CN111928267A - Garbage incinerator fire grate segment with metal ceramic sheet embedded on surface and preparation method thereof - Google Patents
Garbage incinerator fire grate segment with metal ceramic sheet embedded on surface and preparation method thereof Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000919 ceramic Substances 0.000 title abstract description 16
- 229910052751 metal Inorganic materials 0.000 title abstract description 15
- 239000002184 metal Substances 0.000 title abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 30
- 238000005299 abrasion Methods 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 238000005266 casting Methods 0.000 claims abstract description 15
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- 239000011812 mixed powder Substances 0.000 claims description 18
- 239000002699 waste material Substances 0.000 claims description 16
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 238000007133 aluminothermic reaction Methods 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000005495 investment casting Methods 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/04—Casting in, on, or around objects which form part of the product for joining parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
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Abstract
Description
技术领域technical field
本发明属于表面工程技术领域,涉及一种表面镶嵌金属陶瓷片的垃圾焚烧炉炉排片及其制备方法。The invention belongs to the technical field of surface engineering, and relates to a garbage incinerator grate sheet with a surface inlaid metal ceramic sheet and a preparation method thereof.
背景技术Background technique
垃圾焚烧炉炉排片在炉内的高温、腐蚀性气体和摩擦磨损条件下推送燃烧着的垃圾,与垃圾接触的表面磨蚀严重,因目前炉排片材质为1Gr18Ni9Ti,耐腐蚀性能很好,主要是高温磨损失效。国产化垃圾焚烧炉炉排片使用寿命短(7-10个月),影响焚烧炉的长周期稳定使用,迫切需要通过设计、材料、工艺等方面的改进,提高炉排片的服役周期。The grate sheet of the garbage incinerator pushes the burning garbage under the conditions of high temperature, corrosive gas and friction and wear in the furnace, and the surface in contact with the garbage is seriously eroded. Because the material of the grate sheet is currently 1Gr18Ni9Ti, the corrosion resistance is very good, mainly high temperature wear failure. Domestic waste incinerator grate slices have a short service life (7-10 months), which affects the long-term stable use of the incinerator. It is urgent to improve the service cycle of the grate slices through improvements in design, materials, and processes.
发明内容SUMMARY OF THE INVENTION
本发明目的之一在于为克服上述不足,提供一种表面镶嵌金属陶瓷片的垃圾焚烧炉炉排片,该炉排片具有较长的服役周期。One of the objectives of the present invention is to provide a garbage incinerator grate sheet with a surface inlaid metal ceramic sheet in order to overcome the above deficiencies, and the grate sheet has a longer service period.
本发明目的之二在于提供上述炉排片的制备方法,该方法制备工艺简单,且所制备的垃圾焚烧炉炉排片表面镶嵌金属陶瓷片与炉排片表面结合强度高,使用寿命长。The second purpose of the present invention is to provide a preparation method of the above-mentioned grate sheet, which has a simple preparation process, and the surface of the prepared garbage incinerator grate sheet is inlaid with a metal ceramic sheet and has a high bonding strength and a long service life.
为此,本发明第一方面提供了一种表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片,其包括炉排片、分布于炉排片易磨蚀区表面的多个凹坑,以及镶嵌于凹坑内的金属陶瓷片。To this end, the first aspect of the present invention provides an abrasion-resistant garbage incinerator grate sheet with a surface inlaid cermet sheet, which includes a grate sheet, a plurality of pits distributed on the surface of the easily erodible area of the grate sheet, and inlaid in the concave Cermet sheet inside the pit.
根据本发明,炉排片易磨蚀区表面的凹坑是在炉排片铸造成形时生成;所述凹坑的底部平坦,深度为2-3mm;优选地,相邻两个凹坑之间彼此相连并通过共用一个侧壁彼此分隔,进一步优选地,所述侧壁的厚度为2-3mm。According to the present invention, the pits on the surface of the easily erodable area of the grate sheet are formed when the grate sheet is cast and formed; the bottom of the pit is flat and the depth is 2-3 mm; preferably, two adjacent pits are connected to each other and They are separated from each other by sharing a side wall, further preferably, the thickness of the side wall is 2-3mm.
本发明中,凹坑包括多边形凹坑、圆形凹坑、椭圆形凹坑和曲边多边形凹坑中的一种或几种;所述多边形包括矩形、正方形、菱形、六边形中的一种或多种;所述曲边多边形包括曲边矩形、曲边正方形、曲边菱形、曲边六边形中的一种或多种。In the present invention, the pits include one or more of polygonal pits, circular pits, elliptical pits and curved polygonal pits; the polygons include one or more of rectangle, square, rhombus, and hexagon. one or more; the curved polygon includes one or more of a curved rectangle, a curved square, a curved rhombus, and a curved hexagon.
根据本发明,所述金属陶瓷片通过自蔓延反应铸焊法镶嵌于凹坑内;优选地,所述金属陶瓷片与凹坑的侧壁和底部为冶金结合。According to the present invention, the cermet sheet is embedded in the pit by a self-propagating reaction casting welding method; preferably, the cermet sheet and the side wall and bottom of the pit are metallurgically bonded.
本发明中,所述金属陶瓷片含有Ti、C和Mo;优选地,所述金属陶瓷片为TiCMo金属陶瓷片。In the present invention, the cermet sheet contains Ti, C and Mo; preferably, the cermet sheet is a TiCMo cermet sheet.
本发明第二方面提供了如本发明第一方面所述的表面镶嵌金属陶瓷片的垃圾焚烧炉炉排片的制备方法,其包括:The second aspect of the present invention provides a method for preparing a garbage incinerator grate sheet with a surface inlaid cermet sheet as described in the first aspect of the present invention, comprising:
步骤B,将C粉末、Ti粉末和Mo粉末混合后进行球磨细化后,制成TiCMo混合粉料;In step B, the C powder, the Ti powder and the Mo powder are mixed and then ball-milled and refined to prepare a TiCMo mixed powder;
步骤C,将TiCMo混合粉料装入多边形模具中,压制成TiCMo压坯;Step C, the TiCMo mixed powder is loaded into the polygonal mold, and pressed into a TiCMo compact;
步骤D,将铝热反应产生的钢水浇注到炉排片易磨蚀区表面的凹坑后,立即将TiCMo压坯放入凹坑,凹坑中的钢水与炉排片焊接在一起,同时引燃压坯使其发生自蔓延反应,反应产生的高温压坯与钢水焊接在一起,待反应刚刚结束在压坯表面向下加压,将压坯压缩到与侧壁同高,从而得到表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片。In step D, after pouring the molten steel produced by the aluminothermic reaction into the pit on the surface of the easily erodable area of the grate sheet, immediately put the TiCMo compact into the pit, the molten steel in the pit is welded with the grate sheet, and the compact is ignited at the same time. A self-propagating reaction occurs, and the high-temperature green compact produced by the reaction is welded with molten steel. After the reaction is just over, the surface of the green compact is pressed down, and the green compact is compressed to the same height as the side wall, thereby obtaining a surface inlaid cermet sheet. wear-resistant waste incinerator grate pieces.
根据本发明,所述压坯高度为凹坑深度的3-5倍,所述压坯尺寸略小于炉排片表面的凹坑尺寸。According to the present invention, the height of the green compact is 3-5 times the depth of the pit, and the size of the green compact is slightly smaller than the size of the pit on the surface of the grate sheet.
在本发明的一些实施例中,所述TiCMo混合粉料中,C粉末与Ti粉末的原子比为1:1,Mo粉末的用量为C粉末和Ti粉末总质量的5%。In some embodiments of the present invention, in the TiCMo mixed powder, the atomic ratio of C powder to Ti powder is 1:1, and the amount of Mo powder is 5% of the total mass of C powder and Ti powder.
根据本发明方法,在步骤B之前还包括步骤A,用精密铸造工艺成形炉排片,且在炉排片易磨蚀部位铸造出多个凹坑。According to the method of the present invention, before step B, it also includes step A, forming the grate sheet by a precision casting process, and casting a plurality of pits on the erodible part of the grate sheet.
本发明中,所述凹坑的底部平坦,深度为2-3mm;优选地,相邻两个凹坑之间彼此相连并通过共用一个侧壁彼此分隔,进一步优选地,所述侧壁的厚度为2-3mm。In the present invention, the bottom of the pit is flat and the depth is 2-3 mm; preferably, two adjacent pits are connected to each other and separated from each other by sharing a side wall, further preferably, the thickness of the side wall 2-3mm.
本发明的有益效果是:The beneficial effects of the present invention are:
碳化钛(TiC)是金属陶瓷,具有很高的高温化学稳定性,与盐酸、硫酸几乎不起化学反应,极耐腐蚀,是炉排片表面防磨蚀涂层的最佳选择。碳化钛(TiC)原子间以很强的共价键结合,涂层内聚强度高,用做炉排片涂层具有很强的抗磨蚀能力。具有高的熔点、沸点和硬度,硬度仅次于金刚石,有良好的导电性,可当作焊接材料与金属焊接。碳化钛是典型的过渡金属碳化物。它是由离子键、共价键和金属键混合在同一晶体结构中,晶体的结构决定了其具有高硬度、高熔点、耐磨损以及导电性等基本特征。以往TiC被广泛用于制造金属陶瓷,耐热合金、硬质合金、抗磨材料、高温辐射材料以及其它高温真空器件,用做高温耐磨蚀涂层是本发明一个创新。Mo的加入起细化晶粒,提高热强性,在高温时保持足够的强度和抗蠕变能力。侧壁起限制镶块横向移动,提高使用寿命的作用。该方法工艺简单,快速高效,成本低廉,节约能源、镶嵌焊接的陶瓷片结合强度高,使用寿命长。Titanium carbide (TiC) is a cermet with high high temperature chemical stability, almost no chemical reaction with hydrochloric acid and sulfuric acid, and is extremely corrosion-resistant. It is the best choice for anti-abrasion coatings on the surface of grate sheets. Titanium carbide (TiC) atoms are bonded by strong covalent bonds, and the coating has high cohesive strength. It has strong anti-abrasion ability when used as a grate coating. It has high melting point, boiling point and hardness, and its hardness is second only to diamond. It has good electrical conductivity and can be used as a welding material to weld metals. Titanium carbide is a typical transition metal carbide. It is composed of ionic bonds, covalent bonds and metal bonds mixed in the same crystal structure. The crystal structure determines its basic characteristics such as high hardness, high melting point, wear resistance and electrical conductivity. In the past, TiC has been widely used in the manufacture of cermets, heat-resistant alloys, cemented carbides, anti-wear materials, high-temperature radiation materials and other high-temperature vacuum devices. It is an innovation of the present invention to be used as a high-temperature wear-resistant coating. The addition of Mo can refine grains, improve thermal strength, and maintain sufficient strength and creep resistance at high temperatures. The side walls play a role in limiting the lateral movement of the inserts and improving the service life. The method has the advantages of simple process, rapidity and high efficiency, low cost, energy saving, high bonding strength and long service life of the inlaid welded ceramic sheets.
附图说明Description of drawings
下面将结合附图来说明本发明。The present invention will be described below with reference to the accompanying drawings.
图1为易磨蚀区表面具有多个凹坑的垃圾焚烧炉炉排片的示意图。FIG. 1 is a schematic diagram of a garbage incinerator grate sheet with a plurality of pits on the surface of the easily eroded area.
图2为制做TiCMo压坯的模具的示意图。FIG. 2 is a schematic diagram of a mold for making TiCMo compacts.
图3为制做TiCMo压坯的钢板的示意图。FIG. 3 is a schematic diagram of a steel sheet for making TiCMo green compacts.
图4为制做TiCMo压坯的凸模的示意图。FIG. 4 is a schematic diagram of a punch for making TiCMo compacts.
图5为TiCMo压坯的示意图。Figure 5 is a schematic diagram of a TiCMo compact.
图6为表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片的示意图。FIG. 6 is a schematic diagram of a grate sheet of an abrasion-resistant waste incinerator with a cermet sheet inlaid on the surface.
图中附图标记的含义如下:The meanings of the reference numbers in the figure are as follows:
1垃圾焚烧炉炉排片;2凹坑;21凹坑的底部;22凹坑的侧壁;3金属陶瓷片;4制做TiCMo压坯的模具;42模具侧壁;5制做TiCMo压坯的凹模底板;6制做TiCMo压坯的凸模;7TiCMo压坯。1 Garbage incinerator grate sheet; 2 pit; 21 bottom of pit; 22 side wall of pit; 3 cermet sheet; 4 mold for making TiCMo compact; Die bottom plate; 6 punches for making TiCMo compacts; 7TiCMo compacts.
具体实施方式Detailed ways
为使本发明容易理解,下面将结合附图来详细说明本发明。但在详细描述本发明前,应当理解本发明不限于描述的具体实施方式。还应当理解,本文中使用的术语仅为了描述具体实施方式,而并不表示限制性的。In order to facilitate the understanding of the present invention, the present invention will be described in detail below with reference to the accompanying drawings. Before the present invention is described in detail, however, it is to be understood that this invention is not limited to the particular embodiments described. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments and is not intended to be limiting.
除非另有定义,本文中使用的所有术语与本发明所属领域的普通技术人员的通常理解具有相同的意义。虽然与本文中描述的方法和材料类似或等同的任何方法和材料也可以在本发明的实施或测试中使用,但是现在描述了优选的方法和材料。Unless otherwise defined, all terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although any methods and materials similar or equivalent to those described herein can also be used in the practice or testing of the present invention, the preferred methods and materials are now described.
如前所述,现有的垃圾焚烧炉炉排片主要是高温磨损失效,国产化垃圾焚烧炉炉排片使用寿命短(7-10个月),影响焚烧炉的长周期稳定使用。鉴于此,本发明人对于垃圾焚烧炉炉排片耐高温磨蚀技术进行了大量研究。As mentioned above, the existing waste incinerator grate pieces are mainly damaged by high temperature wear, and the domestically produced waste incinerator grate pieces have a short service life (7-10 months), which affects the long-term stable use of the incinerator. In view of this, the inventors have conducted a lot of research on the high temperature abrasion resistance technology of the grate sheets of the waste incinerator.
本发明人研究发现,在炉排片铸造成形时炉排片易磨蚀区表面制成若干凹坑,然后通过自蔓延反应铸焊法将金属陶瓷片镶嵌于凹坑内,由此获得的垃圾焚烧炉炉排片,镶嵌焊接的陶瓷片与炉排片表面结合强度高,使用时不易脱落,使用寿命长。本发明正是基于上述发现做出的。The inventors of the present invention have found that several pits are formed on the surface of the easily erodable area of the grate sheet when the grate sheet is cast and formed, and then the cermet sheet is embedded in the pit by the self-propagating reaction casting and welding method. The waste incinerator grate sheet thus obtained , The inlaid welded ceramic sheet and the surface of the grate sheet have high bonding strength, are not easy to fall off when used, and have a long service life. The present invention has been made based on the above findings.
因此,本发明第一方面所涉及的表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片包括炉排片、分布于炉排片易磨蚀区表面的多个凹坑,以及镶嵌于凹坑内的金属陶瓷片;其中,分布于炉排片易磨蚀区表面的凹坑是在炉排片铸造成形时生成;所述金属陶瓷片通过自蔓延反应铸焊法镶嵌于凹坑内,由此,所述金属陶瓷片与凹坑的侧壁和底部为冶金结合。Therefore, the abrasion-resistant waste incinerator grate sheet with a surface inlaid cermet sheet involved in the first aspect of the present invention includes a grate sheet, a plurality of pits distributed on the surface of the easy-to-wear area of the grate sheet, and a cermet embedded in the pit. Wherein, the pits distributed on the surface of the easy-to-wear area of the grate sheet are generated when the grate sheet is cast and formed; the cermet sheet is embedded in the pit by the self-propagating reaction casting and welding method, whereby the cermet sheet and the The side walls and bottom of the pit are metallurgically bonded.
本发明中,所述凹坑的底部平坦,深度为2-3mm;优选地,相邻两个凹坑之间彼此相连并通过共用一个侧壁彼此分隔,因此,本发明中也将凹坑的侧壁称为棱边进一步优选地,所述侧壁的厚度为2-3mm。In the present invention, the bottom of the pit is flat and the depth is 2-3 mm; preferably, two adjacent pits are connected to each other and separated from each other by sharing a side wall. Therefore, in the present invention, the pits are also The side walls are called edges. Further preferably, the thickness of the side walls is 2-3 mm.
本发明中,所述凹坑包括多边形凹坑、圆形凹坑、椭圆形凹坑和曲边多边形凹坑中的一种或几种;其中,所述多边形包括矩形、正方形、菱形、六边形中的一种或多种;所述曲边多边形包括曲边矩形、曲边正方形、曲边菱形、曲边六边形中的一种或多种。In the present invention, the pits include one or more of polygonal pits, circular pits, elliptical pits and curved polygonal pits; wherein, the polygons include rectangles, squares, rhombuses, hexagons One or more of curved polygons; the curved polygons include one or more of curved rectangles, curved squares, curved rhombus, and curved hexagons.
具体地,所述凹坑包括矩形、正方形、菱形、六边形、曲边矩形、曲边正方形、曲边菱形和曲边六边形中的一种或多种;优选为矩形、六边形和圆形中的一种或几种,进一步优选为六边形。Specifically, the pits include one or more of rectangles, squares, diamonds, hexagons, curved rectangles, curved squares, curved diamonds and curved hexagons; preferably rectangles and hexagons and one or more of circular, more preferably hexagonal.
本发明中,所述金属陶瓷片含有Ti、C和Mo;优选地,所述金属陶瓷片为TiCMo金属陶瓷片。In the present invention, the cermet sheet contains Ti, C and Mo; preferably, the cermet sheet is a TiCMo cermet sheet.
本发明第二方面所涉及的如本发明第一方面所述的表面镶嵌金属陶瓷片的垃圾焚烧炉炉排片的制备方法包括:The preparation method of the garbage incinerator grate sheet with the surface inlaid metal ceramic sheet as described in the first aspect of the present invention involved in the second aspect of the present invention includes:
步骤A,用精密铸造工艺成形炉排片,且在炉排片易磨蚀部位铸造出多个凹坑,使得所述凹坑的底部平坦,深度为2-3mm;并使得相邻两个凹坑之间彼此相连并通过共用一个侧壁彼此分隔开,优选地,所述侧壁的厚度为2-3mm;In step A, the grate sheet is formed by the precision casting process, and a plurality of pits are cast on the easily eroded part of the grate sheet, so that the bottom of the pit is flat and the depth is 2-3 mm; and the gap between two adjacent pits is made. connected to each other and separated from each other by sharing a side wall, preferably, the thickness of the side wall is 2-3mm;
步骤B,将C粉末、Ti粉末和Mo粉末混合后进行球磨细化后,制成TiCMo混合粉料;所述TiCMo混合粉料中,C粉末与Ti粉末的原子比为1:1,Mo粉末的用量为C粉末和Ti粉末总质量的5%;In step B, the C powder, the Ti powder and the Mo powder are mixed and then ball-milled and refined to make a TiCMo mixed powder; in the TiCMo mixed powder, the atomic ratio of the C powder to the Ti powder is 1:1, and the Mo powder is The dosage is 5% of the total mass of C powder and Ti powder;
步骤C,将TiCMo混合粉料装入多边形模具中,压制成TiCMo压坯;使得压坯高度为凹坑深度的3-5倍,所述压坯尺寸略小于炉排片表面的凹坑尺寸;优选地,所述压坯的密度为其理论密度的60%-80%;In step C, the TiCMo mixed powder is loaded into the polygonal mold and pressed into a TiCMo compact; the compact height is 3-5 times the depth of the pit, and the compact size is slightly smaller than the pit size on the surface of the grate sheet; Preferably, the density of the compact is 60%-80% of its theoretical density;
步骤D,将铝热反应产生的钢水浇注到炉排片易磨蚀区表面的凹坑后,立即将TiCMo压坯放入凹坑,凹坑中的钢水与炉排片焊接在一起,同时引燃压坯使其发生自蔓延反应,反应产生的高温压坯与钢水焊接在一起,待反应刚刚结束在压坯表面向下加压,将压坯压缩到与侧壁同高,从而得到表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片。In step D, after pouring the molten steel produced by the aluminothermic reaction into the pit on the surface of the easily erodable area of the grate sheet, immediately put the TiCMo compact into the pit, the molten steel in the pit is welded with the grate sheet, and the compact is ignited at the same time. A self-propagating reaction occurs, and the high-temperature green compact produced by the reaction is welded with molten steel. After the reaction is just over, the surface of the green compact is pressed down, and the green compact is compressed to the same height as the side wall, thereby obtaining a surface inlaid cermet sheet. wear-resistant waste incinerator grate pieces.
值得一提的是,在压坯表面向下加压,将压坯压缩到与侧壁同高的过程中,部分钢水沿凹坑侧壁向上流动,使侧壁与压坯焊合。It is worth mentioning that when the surface of the green compact is pressed downward to compress the green compact to the same height as the side wall, part of the molten steel flows upward along the side wall of the pit, so that the side wall and the green compact are welded together.
本发明中,所述多边形模具为制备TiCMo压坯的模具,其由侧壁围成多边形空心柱体,无盖也无底板,本发明中也称为TiCMo压坯的模具或压坯模具。所述压坯模具与作为压坯底板用的钢板和凸模(冲头)配合使用,用于制作压坯。In the present invention, the polygonal mold is a mold for preparing TiCMo compacts, which is surrounded by side walls to form a polygonal hollow cylinder without a cover or a bottom plate, and is also referred to as a TiCMo compact mold or a compact mold in the present invention. The green compacting die is used in conjunction with a steel plate and a punch (punch) as a bottom plate for compacting, and is used for making compacts.
与凹坑的形状相对应,所述模具包括多边形模具、圆形模具、椭圆形模具和曲边多边形模具中的一种或几种;其中,所述多边形包括矩形、正方形、菱形、六边形中的一种或多种;所述曲边多边形包括曲边矩形、曲边正方形、曲边菱形、曲边六边形中的一种或多种。Corresponding to the shape of the pit, the mold includes one or more of a polygonal mold, a circular mold, an oval mold and a curved polygonal mold; wherein, the polygon includes a rectangle, a square, a rhombus, and a hexagon. One or more of; the curved polygon includes one or more of a curved rectangle, a curved square, a curved rhombus, and a curved hexagon.
具体地,所述模具包括矩形、正方形、菱形、六边形、曲边矩形、曲边正方形、曲边菱形和曲边六边形中的一种或多种;优选为矩形、六边形和圆形中的一种或几种,进一步优选为六边形。Specifically, the mold includes one or more of rectangles, squares, diamonds, hexagons, curved rectangles, curved squares, curved diamonds and curved hexagons; preferably rectangles, hexagons and One or more kinds of circles, more preferably hexagons.
本发明中所述用语“铸焊”是一种用范(模)组合成铸型进行浇铸的方法对金属进行铸接、铸焊、铸镶的操作。The term "cast welding" mentioned in the present invention refers to the operation of casting, welding and casting of metal by combining a mold (mold) into a casting mold for casting.
本发明中所述用语“自蔓延反应”是指自蔓延高温合成反应;所述自蔓延高温合成(self-propagation high-temperature synthesis,简称SHS),又称为燃烧合成(combustion synthesis)技术,是利用反应物之间高的化学反应热的自加热和自传导作用来合成材料的一种技术,当反应物一旦被引燃,便会自动向尚未反应的区域传播,直至反应完全,是制备无机化合物高温材料的一种新方法。The term "self-propagating reaction" in the present invention refers to a self-propagating high-temperature synthesis reaction; the self-propagation high-temperature synthesis (SHS for short), also known as combustion synthesis (combustion synthesis) technology, is a A technology for synthesizing materials by using the self-heating and self-conduction of the high chemical reaction heat between the reactants. Once the reactants are ignited, they will automatically spread to the unreacted area until the reaction is complete. A new method for compounding high temperature materials.
本发明中所述用语“自蔓延反应铸焊法”是指通过自蔓延反应实现铸焊的方法;例如,本发明中制备表面镶嵌金属陶瓷片的垃圾焚烧炉炉排片的方法中的步骤D中的操作。The term "self-propagating reaction casting welding method" mentioned in the present invention refers to a method for realizing cast welding through self-propagating reaction; operation.
本发明中所述“压坯的理论密度”可以按照式(1)或(2)进行计算:The "theoretical density of the green compact" in the present invention can be calculated according to formula (1) or (2):
压坯的理论密度ρ=1/(∑mi/ρi)(1)Theoretical density of green compact ρ=1/(∑mi/ρi)(1)
式(1)中,ρ为压坯的理论密度,单位是g/cm3;In formula (1), ρ is the theoretical density of the green compact, and the unit is g/cm 3 ;
mi为制备压坯的混合粉料中元素i的质量分数;mi is the mass fraction of element i in the mixed powder for preparing the compact;
ρi为制备压坯的混合粉料中元素i的密度,单位是g/cm3;ρi is the density of element i in the mixed powder for preparing the compact, the unit is g/cm 3 ;
压坯的理论密度ρ=∑Vi×ρi(2)The theoretical density of the green compact ρ=∑Vi×ρi(2)
式(2)中,ρ为压坯的理论密度,单位是g/cm3;In formula (2), ρ is the theoretical density of the green compact, and the unit is g/cm 3 ;
Vi为制备压坯的混合粉料中元素i的体积分数;Vi is the volume fraction of element i in the mixed powder for preparing the compact;
ρi为制备压坯的混合粉料中元素i的密度,单位是g/cm3。ρi is the density of element i in the mixed powder for preparing the compact, in g/cm 3 .
在本发明的一些具体的实施例中:采用本发明方法制备表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片,如图1-6所示,其包括以下步骤:In some specific embodiments of the present invention: the method of the present invention is used to prepare the anti-erosion garbage incinerator grate sheet with the surface inlaid cermet sheet, as shown in Figures 1-6, which includes the following steps:
(1)炉排片材质1Gr18Ni9Ti,精密铸造成形,在易产生磨蚀失效的表面铸造时铸造出深度2-3mm的凹坑2,侧壁22边长根据部位不同而不同,圆弧或直角转弯处边长小,平面处边长长(图中未示出),并使得相邻两个凹坑之间彼此相连并通过共用一个侧壁彼此分隔开,且所述侧壁的厚度为2-3mm(见图1),凹坑底部21为平面;(1) The material of the grate sheet is 1Gr18Ni9Ti. It is formed by precision casting. When casting on the surface that is prone to abrasion failure, a
(2)按自蔓延反应原理配制Ti+C+Mo=TiCMo自蔓延粉末材料,混合均匀,制成TiCMo混合粉料;(2) Prepare Ti+C+Mo=TiCMo self-propagating powder material according to the principle of self-propagating reaction, mix well, and make TiCMo mixed powder;
(3)将TiCMo混合粉料装入与比凹坑略小的TiCMo压坯模具4(见图2)中压实成压坯7(见图5),压坯7高度为凹坑侧壁22高度的3-5倍;(3) Put the TiCMo mixed powder into the TiCMo compact mold 4 (see Figure 2) that is slightly smaller than the pit and compact it into a compact 7 (see Figure 5), and the height of the compact 7 is the
(4)将铝热反应产生的钢水浇注到凹坑2中后,立即将压坯7放入凹坑2,凹坑2中的钢水引燃压坯7的自蔓延反应,待反应刚刚结束加压,得到表面镶嵌金属陶瓷片3垃圾焚烧炉炉排片。(4) after the molten steel produced by the aluminothermic reaction is poured into the
值得一提的是,在压坯7表面向下加压,将压坯7压缩到与凹坑侧壁22同高的过程中,部分钢水沿凹坑侧壁22向上流动,使凹坑侧壁22与压坯7焊合。It is worth mentioning that during the process of pressing the surface of the
上述凹坑2是由侧壁22和底部21构成的多边形凹槽,优选多边形为正六边形或矩形或圆形,进一步优选为正六边形。The above-mentioned
相应地,上述TiCMo压坯模具4由侧壁42围成多边形空心柱体,无盖也无底板,优选多边形为正六边形或矩形或圆形,进一步优选为正六边形。所述压坯模具4与作为压坯凹模底板用的钢板5(见图3)和凸模(冲头)6(见图4)配合使用,用于制作压坯7。Correspondingly, the above-mentioned TiCMo
本发明人研究发现,六边形的凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成稳定的蜂窝结构,由此制成的表面镶嵌金属陶瓷片垃圾焚烧炉炉排片具有较好的稳定性和耐高温防磨蚀性。The inventors have found that the
在本发明的一些进一步具体的实施例中,所述表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片如图6所示。图6中,表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片包括炉排片1、分布于炉排片易磨蚀区表面的多个凹坑2,以及镶嵌于凹坑内的金属陶瓷片3;其中,分布于炉排片易磨蚀区表面的凹坑2是在炉排片铸造成形时生成;所述金属陶瓷片3通过自蔓延反应铸焊法镶嵌于凹坑2内,由此,所述金属陶瓷片3与凹坑2的侧壁22和底部为冶金结合。In some further specific embodiments of the present invention, the abrasion-resistant waste incinerator grate sheet with the surface inlaid cermet sheet is shown in FIG. 6 . In Fig. 6, the abrasion-resistant waste incinerator grate sheet with cermet inlaid on the surface includes a
所述凹坑2的底部平坦,深度为2-3mm;所述凹坑2优选为正六边形;相邻两个凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成稳定的蜂窝结构,优选地,所述侧壁22的厚度为2-3mm。由此构成的表面镶嵌金属陶瓷片垃圾焚烧炉炉排片,具有较好的稳定性和耐高温防磨蚀性。The bottom of the
所述金属陶瓷片含有Ti、C和Mo;优选地,所述金属陶瓷片为TiCMo金属陶瓷片。The cermet sheet contains Ti, C and Mo; preferably, the cermet sheet is a TiCMo cermet sheet.
实施例Example
为使本发明更加容易理解,下面将结合实施例来进一步详细说明本发明,这些实施例仅起说明性作用,并不局限于本发明的应用范围。本发明中所使用的原料或组分若无特殊说明均可以通过商业途径或常规方法获得。In order to make the present invention easier to understand, the present invention will be further described in detail below with reference to the embodiments, which are only for illustrative purposes and do not limit the scope of application of the present invention. The raw materials or components used in the present invention can be obtained through commercial channels or conventional methods unless otherwise specified.
本发明中炉排片抗磨蚀性能直接利用生产中的实际消耗率来进行检测。In the present invention, the anti-abrasion performance of the grate sheet is directly detected by the actual consumption rate in production.
实施例1:Example 1:
制备表面镶嵌金属陶瓷片3的耐磨蚀垃圾焚烧炉炉排片,如图1-4所示。Prepare the abrasion-resistant waste incinerator grate sheet with the cermet sheet 3 on the surface, as shown in Figure 1-4.
(1)炉排片材质1Gr18Ni9Ti,精密铸造成形,在易产生磨蚀失效的表面铸造时铸造出深度2-3mm的正六边形凹坑2,侧壁22边长根据部位不同而不同,炉排片1圆弧或直角转弯处边长小,平面处边长长,相邻两个凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成稳定的蜂窝结构,且所述侧壁22的厚度为2-3mm(见图1);(1) The material of the grate sheet is 1Gr18Ni9Ti. It is formed by precision casting. When casting on the surface that is prone to abrasion failure, a regular
(2)250目C粉和Ti粉按原子比1:1配制,加入5wt%的Mo粉,球磨9小时,制成TiCMo混合粉料;(2) 250 mesh C powder and Ti powder were prepared at an atomic ratio of 1:1, 5wt% Mo powder was added, and ball-milled for 9 hours to prepare a TiCMo mixed powder;
(3)将制成TiCMo混合粉料装入正六边形模具4(见图2),通过压坯模具4与作为压坯底板用的钢板5(见图3)和凸模(冲头)6(见图4)配合使用,在压坯模具4中压成与凹坑2形状相同、尺寸略小的压制成TiCMo压坯7(见图5),TiCMo压坯7密度为其理论密度的60%-80%,TiCMo压坯7高度为侧壁21高度的3-5倍。(3) Load the finished TiCMo mixed powder into a regular hexagonal mold 4 (see Figure 2), pass through the green
(4)将铝热反应产生的钢水浇注到凹坑2中后,立即将TiCMo压坯7放入凹坑2,凹坑2中的钢水引燃压坯7的自蔓延反应,待反应刚刚结束限位加压,从而得到表面镶嵌金属陶瓷片3的耐磨蚀垃圾焚烧炉炉排片(见图6)。(4) after the molten steel produced by the aluminothermic reaction is poured into the
在压坯7表面向下加压,将压坯7压缩到与凹坑侧壁22同高的过程中,部分钢水沿凹坑侧壁22向上流动,使凹坑侧壁22与压坯7焊合。During the process of pressing the surface of the
上述过程所制备的表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片如图6所示。图6中,表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片包括炉排片1、分布于炉排片易磨蚀区表面的多个凹坑2,以及镶嵌于凹坑内的金属陶瓷片3;其中,分布于炉排片易磨蚀区表面的凹坑2是在炉排片铸造成形时生成;所述金属陶瓷片3通过自蔓延反应铸焊法镶嵌于凹坑2内,由此,所述金属陶瓷片3与凹坑2的侧壁22和底部为冶金结合。The anti-erosion garbage incinerator grate sheet with the surface inlaid metal ceramic sheet prepared by the above process is shown in Figure 6. In Fig. 6, the abrasion-resistant waste incinerator grate sheet with cermet inlaid on the surface includes a
所述凹坑2的底部平坦,深度为2-3mm;所述凹坑2优选为正六边形;相邻两个凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成稳定的蜂窝结构,优选地,所述侧壁22的厚度为2-3mm。由此构成的表面镶嵌金属陶瓷片垃圾焚烧炉炉排片,具有较好的稳定性和耐高温防磨蚀性。The bottom of the
所述金属陶瓷片含有Ti、C和Mo;优选地,所述金属陶瓷片为TiCMo金属陶瓷片。The cermet sheet contains Ti, C and Mo; preferably, the cermet sheet is a TiCMo cermet sheet.
直接利用生产中的实际消耗率来检测本实施例中表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片的耐高温防磨蚀性,结果表明本实施例中这种炉排片具有良好的耐高温(800-900℃)防磨蚀性,其服役寿命约为原炉排片服役寿命(国产化垃圾焚烧炉炉排片使用寿命7-10个月)的5-10倍。The actual consumption rate in production is directly used to detect the high temperature and anti-abrasion resistance of the abrasion-resistant waste incinerator grate sheet inlaid with metal ceramic sheets on the surface in this embodiment. The results show that this kind of grate sheet in this embodiment has good high temperature resistance. (800-900 ℃) anti-abrasion, its service life is about 5-10 times of the service life of the original grate (the service life of the domestic waste incinerator grate is 7-10 months).
实施例2:Example 2:
本实施例与实施例1不同的是:The difference between this embodiment and
在步骤(1)中,在易产生磨蚀失效的表面铸造时铸造出深度2-3mm的矩形凹坑2;相邻两个凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成网格结构。In step (1), a
在步骤(3)中,将制成TiCMo混合粉料装入矩形模具4中压成与凹坑2形状相同。In step (3), the finished TiCMo mixed powder is loaded into the
上述过程所制备的表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片与实施例1中所制备的表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片不同之处在于,所述凹坑2为矩形,相应于此,所述TiCMo金属陶瓷片3也为矩形,相邻两个凹坑2之间彼此相连并通过共用一个侧壁22彼此分隔,形成网格结构。The difference between the abrasion-resistant garbage incinerator grate sheet with the surface inlaid cermet sheet prepared in the above process and the abrasion-resistant garbage incinerator grate sheet with the cermet sheet inlaid on the surface prepared in Example 1 is that the
直接利用生产中的实际消耗率来检测本实施例中表面镶嵌金属陶瓷片的耐磨蚀垃圾焚烧炉炉排片的耐高温防磨蚀性,结果表明本实施例中这种炉排片具有良好的耐高温(800-900℃)防磨蚀性,其服役寿命约为原炉排片服役寿命(国产化垃圾焚烧炉炉排片使用寿命7-10个月)的5-9倍。The actual consumption rate in production is directly used to detect the high temperature and anti-abrasion resistance of the abrasion-resistant waste incinerator grate sheet inlaid with metal ceramic sheets on the surface in this embodiment. The results show that this kind of grate sheet in this embodiment has good high temperature resistance. (800-900 ℃) anti-abrasion, its service life is about 5-9 times of the service life of the original grate (the service life of the domestic waste incinerator grate is 7-10 months).
应当注意的是,以上所述的实施例仅用于解释本发明,并不构成对本发明的任何限制。通过参照典型实施例对本发明进行了描述,但应当理解为其中所用的词语为描述性和解释性词汇,而不是限定性词汇。可以按规定在本发明权利要求的范围内对本发明做出修改,以及在不背离本发明的范围和精神内对本发明进行修订。尽管其中描述的本发明涉及特定的方法、材料和实施例,但是并不意味着本发明限于其中公开的特定例,相反,本发明可扩展至其他所有具有相同功能的方法和应用。It should be noted that the above-mentioned embodiments are only used to explain the present invention, and do not constitute any limitation to the present invention. The present invention has been described with reference to typical embodiments, but it is to be understood that the words used therein are words of description and explanation, rather than words of limitation. Modifications can be made to the invention as specified within the scope of the claims of the invention, as well as modifications of the invention without departing from the scope and spirit of the invention. Although the invention described herein refers to the specific methods, materials and embodiments, it is not intended to be limited to the specific examples disclosed therein, but rather, the invention extends to all other methods and applications having the same function.
Claims (10)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113145829A (en) * | 2021-01-29 | 2021-07-23 | 自贡长城硬面材料有限公司 | Preparation method of composite wear-resistant element |
CN117346148A (en) * | 2023-10-26 | 2024-01-05 | 华北电力大学 | A kind of air staged combustion technology in the combustion section of garbage incinerator |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH074634A (en) * | 1993-06-17 | 1995-01-10 | Hitachi Zosen Corp | Garbage incinerator grate |
CN101813123A (en) * | 2010-05-07 | 2010-08-25 | 山东大学 | Rubber covered roll and production method thereof |
CN202100925U (en) * | 2011-05-12 | 2012-01-04 | 中山市华山特种陶瓷有限公司 | Ceramic steel composite lining |
CN102937374A (en) * | 2012-10-25 | 2013-02-20 | 江苏大学 | Preparation method of composite sintering machine grate bar |
CN103111793A (en) * | 2013-02-27 | 2013-05-22 | 吉林大学 | Method for preparing great-depth bionic heteroplasmons on surfaces on thick-wall parts |
CN103949648A (en) * | 2014-05-08 | 2014-07-30 | 吉林大学 | Preparation method of high-strength high-toughness bionic-function surface wear resistance composite material |
CN110125368A (en) * | 2019-05-14 | 2019-08-16 | 北京科技大学 | A kind of process preparing inexpensive wear-resistant coating on metal casting surface |
CN213066125U (en) * | 2020-07-27 | 2021-04-27 | 江苏科环新材料有限公司 | Garbage incinerator fire grate with metal ceramic sheet embedded on surface |
-
2020
- 2020-07-27 CN CN202010729457.1A patent/CN111928267A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH074634A (en) * | 1993-06-17 | 1995-01-10 | Hitachi Zosen Corp | Garbage incinerator grate |
CN101813123A (en) * | 2010-05-07 | 2010-08-25 | 山东大学 | Rubber covered roll and production method thereof |
CN202100925U (en) * | 2011-05-12 | 2012-01-04 | 中山市华山特种陶瓷有限公司 | Ceramic steel composite lining |
CN102937374A (en) * | 2012-10-25 | 2013-02-20 | 江苏大学 | Preparation method of composite sintering machine grate bar |
CN103111793A (en) * | 2013-02-27 | 2013-05-22 | 吉林大学 | Method for preparing great-depth bionic heteroplasmons on surfaces on thick-wall parts |
CN103949648A (en) * | 2014-05-08 | 2014-07-30 | 吉林大学 | Preparation method of high-strength high-toughness bionic-function surface wear resistance composite material |
CN110125368A (en) * | 2019-05-14 | 2019-08-16 | 北京科技大学 | A kind of process preparing inexpensive wear-resistant coating on metal casting surface |
CN213066125U (en) * | 2020-07-27 | 2021-04-27 | 江苏科环新材料有限公司 | Garbage incinerator fire grate with metal ceramic sheet embedded on surface |
Non-Patent Citations (1)
Title |
---|
徐克玷: "《钼的材料科学与工程》", 31 July 2014, 北京:冶金工业出版社, pages: 635 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113145829A (en) * | 2021-01-29 | 2021-07-23 | 自贡长城硬面材料有限公司 | Preparation method of composite wear-resistant element |
CN117346148A (en) * | 2023-10-26 | 2024-01-05 | 华北电力大学 | A kind of air staged combustion technology in the combustion section of garbage incinerator |
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