[go: up one dir, main page]

CN112757741A - Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof - Google Patents

Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof Download PDF

Info

Publication number
CN112757741A
CN112757741A CN202011631617.5A CN202011631617A CN112757741A CN 112757741 A CN112757741 A CN 112757741A CN 202011631617 A CN202011631617 A CN 202011631617A CN 112757741 A CN112757741 A CN 112757741A
Authority
CN
China
Prior art keywords
ammonia gas
layer
functional
film
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011631617.5A
Other languages
Chinese (zh)
Inventor
房婷玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Fulio Material Technology Co ltd
Original Assignee
Beijing Fulio Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Fulio Material Technology Co ltd filed Critical Beijing Fulio Material Technology Co ltd
Priority to CN202011631617.5A priority Critical patent/CN112757741A/en
Publication of CN112757741A publication Critical patent/CN112757741A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00—Protection of plants
    • A01G13/30—Ground coverings
    • A01G13/32—Mats; Nets; Sheets or films
    • A01G13/33—Sheets or films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0076—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised in that the layers are not bonded on the totality of their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/90—Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2410/00—Agriculture-related articles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fluid Mechanics (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明属于功能膜及其制备的技术领域，公开了一种阻截堆肥过程中氨气逸散的功能膜及其制备方法。该功能膜是通过选用纱织密度高的聚酯纤维牛津布或无纺布作为面料层的第一道防线，用来保护第二层高分子薄膜，避免薄膜磨损；选用适当厚度，孔径较小的膨体聚四氟乙烯薄膜等来提升防水透气性能；选用具有吸附未成型水凝液态水滴的气态氨气分子的活性炭无纺布作为吸附层经上胶热压复合工艺制备得到。该功能膜具有吸附少量随水蒸气及其他气体一同逸出的氨气，从而进一步提高功能性覆盖膜的阻氨性能。该功能膜制备膜工艺对未溶解于液态水的氨气分子进行二次阻隔，进一步减少了氨气逸散率。该功能膜适用于陈腐垃圾处理和土壤修复领域中防止氨气逸散的。

Figure 202011631617

The invention belongs to the technical field of functional membranes and preparations thereof, and discloses a functional membrane for intercepting the escape of ammonia gas in a composting process and a preparation method thereof. The functional film is used to protect the second layer of polymer film by using polyester fiber Oxford cloth or non-woven fabric with high yarn density as the first line of defense of the fabric layer to protect the second layer of polymer film and avoid film abrasion; appropriate thickness is selected, and the pore size is small. Activated carbon non-woven fabric with gaseous ammonia molecules that adsorb unformed hydraulic liquid water droplets is used as the adsorption layer to improve the waterproof and breathable performance. The functional film can adsorb a small amount of ammonia gas that escapes together with water vapor and other gases, thereby further improving the ammonia barrier performance of the functional covering film. The membrane preparation process of the functional membrane performs secondary barrier to the ammonia gas molecules that are not dissolved in the liquid water, and further reduces the ammonia gas escape rate. The functional film is suitable for preventing ammonia gas from escaping in the fields of stale garbage disposal and soil remediation.

Figure 202011631617

Description

Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof
Technical Field
The invention belongs to the technical field of functional films and preparation thereof, and particularly relates to a functional film for stopping ammonia gas dissipation in a composting process and a preparation method thereof.
Background
Garbage, this misplaced resource, is gaining increasing attention. The composting technology is taken as a current mainstream garbage treatment technology at home and abroad, not only makes up for a plurality of defects of the current garbage treatment method, but also researches show that decomposed products obtained after composting various garbage have the characteristics of high content of nutrient components, loose texture, no harmful germs and the like, are very suitable for urban landscaping and agricultural use, and have very good development prospects.
The Membrane Covering Technology (MCT) is a research topic that many researchers in related research fields pay attention to as the core of modern composting Technology, and how to effectively block odor emission in the composting process is a research hotspot of the Technology, and especially, emission control of ammonia gas is a key point. The ammonia gas barrier in the film covering technology is also researched at home and abroad: research sponsored by the federal foundation (DBU) and University of Stuttgart's institute from a germany show a relative 89.9% reduction in the total amount of odor emissions from modern forced-ventilated membrane-covered composting processes, relative to traditional open-ventilated composting processes for windrow composting. Lujihua considers that the membrane covering technology can effectively block odor, does not need a special deodorization system, and can save a large amount of investment and operation cost. The research on the ammonia blocking special effect of the functional covering film particularly carried out by Liguangkun and the like shows that the existence of the functional film can reduce the ammonia gas dissipation amount by about 57 percent, and meanwhile, the nitrogen content of the final compost product can be improved and a certain nitrogen fixing effect can be achieved.
Although the film covering technology has the function of blocking odor in the composting process, the existing research shows that the functional covering film has the diameter of 0.2-2.0 um micropores and has extremely limited blocking effect on ammonia molecules with the blocking molecular diameter of only 0.365-0.38 nm due to the limitation of the existing film making process; in addition, a part of ammonia gas which is not dissolved in liquid water and is escaped along with water vapor is not taken a secondary blocking measure.
Disclosure of Invention
In order to solve the problems in the prior art, the invention aims to provide a functional film for stopping the dissipation of ammonia gas in the composting process and a preparation method thereof.
The technical scheme adopted by the invention is as follows: the utility model provides a block functional membrane of compost in-process ammonia loss, functional membrane includes basic unit, function inoxidizing coating and adsorbed layer, be equipped with first adhesive linkage between basic unit and the function inoxidizing coating, be equipped with the second adhesive linkage between function inoxidizing coating and the adsorbed layer, basic unit, first adhesive linkage, function inoxidizing coating, second adhesive linkage and adsorbed layer are connected in order.
Preferably, the base layer comprises polyester oxford and/or non-woven fabric.
The polyester fiber oxford fabric is also called terylene oxford fabric. The characteristics of the terylene and the oxford are mixed, and the application range is wider. Terylene is an important variety in synthetic fibers and is the trade name of polyester fibers in China. It is made up by using refined terephthalic acid (PTA) or dimethyl terephthalate (DMT) and Ethylene Glycol (EG) as raw material, and making them pass through the processes of esterification, ester exchange and polycondensation reaction to obtain the fibre-forming high polymer polyethylene terephthalate (PET), spinning and post-treatment so as to obtain the invented fibre. Dacron has a wide range of applications and is used in a large number of articles of clothing and industry. The terylene has excellent setting performance. The flat and straight, fluffy or pleated shape and the like generated after the terylene yarn or the fabric is shaped can be kept for a long time after being washed for many times in use. The terylene has the characteristics of 1) high strength, and the impact strength is 4 times higher than that of the nylon and 20 times higher than that of the viscose fiber. 2) And the elasticity is good. The elasticity is close to that of wool, and the elastic fabric can be almost completely recovered when the elastic fabric is stretched by 5 to 6 percent. The wrinkle resistance is superior to other fibers, i.e. the fabric is not wrinkled and has good dimensional stability. The elasticity is 2-3 times higher than that of chinlon. 3) And the heat resistance is good. 4) And the water absorption is good. 5) And the wear resistance is good. The wear resistance is second to the best wear resistance chinlon, and is better than other natural fibers and synthetic fibers. 6) And the light resistance is good. The light fastness is next to acrylic fiber. 7) And corrosion resistance. Can resist bleaching agent, oxidant, hydrocarbon, ketone, petroleum product and inorganic acid. It is resistant to dilute alkali and mildew, but can be decomposed by hot alkali. 8) And the dyeing property is poor.
Nonwoven fabrics, also known as nonwovens, are composed of oriented or random fibers. It is called a cloth because of its appearance and certain properties. The non-woven fabric has the characteristics of moisture resistance, air permeability, flexibility, light weight, no combustion supporting, easy decomposition, no toxicity or irritation, rich color, low price, recycling and the like. For example, the polypropylene (pp material) granules are mostly adopted as raw materials and are produced by a continuous one-step method of high-temperature melting, spinning, laying a line and hot-pressing coiling.
Preferably, the gram weight of the base layer is 200 +/-10 g/m2。
Preferably, the functional protective layer comprises a high polymer film layer, and the high polymer film layer comprises an expanded polytetrafluoroethylene film layer.
Preferably, the thickness of the expanded polytetrafluoroethylene film layer is 30-35 μm; the aperture of the expanded polytetrafluoroethylene film layer is not more than 0.1 mu m.
Preferably, the adsorption layer comprises activated carbon non-woven fabric, and the gram weight of the adsorption layer is 150 +/-10 g/m2。
Preferably, the first adhesive layer comprises polyurethane hot melt adhesive and/or polyvinyl alcohol environment-friendly adhesive.
Preferably, the second adhesive layer includes any one of a polyurethane hot melt adhesive and a polyvinyl alcohol environmental protection adhesive.
Expanded polytetrafluoroethylene (expanded PTFE) is a novel medical polymer material and is prepared from polytetrafluoroethylene resin by special processing methods such as stretching and the like. White, rich in elasticity and flexibility, has a reticular structure formed by connecting microfine fibers, and the microfine fibers form countless pores, so that the expanded PTFE can be bent at will (over 360 degrees), and has good blood compatibility and biological aging resistance. The fiber membrane has the characteristics of high strength, low shrinkage, abrasion resistance and the like, and has extremely strong ultraviolet resistance, so that the fiber membrane has good stability and integrity in extreme environments. Such fibers are used in a wide variety of applications and may be woven, spun, braided or sewn into a variety of fabrics including compression wrap, sewing thread, construction fabric, dental floss, and the like. Has good chemical resistance and abrasion resistance, and extremely strong high temperature and low temperature resistance, and is very suitable for the transportation and sealing of industrial liquid.
Polyurethane hot melt adhesive, also called hot melt adhesive, is solid at room temperature, is heated to a certain temperature to be melted into viscous liquid, and becomes solid after being cooled to room temperature, and has strong adhesive effect. Has the advantages of high bonding speed, no toxicity, simple bonding process, better bonding strength and flexibility, and the like. Polyurethane hot melt adhesives can be divided into two categories: one is thermoplastic polyurethane elastomer hot melt adhesive, and the other is reactive polyurethane hot melt adhesive. The latter are again of the closed and moisture-curing hot-melt type. The blocking type is used only for maintenance treatment or the like because the dissociation temperature of the blocking agent is as high as 100 ℃ or higher, which causes bubbles to be generated in the adhesive layer. The moisture-curing hot-melt polyurethane adhesive is single-component and solvent-free, meets the environmental protection regulations and is convenient to use. The hot melt polyurethane adhesive is mainly characterized in that the function of hydrogen bonds in the composition is utilized to carry out physical crosslinking, so that the polyurethane hot melt adhesive has excellent elasticity and strength. The hot-melt polyurethane adhesive loses the hydrogen bond function after being heated, becomes molten viscous liquid, and recovers the original physical properties after being cooled. Therefore, the polyurethane hot melt adhesive has the characteristics of high bonding strength, solvent resistance, wear resistance and the like, has high use reliability, good chemical and physical uniformity, simple and convenient bonding process (reduced production cost), less waste (the unused adhesive can be stored and reused later), does not have mixing problem, and can ensure that the adhesive can achieve the optimal physical performance. In addition, because the hot melt adhesive does not use organic solvent, the production field can not be polluted, thereby being welcomed by users, being widely applied to the bonding of various materials and being particularly suitable for the bonding of fabrics.
The polyvinyl alcohol environment-friendly adhesive is a production method of a novel pollution-free quick-drying aqueous adhesive, and is applied to artificial board production to realize pollution-free cold pressing production of artificial boards.
A preparation method of a functional film for stopping ammonia gas dissipation in a composting process comprises the steps of carrying out gluing and hot-pressing composite forming on a base layer, an adhesive layer, a functional protective layer, the adhesive layer and an adsorption layer by a hot melting device, curing, solidifying and packaging to obtain a finished product.
Preferably, the temperature of the hot-pressing composite process is 130-140 ℃.
The invention has the beneficial effects that:
the invention provides a functional film for stopping ammonia gas dissipation in a composting process, which is characterized in that polyester fiber oxford cloth or non-woven fabric with high yarn weaving density is selected as a first defense line of a fabric layer to protect a second layer of high molecular film and avoid the abrasion of the film; the waterproof and air-permeable performance is improved by selecting an expanded polytetrafluoroethylene film with proper thickness and small aperture; the preparation method comprises the steps of selecting an activated carbon non-woven fabric with gaseous ammonia molecules for adsorbing unformed hydraulic liquid water drops as an adsorption layer, and preparing the activated carbon non-woven fabric through a gluing hot-pressing compounding process. The functional film can adsorb a small amount of ammonia gas which escapes along with water vapor and other gases, thereby further improving the ammonia resistance of the functional covering film. The functional film preparation process carries out secondary blocking on ammonia molecules which are not dissolved in liquid water, and further reduces the ammonia gas dissipation rate. The functional film is suitable for preventing ammonia gas from dissipating in the fields of stale waste treatment and soil remediation.
Drawings
FIG. 1 is a schematic structural diagram of example 1 provided by the present invention;
FIG. 2 is a schematic structural diagram of example 2 provided by the present invention;
FIG. 3 is a schematic structural diagram of example 3 provided by the present invention;
fig. 4 is a schematic structural diagram of embodiment 4 provided by the present invention.
In the figure: 1-polyester oxford; 2-polyurethane hot melt adhesive; 3-expanded polytetrafluoroethylene film; 4-activated carbon non-woven fabric; 5-non-woven fabrics; 6-polyvinyl alcohol environment-friendly glue.
Detailed Description
The present invention is further illustrated below with reference to specific examples. It will be appreciated by those skilled in the art that the following examples, which are set forth to illustrate the present invention, are intended to be part of the present invention, but not to be construed as limiting the scope of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. The examples were carried out under the conventional conditions, unless otherwise specified. The reagents used are all conventional products which are commercially available.
Example 1, as shown in figure 1:
a preparation method of a functional film for stopping ammonia dissipation in a composting process comprises the steps of adopting a hot melting device to carry out gluing and hot pressing composite forming on polyester fiber oxford cloth 1, polyurethane hot melt adhesive 2, expanded polytetrafluoroethylene film 3, polyvinyl alcohol environment-friendly glue 6 and activated carbon non-woven fabric 4 at 130 ℃ through a gluing and hot pressing composite process, curing and packaging to obtain a finished product.
In the above specific embodiment 1, the polyurethane hot melt adhesive 2 and the polyvinyl alcohol environment-friendly adhesive 10 adopt a whole cloth cover coating mode.
Example 2, as shown in fig. 2:
a preparation method of a functional film for stopping ammonia dissipation in a composting process comprises the steps of adopting a hot melting device to carry out gluing, hot pressing and compounding on polyester fiber oxford 1, polyurethane hot melt adhesive 2, an expanded polytetrafluoroethylene film 3, the polyurethane hot melt adhesive 2 and activated carbon non-woven fabric 4 at 140 ℃ for composite forming, curing, solidifying and packaging to obtain a finished product.
The polyurethane hot melt adhesive 2 in the above-mentioned embodiment 2 is applied by spot coating at equal intervals.
Example 3, as shown in fig. 3:
a preparation method of a functional film for stopping ammonia dissipation in a composting process comprises the steps of adopting a hot melting device to carry out compound molding on non-woven fabric 5, polyurethane hot melt adhesive 2, expanded polytetrafluoroethylene film 3, polyvinyl alcohol environment-friendly adhesive 6 and activated carbon non-woven fabric 4 at 130 ℃ through a gluing and hot-pressing compound process, curing, solidifying and packaging to obtain a finished product.
In the above specific embodiment 3, the polyurethane hot melt adhesive 2 and the polyvinyl alcohol environment-friendly adhesive 10 are applied at intervals.
Example 4, as shown in fig. 4:
a preparation method of a functional film for stopping ammonia dissipation in a composting process comprises the steps of adopting a hot melting device to carry out gluing, hot pressing and compounding on polyester fiber oxford 1, polyurethane hot melt adhesive 2, an expanded polytetrafluoroethylene film 3, the polyurethane hot melt adhesive 2 and activated carbon non-woven fabric 4 at 140 ℃ for composite forming, curing, solidifying and packaging to obtain a finished product.
The polyurethane hot melt adhesive 2 in the above specific embodiment 4 adopts a mode of coating the whole cloth surface.
The polyester fiber oxford fabric is made of a material with the gram weight of 200 +/-10 g/square meter and high warp density and weft density.
Expanded polytetrafluoroethylene film, manufacturer: hunan Senno fluorine materials science and technology, model: FLFZM001, cat no: FL015, width: 1650 mm.
Non-woven fabrics, manufacturer: shanghai stingchen clarification plant ltd, thickness: 0.2-0.4mm, weaving mode: and (5) plain weaving.
Polyurethane hot melt adhesive, manufacturer: the three-island new material company, Huizhou, has more than or equal to 95% of effective substances and the color: transparent, light yellow.
Polyvinyl alcohol environmental protection glue, manufacturer: henan stone spring chemical products, Inc., viscosity: 3 to 70 percent; the drying weight loss is less than or equal to 5.0.
Hot melt adhesive device, Shenzhen europe ricks science and technology Limited, power, 350W, spit out the frequency: 1-200 (times/min), type: OL-331R, air source: air compressor, minimum discharge: 0.02mL, discharge time adjustment: 0.1-9999 s.
Examples of the experiments
Selecting two stacks of aged garbage stacks with similar overall components (any garbage stack cannot keep complete component consistency, and the overall stacked raw materials are knowable). One as the experimental group and one as the control group.
The experimental group was covered with the functional film of example 1 described above, and the control group was covered with a polyethylene film (37075; city-singing plastics ltd, cat # cs4 x 6, thickness: 0.06 mm).
The experimental environment is as follows: the temperature and humidity of the environment of the experimental group and the control group are consistent. When the composting time was observed to be 12 hours and 48 hours, the amount of ammonia gas dissipated from the surface of the compost covering film was measured.
The detection of ammonia escape volume uses the portable ammonia detector of Shandun science and technology Limited, product model: uSafe 2000-NH3And (4) detecting, wherein the detection result data can be embodied on the display screen.
The initial ammonia concentration was set to 5.3ppm at the time of measurement as a standard for the ammonia content in the atmospheric environment.
The dissipation rate is (real-time detection data-initial data)/initial data × 100%.
The experimental results are as follows:
Figure RE-GDA0002962289180000071
the above experimental data show that the functional film prepared in the embodiment of the present invention has a significantly higher dissipation prevention capability when ammonia gas is dissipated than the control group.
The invention provides a functional film for stopping ammonia gas dissipation in a composting process, which is characterized in that polyester fiber oxford cloth or non-woven fabric with high weaving density is selected as a first defense line of a fabric layer to protect a second layer of high molecular film and avoid the abrasion of the film; the waterproof and air-permeable performance is improved by selecting an expanded polytetrafluoroethylene film with proper thickness and small aperture; the preparation method comprises the steps of selecting an activated carbon non-woven fabric with gaseous ammonia molecules for adsorbing unformed hydraulic liquid water drops as an adsorption layer, and preparing the activated carbon non-woven fabric through a gluing hot-pressing compounding process. The functional film can adsorb a small amount of ammonia gas which escapes along with water vapor and other gases, thereby further improving the ammonia resistance of the functional covering film. The functional film preparation process carries out secondary blocking on ammonia molecules which are not dissolved in liquid water, and further reduces the ammonia gas dissipation rate. The functional film is suitable for preventing ammonia gas from dissipating in the fields of stale waste treatment and soil remediation.
While particular embodiments of the present invention have been illustrated and described, it will be appreciated that the present invention is not limited to the above-described alternative embodiments, and that various other forms of product may be devised by anyone in light of the present invention. The foregoing detailed description should not be construed as limiting the scope of the invention, and it will be understood by those skilled in the art that modifications may be made to the technical solutions described in the foregoing embodiments, or that equivalent substitutions may be made to some or all of the technical features thereof, without departing from the spirit and scope of the invention, and that these modifications or substitutions may not substantially depart from the essence of the corresponding technical solutions.

Claims (10)

1. The utility model provides a block functional membrane of compost in-process ammonia loss, its characterized in that, functional membrane includes basic unit, function inoxidizing coating and adsorbed layer, be equipped with first adhesive linkage between basic unit and the function inoxidizing coating, be equipped with the second adhesive linkage between function inoxidizing coating and the adsorbed layer, basic unit, first adhesive linkage, function inoxidizing coating, second adhesive linkage and adsorbed layer connect in order.
2. The functional film for blocking the escape of ammonia gas during composting as claimed in claim 1, wherein said base layer comprises polyester oxford and/or non-woven fabric.
3. The functional film for stopping ammonia gas escape in composting as claimed in claim 2, wherein said base layer has a grammage of 200 ± 10g/m2。
4. The functional film for blocking ammonia gas escape in composting of claim 1 wherein said functional protective layer comprises a polymeric film layer comprising expanded polytetrafluoroethylene.
5. The functional film for stopping ammonia gas escape in the composting process as claimed in claim 4, wherein the thickness of the expanded polytetrafluoroethylene film layer is 30-35 μm; the aperture of the expanded polytetrafluoroethylene film layer is not more than 0.1 mu m.
6. The functional film for stopping ammonia gas escape in composting process as claimed in claim 1, wherein said absorbent layer comprises activated carbon non-woven fabric, and the grammage of said absorbent layer is 150 ± 10g/m2。
7. The functional film for blocking ammonia gas escape in a composting process as claimed in claim 1, wherein the first adhesive layer comprises polyurethane hot melt adhesive and/or polyvinyl alcohol environment-friendly adhesive.
8. The functional film for blocking ammonia gas escape in a composting process as claimed in claim 1, wherein the second adhesive layer comprises any one of polyurethane hot melt adhesive and polyvinyl alcohol environmental friendly adhesive.
9. The method for preparing a functional film for stopping ammonia gas dissipation in composting as claimed in any of claims 1-8, wherein the method comprises using a hot melting device to compound and form the base layer, the adhesive layer, the functional protective layer, the adhesive layer and the absorbent layer by gluing and hot pressing, curing and packaging to obtain the final product.
10. The method as claimed in claim 9, wherein the temperature of the thermo-compression process is 130-140 ℃.
CN202011631617.5A 2020-12-31 2020-12-31 Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof Pending CN112757741A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011631617.5A CN112757741A (en) 2020-12-31 2020-12-31 Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011631617.5A CN112757741A (en) 2020-12-31 2020-12-31 Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof

Publications (1)

Publication Number Publication Date
CN112757741A true CN112757741A (en) 2021-05-07

Family

ID=75699634

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011631617.5A Pending CN112757741A (en) 2020-12-31 2020-12-31 Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112757741A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117067737B (en) * 2023-08-14 2024-02-09 青岛中海环境工程有限公司 Polytetrafluoroethylene composite membrane for compost fermentation and processing technology thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130125757A1 (en) * 2009-07-22 2013-05-23 Donaldson Company, Inc. Filter media construction using ptfe film and carbon web for hepa efficiency and odor control
CN104191680A (en) * 2014-09-03 2014-12-10 青岛志腾工贸有限公司 Cover film material applied to solid waste composting fermentation process
CN204196386U (en) * 2014-09-18 2015-03-11 安徽宏远无纺布业有限公司 A kind of water proof nonwoven cloth that can absorb peculiar smell
CN104492162A (en) * 2014-12-03 2015-04-08 中材科技股份有限公司 Polytetrafluoroethylene microporous membrane composite filter screen for air purifier and preparation method of filter screen
CN109049909A (en) * 2018-07-27 2018-12-21 湖州森诺氟材料科技有限公司 The polytetrafluoroethylcomposite composite film and production technology of bacteriostasis, and deodorization
CN109160829A (en) * 2018-09-26 2019-01-08 秦皇岛领先康地农业技术有限公司 A kind of feces of livestock and poultry nanometer film aerobic composting device
CN208732947U (en) * 2018-05-22 2019-04-12 机科发展科技股份有限公司 The functional cover film of compost
WO2019189638A1 (en) * 2018-03-30 2019-10-03 東レ株式会社 Multilayer filter material
CN211493107U (en) * 2019-11-15 2020-09-15 广东雅丽斯佳新材料有限公司 Deodorization waterproof PVC weaves wall paper

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130125757A1 (en) * 2009-07-22 2013-05-23 Donaldson Company, Inc. Filter media construction using ptfe film and carbon web for hepa efficiency and odor control
CN104191680A (en) * 2014-09-03 2014-12-10 青岛志腾工贸有限公司 Cover film material applied to solid waste composting fermentation process
CN204196386U (en) * 2014-09-18 2015-03-11 安徽宏远无纺布业有限公司 A kind of water proof nonwoven cloth that can absorb peculiar smell
CN104492162A (en) * 2014-12-03 2015-04-08 中材科技股份有限公司 Polytetrafluoroethylene microporous membrane composite filter screen for air purifier and preparation method of filter screen
WO2019189638A1 (en) * 2018-03-30 2019-10-03 東レ株式会社 Multilayer filter material
CN208732947U (en) * 2018-05-22 2019-04-12 机科发展科技股份有限公司 The functional cover film of compost
CN109049909A (en) * 2018-07-27 2018-12-21 湖州森诺氟材料科技有限公司 The polytetrafluoroethylcomposite composite film and production technology of bacteriostasis, and deodorization
CN109160829A (en) * 2018-09-26 2019-01-08 秦皇岛领先康地农业技术有限公司 A kind of feces of livestock and poultry nanometer film aerobic composting device
CN211493107U (en) * 2019-11-15 2020-09-15 广东雅丽斯佳新材料有限公司 Deodorization waterproof PVC weaves wall paper

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117067737B (en) * 2023-08-14 2024-02-09 青岛中海环境工程有限公司 Polytetrafluoroethylene composite membrane for compost fermentation and processing technology thereof

Similar Documents

Publication Publication Date Title
CN102071539B (en) Double-layer water-adsorption and moisture-transfer non-woven fabric and preparation method thereof
EP0606362B1 (en) Sulfonated polyesters and their use in compostable products such as disposable diapers
CN201550655U (en) Antistatic antibiotic crease-resistance fabric
CN109572082B (en) Composite fiber membrane capable of being used for high-efficiency low-resistance anti-haze mask
CN108579212A (en) A kind of functionalized nano-fiber filtering material and its preparation method and application
CN105729918B (en) It is a kind of type of respiration one-way wet-guide protective materials and the application in textile product to be prepared
CN109433024A (en) Membrane material or aerogel material containing metal organic framework nanofiber and the preparation method and application thereof
CN102167895A (en) Preparation method of waste wool/polylactic acid ecological composite material
CN103590196A (en) Production method of high-adsorptivity melt-blow non-woven fabrics
CN107502990A (en) A kind of high water absorption moisture absorption polyester fiber, high water absorption Hygroscopic material and preparation and application
CN203305615U (en) Waterproof ventilated compound fabric
CN104831466B (en) A kind of manufacture method of the screen cloth for bedding
CN112757741A (en) Functional film for stopping ammonia gas dissipation in composting process and preparation method thereof
WO2025190250A1 (en) Nanofiber composite air purification filter material and preparation method therefor
CN111979645A (en) Bio-based polyester non-woven fabric and preparation method thereof
WO2015002555A1 (en) Biodegradable, combustible or noncombustible nonwoven, process of manufacture and use
CN112622389A (en) Waterproof antibacterial fabric and preparation method thereof
CN105029795A (en) Waterproof non-woven cloth
CN118238498B (en) Preparation method of high-elasticity quick-drying fabric
CN112709005A (en) Preparation method of high-oil-absorption melt-blown non-woven fabric
CN110055683B (en) Fly ash reinforced superfine fiber degradable non-woven material and preparation method thereof
CN112095230A (en) Super-soft super-fluffy spun-bonded non-woven fabric and preparation method thereof
CN113796605B (en) Medical protective clothing fabric resistant to repeated decontamination and protective clothing
CN105582744A (en) Silk nanofiber filtering material as well as preparation method and application thereof
CN117227288A (en) High-antistatic non-woven fabric of composite fiber and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20210507