CN112331566B - Lead frame surface roughness manufacturing equipment and manufacturing method - Google Patents
Lead frame surface roughness manufacturing equipment and manufacturing method Download PDFInfo
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- 230000003746 surface roughness Effects 0.000 title claims abstract description 185
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 116
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- 239000010949 copper Substances 0.000 claims abstract description 187
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- 229910052802 copper Inorganic materials 0.000 claims abstract description 180
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- 238000005516 engineering process Methods 0.000 claims abstract description 25
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/48—Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the groups H01L21/18 - H01L21/326 or H10D48/04 - H10D48/07
- H01L21/4814—Conductive parts
- H01L21/4821—Flat leads, e.g. lead frames with or without insulating supports
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/18—Electroplating using modulated, pulsed or reversing current
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/48—Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the groups H01L21/18 - H01L21/326 or H10D48/04 - H10D48/07
- H01L21/4814—Conductive parts
- H01L21/4821—Flat leads, e.g. lead frames with or without insulating supports
- H01L21/4835—Cleaning, e.g. removing of solder
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Lead Frames For Integrated Circuits (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
Description
技术领域Technical Field
本发明属于连续引线框架表面处理制造技术领域,具体涉及一种引线框架表面粗糙度的制造设备及制造方法。The invention belongs to the technical field of continuous lead frame surface treatment manufacturing, and in particular relates to a lead frame surface roughness manufacturing device and a manufacturing method.
背景技术Background Art
由高精密芯片和引线框架封装而成的精密集成电路是现代电子信息产业的重要核心电子产品。其中,引线框架的重要作用是支撑芯片、保护内部元件、连接外部电路,是集成电路中的关键材料。随着电子信息高新技术的迅速发展,产品向微型化、多功能和智能化发展。因此,促使引线框架材料向着引线节距微细化、高密度的方向发展。这不仅对引线框架材料的强度和导电性提出了更高的要求,而且对材料的加工性能也提出了更高的要求。例如,引线框架材料不允许出现擦伤、脱皮、氧化、水迹和外观颜色不均匀等缺陷。Precision integrated circuits made of high-precision chips and lead frames are important core electronic products in the modern electronic information industry. Among them, the important role of the lead frame is to support the chip, protect the internal components, and connect the external circuit. It is a key material in the integrated circuit. With the rapid development of electronic information high-tech, products are developing towards miniaturization, multi-function and intelligence. Therefore, the lead frame material is driven to develop in the direction of fine lead pitch and high density. This not only puts higher requirements on the strength and conductivity of the lead frame material, but also puts higher requirements on the processing performance of the material. For example, the lead frame material is not allowed to have defects such as scratches, peeling, oxidation, water marks and uneven appearance color.
半导体集成电路的引线框架材料制造方法以引线框架材料表面采用感光干膜热压工艺已经成为主流。近年来,随着半导体的高集成化,由于半导体封装基板和印刷布线基板电路的微细化发展,对引线框架材料表面质量的要求越来越高。也就是说,引线框架材料表面粗糙度是影响干膜热压工艺的重要因素,也是封装过程能否与封装材料紧密结合的关键要素。因此,研究开发引线框架材料表面的清洗生产设备成为十分重要的课题,特别是研究开发引线框架材料表面粗糙度的制造方法以及制造设备成为亟待解决的课题。The lead frame material manufacturing method for semiconductor integrated circuits has become the mainstream of using a photosensitive dry film hot pressing process on the lead frame material surface. In recent years, with the high integration of semiconductors, the requirements for the surface quality of lead frame materials have become increasingly higher due to the miniaturization of semiconductor packaging substrates and printed wiring substrate circuits. In other words, the surface roughness of the lead frame material is an important factor affecting the dry film hot pressing process, and it is also a key factor in whether the packaging process can be closely integrated with the packaging material. Therefore, the research and development of cleaning production equipment for the surface of lead frame materials has become a very important topic, especially the research and development of manufacturing methods and manufacturing equipment for the surface roughness of lead frame materials has become a topic that needs to be solved urgently.
专利文献1(CN 101864586 B):记载了将金属材料通过脱脂和酸洗进行前处理并烘干后,在金属材料的上下两面用感光膜通过热压处理后,用紫外光穿过特制的引线框架图案的模具对贴有感光膜引线框架进行曝光,并用显影溶液处理后进行蚀刻和电镀处理制备引线框架材料的方法。然而,该方法存在着感光膜与金属材料表面有结合不牢固的缺陷,导致电镀溶液浸入感光膜与金属之间的间隙而被电镀并导致蚀刻区域的微小部分没有被蚀刻或完全没被蚀刻去除的问题。Patent document 1 (CN 101864586 B): describes a method for preparing a lead frame material by pre-treating the metal material by degreasing and pickling and drying it, applying a photosensitive film to the upper and lower surfaces of the metal material by hot pressing, exposing the lead frame with the photosensitive film by ultraviolet light through a mold with a special lead frame pattern, and etching and electroplating the lead frame after treating it with a developing solution. However, this method has the defect that the photosensitive film is not firmly bonded to the surface of the metal material, resulting in the electroplating solution infiltrating the gap between the photosensitive film and the metal to be electroplated, and causing a small part of the etching area to not be etched or not be etched away at all.
专利文献2(JP 6406711 B2):叙述了片式引线框架的制造方法,第一镀层的步骤包括在金属板的正面和背面的预定位置依次形成Ni镀层,Pd镀层和Au镀层。第二镀层优选为形成Ag镀层的方法。然而,所述制造方法是片式生产工艺,存在生产效率低,产品质量不均匀的缺陷;此外,文中没有记载金属材料的清洗工艺流程。Patent document 2 (JP 6406711 B2): describes a method for manufacturing a chip lead frame, wherein the first plating step includes sequentially forming a Ni plating layer, a Pd plating layer, and an Au plating layer at predetermined positions on the front and back of a metal plate. The second plating layer is preferably a method for forming an Ag plating layer. However, the manufacturing method is a chip production process, which has the disadvantages of low production efficiency and uneven product quality; in addition, the document does not record the cleaning process of the metal material.
专利文献3(JP 4431860 B2):描述了表面粗化剂过氧化氢与硫酸体系对铜以及铜合金材料表面进行粗化提供引线框架材料的方法。但是,近年来,由于蚀刻图案的微细化,因此对金属材料表面与感光干膜热压结合强度的要求越来越高,表面粗化剂方法所提供的金属表面的结合强度不充分。此外,用该方法粗化后的铜表面具有非常容易氧化的缺陷。Patent document 3 (JP 4431860 B2): describes a method for roughening the surface of copper and copper alloy materials using a surface roughening agent hydrogen peroxide and sulfuric acid system to provide a lead frame material. However, in recent years, due to the miniaturization of etching patterns, the requirements for the hot pressing bonding strength between the metal material surface and the photosensitive dry film have become increasingly higher, and the bonding strength of the metal surface provided by the surface roughening agent method is insufficient. In addition, the copper surface roughened by this method has the defect of being very easy to oxidize.
专利文献4(JP 1997-298265 A):提出了在引线框架表面形成多层不同密度的镍镀层来提高与封装材料结合强度的技术。采用多层镍镀层的下层由形成平滑且致密的层的镍镀层形成,其上层由使垂直方向的晶体生长优先的脉冲镍镀层形成。但是,在该多镀层技术中,无法得到上部镍镀层的足够的表面粗糙度,致使与封装材料的结合力弱。因此,该技术存在着与封装材料结合强度不足的缺陷。Patent document 4 (JP 1997-298265 A): A technique for forming multiple layers of nickel plating with different densities on the surface of a lead frame to improve the bonding strength with a packaging material is proposed. The lower layer of the multi-layer nickel plating is formed by a nickel plating layer that forms a smooth and dense layer, and the upper layer is formed by a pulse nickel plating layer that prioritizes crystal growth in the vertical direction. However, in this multi-layer plating technology, it is impossible to obtain sufficient surface roughness of the upper nickel plating layer, resulting in weak bonding with the packaging material. Therefore, this technology has the defect of insufficient bonding strength with the packaging material.
专利文献5(JP 2004-339584 A):提供了在引线框架表面形成多种不同金属镀层提高与封装材料结合强度的技术。通过两种不同的镀镍条件先后镀上两种不同厚度的镍镀层并使其总厚度为1.0μm,再在其上进行0.03μm的钯镀层,并且在该钯镀层上进一步进行0.01μm的金镀层;虽然,在第二层镍的形成工艺中采用脉冲逆向电解技术得到适宜表面粗糙度的引线框架,能与封装材料的粘合强度达到各种产品规格要求。但是,表面电解析出的金是化学稳定性极高的贵金属,不会产生氧化使表面粗化,因此会使与封装材料结合性能降低;同时,多种不同金属镀层的引线框架的生产工艺要求高,使用的贵金属价格昂贵产品成本增加,在实际生产中难于实现。Patent document 5 (JP 2004-339584 A): Provides a technology for forming a plurality of different metal coatings on the surface of a lead frame to improve the bonding strength with the packaging material. Two nickel coatings of different thicknesses are successively plated under two different nickel plating conditions to make the total thickness of 1.0 μm, and then a 0.03 μm palladium coating is performed thereon, and a 0.01 μm gold coating is further performed on the palladium coating; although, in the process of forming the second layer of nickel, a pulse reverse electrolysis technology is used to obtain a lead frame with a suitable surface roughness, and the bonding strength with the packaging material can meet various product specification requirements. However, the gold electrolytically precipitated on the surface is a precious metal with extremely high chemical stability, and will not produce oxidation to roughen the surface, so it will reduce the bonding performance with the packaging material; at the same time, the production process requirements of the lead frame with multiple different metal coatings are high, and the precious metals used are expensive, which increases the product cost, and it is difficult to achieve in actual production.
专利文献1~5提供了多种引线框架的生产加工方法,然而文献1存在着感光干膜与引线框架材料表面有结合不牢固的缺陷,导致电镀溶液浸入感光膜与金属之间的间隙而被电镀并导致蚀刻区域的微小部分没有被蚀刻或完全没被蚀刻去除的问题;文献2存在生产效率低,产品质量不均匀的缺陷;此外,文中也没有记载金属材料的清洗工艺流程;文献3用化学药水进行表面粗化方法所提供的金属表面的结合强度不充分,另外,粗化后的引线框架材料表面具有非常容易氧化的缺陷。文献4存在多镀层技术中,无法得到足够的表面粗糙度,致使与封装材料的结合力弱;因此,该技术存在着与封装材料结合强度不足的缺陷。文献5存在多种不同贵金属镀层的引线框架与封装材料结合性能降低并且生产工艺要求高,使用的贵金属价格昂贵产品成本增加,在实际生产制造难于实现。Patent documents 1 to 5 provide a variety of lead frame production and processing methods. However, document 1 has the defect that the photosensitive dry film is not firmly bonded to the surface of the lead frame material, resulting in the electroplating solution penetrating the gap between the photosensitive film and the metal and being electroplated, resulting in a small part of the etching area not being etched or not being etched away at all; document 2 has the defects of low production efficiency and uneven product quality; in addition, the cleaning process of the metal material is not recorded in the text; document 3 uses a chemical solution to roughen the surface. The bonding strength of the metal surface provided is insufficient, and the roughened lead frame material surface has the defect of being very easy to oxidize. Document 4 has a multi-layer plating technology that cannot obtain sufficient surface roughness, resulting in weak bonding with the packaging material; therefore, this technology has the defect of insufficient bonding strength with the packaging material. Document 5 has a plurality of different precious metal plating lead frames with reduced bonding performance with the packaging material and high production process requirements. The precious metals used are expensive and the product cost increases, which is difficult to achieve in actual production and manufacturing.
以上所述问题是引线框架表面处理生产线制造行业亟待解决的重大课题。引线框架材料的带宽一般在100mm以上,甚至是带宽在300-400mm,而端子材料的带宽一般在20mm以下,针对宽度较高的引线框架材料进行表面处理要保证膜厚度均匀具有更高的难度。首先,在引线框架材料表面处理生产线的连续生产中要能满足以下要求:1)引线框架材料表面与感光干膜的结合要牢固;2)引线框架材料表面粗糙度要满足与封装材料的热压结合牢固,保证集成电路产品质量和生产效率;3)要解决引线框架产品质量不均匀的缺陷;4)引线框架材料表面粗糙度要满足与封装材料的热压结合牢固的同时,引线框架材料表面的电解铜膜厚也需要达到均匀化;5)需要解决化学药水粗化工艺的引线框架表面与感光干膜热压结合强度不足及材料表面有非常容易氧化的缺陷。6)要提供具有优异耐腐蚀性能的引线框架产品。The above-mentioned problems are major issues that need to be solved urgently in the lead frame surface treatment production line manufacturing industry. The bandwidth of the lead frame material is generally above 100mm, or even 300-400mm, while the bandwidth of the terminal material is generally below 20mm. It is more difficult to ensure uniform film thickness for surface treatment of lead frame materials with higher width. First of all, the following requirements must be met in the continuous production of the lead frame material surface treatment production line: 1) The lead frame material surface must be firmly bonded to the photosensitive dry film; 2) The surface roughness of the lead frame material must meet the requirements of firm hot-pressing bonding with the packaging material to ensure the quality and production efficiency of integrated circuit products; 3) The defect of uneven quality of lead frame products must be solved; 4) The surface roughness of the lead frame material must meet the requirements of firm hot-pressing bonding with the packaging material, and the thickness of the electrolytic copper film on the surface of the lead frame material must also be uniform; 5) The problem of insufficient hot-pressing bonding strength between the lead frame surface and the photosensitive dry film in the chemical solution roughening process and the defect that the material surface is very easy to oxidize must be solved. 6) Lead frame products with excellent corrosion resistance must be provided.
发明内容Summary of the invention
本发明旨在至少解决现有技术中存在的技术问题之一。The present invention aims to solve at least one of the technical problems existing in the prior art.
为此,本发明提出一种线框架表面粗糙度的制造设备,该线框架表面粗糙度的制造设备生产的引线框架材料的电解铜膜厚均匀性得到提高,增强了引线框架材料表面与感光干膜的结合强度,不仅具有优异的耐腐蚀性,与封装材料的优异粘合力,而且产品质量得到保障。该引线框架表面粗糙度的制造设备具有生产效率高、产品质量高、成品率高等优点。To this end, the present invention proposes a wire frame surface roughness manufacturing device, the lead frame material produced by the wire frame surface roughness manufacturing device has improved uniformity of electrolytic copper film thickness, enhanced bonding strength between the lead frame material surface and the photosensitive dry film, not only has excellent corrosion resistance, excellent adhesion with packaging materials, but also product quality is guaranteed. The lead frame surface roughness manufacturing device has the advantages of high production efficiency, high product quality, high yield rate, etc.
为此,本发明还提出一种线框架表面粗糙度的制造方法,该方法具有产品质量高、生产效率高等优点。To this end, the present invention also proposes a method for manufacturing the surface roughness of a wire frame, which has the advantages of high product quality and high production efficiency.
根据本发明第一方面实施例的引线框架表面粗糙度的制造设备,按生产工艺顺序从前至后依次设置有:放料装置、清洗装置、电解铜装置和收料装置,所述放料装置能够对料盘上的引线框架材料进行放料;所述清洗装置能够对引线框架材料进行清洗,去除表面杂质;所述收料装置能够将处理好的引线框架材料进行收卷;所述电解铜装置能够通过脉冲逆向电解技术对引线框架材料的表面粗糙度进行调控,所述电解铜装置包括:脉冲逆向电源,所述脉冲逆向电源能够输出脉冲正、反向电流和正、反向脉冲时间;电解铜工艺槽,所述电解铜工艺槽的数量为多个,所述引线框架材料可以从多个所述电解铜工艺槽穿过,所述引线框架材料不断向前移动形成移动路径;电解铜药水,所述电解铜药水设在所述电解铜工艺槽内,所述引线框架材料能够浸在所述电解铜药水中。According to the manufacturing equipment of the lead frame surface roughness of the embodiment of the first aspect of the present invention, the following are arranged in order from front to back in the production process sequence: a feeding device, a cleaning device, an electrolytic copper device and a material receiving device, wherein the feeding device can feed the lead frame material on the material tray; the cleaning device can clean the lead frame material and remove surface impurities; the material receiving device can reel up the processed lead frame material; the electrolytic copper device can regulate the surface roughness of the lead frame material by pulse reverse electrolysis technology, and the electrolytic copper device comprises: a pulse reverse power supply, which can output pulse positive and reverse currents and positive and reverse pulse times; an electrolytic copper process tank, wherein the number of the electrolytic copper process tanks is multiple, the lead frame material can pass through the multiple electrolytic copper process tanks, and the lead frame material continuously moves forward to form a moving path; an electrolytic copper solution, wherein the electrolytic copper solution is arranged in the electrolytic copper process tank, and the lead frame material can be immersed in the electrolytic copper solution.
根据本发明实施例的引线框架表面粗糙度的制造设备,主要由放料装置、清洗装置、电解铜装置和收料装置组成,通过清洗装置能够得到清洁的引线框架材料,在电解铜装置中采用脉冲逆向电解技术来调节控制引线框架材料表面的粗糙度,不仅能够增加Cu镀层的晶粒尺寸和表面粗糙度,使在引线框架材料和封装材料之间产生了很强的粘合效应,而且电解析出层中的诸如针孔之类的缺陷很少,具有良好的耐腐蚀性能。该设备生产的引线框架材料的电解铜膜厚均匀性得到提高,增强了引线框架材料表面与感光干膜的结合强度,不仅具有优异的耐腐蚀性,与封装材料的优异粘合力,而且产品质量得到保障。该引线框架表面粗糙度的制造设备具有生产效率高、产品质量高、成品率高等优点。The manufacturing equipment for the surface roughness of the lead frame according to the embodiment of the present invention is mainly composed of a discharge device, a cleaning device, an electrolytic copper device and a receiving device. The cleaning device can obtain clean lead frame materials. In the electrolytic copper device, pulse reverse electrolysis technology is used to adjust and control the surface roughness of the lead frame material, which can not only increase the grain size and surface roughness of the Cu plating layer, so that a strong bonding effect is generated between the lead frame material and the packaging material, but also there are few defects such as pinholes in the electrolytic deposition layer, and it has good corrosion resistance. The uniformity of the electrolytic copper film thickness of the lead frame material produced by the equipment is improved, and the bonding strength between the surface of the lead frame material and the photosensitive dry film is enhanced. It not only has excellent corrosion resistance and excellent adhesion with the packaging material, but also the product quality is guaranteed. The manufacturing equipment for the surface roughness of the lead frame has the advantages of high production efficiency, high product quality, and high yield rate.
根据本发明一个实施例,每个所述电解铜工艺槽内均设有两个电极板,两个所述电极板相对设置在所述引线框架材料的两侧,所述移动路径位于两个所述电极板之间。According to one embodiment of the present invention, two electrode plates are provided in each of the electrolytic copper process tanks. The two electrode plates are arranged opposite to each other on both sides of the lead frame material, and the moving path is located between the two electrode plates.
根据本发明一个实施例,电极板的表面积与浸在每个电解铜工艺槽中的所述引线框架材料的表面积比为5:1。According to one embodiment of the present invention, the ratio of the surface area of the electrode plate to the surface area of the lead frame material immersed in each electrolytic copper process tank is 5:1.
根据本发明一个实施例,所述电极板的形状形成为片面、网状或者异形状,每个所述电解铜工艺槽内的两个电极板为相同形状或者不同形状的组合。According to one embodiment of the present invention, the shape of the electrode plate is formed into a flat surface, a mesh or a special shape, and the two electrode plates in each of the electrolytic copper process tanks are the same shape or a combination of different shapes.
根据本发明第二方面实施例的引线框架表面粗糙度的制造设备,通过脉冲逆向电解技术对引线框架表面粗糙度进行调控,其特征在于,包括以下步骤:According to the second aspect of the present invention, the lead frame surface roughness manufacturing equipment is used to adjust the lead frame surface roughness by pulse reverse electrolysis technology, and is characterized in that it includes the following steps:
S1、分析测试引线框架表面粗糙度,计算得出引线框架表面粗糙度算数平均值;S1. Analyze and test the surface roughness of the lead frame, and calculate the arithmetic average of the surface roughness of the lead frame;
S2、将引线框架材料从放料机导出,进入电解脱脂槽清洗,然后再进入酸活化槽清洗,得到清洁的引线框架材料;S2, the lead frame material is led out from the unloading machine, enters the electrolytic degreasing tank for cleaning, and then enters the acid activation tank for cleaning to obtain a clean lead frame material;
S3、电解镀铜工段:根据电解铜表面粗糙度,确定脉冲逆向电源输出的脉冲正、反向电流和正、反向脉冲时间;S3, electrolytic copper plating section: according to the surface roughness of electrolytic copper, determine the pulse positive and reverse currents and the positive and reverse pulse times output by the pulse reverse power supply;
S4、将所述脉冲正、反向电流通过电极板施加在所述引线框架材料表面,并使施加在所述引线框架材料上的电流方向朝向电极板面;S4, applying the pulsed positive and reverse currents to the surface of the lead frame material through the electrode plate, and making the direction of the current applied to the lead frame material toward the electrode plate surface;
S5、开启脉冲逆向电源,预热后,控制施加正反向脉冲电流和所述正、反向脉冲时间按引线框架材料的移动路径依次经过多个电解铜工艺槽的处理后得到产品所需引线框架表面粗糙度。S5. Turn on the pulse reverse power supply, and after preheating, control the application of positive and reverse pulse currents and the positive and reverse pulse times according to the moving path of the lead frame material, and then pass through multiple electrolytic copper process tanks in sequence to obtain the lead frame surface roughness required for the product.
根据本发明一个实施例,电解铜表面粗糙度=产品所需引线框架材料表面粗糙度-引线框架材料表面粗糙度。According to one embodiment of the present invention, the surface roughness of electrolytic copper = the surface roughness of the lead frame material required for the product - the surface roughness of the lead frame material.
根据本发明一个实施例,所述电解铜表面粗糙度的算数平均值范围均为0.05μm~5.0μm。According to one embodiment of the present invention, the arithmetic mean value of the surface roughness of the electrolytic copper is in the range of 0.05 μm to 5.0 μm.
根据本发明一个实施例,所述脉冲逆向电源输出的脉冲正向电流范围为5A~500A,所述脉冲逆向电源输出的反向电流范围为20A~1000A。According to one embodiment of the present invention, the pulse forward current range of the pulse reverse power supply output is 5A-500A, and the reverse current range of the pulse reverse power supply output is 20A-1000A.
根据本发明一个实施例,所述脉冲逆向电源输出的脉冲正向脉冲时间可选范围为5ms~100ms;所述脉冲逆向电源输出的脉冲反向脉冲时间范围为1ms~30ms。According to one embodiment of the present invention, the pulse forward pulse time of the pulse reverse power supply output may be in the range of 5ms to 100ms; the pulse reverse pulse time of the pulse reverse power supply output may be in the range of 1ms to 30ms.
根据本发明一个实施例,所述电解铜工艺槽内设有电解铜药水,所述电解铜药水需要满足所述脉冲逆向电源输出的脉冲正、反向电流密度使用范围。According to one embodiment of the present invention, an electrolytic copper solution is provided in the electrolytic copper process tank, and the electrolytic copper solution needs to meet the use range of the pulse forward and reverse current density output by the pulse reverse power supply.
根据本发明一个实施例,脉冲正向电流密度范围为2A/dm2~70A/dm2,脉冲反向电流密度范围为5A/dm2~170A/dm2。According to one embodiment of the present invention, the pulse forward current density ranges from 2A/dm 2 to 70A/dm 2 , and the pulse reverse current density ranges from 5A/dm 2 to 170A/dm 2 .
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the present invention will be given in part in the following description and in part will be obvious from the following description, or will be learned through practice of the present invention.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
本发明的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present invention will become apparent and easily understood from the description of the embodiments in conjunction with the following drawings, in which:
图1是根据本发明实施例的引线框架表面粗糙度的制造方法的步骤流程图。FIG. 1 is a flowchart of a method for manufacturing surface roughness of a lead frame according to an embodiment of the present invention.
图2是引线框架表面处理的整体工艺流程图;FIG2 is an overall process flow chart of lead frame surface treatment;
图3是根据本发明实施例的引线框架表面粗糙度的制造方法的脉冲逆向电源输出波形图。FIG. 3 is a pulse reverse power output waveform diagram of a method for manufacturing surface roughness of a lead frame according to an embodiment of the present invention.
图4是根据本发明实施例的引线框架表面粗糙度的制造方法的引线框架材料表面粗糙度制造设备。FIG. 4 is a diagram of a lead frame material surface roughness manufacturing device according to a lead frame surface roughness manufacturing method according to an embodiment of the present invention.
图5是根据本发明实施例的引线框架表面粗糙度的制造方法的实施1连续引线框架材料。FIG. 5 is a diagram of a continuous lead frame material according to an embodiment of a method for manufacturing a lead frame surface roughness according to an embodiment of the present invention.
图6是根据本发明实施例的引线框架表面粗糙度的制造方法的引线框架材料表面粗糙度制造设备图。FIG. 6 is a diagram of a lead frame material surface roughness manufacturing device according to a lead frame surface roughness manufacturing method according to an embodiment of the present invention.
图7是根据本发明实施例的引线框架表面粗糙度的制造方法的实施2连续引线框架材料附图。FIG. 7 is a diagram of a continuous lead frame material according to an embodiment of a method for manufacturing a lead frame surface roughness according to an embodiment of the present invention.
图8是根据本发明实施例的引线框架表面粗糙度的制造方法的片式引线框架材料表面粗糙度的制造设备结构图。8 is a structural diagram of a manufacturing device for the surface roughness of a sheet lead frame material according to a method for manufacturing the surface roughness of a lead frame according to an embodiment of the present invention.
图9是根据本发明实施例的引线框架表面粗糙度的制造方法的实施3的片式引线框架材料结构图。FIG. 9 is a structural diagram of a sheet lead frame material according to Embodiment 3 of a method for manufacturing surface roughness of a lead frame according to an embodiment of the present invention.
附图标记:Reference numerals:
脉冲逆向电源300;脉冲逆向电源310-370;Pulse reverse power supply 300; Pulse reverse power supply 310-370;
连续引线框架材料200;Continuous lead frame material 200;
连续引线框架材料500;Continuous lead frame material 500;
连续引线框架材料700;Continuous lead frame material 700;
放料装置10;放料导轮11;进口处阴极导电13a;出口处阴极导电13b;Discharging device 10; discharging guide wheel 11; cathode conductive 13a at the inlet; cathode conductive 13b at the outlet;
电解铜工艺槽30;电解铜工艺槽30a-30g;Electrolytic copper process tank 30; Electrolytic copper process tanks 30a-30g;
电极板40;上阳极板40a;下阳极板40b;Electrode plate 40; upper anode plate 40a; lower anode plate 40b;
收料导轮50;收料装置51。Material collecting guide wheel 50; material collecting device 51.
具体实施方式DETAILED DESCRIPTION
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present invention, and cannot be understood as limiting the present invention.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of the present invention, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise", "axial", "radial", "circumferential" and the like indicate positions or positional relationships based on the positions or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the present invention. In addition, features defined as "first" and "second" may explicitly or implicitly include one or more of the features. In the description of the present invention, unless otherwise specified, "multiple" means two or more.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
下面参考附图具体描述根据本发明实施例的引线框架表面粗糙度的制造设备。The following describes in detail an apparatus for manufacturing the surface roughness of a lead frame according to an embodiment of the present invention with reference to the accompanying drawings.
如图4所示,根据本发明实施例的引线框架表面粗糙度的制造设备,包括:放料装置10、清洗装置、电解铜装置和收料装置51。As shown in FIG. 4 , the lead frame surface roughness manufacturing equipment according to the embodiment of the present invention includes: a material discharging device 10 , a cleaning device, a copper electrolysis device and a material receiving device 51 .
具体地,根据本发明实施例的引线框架表面粗糙度的制造设备,放料装置10能够对料盘上的引线框架材料进行放料;清洗装置能够对引线框架材料进行清洗,去除表面杂质;电解铜装置能够通过脉冲逆向电解技术对引线框架材料的表面粗糙度进行调控,包括:脉冲逆向电源300,脉冲逆向电源300能够输出脉冲正、反向电流和正、反向脉冲时间;电解铜工艺槽30,电解铜工艺槽30的数量为多个,引线框架材料可以从多个电解铜工艺槽30穿过,引线框架材料不断向前移动形成移动路径;电解铜药水,电解铜药水设在电解铜工艺槽30内,引线框架材料能够浸在电解铜药水中。收料装置51能够将处理好的引线框架材料进行收卷。Specifically, according to the lead frame surface roughness manufacturing equipment of the embodiment of the present invention, the discharge device 10 can discharge the lead frame material on the material tray; the cleaning device can clean the lead frame material to remove surface impurities; the electrolytic copper device can adjust the surface roughness of the lead frame material through pulse reverse electrolysis technology, including: a pulse reverse power supply 300, the pulse reverse power supply 300 can output pulse positive and reverse currents and positive and reverse pulse times; electrolytic copper process tanks 30, the number of electrolytic copper process tanks 30 is multiple, the lead frame material can pass through multiple electrolytic copper process tanks 30, and the lead frame material continuously moves forward to form a moving path; electrolytic copper solution, the electrolytic copper solution is set in the electrolytic copper process tank 30, and the lead frame material can be immersed in the electrolytic copper solution. The material collection device 51 can roll up the processed lead frame material.
根据本发明的一个实施例,每个电解铜工艺槽30内均设有两个电极板40,两个电极板40相对设置在引线框架材料的两侧,移动路径位于两个电极板40之间。该电极板40即为阳极板,电解铜工艺槽30的数量可以为多个,电解铜工艺槽30上设有延引线框架材料运行方向贯通的通道,引线框架材料可以从电解铜工艺槽30穿出。在脉冲逆向电源300的作用下,电解铜工艺槽30内发生电解作用,引线框架材料为阴极,两个电极板40相对设置在引线框架材料的两侧,可使引线框架材料两面都发生电解作用,根据电流方向的不同,引线框架材料表面能够析出铜或者剥离铜。According to one embodiment of the present invention, two electrode plates 40 are provided in each electrolytic copper process tank 30, and the two electrode plates 40 are arranged on both sides of the lead frame material in a relative manner, and the moving path is located between the two electrode plates 40. The electrode plate 40 is an anode plate, and the number of the electrolytic copper process tanks 30 can be multiple. The electrolytic copper process tanks 30 are provided with a channel extending along the running direction of the lead frame material, and the lead frame material can pass through the electrolytic copper process tanks 30. Under the action of the pulse reverse power supply 300, electrolysis occurs in the electrolytic copper process tank 30, the lead frame material is the cathode, and the two electrode plates 40 are arranged on both sides of the lead frame material in a relative manner, so that electrolysis can occur on both sides of the lead frame material. According to the different directions of the current, copper can be precipitated or stripped from the surface of the lead frame material.
进一步地,电极板40的表面积与浸在每个电解铜工艺槽30中的引线框架材料的表面积比为5:1,优选为3:1,更优选为2:1。在电解铜工艺槽30中,该电极板40即为阳极板,引线框架材料为阴极,也就是说要满足阳极材料面积与阴极材料面积比5:1的要求。Furthermore, the surface area ratio of the electrode plate 40 to the surface area of the lead frame material immersed in each electrolytic copper process tank 30 is 5:1, preferably 3:1, and more preferably 2:1. In the electrolytic copper process tank 30, the electrode plate 40 is the anode plate, and the lead frame material is the cathode, that is, the requirement of the ratio of the anode material area to the cathode material area of 5:1 must be met.
优选地,电极板40的形状形成为片面、网状或者异形状,每个电解铜工艺槽30内的两个电极板40为相同形状或者不同形状的组合。电极板40可采用可溶性金属和非可溶性金属的组合,也可采用在非可溶性电极板40,在电极板40表面电解贵金属。电极板40可以是平板弯曲成圆弧形、网状弯曲成圆弧形,只要可以满足电极板40的表面积与浸在每个电解铜工艺槽30中的引线框架材料的表面积比为5:1的要求即可。也就是说,两个电极板40的形状可以是不同形状的组合,可以一个是片状,另一个是异形状,也可以是一个为网状,另一个为片状,可以根据实际需求来设定其大小、形状及组合,具有很高的适用性。通过阳极大小和形状的调节,可以满足阳极材料面积与阴极材料面积比5:1的要求,使引线框架材料表面电解铜膜厚均匀性得到提高,产品质量得到保障,提高了引线框架表面处理生产线的生产效率。Preferably, the shape of the electrode plate 40 is formed into a sheet, a mesh or a special shape, and the two electrode plates 40 in each electrolytic copper process tank 30 are the same shape or a combination of different shapes. The electrode plate 40 can be a combination of soluble metals and insoluble metals, or a non-soluble electrode plate 40 can be used to electrolyze precious metals on the surface of the electrode plate 40. The electrode plate 40 can be a flat plate bent into an arc shape, or a mesh bent into an arc shape, as long as the surface area ratio of the electrode plate 40 to the surface area of the lead frame material immersed in each electrolytic copper process tank 30 is 5:1. In other words, the shape of the two electrode plates 40 can be a combination of different shapes, one can be a sheet and the other can be a special shape, or one can be a mesh and the other can be a sheet. The size, shape and combination can be set according to actual needs, and it has high applicability. By adjusting the size and shape of the anode, the requirement of a ratio of the anode material area to the cathode material area of 5:1 can be met, so that the uniformity of the electrolytic copper film thickness on the surface of the lead frame material is improved, the product quality is guaranteed, and the production efficiency of the lead frame surface treatment production line is improved.
其中需要说明的是,引线框架材料采用水平输送的方式通过电解铜工艺槽,因为引线框架材料的带宽相对于端子材料的带宽要大的多,竖直输送无法保证引线框架材料运行过程中的平稳性,进而影响表面粗糙度的处理。水平输送的方式更加的稳定,便于进行表面粗糙度的处理。It should be noted that the lead frame material is transported horizontally through the electrolytic copper process tank. Because the bandwidth of the lead frame material is much larger than that of the terminal material, vertical transportation cannot ensure the stability of the lead frame material during operation, which in turn affects the surface roughness treatment. The horizontal transportation method is more stable and convenient for surface roughness treatment.
由此,根据本发明实施例的引线框架表面粗糙度的制造设备,主要由放料装置10、清洗装置、电解铜装置和收料装置51组成,通过清洗装置能够得到清洁的引线框架材料,在电解铜装置中采用脉冲逆向电解技术来调节控制引线框架材料表面的粗糙度。该设备生产的引线框架材料的电解铜膜厚均匀性得到提高,增强了引线框架材料表面与感光干膜的结合强度,不仅具有优异的耐腐蚀性,与封装材料的优异粘合力,而且产品质量得到保障。该引线框架表面粗糙度的制造设备具有生产效率高、产品质量高、成品率高等优点。Therefore, the lead frame surface roughness manufacturing equipment according to the embodiment of the present invention is mainly composed of a discharge device 10, a cleaning device, an electrolytic copper device and a receiving device 51. The cleaning device can obtain clean lead frame materials, and the pulse reverse electrolysis technology is used in the electrolytic copper device to adjust and control the surface roughness of the lead frame material. The uniformity of the electrolytic copper film thickness of the lead frame material produced by the equipment is improved, and the bonding strength between the surface of the lead frame material and the photosensitive dry film is enhanced. It not only has excellent corrosion resistance and excellent adhesion with the packaging material, but also the product quality is guaranteed. The lead frame surface roughness manufacturing equipment has the advantages of high production efficiency, high product quality, and high yield rate.
需要说明的是,电极板40也为阳极板,阳极板包括上阳极板40a和下阳极板40b。It should be noted that the electrode plate 40 is also an anode plate, and the anode plate includes an upper anode plate 40a and a lower anode plate 40b.
下面参考附图具体描述根据本发明实施例的引线框架表面粗糙度的制造方法。The method for manufacturing the surface roughness of a lead frame according to an embodiment of the present invention will be described in detail below with reference to the accompanying drawings.
如图1和图2所示,根据本发明实施例的引线框架表面粗糙度的制造方法,通过脉冲逆向电解技术对引线框架表面粗糙度进行调控,包括以下步骤:As shown in FIG. 1 and FIG. 2 , the method for manufacturing the surface roughness of a lead frame according to an embodiment of the present invention regulates the surface roughness of the lead frame by pulse reverse electrolysis technology, and includes the following steps:
S1、分析测试引线框架表面粗糙度,计算得出引线框架表面粗糙度算数平均值;S1. Analyze and test the surface roughness of the lead frame, and calculate the arithmetic average of the surface roughness of the lead frame;
S2、将引线框架材料从放料机导出,进入电解脱脂槽清洗,然后再进入酸活化槽清洗,得到清洁的引线框架材料;S2, the lead frame material is led out from the unloading machine, enters the electrolytic degreasing tank for cleaning, and then enters the acid activation tank for cleaning to obtain a clean lead frame material;
S3、电解镀铜工段:根据电解铜表面粗糙度,确定脉冲逆向电源300输出的脉冲正、反向电流和正、反向脉冲时间;S3, electrolytic copper plating section: according to the surface roughness of electrolytic copper, the pulse positive and reverse currents and the positive and reverse pulse times output by the pulse reverse power supply 300 are determined;
S4、将脉冲正、反向电流通过电极板40施加在引线框架材料表面,并使施加在引线框架材料上的电流方向朝向电极板40面;S4, applying pulsed positive and reverse currents to the surface of the lead frame material through the electrode plate 40, and making the direction of the current applied to the lead frame material toward the surface of the electrode plate 40;
S5、开启脉冲逆向电源300,预热后,控制施加正反向脉冲电流和正、反向脉冲时间按引线框架材料的移动路径依次经过多个电解铜工艺槽30的处理后得到产品所需引线框架表面粗糙度。S5. Turn on the pulse reverse power supply 300. After preheating, control the application of positive and reverse pulse currents and the positive and reverse pulse times according to the moving path of the lead frame material. After being processed in multiple electrolytic copper process tanks 30 in sequence, the lead frame surface roughness required for the product is obtained.
换言之,根据本发明实施例的引线框架表面粗糙度的制造方法,通过脉冲逆向电解技术对引线框架表面粗糙度进行调控,通过分析测试引线框架表面粗糙度,可以得出电解铜表面粗糙度,即电解铜表面粗糙度Ra1=产品所需引线框架材料表面粗糙度Ra2-引线框架材料表面粗糙度Ra。根据电解铜表面粗糙度,可确定脉冲逆向电源300输出的脉冲正、反向电流和正、反向脉冲时间的最佳组合。In other words, according to the manufacturing method of the lead frame surface roughness of the embodiment of the present invention, the surface roughness of the lead frame is regulated by the pulse reverse electrolysis technology, and the surface roughness of the electrolytic copper can be obtained by analyzing and testing the surface roughness of the lead frame, that is, the surface roughness Ra1 of the electrolytic copper = the surface roughness Ra2 of the lead frame material required for the product - the surface roughness Ra of the lead frame material. According to the surface roughness of the electrolytic copper, the optimal combination of the pulsed positive and reverse currents and the positive and reverse pulse times output by the pulse reverse power supply 300 can be determined.
首先,引线框架材料从放料10导出通过放料导轮11后,进入电解脱脂槽清洗除去金属材料表面的油脂等,然后进入酸活化槽清洗除去金属材料表面的锈斑及氧化物等,得到清洁的引线框架材料。然后进入电解镀铜工段,在电解铜工艺槽30内,电极板40为阳极,在电解铜药水中的引线框架材料为阴极,脉冲逆向电源300作用下发生电解作用,引线框架材料表面的粗糙度发生改变。具体地,施加的正、反向脉冲电流和正、反向脉冲时间不同,引线框架材料表面发生的电解作用也就不同。First, the lead frame material is led out from the discharge 10 and passes through the discharge guide wheel 11, and then enters the electrolytic degreasing tank to clean and remove the grease on the surface of the metal material, and then enters the acid activation tank to clean and remove the rust and oxide on the surface of the metal material to obtain a clean lead frame material. Then it enters the electrolytic copper plating section. In the electrolytic copper process tank 30, the electrode plate 40 is the anode, and the lead frame material in the electrolytic copper solution is the cathode. Electrolysis occurs under the action of the pulse reverse power supply 300, and the roughness of the surface of the lead frame material changes. Specifically, the applied positive and reverse pulse currents and the positive and reverse pulse times are different, and the electrolysis occurring on the surface of the lead frame material is also different.
也就是说,在脉冲逆向电解铜工艺中,由脉冲逆向电源300输出的施加在引线框架的电流进行周期性变化。当脉冲逆向电源300施加正向脉冲电流时,在引线框架表面上电解析出铜,呈现脉冲正向波形;当脉冲逆向电源300施加逆向脉冲电流时,引线框架材料表面电解剥离铜,则呈现脉冲逆向波形。当脉冲逆向电源300的反复周期性变化后,引线框架材料表面不断地析出铜和剥离铜,通过设置不同的正、反向脉冲时间,可以控制引线框架材料表面析出铜和剥离铜的多少,从而改变铜膜厚度,具体地,当正向脉冲时间较长时,引线框架材料表面析出铜较多,铜膜厚度相对较厚,当反向脉冲时间较长时,引线框架材料表面剥离铜较多,铜膜厚度将会变薄。不仅可以实现Cu镀层的厚度均匀,也可以根据不同要求来实现引线框架材料表面粗糙度的不同。通过逆向脉冲电流电解剥离铜的同时,可以去除引线框架表面Cu镀层中吸收的氢原子,消除了由于铜层中含有的氢原子所导致的Cu镀层的脆性,并且改善了诸如弯曲的可加工性。That is to say, in the pulse reverse electrolytic copper process, the current applied to the lead frame output by the pulse reverse power supply 300 changes periodically. When the pulse reverse power supply 300 applies a forward pulse current, copper is electrolytically precipitated on the surface of the lead frame, presenting a pulse forward waveform; when the pulse reverse power supply 300 applies a reverse pulse current, copper is electrolytically stripped from the surface of the lead frame material, presenting a pulse reverse waveform. After the repeated periodic changes of the pulse reverse power supply 300, copper is continuously precipitated and stripped from the surface of the lead frame material. By setting different forward and reverse pulse times, the amount of copper precipitated and stripped from the surface of the lead frame material can be controlled, thereby changing the thickness of the copper film. Specifically, when the forward pulse time is longer, more copper is precipitated on the surface of the lead frame material, and the copper film thickness is relatively thick. When the reverse pulse time is longer, more copper is stripped from the surface of the lead frame material, and the copper film thickness will become thinner. Not only can the thickness of the Cu plating layer be uniform, but also the surface roughness of the lead frame material can be different according to different requirements. By electrolytically stripping copper with a reverse pulse current, hydrogen atoms absorbed in the Cu plating layer on the surface of the lead frame can be removed, eliminating the brittleness of the Cu plating layer caused by hydrogen atoms contained in the copper layer and improving workability such as bending.
另外,脉冲逆向电解铜工艺中,容易形成粒径大的Cu结晶粒子。在施加逆向脉冲电流时,晶粒的粒径越小则优先被电解剥离;这是由于,晶粒的粒径越小,则表面自由能越高,越不稳定的缘故。如图3所示,当通过使用这种周期性地逆向极性的电流波形交替且重复地施加正向脉冲电流和逆向脉冲电流时,形成了具有大晶粒的粗铜表面。因此,在引线框架和封装材料之间产生很强的结合效应,因而可以获得很强的封装材料粘合性能。In addition, in the pulse reverse electrolytic copper process, Cu crystal particles with large grain size are easily formed. When the reverse pulse current is applied, the smaller the grain size, the more it is electrolytically stripped; this is because the smaller the grain size, the higher the surface free energy and the more unstable it is. As shown in Figure 3, when the forward pulse current and the reverse pulse current are applied alternately and repeatedly by using this periodically reversed polarity current waveform, a rough copper surface with large grains is formed. Therefore, a strong bonding effect is generated between the lead frame and the packaging material, so that a strong packaging material bonding performance can be obtained.
也就是说,当进行脉冲逆向电源300电解铜工艺时,金属铜在晶体的外延生长中比在晶核的生成中Cu的析出更快,增加了Cu镀层的晶粒尺寸和表面粗糙度。由于这种不规则形状的、粗糙的表面形态,在引线框架材料和封装材料之间产生了很强的粘合效应,因而获得的封装材料具有很强的粘合性能。周期性地逆向极性的电流波形交替且重复地施加正向脉冲电流和逆向脉冲电流时,电解析出铜层中由于氢吸收而引起的应变和杂质的混合比通常的直流电解析出铜中层的应变和杂质的混合较小。因此,电解析出层中的诸如针孔之类的缺陷很少,可以获得优异的耐腐蚀性。通过本发明的引线框架材料表面粗糙度的制造方法及制造设备代替化学药水粗化工艺,能大幅度提高引线框架表面处理的生产效率并且产品质量有极大的提高;通过引线框架材料表面粗糙度的调节及控制,扩大了引线框架在后续实际应用的范围,提高了产品质量合格率。That is to say, when the pulse reverse power supply 300 electrolytic copper process is carried out, the precipitation of metal copper in the epitaxial growth of the crystal is faster than that in the generation of the crystal nucleus, which increases the grain size and surface roughness of the Cu plating layer. Due to this irregular shape and rough surface morphology, a strong bonding effect is generated between the lead frame material and the packaging material, so that the obtained packaging material has a strong bonding performance. When the current waveform of periodically reversed polarity alternately and repeatedly applies the forward pulse current and the reverse pulse current, the strain and impurity mixing caused by hydrogen absorption in the electrolytic copper layer are smaller than the strain and impurity mixing in the layer of the conventional direct current electrolytic copper. Therefore, there are few defects such as pinholes in the electrolytic deposition layer, and excellent corrosion resistance can be obtained. By replacing the chemical solution roughening process with the manufacturing method and manufacturing equipment of the lead frame material surface roughness of the present invention, the production efficiency of the lead frame surface treatment can be greatly improved and the product quality is greatly improved; by adjusting and controlling the surface roughness of the lead frame material, the scope of subsequent practical applications of the lead frame is expanded, and the product quality qualification rate is improved.
由此,根据本发明实施例的引线框架表面粗糙度的制造方法,通过脉冲逆向电解技术实施电解铜工艺,不仅能够增加Cu镀层的晶粒尺寸和表面粗糙度,使在引线框架材料和封装材料之间产生了很强的粘合效应,而且电解析出层中的诸如针孔之类的缺陷很少,具有良好的耐腐蚀性能。该方法能够代替化学药水粗化工艺,能大幅度提高引线框架表面处理的生产效率并且电解铜膜均匀性得到提高,产品质量得到保障。通过对引线框架材料表面粗糙度的调节及控制,扩大了引线框架在后续实际应用的范围,提高了产品质量合格率。Therefore, according to the manufacturing method of the lead frame surface roughness of the embodiment of the present invention, the electrolytic copper process is implemented by pulse reverse electrolysis technology, which can not only increase the grain size and surface roughness of the Cu plating layer, so that a strong bonding effect is generated between the lead frame material and the packaging material, but also there are few defects such as pinholes in the electrolytic deposition layer, and it has good corrosion resistance. This method can replace the chemical solution roughening process, can greatly improve the production efficiency of the lead frame surface treatment, and the uniformity of the electrolytic copper film is improved, and the product quality is guaranteed. By adjusting and controlling the surface roughness of the lead frame material, the scope of the lead frame in subsequent practical applications is expanded, and the product quality qualification rate is improved.
很据本发明的一个实施例,电解铜表面粗糙度Ra1=产品所需引线框架材料表面粗糙度Ra2-引线框架材料表面粗糙度Ra。脉冲逆向电源300输出的脉冲正、反向电流和正、反向脉冲时间的设定和调节与电解铜表面粗糙度的分布以及电解铜表面粗糙度的算数平均值息息相关,所以电解铜表面粗糙度的确定对脉冲逆向电解技术对引线框架表面粗糙度进行调控起到很大的作用。According to one embodiment of the present invention, the surface roughness Ra1 of the electrolytic copper = the surface roughness Ra2 of the lead frame material required for the product - the surface roughness Ra of the lead frame material. The setting and adjustment of the pulsed positive and reverse currents and the positive and reverse pulse times output by the pulsed reverse power supply 300 are closely related to the distribution of the surface roughness of the electrolytic copper and the arithmetic mean of the surface roughness of the electrolytic copper. Therefore, the determination of the surface roughness of the electrolytic copper plays a great role in regulating the surface roughness of the lead frame by the pulsed reverse electrolysis technology.
进一步地,电解铜表面粗糙度、产品所需引线框架材料表面粗糙度、引线框架材料表面粗糙度的算数平均值范围均为0.05μm~5.0μm。Furthermore, the surface roughness of the electrolytic copper, the surface roughness of the lead frame material required for the product, and the arithmetic average of the surface roughness of the lead frame material are all in the range of 0.05 μm to 5.0 μm.
可选地,脉冲逆向电源300输出的脉冲正向电流范围为5A~500A,脉冲逆向电源300输出的反向电流范围为20A~1000A。Optionally, the pulse forward current range of the pulse reverse power supply 300 is 5A to 500A, and the reverse current range of the pulse reverse power supply 300 is 20A to 1000A.
进一步地,脉冲逆向电源300输出的脉冲正向脉冲时间可选范围为5ms~100ms;脉冲逆向电源300输出的脉冲反向脉冲时间范围为1ms~30ms。Furthermore, the pulse forward pulse time output by the pulse reverse power supply 300 can be selected in the range of 5ms to 100ms; the pulse reverse pulse time output by the pulse reverse power supply 300 can be selected in the range of 1ms to 30ms.
在本发明的一些具体实施方式中,电解铜工艺槽30内设有电解铜药水,电解铜药水需要满足脉冲逆向电源300输出的脉冲正、反向电流密度使用范围。In some specific embodiments of the present invention, electrolytic copper solution is provided in the electrolytic copper process tank 30 , and the electrolytic copper solution needs to meet the use range of the pulse forward and reverse current density output by the pulse reverse power supply 300 .
可选地,脉冲正向电流密度范围为2A/dm2~70A/dm2,脉冲反向电流密度范围为5A/dm2~170A/dm2。脉冲逆向电源300输出电流A=电解铜药水电流密度A/dm2×材料表面积dm2;脉冲正向电流密度优选范围5A/dm2~60A/dm2,更优选范围10A/dm2~50A/dm2;脉冲反向电流密度优选范围10A/dm2~160A/dm2,更优选范围20A/dm2~150A/dm2。Optionally, the pulse forward current density ranges from 2A/dm 2 to 70A/dm 2 , and the pulse reverse current density ranges from 5A/dm 2 to 170A/dm 2 . The pulse reverse power supply 300 outputs a current A=electrolytic copper solution current density A/dm 2 ×material surface area dm 2 ; the pulse forward current density preferably ranges from 5A/dm 2 to 60A/dm 2 , and more preferably ranges from 10A/dm 2 to 50A/dm 2 ; the pulse reverse current density preferably ranges from 10A/dm 2 to 160A/dm 2 , and more preferably ranges from 20A/dm 2 to 150A/dm 2 .
根据本发明的一个实施例,每个电解铜工艺槽30内均设有两个电极板40,两个电极板40相对设置在引线框架材料的两侧,移动路径位于两个电极板40之间。该电极板40即为阳极板,电解铜工艺槽30的数量可以为多个,电解铜工艺槽30上设有延引线框架材料运行方向贯通的通道,引线框架材料可以从电解铜工艺槽30穿出。在脉冲逆向电源300的作用下,电解铜工艺槽30内发生电解作用,引线框架材料为阴极,两个电极板40相对设置在引线框架材料的两侧,可使引线框架材料两面都发生电解作用,根据电流方向的不同,引线框架材料表面能够析出铜或者剥离铜。According to one embodiment of the present invention, two electrode plates 40 are provided in each electrolytic copper process tank 30, and the two electrode plates 40 are arranged on both sides of the lead frame material in a relative manner, and the moving path is located between the two electrode plates 40. The electrode plate 40 is an anode plate, and the number of the electrolytic copper process tanks 30 can be multiple. The electrolytic copper process tanks 30 are provided with a channel extending along the running direction of the lead frame material, and the lead frame material can pass through the electrolytic copper process tanks 30. Under the action of the pulse reverse power supply 300, electrolysis occurs in the electrolytic copper process tank 30, the lead frame material is the cathode, and the two electrode plates 40 are arranged on both sides of the lead frame material in a relative manner, so that electrolysis can occur on both sides of the lead frame material. According to the different directions of the current, copper can be precipitated or stripped from the surface of the lead frame material.
进一步地,电极板40的表面积与浸在每个电解铜工艺槽30中的引线框架材料的表面积比为5:1,优选为3:1,更优选为2:1。在电解铜工艺槽30中,该电极板40即为阳极板,引线框架材料为阴极,也就是说要满足阳极材料面积与阴极材料面积比5:1的要求。Furthermore, the surface area ratio of the electrode plate 40 to the surface area of the lead frame material immersed in each electrolytic copper process tank 30 is 5:1, preferably 3:1, and more preferably 2:1. In the electrolytic copper process tank 30, the electrode plate 40 is the anode plate, and the lead frame material is the cathode, that is, the requirement of the ratio of the anode material area to the cathode material area of 5:1 must be met.
可选地,电极板40的形状形成为片面、网状或者异形状。电极板40可采用可溶性金属和非可溶性金属的组合,也可采用在非可溶性电极板40,在电极板40表面电解贵金属。电极板40可以是平板弯曲成圆弧形、网状弯曲成圆弧形,只要可以满足电极板40的表面积与浸在每个电解铜工艺槽30中的引线框架材料的表面积比为5:1的要求即可。Optionally, the shape of the electrode plate 40 is formed into a single surface, a mesh or a special shape. The electrode plate 40 can be a combination of a soluble metal and an insoluble metal, or a noble metal can be electrolyzed on the surface of the electrode plate 40 by using an insoluble electrode plate 40. The electrode plate 40 can be a flat plate bent into an arc shape, or a mesh bent into an arc shape, as long as the surface area ratio of the electrode plate 40 to the surface area of the lead frame material immersed in each electrolytic copper process tank 30 is 5:1.
优选地,每个电解铜工艺槽30内的两个电极板40为相同形状或者不同形状的组合。也就是说,两个电极板40的形状可以是不同形状的组合,可以一个是片状,另一个是异形状,也可以是一个为网状,另一个为片状,可以根据实际需求来设定其大小、形状及组合,具有很高的适用性。通过阳极大小和形状的调节,可以满足阳极材料面积与阴极材料面积比5:1的要求,使引线框架材料表面电解铜膜厚均匀性得到提高,产品质量得到保障,提高了引线框架表面处理生产线的生产效率。Preferably, the two electrode plates 40 in each electrolytic copper process tank 30 are of the same shape or a combination of different shapes. That is to say, the shape of the two electrode plates 40 can be a combination of different shapes, one can be sheet-shaped and the other can be of a different shape, or one can be mesh-shaped and the other can be sheet-shaped, and the size, shape and combination can be set according to actual needs, which has high applicability. By adjusting the size and shape of the anode, the requirement of a ratio of the anode material area to the cathode material area of 5:1 can be met, so that the uniformity of the electrolytic copper film thickness on the surface of the lead frame material is improved, the product quality is guaranteed, and the production efficiency of the lead frame surface treatment production line is improved.
由此,通过该引线框架表面粗糙度的制造方法进行生产能够满足以下要求:1)引线框架材料表面与感光干膜的结合要牢固;2)引线框架材料表面粗糙度要满足与封装材料的热压结合牢固,保证集成电路产品质量和生产效率;3)要解决引线框架产品质量不均匀的缺陷;4)引线框架材料表面粗糙度要满足与封装材料的热压结合牢固的同时,引线框架材料表面的电解铜膜厚也需要达到均匀化;5)需要解决化学药水粗化工艺的引线框架表面与感光干膜热压结合强度不足及材料表面有非常容易氧化的缺陷。6)要提供具有优异耐腐蚀性能的引线框架产品。Therefore, the production by the manufacturing method of the lead frame surface roughness can meet the following requirements: 1) The lead frame material surface must be firmly bonded to the photosensitive dry film; 2) The lead frame material surface roughness must meet the requirements of firmly bonding with the packaging material by hot pressing to ensure the quality and production efficiency of integrated circuit products; 3) The defect of uneven quality of lead frame products must be solved; 4) The lead frame material surface roughness must meet the requirements of firmly bonding with the packaging material by hot pressing, and the thickness of the electrolytic copper film on the lead frame material surface must also be uniform; 5) The defect of insufficient hot pressing bonding strength between the lead frame surface and the photosensitive dry film in the chemical roughening process and the defect that the material surface is very easy to oxidize must be solved. 6) A lead frame product with excellent corrosion resistance must be provided.
总而言之,通过脉冲逆向电源300为基础的脉冲逆向电解技术、选择型金属阳极、阳极大小和形状的调节和脉冲电解用铜药水三要素,是实现为集成电路产业提供高品质和高性能引线框架材料及不断挑战高端引线框架生产制造技术的重要基础。不仅能够使引线框架材料表面电解铜膜厚均匀性得到提高,具有优异的耐腐蚀性,对封装材料的优异粘合力,而且产品质量得到保障,提高了引线框架表面处理生产线的生产效率。In summary, the three elements of pulse reverse electrolysis technology based on pulse reverse power supply 300, selective metal anode, adjustment of anode size and shape, and copper solution for pulse electrolysis are the important foundation for providing high-quality and high-performance lead frame materials for the integrated circuit industry and continuously challenging high-end lead frame production and manufacturing technology. Not only can the uniformity of electrolytic copper film thickness on the surface of lead frame materials be improved, with excellent corrosion resistance and excellent adhesion to packaging materials, but also the product quality is guaranteed, and the production efficiency of the lead frame surface treatment production line is improved.
其中需要说明的是,本发明的引线框架材料可以是金属材料,金属材料可以是由铜、镍、钴、钨、钼、铬和锌当中所选择的任意一个单体或铜、镍、钴、磷、钨、砷、钼、铬和锌当中所选择的任意两种或两种以上组成的合金;也可以是铁及其铁合金,还可以是各种不锈钢材料;所有金属材料可以是连续带材,也可以是连续引线框架材料。除此之外,凡是表面附有金属箔的材料都可以通过本发明的制造方法和制造设备进行表面粗糙度的生产加工;例如,各种塑料薄膜的单面或者双面附有金属薄膜的材料都可以制造所需求的表面粗糙度材料;It should be noted that the lead frame material of the present invention can be a metal material, and the metal material can be any single body selected from copper, nickel, cobalt, tungsten, molybdenum, chromium and zinc, or an alloy composed of any two or more selected from copper, nickel, cobalt, phosphorus, tungsten, arsenic, molybdenum, chromium and zinc; it can also be iron and its iron alloys, and can also be various stainless steel materials; all metal materials can be continuous strips or continuous lead frame materials. In addition, all materials with metal foil on the surface can be processed by the manufacturing method and manufacturing equipment of the present invention for surface roughness production; for example, various plastic films with metal films on one or both sides can be used to manufacture the required surface roughness materials;
金属材料可选宽度范围10mm~1000mm;金属材料可选厚度范围0.03mm~0.30mm;金属材料表面粗糙度的算数平均值可选范围0.06μm~2.0μmThe optional width range of metal materials is 10mm~1000mm; the optional thickness range of metal materials is 0.03mm~0.30mm; the arithmetic mean value of the surface roughness of metal materials can be selected from 0.06μm~2.0μm
下面通过具体实施例及对比实施例使本专业技术人员更全面的理解本发明,但并不因此将本发明限制在的实施例范围之中。The following specific examples and comparative examples will enable those skilled in the art to more fully understand the present invention, but the present invention is not limited to the scope of the embodiments.
【金属材料】【Metal materials】
本发明的引线框架材料可以是金属材料,金属材料可以是由铜、镍、钴、钨、钼、铬和锌当中所选择的任意一个单体或铜、镍、钴、磷、钨、砷、钼、铬和锌当中所选择的任意两种或两种以上组成的合金;也可以是铁及其铁合金,还可以是各种不锈钢材料;所有金属材料可以是连续带材,也可以是连续引线框架材料。除此之外,凡是表面附有金属箔的材料都可以通过本发明的制造方法和制造设备进行表面粗糙度的生产加工;例如,各种塑料薄膜的单面或者双面附有金属薄膜的材料都可以制造所需求的表面粗糙度材料;The lead frame material of the present invention can be a metal material, which can be any single material selected from copper, nickel, cobalt, tungsten, molybdenum, chromium and zinc, or an alloy composed of any two or more selected from copper, nickel, cobalt, phosphorus, tungsten, arsenic, molybdenum, chromium and zinc; it can also be iron and its iron alloy, or various stainless steel materials; all metal materials can be continuous strips or continuous lead frame materials. In addition, all materials with metal foil on the surface can be processed by the manufacturing method and manufacturing equipment of the present invention; for example, various plastic films with metal films on one or both sides can be used to manufacture the required surface roughness materials;
金属材料可选宽度范围10mm~1000mm;金属材料可选厚度范围0.03mm~0.30mm;The optional width range of metal materials is 10mm~1000mm; the optional thickness range of metal materials is 0.03mm~0.30mm;
金属材料表面粗糙度的算数平均值可选范围0.1μm~10.0μm。The arithmetic mean value of the surface roughness of the metal material can be selected in the range of 0.1μm to 10.0μm.
【感光干膜】【Photosensitive dry film】
感光干膜表面与金属材料表面进行热压处理,得到粘合坚固、表面质量均匀的贴膜金属材料。感光干膜原材料的厚度可选范围:20~60μm;感光干膜原材料表面粗糙度可选范围:0.75~1.87μm;金属材料与感光干膜贴合后的材料厚度可选范围:0.05~0.36mm;感光干膜一侧粗糙度可选范围:0.85~2.35μm;The surface of the photosensitive dry film and the surface of the metal material are heat-pressed to obtain a film-bonded metal material with strong adhesion and uniform surface quality. The thickness of the raw material of the photosensitive dry film can be selected in the range of 20 to 60 μm; the surface roughness of the raw material of the photosensitive dry film can be selected in the range of 0.75 to 1.87 μm; the thickness of the material after the metal material and the photosensitive dry film are laminated can be selected in the range of 0.05 to 0.36 mm; the roughness of one side of the photosensitive dry film can be selected in the range of 0.85 to 2.35 μm;
【电解铜药水】【Electrolytic copper solution】
所采用的电解铜药水要能满足:正向电流密度可选范围2A/dm2~70A/dm2;反向电流密度可选范围5A/dm2~170A/dm2;电解铜药水在正向电流条件下对引线框架材料表面能电解析出铜而在逆向电流条件下对引线框架材料表面能电解剥离铜的特殊要求。The electrolytic copper solution used must be able to meet the following requirements: the forward current density can be in the range of 2A/dm 2 to 70A/dm 2 ; the reverse current density can be in the range of 5A/dm 2 to 170A/dm 2 ; the electrolytic copper solution must be able to electrolytically separate copper from the surface of the lead frame material under forward current conditions and to electrolytically strip copper from the surface of the lead frame material under reverse current conditions.
实施例1Example 1
(1)表面粗糙度的分析测定(1) Analysis and measurement of surface roughness
如图5所示,原材料铜带C19400,宽度350mm,厚度0.12mm。用形状测量检测仪VK-X系列分析测试粗糙度Ra为0.08~0.15μm,多组数据计算出平均值为0.11μm。As shown in Figure 5, the raw material copper strip C19400 has a width of 350 mm and a thickness of 0.12 mm. The roughness Ra is 0.08 to 0.15 μm when analyzed and tested by the shape measuring instrument VK-X series. The average value calculated from multiple sets of data is 0.11 μm.
(2)根据选用的感光干膜的热压贴膜要求,金属材料表面粗糙度范围Ra为1.3~1.5μm。(2) According to the requirements of hot pressing of the selected photosensitive dry film, the surface roughness range of the metal material Ra is 1.3 to 1.5 μm.
(3)脉冲逆向电解技术制造材料的表面粗糙度Ra=(1.2~1.5μm)-(0.08~0.15μm),即生产加工粗糙度范围Ra为1.12~1.35μm。(3) The surface roughness of the material manufactured by pulse reverse electrolysis technology is Ra = (1.2~1.5μm)-(0.08~0.15μm), that is, the production and processing roughness range Ra is 1.12~1.35μm.
(4)根据产品生产加工要求,对金属材料进行双面粗糙度表面处理。(4) According to the product production and processing requirements, the metal material is subjected to double-sided roughness surface treatment.
(5)引线框架材料表面粗糙度的制造(5) Manufacturing of surface roughness of lead frame materials
如图1所示,首先,金属原材料从放料10导出通过放料导轮11后,进入电解脱脂槽清洗除去金属材料表面的油脂等,然后进入酸活化槽清洗除去金属材料表面的锈斑及氧化物等,得到清洁的金属材料。As shown in Figure 1, first, the metal raw material is discharged from the discharge 10 and passes through the discharge guide wheel 11, and then enters the electrolytic degreasing tank to clean and remove grease on the surface of the metal material, and then enters the acid activation tank to clean and remove rust and oxides on the surface of the metal material to obtain a clean metal material.
然后,在第一电解铜工艺槽30a,引线框架材料的上下两侧设有上阳极板40a和下阳极板40b与脉冲逆向电源310的阳极输出连接;进口处阴极导电13a和出口处阴极导电13b与脉冲逆向电源310的阴极输出连接。第二电解铜区域至第七镀铜区域的连接方式与第一电解铜区域的连接方式相同。如图1和图4所示。Then, in the first electrolytic copper process tank 30a, upper and lower anode plates 40a and lower anode plates 40b are provided on the upper and lower sides of the lead frame material and connected to the anode output of the pulse reverse power supply 310; the cathode conductive 13a at the inlet and the cathode conductive 13b at the outlet are connected to the cathode output of the pulse reverse power supply 310. The connection method from the second electrolytic copper area to the seventh copper plating area is the same as the connection method of the first electrolytic copper area, as shown in Figures 1 and 4.
如表1所示,由于原材料铜带宽度350mm,表面积较大,并且产品需要的引线框架材料表面粗糙度Ra 1.30~1.50μm与原材料粗糙度Ra 0.08~0.15μm相比差距较大,优选7单元的电解铜工艺进行表面粗糙度的处理;将七台脉冲逆向电源310至370的制造引线框架表面粗糙度的总额度设为21等分,每一等分的表面粗糙度为0.06~0.07μm;例如实验条件No.1的脉冲逆向电源310占15份,处理后需要达到的表面粗糙度范围Ra 0.92~1.07μm,脉冲逆向电源320至370的6台脉冲逆向电源300各占1份,用每台脉冲逆向电源300处理后,材料表面粗糙度都要满足Ra 0.06~0.07μm。As shown in Table 1, since the raw material copper strip width is 350 mm, the surface area is large, and the surface roughness Ra 1.30-1.50 μm of the lead frame material required by the product is quite different from the raw material roughness Ra 0.08-0.15 μm, it is preferred to use a 7-unit electrolytic copper process for surface roughness treatment; the total amount of surface roughness of the lead frame manufactured by seven pulse reverse power supplies 310 to 370 is set to 21 equal parts, and the surface roughness of each part is 0.06-0.07 μm; for example, the pulse reverse power supply 310 of experimental condition No. 1 accounts for 15 parts, and the surface roughness range Ra 0.92-1.07 μm is required after treatment, and the 6 pulse reverse power supplies 300 of pulse reverse power supplies 320 to 370 each account for 1 part, and after treatment with each pulse reverse power supply 300, the surface roughness of the material must meet Ra 0.06-0.07 μm.
引线框架材料表面粗糙度制造生产线的运行速度优选为1.5m/min。当7台脉冲逆向电源300采用表1中条件No.7时,7次电解铜层粗糙度的范围均在0.18~0.21μm,即7台脉冲逆向电源300所设定的正反向脉冲电流和正反向脉冲时间条件相同,所得到的从最下层到表层的表面粗糙度以及致密度相差很小,引线框架材料表面特性均匀一致。The running speed of the lead frame material surface roughness manufacturing production line is preferably 1.5 m/min. When the 7 pulse reverse power supplies 300 adopt condition No. 7 in Table 1, the roughness of the 7 electrolytic copper layers is in the range of 0.18 to 0.21 μm, that is, the forward and reverse pulse currents and forward and reverse pulse time conditions set by the 7 pulse reverse power supplies 300 are the same, and the surface roughness and density obtained from the bottom layer to the surface layer are very small, and the surface characteristics of the lead frame material are uniform.
当采用条件No.1时,脉冲逆向电源310需要设定较大正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值要小,反向脉冲时间的设定需较短;得到的电解铜粗糙度较大而且致密度较差;随后六台脉冲逆向电源320至370的设定条件与条件No.7比较是较小的正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值与条件No.7相比稍大,反向脉冲时间要比No.7短很多;因此所得到的表面粗糙度在达到产品规格的同时,与条件No.7相比表面致密度较好。When condition No. 1 is adopted, the pulse reverse power supply 310 needs to set a larger forward pulse current and a longer forward pulse time, while the setting value of the reverse pulse current should be smaller and the reverse pulse time should be shorter; the electrolytic copper obtained has a larger roughness and a poorer density; the setting conditions of the subsequent six pulse reverse power supplies 320 to 370 are smaller forward pulse currents and longer forward pulse times compared with condition No. 7, while the setting value of the reverse pulse current is slightly larger than that of condition No. 7, and the reverse pulse time is much shorter than that of No. 7; therefore, the surface roughness obtained meets the product specifications and has a better surface density than condition No. 7.
当采用条件No.2至No.6时,引线框架材料表面粗糙度在达到要求的同时,致密度范围在条件No.1和No.7之间。When conditions No. 2 to No. 6 are adopted, the surface roughness of the lead frame material meets the requirements and the density range is between conditions No. 1 and No. 7.
当采用条件No.13时,六台脉冲逆向电源310至360需要设定较小的正向脉冲电流和较长的正向脉冲时间,而设定大的反向脉冲电流和很短的反向脉冲时间;得到的镀铜层粗糙度较小并且致密度较好。最后一台脉冲逆向电源370的设定条件是较大的正向脉冲电流和较长的正向脉冲时间,而设定较大的反向脉冲电流和较短的反向脉冲时间,因此所得到的表面粗糙度在达到产品规格的同时,与条件No.7相比表面致密度较差。When condition No.13 is adopted, the six pulse reverse power supplies 310 to 360 need to set a smaller forward pulse current and a longer forward pulse time, and set a large reverse pulse current and a very short reverse pulse time; the resulting copper plating layer has a smaller roughness and better density. The setting conditions of the last pulse reverse power supply 370 are a larger forward pulse current and a longer forward pulse time, and a larger reverse pulse current and a shorter reverse pulse time, so the surface roughness obtained meets the product specifications, but the surface density is poorer than that of condition No.7.
当采用条件No.8至No.12时,引线框架材料表面粗糙度在达到要求的同时,致密度处在条件No.7和No.13之间。When conditions No. 8 to No. 12 are adopted, the surface roughness of the lead frame material meets the requirements and the density is between conditions No. 7 and No. 13.
引线框架表面粗糙度用形状测量检测仪VK-X系列分析测试。引线框架粗铜材料用作后续镀银的原料,必须能够与镀银层形成致密坚固的结合层是判断引线框架表面规格的标准。The surface roughness of the lead frame is analyzed and tested using the VK-X series shape measurement tester. The lead frame raw copper material is used as the raw material for subsequent silver plating, and must be able to form a dense and solid bonding layer with the silver plating layer, which is the standard for judging the surface specifications of the lead frame.
用感光干膜验证引线框架材料表面粗糙度和致密度的效果。Use photosensitive dry film to verify the effect of surface roughness and density on lead frame materials.
当选定感光干膜的品牌和型号后,用形状测量检测仪VK-X系列分析测试粗糙度Ra为1.3~1.85μm,多组数据平均值Ra为1.58μm;与上述制造的金属材料通过压膜机进行热压后的表面粗糙度规格范围1.57~1.93μm。以此规格范围作为检查标准,将上述各种条件生产制造的金属材料与感光干膜压热的产品经过形状测量检测仪VK-X检测,既能确定最佳的金属材料表面粗糙度的制造方法和最佳的脉冲逆向电源300的设定条件。After selecting the brand and model of the photosensitive dry film, the roughness Ra of the VK-X series of shape measuring and testing instruments is 1.3-1.85μm, and the average value Ra of multiple sets of data is 1.58μm; the surface roughness specification range of the metal material manufactured above after hot pressing by the laminator is 1.57-1.93μm. Using this specification range as the inspection standard, the metal materials manufactured under the above conditions and the products pressed by the photosensitive dry film are tested by the shape measuring and testing instrument VK-X, which can determine the best manufacturing method for the surface roughness of the metal material and the best setting conditions of the pulse reverse power supply 300.
由此,本实施列的最佳条件是No.2。Therefore, the best condition in this embodiment is No.2.
实施例2Example 2
(1)表面粗糙度的分析测定(1) Analysis and measurement of surface roughness
如图7所示,卷式引线框架,宽度115mm,厚度0.15mm,金属原材料为C14410。用形状测量检测仪VK-X系列分析测试粗糙度Ra为0.12~0.21μm,多组数据计算平均值为0.17μm。As shown in Figure 7, the rolled lead frame has a width of 115 mm and a thickness of 0.15 mm, and the metal raw material is C14410. The roughness Ra is 0.12 to 0.21 μm when analyzed and tested by the shape measuring instrument VK-X series, and the average value calculated by multiple sets of data is 0.17 μm.
(2)根据后续镀银工艺的要求,引线框架表面粗糙度需求范围为2.5~3.7μm;(2) According to the requirements of the subsequent silver plating process, the lead frame surface roughness requirement range is 2.5 to 3.7 μm;
(3)脉冲逆向电解技术制造的表面粗糙度Ra=(2.5~3.7μm)-(0.12~0.21μm),即生产加工粗糙度范围Ra为2.38~3.49μm。(3) The surface roughness Ra manufactured by pulse reverse electrolysis technology is (2.5-3.7 μm)-(0.12-0.21 μm), that is, the production and processing roughness range Ra is 2.38-3.49 μm.
(4)根据生产加工要求,对引线框架材料的单面进行粗糙度表面处理。(4) According to the production and processing requirements, the single side of the lead frame material is subjected to roughness surface treatment.
(5)引线框架表面处理(5) Lead frame surface treatment
如图1所示,首先,金属原材料从放料10导出通过放料导轮11后,进入电解脱脂槽清洗除去金属材料表面的油脂等,然后进入酸活化槽清洗除去金属材料表面的锈斑及氧化物等,得到清洁的金属材料。As shown in Figure 1, first, the metal raw material is discharged from the discharge 10 and passes through the discharge guide wheel 11, and then enters the electrolytic degreasing tank to clean and remove grease on the surface of the metal material, and then enters the acid activation tank to clean and remove rust and oxides on the surface of the metal material to obtain a clean metal material.
然后,在第一电解铜工艺槽30a,引线框架材料的上下两侧设有上阳极板40a和下阳极板40b与脉冲逆向电源310的阳极输出连接;进口处阴极导电13a和出口处阴极导电13b与脉冲逆向电源310的阴极输出连接。第二电解铜区域至第六电解铜区域的连接方式与第一电解铜区域的连接方式相同,如图6所示。Then, in the first electrolytic copper process tank 30a, upper and lower anode plates 40a and lower anode plates 40b are provided on the upper and lower sides of the lead frame material and connected to the anode output of the pulse reverse power supply 310; the cathode conductive 13a at the inlet and the cathode conductive 13b at the outlet are connected to the cathode output of the pulse reverse power supply 310. The connection method from the second electrolytic copper area to the sixth electrolytic copper area is the same as the connection method of the first electrolytic copper area, as shown in FIG6 .
如表2所示,卷式引线框架材料宽度115mm,表面积与实施例1相比不足三分之一,选用6单元的电解铜工艺进行表面粗糙度的处理;产品需求的材料表面粗糙度为Ra2.38~3.49μm;将六台脉冲逆向电源310至360的制造金属表面粗糙度的总额度设为18等份,每一等分的表面粗糙度为0.132~0.193μm;例如实验条件No.1的脉冲逆向电源310占11份,处理后需要达到的表面粗糙度范围Ra 1.454~2.132μm,脉冲逆向电源320占3份,处理后需要达到的表面粗糙度范围Ra 0.396~0.581μm,脉冲逆向电源320至360的4台脉冲逆向电源300各占1份,用每台脉冲逆向电源300处理后,材料表面粗糙度都要满足Ra 0.132~0.193μm。As shown in Table 2, the width of the rolled lead frame material is 115 mm, and the surface area is less than one-third of that in Example 1. A 6-unit electrolytic copper process is used for surface roughness treatment. The surface roughness of the material required by the product is Ra2.38-3.49 μm. The total amount of the surface roughness of the manufactured metal of the six pulse reverse power supplies 310 to 360 is set to 18 equal parts, and the surface roughness of each equal part is 0.132-0.193 μm. For example, the pulse reverse power supply 310 of the experimental condition No. 1 accounts for 11 parts, and the surface roughness range Ra 1.454-2.132 μm is required after treatment. The pulse reverse power supply 320 accounts for 3 parts, and the surface roughness range Ra 0.396-0.581 μm is required after treatment. The four pulse reverse power supplies 300 of the pulse reverse power supplies 320 to 360 each account for 1 part. After treatment with each pulse reverse power supply 300, the surface roughness of the material must meet Ra 0.132~0.193μm.
引线框架材料表面粗糙度制造生产线的运行速度优选为2.0m/min;当6台脉冲逆向电源300采用表2中条件No.9时,6次电解铜层粗糙度的范围均在0.396~0.581μm,即6台脉冲逆向电源300所设定的正反向脉冲电流和正反向脉冲时间条件相同,所得到的从最下层到表层的表面粗糙度以及致密度相差很小,引线框架材料表面特性均匀一致。The running speed of the lead frame material surface roughness manufacturing production line is preferably 2.0 m/min; when the six pulse reverse power supplies 300 adopt condition No. 9 in Table 2, the roughness range of the six electrolytic copper layers is 0.396-0.581 μm, that is, the forward and reverse pulse currents and forward and reverse pulse time conditions set by the six pulse reverse power supplies 300 are the same, and the surface roughness and density obtained from the bottom layer to the surface layer are very small, and the surface characteristics of the lead frame material are uniform.
当采用条件No.1时,脉冲逆向电源310需要设定较大正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值要小,反向脉冲时间的设定需较短;得到的电解铜粗糙度较大而且致密度较差;脉冲逆向电源320所需设定的条件与No.9时6台脉冲逆向电源300所采用的条件相同,随后四台脉冲逆向电源330至360的设定条件与条件No.9比较是较小的正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值与条件No.9相比稍大,反向脉冲时间要比No.9短很多;因此所得到的电解铜表面粗糙度在达到产品规格要求的同时,与条件No.9相比表面致密度较好。When condition No. 1 is adopted, the pulse reverse power supply 310 needs to be set with a larger forward pulse current and a longer forward pulse time, while the setting value of the reverse pulse current should be smaller and the reverse pulse time should be shorter; the electrolytic copper obtained has a larger roughness and a poorer density; the conditions required to be set for the pulse reverse power supply 320 are the same as the conditions adopted by the six pulse reverse power supplies 300 in No. 9, and the setting conditions of the subsequent four pulse reverse power supplies 330 to 360 are smaller forward pulse currents and longer forward pulse times compared with condition No. 9, while the setting value of the reverse pulse current is slightly larger than that of condition No. 9, and the reverse pulse time is much shorter than that of No. 9; therefore, the surface roughness of the electrolytic copper obtained meets the product specification requirements, and the surface density is better than that of condition No. 9.
当采用条件No.2、No.3、No.4、No.5、No.6、No.7和No.8时,引线框架材料表面粗糙度在达到要求的同时,致密度处在No.1和No.9之间。When conditions No. 2, No. 3, No. 4, No. 5, No. 6, No. 7 and No. 8 are adopted, the surface roughness of the lead frame material meets the requirements and the density is between No. 1 and No. 9.
当采用条件No.17时,四台脉冲逆向电源310至340需要设定较小的正向脉冲电流和较长的正向脉冲时间,而设定大的反向脉冲电流和很短的反向脉冲时间;得到的镀铜层粗糙度较小并且致密度较好。脉冲逆向电源350所需设定的条件与No.9时6台脉冲逆向电源300所采用的条件相同,最后一台脉冲逆向电源360的设定条件是较大的正向脉冲电流和较长的正向脉冲时间,而设定较大的反向脉冲电流和较短的反向脉冲时间,因此所得到的表面粗糙度在达到产品规格的同时,与条件No.9相比表面致密度较差。When condition No.17 is adopted, the four pulse reverse power supplies 310 to 340 need to set a smaller forward pulse current and a longer forward pulse time, and set a large reverse pulse current and a very short reverse pulse time; the resulting copper plating layer has a smaller roughness and better density. The conditions required to be set for the pulse reverse power supply 350 are the same as the conditions used by the six pulse reverse power supplies 300 in No.9. The setting conditions for the last pulse reverse power supply 360 are a larger forward pulse current and a longer forward pulse time, and a larger reverse pulse current and a shorter reverse pulse time are set. Therefore, the surface roughness obtained meets the product specifications, but the surface density is poorer than that of condition No.9.
当采用条件No.8至No.16时,引线框架材料表面粗糙度在达到要求的同时,致密度处在条件No.9和No.17之间。When conditions No. 8 to No. 16 are adopted, the surface roughness of the lead frame material meets the requirements and the density is between conditions No. 9 and No. 17.
由此,本实施列的最佳条件是No.3。Therefore, the best condition in this embodiment is No.3.
实施例3Example 3
(1)表面粗糙度的分析测定(1) Analysis and measurement of surface roughness
如图9所示,片式引线框架,宽度105mm,厚度0.20mm,金属原材料为C14410。用形状测量检测仪VK-X系列分析测试粗糙度Ra为0.15~0.23μm,多组数据平均值Ra为0.19μm。As shown in Figure 9, the chip lead frame has a width of 105mm and a thickness of 0.20mm, and the metal raw material is C14410. The roughness Ra of the shape measuring instrument VK-X series is 0.15 to 0.23μm, and the average value Ra of multiple sets of data is 0.19μm.
(2)根据后续镀银工艺的要求,引线框架表面粗糙度需求范围为Ra为3.5~4.9μm。(2) According to the requirements of the subsequent silver plating process, the lead frame surface roughness requirement range is Ra 3.5 to 4.9 μm.
(3)脉冲逆向电解技术制造的表面粗糙度Ra=(3.5~4.9μm)-(0.15~0.23μm),既生产加工粗糙度范围Ra为3.35~4.67μm;(3) The surface roughness Ra manufactured by pulse reverse electrolysis technology is (3.5-4.9 μm)-(0.15-0.23 μm), that is, the production and processing roughness range Ra is 3.35-4.67 μm;
(4)根据生产加工要求,对片式引线框架单面进行粗糙度表面处理;(4) According to the production and processing requirements, the single side of the chip lead frame is subjected to roughness surface treatment;
(5)片式引线框架表面处理(5) Surface treatment of chip lead frame
如图1所示,首先,引线框架材料从放料10导出通过放料导轮11后,进入电解脱脂槽清洗除去金属材料表面的油脂等,然后进入酸活化槽清洗除去金属材料表面的锈斑及氧化物等,得到清洁的金属材料。As shown in FIG1 , first, the lead frame material is discharged from the discharge 10 and passes through the discharge guide wheel 11, and then enters the electrolytic degreasing tank to clean and remove grease on the surface of the metal material, and then enters the acid activation tank to clean and remove rust and oxides on the surface of the metal material to obtain a clean metal material.
然后,在第一电解铜工艺槽30a,引线框架材料的上下两侧设有上阳极板40a和下阳极板40b与脉冲逆向电源310的阳极输出连接;进口处阴极导电13a和出口处阴极导电13b与脉冲逆向电源310的阴极输出连接。第二电解铜区域至第六电解铜区域的连接方式与第一电解铜区域的连接方式相同,如图3和图8所示。Then, in the first electrolytic copper process tank 30a, upper and lower anode plates 40a and lower anode plates 40b are provided on the upper and lower sides of the lead frame material and connected to the anode output of the pulse reverse power supply 310; the cathode conductive 13a at the inlet and the cathode conductive 13b at the outlet are connected to the cathode output of the pulse reverse power supply 310. The connection method from the second electrolytic copper area to the sixth electrolytic copper area is the same as the connection method of the first electrolytic copper area, as shown in Figures 3 and 8.
如表3所示,片式引线框架,宽度105mm,表面积与实施例1相比不足三分之一,优选5单元的电解铜工艺进行表面粗糙度的处理;产品需求的材料表面粗糙度为Ra3.35~4.67μm;将五台脉冲逆向电源310至350的制造金属表面粗糙度的总额度设为20等份,每一等分的表面粗糙度为0.167~0.233μm;例如实验条件No.1的脉冲逆向电源310占15份,处理后需要达到的表面粗糙度范围Ra 2.512~3.503μm,脉冲逆向电源320占2份,处理后需要达到的表面粗糙度范围Ra 0.335~0.467μm,脉冲逆向电源320至350的3台脉冲逆向电源300各占1份,用每台脉冲逆向电源300处理后,材料表面粗糙度都要满足Ra 0.167~0.233μm。As shown in Table 3, the chip lead frame has a width of 105 mm and a surface area less than one-third of that in Example 1. The surface roughness of the electrolytic copper process of 5 units is preferably processed; the surface roughness of the material required by the product is Ra3.35-4.67 μm; the total amount of the surface roughness of the metal manufactured by the five pulse reverse power supplies 310 to 350 is set to 20 equal parts, and the surface roughness of each equal part is 0.167-0.233 μm; for example, the pulse reverse power supply 310 of the experimental condition No. 1 accounts for 15 parts, and the surface roughness range Ra 2.512-3.503 μm is required after treatment, the pulse reverse power supply 320 accounts for 2 parts, and the surface roughness range Ra 0.335-0.467 μm is required after treatment, and the three pulse reverse power supplies 300 of the pulse reverse power supplies 320 to 350 each account for 1 part, and after treatment with each pulse reverse power supply 300, the surface roughness of the material must meet Ra 0.167~0.233μm.
片式引线框架材料表面粗糙度制造生产线的运行速度优选为1.5m/min;当5台脉冲逆向电源300采用表3中条件No.9时,5次电解铜层粗糙度的范围均在0.670~0.934μm,即6台脉冲逆向电源300所设定的正反向脉冲电流和正反向脉冲时间条件相同,所得到的从最下层到表层的表面粗糙度以及致密度相差很小,引线框架材料表面特性均匀一致。The operating speed of the surface roughness manufacturing production line of the chip lead frame material is preferably 1.5m/min; when the five pulse reverse power supplies 300 adopt condition No. 9 in Table 3, the roughness range of the five electrolytic copper layers is all between 0.670 and 0.934μm, that is, the forward and reverse pulse currents and forward and reverse pulse time conditions set by the six pulse reverse power supplies 300 are the same, and the surface roughness and density obtained from the bottom layer to the surface layer are very small, and the surface characteristics of the lead frame material are uniform.
当采用条件No.1时,脉冲逆向电源310需要设定较大正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值要小,反向脉冲时间的设定需较短;得到的电解铜粗糙度较大而且致密度较差;脉冲逆向电源320所需设定的条件与No.9的5台脉冲逆向电源300所采用的条件不同,采用的是较小的正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值与条件No.9相比稍大,反向脉冲时间要比No.9短很多;随后三台脉冲逆向电源330至350的设定条件与条件No.9比较是较小的正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值与条件No.9相比稍大,反向脉冲时间要比No.9短很多。因此所得到的电解铜表面粗糙度在达到产品规格要求的同时,与条件No.9相比表面致密度较好。When condition No. 1 is adopted, the pulse reverse power supply 310 needs to set a larger forward pulse current and a longer forward pulse time, while the setting value of the reverse pulse current should be smaller and the setting value of the reverse pulse time should be shorter; the electrolytic copper obtained has a larger roughness and a poorer density; the conditions required to be set for the pulse reverse power supply 320 are different from the conditions adopted by the five pulse reverse power supplies 300 of No. 9, which adopt a smaller forward pulse current and a longer forward pulse time, while the setting value of the reverse pulse current is slightly larger than that of condition No. 9, and the reverse pulse time is much shorter than that of No. 9; the setting conditions of the subsequent three pulse reverse power supplies 330 to 350 are smaller forward pulse currents and longer forward pulse times compared with condition No. 9, while the setting value of the reverse pulse current is slightly larger than that of condition No. 9, and the reverse pulse time is much shorter than that of No. 9. Therefore, the surface roughness of the electrolytic copper obtained meets the product specification requirements, and the surface density is better than that of condition No. 9.
当采用条件No.2、No.3、No.4、No.5、No.6、No.7和No.8时,引线框架材料表面粗糙度在达到要求的同时,致密度处在No.1和No.9之间。When conditions No. 2, No. 3, No. 4, No. 5, No. 6, No. 7 and No. 8 are adopted, the surface roughness of the lead frame material meets the requirements and the density is between No. 1 and No. 9.
当采用条件No.17时,三台脉冲逆向电源310至330需要设定较小的正向脉冲电流和较长的正向脉冲时间,而设定大的反向脉冲电流和很短的反向脉冲时间;得到的镀铜层When condition No. 17 is adopted, the three pulse reverse power supplies 310 to 330 need to be set with a smaller forward pulse current and a longer forward pulse time, and a larger reverse pulse current and a very short reverse pulse time; the copper plating layer obtained
粗糙度较小并且致密度较好。脉冲逆向电源340所需设定的条件与No.9时5台脉冲逆向电源300所采用的条件不同,采用的是较小的正向脉冲电流和较长的正向脉冲时间,而反向脉冲电流的设定值与条件No.9相比稍大,反向脉冲时间要比No.9短很多;最后面一台脉冲逆向电源350的设定条件是较大的正向脉冲电流和较长的正向脉冲时间,而设定较大的反向脉冲电流和较短的反向脉冲时间,因此所得到的表面粗糙度在达到产品规格的同时,与条件No.9比较表面致密度更差。The roughness is small and the density is good. The conditions required to set the pulse reverse power supply 340 are different from the conditions used by the five pulse reverse power supplies 300 in No. 9. A smaller forward pulse current and a longer forward pulse time are used, and the setting value of the reverse pulse current is slightly larger than that of condition No. 9, and the reverse pulse time is much shorter than that of No. 9; the setting conditions of the last pulse reverse power supply 350 are a larger forward pulse current and a longer forward pulse time, and a larger reverse pulse current and a shorter reverse pulse time are set. Therefore, the surface roughness obtained meets the product specifications, but the surface density is worse than that of condition No. 9.
当采用条件No.8至No.16时,引线框架材料表面粗糙度在达到要求的同时,致密度处在条件No.9和No.17之间。When conditions No. 8 to No. 16 are adopted, the surface roughness of the lead frame material meets the requirements and the density is between conditions No. 9 and No. 17.
由此,本实施列的最佳条件是No.4。Therefore, the best condition in this embodiment is No.4.
表1、表2、表3分别为7台脉冲逆向电源300对应的引线框架表面粗糙度的分配额度、6台脉冲逆向电源300对应的引线框架表面粗糙度的分配额度、5台脉冲逆向电源300对应的引线框架表面粗糙度的分配额度。其中包括每一台脉冲逆向电源300的分配份数和具体表面粗糙度范围。Table 1, Table 2, and Table 3 are respectively the allocation quotas of the lead frame surface roughness corresponding to 7 pulse reverse power supplies 300, the allocation quotas of the lead frame surface roughness corresponding to 6 pulse reverse power supplies 300, and the allocation quotas of the lead frame surface roughness corresponding to 5 pulse reverse power supplies 300. They include the number of allocations and the specific surface roughness range of each pulse reverse power supply 300.
表1:7台脉冲逆向电源对应的引线框架表面粗糙度的分配额度单位:μmTable 1: Distribution of lead frame surface roughness for 7 pulse reverse power supplies Unit: μm
表2:6台脉冲逆向电源对应的引线框架表面粗糙度的分配额度单位:μmTable 2: Distribution of lead frame surface roughness for 6 pulse reverse power supplies Unit: μm
表3:5台脉冲逆向电源对应的引线框架表面粗糙度的分配额度单位:μmTable 3: Distribution of lead frame surface roughness for 5 pulse reverse power supplies Unit: μm
由此,调节控制各单元可选脉冲逆向电源300输出电流各不相同,同时调节控制各单元可选脉冲逆向电源300输出脉冲时间也各不相同,通过所选不同设定条件单元的各种排列组合,设计表面粗糙度需求范围的试验方案并对实验结果优化处理,优选出最佳的材料表面粗糙度的实验方法,得到引线框架生产要求的所需引线框架材料表面粗糙度Therefore, the output current of each unit of the optional pulse reverse power supply 300 is adjusted to be different, and the output pulse time of each unit of the optional pulse reverse power supply 300 is also adjusted to be different. By selecting various permutations and combinations of different setting condition units, a test plan with a required range of surface roughness is designed and the experimental results are optimized, and the best experimental method for material surface roughness is selected to obtain the required lead frame material surface roughness required for lead frame production.
调节控制引线框架材料表面粗糙度的电解铜工艺可选范围3单元~12单元,优选范围4单元~11单元,更优选范围5单元~10单元。The electrolytic copper process for adjusting and controlling the surface roughness of the lead frame material can be selected in the range of 3 units to 12 units, preferably in the range of 4 units to 11 units, and more preferably in the range of 5 units to 10 units.
如图1至图9所示,根据本发明实施例的引线框架材料表面粗糙度的制造方法,能够将引线框架材料电解加工成产品所需的表面粗糙度。通过脉冲逆向电解技术和优选电解铜药水对连续引线框架材料200、500和700进行表面处理。引线框架材料表面粗糙度的生产加工条件可以通过设计表面粗糙度需求范围的试验方案进行确定,并对实验结果优化处理,优选出最佳的材料表面粗糙度的制造方法,其具有连续生产加工效率高,增加引线框架材料表面与感光干膜的结合强度以及与封装材料的结合强度,提高引线框架产品质量。As shown in Figures 1 to 9, according to the manufacturing method of the surface roughness of the lead frame material according to the embodiment of the present invention, the lead frame material can be electrolytically processed into the surface roughness required by the product. The continuous lead frame materials 200, 500 and 700 are surface treated by pulse reverse electrolysis technology and preferred electrolytic copper solution. The production and processing conditions of the surface roughness of the lead frame material can be determined by designing a test plan with a required range of surface roughness, and optimizing the experimental results to select the best manufacturing method of the material surface roughness, which has high continuous production and processing efficiency, increases the bonding strength between the surface of the lead frame material and the photosensitive dry film and the bonding strength with the packaging material, and improves the quality of the lead frame product.
本发明的引线框架材料可以是金属材料,金属材料可以是由铜、镍、钴、钨、钼、铬和锌当中所选择的任意一个单体或铜、镍、钴、磷、钨、砷、钼、铬和锌当中所选择的任意两种或两种以上组成的合金;也可以是铁及其铁合金,还可以是各种不锈钢材料;所有金属材料可以是连续带材,也可以是连续引线框架材料。除此之外,凡是表面附有金属箔的材料都可以通过本发明的制造方法和制造设备进行表面粗糙度的生产加工。例如,各种塑料薄膜的单面或者双面附有金属薄膜的材料都可以制造所需求的表面粗糙度材料。The lead frame material of the present invention can be a metal material, and the metal material can be any single body selected from copper, nickel, cobalt, tungsten, molybdenum, chromium and zinc, or an alloy composed of any two or more selected from copper, nickel, cobalt, phosphorus, tungsten, arsenic, molybdenum, chromium and zinc; it can also be iron and its iron alloy, and can also be various stainless steel materials; all metal materials can be continuous strips or continuous lead frame materials. In addition, all materials with metal foil attached to the surface can be processed by the manufacturing method and manufacturing equipment of the present invention for surface roughness production. For example, various plastic films with metal films attached to one or both sides can be used to manufacture the required surface roughness materials.
引线框架材料的板厚可选范围是0.03mm~0.80mm,优选范围是0.05mm~0.55mm,更优选范围是0.07mm~0.35mm;金属材料宽度可选范围50mm~1000mm,优选范围80mm~700mm,更优选范围是100mm~500mm。The thickness of the lead frame material can be in the range of 0.03mm to 0.80mm, preferably in the range of 0.05mm to 0.55mm, and more preferably in the range of 0.07mm to 0.35mm; the width of the metal material can be in the range of 50mm to 1000mm, preferably in the range of 80mm to 700mm, and more preferably in the range of 100mm to 500mm.
感光干膜表面与引线框架材料表面要进行热压处理,得到结合坚固、表面厚度均匀的贴膜引线框架材料。感光干膜原材料的厚度可选范围是20~100μm,优选范围是20~80μm,更优选范围是20~80μm。另外,感光干膜原材料表面粗糙度可选范围是0.65~2.17μm,优选范围是0.55~2.07μm,更优选范围是0.50~1.97μm。感光干膜与引线框架材料热压结合后的感光干膜一侧粗糙度可选范围是1.05~2.65μm,优选范围是0.95~2.50μm,更优选范围是0.85~2.30μm。The surface of the photosensitive dry film and the surface of the lead frame material must be subjected to heat pressing treatment to obtain a film lead frame material with a strong bond and uniform surface thickness. The thickness of the photosensitive dry film raw material can be in the range of 20 to 100 μm, preferably in the range of 20 to 80 μm, and more preferably in the range of 20 to 80 μm. In addition, the surface roughness of the photosensitive dry film raw material can be in the range of 0.65 to 2.17 μm, preferably in the range of 0.55 to 2.07 μm, and more preferably in the range of 0.50 to 1.97 μm. The roughness of one side of the photosensitive dry film after the photosensitive dry film is heat-pressed with the lead frame material can be in the range of 1.05 to 2.65 μm, preferably in the range of 0.95 to 2.50 μm, and more preferably in the range of 0.85 to 2.30 μm.
脉冲逆向电解技术是由脉冲逆向电源300输出的正向脉冲波形和反向脉冲波形的电流通过阳极板和电解铜药水传输到引线框架材料表面以及正向脉冲时间和反向脉冲时间组成。优选地,脉冲逆向电源300输出的双脉冲正向电流可选范围5A~500A,优选范围10A~450A,更优选范围20A~430A;双脉冲整流器输出的反向电流可选范围20A~1000A,优选范围30A~900A,更优选范围50A~850A;脉冲逆向电源300输出的双脉冲正向脉冲时间可选范围5ms~100ms,优选范围7ms~70ms,更优选范围10ms~50ms;脉冲逆向电源300输出的反向脉冲时间可选范围1ms~30ms,优选范围3ms~20ms,更优选范围5ms~10ms。The pulse reverse electrolysis technology is composed of the current of the forward pulse waveform and the reverse pulse waveform output by the pulse reverse power supply 300 being transmitted to the surface of the lead frame material through the anode plate and the electrolytic copper solution, as well as the forward pulse time and the reverse pulse time. Preferably, the double pulse forward current output by the pulse reverse power supply 300 can be selected in the range of 5A to 500A, preferably in the range of 10A to 450A, and more preferably in the range of 20A to 430A; the reverse current output by the double pulse rectifier can be selected in the range of 20A to 1000A, preferably in the range of 30A to 900A, and more preferably in the range of 50A to 850A; the double pulse forward pulse time output by the pulse reverse power supply 300 can be selected in the range of 5ms to 100ms, preferably in the range of 7ms to 70ms, and more preferably in the range of 10ms to 50ms; the reverse pulse time output by the pulse reverse power supply 300 can be selected in the range of 1ms to 30ms, preferably in the range of 3ms to 20ms, and more preferably in the range of 5ms to 10ms.
其中,电解铜药水的正向电流密度可选范围2A/dm2~70A/dm2,优选范围5A/dm2~60A/dm2,更优选范围10A/dm2~50A/dm2;电解铜药水的反向电流密度可选范围5A/dm2~170A/dm2,优选范围10A/dm2~160A/dm2,更优选范围20A/dm2~150A/dm2。The forward current density of the electrolytic copper solution may be in the range of 2A/dm 2 to 70A/dm 2 , preferably in the range of 5A/dm 2 to 60A/dm 2 , and more preferably in the range of 10A/dm 2 to 50A/dm 2 ; the reverse current density of the electrolytic copper solution may be in the range of 5A/dm 2 to 170A/dm 2 , preferably in the range of 10A/dm 2 to 160A/dm 2 , and more preferably in the range of 20A/dm 2 to 150A/dm 2 .
进一步地,阳极板表面积与浸在每个电解铜药水槽中的引线框架材料的表面积比可选为5:1,优选为3:1,更优选为2:1;而阳极板可采用可溶性金属和非可溶性金属,也可采用在非可溶性阳极板表面电解贵金属的方法;阳极的形状可以片形和网状,也可以是异形,例如平板弯曲成圆弧形,或是网状弯曲成圆弧形,又例如在平面板上依据位置不同打孔的大小和分布也不相同的各种组合,为了满足阳极面积与阴极面积比5:1的要求,也可以将两种不同形状的阳极或两种以上进行组合而成。引线框架表面粗糙度算数平均值的可选范围0.05μm~5.0μm,优选为0.07μm~4.5μm,更优选为0.09μm~3.9μm。Furthermore, the ratio of the surface area of the anode plate to the surface area of the lead frame material immersed in each electrolytic copper solution tank can be selected as 5:1, preferably 3:1, and more preferably 2:1; the anode plate can be made of soluble metals and insoluble metals, or the method of electrolyzing precious metals on the surface of insoluble anode plates can be adopted; the shape of the anode can be sheet-shaped and mesh-shaped, or it can be a special shape, such as bending a flat plate into an arc shape, or bending a mesh into an arc shape, and for example, various combinations of different sizes and distributions of holes punched on a flat plate according to different positions. In order to meet the requirement of a ratio of anode area to cathode area of 5:1, two or more anodes of different shapes can also be combined. The optional range of the arithmetic mean of the surface roughness of the lead frame is 0.05μm to 5.0μm, preferably 0.07μm to 4.5μm, and more preferably 0.09μm to 3.9μm.
根据本发明实施例的引线框架表面粗糙度的制造设备的其他结构和操作对于本领域技术人员而言都是可以理解并且容易实现的,因此不再详细描述。Other structures and operations of the lead frame surface roughness manufacturing equipment according to the embodiment of the present invention are understandable and easy to implement for those skilled in the art, and thus will not be described in detail.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示意性实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "illustrative embodiments", "examples", "specific examples", or "some examples" means that the specific features, structures, materials, or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials, or characteristics described may be combined in any one or more embodiments or examples in a suitable manner.
尽管已经示出和描述了本发明的实施例,本领域的普通技术人员可以理解:在不脱离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the claims and their equivalents.
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CN202011204117.3A CN112331566B (en) | 2020-11-02 | 2020-11-02 | Lead frame surface roughness manufacturing equipment and manufacturing method |
PCT/CN2021/124340 WO2022089232A1 (en) | 2020-11-02 | 2021-10-18 | Manufacturing equipment and manufacturing method for lead frame surface roughness |
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CN112331566B (en) * | 2020-11-02 | 2024-09-27 | 昆山一鼎工业科技有限公司 | Lead frame surface roughness manufacturing equipment and manufacturing method |
CN114171487B (en) * | 2021-12-06 | 2022-07-12 | 天水华洋电子科技股份有限公司 | Surface treatment device for integrated circuit lead frame |
Citations (2)
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JPH0832005A (en) * | 1994-07-12 | 1996-02-02 | Sony Corp | Plating equipment for lead frame |
CN109468670A (en) * | 2018-11-16 | 2019-03-15 | 中山品高电子材料有限公司 | Method for electroplating copper layer on lead frame |
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US6558231B1 (en) * | 2000-10-17 | 2003-05-06 | Faraday Technology Marketing Goup, Llc | Sequential electromachining and electropolishing of metals and the like using modulated electric fields |
US7192809B2 (en) * | 2005-02-18 | 2007-03-20 | Texas Instruments Incorporated | Low cost method to produce high volume lead frames |
JP4981488B2 (en) * | 2007-03-09 | 2012-07-18 | 古河電気工業株式会社 | Roughened rolled copper plate and method for producing the same |
JP6093646B2 (en) * | 2013-05-14 | 2017-03-08 | 新光電気工業株式会社 | Manufacturing method of plating film |
JP7119574B2 (en) * | 2018-05-25 | 2022-08-17 | 三菱マテリアル株式会社 | Lead frame and manufacturing method thereof |
CN109989083A (en) * | 2019-04-28 | 2019-07-09 | 天水华洋电子科技股份有限公司 | Pretreating process is electroplated in the super roughening lead frame of one kind |
CN111304700A (en) * | 2020-03-26 | 2020-06-19 | 深圳市惟华电子科技有限公司 | Preparation method of reverse copper foil |
CN112331566B (en) * | 2020-11-02 | 2024-09-27 | 昆山一鼎工业科技有限公司 | Lead frame surface roughness manufacturing equipment and manufacturing method |
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Patent Citations (2)
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JPH0832005A (en) * | 1994-07-12 | 1996-02-02 | Sony Corp | Plating equipment for lead frame |
CN109468670A (en) * | 2018-11-16 | 2019-03-15 | 中山品高电子材料有限公司 | Method for electroplating copper layer on lead frame |
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Denomination of invention: Manufacturing equipment and method for surface roughness of lead frame Granted publication date: 20240927 Pledgee: Bank of Jiangsu Co.,Ltd. Suzhou Branch Pledgor: KUNSHAN A TRIPOD PLATING EQUIPMENT Co.,Ltd. Registration number: Y2024980049862 |
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