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CN113041174B - Camellia oleifera seed oil essence containing hydrolyzed vegetable protein and its preparation method and application - Google Patents

Camellia oleifera seed oil essence containing hydrolyzed vegetable protein and its preparation method and application Download PDF

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CN113041174B
CN113041174B CN202110194990.7A CN202110194990A CN113041174B CN 113041174 B CN113041174 B CN 113041174B CN 202110194990 A CN202110194990 A CN 202110194990A CN 113041174 B CN113041174 B CN 113041174B
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seed oil
skin
mixture
camellia seed
oil essence
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CN113041174A (en
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张晖
李永泉
廖柏勇
王溢
谈静
吴伟
代文魁
郭微
涂攀峰
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Zhongkai University of Agriculture and Engineering
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    • AHUMAN NECESSITIES
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    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
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    • A61K8/675Vitamin B3 or vitamin B3 active, e.g. nicotinamide, nicotinic acid, nicotinyl aldehyde
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Abstract

The invention discloses a camellia seed oil essence containing hydrolyzed vegetable proteins and a preparation method thereof, and belongs to the technical field of skin care products. According to the camellia seed oil essence containing the vegetable proteins, the refined camellia seed oil with proper content is used for replacing the camellia seed oil prepared conventionally as an effective component, so that the odor is greatly reduced, and the skin compatibility is good; the camellia seed oil is rich in sterols, tocopherols, squalene and other antioxidant nutrients, so that symptoms such as wrinkles, chapping and the like of human skin can be effectively repaired; the white appearance of natural plant products in the application process can be effectively relieved by adding the hydrolyzed pea protein with specific content into the product components, so that the obtained oil tea seed oil essence has light, non-sticky and lubricating texture. The invention also provides a preparation method of the product, which has simple operation steps and can realize industrialized mass production. The invention also provides application of the product in preparing skin care products.

Description

一种含水解植物蛋白的油茶籽油精华液及其制备方法与应用Camellia oil essence containing hydrolyzed plant protein and preparation method and application thereof

技术领域Technical Field

本发明涉及护肤品技术领域,具体涉及一种含水解植物蛋白的油茶籽油精华液及其制备方法与应用。The invention relates to the technical field of skin care products, and in particular to a camellia oil essence containing hydrolyzed plant protein and a preparation method and application thereof.

背景技术Background Art

皮肤是人的身体器官中最大的器官,具有保护、排泄、调节体温和感受外界刺激等作用。皮肤常常受到氧化、干燥、紫外线等种种因素的刺激,容易受到损伤,此时如果不注意保养,皮肤状态迟早会变差的,干燥缺水、斑点、细纹等都是最常见的问题。又比如现代的生活节奏繁忙且充满动感长期劳累奔波,需要随时随地保持旺盛的精力,汗水与油腻厚厚的覆盖在皮肤表层,加重表面肌肤的负担,毛孔完全堵死,为了排出更多的油脂,毛孔会渐渐粗大、明显,肌肤渐粗糙,越发显得肌肤不平滑、肤质不均。The skin is the largest organ in the human body, and it has the functions of protection, excretion, regulating body temperature, and sensing external stimuli. The skin is often stimulated by various factors such as oxidation, dryness, and ultraviolet rays, and is easily damaged. If you do not pay attention to maintenance at this time, the skin condition will deteriorate sooner or later. Dryness, dehydration, spots, fine lines, etc. are the most common problems. For example, the pace of modern life is busy and dynamic. Long-term fatigue and running around require you to maintain vigorous energy anytime and anywhere. Sweat and grease are thickly covered on the surface of the skin, increasing the burden on the surface skin, and completely blocking the pores. In order to discharge more oil, the pores will gradually become larger and more obvious, and the skin will gradually become rough, making the skin more uneven and uneven.

为了保护皮肤免受损害和焕发光彩,必须重视皮肤的日常护理。要真正做到护肤,需让肌肤软化,使角质层可以吸收更多水份,渗透和吸收能力都会加强让营养物质与表皮细胞零距离地接触,深层吸收,从而达到活化肌肤,使皮肤光洁健康充满活力。In order to protect the skin from damage and make it glow, it is necessary to pay attention to daily skin care. To truly protect the skin, the skin needs to be softened so that the stratum corneum can absorb more water, and the penetration and absorption capacity will be enhanced to allow nutrients to come into close contact with the epidermal cells and be deeply absorbed, thereby activating the skin and making it smooth, healthy and full of vitality.

精华液作为一种富含浓缩高营养成分的护肤品,因其具有显著的抗皱、抗衰、紧致及保湿美白等多重功效,日渐成为护肤品领域的主流。然而现有精华液中不可避免会添加很多人工合成添加剂或助剂,虽然能保障产品具有一些特定性质(防腐防变质、气味独特、外观时尚),但是却往往忽略了产品本身所注重的护肤效果,也忽略了使用时皮肤的舒适程度,甚至部分产品长时间使用会对皮肤产生一定的消极效果;基于这些原因,人们开始使用一些天然植物成分来代替这些化学合成物质。但是,并非天然植物添加的种类和含量越多越好,人们发现,一些富含天然成分的化妆品在使用后皮肤容易出现起白现象,天然成分也与合成物质一样,不能盲目添加。As a skin care product rich in concentrated and highly nutritious ingredients, essence has gradually become the mainstream in the field of skin care products because of its significant anti-wrinkle, anti-aging, firming, moisturizing and whitening effects. However, many artificial synthetic additives or auxiliaries are inevitably added to existing essences. Although they can ensure that the products have certain specific properties (anti-corrosion and anti-deterioration, unique smell, fashionable appearance), they often ignore the skin care effects that the products themselves focus on, and also ignore the comfort of the skin during use. Even some products will have certain negative effects on the skin after long-term use. For these reasons, people began to use some natural plant ingredients to replace these chemical synthetic substances. However, it is not the case that the more types and contents of natural plants added, the better. People have found that some cosmetics rich in natural ingredients are prone to whitening of the skin after use. Natural ingredients, like synthetic substances, cannot be added blindly.

油茶籽油作为一种常见的植物提取物,其含有的脂肪酸组成和甘油酯构型有益于人体健康,且该物质中含有多种可溶性维生素,若该类活性物质被运用于护肤品中,不仅可使其制备的产品更加贴合人体皮肤,同时可赋予该产品滋润、修护皮肤的特性,提升产品的质感。CN109568202A公开了一种茶油润颜精华液精选油茶籽油、甘油、燕麦肽、野大豆籽提取物等原料按比例配伍,其中油茶籽油发挥着清洁、消炎、保护、滋润创面及软化痴皮的作用,制备的产品可有效起到保湿抗衰的功效。CN109528526A公开了一种植物精华皮肤调理剂及其制备方法和控油祛痘应用,该调理剂产品由茉莉花水、蒲公英提取物、菊花提取物、油茶籽油和亚麻籽油等天然成分作为原料,各中药配方遵循君臣佐使,使产品具有良好的控油、紧致肌肤的作用。Camellia oil is a common plant extract, and its fatty acid composition and glyceride configuration are beneficial to human health. In addition, the substance contains a variety of soluble vitamins. If such active substances are used in skin care products, not only can the products prepared by the camellia oil be more suitable for human skin, but also the products can be given the characteristics of moisturizing and repairing the skin, thereby improving the texture of the products. CN109568202A discloses a tea oil moisturizing essence, which selects camellia oil, glycerin, oat peptides, wild soybean seed extract and other raw materials in proportion, wherein the camellia oil plays the role of cleaning, anti-inflammatory, protecting, moisturizing wound surface and softening the skin, and the prepared product can effectively play the role of moisturizing and anti-aging. CN109528526A discloses a plant essence skin conditioner and its preparation method and oil control and acne removal application. The conditioner product is made of natural ingredients such as jasmine water, dandelion extract, chrysanthemum extract, camellia oil and linseed oil as raw materials, and each Chinese medicine formula follows the principle of monarch, minister, assistant and envoy, so that the product has good oil control and skin tightening effects.

然而,现有产品往往忽略了油茶籽油本身的缺陷。油茶籽油存在着其固有的难闻气味,但是现有产品往往只是将其当做普通的功效剂或油性基质使用,没有考虑其含量搭配或进行特殊处理;而现有传统方法制备的油茶籽油由于杂质较多,性质不稳定容易氧化,所以在储存或制备成产品后会进一步产生一些酸臭味。因此,即使利用油茶籽油制备了高护肤效果的纯天然护肤品,这类产品也因其不和谐的气味难以得到消费者的青睐;而若通过对护肤品的后续加工或添加除臭助剂等去除产品的异味,又会导致产品的生产成本提高,经济效益变低。However, existing products often ignore the defects of camellia oil itself. Camellia oil has its inherent unpleasant smell, but existing products often only use it as an ordinary efficacy agent or oily matrix, without considering its content or special treatment; and the camellia oil prepared by the existing traditional method has many impurities, unstable properties and easy oxidation, so it will further produce some sour and smelly smells after storage or preparation into products. Therefore, even if pure natural skin care products with high skin care effects are prepared using camellia oil, such products are difficult to be favored by consumers due to their discordant smell; and if the odor of the product is removed by subsequent processing of the skin care products or adding deodorizing agents, the production cost of the product will increase and the economic benefits will become low.

发明内容Summary of the invention

基于现有技术的不足,本发明的目的在于提供一种含水解植物蛋白的油茶籽油精华液,该产品富含天然植物成分且没有传统油茶籽油产品特有的浓重气味,具有优异的肌肤保湿、修护和美白功效,使用后不会出现起白现象。Based on the deficiencies of the prior art, the purpose of the present invention is to provide a camellia oil essence containing hydrolyzed plant protein, which is rich in natural plant ingredients and does not have the strong smell unique to traditional camellia oil products. It has excellent skin moisturizing, repairing and whitening effects, and will not cause whitening after use.

为了达到上述目的,本发明采取的技术方案为:In order to achieve the above object, the technical solution adopted by the present invention is:

一种含水解植物蛋白的油茶籽油精华液,包括以下组分:植物提取物、保湿剂、皮肤调理剂及余量水;所述植物提取物中包括占所述油茶籽油精华液质量0.1~0.5%的水解豌豆蛋白和0.3~0.7%的精制油茶(CAMELLIA OLEIFERA)籽油。A camellia oleifera oil essence containing hydrolyzed plant protein comprises the following components: plant extract, moisturizer, skin conditioner and balance water; the plant extract comprises 0.1-0.5% of hydrolyzed pea protein and 0.3-0.7% of refined camellia oleifera seed oil by weight of the camellia oleifera oil essence.

本发明所述含水解植物蛋白的油茶籽油精华液的组分中,以适当含量的精制油茶籽油代替传统制取的油茶籽油作为功效成分,其异味性大大降低,对肌肤相容性好;油茶籽油中富含的甾醇、生育酚、角鲨烯等抗氧化营养物质,可有效修复人体皮肤出现的褶皱、干裂等症状;通过在产品组分中添加特定含量的水解豌豆蛋白与保湿剂、皮肤调理剂相搭配,可有效缓解天然植物产品在应用过程中出现的起白现象,使得到的油茶籽油精华液具有轻盈、不粘腻和润滑的质感。In the components of the camellia oil essence containing hydrolyzed plant protein of the present invention, an appropriate amount of refined camellia oil is used as an effective ingredient instead of traditionally prepared camellia oil, so that the odor is greatly reduced and the skin compatibility is good; the camellia oil is rich in antioxidant nutrients such as sterols, tocopherol, squalene, etc., which can effectively repair the wrinkles, cracks and other symptoms of human skin; by adding a specific amount of hydrolyzed pea protein to the product components in combination with a moisturizer and a skin conditioner, the whitening phenomenon of natural plant products during the application process can be effectively alleviated, so that the obtained camellia oil essence has a light, non-greasy and lubricated texture.

优选地,所述精制油茶籽油经过低温精制得到,所述低温精制包括脱胶、脱酸、脱色、除臭和脱蜡步骤,所述除臭步骤的温度不高于150℃。Preferably, the refined camellia oil is obtained by low-temperature refining, which includes degumming, deacidification, decolorization, deodorization and dewaxing steps, and the temperature of the deodorization step is not higher than 150°C.

更优选地,所述精制茶油籽的酸价<0.5mg.KOH/g,过氧化值<1.5mmol/kg,所述精制茶油籽中水分和挥发性物质的质量百分含量<0.15%。More preferably, the acid value of the refined tea oil seeds is less than 0.5 mg.KOH/g, the peroxide value is less than 1.5 mmol/kg, and the mass percentage of water and volatile substances in the refined tea oil seeds is less than 0.15%.

发明人经过多次测试发现,传统油茶籽油制备方法往往使用高温方法进行提炼处理,此类方法得到的产品不仅杂质多,气味浓重,同时会造成甾醇等营养成分流失甚至失活,极不利于油茶籽油在后续护肤品中的使用。本发明所述精制油茶籽油以低温多步法进行提炼,同时严格限定制备的油茶籽油的理化指标及控制气味及不稳定性来源(游离脂肪酸等)的含量,不仅可使浓重气味消除,还能进一步提升其在制备的油茶籽油精华液中的抗氧化润肤能力。The inventors have found through multiple tests that the traditional camellia oil preparation method often uses a high temperature method for refining. The products obtained by such methods not only have many impurities and a strong odor, but also cause the loss or even inactivation of nutrients such as sterols, which is extremely unfavorable for the use of camellia oil in subsequent skin care products. The refined camellia oil of the present invention is refined by a low-temperature multi-step method, and at the same time, the physical and chemical indicators of the prepared camellia oil are strictly limited, and the content of the odor and instability source (free fatty acids, etc.) is controlled, which can not only eliminate the strong odor, but also further enhance its antioxidant and moisturizing ability in the prepared camellia oil essence.

更优选地,所述精制油茶籽油可选用广东宝华农业科技股份有限公司生产的有机油茶籽油。More preferably, the refined camellia oil can be organic camellia oil produced by Guangdong Baohua Agricultural Science and Technology Co., Ltd.

所述产品纯度高,气味小,稳定性高,可有效用于本发明所述油茶籽油精华液中。The product has high purity, low odor and high stability, and can be effectively used in the camellia seed oil essence of the present invention.

优选地,所述植物提取物中包括占所述油茶籽油精华液质量0.2~0.4%的水解豌豆蛋白和0.4~0.6%的精制油茶籽油;Preferably, the plant extract comprises 0.2-0.4% of hydrolyzed pea protein and 0.4-0.6% of refined camellia oil by weight of the camellia oil essence;

更优选地,所述植物提取物中包括占所述油茶籽油精华液质量0.3%的水解豌豆蛋白和0.5%的精制油茶籽油。More preferably, the plant extract comprises 0.3% of hydrolyzed pea protein and 0.5% of refined camellia oil by weight of the camellia oil essence.

所述配比下的含水解植物蛋白的油茶籽油精华液不仅具有更加协调的气味,同时其保湿护肤效果更加,与皮肤相容性更好。The camellia oil essence containing hydrolyzed plant protein in the above ratio not only has a more harmonious smell, but also has a better moisturizing and skin care effect and better compatibility with the skin.

优选地,所述保湿剂包括1,2-戊二醇、丁二醇、1,2-己二醇、甘油、神经酰胺-3和氢化软磷脂。Preferably, the moisturizing agent includes 1,2-pentanediol, butylene glycol, 1,2-hexanediol, glycerin, ceramide-3 and hydrogenated phospholipids.

更优选地,所述保湿剂包括占所述油茶籽油精华液质量0.5~1.5%的1,2-戊二醇、2.5~3.5%的丁二醇、0.4~0.6%的1,2-己二醇、0.05~0.15%的甘油、0.02~0.03%的神经酰胺-3和0.02~0.03%的氢化软磷脂。More preferably, the moisturizer includes 0.5-1.5% of 1,2-pentanediol, 2.5-3.5% of butylene glycol, 0.4-0.6% of 1,2-hexanediol, 0.05-0.15% of glycerol, 0.02-0.03% of ceramide-3 and 0.02-0.03% of hydrogenated phospholipids, based on the mass of the camellia oil essence.

所述保湿剂中,1,2-戊二醇和丁二醇在化妆品成分中都是典型的合成小分子保湿剂,具有锁水和抗菌的作用,对人体皮肤无刺激;神经酰胺-3是一种脂质物质,它和构成皮肤角质层的物质结构相近,能很快渗透进皮肤,和角质层中的水结合,形成一种网状结构,锁住水分,对肌肤保湿修护有良好作用,是角质层中重要的活肤成分,能增强皮肤屏障,重建细胞;氢化卵磷脂是卵磷脂的部分水解物,相比卵磷脂具有更好的亲水能力,可为人的皮肤和毛发吸收水分并能促进其他营养物质的渗透。通过上述各组分进行协同搭配,得到的油茶籽油精华液产品可充分提升皮肤的含水量,使用后可快速被皮肤吸收,同时各组分性质温和,对皮肤无刺激。Among the moisturizers, 1,2-pentanediol and butanediol are typical synthetic small molecule moisturizers in cosmetic ingredients, which have the effects of water locking and antibacterial, and are non-irritating to human skin; ceramide-3 is a lipid substance, which is similar to the material structure that constitutes the stratum corneum of the skin, can quickly penetrate into the skin, and combine with the water in the stratum corneum to form a mesh structure, lock in moisture, and have a good effect on skin moisturizing and repairing. It is an important skin-activating ingredient in the stratum corneum, which can enhance the skin barrier and rebuild cells; hydrogenated lecithin is a partial hydrolyzate of lecithin, which has better hydrophilicity than lecithin, can absorb moisture for human skin and hair, and can promote the penetration of other nutrients. By synergistically matching the above components, the obtained camellia oil essence product can fully increase the water content of the skin, can be quickly absorbed by the skin after use, and at the same time, each component is mild in nature and non-irritating to the skin.

优选地,所述皮肤调理剂包括烟酰胺、透明质酸钠交联聚合物、棕榈酰三肽-1、甘草酸二钾、β-葡聚糖和菊粉。Preferably, the skin conditioning agent comprises niacinamide, sodium hyaluronate crosspolymer, palmitoyl tripeptide-1, dipotassium glycyrrhizinate, β-glucan and inulin.

更优选地,所述皮肤调理剂包括占所述油茶籽油精华液质量3~5%的烟酰胺、0.5~1.5%的透明质酸钠交联聚合物、0.05~0.15%的棕榈酰三肽-1、0.1~0.3%的甘草酸二钾、0.1~0.3%的β-葡聚糖和0.001~0.003%的菊粉。More preferably, the skin conditioner comprises 3-5% niacinamide, 0.5-1.5% sodium hyaluronate cross-linked polymer, 0.05-0.15% palmitoyl tripeptide-1, 0.1-0.3% dipotassium glycyrrhizinate, 0.1-0.3% β-glucan and 0.001-0.003% inulin, based on the mass of the camellia oil essence.

所述皮肤调理剂中,烟酰胺具有很高的安全性,也是临床皮肤科治疗中的一种基础性维生素类补充剂,它在抑制黑色素沉着、抗炎等方面有很好的疗效,也能够维持肌肤含水量,促进真皮层微循环,还能极大减少或消除皮肤老化现象,减少自由基对皮肤的伤害,起到预防老化、修复皮肤和减少面部暗沉的作用;透明质酸钠是一种酸性粘多糖,天然存在于角膜皮中,可吸收其本身重量1000倍水分,以达到通过保留皮肤水分、阻止水分经表皮流失,而当皮肤受到损伤时其又能充当皮肤屏障,同时令皮肤增加光泽,改善皮肤营养代谢,使皮肤柔、光滑、去皱、增加弹性;棕榈酰三肽-1是由小麦和大豆蛋白结合而成,该成分能够刺激皮肤中胶原蛋白合成;甘草酸二钾主要为甘草根部及茎部的甘草甜素(甘草酸)成分,具有抗刺激及控油、退红肿消炎愈合作用;β-葡聚糖作为天然植物胶聚糖,在化妆品中一般充当皮肤调理剂和保湿剂使用,同时该成分还有一定的抗敏抗炎作用;菊粉富含具有抗炎作用的三萜类化合物,可治疗皮炎,对皮肤的诱导性过敏有抑制作用,同时能消除自由基,对黑色素细胞也有一定的抑制作用,可起到缓解衰老和美白祛斑的功效。通过上述组分的配合,最终得到的油茶籽油精华液可实现对皮肤的多重护理,除了基本的保湿美白功效外,还能提升皮肤各项属性。Among the skin conditioners, niacinamide has high safety and is also a basic vitamin supplement in clinical dermatology. It has good therapeutic effects in inhibiting melanin deposition and anti-inflammation, and can also maintain skin moisture, promote dermal microcirculation, and greatly reduce or eliminate skin aging, reduce the damage of free radicals to the skin, and play a role in preventing aging, repairing the skin and reducing facial dullness; sodium hyaluronate is an acidic mucopolysaccharide that naturally exists in the corneal skin and can absorb 1000 times its own weight in water to retain skin moisture and prevent water loss through the epidermis. When the skin is damaged, it can act as a skin barrier, while increasing the skin's luster and improving skin nutrient metabolism. It can make the skin soft, smooth, wrinkle-free and elastic; Palmitoyl tripeptide-1 is a combination of wheat and soy protein, which can stimulate the synthesis of collagen in the skin; Dipotassium glycyrrhizinate is mainly glycyrrhizin (glycyrrhizic acid) from the root and stem of licorice, which has anti-irritation, oil control, anti-redness, swelling, anti-inflammatory and healing effects; β-glucan, as a natural plant polysaccharide, is generally used as a skin conditioner and moisturizer in cosmetics, and this ingredient also has certain anti-allergic and anti-inflammatory effects; Inulin is rich in triterpenoid compounds with anti-inflammatory effects, which can treat dermatitis, inhibit skin-induced allergies, eliminate free radicals, and have a certain inhibitory effect on melanocytes, which can relieve aging and whiten and remove spots. Through the combination of the above components, the camellia seed oil essence finally obtained can achieve multiple care for the skin. In addition to the basic moisturizing and whitening effects, it can also improve various skin properties.

优选地,所述含水解植物蛋白的油茶籽油精华液的组分中还包括乳化剂、抗氧剂和缓冲剂。Preferably, the components of the camellia oil essence containing hydrolyzed plant protein also include an emulsifier, an antioxidant and a buffer.

更优选地,所述乳化剂包括PEG-20甲基葡糖倍半硬脂酸酯、卡波姆、聚山梨醇酯-20、蔗糖硬脂酸酯和聚甘油-10硬脂酸酯。More preferably, the emulsifier includes PEG-20 methyl glucose sesquistearate, carbomer, polysorbate-20, sucrose stearate and polyglyceryl-10 stearate.

通过上述乳化剂的复配,不仅可使产品中各组分可充分混合并实现迅速乳化,同时可保障产品具备良好的稳定性,不易分层。Through the compounding of the above-mentioned emulsifiers, not only can the components in the product be fully mixed and rapidly emulsified, but also the product can be guaranteed to have good stability and not be easily stratified.

更优选地,所述乳化剂包括占所述油茶籽油精华液质量0.05~0.15%的PEG-20甲基葡糖倍半硬脂酸酯、0.05~0.15%的卡波姆、0.05~0.15%的聚山梨醇酯-20、0.02~0.03%的蔗糖硬脂酸酯和0.02~0.03%的聚甘油-10硬脂酸酯。More preferably, the emulsifier includes 0.05-0.15% of PEG-20 methyl glucose sesquistearate, 0.05-0.15% of carbomer, 0.05-0.15% of polysorbate-20, 0.02-0.03% of sucrose stearate and 0.02-0.03% of polyglycerol-10 stearate, based on the mass of the camellia oil essence.

优选地,所述抗氧剂包括透明质酸钠和对羟基苯乙酮,所述缓冲剂包括柠檬酸和柠檬酸钠。Preferably, the antioxidant comprises sodium hyaluronate and p-hydroxyacetophenone, and the buffer comprises citric acid and sodium citrate.

更优选地,所述抗氧剂包括占所述油茶籽油精华液质量0.01~0.03%的透明质酸钠和0.3~0.5%的对羟基苯乙酮,所述缓冲剂包括占所述油茶籽油精华液质量0.3~0.5%的柠檬酸和0.3~0.5%的柠檬酸钠。More preferably, the antioxidant comprises 0.01-0.03% sodium hyaluronate and 0.3-0.5% p-hydroxyacetophenone based on the mass of the camellia oil essence, and the buffer comprises 0.3-0.5% citric acid and 0.3-0.5% sodium citrate based on the mass of the camellia oil essence.

通过在所述油茶籽油精华液中添加上述适当的功能助剂,不仅可使产品的物理性质更加稳定,同时可为产品丰富其功能性,对使用者皮肤起到一定的抗衰老氧化效果。By adding the above-mentioned appropriate functional additives to the camellia oil essence, not only can the physical properties of the product be made more stable, but also the functionality of the product can be enriched, and a certain anti-aging and oxidation effect can be exerted on the user's skin.

优选地,所述含水解植物蛋白的油茶籽油精华液,包括以下质量百分含量的组分:0.3%水解豌豆蛋白、0.5%精制油茶籽油、0.1%PEG-20甲基葡糖倍半硬脂酸酯、1%1,2-戊二醇、0.02%透明质酸钠、3.1%丁二醇、0.4%对羟基苯乙酮、4%烟酰胺、1%透明质酸钠交联聚合物、0.4%柠檬酸、0.4%柠檬酸钠、0.5%1,2-己二醇、0.1%甘油、0.1%卡波姆、0.1%聚山梨醇酯-20、0.1%棕榈酰三肽-1、0.2%甘草酸二钾、0.2%β-葡聚糖、0.002%菊粉、0.025%神经酰胺-3、0.025%氢化卵磷脂、0.025%蔗糖硬脂酸酯和0.025%聚甘油-10硬脂酸酯。Preferably, the camellia oil essence containing hydrolyzed plant protein comprises the following components in percentage by weight: 0.3% hydrolyzed pea protein, 0.5% refined camellia oil, 0.1% PEG-20 methyl glucose sesquistearate, 1% 1,2-pentanediol, 0.02% sodium hyaluronate, 3.1% butylene glycol, 0.4% p-hydroxyacetophenone, 4% niacinamide, 1% sodium hyaluronate cross-linked polymer, 0.4% citric acid. , 0.4% sodium citrate, 0.5% 1,2-hexanediol, 0.1% glycerin, 0.1% carbomer, 0.1% polysorbate-20, 0.1% palmitoyl tripeptide-1, 0.2% dipotassium glycyrrhizate, 0.2% beta-glucan, 0.002% inulin, 0.025% ceramide-3, 0.025% hydrogenated lecithin, 0.025% sucrose stearate and 0.025% polyglyceryl-10 stearate.

通过上述配比下得到的油茶籽油精华液具有优异的皮肤保湿美白修护效果,产品无特殊不和谐异味且使用后无明显起白现象。The camellia oil essence obtained by the above ratio has excellent skin moisturizing, whitening and repairing effects. The product has no special unharmonious odor and no obvious whitening phenomenon after use.

本发明的另一目的还在于提供所述含水解植物蛋白的油茶籽油精华液的制备方法,包括以下步骤:Another object of the present invention is to provide a method for preparing the camellia oil essence containing hydrolyzed plant protein, comprising the following steps:

(1)将水解豌豆蛋白用水浸泡至湿润,加热并保温搅拌均匀,得混合物A;(1) soaking the hydrolyzed pea protein in water until it is moistened, heating and stirring the mixture evenly while keeping the temperature constant to obtain a mixture A;

(2)将步骤(1)所得混合物A均质并依次加入精制油茶籽油和PEG-20甲基葡糖倍半硬脂酸酯,均质乳化后真空消泡,冷却,加入常温下预先混合分散好的1,2-戊二醇和透明质酸钠并搅拌混合至完全溶解,得混合物B;(2) homogenizing the mixture A obtained in step (1) and sequentially adding refined camellia oil and PEG-20 methyl glucose sesquistearate, homogenizing and emulsifying, vacuum defoaming, cooling, adding 1,2-pentanediol and sodium hyaluronate pre-mixed and dispersed at room temperature, and stirring and mixing until completely dissolved, to obtain a mixture B;

(3)将适量丁二醇与对羟基苯乙酮混合并加热搅拌均匀后,加入步骤(2)所得混合物B中,搅拌至完全溶解,冷却,得混合物C;(3) mixing an appropriate amount of butanediol and p-hydroxyacetophenone, heating and stirring to obtain a uniform mixture, adding the mixture to the mixture B obtained in step (2), stirring until completely dissolved, and cooling to obtain a mixture C;

(4)将神经酰胺-3、氢化卵磷脂、蔗糖硬脂酸酯和聚甘油-10硬脂酸酯用水溶解均匀后,得混合物D;(4) Dissolving ceramide-3, hydrogenated lecithin, sucrose stearate and polyglyceryl-10 stearate in water to obtain a mixture D;

(5)将烟酰胺、透明质酸钠交联聚合物、柠檬酸、柠檬酸钠、1,2-己二醇、甘油、余量的丁二醇、卡波姆、聚山梨醇酯-20、棕榈酰三肽-1、甘草酸二钾、β-葡聚糖、菊粉以及混合物D依次加入步骤(3)所得混合物C中并搅拌混合至完全溶解,冷却,即得所述含水解植物蛋白的油茶籽油精华液。(5) Niacinamide, sodium hyaluronate cross-linked polymer, citric acid, sodium citrate, 1,2-hexanediol, glycerol, the remaining amount of butylene glycol, carbomer, polysorbate-20, palmitoyl tripeptide-1, dipotassium glycyrrhizinate, β-glucan, inulin and mixture D are sequentially added to the mixture C obtained in step (3) and stirred until completely dissolved, and cooled to obtain the camellia oil essence containing hydrolyzed plant protein.

本发明所述含水解植物蛋白的油茶籽油精华液的制备方法操作步骤简单,可实现工业化大规模生产。The preparation method of the camellia oil essence containing hydrolyzed plant protein of the present invention has simple operation steps and can realize industrial large-scale production.

优选地,步骤(1)所述加热的温度为70~80℃,保温的时间为15~25min;步骤(1)所述加热的温度为55~65℃。Preferably, the heating temperature in step (1) is 70-80°C, and the insulation time is 15-25 minutes; the heating temperature in step (1) is 55-65°C.

优选地,步骤(2)所述冷却后的温度为60℃以下,步骤(3)所述冷却后的温度为45℃以下,步骤(5)所述冷却后的温度为35℃以下。Preferably, the temperature after cooling in step (2) is below 60°C, the temperature after cooling in step (3) is below 45°C, and the temperature after cooling in step (5) is below 35°C.

所述条件下各组分充分溶解混合均匀,制备的产品稳定性更高。Under the above conditions, each component is fully dissolved and mixed evenly, and the prepared product has higher stability.

本发明的再一目的在于提供所述含水解植物蛋白的油茶籽油精华液在制备护肤品中的应用。Another object of the present invention is to provide the use of the camellia oil essence containing hydrolyzed plant protein in the preparation of skin care products.

本发明所述油茶籽油精华液保湿美白效果好,气味性协调且皮肤适应性强,可直接在皮肤上进行使用,也可根据需求进一步加工成多种护肤品,且各类产品使用后不会出现起白现象。The camellia seed oil essence of the invention has good moisturizing and whitening effects, harmonious odor and strong skin adaptability, can be directly used on the skin, and can also be further processed into a variety of skin care products according to needs, and various products will not cause whitening after use.

本发明的有益效果在于:本发明提供了一种含水解植物蛋白的油茶籽油精华液,该产品以适当含量的精制油茶籽油代替传统制取的油茶籽油作为功效成分,其异味性大大降低,对肌肤相容性好;油茶籽油中富含的甾醇、生育酚、角鲨烯等抗氧化营养物质,可有效修复人体皮肤出现的褶皱、干裂等症状;通过在产品组分中添加特定含量的水解豌豆蛋白与保湿剂、皮肤调理剂相搭配,可有效缓解天然植物产品在应用过程中出现的起白现象,使得到的油茶籽油精华液具有轻盈、不粘腻和润滑的质感。本发明还提供了所述含水解植物蛋白的油茶籽油精华液的制备方法,该制备方法操作步骤简单,可实现工业化大规模生产。本发明还提供了所述含水解植物蛋白的油茶籽油精华液在制备护肤品中的应用。The beneficial effects of the present invention are as follows: the present invention provides a camellia oil essence containing hydrolyzed plant protein, the product uses an appropriate amount of refined camellia oil instead of traditionally prepared camellia oil as an effective ingredient, the odor is greatly reduced, and the skin compatibility is good; the camellia oil is rich in antioxidant nutrients such as sterols, tocopherol, squalene, etc., which can effectively repair the wrinkles, cracks and other symptoms of human skin; by adding a specific amount of hydrolyzed pea protein to the product components and matching it with a moisturizer and a skin conditioner, the whitening phenomenon of natural plant products during the application process can be effectively alleviated, so that the obtained camellia oil essence has a light, non-greasy and lubricated texture. The present invention also provides a preparation method of the camellia oil essence containing hydrolyzed plant protein, the preparation method has simple operation steps, and can realize industrial large-scale production. The present invention also provides the application of the camellia oil essence containing hydrolyzed plant protein in the preparation of skin care products.

具体实施方式DETAILED DESCRIPTION

为了更好地说明本发明的目的、技术方案和优点,下面将结合具体实施例对本发明作进一步说明,其目的在于详细地理解本发明的内容,而不是对本发明的限制。In order to better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described below in conjunction with specific embodiments, the purpose of which is to understand the contents of the present invention in detail rather than to limit the present invention.

实施例1~5Embodiments 1 to 5

本发明所述含水解植物蛋白的油茶籽油精华液的实施例,各实施例中所述含水解植物蛋白的油茶籽油精华液的配方如表1所示,所述精制油茶籽油为广东宝华农业科技股份有限公司生产的25°有机油茶籽油,其酸价为0.13mg.KOH/g,过氧化值为1.1mmol/kg,所述精制茶油籽中水分和挥发性物质的质量百分含量为0.11%;所述精制油茶籽油经过低温精制得到,所述低温精制包括脱胶、脱酸、脱色、除臭和脱蜡步骤,所述除臭步骤的温度为150℃。The embodiments of the camellia oil essence containing hydrolyzed plant protein of the present invention, the formula of the camellia oil essence containing hydrolyzed plant protein in each embodiment is shown in Table 1, the refined camellia oil is 25° organic camellia oil produced by Guangdong Baohua Agricultural Science and Technology Co., Ltd., its acid value is 0.13mg.KOH/g, the peroxide value is 1.1mmol/kg, and the mass percentage of water and volatile matter in the refined camellia oil seeds is 0.11%; the refined camellia oil is obtained by low-temperature refining, the low-temperature refining includes degumming, deacidification, decolorization, deodorization and dewaxing steps, and the temperature of the deodorization step is 150°C.

所述含水解植物蛋白的油茶籽油精华液的制备方法,包括以下步骤:The method for preparing the camellia oil essence containing hydrolyzed plant protein comprises the following steps:

(1)将水解豌豆蛋白用水浸泡至湿润,加热至75℃并保温20min,搅拌均匀,得混合物A;(1) Soaking the hydrolyzed pea protein in water until it is moist, heating it to 75° C. and keeping it warm for 20 minutes, and stirring it evenly to obtain a mixture A;

(2)将步骤(1)所得混合物A低俗均质并依次加入精制油茶籽油和PEG-20甲基葡糖倍半硬脂酸酯,均质乳化5min后真空消泡,自然降温并冷却至60℃,加入常温下预先混合分散好的1,2-戊二醇和透明质酸钠并搅拌混合10min至完全溶解,得混合物B;(2) homogenizing the mixture A obtained in step (1) and sequentially adding refined camellia oil and PEG-20 methyl glucose sesquistearate, homogenizing and emulsifying for 5 minutes, vacuum defoaming, naturally cooling to 60° C., adding 1,2-pentanediol and sodium hyaluronate pre-mixed and dispersed at room temperature, and stirring and mixing for 10 minutes until completely dissolved, to obtain a mixture B;

(3)将适量丁二醇与对羟基苯乙酮混合并加热至60℃搅拌均匀后,加入步骤(2)所得混合物B中,搅拌5min至完全溶解,冷却至45℃以下,得混合物C;(3) Mixing an appropriate amount of butanediol and p-hydroxyacetophenone, heating to 60° C. and stirring evenly, adding the mixture to the mixture B obtained in step (2), stirring for 5 min until completely dissolved, and cooling to below 45° C. to obtain a mixture C;

(4)将神经酰胺-3、氢化卵磷脂、蔗糖硬脂酸酯和聚甘油-10硬脂酸酯用水溶解均匀后,得混合物D;(4) Dissolving ceramide-3, hydrogenated lecithin, sucrose stearate and polyglyceryl-10 stearate in water to obtain a mixture D;

(5)将烟酰胺、透明质酸钠交联聚合物、柠檬酸、柠檬酸钠、1,2-己二醇、甘油、余量的丁二醇、卡波姆、聚山梨醇酯-20、棕榈酰三肽-1、甘草酸二钾、β-葡聚糖、菊粉以及混合物D依次加入步骤(3)所得混合物C中并搅拌混合至完全溶解,冷却至35℃以下,检验,灌装,包装,即得所述白色半透明液态的含水解植物蛋白的油茶籽油精华液。(5) Niacinamide, sodium hyaluronate cross-linked polymer, citric acid, sodium citrate, 1,2-hexanediol, glycerol, the remaining amount of butylene glycol, carbomer, polysorbate-20, palmitoyl tripeptide-1, dipotassium glycyrrhizinate, β-glucan, inulin and mixture D are sequentially added to the mixture C obtained in step (3) and stirred until completely dissolved, cooled to below 35° C., inspected, filled and packaged to obtain the white translucent liquid camellia oil essence containing hydrolyzed plant protein.

对实施例1~5所得产品进行成分及性质分析,所述测试结果如表2所示,所述测试方法为QB/T 2660-2004化妆水。各产品成分及理化测试均符合指标,产品检验合格,可实现工业化生产、销售。The components and properties of the products obtained in Examples 1 to 5 were analyzed, and the test results are shown in Table 2. The test method is QB/T 2660-2004 lotion. The components and physical and chemical tests of each product meet the indicators, and the product inspection is qualified, and can be industrialized for production and sales.

表1Table 1

Figure BDA0002945100360000091
Figure BDA0002945100360000091

表2Table 2

Figure BDA0002945100360000092
Figure BDA0002945100360000092

Figure BDA0002945100360000101
Figure BDA0002945100360000101

对比例1~4Comparative Examples 1 to 4

对比例1~4所述油茶籽油精华液与实施例1的差别仅在于配方上的不同,各对比例中所述油茶籽油精华液的配方如表3所示。The difference between the camellia oil essences described in Comparative Examples 1 to 4 and Example 1 is only the difference in formula. The formulas of the camellia oil essences in each comparative example are shown in Table 3.

表3Table 3

Figure BDA0002945100360000102
Figure BDA0002945100360000102

Figure BDA0002945100360000111
Figure BDA0002945100360000111

对比例5Comparative Example 5

本对比例与实施例1的差别仅在于,本对比例所用油茶籽油为市售未经过低温精制的普通油茶籽油,该油茶籽油的酸价为0.37mg.KOH/g,过氧化值为2.6mmol/kg,所述精制茶油籽中水分和挥发性物质的质量百分含量为0.18%。The only difference between this comparative example and Example 1 is that the camellia oil used in this comparative example is commercially available ordinary camellia oil that has not been low-temperature refined, the acid value of the camellia oil is 0.37 mg.KOH/g, the peroxide value is 2.6 mmol/kg, and the mass percentage of water and volatile substances in the refined camellia oil seeds is 0.18%.

效果例1Effect Example 1

为验证本发明所述油茶籽油精华液的使用功效,将实施例1~5以及对比例1~5所得油茶籽油精华液进行保湿效果测试。In order to verify the efficacy of the camellia oil essence of the present invention, the camellia oil essences obtained in Examples 1 to 5 and Comparative Examples 1 to 5 were tested for moisturizing effects.

测试方法:Test method:

筛选20~45岁志愿者人群100名,所述志愿者是无严重系统疾病,无免疫缺陷或自身免疫性疾病者,无活动性过敏性疾病者,既往对化妆品无严重过敏史者,近一个月未曾使用过激素类药物及免疫抑制剂者,未参加其他临床测试者受试者。将志愿者分为10组,每组10人,各组之间无显著差异,试验前(即未使用本发明实施例及对比例所得产品)测试一次,每天晚上洁面后使用受试精华液,从使用样品的时间开始计时,于28天测定测试区域的角质层水分含量、皮肤光泽度。所述受试产品分别为实施例1~5和对比例1~6的护肤品产品。所述角质层水分含量和皮肤光泽度分别使用皮肤水分测试探头Cornometer CM825和皮肤光泽度测试探头Skin-Glossymeter GL200进行测试得到。100 volunteers aged 20 to 45 were screened. The volunteers had no serious systemic diseases, no immunodeficiency or autoimmune diseases, no active allergic diseases, no history of severe allergies to cosmetics, had not used hormone drugs and immunosuppressants in the past month, and had not participated in other clinical test subjects. The volunteers were divided into 10 groups, 10 people in each group, and there was no significant difference between the groups. Before the test (i.e., the products obtained by the embodiments of the present invention and the comparative examples were not used), the test was conducted once, and the tested essence was used after cleansing every night. The timing was started from the time when the sample was used, and the stratum corneum moisture content and skin glossiness of the test area were measured in 28 days. The tested products were the skin care products of Examples 1 to 5 and Comparative Examples 1 to 6, respectively. The stratum corneum moisture content and skin glossiness were tested using the skin moisture test probe Cornometer CM825 and the skin gloss test probe Skin-Glossymeter GL200, respectively.

结果数据分析:Results Data Analysis:

a.水分、光泽度变化量的计算a. Calculation of moisture and gloss changes

使用样品后受试部位的测量值减去使用前受试部位的空白对照值,得到使用产品前后受试部位角质层水分含量、皮肤光泽度的变化量均值,计算公式如下式(1)和式(2)。The measured value of the test site after using the sample was subtracted from the blank control value of the test site before use to obtain the average change in stratum corneum moisture content and skin glossiness of the test site before and after using the product. The calculation formula is as follows: (1) and (2).

(1)T=(Mx-Mo)/10;(2)G=(Nx-No)/10;其式中:T为皮肤水分变化量;Mx为使用产品28天后,皮肤水分的测量值;Mo为皮肤水分空白对照测量值;G为皮肤光泽度变化量;Nx为使用产品28天后,皮肤光泽度的测量值;No为皮肤光泽度空白对照测量值。(1) T = ( Mx - Mo )/10; (2) G = ( Nx - No )/10; where: T is the change in skin moisture; Mx is the measured value of skin moisture after using the product for 28 days; Mo is the blank control measured value of skin moisture; G is the change in skin gloss; Nx is the measured value of skin gloss after using the product for 28 days; No is the blank control measured value of skin gloss.

测试结果如表4所示。The test results are shown in Table 4.

表4Table 4

Figure BDA0002945100360000121
Figure BDA0002945100360000121

Figure BDA0002945100360000131
Figure BDA0002945100360000131

从表4测试结果可知,实施例1~5所得产品对使用者皮肤的含水量和光泽度存在显著的提升作用,其中实施例1~3所得产品的提升程度较高于实施例4和5的产品,而从对比例1~5所得产品的测试结果可知,植物提取物含量的多少对产品的保湿美白效果具有较大影响,尤其是油茶籽油和水解豌豆蛋白的含量不足时,产品使用后的皮肤含水量及光泽度提升度显著减弱,但其含量逐渐增大至优选范围之外后,产品的保湿美白效果提升不大,反而造成生产成本的增加。From the test results in Table 4, it can be seen that the products obtained in Examples 1 to 5 have a significant effect on improving the moisture content and glossiness of the user's skin, among which the improvement degree of the products obtained in Examples 1 to 3 is higher than that of the products in Examples 4 and 5. From the test results of the products obtained in Comparative Examples 1 to 5, it can be seen that the amount of plant extract has a great influence on the moisturizing and whitening effects of the products, especially when the content of camellia seed oil and hydrolyzed pea protein is insufficient, the improvement of skin moisture content and glossiness after use of the product is significantly weakened, but when their content gradually increases to outside the preferred range, the moisturizing and whitening effects of the product are not greatly improved, but instead increase the production cost.

效果例2Effect Example 2

为检测本发明所述含水解植物蛋白的油茶籽油精华液的使用体验,对实施例1~5及对比例1~5的10个产品进行用户体验测试,即对效果例1所述志愿者进行回访调查,针对志愿者使用后是否发生起白现象、气味评价、使用皮肤舒适度评价进行统计。其中气味评价总分5分,5评分标准为:气味协调自然,有愉悦香气;4评分标准为:气味协调,有一定香气;3评分标准为:气味一般,有一定特殊气味,但总体协调,不反感;2评分标准:有一定的不和谐气味,协调较弱,习惯后总体适应;1分评分标准:不和谐异味明显,令人反感,无法适应。使用皮肤舒适度评价总分5分,5评分标准为:使用时质感舒适,使用后皮肤吸收快;4评分标准为:使用时质感较好,使用后皮肤吸收较快;3评分标准为:使用时质感一般,使用后皮肤吸收速度一般(总体与市售精华液相同);2评分标准为:使用时质感不好(不细腻或不滑润),或者使用后吸收速度较慢;1评分标准为:使用时质感差,且使用后皮肤吸收速度慢。将上述评分统计后取平均值,所述结果如表5所示。In order to detect the user experience of the camellia oil essence containing hydrolyzed plant protein of the present invention, the user experience test was conducted on the 10 products of Examples 1 to 5 and Comparative Examples 1 to 5, that is, a return visit survey was conducted on the volunteers described in Effect Example 1, and statistics were collected on whether the volunteers had whitening phenomenon after use, odor evaluation, and skin comfort evaluation. The total score of odor evaluation is 5 points, and the scoring standard of 5 is: the odor is harmonious and natural, with a pleasant aroma; the scoring standard of 4 is: the odor is harmonious and has a certain aroma; the scoring standard of 3 is: the odor is general, with a certain special odor, but it is generally coordinated and not offensive; the scoring standard of 2 is: there is a certain disharmonious odor, the coordination is weak, and it is generally adapted after getting used to it; the scoring standard of 1 point is: the disharmonious odor is obvious, offensive, and it is impossible to adapt. The total score of skin comfort evaluation is 5 points, and the scoring standard of 5 is: comfortable texture when used, and the skin absorbs quickly after use; the scoring standard of 4 is: good texture when used, and the skin absorbs quickly after use; the scoring standard of 3 is: average texture when used, and the skin absorbs quickly after use (generally the same as the commercially available essence); the scoring standard of 2 is: bad texture when used (not delicate or smooth), or slow absorption after use; the scoring standard of 1 is: poor texture when used, and slow skin absorption after use. The above scores are counted and the average is taken, and the results are shown in Table 5.

表5Table 5

Figure BDA0002945100360000132
Figure BDA0002945100360000132

Figure BDA0002945100360000141
Figure BDA0002945100360000141

从表中可以看出,只有在产品中添加适当含量的水解豌豆蛋白,所得产品才能避免传统商品使用后出现的起白现象,而随着其含量逐渐增多并超过优选范围,对产品的功效增幅变弱,反而生产成本提高;产品的特殊气味来源主要为油茶籽油,而相比于使用传统市售油茶籽油原料的对比例5所得产品,实施例1~5制备的产品总体气味令人愉悦,评分均在4.5分以上;综合而言,实施例1~3所得产品具有良好的使用体验和优异的皮肤质量提升效果,其中实施例1所得产品效果最佳。It can be seen from the table that only by adding an appropriate amount of hydrolyzed pea protein to the product can the obtained product avoid the whitening phenomenon that occurs after use of traditional products. As its content gradually increases and exceeds the preferred range, the increase in the efficacy of the product becomes weaker, and the production cost increases instead. The special smell of the product mainly comes from camellia oil. Compared with the product obtained in Comparative Example 5 using traditional commercially available camellia oil raw materials, the overall smell of the products prepared in Examples 1 to 5 is pleasant, and the scores are all above 4.5 points. In general, the products obtained in Examples 1 to 3 have a good use experience and excellent skin quality improvement effect, among which the product obtained in Example 1 has the best effect.

最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention rather than to limit the scope of protection of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solution of the present invention can be modified or replaced by equivalents without departing from the essence and scope of the technical solution of the present invention.

Claims (4)

1. The camellia seed oil essence containing the hydrolyzed vegetable protein is characterized by comprising the following components: plant extract, humectant, skin conditioning agent, emulsifier, antioxidant, buffer and balance water; the plant extract comprises hydrolyzed pea protein accounting for 0.3 percent of the mass of the camellia seed oil essence and refined camellia seed oil accounting for 0.5 percent of the mass of the camellia seed oil essence; the humectant comprises 0.5-1.5% of 1, 2-pentanediol, 2.5-3.5% of butanediol, 0.4-0.6% of 1, 2-hexanediol, 0.05-0.15% of glycerol, 0.02-0.03% of ceramide-3 and 0.02-0.03% of hydrogenated lecithin by mass of the camellia seed oil essence; the skin conditioner comprises 3-5% of nicotinamide, 0.5-1.5% of sodium hyaluronate crosslinked polymer, 0.05-0.15% of palmitoyl tripeptide-1, 0.1-0.3% of dipotassium glycyrrhizinate, 0.1-0.3% of beta-glucan and 0.001-0.003% of inulin, wherein the nicotinamide, the sodium hyaluronate crosslinked polymer, the palmitoyl tripeptide-1, the dipotassium glycyrrhizinate, the beta-glucan and the inulin account for the mass of the camellia seed oil essence; the emulsifier comprises 0.05-0.15% of PEG-20 methyl glucose sesquistearate, 0.05-0.15% of carbomer, 0.05-0.15% of polysorbate-20, 0.02-0.03% of sucrose stearate and 0.02-0.03% of polyglycerol-10 stearate by mass of the oil tea seed oil essence; the antioxidant comprises sodium hyaluronate accounting for 0.01-0.03% of the mass of the camellia seed oil essence and p-hydroxyacetophenone accounting for 0.3-0.5%, and the buffer comprises citric acid accounting for 0.3-0.5% of the mass of the camellia seed oil essence and sodium citrate accounting for 0.3-0.5%;
the refined oil tea seed oil is obtained through low-temperature refining, wherein the low-temperature refining comprises the steps of degumming, deacidification, decolorization, deodorization and dewaxing, and the temperature of the deodorization step is not higher than 150 ℃; the acid value of the refined tea oil seeds is less than 0.5mg.KOH/g, the peroxide value is less than 1.5mmol/kg, and the mass percentage of moisture and volatile substances in the refined tea oil seeds is less than 0.15%.
2. The plant protein containing camellia seed oil essence of claim 1, wherein the plant protein containing camellia seed oil essence comprises the following components in percentage by mass: 0.3% hydrolyzed pea protein, 0.5% refined camellia seed oil, 0.1% PEG-20 methyl glucagons sesquistearate, 1%1, 2-pentanediol, 0.02% sodium hyaluronate, 3.1% butylene glycol, 0.4% p-hydroxyacetophenone, 4% nicotinamide, 1% sodium hyaluronate cross-linked polymer, 0.4% citric acid, 0.4% sodium citrate, 0.5%1, 2-hexanediol, 0.1% glycerol, 0.1% carbomer, 0.1% polysorbate-20, 0.1% palmitoyl tripeptide-1, 0.2% dipotassium glycyrrhizinate, 0.2% beta-glucan, 0.002% inulin, 0.025% ceramide-3, 0.025% hydrogenated lecithin, 0.025% sucrose stearate, and 0.025% polyglycerol-10 stearate.
3. The preparation method of the camellia seed oil essence containing hydrolyzed vegetable proteins as claimed in any one of claims 1-2, which is characterized by comprising the following steps:
(1) Soaking hydrolyzed pea protein in water until the hydrolyzed pea protein is wet, heating, preserving heat and uniformly stirring to obtain a mixture A;
(2) Homogenizing the mixture A obtained in the step (1), sequentially adding refined camellia oleosa seed oil and PEG-20 methyl glucose sesquistearate, homogenizing and emulsifying, vacuum defoaming, cooling, adding 1, 2-pentanediol and sodium hyaluronate which are mixed and dispersed in advance at normal temperature, and stirring and mixing until the mixture A and the mixture B are completely dissolved to obtain a mixture B;
(3) Mixing a proper amount of butanediol with the p-hydroxyacetophenone, heating and stirring uniformly, adding the mixture into the mixture B obtained in the step (2), stirring until the mixture is completely dissolved, and cooling to obtain a mixture C;
(4) Dissolving ceramide-3, hydrogenated lecithin, sucrose stearate and polyglycerol-10 stearate with water uniformly to obtain a mixture D;
(5) Sequentially adding nicotinamide, sodium hyaluronate crosslinked polymer, citric acid, sodium citrate, 1, 2-hexanediol, glycerol, the balance of butanediol, carbomer, polysorbate-20, palmitoyl tripeptide-1, dipotassium glycyrrhizinate, beta-glucan, inulin and the mixture D into the mixture C obtained in the step (3), stirring and mixing until the mixture C is completely dissolved, and cooling to obtain the camellia seed oil essence containing the hydrolyzed plant proteins.
4. The use of the oil tea seed oil essence containing hydrolyzed vegetable proteins as claimed in any one of claims 1-2 in the preparation of skin care products.
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CN109602668A (en) * 2019-02-22 2019-04-12 浙江康知秀日用品有限公司 A kind of anti-aging anti-wrinkle composition and its application
CN111214417A (en) * 2020-03-10 2020-06-02 广州澳特朗生物技术有限公司 Yeast essence with effects of tightening and resisting wrinkles and preparation method and application thereof
CN112156032A (en) * 2020-10-27 2021-01-01 成都律恩泽雅科技有限公司 Whitening essence milk and preparation method thereof

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