CN111979645A - Bio-based polyester non-woven fabric and preparation method thereof - Google Patents
Bio-based polyester non-woven fabric and preparation method thereof Download PDFInfo
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- CN111979645A CN111979645A CN202010865055.4A CN202010865055A CN111979645A CN 111979645 A CN111979645 A CN 111979645A CN 202010865055 A CN202010865055 A CN 202010865055A CN 111979645 A CN111979645 A CN 111979645A
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- 229920000728 polyester Polymers 0.000 title claims abstract description 106
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 48
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 25
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 21
- 229920001634 Copolyester Polymers 0.000 claims abstract description 20
- 230000008569 process Effects 0.000 claims abstract description 17
- -1 succinic acid-pentanediol ester Chemical class 0.000 claims abstract description 17
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 14
- RKLJSFSLDCKWPH-UHFFFAOYSA-N C(CCCCC(=O)O)(=O)O.C(CCCC)(N)N Chemical compound C(CCCCC(=O)O)(=O)O.C(CCCC)(N)N RKLJSFSLDCKWPH-UHFFFAOYSA-N 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 12
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 12
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 claims abstract description 12
- 239000010453 quartz Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 13
- 239000003208 petroleum Substances 0.000 claims description 13
- 239000003963 antioxidant agent Substances 0.000 claims description 12
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 12
- 239000003017 thermal stabilizer Substances 0.000 claims description 12
- 238000009987 spinning Methods 0.000 claims description 9
- 239000001361 adipic acid Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 6
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 6
- 235000011037 adipic acid Nutrition 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 239000001384 succinic acid Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 6
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- XYZQXPSPSPYZHF-UHFFFAOYSA-N C(CCCC)(O)O.C(CCC(=O)O)(=O)O Chemical compound C(CCCC)(O)O.C(CCC(=O)O)(=O)O XYZQXPSPSPYZHF-UHFFFAOYSA-N 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 8
- 230000009172 bursting Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 230000036541 health Effects 0.000 abstract description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 6
- 239000002028 Biomass Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920004934 Dacron® Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012075 bio-oil Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- KJOMYNHMBRNCNY-UHFFFAOYSA-N pentane-1,1-diamine Chemical compound CCCCC(N)N KJOMYNHMBRNCNY-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
- D04H3/011—Polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
- D04H3/11—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a bio-based polyester non-woven fabric and a preparation method thereof, wherein the bio-based polyester non-woven fabric is prepared by a spunlace process of bio-based polyester filaments; the bio-based polyester filament is prepared from the following raw materials in parts by weight: 80-88 parts of bio-based succinic acid-pentanediol ester copolyester, 12-16 parts of bio-based poly (pentanediamine adipate), 6-9 parts of thermoplastic elastomer, 1.5-2.5 parts of carboxylated carbon nanotubes, 2-3.5 parts of quartz fibers, 3-5 parts of calcium carbonate, 0.8-1.2 parts of cerium dioxide and 5-7 parts of maleic anhydride grafted polypropylene. The invention has large bursting strength and breaking strength which are very close to the common PET non-woven fabric, good mechanical property, durability, good biodegradability, environmental protection, health and high use comfort; the composite material has good comprehensive mechanical property and good comprehensive use performance, and has wide market application prospect.
Description
Technical Field
The invention relates to the technical field of non-woven fabrics, in particular to a bio-based polyester non-woven fabric and a preparation method thereof.
Background
Nonwoven fabrics, also known as nonwovens, are composed of oriented or random fibers. It is called a cloth because of its appearance and certain properties. The non-woven fabric has no warp and weft, is very convenient to cut and sew, is light in weight and easy to shape, and is popular with hand fans.
Because it is a fabric formed without spinning a woven fabric, it is formed by orienting or randomly arranging textile staple fibers or filaments to form a web structure and then reinforcing them by mechanical, thermal or chemical means.
The fabric is not interwoven and knitted by yarns one by one, but the fibers are directly bonded together by a physical method, so that when a user takes the fabric into the clothes, the user can find that one thread end cannot be drawn out. The non-woven fabric breaks through the traditional spinning principle and has the characteristics of short process flow, high production rate, high yield, low cost, wide application, multiple raw material sources and the like.
Biomass belongs to plant-fixed solar energy, and billions of tons of biomass can be used for producing bio-oil every year in China; millions of tons of polyester garbage are generated in industry and daily life every year, and if the materials are not properly treated, the environment is polluted, and solar energy resources and petroleum resources are seriously wasted. Due to the advantages of abundant biomass resources, strong renewability, environmental improvement, sustainability, and material properties, the development and utilization of biomass resources are of great interest to scientists. The reasonable utilization of biomass energy can keep the carbon balance in nature, is not only beneficial to the development of agriculture, forestry and industry, but also has important significance for inhibiting greenhouse effect and protecting ecological environment.
Polyester fibers, commonly known as "dacron". The PET fiber is a synthetic fiber obtained by spinning polyester formed by polycondensation of organic dibasic acid and dihydric alcohol, is called PET fiber for short, and belongs to a high molecular compound. The polyester fiber has high strength, high modulus and low water absorption, and can be widely used as civil fabrics and industrial fabrics. The original defects of the polyester fiber, such as static phenomenon and difficult dyeing in textile processing, poor sweat absorption and air permeability, easy fusion into cavities when meeting sparks and the like, can be reduced and improved to a certain extent along with the mixing of the hydrophilic fiber.
However, the (polyester) nonwoven fabrics currently used have the following problems:
or the mechanical properties such as bursting strength, breaking strength and the like are poor and the cable is not durable; or can not be degraded and is not environment-friendly.
Disclosure of Invention
Based on the above situation, the present invention is directed to a bio-based polyester nonwoven fabric and a method for preparing the same, which can effectively solve the above problems.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
a bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
80-88 parts of bio-based succinic acid-pentanediol copolyester,
12-16 parts of bio-based poly (pentanediamine adipate),
6-9 parts of thermoplastic elastomer,
1.5-2.5 parts of carboxylated carbon nano tube,
2-3.5 parts of quartz fiber,
3-5 parts of calcium carbonate,
0.8 to 1.2 parts of cerium dioxide,
5-7 parts of maleic anhydride grafted polypropylene;
the bio-based poly (glutaric acid) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine, and can be prepared by a conventional method, which is not described herein again;
the bio-based succinic acid-pentanediol ester copolyester is prepared by polymerization reaction of petroleum-based succinic acid and bio-based 1, 5-pentanediol, and can be prepared by a conventional method, and details are not repeated here.
Preferably, the bio-based polyester filament is prepared from the following raw materials in parts by weight:
84 parts of bio-based succinic acid-pentanediol ester copolyester,
14 parts of bio-based poly (pentanediaminadipate),
7.5 parts of thermoplastic elastomer,
2 parts of carboxylated carbon nano tube,
2.7 parts of quartz fiber,
4 portions of calcium carbonate,
1 part of cerium dioxide,
6 parts of maleic anhydride grafted polypropylene.
Preferably, the thermoplastic elastomer is a polyamide-based thermoplastic elastomer.
Preferably, the bio-based polyester filament further comprises the following raw materials in parts by weight: thermal stabilizer: 3-4 parts.
Preferably, the heat stabilizer is 9005A-2. The heat stability of the bio-based polyester non-woven fabric prepared from the bio-based polyester filaments in the processing process can be better improved.
Preferably, the bio-based polyester filament further comprises the following raw materials in parts by weight: antioxidant: 3-4 parts.
Preferably, the antioxidant is 4426-S. Can better improve the oxidation and aging resistance of the bio-based polyester non-woven fabric prepared from the bio-based polyester filaments.
Preferably, the bio-based polyester filament further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: 3-4 parts.
Preferably, the ultraviolet light resisting agent is an ultraviolet absorbent UV-329. The ultraviolet aging resistance of the bio-based polyester non-woven fabric prepared from the bio-based polyester filaments can be better improved.
The invention also provides a preparation method of the bio-based polyester non-woven fabric, which comprises the following steps:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
D. the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
Compared with the prior art, the invention has the following advantages and beneficial effects:
the bio-based polyester non-woven fabric is prepared by selecting raw materials, optimizing the content of each raw material, selecting bio-based succinic acid-pentanediol ester copolyester, bio-based poly (pentanediamine adipate), a thermoplastic elastomer, a carboxylated carbon nanotube, quartz fiber, calcium carbonate, cerium dioxide, maleic anhydride grafted polypropylene and the like in a proper proportion, fully playing respective advantages, complementing and promoting each other, and compared with the common PET non-woven fabric, the prepared bio-based polyester non-woven fabric has the advantages of high bursting strength and breaking strength under the condition of the same thickness, is very close to the common PET non-woven fabric, has good mechanical property, durability, good biodegradation performance, environmental protection, health and high use comfort level; the composite material has good comprehensive mechanical property and good comprehensive use performance, and has wide market application prospect.
The bio-based polyester filament in the bio-based polyester non-woven fabric disclosed by the invention adopts bio-based succinic acid-pentanediol ester copolyester as a main raw material, and the mechanical properties such as strength and the like can be improved by adding a proper proportion of bio-based poly (pentanediamine adipate); and both are bio-based raw materials, have good air permeability and skin-friendly performance, and also have biodegradability and are environment-friendly.
The thermoplastic elastomer (preferably polyamide thermoplastic elastomer) with a proper proportion is added, the compatibility with the bio-based succinic acid-pentanediol ester copolyester and the bio-based poly-adipic acid pentanediamine is good, the mechanical properties such as strength and the like can be improved, and the thermoplastic elastomer and the components thereof are matched with each other to realize a good synergistic effect, so that the elasticity and the flexibility of the bio-based polyester non-woven fabric are greatly improved, and the use comfort is increased.
The carboxylated carbon nano tube with a proper proportion is added, has good compatibility with other raw materials, and can obviously improve the mechanical properties such as strength and the like.
And the mechanical properties such as strength and the like are further improved by adding the quartz fiber in a proper proportion.
The calcium carbonate with proper proportion is added to further play a role in enhancing and improving the mechanical properties such as strength and the like.
The cerium dioxide with a proper proportion is added, so that the cerium dioxide has a certain reinforcing effect, the mechanical properties such as strength and the like can be further improved, the cerium dioxide also has a certain crosslinking effect on the raw material system, a small amount of slow crosslinking can be promoted in the subsequent use process (illumination environment), the mechanical properties such as strength and the like, which are caused by aging and fracture of macromolecular chains such as bio-based succinic acid-pentanediol ester copolyester, bio-based poly (glutaric acid) and the like, are compensated to a certain extent, the service life is prolonged, and the mechanical properties such as strength and the like are kept good.
The maleic anhydride grafted polypropylene with a proper proportion is added as the compatilizer, so that the good compatibility of other raw materials in the invention is ensured, and the performance of the bio-based polyester non-woven fabric is ensured.
The preparation method has simple process and simple and convenient operation, and saves manpower and equipment cost.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
Example 1:
a bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
80-88 parts of bio-based succinic acid-pentanediol copolyester,
12-16 parts of bio-based poly (pentanediamine adipate),
6-9 parts of thermoplastic elastomer,
1.5-2.5 parts of carboxylated carbon nano tube,
2-3.5 parts of quartz fiber,
3-5 parts of calcium carbonate,
0.8 to 1.2 parts of cerium dioxide,
5-7 parts of maleic anhydride grafted polypropylene;
the bio-based poly (pentanediamine adipate) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine;
the bio-based succinic acid-pentanediol ester copolyester is prepared by carrying out polymerization reaction on petroleum-based succinic acid and bio-based 1, 5-pentanediol.
In this embodiment, the bio-based polyester filament is preferably made of the following raw materials in parts by weight:
84 parts of bio-based succinic acid-pentanediol ester copolyester,
14 parts of bio-based poly (pentanediaminadipate),
7.5 parts of thermoplastic elastomer,
2 parts of carboxylated carbon nano tube,
2.7 parts of quartz fiber,
4 portions of calcium carbonate,
1 part of cerium dioxide,
6 parts of maleic anhydride grafted polypropylene.
In the present embodiment, the thermoplastic elastomer is preferably a polyamide-based thermoplastic elastomer.
In this embodiment, the bio-based polyester filament preferably further comprises the following raw materials in parts by weight: thermal stabilizer: 3-4 parts.
In this example, the heat stabilizer is preferably a heat stabilizer 9005A-2.
In this embodiment, the bio-based polyester filament preferably further comprises the following raw materials in parts by weight: antioxidant: 3-4 parts.
In this embodiment, the antioxidant is preferably 4426-S.
In this embodiment, the bio-based polyester filament preferably further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: 3-4 parts.
In the present embodiment, the ultraviolet light resistant agent is preferably an ultraviolet absorber UV-329.
The embodiment also provides a preparation method of the bio-based polyester non-woven fabric, which comprises the following steps:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
D. the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
Example 2:
a bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
80 parts of bio-based succinic acid-pentanediol ester copolyester,
12 parts of bio-based poly (pentanediamine adipate),
6 parts of thermoplastic elastomer,
1.5 parts of carboxylated carbon nano tube,
2 parts of quartz fiber,
3 portions of calcium carbonate,
0.8 part of cerium dioxide,
5 parts of maleic anhydride grafted polypropylene;
the bio-based poly (pentanediamine adipate) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine;
the bio-based succinic acid-pentanediol ester copolyester is prepared by carrying out polymerization reaction on petroleum-based succinic acid and bio-based 1, 5-pentanediol.
In this embodiment, the thermoplastic elastomer is a polyamide-based thermoplastic elastomer.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: thermal stabilizer: and 3 parts.
In this example, the thermal stabilizer was thermal stabilizer 9005A-2.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: antioxidant: 4 parts.
In this example, the antioxidant is 4426-S.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: and 3 parts.
In the embodiment, the ultraviolet resisting agent is an ultraviolet absorbent UV-329.
In this embodiment, the method for preparing the bio-based polyester non-woven fabric includes the following steps:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
D. the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
Example 3:
a bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
88 parts of biobased succinic acid-pentanediol ester copolyester,
16 portions of bio-based poly (pentanediamine adipate),
9 parts of thermoplastic elastomer,
2.5 parts of carboxylated carbon nano tube,
3.5 parts of quartz fiber,
5 portions of calcium carbonate,
1.2 parts of cerium dioxide,
7 parts of maleic anhydride grafted polypropylene;
the bio-based poly (pentanediamine adipate) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine;
the bio-based succinic acid-pentanediol ester copolyester is prepared by carrying out polymerization reaction on petroleum-based succinic acid and bio-based 1, 5-pentanediol.
In this embodiment, the thermoplastic elastomer is a polyamide-based thermoplastic elastomer.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: thermal stabilizer: 4 parts.
In this example, the thermal stabilizer was thermal stabilizer 9005A-2.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: antioxidant: and 3 parts.
In this example, the antioxidant is 4426-S.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: 4 parts.
In the embodiment, the ultraviolet resisting agent is an ultraviolet absorbent UV-329.
In this embodiment, the method for preparing the bio-based polyester non-woven fabric includes the following steps:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
D. the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
Example 4:
a bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
84 parts of bio-based succinic acid-pentanediol ester copolyester,
14 parts of bio-based poly (pentanediaminadipate),
7.5 parts of thermoplastic elastomer,
2 parts of carboxylated carbon nano tube,
2.7 parts of quartz fiber,
4 portions of calcium carbonate,
1 part of cerium dioxide,
6 parts of maleic anhydride grafted polypropylene;
the bio-based poly (pentanediamine adipate) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine;
the bio-based succinic acid-pentanediol ester copolyester is prepared by carrying out polymerization reaction on petroleum-based succinic acid and bio-based 1, 5-pentanediol.
In this embodiment, the thermoplastic elastomer is a polyamide-based thermoplastic elastomer.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: thermal stabilizer: 3.5 parts.
In this example, the thermal stabilizer was thermal stabilizer 9005A-2.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: antioxidant: 3.5 parts.
In this example, the antioxidant is 4426-S.
In this embodiment, the bio-based polyester filament further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: 3.5 parts.
In the embodiment, the ultraviolet resisting agent is an ultraviolet absorbent UV-329.
In this embodiment, the method for preparing the bio-based polyester non-woven fabric includes the following steps:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
D. the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
The bio-based polyester nonwoven fabrics obtained in examples 2 to 4 of the present invention and the general PET nonwoven fabric were subjected to the performance test, and the test results are shown in table 1.
TABLE 1
As can be seen from the above table, compared with the common PET nonwoven fabric, the bio-based polyester nonwoven fabric of the present invention has the following advantages: under the condition of the same thickness, the bursting strength and the breaking strength are high, the material is very close to the common PET non-woven fabric, the mechanical property is good, and the material is durable.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.
Claims (10)
1. The bio-based polyester non-woven fabric is characterized in that the bio-based polyester non-woven fabric is prepared by carrying out a spunlace process on bio-based polyester filaments;
the bio-based polyester filament is prepared from the following raw materials in parts by weight:
80-88 parts of bio-based succinic acid-pentanediol copolyester,
12-16 parts of bio-based poly (pentanediamine adipate),
6-9 parts of thermoplastic elastomer,
1.5-2.5 parts of carboxylated carbon nano tube,
2-3.5 parts of quartz fiber,
3-5 parts of calcium carbonate,
0.8 to 1.2 parts of cerium dioxide,
5-7 parts of maleic anhydride grafted polypropylene;
the bio-based poly (pentanediamine adipate) is prepared by polymerizing bio-based adipic acid and petroleum-based 1, 5-pentanediamine;
the bio-based succinic acid-pentanediol ester copolyester is prepared by carrying out polymerization reaction on petroleum-based succinic acid and bio-based 1, 5-pentanediol.
2. The bio-based polyester nonwoven fabric according to claim 1, wherein the bio-based polyester filaments are made of raw materials comprising, by weight:
84 parts of bio-based succinic acid-pentanediol ester copolyester,
14 parts of bio-based poly (pentanediaminadipate),
7.5 parts of thermoplastic elastomer,
2 parts of carboxylated carbon nano tube,
2.7 parts of quartz fiber,
4 portions of calcium carbonate,
1 part of cerium dioxide,
6 parts of maleic anhydride grafted polypropylene.
3. The bio-based polyester nonwoven fabric according to claim 1, wherein the thermoplastic elastomer is a polyamide-based thermoplastic elastomer.
4. The bio-based polyester nonwoven fabric according to claim 1, wherein the bio-based polyester filament further comprises the following raw materials in parts by weight: thermal stabilizer: 3-4 parts.
5. The bio-based polyester nonwoven fabric according to claim 4, wherein the heat stabilizer is 9005A-2.
6. The bio-based polyester nonwoven fabric according to claim 1, wherein the bio-based polyester filament further comprises the following raw materials in parts by weight: antioxidant: 3-4 parts.
7. The bio-based polyester nonwoven fabric according to claim 6, wherein the antioxidant is 4426-S.
8. The bio-based polyester nonwoven fabric according to claim 1, wherein the bio-based polyester filament further comprises the following raw materials in parts by weight: anti-ultraviolet light agent: 3-4 parts.
9. The bio-based polyester nonwoven fabric according to claim 8, wherein the anti-UV agent is UV-329.
10. A method for preparing a bio-based polyester nonwoven fabric according to any one of claims 1 to 9, comprising the steps of:
A. weighing the raw materials of the bio-based polyester filament according to the parts by weight, drying and uniformly mixing for later use;
B. feeding the mixed raw materials into a double-screw extruder to be melted into a mixed melt;
C. the mixed melt enters a spinning machine, is sprayed out from a spinneret plate to form a strand silk, and is subjected to air blowing cooling, oiling, stretching shaping and winding to obtain the bio-based polyester filament;
the bio-based polyester filament is subjected to a spunlace process to prepare the bio-based polyester non-woven fabric.
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