CN113057901B - Oil tea seed oil skin care composition containing hydrolyzed vegetable protein and preparation method and application thereof - Google Patents
Oil tea seed oil skin care composition containing hydrolyzed vegetable protein and preparation method and application thereof Download PDFInfo
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Abstract
本发明公开了一种含水解植物蛋白的油茶籽油护肤组合物及其制备方法与应用,属于护肤品技术领域。本发明所述油茶籽油护肤组合物以适当含量的精制油茶籽油代替传统制取的油茶籽油作为功效成分,其异味性大大降低,对肌肤相容性好;油茶籽油中富含的甾醇、生育酚、角鲨烯等抗氧化营养物质,可有效修复人体皮肤出现的褶皱、干裂等症状;通过在产品组分中添加特定含量的水解豌豆蛋白与其他组分相搭配,可有效缓解天然植物产品在应用过程中出现的起白现象,使得到的护肤组合物具有轻盈、不粘腻和润滑的质感。本发明还公开了所述产品的制备方法,该方法操作步骤简单,可实现工业化大规模生产。本发明还公开了所述产品在制备护肤品中的应用。The invention discloses a camellia oleifera oil skin care composition containing hydrolyzed plant protein and its preparation method and application, and belongs to the technical field of skin care products. The Camellia oleifera seed oil skin care composition of the present invention uses an appropriate content of refined Camellia oleifera seed oil as the functional ingredient instead of the traditionally prepared Camellia oleifera seed oil. Its odor is greatly reduced and has good compatibility with the skin; the Camellia oleifera seed oil is rich in Antioxidant nutrients such as sterols, tocopherols, and squalene can effectively repair wrinkles, dryness and other symptoms of human skin. By adding a specific content of hydrolyzed pea protein to the product components and matching it with other components, it can effectively alleviate the symptoms. The whitening phenomenon that occurs during the application process of natural plant products makes the resulting skin care composition have a light, non-sticky and smooth texture. The invention also discloses a preparation method of the product, which has simple operation steps and can realize industrial large-scale production. The invention also discloses the application of the product in preparing skin care products.
Description
技术领域Technical field
本发明涉及护肤品技术领域,具体涉及一种含水解植物蛋白的油茶籽油护肤组合物及其制备方法与应用。The present invention relates to the technical field of skin care products, and specifically relates to a camellia oleifera seed oil skin care composition containing hydrolyzed plant protein and its preparation method and application.
背景技术Background technique
皮肤是人的身体器官中最大的器官,具有保护、排泄、调节体温和感受外界刺激等作用。皮肤常常受到氧化、干燥、紫外线等种种因素的刺激,容易受到损伤,此时如果不注意保养,皮肤状态迟早会变差的,干燥缺水、斑点、细纹等都是最常见的问题。又比如现代的生活节奏繁忙且充满动感长期劳累奔波,需要随时随地保持旺盛的精力,汗水与油腻厚厚的覆盖在皮肤表层,加重表面肌肤的负担,毛孔完全堵死,为了排出更多的油脂,毛孔会渐渐粗大、明显,肌肤渐粗糙,越发显得肌肤不平滑、肤质不均。The skin is the largest organ in the human body and has the functions of protection, excretion, regulating body temperature and sensing external stimuli. The skin is often stimulated by various factors such as oxidation, dryness, and ultraviolet rays, and is easily damaged. If you do not pay attention to maintenance at this time, the skin condition will deteriorate sooner or later. Dryness, dehydration, spots, fine lines, etc. are the most common problems. Another example is the busy and dynamic pace of modern life, long-term fatigue and running around, and the need to maintain strong energy anytime and anywhere. Sweat and oil thickly cover the surface of the skin, increasing the burden on the surface skin, and the pores are completely blocked, in order to discharge more oil. , the pores will gradually become enlarged and obvious, the skin will become rough, and the skin will become increasingly uneven and uneven.
为了保护皮肤免受损害和焕发光彩,必须重视皮肤的日常护理。要真正做到护肤,需让肌肤软化,使角质层可以吸收更多水份,渗透和吸收能力都会加强让营养物质与表皮细胞零距离地接触,深层吸收,从而达到活化肌肤,使皮肤光洁健康充满活力。In order to protect your skin from damage and keep it glowing, you must pay attention to daily skin care. To truly achieve skin care, the skin needs to be softened so that the stratum corneum can absorb more water. The penetration and absorption capabilities will be enhanced, allowing nutrients to come into close contact with epidermal cells and be absorbed deeply, thereby activating the skin and making the skin smooth and healthy. Energetic.
现有护肤产品会添加很多人工合成添加剂或助剂,虽然能保障产品具有一些特定性质(方便保存、气味独特、外观时尚),但是却往往忽略了产品本身所注重的护肤效果,甚至部分产品长时间使用会对皮肤产生一定的消极效果;基于这些原因,人们开始使用一些天然植物成分来代替这些化学合成物质。但是,并非天然植物添加的种类和含量越多越好,人们发现,一些富含天然成分的化妆品在使用后皮肤容易出现起白现象,天然成分也与合成物质一样,不能盲目添加。Existing skin care products add a lot of artificial additives or auxiliaries. Although they can ensure that the product has certain properties (easy to store, unique smell, fashionable appearance), the skin care effect of the product itself is often ignored, and some products even have long-lasting effects. Long-term use will have certain negative effects on the skin; for these reasons, people have begun to use some natural plant ingredients to replace these chemically synthesized substances. However, it is not that the more types and contents of natural plants added, the better. People have found that some cosmetics rich in natural ingredients are prone to whitening of the skin after use. Natural ingredients, like synthetic substances, cannot be added blindly.
油茶籽油作为一种常见的植物提取物,其含有的脂肪酸组成和甘油酯构型有益于人体健康,且该物质中含有多种可溶性维生素,若该类活性物质被运用于护肤品中,不仅可使其制备的产品更加贴合人体皮肤,同时可赋予该产品滋润、修护皮肤的特性,提升产品的质感。CN107550805A公开了一种蚕丝水解蛋白液,该面膜液产品中以水溶性油茶籽油搭配红茶菌发酵液、蚕丝水解蛋白等天然提取物,充分保留发挥油茶籽油的抗衰老,抗氧化效果;CN105902436A公开了一种应用油茶籽粕提取液的祛痘修复面膜,该技术方案中通过油茶籽油与油茶籽粕提取液相搭配制备具有强效杀菌消炎活性的营养面膜。Camellia oleifera seed oil is a common plant extract. Its fatty acid composition and glyceride configuration are beneficial to human health, and it contains a variety of soluble vitamins. If this type of active substance is used in skin care products, it will not only It can make the products prepared by it more suitable for human skin, and at the same time, it can give the product the characteristics of moisturizing and repairing the skin, and improve the texture of the product. CN107550805A discloses a silk hydrolyzed protein liquid. In this facial mask liquid product, water-soluble camellia seed oil is combined with natural extracts such as kombucha fermentation liquid and silk hydrolyzed protein to fully retain and exert the anti-aging and antioxidant effects of camellia seed oil; CN105902436A An anti-acne and repair facial mask using Camellia oleifera seed meal extract is disclosed. In this technical solution, a nutritional facial mask with powerful bactericidal and anti-inflammatory activity is prepared by combining Camellia oleifera seed oil and Camellia oleifera seed meal extract.
然而,现有产品往往忽略了油茶籽油本身的缺陷。油茶籽油存在着其固有的难闻气味,但是现有产品往往只是将其当做普通的功效剂或油性基质使用,没有考虑其含量搭配或进行特殊处理;而现有传统方法制备的油茶籽油由于杂质较多,性质不稳定容易氧化,所以在储存或制备成产品后会进一步产生一些酸臭味。因此,即使利用油茶籽油制备了高护肤效果的纯天然护肤品,这类产品也因其不和谐的气味难以得到消费者的青睐;而若通过对护肤品的后续加工或添加除臭助剂等去除产品的异味,又会导致产品的生产成本提高,经济效益变低。However, existing products often ignore the shortcomings of camellia seed oil itself. Camellia oleifera seed oil has its inherent unpleasant odor, but existing products often use it as an ordinary functional agent or oil base without considering its content or special treatment; while the existing oleifera seed oil prepared by traditional methods Due to the large number of impurities and unstable properties, it is easily oxidized, so it will further produce some sour smell after storage or preparation into products. Therefore, even if Camellia oleifera seed oil is used to prepare pure natural skin care products with high skin care effects, such products are difficult to gain favor from consumers due to their disharmonious smell; and if the skin care products are subsequently processed or deodorizing aids are added Removing the odor of the product will increase the production cost of the product and reduce the economic benefits.
发明内容Contents of the invention
基于现有技术的不足,本发明的目的在于提供一种含水解植物蛋白的油茶籽油护肤组合物,该产品富含天然植物成分且没有传统油茶籽油产品特有的浓重气味,具有优异的肌肤保湿、修护和美白功效,使用后不会出现起白现象。Based on the shortcomings of the existing technology, the object of the present invention is to provide a camellia seed oil skin care composition containing hydrolyzed plant protein. This product is rich in natural plant ingredients and does not have the strong smell unique to traditional camellia seed oil products, and has excellent skin care properties. It has moisturizing, repairing and whitening effects, and there will be no whitening after use.
为了达到上述目的,本发明采取的技术方案为:In order to achieve the above objects, the technical solutions adopted by the present invention are:
一种含水解植物蛋白的油茶籽油护肤组合物,包括以下组分:植物提取物、保湿剂及余量水;所述植物提取物中包括占所述油茶籽油护肤组合物质量0.3~0.7%的水解豌豆蛋白和0.3~0.7%的精制油茶(CAMELLIA OLEIFERA)籽油。A Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein, including the following components: plant extract, moisturizer and remaining water; the plant extract includes 0.3~0.7% of the mass of the Camellia oleifera seed oil skin care composition % hydrolyzed pea protein and 0.3~0.7% refined camellia oleifera (CAMELLIA OLEIFERA) seed oil.
本发明所述含水解植物蛋白的油茶籽油护肤组合物的组分中,以适当含量的精制油茶籽油代替传统制取的油茶籽油作为功效成分,其异味性大大降低,对肌肤相容性好;油茶籽油中富含的甾醇、生育酚、角鲨烯等抗氧化营养物质,可有效修复人体皮肤出现的褶皱、干裂等症状;通过在产品组分中添加特定含量的水解豌豆蛋白与其他组分相搭配,可有效缓解天然植物产品在应用过程中出现的起白现象,使得到的护肤组合物具有轻盈、不粘腻和润滑的质感。Among the components of the Camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein according to the present invention, an appropriate content of refined Camellia oleifera seed oil is used as the functional ingredient instead of the traditionally prepared Camellia oleifera seed oil. Its odor is greatly reduced and it is compatible with the skin. Good sex; Camellia oleifera seed oil is rich in antioxidant nutrients such as sterols, tocopherol, squalene, etc., which can effectively repair wrinkles, dryness and other symptoms of human skin; by adding a specific content of hydrolyzed pea protein to the product components When combined with other components, it can effectively alleviate the whitening phenomenon that occurs during the application process of natural plant products, making the resulting skin care composition have a light, non-sticky and smooth texture.
优选地,所述精制油茶籽油经过低温精制得到,所述低温精制包括脱胶、脱酸、脱色、除臭和脱蜡步骤,所述除臭步骤的温度不高于150℃。Preferably, the refined Camellia oleifera seed oil is obtained through low-temperature refining, which includes degumming, deacidification, decolorization, deodorization and dewaxing steps, and the temperature of the deodorization step is not higher than 150°C.
更优选地,所述精制油茶籽油的酸价<0.5mg.KOH/g,过氧化值<1.5mmol/kg,所述精制油茶籽油中水分和挥发性物质的质量百分含量<0.15%。More preferably, the acid value of the refined camellia seed oil is <0.5mg.KOH/g, the peroxide value is <1.5mmol/kg, and the mass percentage of moisture and volatile substances in the refined camellia seed oil is <0.15%. .
发明人经过多次测试发现,传统油茶籽油制备方法往往使用高温方法进行提炼处理,此类方法得到的产品不仅杂质多,气味浓重,同时会造成甾醇等营养成分流失甚至失活,极不利于油茶籽油在后续护肤品中的使用。本发明所述精制油茶籽油以低温多步法进行提炼,同时严格限定制备的油茶籽油的理化指标及控制气味及不稳定性来源(游离脂肪酸等)的含量,不仅可使浓重气味消除,还能进一步提升其在制备的油茶籽油护肤组合物中的抗氧化润肤能力。After many tests, the inventor found that traditional camellia seed oil preparation methods often use high-temperature methods for refining. The products obtained by such methods not only have many impurities and have a strong smell, but also cause the loss or even inactivation of nutrients such as sterols, which is extremely unfavorable. The use of Camellia oleifera seed oil in subsequent skin care products. The refined Camellia oleifera seed oil of the present invention is refined by a low-temperature multi-step method, while strictly limiting the physical and chemical indicators of the prepared Camellia oleifera seed oil and controlling the content of odor and sources of instability (free fatty acids, etc.), which can not only eliminate the strong odor, It can also further enhance its antioxidant and emollient ability in the prepared Camellia oleifera seed oil skin care composition.
更优选地,所述精制油茶籽油可选用广东宝华农业科技股份有限公司生产的有机油茶籽油。More preferably, the refined Camellia oleifera seed oil can be organic Camellia oleifera seed oil produced by Guangdong Baohua Agricultural Science and Technology Co., Ltd.
所述产品纯度高,气味小,稳定性高,可有效用于本发明所述油茶籽油护肤组合物中。The product has high purity, low odor and high stability, and can be effectively used in the Camellia oleifera seed oil skin care composition of the present invention.
优选地,所述植物提取物中包括占所述油茶籽油护肤组合物质量0.4~0.6%的水解豌豆蛋白和0.4~0.6%的精制油茶籽油;Preferably, the plant extract includes 0.4~0.6% of hydrolyzed pea protein and 0.4~0.6% of refined camellia oleifera seed oil, accounting for 0.4~0.6% of the mass of the Camellia oleifera seed oil skin care composition;
更优选地,所述植物提取物中包括占所述油茶籽油护肤组合物质量0.5%的水解豌豆蛋白和0.5%的精制油茶籽油。More preferably, the plant extract includes 0.5% hydrolyzed pea protein and 0.5% refined camellia seed oil accounting for the mass of the Camellia oleifera seed oil skin care composition.
所述配比下的护肤组合物不仅具有更加协调的气味,同时其保湿护肤效果更加,与皮肤相容性更好。The skin care composition in the above ratio not only has a more harmonious smell, but also has better moisturizing and skin care effects and better compatibility with the skin.
优选地,所述植物提取物还包括母菊(CHAMOMILLA RECUTITA)花提取物和卡瓦胡椒(PIPER METHYSTICUM)叶/根/茎提取物。Preferably, the plant extract further includes CHAMOMILLA RECUTITA flower extract and PIPER METHYSTICUM leaf/root/stem extract.
所述植物提取物中,母菊花提取物具有丰富的挥发油、黄酮类化合物、氨基酸、绿原酸和微量元素等,当用于化妆护肤品时具有显著的抗菌、抗氧化和舒缓抗敏的生物活性,适用于各类皮肤性质人群;卡瓦胡椒叶/根/茎提取物一般用于皮肤调理剂,因其含有醉椒素、二氢醉椒素、醉椒苦素、二氢醉椒苦素、甲氧基醉椒素和去甲氧基醉椒素等重要活性成分,相比于其他植物提取物具有更好的药理抗菌消炎及皮肤调理功效。通过上述两种组分与水解豌豆蛋白和精制油茶籽油相搭配,其得到的护肤组合物具有更好的皮肤护理效果,其适用性更大。Among the plant extracts, chamomilla flower extract is rich in volatile oils, flavonoids, amino acids, chlorogenic acid and trace elements. When used in cosmetics and skin care products, it has significant antibacterial, antioxidant and soothing anti-allergic properties. Active, suitable for people with various skin types; Kava pepper leaf/root/stem extract is generally used as a skin conditioner because it contains capsaicin, dihydrocapsaicin, capsicum, and dihydrocapsicum. It contains important active ingredients such as cinnamon, methoxycapsaicin and demethoxycapsaicin. Compared with other plant extracts, it has better pharmacological antibacterial, anti-inflammatory and skin conditioning effects. By combining the above two components with hydrolyzed pea protein and refined tea seed oil, the skin care composition obtained has better skin care effect and greater applicability.
更优选地,所述植物提取物还包括占所述油茶籽油护肤组合物质量2~4%的母菊花提取物和0.4~0.6%的卡瓦胡椒叶/根/茎提取物。More preferably, the plant extract also includes chamomile flower extract accounting for 2~4% of the mass of the Camellia oleifera seed oil skin care composition and 0.4~0.6% Kava pepper leaf/root/stem extract.
所述添加量下制备得到的油茶籽油护肤组合物具有更加显著的舒缓肌肤及修复保湿的效果。The Camellia oleifera seed oil skin care composition prepared at the above added amount has more significant effects of soothing the skin and repairing and moisturizing the skin.
优选地,所述保湿剂包括精氨酸、丁二醇、泛醇、聚乙二醇-32、聚乙二醇-8和1,2-己二醇。Preferably, the humectants include arginine, butylene glycol, panthenol, polyethylene glycol-32, polyethylene glycol-8 and 1,2-hexanediol.
更优选地,所述保湿剂包括占所述油茶籽油护肤组合物质量0.1~0.3%的精氨酸、2~4%的丁二醇、1~3%的泛醇、1~3%的聚乙二醇-32、0.5~1.5%的聚乙二醇-8和0.4~0.6%的1,2-己二醇。More preferably, the moisturizing agent includes 0.1~0.3% of arginine, 2~4% of butylene glycol, 1~3% of panthenol, 1~3% of the mass of the Camellia oleifera seed oil skin care composition. Polyethylene glycol-32, 0.5~1.5% polyethylene glycol-8 and 0.4~0.6% 1,2-hexanediol.
所述保湿剂中,精氨酸属于碱性氨基酸,常被用于调理干燥性皮肤,且可与果酸、海藻糖等植物成分发生协同作用,保持肌肤水分,减少皮屑生成;泛醇主要用作保湿剂和皮肤调理剂,经皮肤吸收后可增加皮肤中透明质酸含量,促进人体蛋白质、脂肪、糖类的代谢,保护皮肤和黏膜,具有强效保湿效果;聚乙二醇-8在化妆品中既是保湿剂,也是稳定剂,有助于保障产品的稳定性;通过上述各组分进行协同搭配,得到的护肤组合物产品可充分提升皮肤的含水量,使用后可快速被皮肤吸收,同时各组分性质温和,对皮肤无刺激。Among the moisturizers, arginine is an alkaline amino acid that is often used to condition dry skin, and can synergize with plant ingredients such as fruit acid and trehalose to maintain skin moisture and reduce dandruff; panthenol is mainly It is used as a moisturizer and skin conditioner. After being absorbed through the skin, it can increase the content of hyaluronic acid in the skin, promote the metabolism of protein, fat, and sugar in the human body, protect the skin and mucous membranes, and has a strong moisturizing effect; polyethylene glycol-8 It is both a moisturizer and a stabilizer in cosmetics, helping to ensure the stability of the product; through the synergistic combination of the above components, the resulting skin care composition product can fully increase the moisture content of the skin and can be quickly absorbed by the skin after use. , and each component is mild in nature and non-irritating to the skin.
优选地,所述含水解植物蛋白的油茶籽油护肤组合物的组分还包括乳化剂抗氧化剂和皮肤调理剂;Preferably, the components of the Camellia oleifera oil skin care composition containing hydrolyzed vegetable protein also include emulsifiers, antioxidants and skin conditioning agents;
更优选地,所述乳化剂包括PEG-20 甲基葡糖倍半硬脂酸酯,所述抗氧化剂包括对羟基苯乙酮,所述皮肤调理剂包括甘草酸二钾;More preferably, the emulsifier includes PEG-20 methylglucose sesquistearate, the antioxidant includes p-hydroxyacetophenone, and the skin conditioning agent includes dipotassium glycyrrhizinate;
更优选地,所述含水解植物蛋白的油茶籽油护肤组合物的组分还包括占所述油茶籽油护肤组合物质量0.2~0.4%的PEG-20 甲基葡糖倍半硬脂酸酯、0.4~0.6%的对羟基苯乙酮和0.1~0.3%的甘草酸二钾。More preferably, the components of the Camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein also include PEG-20 methylglucose sesquistearate accounting for 0.2~0.4% of the mass of the Camellia oleifera seed oil skin care composition. , 0.4~0.6% p-hydroxyacetophenone and 0.1~0.3% dipotassium glycyrrhizinate.
通过在所述油茶籽油护肤组合物中添加上述适当的功能助剂,不仅可使产品的物理性质更加稳定,同时可为产品丰富其功能性,对使用者皮肤起到一定的抗衰老氧化及修复调理效果。By adding the above-mentioned appropriate functional additives to the Camellia oleifera seed oil skin care composition, not only can the physical properties of the product be more stable, but also the functionality of the product can be enriched, and the user's skin can have certain anti-aging, oxidation and Repair conditioning effects.
优选地,所述含水解植物蛋白的油茶籽油护肤组合物,包括以下质量百分含量的组分:0.5%精制油茶籽油、0.3% PEG-20 甲基葡糖倍半硬脂酸酯、0.5%水解豌豆蛋白、0.2%精氨酸、3%丁二醇、0.5%对羟基苯乙酮、2%泛醇、2%聚乙二醇-32、1%聚乙二醇-8、3%母菊花提取物、0.5% 1,2-己二醇、0.5%卡瓦胡椒叶/根/茎提取物、0.2%甘草酸二钾及余量水。Preferably, the Camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein includes the following mass percentage components: 0.5% refined Camellia oleifera seed oil, 0.3% PEG-20 methylglucose sesquistearate, 0.5% hydrolyzed pea protein, 0.2% arginine, 3% butylene glycol, 0.5% p-hydroxyacetophenone, 2% panthenol, 2% polyethylene glycol-32, 1% polyethylene glycol-8, 3 % Chamomile flower extract, 0.5% 1,2-hexanediol, 0.5% Kava kava leaf/root/stem extract, 0.2% dipotassium glycyrrhizinate and the balance water.
通过上述配比下得到的油茶籽油护肤组合物具有优异的皮肤保湿美白修护效果,产品无特殊不和谐异味且使用后无明显起白现象。The Camellia oleifera seed oil skin care composition obtained through the above ratio has excellent skin moisturizing, whitening and repairing effects. The product has no special discordant odor and no obvious whitening after use.
本发明的另一目的还在于提供所述含水解植物蛋白的油茶籽油护肤组合物的制备方法,包括以下步骤:Another object of the present invention is to provide a method for preparing the Camellia oleifera oil skin care composition containing hydrolyzed plant protein, which includes the following steps:
(1)将精制油茶籽油、PEG-20 甲基葡糖倍半硬脂酸酯和水解豌豆蛋白用水浸泡完全后,加热并保温搅拌均匀,冷却,得混合物A;(1) Soak the refined camellia seed oil, PEG-20 methylglucose sesquistearate and hydrolyzed pea protein in water, heat and keep warm, stir evenly, and cool to obtain mixture A;
(2)在步骤(1)所得混合物A中加入精氨酸,混合搅拌至溶解,得混合物B;(2) Add arginine to mixture A obtained in step (1), mix and stir until dissolved, to obtain mixture B;
(3)将丁二醇和对羟基苯乙酮加热混合均匀后,加入步骤(2)所得混合物B中,混合搅拌至溶解,冷却,得混合物C;(3) Heat butylene glycol and p-hydroxyacetophenone and mix them evenly, then add them to mixture B obtained in step (2), mix and stir until dissolved, and cool to obtain mixture C;
(4)在步骤(3)所得混合物C中依次加入泛醇、聚乙二醇-32、聚乙二醇-8、母菊花提取物、1,2-己二醇、卡瓦胡椒叶/根/茎提取物和甘草酸二钾,混合搅拌至完全溶解后,冷却,即得所述含水解植物蛋白的油茶籽油护肤组合物。(4) Add panthenol, polyethylene glycol-32, polyethylene glycol-8, chamomilla flower extract, 1,2-hexanediol, and kava leaves/roots to the mixture C obtained in step (3). /stem extract and dipotassium glycyrrhizinate, mix and stir until completely dissolved, and then cool to obtain the oil tea seed oil skin care composition containing hydrolyzed plant protein.
本发明所述含水解植物蛋白的油茶籽油护肤组合物的制备方法操作步骤简单,可实现工业化大规模生产。The preparation method of the Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein of the present invention has simple operation steps and can realize industrial large-scale production.
优选地,步骤(1)所述加热的温度为70~80℃,保温的时间为15~25min;Preferably, the heating temperature in step (1) is 70~80°C, and the heat preservation time is 15~25 minutes;
优选地,步骤(1)所述冷却后的温度为60℃以下,步骤(3)所述冷却后的温度为45℃以下,步骤(4)所述冷却后的温度为35℃以下。Preferably, the temperature after cooling in step (1) is below 60°C, the temperature after cooling in step (3) is below 45°C, and the temperature after cooling in step (4) is below 35°C.
所述条件下各组分充分溶解混合均匀,制备的产品稳定性更高。Under the conditions described, each component is fully dissolved and mixed evenly, and the prepared product has higher stability.
本发明的再一目的在于提供所述含水解植物蛋白的油茶籽油护肤组合物在制备护肤品中的应用。Another object of the present invention is to provide the use of the Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein in the preparation of skin care products.
本发明所述油茶籽油护肤组合物保湿美白效果好,气味性协调且皮肤适应性强,可用于多种护肤品中,且各类产品使用后不会出现起白现象。The Camellia oleifera seed oil skin care composition of the present invention has good moisturizing and whitening effects, coordinated odor and strong skin adaptability, can be used in a variety of skin care products, and will not cause whitening after use of various products.
优选地,所述护肤品包括面膜。Preferably, the skin care product includes a facial mask.
本发明的有益效果在于:本发明提供了一种含水解植物蛋白的油茶籽油护肤组合物,该产品以适当含量的精制油茶籽油代替传统制取的油茶籽油作为功效成分,其异味性大大降低,对肌肤相容性好;油茶籽油中富含的甾醇、生育酚、角鲨烯等抗氧化营养物质,可有效修复人体皮肤出现的褶皱、干裂等症状;通过在产品组分中添加特定含量的水解豌豆蛋白与其他组分相搭配,可有效缓解天然植物产品在应用过程中出现的起白现象,使得到的护肤组合物具有轻盈、不粘腻和润滑的质感。本发明还提供了所述含水解植物蛋白的油茶籽油护肤组合物的制备方法,该制备方法操作步骤简单,可实现工业化大规模生产。本发明还提供了所述含水解植物蛋白的油茶籽油护肤组合物在制备护肤品中的应用。The beneficial effects of the present invention are: the present invention provides a camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein. This product uses an appropriate content of refined camellia oleifera seed oil as the functional ingredient instead of the traditionally produced camellia oleifera seed oil, and its odor resistance It is greatly reduced and has good skin compatibility; Camellia oleifera seed oil is rich in sterols, tocopherols, squalene and other antioxidant nutrients, which can effectively repair wrinkles, dryness and other symptoms of human skin; by adding it to the product components Adding a specific content of hydrolyzed pea protein in combination with other components can effectively alleviate the whitening phenomenon that occurs during the application of natural plant products, making the resulting skin care composition have a light, non-sticky and smooth texture. The present invention also provides a preparation method of the Camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein. The preparation method has simple operation steps and can realize industrial large-scale production. The present invention also provides the use of the Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein in the preparation of skin care products.
具体实施方式Detailed ways
为了更好地说明本发明的目的、技术方案和优点,下面将结合具体实施例对本发明作进一步说明,其目的在于详细地理解本发明的内容,而不是对本发明的限制。In order to better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described below in conjunction with specific embodiments. The purpose is to understand the content of the present invention in detail, but not to limit the present invention.
实施例1~5Examples 1~5
本发明所述含水解植物蛋白的油茶籽油护肤组合物的实施例,各实施例中所述含水解植物蛋白的油茶籽油护肤组合物的配方如表1所示,所述精制油茶籽油为广东宝华农业科技股份有限公司生产的25°有机油茶籽油,其酸价为0.13 mg.KOH/g,过氧化值为1.1mmol/kg,所述精制油茶籽油中水分和挥发性物质的质量百分含量为0.11%;所述精制油茶籽油经过低温精制得到,所述低温精制包括脱胶、脱酸、脱色、除臭和脱蜡步骤,所述除臭步骤的温度为150℃。Examples of the Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein according to the present invention. The formula of the Camellia oleifera seed oil skin care composition containing hydrolyzed plant protein described in each embodiment is as shown in Table 1. The refined Camellia oleifera seed oil The 25° organic camellia seed oil produced by Guangdong Baohua Agricultural Science and Technology Co., Ltd. has an acid value of 0.13 mg.KOH/g and a peroxide value of 1.1mmol/kg. The water and volatile substances in the refined camellia seed oil are The mass percentage is 0.11%; the refined camellia seed oil is obtained through low-temperature refining, which includes degumming, deacidification, decolorization, deodorization and dewaxing steps, and the temperature of the deodorization step is 150°C.
所述含水解植物蛋白的油茶籽油护肤组合物的制备方法,包括以下步骤:The preparation method of the Camellia oleifera seed oil skin care composition containing hydrolyzed vegetable protein includes the following steps:
(1)将精制油茶籽油、PEG-20 甲基葡糖倍半硬脂酸酯和水解豌豆蛋白用水浸泡完全后,加热至75℃并保温20min,搅拌均匀,冷却至60℃以下,得混合物A;(1) Soak the refined Camellia oleifera seed oil, PEG-20 methyl glucose sesquistearate and hydrolyzed pea protein in water, heat to 75°C and keep warm for 20 minutes, stir evenly, and cool to below 60°C to obtain a mixture A;
(2)在步骤(1)所得混合物A中加入精氨酸,混合搅拌5min至溶解,得混合物B;(2) Add arginine to mixture A obtained in step (1), mix and stir for 5 minutes until dissolved, to obtain mixture B;
(3)将丁二醇和对羟基苯乙酮加热至60℃混合均匀后,加入步骤(2)所得混合物B中,混合搅拌5min至溶解,冷却至45℃以下,得混合物C;(3) Heat butanediol and p-hydroxyacetophenone to 60°C and mix evenly, then add it to mixture B obtained in step (2), mix and stir for 5 minutes until dissolved, and cool to below 45°C to obtain mixture C;
(4)在步骤(3)所得混合物C中依次加入泛醇、聚乙二醇-32、聚乙二醇-8、母菊花提取物、1,2-己二醇、卡瓦胡椒叶/根/茎提取物和甘草酸二钾,混合搅拌10min至完全溶解后,冷却至35℃以下,检验,灌装,包装,即得所述微黄色透明液态的含水解植物蛋白的油茶籽油护肤组合物。(4) Add panthenol, polyethylene glycol-32, polyethylene glycol-8, chamomilla flower extract, 1,2-hexanediol, and kava leaves/roots to the mixture C obtained in step (3). /stem extract and dipotassium glycyrrhizate, mix and stir for 10 minutes until completely dissolved, cool to below 35°C, inspect, fill, and package, to obtain the light yellow transparent liquid tea oil skin care combination containing hydrolyzed plant protein things.
对实施例1~5所得产品进行成分及性质分析,所述测试结果如表2所示,所述测试方法为QB/T 1857-2013 润肤膏霜。各产品成分及理化测试均符合指标,产品检验合格,可实现工业化生产、销售。The components and properties of the products obtained in Examples 1 to 5 were analyzed. The test results are shown in Table 2. The test method is QB/T 1857-2013 moisturizing cream. The ingredients and physical and chemical tests of each product are in line with the indicators, and the product has passed the inspection and can realize industrial production and sales.
表1Table 1
表2Table 2
对比例1~4Comparative Examples 1~4
对比例1~4所述油茶籽油护肤组合物与实施例1的差别仅在于配方上的不同,各对比例中所述油茶籽油护肤组合物的配方如表3所示。The difference between the Camellia oleifera seed oil skin care compositions described in Comparative Examples 1 to 4 and Example 1 is only in the formula. The formulas of the Camellia oleifera seed oil skin care compositions described in each Comparative Example are as shown in Table 3.
表3table 3
对比例5Comparative example 5
本对比例与实施例1的差别仅在于,本对比例所用油茶籽油为市售未经过低温精制的普通油茶籽油,该油茶籽油的酸价为0.37mg.KOH/g,过氧化值为2.6mmol/kg,所述精制油茶籽油中水分和挥发性物质的质量百分含量为0.18%。The only difference between this comparative example and Example 1 is that the Camellia oleifera seed oil used in this Comparative Example is commercially available ordinary Camellia oleifera seed oil that has not been refined at low temperatures. The acid value of the Camellia oleifera seed oil is 0.37 mg.KOH/g, and the peroxide value is 2.6mmol/kg, and the mass percentage of moisture and volatile substances in the refined camellia seed oil is 0.18%.
效果例1Effect example 1
为验证本发明所述油茶籽油护肤组合物的使用功效,将实施例1~5以及对比例1~5所得油茶籽油护肤组合物制备成面膜,对各面膜产品进行保湿效果测试。In order to verify the efficacy of the Camellia oleifera seed oil skin care composition of the present invention, the Camellia oleifera seed oil skin care compositions obtained in Examples 1 to 5 and Comparative Examples 1 to 5 were prepared into facial masks, and the moisturizing effect of each facial mask product was tested.
测试方法:Test Methods:
筛选 20~45 岁志愿者人群100名,所述志愿者是无严重系统疾病,无免疫缺陷或自身免疫性疾病者,无活动性过敏性疾病者,既往对化妆品无严重过敏史者,近一个月未曾使用过激素类药物及免疫抑制剂者,未参加其他临床测试者受试者。将志愿者分为10组,每组10人,各组之间无显著差异,试验前(即未使用本发明实施例及对比例所得产品)测试一次,每天晚上洁面后使用受试面膜,从使用样品的时间开始计时,于28 天测定测试区域的角质层水分含量、皮肤光泽度。所述受试产品分别为实施例1~5和对比例1~6的护肤品产品。所述角质层水分含量和皮肤光泽度分别使用皮肤水分测试探头 Cornometer CM825和皮肤光泽度测试探头 Skin-GlossymeterGL200进行测试得到。Screen 100 volunteers aged 20 to 45 years old. The volunteers have no serious systemic diseases, no immune deficiencies or autoimmune diseases, no active allergic diseases, and no history of severe allergies to cosmetics in the past one year. Subjects who have not used hormonal drugs and immunosuppressants for months, and who have not participated in other clinical tests. The volunteers were divided into 10 groups, with 10 people in each group. There was no significant difference between the groups. The test was conducted once before the test (that is, the products obtained by the embodiments and comparative examples of the present invention were not used). The tested mask was used after cleansing every night. The timer starts from the time when the sample is used, and the moisture content of the stratum corneum and skin gloss in the test area are measured on 28 days. The test products are the skin care products of Examples 1 to 5 and Comparative Examples 1 to 6 respectively. The moisture content of the stratum corneum and skin gloss were measured using the skin moisture test probe Cornometer CM825 and the skin gloss test probe Skin-GlossymeterGL200 respectively.
结果数据分析:Result data analysis:
a.水分、光泽度变化量的计算a. Calculation of moisture and gloss changes
使用样品后受试部位的测量值减去使用前受试部位的空白对照值,得到使用产品前后受试部位角质层水分含量、皮肤光泽度的变化量均值,计算公式如下式(1)和式(2)。The measured value of the test site after using the sample is subtracted from the blank control value of the test site before use, and the average change in the moisture content of the stratum corneum and skin gloss of the test site before and after using the product is obtained. The calculation formula is as follows: (1) and Eq. (2).
(1)T=(Mx-Mo)/10;(2)G=(Nx-No)/10;其式中:T为皮肤水分变化量;Mx为使用产品28 天后,皮肤水分的测量值;Mo为皮肤水分空白对照测量值;G为皮肤光泽度变化量;Nx为使用产品 28 天后,皮肤光泽度的测量值;No为皮肤光泽度空白对照测量值。(1) T=(M x -M o )/10; (2) G=(N x -N o )/10; where: T is the change in skin moisture; M x is the skin moisture content after using the product for 28 days The measured value of moisture; M o is the measured value of skin moisture blank control; G is the change in skin gloss; N x is the measured value of skin gloss after using the product for 28 days; N o is the measured value of skin gloss blank control.
测试结果如表4所示。The test results are shown in Table 4.
表4Table 4
从表4测试结果可知,实施例1~5所得产品对使用者皮肤的含水量和光泽度存在显著的提升作用,其中实施例1~3所得产品的提升程度较高于实施例4和5的产品,而从对比例1~5所得产品的测试结果可知,植物提取物含量的多少对产品的保湿美白效果具有较大影响,尤其是油茶籽油和水解豌豆蛋白的含量不足时,产品使用后的皮肤含水量及光泽度提升度显著减弱,但其含量逐渐增大至优选范围之外后,产品的保湿美白效果提升不大,反而造成生产成本的增加。It can be seen from the test results in Table 4 that the products obtained in Examples 1 to 5 have a significant improvement effect on the moisture content and gloss of the user's skin, and the degree of improvement of the products obtained in Examples 1 to 3 is higher than that of Examples 4 and 5. Products, and from the test results of the products obtained in Comparative Examples 1 to 5, it can be seen that the content of plant extracts has a great impact on the moisturizing and whitening effect of the product, especially when the content of Camellia oleifera seed oil and hydrolyzed pea protein is insufficient, after use of the product The skin moisture content and gloss improvement are significantly weakened, but when its content gradually increases beyond the optimal range, the moisturizing and whitening effect of the product is not greatly improved, but instead causes an increase in production costs.
效果例2Effect example 2
为检测本发明所述含水解植物蛋白的油茶籽油护肤组合物制备的面膜的使用体验,对实施例1~5及对比例1~5的10个产品进行用户体验测试,即对效果例1所述志愿者进行回访调查,针对志愿者使用后是否发生起白现象、气味评价、使用皮肤舒适度评价进行统计。其中气味评价总分5分,5评分标准为:气味协调自然,有愉悦香气;4评分标准为:气味协调,有一定香气;3评分标准为:气味一般,有一定特殊气味,但总体协调,不反感;2评分标准:有一定的不和谐气味,协调较弱,习惯后总体适应;1分评分标准:不和谐异味明显,令人反感,无法适应。使用皮肤舒适度评价总分5分,5评分标准为:使用时贴合性好,使用后皮肤吸收快;4评分标准为:使用时面膜贴合性好,使用后皮肤吸收较快;3评分标准为:使用时面膜贴合性一般,使用后皮肤吸收速度一般(总体与市售面膜相同);2评分标准为:使用时贴合性不好(不够自然),或者使用后吸收速度较慢;1评分标准为:使用时皮肤贴合不舒适,且使用后皮肤吸收速度慢。将上述评分统计后取平均值,所述结果如表5所示。In order to detect the use experience of the facial mask prepared from the camellia seed oil skin care composition containing hydrolyzed vegetable protein according to the present invention, user experience testing was conducted on 10 products of Examples 1 to 5 and Comparative Examples 1 to 5, that is, the effect example 1 The volunteers conducted a return visit survey, and statistics were collected on whether whitening occurred after use, odor evaluation, and skin comfort evaluation. Among them, the total score of the smell evaluation is 5 points. The 5 scoring standard is: the smell is harmonious and natural, with a pleasant aroma; the 4 scoring standard is: the smell is harmonious, with a certain aroma; the 3 scoring standard is: the smell is average, with a certain special smell, but overall harmonious, Not objectionable; 2 scoring criteria: There is a certain disharmonious odor, coordination is weak, and overall adaptation is possible after getting used to it; 1 scoring criteria: The disharmonious odor is obvious, objectionable, and unable to adapt. The total score of the skin comfort evaluation is 5 points. The 5 rating standard is: the mask fits well during use and the skin absorbs quickly after use; the 4 rating standard is: the mask fits well during use and the skin absorbs quickly after use; 3 rating The standard is: the fit of the mask is average during use, and the skin absorption rate is average after use (generally the same as that of commercially available masks); 2 The scoring criteria are: the fit is not good during use (not natural enough), or the absorption rate is slow after use. ;1 The scoring criteria are: uncomfortable skin fit during use, and slow skin absorption after use. The above scores were collected and averaged, and the results are shown in Table 5.
表5table 5
从表中可以看出,只有在产品中添加适当含量的水解豌豆蛋白,所得产品才能避免传统商品使用后出现的起白现象,而随着其含量逐渐增多,对产品的功效增幅变弱,反而生产成本提高;产品的特殊气味来源主要为油茶籽油,而相比于使用传统市售油茶籽油原料的对比例5所得产品,实施例1~5制备的面膜产品总体气味令人愉悦,评分均在4分以上;综合而言,实施例1~3所得产品具有良好的使用体验和优异的皮肤质量提升效果,其中实施例1所得产品效果最佳。It can be seen from the table that only by adding an appropriate amount of hydrolyzed pea protein to the product can the resulting product avoid the whitening phenomenon that occurs after the use of traditional products. As its content gradually increases, the effect of the product becomes weaker, and instead The production cost increases; the special odor source of the product is mainly Camellia oleifera seed oil. Compared with the product of Comparative Example 5 using traditional commercial Camellia oleifera seed oil raw materials, the overall smell of the facial mask products prepared in Examples 1 to 5 is pleasant, and the score is All scores are above 4 points; overall, the products obtained in Examples 1 to 3 have good usage experience and excellent skin quality improvement effect, among which the product obtained in Example 1 has the best effect.
最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and do not limit the protection scope of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that The technical solution of the present invention may be modified or equivalently substituted without departing from the essence and scope of the technical solution of the present invention.
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