[go: up one dir, main page]

CN1122285C - Cable insulation structure - Google Patents

Cable insulation structure Download PDF

Info

Publication number
CN1122285C
CN1122285C CN94113695A CN94113695A CN1122285C CN 1122285 C CN1122285 C CN 1122285C CN 94113695 A CN94113695 A CN 94113695A CN 94113695 A CN94113695 A CN 94113695A CN 1122285 C CN1122285 C CN 1122285C
Authority
CN
China
Prior art keywords
layer
matrix
semiconductor layer
insulation
cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN94113695A
Other languages
Chinese (zh)
Other versions
CN1108789A (en
Inventor
马德雷恩·普里冈
罗伯特·加德索
朱塞·伯齐耶
哈冈·亚纳赫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nike Texas France Ltd By Share Ltd
Original Assignee
Alcatel Cable SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9451076&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1122285(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Alcatel Cable SA filed Critical Alcatel Cable SA
Publication of CN1108789A publication Critical patent/CN1108789A/en
Application granted granted Critical
Publication of CN1122285C publication Critical patent/CN1122285C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • H01B9/027Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of semi-conducting layers

Landscapes

  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Installation Of Indoor Wiring (AREA)
  • Insulating Bodies (AREA)

Abstract

本发明的内容是关于一种电缆绝缘结构,它至少包括第一层即与电缆芯线同轴并相接触的半导体层;它外面包着第二层—电绝缘层;第二层外面包着第三层—半导体层,其特征在于:上述半导体层专门由某种基质组成,该基质含有其组成分子量高于1000的非极性聚合物和导电物质电荷。

The content of the present invention relates to a cable insulation structure, which at least includes a first layer, that is, a semiconductor layer that is coaxial with the cable core and is in contact with it; it is wrapped with a second layer—an electrical insulation layer; the second layer is wrapped with The third layer—semiconductor layer, is characterized in that: the above-mentioned semiconductor layer is exclusively composed of a certain matrix, which contains a non-polar polymer with a molecular weight higher than 1000 and electric charges of a conductive substance.

Description

Cable insulation structure
Involved in the present invention is a kind of insulation system of middle pressure, high pressure and superhigh voltage DC or ac cable.
Usually, these cables all are to be made of conductive cable heart yearn and the outsourcing insulation system coaxial with it.This insulation system generally comprises three-decker at least: ground floor is and the contacted semiconductor layer of cable core; The second layer is the electric insulation layer that wraps in the ground floor outside; The 3rd layer is the semiconductor layer that wraps in second layer outside.Some other surrounding layer is used for protecting cable.
In general, insulating barrier all is with high density or low density polyethylene (LDPE), or crosslinked polyethylene, or the ethylene-propylene-diene terpolymer (EPDM) of band methylene main chain is a main component.
Semiconductor layer all is made of a kind of polarization matrix usually, and modal is ethene and alkyl acrylic salt copolymer, load carbon black.Its loadings is that the character according to used carbon black changes.The loadings ratio is usually between 28% to 40% for acetylene carbon black or oven process carbon black.
The insulation of this class cable (dielectric) intensity is very relevant with the interface quality between the insulating barrier with semiconductor layer.Interface between semiconductor layer and the insulating barrier is even there is a bit coarse injustice all can cause the enhancing of electric field, to such an extent as to insulating barrier takes place to puncture and destroyed.
In order in extrusion process, to obtain level and smooth as far as possible interface, at present normally being about 17 polymer with a kind of high melt index or high-melt index (melt index) as the matrix of the semiconductor layer of the high-tension cable of commodity is main component, (high-melt index represents to exist low-molecular-weight, usually measure according to ASTM D1238 standard or NFT51-O16 standard), polymer has very wide molecular weight distribution.Yet it is found that near the electric charge that has living space in the insulating barrier semiconductor layer occurs, the accumulation of space charge can cause the destruction of insulating barrier insulation property, until the puncture that causes insulating barrier.
Some producer of semiconductor layer uses with the matrix (EPR: ethylene-propylene thermoplastic and high-elastic of ethylene copolymer as main component, or EPDM: the ethylene-propylene-diene terpolymer of methylene main chain), toward wherein adding lubricating oil or plasticizer, so that obtain semiconductor surface attitude preferably easily.Yet these lubricating oil or plasticizer are diffused in the insulating barrier and in the very strong semiconductor layer of electric field and the zone that forms a non-constant of insulation property at the interface of insulating barrier.
Purpose of the present invention is intended to work out a kind of insulation system that is used for carrying pressure, high pressure or the extra-high-tension cable of direct current or alternating current, and its insulation property are than the insulation property of known any insulation system in running are all more stable at present.
This cable insulation structure that the present invention introduced is made up of three-decker at least: ground floor is to contact with cable core and coaxial semiconductor layer; The second layer is the electric insulation layer that wraps in the ground floor outside; The 3rd layer is the semiconductor layer that wraps in second layer outside.Semiconductor layer is made up of the matrix that contains non-polar polymer specially, and the molecular weight of this polymers compositions also contains conductive material (electric charge) greater than 1000.
The molecular weight of matrix components preferably can surpass 5000.
If semiconductor layer contains low-molecular-weight compound or additive, resemble lubricating oil or plasticizer etc., these compounds can move in insulating barrier, and the result of this phenomenon has formed space charge, this will cause the enhancing of electric field, thereby might cause later puncture.The enhancing of electric field is relevant with the quantity of electric charge of formation, but also depends on simultaneously the mobility of electric charge: the electric charge of equal number can't resemble when evenly distributing and concentrate the reinforcement that causes electric field distributing.This transport phenomena can produce in the transmission of electricity process of using cable or cable voluntarily.
Only include the high-molecular weight compounds composition in the semiconductor layer constituent of the present invention, this can be avoided the migration of electric charge in insulating barrier to reach the accumulation of the near interface space charge that causes therefrom.
According to first kind of embodiment, matrix is selected from following material: polyethylene, polypropylene, polystyrene and their copolymer, alloyed polymer (from polyethylene, polypropylene, polystyrene and their copolymer, choosing), mixture of compound (, selecting in their copolymer) and blending copolymer above-mentioned from polyethylene, polypropylene, polystyrene.
According to second kind of embodiment of the present invention, the matrix thing is chosen out from polylefin thermoplatic elastomer and composition thereof.
The selection that constitutes the polymer of matrix has determined the quality of itself and interfacial dielectric layer and the mechanical property of the semiconductor layer that makes, and need not to use additive.
Superiority of the present invention is to make the insulation property of insulation system to be stablized, and has also solved the migration problem of low-molecular-weight constituent simultaneously.So just make the interface quality between the different layerings find no fault with.The carbon black that is loaded requires pure as much as possible.People can use the oven process carbon black or use a kind of " KETJEN " carbon black, but preferably select more pure acetylene carbon black for use.
In some cases, also include crosslinking agent in the matrix in addition.Behind the material extrusion molding, people can carry out crosslinking Treatment so that improve its thermal deformation behavior to it.The requirement of this thermal deformation behavior is strict especially for the cable of carrying alternating current.
Other characteristics of the present invention and superiority thereof will show in the following description to embodiment.These embodiments are typical and also not exclusive, have with reference to accompanying drawing simultaneously.Have among the figure:
What Fig. 1 represented is the total block diagram of shock wave experimental provision.
Fig. 2 describes the insulation system sample top view of using for surge test.
Fig. 3 is described to be the profile of sample among Fig. 2.
Surge test will be carried out by means of the device of describing among Fig. 1.This test can calculate the enhancing of electric field in the insulation system.
The sample 1 that is used for the insulation system of surge test is to represent with the top view of Fig. 2, and represents with profile in Fig. 3.On the circular surface of 20mm diameter A, can see some laminations:
-ground floor is a semiconductor layer 2, and thickness B is 0.5mm.
-the second layer is an electric insulation layer 3, and thickness C is 0.8mm.
-Di is a semiconductor layer 4 for three layers, and thickness is identical with layer 2.
Device among Fig. 1 comprises " YAg " (yttrium-aluminium-garnet) laser 10, and its light beam is mapped on the target 11 of counter sample 1, and each semiconductor layer in the sample 1 all forms positive pole (+) and negative pole (-).This light beam is absorbed by (-) utmost point 2 surfaces, makes this surperficial pyrolysis, and the gas that is exhaled in the pyrolysis produces pressure (impact) ripple and passes sample.The indication of volume charge density in picture intelligence electric charge on this pressure wave modulator electrode and the sampling.
Photodiode 12 can make detector 13 and laser 10 synchronous.Circuit is by high voltage source 14 power supplies that resistor 15 is housed.The data of noting are converted, for 16 (processors) that use a computer are handled and reflected on a chart recorder 17 along with the variation of time in running.Laser 10 is transmitted into light wave on the target (target) 11, causes the appearance of space charge and changes Electric Field Distribution, and this electric field can be measured by detector 13.
Embodiment 1
Produce the sample of the similar insulation system of the sample introduced with Fig. 2 according to prior art, it comprises:
Ground floor is a semiconductor layer, it is made of the polarity matrix that with ethene-alkyl acrylic salt copolymer is main component, its " melt index (MI) " value is 8, and the content of its ester is 20%, and the acetylene carbon black filler that is loaded is that 66 parts of carbon blacks are than 100 parts of stroma ground substances with the weight ratio of matrix.
The electric insulation layer of the second layer, it is made of the olefin hydrocarbons thermoplasticity elastomer.
The 3rd layer is that its structure of semiconductor layer is formed identical with ground floor.
This sample carries out surge test by means of the device among Fig. 1.The result is near the negative electrical charge that has occurred the vast scale scope negative pole 2.The enhancing of electric field surpasses 20%, and the several hrs electric charge still falls into and stays in the matrix thing after voltage interruption.
Embodiment 2
According to the similar insulation system sample of sample that prior art for preparing and Fig. 2 are introduced, it comprises:
Ground floor is a semiconductor layer, it is made of the polarization matrix thing that with ethene-alkyl acrylic salt copolymer is main component, its copolymer " melt index (MI) " value is 8, and the content of its ester is 20%, and the acetylene carbon black that is loaded is that 66 parts of carbon blacks are than 100 parts of matrix things with the weight ratio of matrix thing.
The electric insulation layer of the second layer is made of processes for chemically crosslinked polyethylene (PRC).
The 3rd layer is that its structure of semiconductor layer is formed identical with ground floor.
This sample carries out surge test by means of the device among Fig. 1.A large amount of negative electrical charges has appearred in the result near negative pole 2, and still falls in behind interrupt voltage several hours and stay in the insulating barrier matrix.The enhancing of electric field surpasses 20%.
Embodiment 3
The sample of the insulation system of the present invention that the sample that making and Fig. 2 are introduced is similar, it comprises:
Ground floor is a semiconductor layer, and it is made up of nonpolar matrix, and toward wherein adding acetylene carbon black, weight ratio is that 66 parts of carbon blacks are than 100 parts of matrix things; Contain 20% polyethylene (PE) in the matrix thing, its " melt index (MI) " value is 2, and its molecular weight is 10 3-10 7Between, and with 1.1 * 10 6Be the center; Other 80% is ethylene-propylene copolymer, wherein contains weight and is about " MOONEY " viscosity of 50% (according to the NFT43005 canonical measure) and is about 40, and molecular weight is 10 310 7Between, (with 1.2 * 10 5Be the center) ethene.
The second layer is an electric insulation layer, is made of processes for chemically crosslinked polyethylene (PRC).
The 3rd layer is that its formation of semiconductor layer is identical with ground floor.
This sample carries out the surge test test by means of the device among Fig. 1.The enhancing of electric field after voltage interruption, no longer includes in the dielectric substrate to fall into and stays electric charge to exist in 10%.
Embodiment 4
Produce the similar insulation system sample of being introduced with Fig. 2 of the present invention of sample, it comprises:
Ground floor is a semiconductor layer, and it is made up of non-polarised matrix, and toward wherein adding acetylene carbon black, its weight ratio is that 66 parts of carbon blacks are than 100 parts of matrix; Contain 20% polyethylene (PE) in the matrix, its " melt index (MI) " value is 2, and its molecular weight is with 1.1 * 10 6Be the center; In addition 80% be ethylene-propylene copolymer, wherein contain weight and be about 50% ethene, its " MOONEY " viscosity (according to the NFT43005 standard) is about 40, its molecular weight is 10 3-10 7Between, and with 1.2 * 10 5Be the center.
The second layer is an electric insulation layer, is made of the olefin hydrocarbons thermoplasticity elastomer.
The 3rd layer is semiconductor layer, and its formation is identical with ground floor.
This sample carries out surge test by means of the device among Fig. 1.Its electric field strengthens in 10%, after the voltage interruption, no longer includes in the insulation material to fall into and stays electric charge to exist.
Embodiment 5 comparative examples
Describe similar sample among preparation and the embodiment 4, but will be the paraffin oil of matrix thing 5% toward adding weight in the semiconductor layer matrix.
This sample carries out the surge test test by means of the device among Fig. 1.The electric field enhancing is 140% in this case.
Certainly, the present invention is not limited to several embodiments described above, but do not depart from can have under the situation about the invention is intended to many can be by the enforcement modification that the technical staff accepted.Particularly, people can adopt the scheme in the alternative above-mentioned description of all efficient ways in being suitable for scope of the present invention.

Claims (8)

1.电缆绝缘结构,它至少包括半导体第一层,该层与电缆芯线同轴并互相接触,半导体第一层外面包围着电绝缘第二层,电绝缘第二层外面包的是半导体第三层,其特征在于:上述各半导体层都专门由一种基质组成,该基质物只含有其组成分子量高于1000的非极性聚合物和导电物料。1. Cable insulation structure, which includes at least the first layer of semiconductor, which is coaxial with the cable core and contacts each other. The first layer of semiconductor is surrounded by the second layer of electrical insulation, and the second layer of electrical insulation is surrounded by the second layer of semiconductor. Three layers, characterized in that each of the above-mentioned semiconductor layers is exclusively composed of a matrix, and the matrix only contains non-polar polymers and conductive materials whose composition molecular weight is higher than 1000. 2.根据权利要求1所述的绝缘结构,其中上述基质物的组成成分的分子量高于5000。2. The insulating structure according to claim 1, wherein the molecular weight of the constituents of the matrix substance is higher than 5000. 3.根据权利要求1或2中任一项所述的电缆绝缘结构,其中所述基质是从以下物质中选择的:聚乙烯、聚丙烯、聚苯乙烯及它们的共聚物,从聚乙烯、聚丙烯、聚苯乙烯,及其共聚物中选取的掺混共聚物及上述各化合物的混合物。3. The cable insulation structure according to any one of claims 1 or 2, wherein said matrix is selected from the following materials: polyethylene, polypropylene, polystyrene and their copolymers, from polyethylene, Blended copolymers selected from polypropylene, polystyrene, and copolymers thereof, and mixtures of the above-mentioned compounds. 4.根据权利要求1或2所述的绝缘结构,所述基质物是从聚烯烃热塑性高弹体及其混合物中选取的。4. The insulation structure according to claim 1 or 2, said matrix material is selected from polyolefin thermoplastic elastomers and mixtures thereof. 5.根据权利要求1或2所述的绝缘结构,其中所说的装填物料是乙炔炭黑。5. An insulating structure according to claim 1 or 2, wherein said filler material is acetylene black. 6.根据权利要求3所述的绝缘结构,其中所说的装填物料是乙炔炭黑。6. The insulating structure of claim 3, wherein said filler material is acetylene black. 7.根据权利要求4所述的绝缘结构,其中所说的装填物料是乙炔炭黑。7. The insulating structure of claim 4, wherein said filler material is acetylene black. 8.根据权利要求1所述的绝缘结构,所述基质物中另外还有交联剂。8. The insulation structure according to claim 1, wherein said matrix material additionally contains a cross-linking agent.
CN94113695A 1993-09-21 1994-09-21 Cable insulation structure Expired - Fee Related CN1122285C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9311234 1993-09-21
FR9311234A FR2710447B1 (en) 1993-09-21 1993-09-21 Isolation structure for cable.

Publications (2)

Publication Number Publication Date
CN1108789A CN1108789A (en) 1995-09-20
CN1122285C true CN1122285C (en) 2003-09-24

Family

ID=9451076

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94113695A Expired - Fee Related CN1122285C (en) 1993-09-21 1994-09-21 Cable insulation structure

Country Status (7)

Country Link
EP (1) EP0644558B2 (en)
JP (1) JP3658018B2 (en)
KR (1) KR100323179B1 (en)
CN (1) CN1122285C (en)
DE (1) DE69418804T3 (en)
DK (1) DK0644558T4 (en)
FR (1) FR2710447B1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004178867A (en) * 2002-11-25 2004-06-24 Mitsubishi Cable Ind Ltd Power cable
EP1634913B1 (en) 2004-09-10 2008-10-29 Borealis Technology Oy Semiconductive polymer composition
JP4866545B2 (en) * 2004-12-03 2012-02-01 株式会社フジクラ Cable and twisted cable
CH698074B1 (en) * 2005-11-11 2009-05-15 Studer Ag Draht & Kabelwerk Multi-conductor cable for transmitting rectangular extending alternating currents.
EP2711934B1 (en) * 2012-09-25 2018-07-11 Nexans Silicone multilayer insulation for electric cable

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4612139A (en) * 1981-01-30 1986-09-16 Nippon Unicar Co. Limited Semi-conductive polyolefin compositions and cables covered with same
JP4056009B2 (en) * 2000-01-31 2008-03-05 東芝テック株式会社 Inline type pump

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54115798A (en) 1978-03-01 1979-09-08 Fujikura Ltd Semiconductive composition for power cable
JPS5562610A (en) 1978-10-31 1980-05-12 Dainichi Nippon Cables Ltd Power cable
JPS57199108A (en) 1981-06-01 1982-12-07 Showa Electric Wire & Cable Co Crosslinked polyethylene insulated power cable
BR8907103A (en) 1988-09-30 1991-02-05 Exxon Chemical Patents Inc MIXTURES OF LINEAR ETHYLENE INTERPOLYMERS OF INTERPOLYMERS HAVING NARROW DISTRIBUTIONS OF MOLECULAR WEIGHT AND COMPOSITION
JP3081218B2 (en) * 1990-06-22 2000-08-28 財団法人電力中央研究所 Method for improving semiconductive layer interface of polyolefin insulated cable
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4612139A (en) * 1981-01-30 1986-09-16 Nippon Unicar Co. Limited Semi-conductive polyolefin compositions and cables covered with same
JP4056009B2 (en) * 2000-01-31 2008-03-05 東芝テック株式会社 Inline type pump

Also Published As

Publication number Publication date
EP0644558B2 (en) 2003-05-28
KR100323179B1 (en) 2002-06-27
KR950009752A (en) 1995-04-24
CN1108789A (en) 1995-09-20
DE69418804T2 (en) 1999-12-09
EP0644558B1 (en) 1999-06-02
DK0644558T4 (en) 2003-09-22
DE69418804T3 (en) 2004-04-01
FR2710447A1 (en) 1995-03-31
FR2710447B1 (en) 1995-11-10
JPH07169324A (en) 1995-07-04
DK0644558T3 (en) 1999-12-13
JP3658018B2 (en) 2005-06-08
DE69418804D1 (en) 1999-07-08
EP0644558A1 (en) 1995-03-22

Similar Documents

Publication Publication Date Title
EP2092535B1 (en) Energy cable
CA2626131C (en) Energy cable comprising a dielectric fluid and a mixture of thermoplastic polymers
US4621169A (en) Electric cable construction and uses therefor
EP2556516B1 (en) Primary wire for marine and sub-sea cable
AU2010366056B2 (en) Energy cable having stabilized dielectric resistance
AU2004206275A1 (en) Cable with recyclable covering layer
US6005192A (en) Jacket for insulated electric cable
CN1122285C (en) Cable insulation structure
WO2019147027A1 (en) Power cable
US20160096950A1 (en) Voltage-stabilized polymeric compositions
Burns et al. Stress controlling semiconductive shields in medium voltage power distribution cables
CN1276907A (en) Composition for electric cable
EP0971368B1 (en) Semiconductive material, method for producing it and cable jacketed with it
US20210115233A1 (en) Power cable
CN1124868A (en) Cable d'energie a rigidite dielectrique amelioree
JPH02504091A (en) Electrical wire
JP3901790B2 (en) DC cross-linked polyethylene insulated power cable
KR100236782B1 (en) Resin for controlling charge distribution
WO2021176183A1 (en) Cable comprising a semiconductor layer having a smooth surface
CN1462040A (en) Low-voltage cable sheath
WO2023047029A1 (en) Electric cable comprising a semiconductor layer having a smooth surface
JPS5998403A (en) Semiconductive composition
RU40526U1 (en) POWER CABLE
Han et al. New semiconductive compound technology for solid dielectric insulated power cables
JPH01274307A (en) Conductive composite for power cable

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: ARCA KUMBUM CABLE FRANCE CO., LTD.

Free format text: FORMER OWNER: ALCATEL CABLE

Effective date: 20010712

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20010712

Applicant after: Alcatel Cable

Applicant before: Alcatel Cable

C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: NIKE SARY FRANCH CO., LTD.

Free format text: FORMER OWNER: ARCA KUMBUM CABLE FRANCE CO., LTD.

Effective date: 20080808

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20080808

Address after: France

Patentee after: Nike, Texas, France, Limited by Share Ltd

Address before: The French plug DEX.

Patentee before: Alcatel Cable

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030924

Termination date: 20120921