[go: up one dir, main page]

CN113057172A - Ternary compound seed dressing agent containing prothioconazole and fludioxonil - Google Patents

Ternary compound seed dressing agent containing prothioconazole and fludioxonil Download PDF

Info

Publication number
CN113057172A
CN113057172A CN202110223611.2A CN202110223611A CN113057172A CN 113057172 A CN113057172 A CN 113057172A CN 202110223611 A CN202110223611 A CN 202110223611A CN 113057172 A CN113057172 A CN 113057172A
Authority
CN
China
Prior art keywords
seed dressing
agent
fludioxonil
dressing agent
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110223611.2A
Other languages
Chinese (zh)
Inventor
刘言合
陈琦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Runnongtenghui Biotechnology Co ltd
Original Assignee
Anhui Runnongtenghui Biotechnology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Runnongtenghui Biotechnology Co ltd filed Critical Anhui Runnongtenghui Biotechnology Co ltd
Priority to CN202110223611.2A priority Critical patent/CN113057172A/en
Publication of CN113057172A publication Critical patent/CN113057172A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/08Immunising seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Soil Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

The invention discloses a ternary complex seed dressing agent containing prothioconazole and fludioxonil, which comprises an effective component A, B, C, wherein A is prothioconazole, B is fludioxonil, C is one of sedaxane, fluopyram and bixafen, the content of A is 0.2-15%, the content of B is 0.5-15%, and the content of C is 1-45%. After the seed dressing agent is compounded, prothioconazole, fludioxonil and a third active ingredient act to realize synergism, and are not easy to generate drug resistance, the compounding shows synergism, the dosage of the seed dressing agent is reduced compared with a single agent after compounding, the use cost is reduced, eucalyptus oil is added, the pungent smell of the compounded seed dressing agent is increased, underground pests can be effectively repelled, the germination rate of seeds is improved, and the eucalyptus oil is non-toxic and harmless and is more environment-friendly.

Description

Ternary compound seed dressing agent containing prothioconazole and fludioxonil
Technical Field
The invention relates to the technical field of pesticide compounding, in particular to a ternary compound seed dressing agent containing prothioconazole and fludioxonil.
Background
Fludioxonil for preventing and treating stinking smut, snow rot, snow mold, banded sclerotial blight, root rot, take-all disease, glume blight and stalk smut of wheat: barley stripe disease, net blotch, head smut: maize bacterial wilt, stem rot, damping off: cotton rhizoctonia rot, red rot, anthracnose, black root, seed rot: soybean peanut damping off, root rot (caused by fusarium): rice bakanae disease, leaf spot of flax, early leaf blast and damping off: black spot and black shank of rape: potato damping off, scab: vegetable blight, anthracnose, brown spot, gummy stem blight. Is suitable for crops such as wheat, barley, corn, cotton, soybean, peanut, rice, rape, potato, vegetables and the like.
FLUDIOXONIL, named FLUDIOXONIL in English, has a molecular weight of 248.185, a molecular formula of C12H6F2N2O2 and a chemical name of 4- (2, 2-difluoro-1, 3-benzodioxy-4-yl) pyrrole-3-nitrile; 4- (2, 2-difluoro-1, 3-benzodioxol-4-yl) pyrrole-3-carbonitrile. By inhibiting the transfer associated with phosphorylation of glucose and inhibiting the growth of fungal mycelia, the germs die eventually. The action mechanism is unique, and the bactericide has no cross resistance with the existing bactericide. According to FRAC (action group of fungicide resistance) in the international world, the action mechanism of fludioxonil is considered to be the activity of histidine kinase related to osmotic pressure regulation signals, and the fludioxonil is used for treating the leaf surfaces of wheat, barley, corn, pea, rape, rice, vegetables, grapes, lawn and ornamental crops, preventing and treating fusarium nivale, triticale cerealis, rhizoctonia solani and the like and has a special effect on gray mold; treatment of cereal and non-cereal seeds for the control of seed-borne and soil-borne pathogens such as Alternaria, Chaetomium, Aspergillus, Fusarium, Helminthosporium, Rhizoctonia and Penicillium.
In modern agricultural production, the seed is treated with seed coating agent, and this is one of the economic and simple methods for preventing and controlling soil-borne and seed-borne diseases of underground pests and crops. The seed treating agent is one kind of pesticide preparation with filming property for treating crop and other plant seed, and has the functions of allowing water and air to pass through, slow releasing of pesticide, seed fertilizer and other matter, killing underground pests and pests, preventing and treating diseases and systemic diseases, raising seed germination rate, promoting the growth of seedling, etc.
At present, the annual crop seed demand in China is about 700 million tons, the commodity seed amount is about 350 million tons, the coating treatment accounts for about 10 percent, and the two coating agents have huge market demand and very broad prospects.
Disclosure of Invention
The invention aims to solve the technical problems in the prior art and provides a ternary complex seed dressing agent containing prothioconazole and fludioxonil, which has the advantages of good synergistic action and compatibility, time and labor saving, less pollution compared with other pesticide application technologies, high control effect, low toxicity, environmental protection and insect prevention and disease treatment effects.
In order to realize the purpose of the invention, the technical scheme adopted by the invention is as follows:
the ternary complex seed dressing agent comprises an effective component A, B, C, wherein A is prothioconazole, B is fludioxonil, C is one of sedaxane, fluopyram and dipheny, the content of A is 0.2-15%, the content of B is 0.5-15%, and the content of C is 1-45%.
And C is sedaxane.
The content of A is 5%, the content of B is 10% and the content of C is 35%.
The formulation of the ternary complex seed dressing agent is one of a suspended seed coating agent, a seed treatment suspending agent, a microcapsule suspending agent and a dry seed dressing agent.
The dosage form of the ternary complex seed dressing agent is a dry seed dressing agent.
The dry seed dressing agent contains A, B, C, eucalyptus oil, a wetting agent, a dispersing agent, a film forming agent and a filler.
The eucalyptus oil content is 3% -5%, the wetting agent content is 3% -6%, the dispersing agent content is 2.5% -7%, the film-forming agent content is 1% -4%, and the balance is made up to 100% by the filler.
Has the advantages that:
1. after compounding, the prothioconazole, fludioxonil and the third active ingredient have synergistic effect, and are not easy to generate drug resistance: the growth of fungal mycelia is inhibited, so that germs die finally, the three effective components have different action mechanisms on the germs, and the compounding shows synergistic effect;
2. compared with a single agent, the compound preparation reduces the dosage of the agent, and the use cost is reduced: the fludioxonil is used independently, so that the cost is obviously reduced on the premise of ensuring the drug effect.
3. The bactericide has no drug resistance and obvious effect, different mechanisms of all effective components, different action sites and no interactive drug resistance, is not easy to generate drug resistance by mutually mixing germs, and solves the problem of drug resistance generated by singly using a certain bactericide at present;
4. the eucalyptus oil is added, so that the pungent smell of the compound seed dressing agent is increased, underground pests can be effectively driven away, the germination rate of seeds is improved, and the eucalyptus oil is non-toxic, harmless and more environment-friendly.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described with the following embodiments, but the present invention is by no means limited to these examples.
Example 1
The raw materials comprise: 2% of prothioconazole, 4% of fludioxonil, 15% of sedaxane, 4% of eucalyptus oil, 4% of film forming agent, 6% of dispersing agent, 5% of wetting agent and the balance of filling. The materials are uniformly mixed in a mixing and stirring kettle according to the corresponding proportion to prepare the dry seed dressing agent of 2 percent of prothioconazole, 4 percent of fludioxonil and 15 percent of sedaxane.
Example 2
The raw materials comprise: 5% of prothioconazole, 10% of fludioxonil, 35% of sedaxane, 4% of eucalyptus oil, 3% of film forming agent, 5% of dispersing agent, 4% of wetting agent and the balance of filling. The materials are uniformly mixed in a mixing and stirring kettle according to the corresponding proportion to prepare the dry seed dressing agent of 5 percent of prothioconazole, 10 percent of fludioxonil and 35 percent of sedaxane.
Example 3
The raw materials comprise: 7% of prothioconazole, 13% of fludioxonil, 40% of sedaxane, 4% of eucalyptus oil, 2% of film forming agent, 4% of dispersing agent, 3% of wetting agent and the balance of filling. The materials are uniformly mixed in a mixing and stirring kettle according to the corresponding proportion to prepare the dry seed dressing agent of 7 percent of prothioconazole, 13 percent of fludioxonil and 40 percent of sedaxane.
Comparative example 1
5% Prothioconazole suspension seed coating agent (Liyang Zhongnan chemical Co., Ltd.)
Comparative example 2
10% fludioxonil suspension seed coating (Xianzhengda)
1. Experimental Material
The wheat variety to be tested was nineteen of nicotiana (hongze lake farm species ltd., Jiangsu province).
2. Experimental methods
2.1 design of the experiment
A total of 3 treatments were set. Treatment 1: uncoated, as a blank control; and (3) treatment 2: example 1-example 6 agents were applied to seeds for coating treatment; and (3) treatment: comparative example 1-comparative example 3 the agents were applied to the seeds for coating.
Random block arrangement is adopted, 3 times of repetition are carried out, and the area of a cell is 2m2. The number of seeds in each group is equal.
2.2 survey items
And (3) investigating the withering and death rate, the withering rate of the non-necrotic seedlings and the dwarfing inhibition rate at the seedling stage of the wheat.
The control effect (%) of root rot in seedling stage is [ (seedling withering rate in control field-seed coating agent treated seedling withering rate)/seedling withering rate in control field ]. times.100
Dwarfing inhibition (%) of [ ("average plant height in control field-average plant height treated with seed coating)/average plant height in control field ] × 100
And (5) investigating the incidence rate of root rot in the adult wheat growing period. The disease degree of 4 diseases of wheat small spot, leaf spot, brown spot and rust disease is graded and investigated.
Incidence (%) × 100 (number of diseased plants/total number of investigated plants) ×
Disease index [ Σ (number of diseased plants at each stage × representative value at each stage)/(total number of investigated plants × highest representative value) ] × 100
Disease control effect (%) in adult stage ═ control incidence (disease index) — (incidence of disease in control treatment of seed coating agent)/control incidence of disease (disease index) × 100
3. Results and analysis of the experiments
TABLE 1 Effect of different seed dressings on wheat growth at the seedling stage
Figure BDA0002947549090000041
The results of the above experiments show that the wheat seedling withering rate of 3 kinds of compound seed-dressing agents is less than that of a blank control, the root rot prevention effect of the 3 kinds of compound seed-dressing agents is more than 9%, wherein the effective component contents of 5% prothioconazole, 10% fludioxonil, 35% fluopyram dry seed-dressing agent and 7% prothioconazole, 13% fludioxonil, 40% bispyribac dry seed-dressing agent are increased, but the seedling withering rate, the root rot prevention effect and the dwarfing inhibition rate are not obvious.
Table 2 shows the control effect of different seed coating treatments on wheat root rot
Figure BDA0002947549090000042
Figure BDA0002947549090000051
As can be seen from Table 2, the incidence of the wheat treated by the 3 compound seed dressings is lower than that of the blank control and the comparative example, the prevention effect of the compound seed dressing on root rot is more than 69%, and the effect is good.
In order to verify the pest control effect of the compound seed dressing agent, summer corns were subjected to field experiments, treated according to examples 1-3 and comparative examples 1-2, and a blank control group, each treatment was repeated three times, and the test was continued for 3 years, and the germination rate was investigated 30 days after sowing.
Table 3 shows the effect on the germination rate of maize
Serial number Medicament Germination percentage (%)
1 2% prothioconazole, 4% fludioxonil and 15% sedaxane dry seed dressing agent 92.58
2 5% prothioconazole, 10% fludioxonil, 35% fluopyram dry seed-dressing agent 92.99
3 7% prothioconazole, 13% fludioxonil, 40% bixafen dry seed dressing agent 93.04
4 5% prothioconazole suspension seed coating agent 87.21
5 10% fludioxonil suspension seed coating agent 86.37
6 Blank control 82.47
As can be seen from Table 3, after the corn seeds are treated by the compound seed dressing agent of the examples 1 to 3, the germination rate of the corn seeds is obviously improved due to the driving off of underground pests by the pungent odor generated by the addition of eucalyptus oil, and the germination rate is not obviously improved along with the increase of the content of the active ingredients, so that the optimal content of 2% prothioconazole, 4% fludioxonil and 15% sedaxane is the best content.

Claims (7)

1. A ternary complex seed dressing agent containing prothioconazole and fludioxonil is characterized in that: the ternary compound seed dressing agent comprises an effective component A, B, C, wherein A is prothioconazole, B is fludioxonil, C is one of sedaxane, fluopyram and bixafen, the content of A is 0.2% -15%, the content of B is 0.5% -15%, and the content of C is 1% -45%.
2. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 1, which is characterized in that: and C is sedaxane.
3. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 1, which is characterized in that: the content of A is 5%, the content of B is 10% and the content of C is 35%.
4. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 1, which is characterized in that: the formulation of the ternary complex seed dressing agent is one of a suspended seed coating agent, a seed treatment suspending agent, a microcapsule suspending agent and a dry seed dressing agent.
5. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 1, which is characterized in that: the dosage form of the ternary complex seed dressing agent is a dry seed dressing agent.
6. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 5, wherein the weight percentage of the seed dressing agent is as follows: the dry seed dressing agent contains A, B, C, eucalyptus oil, a wetting agent, a dispersing agent, a film forming agent and a filler.
7. The ternary complex seed dressing agent containing prothioconazole and fludioxonil according to claim 6, wherein the weight percentage of the seed dressing agent is as follows: the eucalyptus oil content is 3% -5%, the wetting agent content is 3% -6%, the dispersing agent content is 2.5% -7%, the film-forming agent content is 1% -4%, and the balance is made up to 100% by the filler.
CN202110223611.2A 2021-02-22 2021-02-22 Ternary compound seed dressing agent containing prothioconazole and fludioxonil Pending CN113057172A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110223611.2A CN113057172A (en) 2021-02-22 2021-02-22 Ternary compound seed dressing agent containing prothioconazole and fludioxonil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110223611.2A CN113057172A (en) 2021-02-22 2021-02-22 Ternary compound seed dressing agent containing prothioconazole and fludioxonil

Publications (1)

Publication Number Publication Date
CN113057172A true CN113057172A (en) 2021-07-02

Family

ID=76559228

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110223611.2A Pending CN113057172A (en) 2021-02-22 2021-02-22 Ternary compound seed dressing agent containing prothioconazole and fludioxonil

Country Status (1)

Country Link
CN (1) CN113057172A (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007131678A1 (en) * 2006-05-16 2007-11-22 Bayer Cropscience Ag Fungicidal active substance combinations
CN103719102A (en) * 2013-12-11 2014-04-16 海利尔药业集团股份有限公司 Sterilization composite containing fluopyram and prothioconazole
CN103843770A (en) * 2012-12-07 2014-06-11 海利尔药业集团股份有限公司 Bactericidal composition containing fluopyram and fludioxonil
CN105766933A (en) * 2015-12-24 2016-07-20 南京华洲药业有限公司 Bixafen and prothioconazole containing bactericidal composition and application thereof
CN106342822A (en) * 2016-08-31 2017-01-25 陕西西大华特科技实业有限公司 Fludioxonil, prothioconazole and chlorantraniliprole containing composition and seed coating agent and application of seed coating agent
CN106417311A (en) * 2015-08-12 2017-02-22 四川利尔作物科学有限公司 Seed treating agent composition and application thereof
CN107788001A (en) * 2016-08-29 2018-03-13 四川利尔作物科学有限公司 Seed treatment composition and its application
CN108935486A (en) * 2014-03-11 2018-12-07 江苏龙灯化学有限公司 A kind of bactericidal composition
CN109511661A (en) * 2017-09-20 2019-03-26 佛山市盈辉作物科学有限公司 Containing prothioconazoles, fludioxonil, fluorine pyrrole furanone compounding seed treatment
CN110432277A (en) * 2019-05-09 2019-11-12 广东中迅农科股份有限公司 A kind of insecticidal and bactericidal composition for seed treatment

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007131678A1 (en) * 2006-05-16 2007-11-22 Bayer Cropscience Ag Fungicidal active substance combinations
CN103843770A (en) * 2012-12-07 2014-06-11 海利尔药业集团股份有限公司 Bactericidal composition containing fluopyram and fludioxonil
CN103719102A (en) * 2013-12-11 2014-04-16 海利尔药业集团股份有限公司 Sterilization composite containing fluopyram and prothioconazole
CN108935486A (en) * 2014-03-11 2018-12-07 江苏龙灯化学有限公司 A kind of bactericidal composition
CN106417311A (en) * 2015-08-12 2017-02-22 四川利尔作物科学有限公司 Seed treating agent composition and application thereof
CN105766933A (en) * 2015-12-24 2016-07-20 南京华洲药业有限公司 Bixafen and prothioconazole containing bactericidal composition and application thereof
CN107788001A (en) * 2016-08-29 2018-03-13 四川利尔作物科学有限公司 Seed treatment composition and its application
CN106342822A (en) * 2016-08-31 2017-01-25 陕西西大华特科技实业有限公司 Fludioxonil, prothioconazole and chlorantraniliprole containing composition and seed coating agent and application of seed coating agent
CN109511661A (en) * 2017-09-20 2019-03-26 佛山市盈辉作物科学有限公司 Containing prothioconazoles, fludioxonil, fluorine pyrrole furanone compounding seed treatment
CN110432277A (en) * 2019-05-09 2019-11-12 广东中迅农科股份有限公司 A kind of insecticidal and bactericidal composition for seed treatment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
外崎肇一: "《神奇气味学,拿来就用》", 31 January 2011 *

Similar Documents

Publication Publication Date Title
CN100397992C (en) Seed coating agent for improving cold resistance of super sweet corn seeds
CN102334500B (en) Insect-killing and disease-preventing suspension seed coating formulation
CN112970765A (en) Ternary compound seed dressing agent for preventing and treating plant diseases and insect pests
CN103583525B (en) Pesticide composition containing phenazino-1-carboxylic acid
WO2022053037A1 (en) Method for increasing content and gene expression of aromatic substance in fruits and vegetables by using hydrogen rich water
CN106172421A (en) A kind of containing metconazole and the bactericidal composition of Tebuconazole and application
CN105638717A (en) Suspended seed coating agent and preparation method and application thereof
CN104488950A (en) Pyraclostrobin, phenazine-1-carboxylic acid and thiamethoxam containing suspension concentrate for seed coating as well as preparation method and application thereof
CN107581189B (en) Composition containing oligosaccharide and pyridine bactericidal components
CN109805017A (en) A kind of Fungicidal composition and its application
CN102302020B (en) Pesticidal disease-prevention suspending seed coating agent
CN102972448B (en) Disease-resistant composition, and application and suspended seed coating agent thereof
CN113057172A (en) Ternary compound seed dressing agent containing prothioconazole and fludioxonil
CN115886025B (en) A seed treatment agent containing pentocyclanil and clothianidin and application thereof
CN103931626B (en) Bactericidal composition containing chitosan oligosaccharide
CN100506040C (en) A drought-resistant, salt-alkali and multi-functional cotton seed coating agent
CN103988847B (en) Bactericidal composition containing chitosan oligosaccharide and dithiocyano-methane
CN109984152A (en) Composition containing oligosaccharides and fragrance
CN107372548A (en) Composition pesticide containing captan and fluorine azoles ring bacterium amine and application thereof
CN108157381A (en) Bactericidal composition containing captan and isopyrazam
CN114271276A (en) A kind of plant disease clear suspension agent and its preparation method and application
CN102396479A (en) 23% of tebuconazole-thiram suspension seed coating agent
CN114946864B (en) Synergistic bactericide containing cyprodinil, fludioxonil and terpineol and application thereof
CN115474608B (en) Composition for controlling Wuta-tsai diseases and application thereof
CN119344321B (en) A seed treatment suspension of cyprodinil + fludioxonil + thiamethoxam and its preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210702

RJ01 Rejection of invention patent application after publication