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CN111821838A - A kind of aerosol type air deodorant and preparation method thereof - Google Patents

A kind of aerosol type air deodorant and preparation method thereof Download PDF

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Publication number
CN111821838A
CN111821838A CN201910320521.8A CN201910320521A CN111821838A CN 111821838 A CN111821838 A CN 111821838A CN 201910320521 A CN201910320521 A CN 201910320521A CN 111821838 A CN111821838 A CN 111821838A
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deodorant
parts
aerosol
type air
air
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陈炳耀
宁智勇
董颖
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Guangdong Fuhe Industrial Co ltd
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Guangdong Fuhe Industrial Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)

Abstract

The invention provides an aerosol air deodorant and a preparation method thereof, wherein the formula of the deodorant comprises the following components in parts by weight: 0.1-5.0 parts of wetting agent, 0.01-1 part of long-acting bactericide, 1.0-5.0 parts of deodorant, 0.01-1.0 part of preservative, 0.05-3.0 parts of corrosion inhibitor, 60.0-70.0 parts of deionized water and 30.0-50.0 parts of propellant. The air deodorant has the following beneficial effects: 1. the air mist type air deodorant can effectively capture and adsorb odor molecules, and neutralize and decompose the odor molecules into tasteless harmless substances; 2. the aerosol air deodorant has simple process, convenient use, safe and nontoxic product, no spot, no injury to skin, no irritation to eyes, etc.; 3. the air mist type air deodorant can rapidly remove the peculiar smell of indoor air: smoke smell, mildew smell, kitchen peculiar smell, toilet peculiar smell, formaldehyde peculiar smell, bacteria elimination and the like. The invention also discloses a preparation method of the aerosol air deodorant.

Description

一种气雾型空气除味剂及其制备方法A kind of aerosol type air deodorant and preparation method thereof

技术领域technical field

本发明涉及空气净化领域,特别涉及一种气雾型空气除味剂及其制备方法。The invention relates to the field of air purification, in particular to an aerosol-type air deodorant and a preparation method thereof.

背景技术Background technique

家居装修带来的甲醛异味、环境中的霉味、厨房异味、卫生间异味、房间或车内的烟味等等都会严重刺激人们的感官而带来身体不适,目前最常用的处理异味的方法是通过以香精掩盖“臭味”的空气清新剂,实际并未消除异味。吸附法多采用活性炭、分子筛作为吸附材料对异味物质进行吸附去除,其实用性较广,但存在吸附效率低,需要与相关设备共用等的缺点。The formaldehyde odor caused by home decoration, the musty smell in the environment, the odor in the kitchen, the odor in the bathroom, the odor in the room or in the car, etc. will seriously stimulate people's senses and cause physical discomfort. The most commonly used method to deal with odors is Air fresheners that mask the "smell" with fragrance do not actually eliminate the odor. The adsorption method mostly uses activated carbon and molecular sieve as adsorption materials to adsorb and remove odorous substances, which has a wide range of practicality, but has the disadvantages of low adsorption efficiency and the need to share with related equipment.

发明内容SUMMARY OF THE INVENTION

本发明的一个目的是解决上述缺陷,提供一种气雾型空气除味剂,该除味剂是一种祛除型的产品,它通过捕捉、吸附、耦合等过程分解空气及环境中的异味——氨硫化氢、甲醛、苯等,例如烟味、酒味、体臭汗臭、食物异味、呕吐物臭味、霉味、鱼腥味、油漆溶剂异味等。An object of the present invention is to solve the above-mentioned defect, and provide a kind of aerosol type air deodorant, this deodorant is a kind of elimination type product, it decomposes the peculiar smell in the air and the environment through processes such as capturing, adsorption, coupling— - Ammonia hydrogen sulfide, formaldehyde, benzene, etc., such as smoke, alcohol, body odor, sweat, food, vomit, musty, fish, paint solvent, etc.

本发明的目的是通过以下方案实现的:The purpose of this invention is to realize through the following scheme:

一种气雾型空气除味剂,其配方按重量份包括:An aerosol type air deodorant, the formula of which comprises by weight:

润湿剂 0.1~5.0份Wetting agent 0.1~5.0 parts

长效杀菌剂 0.01~1.0份Long-acting fungicide 0.01 to 1.0 parts

除味剂 0.1~5.0份Deodorant 0.1~5.0 parts

防腐剂 0.01~1.0份Preservative 0.01~1.0 part

缓蚀剂 0.05~3.0份Corrosion inhibitor 0.05~3.0 parts

去离子水 60.0~70.0份Deionized water 60.0~70.0 parts

推进剂 20.0~50.0份。Propellant 20.0 to 50.0 parts.

采用以上技术方案的除味剂,具有以下优点:The deodorant adopting the above technical scheme has the following advantages:

1、该气雾型空气除味剂能有效地捕捉吸附臭味分子,并中和、分解成无味无害物质;1. The aerosol-type air deodorizer can effectively capture and adsorb odor molecules, neutralize and decompose them into odorless and harmless substances;

2、工艺简单,使用方便——在有异味的环境中直接喷洒使用,产品安全无毒,使用后不留斑渍,不伤皮肤,不刺激眼睛等。产品符合美国职业安全与卫生条例(OSHA) 29CFR1910.1200、国家毒性检测《GB15193-1994》、抑菌性能检测《GB15979-2002》、除甲醛《GB/T16129-1995》;2. The process is simple and easy to use - spray directly in the environment with peculiar smell, the product is safe and non-toxic, does not leave stains after use, does not hurt the skin, does not irritate the eyes, etc. The product complies with the US Occupational Safety and Health Regulations (OSHA) 29CFR1910.1200, the national toxicity test "GB15193-1994", the antibacterial performance test "GB15979-2002", and the formaldehyde removal "GB/T16129-1995";

3、能快速去除室内空气异味:烟味、霉味、厨房异味、厕所异味、甲醛异味和消除细菌等。3. Can quickly remove indoor air odor: smoke, musty, kitchen odor, toilet odor, formaldehyde odor and eliminate bacteria, etc.

根据本发明的一个方面,提供了一种气雾型空气除味剂的制备方法,包括以下步骤:According to one aspect of the present invention, there is provided a preparation method of an aerosol-type air deodorant, comprising the following steps:

S1、按重量份配比,将润湿剂加入到容器中,缓慢加入长效杀菌剂和除味剂,以300~500r/min搅拌5~10min至完全溶解后,加入去离子水、防腐剂、缓蚀剂500~600转/分钟搅拌至完全溶解,过滤备用;S1. According to the proportion by weight, add the wetting agent into the container, slowly add the long-acting bactericide and deodorant, stir at 300~500r/min for 5~10min until completely dissolved, then add deionized water and preservative , Stir the corrosion inhibitor at 500-600 r/min until it is completely dissolved, and filter it for later use;

S2、灌装:按一定充填率将剂料灌装至气雾罐中,加入阀门后进行封口、充填推进剂,过水浴后装上按钮、盖子,即制得气雾型空气除味剂。S2. Filling: Fill the agent material into the aerosol can according to a certain filling rate, seal and fill the propellant after adding the valve, and install the button and cover after passing through the water bath to obtain the aerosol-type air deodorant.

具体实施方式Detailed ways

以下实施例对本发明进行说明,但本发明并不受这些实施例所限制。对本发明的具体实施方式进行修改或者对部分技术特征进行等同替换,而不脱离本发明方案的精神,其均应涵盖在本发明请求保护的技术方案范围当中。The following examples illustrate the present invention, but the present invention is not limited by these examples. Modifications to the specific embodiments of the present invention or equivalent replacement of some technical features without departing from the spirit of the solution of the present invention shall all be included in the scope of the technical solution claimed in the present invention.

实施例1Example 1

一种气雾型空气除味剂,按以下重量份配比的成分组成:An aerosol-type air deodorant is composed of the following components in parts by weight:

丙二醇 0.1份Propylene glycol 0.1 part

环氧乙烷 0.01份0.01 part of ethylene oxide

立除味 0.1份0.1 serving of instant deodorization

去离子水 60.0份Deionized water 60.0 parts

卡松 0.01份Casson 0.01 servings

LPG 39.78份LPG 39.78 servings

实施例2Example 2

一种气雾型空气除味剂,按以下重量份配比的成分组成:An aerosol-type air deodorant is composed of the following components in parts by weight:

甘油 5.0份Glycerin 5.0 servings

十二烷基二甲基氯化铵 1.0份Dodecyl dimethyl ammonium chloride 1.0 part

纳米银离子除味剂 5.0份Nano silver ion deodorant 5.0 parts

去离子水 70.0份Deionized water 70.0 parts

苯氧乙醇 1.0份Phenoxyethanol 1.0 part

亚硝酸钠 3.0份Sodium nitrite 3.0 parts

HFO-1234ze 15.0份HFO-1234ze 15.0 servings

实施例3Example 3

一种气雾型空气除味剂,按以下重量份配比的成分组成:An aerosol-type air deodorant is composed of the following components in parts by weight:

丙二醇 1.5份Propylene Glycol 1.5 parts

SPX-3110 0.5份SPX-3110 0.5 copies

立除味 0.5份0.5 servings of instant deodorant

去离子水 65.5份Deionized water 65.5 parts

盐酸奥替尼啶 0.3份Octenidine hydrochloride 0.3 part

磷酸氢二钠 1.0份Disodium hydrogen phosphate 1.0 part

聚乙氧基化铵 0.2份Ammonium polyethoxylate 0.2 part

HFO-1234yf 28.0份HFO-1234yf 28.0 servings

比较例4Comparative Example 4

一种消毒杀菌除味剂,按以下重量份配比的成分组成:A sterilizing and deodorizing agent is composed of the following components in parts by weight:

大豆提取物-聚季铵盐 1.6份Soybean Extract - Polyquaternium 1.6 servings

乙醇 45.1份Ethanol 45.1 parts

复合缓蚀剂 0.1份Composite corrosion inhibitor 0.1 part

去离子水 18.0份Deionized water 18.0 parts

LPG 35.0份LPG 35.0 servings

比较例5Comparative Example 5

一种新车除味剂,按以下重量份配比的成分组成:A new car deodorant is composed of the following ingredients in parts by weight:

季铵盐复合物 5.0份Quaternary Ammonium Salt Complex 5.0 parts

防腐剂 0.5份Preservatives 0.5 servings

玫瑰精油 0.5份Rose essential oil 0.5 parts

乙二醇 4.0份Ethylene glycol 4.0 parts

去离子水 90.0份Deionized water 90.0 parts

实施例1~3、比较例4~5的除味剂的相关性能采用以下方法测试:The relevant properties of the deodorants of Examples 1 to 3 and Comparative Examples 4 to 5 were tested by the following methods:

1.空气试验箱除味效果的测定:1. Determination of deodorization effect of air test box:

①异味祛除试验:在50×30×30cm的试验箱中放入等量的生蒜、尿液等异臭物质,将等量的除味剂喷涂在试验箱中,测定试验箱喷涂除味剂前后箱内异味的浓淡程度。异味的浓淡程度用“+”号为单位表示,“+”号的数量越多表示异味越大,“+”号的数量越少表示异味越淡,“0”表示试验箱内几乎无异味。① Odor removal test: put the same amount of odorous substances such as raw garlic and urine in the test box of 50×30×30cm, spray the same amount of deodorant in the test box, and measure the test box sprayed with deodorant The intensity of the odor in the front and rear boxes. The degree of odor is expressed in units of "+". The more the number of "+" signs, the greater the odor, the smaller the number of "+" signs, the lighter the odor, and the "0" that there is almost no odor in the test chamber.

②甲醛祛除试验:将除味剂喷涂在试验箱中,测定试验箱喷涂除味剂前后箱内甲醛的含量变化。②Formaldehyde removal test: spray the deodorant in the test box, and measure the change of formaldehyde content in the test box before and after spraying the deodorant.

2.杀菌效果试验:按照《消毒技术规范》2001版2.1.11.3.1使用原液浸泡5分钟后测定对大肠杆菌、金黄色葡萄球菌的杀菌率。2. Bactericidal effect test: According to 2.1.11.3.1 of "Technical Specification for Disinfection" 2001 Edition, the sterilization rate against Escherichia coli and Staphylococcus aureus was determined after soaking in the stock solution for 5 minutes.

3.点燃距离的测定:按照标准GB/T 21630危险品 喷雾剂点燃距离试验方法进行测定。3. Determination of ignition distance: according to the standard GB/T 21630 Dangerous Goods - Ignition distance test method for sprays.

4.密闭空间点火测试:按照标准GB/T 21631危险品 喷雾剂封闭空间点燃试验方法进行测定4. Confined space ignition test: according to the standard GB/T 21631 Dangerous Goods - Spray closed space ignition test method

5.刺激性测试:按照《化妆品卫生规范(2007版)》,除味剂产品对手背部喷涂或涂抹,手部皮肤对产品刺激性的感受。5. Irritability test: According to the "Hygienic Standard for Cosmetics (2007 Edition)", the deodorant product is sprayed or smeared on the back of the hand, and the skin of the hand feels irritating to the product.

实施例1~3、比较例4~5所得的除味剂的相关性能测试结果如下表1所示。The relevant performance test results of the deodorants obtained in Examples 1 to 3 and Comparative Examples 4 to 5 are shown in Table 1 below.

Figure DEST_PATH_IMAGE001
Figure DEST_PATH_IMAGE001

由表1的使用效果表明,本发明一种气雾型空气除味剂与比较例4~5相比,其除异味效果优异,试验箱内几乎无异味,比较例4~5为存在轻微异味。The use effect of Table 1 shows that compared with Comparative Examples 4-5, an aerosol-type air deodorant of the present invention has excellent deodorizing effect, almost no odor in the test chamber, and Comparative Examples 4-5 have slight odor. .

本发明一种气雾型空气除味剂与比较例4~5相比,其除甲醛效能达90%以上,比较例4~5维持在50%左右。Compared with Comparative Examples 4-5, the aerosol-type air deodorant of the present invention has a formaldehyde-removing efficiency of over 90%, which is maintained at about 50% in Comparative Examples 4-5.

本发明一种气雾型空气除味剂与比较例4~5相比,其杀灭大肠杆菌、金黄色葡萄球菌效果理想>99%,比较例4加入一定量的乙醇,可起到杀菌作用,比较例5杀菌率在70%以内。Compared with Comparative Examples 4 to 5, an aerosol-type air deodorant of the present invention has an ideal killing effect of >99% on Escherichia coli and Staphylococcus aureus. In Comparative Example 4, adding a certain amount of ethanol can play a bactericidal effect. , the sterilization rate of Comparative Example 5 is within 70%.

本发明一种气雾型空气除味剂与比较例4~5相比,其点燃距离超过90mm,不可燃,比较例4为易燃气雾剂,比较例5为非气雾剂型。Compared with Comparative Examples 4 to 5, an aerosol type air deodorant of the present invention has an ignition distance of more than 90 mm and is non-flammable. Comparative Example 4 is a flammable aerosol, and Comparative Example 5 is a non-aerosol type.

本发明一种气雾型空气除味剂与比较例4~5相比,其不伤皮肤,不刺激眼睛安全无害。Compared with Comparative Examples 4 to 5, an aerosol-type air deodorant of the present invention does not hurt the skin, does not irritate the eyes, and is safe and harmless.

本发明一种气雾型空气除味剂及其制备方法,制作工艺简单,使用便捷安全,具有一定的除异味、除甲醛、杀灭细菌、不伤皮肤,不刺激眼睛无害等性能。The invention is an aerosol type air deodorant and a preparation method thereof. The preparation process is simple, the use is convenient and safe, and the invention has certain performances such as removing odor, removing formaldehyde, killing bacteria, not hurting the skin, not irritating the eyes, harmless, and the like.

Claims (7)

1.一种气雾型空气除味剂,其特征在于,包括A组份和B组份,其中A组分按重量份配比包括:1. an aerosol type air deodorant, is characterized in that, comprises A component and B component, and wherein A component comprises by weight proportion: 润湿剂 0.1~5.0份Wetting agent 0.1~5.0 parts 长效杀菌剂 0.01~1.0份Long-acting fungicide 0.01 to 1.0 parts 除味剂 1.0~5.0份Deodorant 1.0~5.0 parts 防腐剂 0.01~1.0份Preservative 0.01~1.0 part 缓蚀剂 0.05~3.0份Corrosion inhibitor 0.05~3.0 parts 去离子水 60.0~70.0Deionized water 60.0~70.0 推进剂 20.0~50.0份Propellant 20.0~50.0 parts 所述B组分包括气雾罐、阀门、按钮、盖子。The B component includes aerosol cans, valves, buttons, and lids. 2.如权利要求1所述的一种气雾型空气除味剂,其特征在于,所述的润湿剂为丙二醇、甘油中的至少一种;其中丙二醇和甘油为化妆品级。2 . The aerosol-type air deodorant according to claim 1 , wherein the wetting agent is at least one of propylene glycol and glycerin; wherein propylene glycol and glycerin are cosmetic grades. 3 . 3.如权利要求1所述的一种气雾型空气除味剂,其特征在于,所述的长效杀菌剂为3. a kind of aerosol type air deodorant as claimed in claim 1, is characterized in that, described long-acting bactericide is 乙基己基甘油、SPX-3110、聚季铵盐、十六烷基三甲基氯化铵、高铁酸钾、环Ethylhexylglycerin, SPX-3110, Polyquaternium, Cetyltrimethylammonium Chloride, Potassium Ferrate, Cyclo 氧乙烷中的至少一种,其中SPX-3110为自制的强效除臭杀菌剂。At least one of the oxyethanes, of which SPX-3110 is a self-made powerful deodorant fungicide. 4.如权利要求1所述的一种气雾型空气除味剂,其特征在于,所述的除味剂为季铵4. a kind of aerosol type air deodorant as claimed in claim 1, is characterized in that, described deodorant is quaternary ammonium 盐复合物、立除味、纳米银离子除味剂中的至少一种,其中立除味为NATURE’At least one of salt complex, instant deodorization, nano silver ion deodorant, wherein instant deodorization is NATURE' S MISTTM除臭剂,纳米银离子除味剂为PORClean公司纳米材料。S MISTTM deodorant, nano silver ion deodorant is a nano material of PORClean company. 5.如权利要求1所述的一种气雾型空气除味剂,其特征在于,所述的防腐剂为苯甲5. a kind of aerosol type air deodorant as claimed in claim 1, is characterized in that, described antiseptic is benzoyl 酸钠、卡松、苯氧乙醇、盐酸奥替尼啶中的至少一种;所述的缓蚀剂为三乙醇胺、at least one of sodium, kasone, phenoxyethanol, octenidine hydrochloride; described corrosion inhibitor is triethanolamine, 磷酸氢二钠、亚硝酸钠、钼酸钠、聚乙氧基化铵缓蚀剂中的至少一种。At least one of disodium hydrogen phosphate, sodium nitrite, sodium molybdate, polyethoxylated ammonium corrosion inhibitor. 6.如权利要求1所述的一种空气除味剂,其特征在于,所述的推进剂为LPG、二6. a kind of air deodorant as claimed in claim 1 is characterized in that, described propellant is LPG, two 甲醚、CO2、压缩空气、HFO-1234ze中的至少一种。At least one of methyl ether, CO2, compressed air, HFO-1234ze. 7.如权利要求1所述的一种空气除味剂的制备方法,其特征在于,包括以下步骤:7. the preparation method of a kind of air deodorant as claimed in claim 1, is characterized in that, comprises the following steps: 剂料的制备:按重量份配比,将润湿剂加入到容器中,缓慢加入长效杀菌剂Preparation of ingredients: according to the proportion by weight, add the wetting agent to the container, and slowly add the long-acting fungicide 和除味剂,以300~500r/min搅拌5~10min至完全溶解后,加入去离子水、防腐剂、缓蚀剂500~600转/分钟搅拌至完全溶解,过滤备用;and deodorant, stir at 300-500 r/min for 5-10 min until completely dissolved, add deionized water, preservative and corrosion inhibitor, stir at 500-600 r/min until completely dissolved, filter for use; 2) 灌装:按一定充填率将剂料灌装至气雾罐中,加入阀门后进行封口、充填推进剂,过水浴后装上按钮、盖子,即制得气雾型空气除味剂。2) Filling: Fill the agent material into the aerosol can according to a certain filling rate, seal and fill the propellant after adding the valve, and install the button and cover after passing through the water bath to obtain the aerosol-type air deodorant.
CN201910320521.8A 2019-04-20 2019-04-20 A kind of aerosol type air deodorant and preparation method thereof Pending CN111821838A (en)

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Application publication date: 20201027