。当需要确保良好的发芽和健康的植物时，施用杀真菌剂处理和/或其他化学或物理处理。使植物在温室中生长8-22天，其中光周期大约14h，将其白天保持在约29℃并且夜间保持在26℃。根据需要在灌溉溶液中添加营养物(Peters 
15-5-15 5-Ca 2-Mg和铁螯合物)并且定期添加水。必要时用顶置式金属卤化物1000瓦灯提供补充照明。当植物达到第一至第四真叶期时，将它们用于测试。
处理由以下构成：氟氯吡啶酯(4-氨基-3-氯-6-(4-氯-2-氟-3-甲氧基苯基)吡啶甲酸甲酯)的酸或酯，每种配制成SC(悬浮浓缩物)，以及单独和组合的各种除草组分。在酸当量基础上施用式I的化合物的一种形式。
所测试的式I的化合物的形式包括：
基于所测试的比率、配制品中活性成分或酸等价物的浓度以及以187L/ha比率的12mL施用量计算处理要求。
对于由配制化合物构成的处理，将测量量的化合物单独放置在25mL玻璃小瓶中，并且稀释在一定体积的浓缩的1.25％(v/v)
作物油中以获得12X储备溶液。如果测试化合物不容易溶解，则将混合物加热和/或超声处理。通过添加适量的每种储备溶液(例如，1mL)制备施用溶液，并且通过添加10mL 1.25％(v/v)作物油浓缩物的水性混合物稀释至适当的最终浓度，使得最终喷雾溶液含有1.25+/-0.05％(v/v)作物油浓缩物。
对于由技术化合物构成的处理，可以将称重的量单独地放置在25mL玻璃小瓶中，并且溶解在一定体积的97:3v/v丙酮/DMSO中以获得12X储备溶液。如果测试化合物不容易溶解，则可以将混合物加热和/或超声处理。可以通过添加适量的每种储备溶液(例如，1mL)制备施用溶液，并且通过添加10mL 1.5％(v/v)作物油浓缩物的水性混合物稀释至适当的最终浓度，使得最终喷雾溶液含有1.25％(v/v)作物油浓缩物。当使用技术材料时，可以将浓缩的储备溶液添加到喷雾溶液中，使得施用溶液的最终丙酮和DMSO浓度分别为16.2％和0.5％。
对于由配制化合物和技术化合物构成的处理，将称重量的技术材料单独放置在25mL玻璃小瓶中并且溶解在一定体积的97:3v/v丙酮/DMSO中以获得12X储备溶液，并且将测量量的配制化合物单独放置在25mL玻璃小瓶中并且稀释在一定体积的1.5％(v/v)作物油浓缩物或水中以获得12X储备溶液。如果测试化合物不容易溶解，则将混合物加热和/或超声处理。通过添加适量的每种储备溶液(例如，1mL)制备施用溶液，并且通过添加适量的1.5％(v/v)作物油浓缩物的水性混合物稀释至适当的最终浓度，使得最终喷雾溶液含有1.25％(v/v)作物油浓缩物。根据需要，将另外的水和/或97:3v/v丙酮/DMSO添加到单独的施用溶液中，使得所比较的施用溶液的最终丙酮和DMSO浓度分别为8.1％和0.25％。
在施用之前，目视检查所有储备溶液和施用溶液的化合物相容性。用配备有校准为递送187L/ha的8002E喷嘴的顶置Mandel履带式喷雾器在0.503m2的施用面积内以高于平均植物冠层高度18至20英寸(46至50cm)的喷雾高度将喷雾溶液施用于植物材料。将对照植物以相同的方式喷雾溶剂空白。
将经处理的植物和对照植物放置在如上所述的温室中，并且通过地下灌溉进行浇水以防止测试化合物被冲洗掉。大约7、14、21天后，目视确定与未经处理的植物的状况相比测试植物的状况，并且按0至100百分比的量度评分，其中0对应于没有损伤或生长抑制，并且100对应于完全杀死。
测试的化合物、使用的施用率、测试的植物物种、和结果在表1-4中给出。
尽管已经在附图和前述描述中详细说明和描述了所述新颖的技术，但其在特征方面应被认为是说明性的而不是限制性的，应当理解，仅示出和描述了优选的实施方案，并且希望保护符合所述新颖技术的精神的所有改变和修改。同样，虽然使用特定实施例、理论论证、解释和说明来说明所述新颖技术，但这些说明和随附的讨论绝不应被解释为限制所述技术。将本申请中参考的所有专利、专利申请以及对文本、科学论文、出版物等的参考在它们与本说明书的明确教导不矛盾的程度上通过引用以其整体并入本文。
Claims (9)
1.一种除草组合物，其包含除草有效量的
(a)氟氯吡啶酯；
(b)第二除草剂，所述第二除草剂包含草铵膦；和
(c)第三除草剂，所述第三除草剂包含氯氟吡氧乙酸异辛酯；
其中(a)、(b)与(c)之间的重量比是从1:400:70至1:12:2。
2.根据权利要求1所述的组合物，其进一步包含农业上可接受的佐剂或载体。
3.根据权利要求1所述的组合物，其进一步包含至少一种除草剂安全剂。
4.一种防治不希望的植被的方法，其包括以下步骤：使植物，其中所述植物是不希望的植被或其场所；土壤或水，其中所述土壤或所述水允许所述不希望的植被的生长，与除草有效量的组合接触，所述组合包含
(a)氟氯吡啶酯；
(b)第二除草剂，所述第二除草剂包含草铵膦；和
(c)第三除草剂，所述第三除草剂包含氯氟吡氧乙酸异辛酯；
其中(a)、(b)与(c)之间的重量比是从1:400:70至1:12:2。
5.根据权利要求4所述的方法，其中在直播、水播和移栽稻；谷物；小麦；大麦；燕麦；黑麦；高粱；玉米/玉蜀黍；甘蔗；向日葵；油菜；卡诺拉油菜；甜菜；大豆；棉花；菠萝；草地；草原；牧场；休耕地；草皮；树和藤蔓果园；水生物；工业植被管理或路域中防治所述不希望的植被。
6.根据权利要求4所述的方法，其中将所述(a)、(b)和(c)在芽前施用于所述不希望的植被或其场所。
7.根据权利要求4所述的方法，其中在以下耐受性作物中防治所述不希望的植被：草甘膦耐受性作物、5-烯醇丙酮莽草酸-3-磷酸合酶抑制剂耐受性作物、草丁膦耐受性作物、谷氨酰胺合成酶抑制剂耐受性作物、麦草畏耐受性作物、苯氧基生长素耐受性作物、吡啶氧基生长素耐受性作物、合成生长素耐受性作物、生长素运输抑制剂耐受性作物、芳氧基苯氧基丙酸酯耐受性作物、环己二酮耐受性作物、苯基吡唑啉耐受性作物、乙酰辅酶A羧化酶抑制剂耐受性作物、咪唑啉酮耐受性作物、磺酰脲耐受性作物、嘧啶基硫代苯甲酸酯耐受性作物、三唑并嘧啶耐受性作物、磺酰基氨基羰基三唑啉酮耐受性作物、乙酰乳酸合酶或乙酰羟酸合酶抑制剂耐受性作物、4-羟苯基丙酮酸双加氧酶抑制剂耐受性作物、八氢番茄红素去饱和酶抑制剂耐受性作物、类胡萝卜素生物合成抑制剂耐受性作物、原卟啉原氧化酶抑制剂耐受性作物、纤维素生物合成抑制剂耐受性作物、有丝分裂抑制剂耐受性作物、微管抑制剂耐受性作物、极长链脂肪酸抑制剂耐受性作物、脂肪酸和脂质生物合成抑制剂耐受性作物、光合系统I抑制剂耐受性作物、光合系统II抑制剂耐受性作物、三嗪耐受性作物、或溴草腈耐受性作物。
8.根据权利要求7所述的方法，其中所述耐受性作物具有赋予了对多种除草剂或多种作用方式的耐受性的多种或叠加性状。
9.根据权利要求4所述的方法，其中所述不希望的植被包括除草剂抗性或耐受性杂草。
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| PCT/US2019/059008 WO2020092674A1 (en) | 2018-11-02 | 2019-10-31 | Compositions comprising halauxifen and other herbicides and methods thereof |
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| KR100898662B1 (ko) * | 2006-01-13 | 2009-05-22 | 다우 아그로사이언시즈 엘엘씨 | 6-(다-치환 아릴)-4-아미노피콜리네이트 및 그의제초제로서의 용도 |
| EP2571366A1 (de) * | 2010-05-21 | 2013-03-27 | Bayer Intellectual Property GmbH | Herbizide mittel für tolerante oder resistente maiskulturen |
| US20110287933A1 (en) * | 2010-05-21 | 2011-11-24 | Bayer Cropscience Ag | Herbicidal composition for tolerant or resistant oilseed rape crops |
| BR112012029634A2 (pt) * | 2010-05-21 | 2015-10-20 | Bayer Ip Gmbh | agentes herbicidas para as culturas de arroz tolerantes ou resistentes |
| CN103004861B (zh) * | 2011-09-26 | 2014-05-28 | 深圳诺普信农化股份有限公司 | 一种除草组合物 |
| DK2787829T3 (en) * | 2011-12-06 | 2016-12-05 | Dow Agrosciences Llc | Herbicidal composition containing 4-amino-3-chloro-6- (4-CHLORO-2-FLUORO-3-methoxy-phenyl) pyridine-2-carboxylic acid or a derivative thereof and Fluroxypyr OR DERIVATIVES |
| CN103371175A (zh) * | 2012-04-25 | 2013-10-30 | 陕西韦尔奇作物保护有限公司 | 一种含草铵膦的除草组合物 |
| CN103053609B (zh) * | 2012-12-29 | 2014-12-31 | 广东中迅农科股份有限公司 | 草铵膦和吡啶羧酸类除草剂的除草组合物 |
| KR102422133B1 (ko) * | 2013-10-11 | 2022-07-18 | 코르테바 애그리사이언스 엘엘씨 | 수성 제초 농축물 |
| RU2662284C2 (ru) * | 2014-01-15 | 2018-07-25 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Гербицидная композиция, содержащая 4-амино-3-хлор-6-(4-хлор-2-фтор-3-метоксифенил)пиридин-2-карбоновую кислоту, флуроксипир и феноксиауксины |
| WO2017044556A1 (en) * | 2015-09-08 | 2017-03-16 | Dow Agrosciences Llc | Herbicidal compositions containing 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof, a triazolopyrimidine sulfonamide herbicide or a derivative thereof, and glyphosate or a derivative thereof |
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| MX2021005127A (es) | 2021-06-15 |
| EA202191226A1 (ru) | 2021-08-12 |
| EP3873212A1 (en) | 2021-09-08 |
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| UY38441A (es) | 2020-05-29 |
| CN113271777A (zh) | 2021-08-17 |
| WO2020092674A1 (en) | 2020-05-07 |
| AU2019374059A1 (en) | 2021-06-03 |
| CL2021001105A1 (es) | 2021-10-01 |
| BR112021008290A2 (pt) | 2021-08-03 |
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