CN112267292A - Antibacterial and antistatic fabric and preparation method thereof - Google Patents
Antibacterial and antistatic fabric and preparation method thereof Download PDFInfo
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- CN112267292A CN112267292A CN202011196814.9A CN202011196814A CN112267292A CN 112267292 A CN112267292 A CN 112267292A CN 202011196814 A CN202011196814 A CN 202011196814A CN 112267292 A CN112267292 A CN 112267292A
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- antibacterial
- antistatic
- fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 142
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 107
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000006185 dispersion Substances 0.000 claims abstract description 39
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 32
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 20
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 18
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000002791 soaking Methods 0.000 claims abstract description 5
- 239000003242 anti bacterial agent Substances 0.000 claims description 33
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 20
- 239000002216 antistatic agent Substances 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 18
- XHQSLVIGPHXVAK-UHFFFAOYSA-K iron(3+);octadecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XHQSLVIGPHXVAK-UHFFFAOYSA-K 0.000 claims description 13
- 150000008301 phosphite esters Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000012964 benzotriazole Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 230000001678 irradiating effect Effects 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229940113115 polyethylene glycol 200 Drugs 0.000 claims description 4
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 229960001860 salicylate Drugs 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 4
- AYKOTYRPPUMHMT-UHFFFAOYSA-N silver;hydrate Chemical compound O.[Ag] AYKOTYRPPUMHMT-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 11
- 239000002250 absorbent Substances 0.000 description 10
- 230000002745 absorbent Effects 0.000 description 10
- 230000003068 static effect Effects 0.000 description 10
- 230000002195 synergetic effect Effects 0.000 description 9
- 230000005611 electricity Effects 0.000 description 8
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 229960000969 phenyl salicylate Drugs 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The application relates to the field of fabrics, and particularly discloses an antibacterial and antistatic fabric and a preparation method thereof. A preparation method of an antibacterial and antistatic fabric comprises the following steps: s1, feeding the fabric into the antibacterial antistatic dispersion liquid, ultrasonically soaking for 15-30S, and taking out to obtain a pretreated fabric; s2, drying the pretreated fabric until the water content of the pretreated fabric is lower than 85% to obtain the dried pretreated fabric; s3, drying the pressed and dried pretreated fabric at the temperature of 45-65 ℃ to obtain the antibacterial and antistatic fabric; the antibacterial antistatic dispersion liquid is prepared from the following raw materials: nano titanium dioxide, an ultraviolet absorber, nano graphene oxide, diatomite, silver nitrate, water and a dispersing agent. The antibacterial and antistatic fabric prepared by the method can be used for preparing towels, clothes and the like, and has the advantages of good antistatic performance and good antibacterial performance.
Description
Technical Field
The application relates to the field of fabrics, in particular to an antibacterial and antistatic fabric and a preparation method thereof.
Background
Static electricity, which is a static or non-flowing charge, is formed when the charge accumulates on an object or surface. For example, when the chemical fiber clothes rub the human body in winter and the weather is dry, the human body can feel the electric shock needle-prick feeling, which is a bad place of static electricity.
Moreover, the persistent static electricity can cause the pH value of the blood of a human body to be increased, the excretion amount of calcium in urine to be increased, and the blood calcium to be reduced, thereby having adverse effects on the heart, the brain and the skin of the human body.
In recent years, many people have studied antistatic fabrics, and finally, the reason that the antistatic effect of the fabrics can be improved by enhancing the moisture absorption performance of the fabrics is that the static leakage amount of the fabrics is improved after the fabrics absorb moisture in the environment.
However, after the moisture absorption performance of the fabric is enhanced, the fabric is in a relatively humid environment in an environment with high humidity, and the environment is suitable for bacteria growth, so that the fabric is easy to breed bacteria. However, the fabric after breeding bacteria is easy to generate some peculiar smell, and bacterial plaque is easy to form on the fabric when serious, thereby influencing the use of people.
Disclosure of Invention
In order to improve the antistatic performance of the fabric and improve the antibacterial performance of the fabric, the application provides the antibacterial and antistatic fabric and the preparation method thereof.
In a first aspect, the application provides a preparation method of an antibacterial and antistatic fabric, which adopts the following technical scheme:
a preparation method of an antibacterial and antistatic fabric comprises the following steps:
s1, feeding the fabric into the antibacterial antistatic dispersion liquid, ultrasonically soaking for 15-30S, and taking out to obtain a pretreated fabric;
s2, drying the pretreated fabric until the water content of the pretreated fabric is lower than 85% to obtain the dried pretreated fabric;
s3, drying the pressed and dried pretreated fabric at the temperature of 45-65 ℃ to obtain the antibacterial and antistatic fabric;
the antibacterial antistatic dispersion liquid is prepared from the following raw materials in parts by weight:
nano titanium dioxide: 3-6 parts of
Ultraviolet light absorber: 0.3 to 0.6 portion
Nano graphene oxide: 0.6 to 1 portion
Diatomite: 2-5 parts of
Silver nitrate: 0.05 to 0.1 portion
Water: 50 portions of
Dispersing agent: 0.5-1 part.
By adopting the technical scheme, the diatomite has good moisture absorption performance, and can quickly leak out static electricity generated by the fabric, and the addition of silver nitrate can further improve the conductive capability and the antistatic property of the fabric; in addition, the nanometer titanium dioxide and the ultraviolet absorber have a synergistic effect, so that the antibacterial performance of the fabric can be enhanced, the fabric has the advantages of good antistatic performance and good antibacterial performance, the harm of static electricity to a human body is reduced, and the problem that the fabric is easy to grow bacteria to cause odor or bacterial spots is solved.
Preferably, the preparation method of the antibacterial antistatic dispersion liquid is as follows:
preparing an activated antibacterial agent:
ball-milling the mixture of the nano titanium dioxide, the ultraviolet absorber and the nano graphene oxide at the ball-milling speed of 150 and 250rad/min for 1-3h to obtain the antibacterial agent;
irradiating the antibacterial agent under ultraviolet light for 30-60min to obtain activated antibacterial agent;
preparing an antistatic agent:
adding silver nitrate into water, and stirring and dissolving to obtain a silver nitrate solution;
adding diatomite into a silver nitrate solution, and uniformly stirring to obtain an antistatic agent;
preparing an antibacterial antistatic dispersion liquid:
adding an activated antibacterial agent and a dispersing agent into an antistatic agent, and dispersing by ultrasonic vibration to obtain an antibacterial antistatic dispersion liquid.
By adopting the technical scheme, after the activated antibacterial agent and the antistatic agent are uniformly mixed to obtain the antibacterial and antistatic dispersion liquid, the antibacterial and antistatic dispersion liquid is adopted to treat the fabric, so that the fabric can be treated by only one step to obtain the fabric with both the antistatic property and the antibacterial property, and the fabric has the advantages of simple operation process and low equipment requirement.
Preferably, the ultraviolet light absorber is one or a combination of more of salicylate ultraviolet light absorber, benzophenone ultraviolet light absorber and benzotriazole ultraviolet light absorber.
By adopting the technical scheme, the ultraviolet light absorbent can adopt any one or a combination of a plurality of salicylic acid esters, benzophenones and benzotriazoles, can be selected according to actual needs in the actual production process, and is favorable for controlling the cost.
Preferably, the antibacterial antistatic dispersion liquid further comprises the following raw materials in parts by weight:
metal salts of stearic acid: 0.8 to 1.2 portions of
Phosphite ester: 1-1.5 parts.
By adopting the technical scheme, the metal stearate and the phosphite ester are added into the antibacterial antistatic dispersion liquid, wherein the metal stearate and the phosphite ester have a synergistic effect on the improvement of the stability of the ultraviolet light absorbent, so that the antibacterial performance of the fabric can be further enhanced.
Preferably, the preparation method of the antibacterial antistatic dispersion liquid is as follows:
preparing an activated antibacterial agent:
ball-milling a mixture of nano titanium dioxide, an ultraviolet absorber, a metal stearate, phosphite ester and nano graphene oxide at the ball-milling speed of 150-250rad/min for 1-3h to obtain an antibacterial agent;
irradiating the antibacterial agent under ultraviolet light for 30-60min to obtain activated antibacterial agent;
preparing an antistatic agent:
adding silver nitrate into water, and stirring and dissolving to obtain a silver nitrate solution;
adding diatomite into a silver nitrate solution, and uniformly stirring to obtain an antistatic agent;
preparing an antibacterial antistatic dispersion liquid:
adding an activated antibacterial agent and a dispersing agent into an antistatic agent, and dispersing by ultrasonic vibration to obtain an antibacterial antistatic dispersion liquid.
By adopting the technical scheme, the metal stearate and the phosphite ester are added into the nano titanium dioxide, the ultraviolet absorber and the nano graphene oxide, the activated antibacterial agent capable of further improving the antibacterial performance of the fabric is prepared, then the antibacterial agent is uniformly mixed with the antistatic agent to prepare the antibacterial antistatic dispersion liquid, and the fabric is treated by adopting the antibacterial antistatic dispersion liquid, so that the fabric can be processed by only one step to obtain the fabric with both the antistatic performance and the antibacterial performance.
Preferably, the metal stearate is one or a combination of more of calcium stearate, zinc stearate, magnesium stearate and ferric stearate.
By adopting the technical scheme, the metal stearate can adopt any one or more of calcium stearate, zinc stearate, magnesium stearate and ferric stearate, and can be selected according to actual requirements in the actual production process, so that the cost can be controlled.
Preferably, the ultraviolet light absorber is a benzotriazole ultraviolet light absorber, and the benzotriazole ultraviolet light absorber is any one or a combination of more of UV-320, UV-326, UV-327, UV-328, UV-510 and UV-5411.
By adopting the technical scheme, the ultraviolet absorber adopts the benzotriazole ultraviolet absorber, and the ultraviolet absorber and the phosphite ester have a synergistic effect, so that the easy ignition performance of the antibacterial antistatic fabric can be effectively improved.
Preferably, the diatomite has an average particle size of 4.5-5.5 nm.
By adopting the technical scheme, when the average particle size of the diatomite is 4.5-5.5nm, the surface resistivity of the antibacterial antistatic fabric is further reduced, namely the antistatic performance of the antibacterial antistatic fabric is further improved.
Preferably, the dispersant is one or a combination of more of polyethylene glycol 200 and polyethylene glycol 400.
By adopting the technical scheme, the polyethylene glycol 200 or the polyethylene glycol 400 can uniformly mix the antibacterial agent and the antistatic agent to form the antibacterial antistatic dispersion liquid with good dispersion performance, so that the fabric has good antibacterial and antistatic performance.
In a second aspect, the application provides an antibacterial and antistatic fabric, which adopts the following technical scheme:
an antibacterial and antistatic fabric is prepared by any one of the preparation methods of the antibacterial and antistatic fabric.
By adopting the technical scheme, the antibacterial and antistatic fabric with both antibacterial performance and antistatic performance can be obtained, the harm of static electricity to a human body is reduced, and the problem that the fabric is easy to breed bacteria to cause odor or bacterial spots is solved.
In summary, the present application has the following beneficial effects:
1. due to the adoption of the diatomite with good moisture absorption performance, static electricity generated by the fabric can be quickly leaked out, and due to the addition of the silver nitrate, the conductive capacity of the fabric can be further improved, and the antistatic performance of the fabric is improved; in addition, the nanometer titanium dioxide and the ultraviolet absorber have a synergistic effect, so that the antibacterial performance of the fabric can be enhanced, the fabric has the advantages of good antistatic performance and good antibacterial performance, the harm of static electricity to a human body is reduced, and the problem that the fabric is easy to grow bacteria to cause odor or bacterial spots is solved.
2. The application preferably adds stearic acid metal salt and phosphite ester to the antibacterial antistatic dispersion liquid, wherein, the stearic acid metal salt and the phosphite ester have synergistic effect on the improvement of the stability of the ultraviolet light absorbent, thereby being capable of further enhancing the antibacterial performance of the fabric.
3. The ultraviolet light absorber is preferably a benzotriazole ultraviolet light absorber, and the ultraviolet light absorber and phosphite ester have a synergistic effect and can effectively improve the easy ignition performance of the antibacterial antistatic fabric.
Detailed Description
The present application is further described in detail with reference to examples and comparative examples, wherein the fabrics in the examples and comparative examples are chemical fibers, the present application takes nylon fabrics as an example, and the raw materials involved in the present application are all commercially available.
Examples
TABLE 1 Components and proportions (units/kg) of the antibacterial antistatic dispersions of examples 1 to 7
Example 1
The preparation method of the antibacterial and antistatic fabric comprises the following steps:
s1, feeding the fabric into the antibacterial antistatic dispersion liquid for ultrasonic soaking for 15S, and then taking out to obtain a pretreated fabric;
s2, drying the pretreated fabric until the water content of the pretreated fabric is lower than 85% to obtain the dried pretreated fabric;
s3, drying the pressed and dried pretreated fabric at the temperature of 45 ℃ to obtain the antibacterial and antistatic fabric;
the compounding ratio of the components in the antibacterial and antistatic dispersion liquid in step S1 is as follows according to example 1 in table 1 above:
s1.1, preparing an activated antibacterial agent:
s1.11, ball-milling a mixture of nano titanium dioxide, an ultraviolet light absorber and nano graphene oxide at a ball-milling speed of 250rad/min for 1h to obtain an antibacterial agent; in the embodiment, the ultraviolet light absorbent adopts UV-320;
s1.12, irradiating the antibacterial agent for 30min under ultraviolet light with the wavelength of 280nm to obtain an activated antibacterial agent;
s1.2, preparing an antistatic agent:
s1.21, adding silver nitrate into water, and stirring and dissolving to obtain a silver nitrate solution;
s1.22, adding diatomite with the average particle size of 0.5-1.5nm into a silver nitrate solution, and uniformly stirring to obtain an antistatic agent;
s1.3, preparing an antibacterial antistatic dispersion liquid:
s1.31, adding an activated antibacterial agent and a dispersing agent into an antistatic agent, and dispersing by ultrasonic vibration to obtain an antibacterial antistatic dispersion liquid; in this embodiment, the dispersant is polyethylene glycol 200.
Example 2
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 1:
(1) in the step S1, ultrasonically soaking the fabric in the antibacterial antistatic dispersion liquid for 30S;
(2) in step S3, drying the pressed and dried pretreated fabric at the temperature of 65 ℃;
(3) the ultraviolet light absorbent in the step S1.11 adopts phenyl salicylate, the ball milling speed is 150rad/min, and the ball milling time is 3 h;
(4) in the step S1.12, the antibacterial agent is irradiated for 60min under ultraviolet light with the wavelength of 315 nm;
(5) step S1.31, polyethylene glycol 400 is adopted as the dispersing agent;
(6) the components and proportions of the antibacterial antistatic dispersion of this example were as described in Table 1 above for example 2.
Example 3
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 1:
(1) s1.11, performing ball milling on a mixture of nano titanium dioxide, an ultraviolet absorber, a metal stearate and nano graphene oxide, wherein the ball milling speed is 250rad/min, and the ball milling time is 1h to obtain an antibacterial agent; in the embodiment, the ultraviolet light absorbent adopts UV-320; wherein, the metal stearate in the embodiment adopts ferric stearate;
(2) the components and proportions of the antibacterial antistatic dispersion of this example were as described in Table 1 above for example 3.
Example 4
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 1:
(1) s1.11, performing ball milling on a mixture of nano titanium dioxide, an ultraviolet absorber, phosphite ester and nano graphene oxide at a ball milling speed of 250rad/min for 1h to obtain an antibacterial agent; in the embodiment, the ultraviolet light absorbent adopts UV-320; wherein, the metal stearate in the embodiment adopts ferric stearate;
(2) the components and proportions of the antibacterial antistatic dispersion of this example were as described in Table 1 above for example 4.
Example 5
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 1:
(1) s1.11, performing ball milling on a mixture of nano titanium dioxide, an ultraviolet absorber, a metal stearate, phosphite ester and nano graphene oxide, wherein the ball milling speed is 250rad/min, and the ball milling time is 1h to obtain an antibacterial agent; in the embodiment, the ultraviolet light absorbent adopts UV-320; wherein, the metal stearate in the embodiment adopts ferric stearate;
(2) the components and proportions of the antibacterial antistatic dispersion of this example were as described in Table 1 above for example 5.
Example 6
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 5 in that:
(1) the amounts of metal stearate and phosphite used in step S1.11 are different, with particular reference to example 6 in table 1.
Example 7
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 5 in that:
the components and proportions of the antibacterial antistatic dispersion according to this example were determined in Table 1 above for example 7 using phenyl salicylate as the UV absorber in step S1.11.
Example 8
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 5 in that:
the diatomaceous earth in step S1.22 has an average particle size of 4.5 to 5.5 nm.
Example 9
The preparation method of the antibacterial and antistatic fabric is different from that of the fabric in the embodiment 5 in that:
the diatomaceous earth in step S1.22 has an average particle size of from 10 to 15 nm.
Comparative example
Comparative example 1
A fabric, the preparation method of which is different from that of the fabric in example 1:
the nano titanium dioxide and the ultraviolet absorbent are respectively replaced by nano graphene oxide with the same quantity.
Comparative example 2
A fabric, the preparation method of which is different from that of the fabric in example 1:
the nano titanium dioxide is replaced by nano graphene oxide with the same quantity.
Comparative example 3
A fabric, the preparation method of which is different from that of the fabric in example 1:
the ultraviolet absorbent is replaced by nano graphene oxide with the same quantity.
Performance test
The bacteriostasis rate is as follows: reference is made to GB/T20944.2-2007 evaluation part 2 of antibacterial properties of textiles: the absorption method is used for measuring the bacteriostasis rate of each group of samples prepared in examples 1-9 and comparative examples 1-3, wherein when the bacteriostasis rate is more than or equal to 90%, the antibacterial and antistatic fabric has the antibacterial effect; when the bacteriostasis rate is more than or equal to 99 percent, the antibacterial and antistatic fabric has a good antibacterial effect.
Surface resistivity: reference is made to GB/T12703.4-2010 "assessment of electrostatic properties of textiles section 4: resistivity measurements of surface resistivity were made on each of the groups of samples prepared in examples 1 to 9 and comparative examples 1 to 3; the temperature of the measuring environment is 25 ℃, and the relative humidity is 50%; wherein, when the surface resistivity of the textile is lower than 1 x 107In the process, the antistatic performance of the textile is A grade, and the smaller the surface resistivity is, the better the antistatic performance of the antibacterial antistatic fabric is.
Average ignition time: the ignition time of each group of samples prepared in examples 1-9 and comparative examples 1-3 is measured by referring to GB/T5455-; wherein, the shorter the average ignition time, the more easily the antibacterial and antistatic fabric is ignited.
TABLE 2 Performance test data
| Item | Example 1 | Example 2 | Example 3 | Example 4 |
| Inhibition rate/%) | 91.5 | 92.2 | 93.3 | 91.7 |
| Surface resistivity/omega | 3.25*106 | 3.27*106 | 3.22*106 | 3.28*106 |
| Average ignition time/s | 5.4 | 5.2 | 4.9 | 16.8 |
| Item | Example 5 | Example 6 | Example 7 | Example 8 |
| Inhibition rate/%) | 99.4 | 99.6 | 99.6 | 99.5 |
| Surface resistivity/omega | 3.21*106 | 3.19*106 | 3.23*106 | 2.69*106 |
| Ignition time/s | 18.3 | 18.9 | 6.5 | 18.5 |
| Item | Example 9 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Inhibition rate/%) | 99.3 | 63.6 | 68.4 | 74.9 |
| Surface resistivity/omega | 3.22*106 | 3.25*106 | 3.27*106 | 3.24*106 |
| Average ignition time/s | 18.8 | 5.1 | 4.8 | 5.3 |
As can be seen by combining example 1 and comparative examples 1 to 3, and by combining Table 2, the nano titanium dioxide and the ultraviolet absorber are added simultaneously in example 1, the nano titanium dioxide and the ultraviolet absorber in the comparative example 1 are respectively replaced by the same amount of nano graphene oxide, the nano-titanium dioxide in the comparative example 2 is replaced by the same amount of nano-graphene oxide, the ultraviolet absorber in the comparative example 3 is replaced by the same amount of nano-graphene oxide, as can be seen from the data in Table 2, the bacteriostatic rate of the fabric in example 1 is significantly higher than that of the fabric in comparative examples 1-3, and the surface resistivity of the fabric in the embodiment 1 is not much different from the surface resistivity of the fabric in the comparative examples 1 to 3, which shows that the nano titanium dioxide and the ultraviolet absorber in the application have synergistic effect, and the antibacterial effect of the antibacterial and antistatic fabric can be effectively improved.
It can be seen from the combination of example 1 and examples 3-7 and table 2 that example 3 is based on example 1 and is added with ferric stearate, example 4 is based on example 1 and is added with phosphite, examples 5 and 6 are based on example 1 and are added with ferric stearate and phosphite simultaneously, and example 7 is based on example 5 and is replaced with phenyl salicylate for the ultraviolet light absorber UV-320; wherein, the sum of the total amount of the ferric stearate and the phosphite in the example 5 is equal to the addition amount of the ferric stearate in the example 3 and the addition amount of the phosphite in the example 4; as can be seen from the data in table 2, the bacteriostatic rate of the fabric only with ferric stearate or the fabric only with phosphite is much lower than that of the fabric with ferric stearate and phosphite, which indicates that ferric stearate and phosphite have a synergistic effect, and the antibacterial performance of the fabric can be further improved, so that the fabric has good antibacterial performance and antistatic performance; in addition, it can be seen from table 2 that the average ignition time of the fabric with only iron stearate is much lower than that of the fabric with only phosphite or both iron stearate and phosphite, and when phenyl salicylate is used in example 7 instead of the UV-320, the average ignition time of the fabric in example 7 is also significantly reduced, which indicates that the phosphite and the UV-320 in the present application have a synergistic effect, so that the fabric is not easy to ignite.
As can be seen from the combination of example 5 and examples 8-9 and table 2, the antibacterial and antistatic fabric of example 5 and examples 8-9 is different from each other in the average particle size of diatomite, wherein when the average particle size of diatomite is in the range of 4.5-5.5nm, the surface resistivity of the antibacterial and antistatic fabric is further reduced, that is, the antistatic performance of the antibacterial and antistatic fabric is further improved.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.
Claims (10)
1. The preparation method of the antibacterial and antistatic fabric is characterized by comprising the following steps of: s1, feeding the fabric into the antibacterial antistatic dispersion liquid, ultrasonically soaking for 15-30S, and taking out to obtain a pretreated fabric;
s2, drying the pretreated fabric until the water content of the pretreated fabric is lower than 85% to obtain the dried pretreated fabric;
s3, drying the pressed and dried pretreated fabric at the temperature of 45-65 ℃ to obtain the antibacterial and antistatic fabric;
the antibacterial antistatic dispersion liquid is prepared from the following raw materials in parts by weight:
nano titanium dioxide: 3-6 parts of
Ultraviolet light absorber: 0.3 to 0.6 portion
Nano graphene oxide: 0.6 to 1 portion
Diatomite: 2-5 parts of
Silver nitrate: 0.05 to 0.1 portion
Water: 50 portions of
Dispersing agent: 0.5-1 part.
2. The preparation method of the antibacterial and antistatic fabric according to claim 1 is characterized in that: the preparation method of the antibacterial antistatic dispersion liquid comprises the following steps:
preparing an activated antibacterial agent:
ball-milling the mixture of the nano titanium dioxide, the ultraviolet absorber and the nano graphene oxide at the ball-milling speed of 150 and 250rad/min for 1-3h to obtain the antibacterial agent;
irradiating the antibacterial agent under ultraviolet light for 30-60min to obtain activated antibacterial agent;
preparing an antistatic agent:
adding silver nitrate into water, and stirring and dissolving to obtain a silver nitrate solution;
adding diatomite into a silver nitrate solution, and uniformly stirring to obtain an antistatic agent;
preparing an antibacterial antistatic dispersion liquid:
adding an activated antibacterial agent and a dispersing agent into an antistatic agent, and dispersing by ultrasonic vibration to obtain an antibacterial antistatic dispersion liquid.
3. The preparation method of the antibacterial and antistatic fabric according to claim 1 is characterized in that: the ultraviolet light absorber is any one or a combination of more of salicylate ultraviolet light absorber, benzophenone ultraviolet light absorber and benzotriazole ultraviolet light absorber.
4. The preparation method of the antibacterial and antistatic fabric according to claim 1 is characterized in that: the antibacterial antistatic dispersion liquid also comprises the following raw materials in parts by weight:
metal salts of stearic acid: 0.8 to 1.2 portions of
Phosphite ester: 1-1.5 parts.
5. The preparation method of the antibacterial and antistatic fabric according to claim 4 is characterized in that: the preparation method of the antibacterial antistatic dispersion liquid comprises the following steps:
preparing an activated antibacterial agent:
ball-milling a mixture of nano titanium dioxide, an ultraviolet absorber, a metal stearate, phosphite ester and nano graphene oxide at the ball-milling speed of 150-250rad/min for 1-3h to obtain an antibacterial agent;
irradiating the antibacterial agent under ultraviolet light for 30-60min to obtain activated antibacterial agent;
preparing an antistatic agent:
adding silver nitrate into water, and stirring and dissolving to obtain a silver nitrate solution;
adding diatomite into a silver nitrate solution, and uniformly stirring to obtain an antistatic agent;
preparing an antibacterial antistatic dispersion liquid:
adding an activated antibacterial agent and a dispersing agent into an antistatic agent, and dispersing by ultrasonic vibration to obtain an antibacterial antistatic dispersion liquid.
6. The preparation method of the antibacterial and antistatic fabric according to claim 4 is characterized in that: the metal stearate is one or more of calcium stearate, zinc stearate, magnesium stearate and ferric stearate.
7. The preparation method of the antibacterial and antistatic fabric according to claim 4 or 5, characterized by comprising the following steps: the ultraviolet light absorber is a benzotriazole ultraviolet light absorber, and the benzotriazole ultraviolet light absorber is any one or a composition of more of UV-320, UV-326, UV-327, UV-328, UV-510 and UV-5411.
8. The preparation method of the antibacterial and antistatic fabric according to claim 1 is characterized in that: the average particle size of the diatomite is 4.5-5.5 nm.
9. The preparation method of the antibacterial and antistatic fabric according to claim 1 is characterized in that: the dispersant is one or a combination of more of polyethylene glycol 200 and polyethylene glycol 400.
10. An antibacterial and antistatic fabric is characterized in that: the antibacterial antistatic fabric is prepared by the preparation method of the antibacterial antistatic fabric as claimed in any one of claims 1 to 9.
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Cited By (6)
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| CN112962168A (en) * | 2021-02-05 | 2021-06-15 | 刘德生 | Antibacterial and anti-mite functional fabric |
| CN112981936A (en) * | 2021-03-19 | 2021-06-18 | 广州市龙格派服饰有限公司 | Convenient-to-wear student garment with antibacterial function |
| CN113502657A (en) * | 2021-07-14 | 2021-10-15 | 苏州绿仕环保科技有限公司 | Graphene oxide metal ion composite antibacterial filter element and preparation method thereof |
| CN115559115A (en) * | 2022-09-30 | 2023-01-03 | 深圳华域佳泰纺织科技有限公司 | Preparation method of anti-wool-absorption fabric |
| CN115928422A (en) * | 2022-12-28 | 2023-04-07 | 石狮市宏兴染整织造有限公司 | Preparation method of antibacterial ultraviolet-proof fabric |
| CN116289003A (en) * | 2022-12-09 | 2023-06-23 | 新秀集团有限公司 | Mildew-proof case fabric and preparation method thereof |
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