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CN111653618B - Built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor and manufacturing method thereof - Google Patents

Built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor and manufacturing method thereof Download PDF

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CN111653618B
CN111653618B CN202010378923.6A CN202010378923A CN111653618B CN 111653618 B CN111653618 B CN 111653618B CN 202010378923 A CN202010378923 A CN 202010378923A CN 111653618 B CN111653618 B CN 111653618B
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CN111653618A (en
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何进
何箫梦
李春来
胡国庆
魏益群
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PKU-HKUST SHENZHEN-HONGKONG INSTITUTION
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/015Manufacture or treatment of FETs having heterojunction interface channels or heterojunction gate electrodes, e.g. HEMT
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/40FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
    • H10D30/47FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
    • H10D30/471High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT]
    • H10D30/473High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having confinement of carriers by multiple heterojunctions, e.g. quantum well HEMT
    • H10D30/4732High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having confinement of carriers by multiple heterojunctions, e.g. quantum well HEMT using Group III-V semiconductor material

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Abstract

The invention relates to a built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor and a manufacturing process thereof. The breakdown voltage of the EJ-high electron mobility transistor device can be improved by adjusting the electric field distribution through a built-in PN junction structure. The built-in PN junction is used for improving the electric field distribution inside the device between the grid electrode and the drain electrode, so that higher breakdown voltage is realized. The structural parameter optimized EJ-high electron mobility transistor achieves 2050V breakdown voltage performance at a gate-drain distance of 15 μm due to improved internal electric field distribution in the device between the gate and drain. The optimized transistor with the EJ-high electron mobility transistor structure has an on resistance of 15.37 omega mm and a basic quality factor of 2.734GWcm < -2 > of the power semiconductor device. Compared with a transistor without a built-in PN junction, the breakdown voltage of the novel device EJ-high electron mobility transistor is increased by 32.54%, the basic quality factor of the power semiconductor device is increased by 71.3%, and the on-resistance of the novel device EJ-high electron mobility transistor and the power semiconductor device are not greatly different.

Description

内置PN结硅基高压增强型氮化镓晶体管及制造方法Built-in PN junction silicon-based high-voltage enhancement gallium nitride transistor and manufacturing method

技术领域technical field

本发明属于晶体管领域,尤其涉及一种内置PN结硅基高压增强型氮化镓晶体管及制造方法。The invention belongs to the field of transistors, and in particular relates to a built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor and a manufacturing method.

背景技术Background technique

基于氮化镓的电子器件已成为电源应用中最有前途的候选产品之一。由于氮化铝镓/氮化镓异质结中的强极化电荷,在氮化镓和氮化铝镓之间的界面处形成了高密度的二维电子气。因此,通常使用氮化铝镓/氮化镓高电子迁移率晶体管作为耗尽型器件,在过去的十年中,许多基于氮化镓的电子器件的研究工作都集中在耗尽型氮化铝镓/氮化镓高电子迁移率晶体管上。由于电路应用的诸多局限性,氮化镓增强器件正在兴起。与耗尽型氮化铝镓/氮化镓高电子迁移率晶体管相比,增强型氮化镓基电子器件在电路应用中具有优势。在微波功率放大器和低噪声放大器等电路中,可以不使用负电压源,这样可以大大降低电路的复杂性和成本,并且具有良好的电路兼容性。GaN-based electronics have emerged as one of the most promising candidates for power applications. Due to the strong polarized charges in the AlGaN/GaN heterojunction, a high-density two-dimensional electron gas is formed at the interface between GaN and AlGaN. Therefore, AlGaN/GaN high electron mobility transistors are usually used as depletion-mode devices, and in the past decade, many research efforts on GaN-based electronic devices have focused on depletion-mode AlN Gallium/Gallium Nitride High Electron Mobility Transistors. GaN-enhanced devices are emerging due to many limitations in circuit applications. Compared with depletion-mode AlGaN/GaN high electron mobility transistors, enhancement-mode GaN-based electronic devices have advantages in circuit applications. In circuits such as microwave power amplifiers and low noise amplifiers, negative voltage sources may not be used, which can greatly reduce the complexity and cost of the circuit, and have good circuit compatibility.

为了提高氮化镓基器件的击穿电压,有必要改善栅极和漏极之间的电场分布。衬底电极已用于实现高耐压低表面电场氮化镓高电子迁移率晶体管。但是它只能用于薄的氮化镓缓冲层,对于高击穿电压的、有一定厚度的氮化镓器件而言有一定的限制。To increase the breakdown voltage of GaN-based devices, it is necessary to improve the electric field distribution between the gate and drain. Substrate electrodes have been used to realize high withstand voltage low surface electric field gallium nitride high electron mobility transistors. However, it can only be used for thin GaN buffer layers, and has certain limitations for GaN devices with high breakdown voltage and a certain thickness.

发明内容Contents of the invention

针对上述缺陷,本发明提供了一种内置PN结硅基高压增强型氮化镓晶体管内置PN结硅基高压增强型氮化镓晶体管,其特征在于,包括硅衬底、过渡层、缓冲层、势垒层,内置的N型层和P型层形成的嵌入结在势垒层和缓冲层中形成PN结,二维电子气的一部分替换为高掺杂N型层,同时P型层嵌入在N型层中;从下往上依次为硅衬底、过渡层、缓冲层、势垒层;所述势垒层为氮化铝镓势垒层,在氮化铝镓势垒层上形成二氧化硅作为蚀刻掩模,再蚀刻氮化铝镓阻挡层和氮化镓缓冲层,通过分子束外延的晶体生长技术使N型层和P型层重新生长,在P型层的顶部沉积二氧化硅掩模,形成N型层,作为通过等离子体增强化学气相沉积形成的钝化层,通过电感耦合等离子体蚀刻氮化硅和栅极凹槽,通过沉积氮化硅,作为栅极电介质,形成源电极和漏电极的纯电阻。该内置PN结改善了栅极和漏极之间的器件内部电场分布,从而提高了击穿电压。In view of the above defects, the present invention provides a built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor with a built-in PN junction silicon-based high-voltage enhanced gallium nitride transistor, which is characterized in that it includes a silicon substrate, a transition layer, a buffer layer, The barrier layer, the built-in N-type layer and the embedded junction formed by the P-type layer form a PN junction in the barrier layer and the buffer layer, and a part of the two-dimensional electron gas is replaced by a highly doped N-type layer, while the P-type layer is embedded in the In the N-type layer; from bottom to top, there are silicon substrate, transition layer, buffer layer, and barrier layer; the barrier layer is an aluminum gallium nitride barrier layer, and two layers are formed on the aluminum gallium nitride barrier layer. Silicon oxide is used as an etching mask, and then the aluminum gallium nitride barrier layer and the gallium nitride buffer layer are etched, and the N-type layer and the P-type layer are re-grown by the crystal growth technology of molecular beam epitaxy, and the dioxide oxide is deposited on the top of the P-type layer. Silicon mask, forming N-type layer, as a passivation layer formed by plasma enhanced chemical vapor deposition, etching silicon nitride and gate groove by inductively coupled plasma, by depositing silicon nitride, as gate dielectric, forming The pure resistance of the source and drain electrodes. This built-in PN junction improves the internal electric field distribution of the device between the gate and drain, thereby increasing the breakdown voltage.

本发明提出具有内置PN结的高电子迁移率晶体管新架构来改善模拟器件的击穿电压,使用Sentaurus TCAD工具对该结构进行了仿真,验证了所提出的新结构EJ-高电子迁移率晶体管提供的击穿电压比传统的带优化场板的FPC-高电子迁移率晶体管击穿电压高,品质因素更高。The present invention proposes a new structure of a high electron mobility transistor with a built-in PN junction to improve the breakdown voltage of an analog device. The structure is simulated using the Sentaurus TCAD tool, and the proposed new structure EJ-high electron mobility transistor provides The breakdown voltage is higher than that of the traditional FPC-high electron mobility transistor with an optimized field plate, and the quality factor is higher.

制造工艺的简要步骤,每个图的步骤可总结如下:Brief steps of the manufacturing process, the steps of each figure can be summarized as follows:

(a)在硅衬底上生长过渡层,然后通过金属有机化学气相沉积在过渡层上依次生长缓冲层和氮化铝镓势垒层;(a) growing a transition layer on a silicon substrate, and then sequentially growing a buffer layer and an aluminum gallium nitride barrier layer on the transition layer by metal-organic chemical vapor deposition;

(b)通过使用等离子体增强化学气相沉积法形成二氧化硅作为蚀刻掩模;(b) forming silicon dioxide as an etch mask by using plasma enhanced chemical vapor deposition;

(c)用三氯化硼与氯气混合气体通过变压器耦合等离子体反应性离子蚀刻来蚀刻氮化铝镓阻挡层和氮化镓缓冲层;(c) etching the aluminum gallium nitride barrier layer and the gallium nitride buffer layer by transformer coupled plasma reactive ion etching with boron trichloride and chlorine gas mixture;

(d)进行紫外线臭氧清洗和氟化氢加盐酸的湿法蚀刻相结合的方法,以减少蚀刻表面的杂质浓度,通过分子束外延的晶体生长技术使N型层和P型层重新生长;(d) A method of combining ultraviolet ozone cleaning and wet etching of hydrogen fluoride and hydrochloric acid to reduce the impurity concentration on the etched surface, and re-grow the N-type layer and the P-type layer through the crystal growth technology of molecular beam epitaxy;

(e)使用等离子增强化学气相沉积法在P型层的顶部沉积二氧化硅掩模,并通过硅离子注入形成N型层;(e) depositing a silicon dioxide mask on top of the P-type layer using plasma-enhanced chemical vapor deposition and forming an N-type layer by silicon ion implantation;

(f)注入后,使用氢氟酸去除二氧化硅掩模,然后进行注入后退火,以激活注入的硅,并使用原位远程等离子体预处理技术去除样品表面上的自然氧化物,且表面损伤最小,并沉积氮化硅,作为通过等离子体增强化学气相沉积形成的钝化层;(f) After implantation, the silicon dioxide mask was removed using hydrofluoric acid, followed by a post-implantation anneal to activate the implanted silicon, and an in-situ remote plasma pretreatment technique was used to remove the native oxide on the sample surface, and the surface Minimal damage and deposition of silicon nitride as a passivation layer via plasma enhanced chemical vapor deposition;

(g)通过低功率电感耦合等离子体干法蚀刻,具体是通过电感耦合等离子体蚀刻氮化硅和栅极凹槽;(g) dry etching by low power inductively coupled plasma, in particular silicon nitride and gate grooves by inductively coupled plasma;

(h)通过使用等离子体增强化学气相沉积的方式来沉积氮化硅,作为栅极电介质;(h) depositing silicon nitride as a gate dielectric by using plasma enhanced chemical vapor deposition;

(i)形成栅电极,并形成源电极和漏电极的纯电阻。(i) A gate electrode is formed, and a pure resistance of a source electrode and a drain electrode is formed.

需要说明的是,金属有机化学气相沉积是以Ⅲ族、Ⅱ族元素的有机化合物和V、Ⅵ族元素的氢化物等作为晶体生长源材料,以热分解反应方式在衬底上进行气相外延,生长各种Ⅲ-V主族、Ⅱ-Ⅵ副族化合物半导体以及它们的多元固溶体的薄层单晶材料。It should be noted that metal-organic chemical vapor deposition uses organic compounds of group III and group II elements and hydrides of group V and group VI elements as crystal growth source materials, and conducts vapor phase epitaxy on the substrate by thermal decomposition reaction. Thin-layer single crystal materials of various III-V main group, II-VI subgroup compound semiconductors and their multiple solid solutions are grown.

有益效果:Beneficial effect:

本发明提出了具有内置PN结的硅基氮化镓高电子迁移率晶体管结构,EJ-高电子迁移率晶体管,并通过器件仿真工具给出了其优化特性,并分析了该结构改善的器件电场分布。优化后的EJ-高电子迁移率晶体管器件的Ron为15.37Ωmm,VTH为1.7V,LGN=13μm,品质因素BFOM为2.734GW cm-2,VBK为2050V,RON为15.37Ωmm。与有优化场板的FPC-高电子迁移率晶体管(VBK为1546.6V,Ron为14.98Ωmm),功率半导体器件基础品质因数提高了71.3%,击穿电压几乎提高了32.54%,而RON相差不大。The present invention proposes a silicon-based gallium nitride high electron mobility transistor structure with a built-in PN junction, EJ-high electron mobility transistor, and provides its optimization characteristics through a device simulation tool, and analyzes the device electric field improved by the structure distributed. The optimized EJ-high electron mobility transistor device has Ron of 15.37Ωmm, VTH of 1.7V, LGN=13μm, quality factor BFOM of 2.734GW cm-2, VBK of 2050V, and RON of 15.37Ωmm. Compared with FPC-high electron mobility transistors with optimized field plates (VBK is 1546.6V, Ron is 14.98Ωmm), the basic quality factor of power semiconductor devices is increased by 71.3%, and the breakdown voltage is almost increased by 32.54%, while RON is not much different .

附图说明Description of drawings

图1 (a)FPC-高电子迁移率晶体管(b)EJ-高电子迁移率晶体管结构图示;Figure 1 (a) FPC-high electron mobility transistor (b) EJ-high electron mobility transistor structure diagram;

图2 EJ-高电子迁移率晶体管的制造工艺;Fig. 2 Manufacturing process of EJ-high electron mobility transistor;

图3 EJ-高电子迁移率晶体管晶体管的实验和模拟(a)IDS-VDS性能和(b)击穿特性;Fig. 3 Experimental and simulated (a) IDS-VDS performance and (b) breakdown characteristics of EJ-high electron mobility transistor transistors;

图4 C-高电子迁移率晶体管,FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的沟道电场分布比较;Fig. 4 Comparison of channel electric field distribution of C-high electron mobility transistor, FPC-high electron mobility transistor and EJ-high electron mobility transistor;

图5 C-高电子迁移率晶体管,FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管栅极关断时候的漏源击穿电压比较;Fig. 5 Comparison of the drain-source breakdown voltage of C-HEM transistor, FPC-HEM transistor and EJ-HEM transistor when the gate is turned off;

图6 FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的横向二维电子气分布比较;Figure 6 Comparison of lateral two-dimensional electron gas distribution of FPC-high electron mobility transistor and EJ-high electron mobility transistor;

图7 FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的恒流特性曲线比较;Figure 7 Comparison of constant current characteristic curves of FPC-high electron mobility transistor and EJ-high electron mobility transistor;

图8 FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的栅源转移特性变化曲线比较;Figure 8 Comparison of gate-source transfer characteristic curves of FPC-high electron mobility transistor and EJ-high electron mobility transistor;

图9 EJ-高电子迁移率晶体管改变NN+变化后VBK and RON的变化曲线;Figure 9 EJ-high electron mobility transistor VBK and RON change curve after changing NN+;

图10 EJ-高电子迁移率晶体管改变LGN后,VBK and RON的变化曲线;Fig. 10 EJ-high electron mobility transistor changes the change curve of VBK and RON after LGN is changed;

图11 J-高电子迁移率晶体管结构中VBK和RON随WN变化趋势;Fig.11 Variation trend of VBK and RON with WN in J-high electron mobility transistor structure;

图12 EJ-高电子迁移率晶体管结构中VBK和RON随HP变化后的趋势;Fig.12 The trend of VBK and RON after changing with HP in the EJ-high electron mobility transistor structure;

图13 EJ-高电子迁移率晶体管结构中VBK和RON随NP变化的趋势;Fig.13 The trend of VBK and RON changing with NP in the EJ-high electron mobility transistor structure;

具体实施方式Detailed ways

为使本发明的目的、技术方案和优点更加清楚,下面将对本发明的技术方案进行详细的描述。显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所得到的所有其它实施方式,都属于本发明所保护的范围。In order to make the purpose, technical solution and advantages of the present invention clearer, the technical solution of the present invention will be described in detail below. Apparently, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other implementations obtained by persons of ordinary skill in the art without making creative efforts fall within the protection scope of the present invention.

下面结合附图和实例进一步详细说明本发明的内容,但不以任何方式限制本发明的范围。The content of the present invention will be further described in detail below in conjunction with the accompanying drawings and examples, but the scope of the present invention is not limited in any way.

图1(a)和(b)展示了FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的架构。不带场板的FPC-高电子迁移率晶体管的参数与氮化镓样品中的参数相同。外延层由2.4μm的含铝过渡层,1.6μm的氮化镓缓冲层和21nm的氮化铝镓势垒层组成。FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管中的氮化铝镓势垒的摩尔分数为0.25。无掺杂的氮化镓缓冲层掺杂有1×1015cm-3N型浓度。两种结构均采用全凹陷栅技术,并选择Si3N4作为栅介质和钝化层。栅极电介质的厚度为17nm,钝化层的厚度为100nm。Figure 1(a) and (b) show the architecture of FPC-high electron mobility transistor and EJ-high electron mobility transistor. The parameters of the FPC-high electron mobility transistor without field plate are the same as those in the GaN sample. The epitaxial layer consists of a 2.4μm Al-containing transition layer, a 1.6μm GaN buffer layer and a 21nm AlGaN barrier layer. The mole fraction of AlGaN barrier in FPC-High Electron Mobility Transistor and EJ-High Electron Mobility Transistor is 0.25. The undoped GaN buffer layer is doped with 1×1015 cm-3 N-type concentration. Both structures adopt full recessed gate technology, and choose Si3N4 as the gate dielectric and passivation layer. The thickness of the gate dielectric is 17nm, and the thickness of the passivation layer is 100nm.

表I汇总了FPC-高电子迁移率晶体管和拟议的EJ-高电子迁移率晶体管的关键结构参数的详细信息。Table I summarizes the details of the key structural parameters of the FPC-high electron mobility transistor and the proposed EJ-high electron mobility transistor.

图2显示了该发明结构制造工艺的简要步骤,每个图的步骤可总结如下:Fig. 2 shows the brief steps of the manufacturing process of the inventive structure, and the steps of each figure can be summarized as follows:

(a)在硅衬底上生长过渡层,然后通过金属有机化学气相沉积在过渡层上从下往上依次生长缓冲层和氮化铝镓势垒层。(a) A transition layer is grown on a silicon substrate, and then a buffer layer and an aluminum gallium nitride barrier layer are sequentially grown on the transition layer by metal-organic chemical vapor deposition from bottom to top.

(b)通过使用等离子体增强化学气相沉积法,在氮化铝镓势垒层上形成二氧化硅作为蚀刻掩模,蚀刻掩模上设有凹槽,该凹槽以氮化铝镓势垒层的上表面为底。(b) By using plasma-enhanced chemical vapor deposition, silicon dioxide is formed as an etching mask on the aluminum gallium nitride barrier layer, and the etching mask is provided with grooves, and the grooves are formed by the aluminum gallium nitride barrier layer. The upper surface of the layer is the bottom.

(c)用三氯化硼与氯气混合气体通过变压器耦合等离子体反应性离子蚀刻来蚀刻氮化铝镓阻挡层和氮化镓缓冲层。(c) The aluminum gallium nitride barrier layer and the gallium nitride buffer layer are etched by transformer coupled plasma reactive ion etching with boron trichloride and chlorine gas mixture.

(d)进行紫外线臭氧清洗和氟化氢加盐酸的湿法蚀刻相结合的方法,以减少蚀刻表面的杂质浓度,通过分子束外延的晶体生长技术使N型层和P型层重新生长。(d) A method of combining ultraviolet ozone cleaning and wet etching of hydrogen fluoride and hydrochloric acid to reduce the impurity concentration on the etched surface, and re-grow the N-type layer and the P-type layer through the crystal growth technology of molecular beam epitaxy.

(e)使用等离子增强化学气相沉积法在P型层的顶部沉积二氧化硅掩模,并通过硅离子注入形成N型层。(e) A silicon dioxide mask is deposited on top of the P-type layer using plasma-enhanced chemical vapor deposition, and an N-type layer is formed by silicon ion implantation.

(f)注入后,使用氢氟酸去除二氧化硅掩模,然后进行注入后退火,以激活注入的硅,并使用原位远程等离子体预处理技术去除样品表面上的自然氧化物,且表面损伤最小,并沉积氮化硅,作为通过等离子体增强化学气相沉积形成的钝化层,,所述钝化层为图2(f)中的最上面那层。(f) After implantation, the silicon dioxide mask was removed using hydrofluoric acid, followed by a post-implantation anneal to activate the implanted silicon, and an in-situ remote plasma pretreatment technique was used to remove the native oxide on the sample surface, and the surface The damage is minimal and silicon nitride is deposited as a passivation layer by plasma enhanced chemical vapor deposition, which is the uppermost layer in Figure 2(f).

(g)通过低功率电感耦合等离子体干法蚀刻,具体是通过电感耦合等离子体蚀刻氮化硅和栅极凹槽。(g) Dry etching by low power inductively coupled plasma, specifically silicon nitride and gate recesses by inductively coupled plasma.

(h)通过使用等离子体增强化学气相沉积的方式来沉积氮化硅,作为栅极电介质。(h) Depositing silicon nitride as the gate dielectric by using plasma enhanced chemical vapor deposition.

(i)形成栅电极,并形成源电极和漏电极的纯电阻。(i) A gate electrode is formed, and a pure resistance of a source electrode and a drain electrode is formed.

需要说明的是,金属有机化学气相沉积是以Ⅲ族、Ⅱ族元素的有机化合物和V、Ⅵ族元素的氢化物等作为晶体生长源材料,以热分解反应方式在衬底上进行气相外延,生长各种Ⅲ-V主族、Ⅱ-Ⅵ副族化合物半导体以及它们的多元固溶体的薄层单晶材料。It should be noted that metal-organic chemical vapor deposition uses organic compounds of group III and group II elements and hydrides of group V and group VI elements as crystal growth source materials, and conducts vapor phase epitaxy on the substrate by thermal decomposition reaction. Thin-layer single crystal materials of various III-V main group, II-VI subgroup compound semiconductors and their multiple solid solutions are grown.

其中,金属有机化学气相沉积是以Ⅲ族、Ⅱ族元素的有机化合物和V、Ⅵ族元素的氢化物等作为晶体生长源材料,以热分解反应方式在衬底上进行气相外延,生长各种Ⅲ-V主族、Ⅱ-Ⅵ副族化合物半导体以及它们的多元固溶体的薄层单晶材料。Among them, metal-organic chemical vapor deposition uses organic compounds of group III and group II elements and hydrides of group V and group VI elements as crystal growth source materials, and conducts vapor phase epitaxy on the substrate in a thermal decomposition reaction method to grow various Thin-layer single crystal materials of III-V main group, II-VI subgroup compound semiconductors and their multiple solid solutions.

表1:主要结构参数Table 1: Main structural parameters

这两个结构由Synopsys Inc.的Sentaurus TCAD软件进行仿真。为了验证我们使用仿真工具模拟EJ-高电子迁移率晶体管新结构性能的可靠性,首先使用BENCHMARK TEST的方法,让仿真模型、参数和缺省参数得到实验数据的证实。为了与实验和真实物量更精确地对应,我们选择了一些广泛使用的物理模型,例如Recombination模型,Shockley ReadHall(SRH)模型,Auger模型和Mobility模型,DopingDep模型和高饱和度模型。此外,通过压电极化(应变)模型计算了氮化铝镓和氮化镓的极化效应。在电荷载流子与晶格处于热平衡的假设下,使用热电子模型来说明自热效应。雪崩模型用于模拟器件击穿仿真。The two structures were simulated by Synopsys Inc.'s Sentaurus TCAD software. In order to verify the reliability of our use of simulation tools to simulate the performance of the new structure of EJ-high electron mobility transistors, we first use the method of BENCHMARK TEST to make the simulation model, parameters and default parameters confirmed by experimental data. In order to correspond more precisely with the experimental and real quantities, we selected some widely used physical models, such as Recombination model, Shockley ReadHall (SRH) model, Auger model and Mobility model, DopingDep model and high saturation model. In addition, the polarization effects of AlGaN and GaN were calculated by the piezoelectric polarization (strain) model. Under the assumption that the charge carriers are in thermal equilibrium with the lattice, a hot electron model is used to account for the self-heating effect. The avalanche model is used to simulate device breakdown simulation.

图3(a)比较了实验结果和TCAD的模拟结果在VDS=10V和VGS=2、4、6、8和10V时的IDS-VDS特性。从图中可以看出,具有不同VGS的IDS-VDS特性与实验结果吻合得很好,并且用Sentaurus进行的TCAD模拟得出的RON为14.98Ωmm,接近于实验结果的16.1Ωmm。Figure 3(a) compares the IDS-VDS characteristics of the experimental results and the simulation results of TCAD at VDS = 10V and VGS = 2, 4, 6, 8 and 10V. It can be seen from the figure that the IDS-VDS characteristics with different VGS are in good agreement with the experimental results, and the RON obtained by the TCAD simulation with Sentaurus is 14.98Ωmm, which is close to the experimental result of 16.1Ωmm.

图3(b)显示了EJ-高电子迁移率晶体管晶体管的仿真和实验IDS-VDS和击穿特性。模拟器件的击穿电压接近于实验结果。与实验结果相比,模拟器件的泄漏电流与实验测试数据几乎一致。因为场板对击穿电压特性有很大影响,所以我们更愿意选择经过优化场板的EJ-高电子迁移率晶体管进行比较。Figure 3(b) shows the simulated and experimental IDS-VDS and breakdown characteristics of the EJ-high electron mobility transistor. The breakdown voltage of the simulated devices is close to the experimental results. Compared with the experimental results, the leakage current of the simulated device is almost consistent with the experimental test data. Because the field plate has a great influence on the breakdown voltage characteristics, we prefer to choose the EJ-high electron mobility transistor with optimized field plate for comparison.

模拟结果和各种情形比较情况如下:The simulation results are compared with various scenarios as follows:

图4绘出了三种氮化镓高电子迁移率晶体管击穿的情况下器件沟道电场分布的比较。该图显示了高电场聚集在常规氮化镓高电子迁移率晶体管,也即是C-高电子迁移率晶体管中栅电极角的漏极侧。对于C-高电子迁移率晶体管,栅极附近的电场峰值达到4×106V/cm,几乎达到氮化镓材料的临界电场。因此,在二维电子气完全耗尽之前,该晶体管已经击穿。对于FPC-高电子迁移率晶体管,在引入栅极场板和漏极场板的情况下,栅极附近的电场急剧减小,并且峰值电场出现在栅极场板附近的位置。另外,随着漏场板的长度增加,漏场板附近的峰值电场向左移动。与C-高电子迁移率晶体管相比,FPC-高电子迁移率晶体管可以改善栅极和漏极之间的电场分布。为了进一步改善栅极和漏极之间的电场分布,我们提出了EJ-高电子迁移率晶体管。Figure 4 plots a comparison of device channel electric field distributions for three GaN high electron mobility transistors under breakdown. This figure shows that the high electric field is concentrated on the drain side of the gate electrode corner in a conventional GaN high electron mobility transistor, that is, a C-high electron mobility transistor. For C-high electron mobility transistors, the peak value of the electric field near the gate reaches 4×106V/cm, almost reaching the critical electric field of GaN material. Thus, the transistor breaks down before the two-dimensional electron gas is completely depleted. For FPC-high electron mobility transistors, with the introduction of the gate field plate and the drain field plate, the electric field near the gate decreases sharply, and the peak electric field appears at the position near the gate field plate. In addition, the peak electric field near the drain plate shifts to the left as the length of the drain plate increases. Compared with C-high electron mobility transistor, FPC-high electron mobility transistor can improve the electric field distribution between gate and drain. To further improve the electric field distribution between the gate and drain, we propose the EJ-high electron mobility transistor.

对于硅基氮化镓高电子迁移率晶体管,漏极泄漏电流主要由衬底-漏极泄漏电流和源极-漏极泄漏电流组成。在仿真中,衬底浮置以避免衬底-漏极泄漏电流,而浮置衬底可以实现更高的器件额定电压,并为高漏极偏置开关操作提供更好的动态RON。另一方面,源极-漏极泄漏电流主要由缓冲器泄漏电流引起。在FPC-高电子迁移率晶体管引入内置N型层和P型层时,N型层和无掺杂的氮化镓缓冲层形成N-/N+结,该N-/N+结在氮化镓缓冲层中引入峰值电场,从而改善了器件内部电场分布。N型层和P型层形成内置PN结,其改善了栅极和N型层之间的电场分布。由于漏场板下方的P型层,漏场板附近的峰值电场急剧减小。另外,高N掺杂的氮化镓层与缓冲层接触,并且其改变了缓冲漏电流路径,这使得EJ-高电子迁移率晶体管更难以击穿。For GaN-on-Si high electron mobility transistors, the drain leakage current mainly consists of substrate-drain leakage current and source-drain leakage current. In simulations, the substrate is floated to avoid substrate-drain leakage current, while the floating substrate can achieve higher device voltage rating and provide better dynamic RON for high drain bias switching operation. On the other hand, the source-drain leakage current is mainly caused by the buffer leakage current. When the FPC-high electron mobility transistor introduces the built-in N-type layer and P-type layer, the N-type layer and the undoped GaN buffer layer form an N-/N+ junction, and the N-/N+ junction is in the GaN buffer The peak electric field is introduced into the layer, thereby improving the electric field distribution inside the device. The N-type layer and the P-type layer form a built-in PN junction, which improves the electric field distribution between the gate and the N-type layer. Due to the P-type layer below the drain plate, the peak electric field decreases sharply near the drain plate. In addition, the highly N-doped gallium nitride layer is in contact with the buffer layer, and it changes the buffer leakage current path, which makes it more difficult for the EJ-high electron mobility transistor to break down.

图5给出了C-高电子迁移率晶体管,FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的截止状态特性,并比较了LGD=15μm的三种架构的VGS=0V的仿真截止状态特性曲线。击穿电压定义为在截止状态下漏极电流为10-6A/mm时的电压。C-高电子迁移率晶体管的模拟击穿电压为868.3V,FPC-高电子迁移率晶体管的模拟击穿电压为1546.6V,EJ-HMT的模拟击穿电压为2050V。使用场板方面,C-高电子迁移率晶体管的击穿能力无疑得到了提高。且内置PN结有助于FPC-高电子迁移率晶体管进一步改善击穿特性。FPC-高电子迁移率晶体管的模拟击穿电压提高了32.54%。Figure 5 shows the off-state characteristics of C-high electron mobility transistor, FPC-high electron mobility transistor and EJ-high electron mobility transistor, and compares the simulated cut-off of VGS=0V for the three architectures with LGD=15μm State characteristic curve. The breakdown voltage is defined as the voltage at which the drain current is 10-6A/mm in the off state. The simulated breakdown voltage of C-high electron mobility transistor is 868.3V, the simulated breakdown voltage of FPC-high electron mobility transistor is 1546.6V, and the simulated breakdown voltage of EJ-HMT is 2050V. In terms of using field plates, the breakdown capability of C-high electron mobility transistors has undoubtedly been improved. And the built-in PN junction helps the FPC-high electron mobility transistor to further improve the breakdown characteristics. The simulated breakdown voltage of the FPC-high electron mobility transistor was increased by 32.54%.

二维电子气中的横向电子密度分布如图6所示。为了与实验结果相吻合,在氮化铝镓/氮化镓异质结的表面设置了4.8×1012cm-3陷阱,其二维电子气密度N二维电子气为1.25×1019cm-3。P型层的掺杂浓度为1×1017cm-3,足以耗尽N型层产生的额外电荷。P型层区域中的二维电子气被P型层代替。P型层嵌入在N型层中,从而切断了栅极和漏极之间的二维电子气部分。N型层的掺杂浓度值为1×1019cm-3,接近二维电子气密度(N二维电子气)。尽管二维电子气的一部分被N型层和P型层代替,但从N型层到P型层(LPN)的距离为0.01μm仍然适合实现低沟道电阻。The lateral electron density distribution in the 2D electron gas is shown in Fig. 6. In order to be consistent with the experimental results, a 4.8×1012cm-3 trap was set on the surface of the AlGaN/GaN heterojunction, and its two-dimensional electron gas density N was 1.25×1019cm-3. The doping concentration of the P-type layer is 1×1017cm-3, which is enough to deplete the extra charge generated by the N-type layer. The two-dimensional electron gas in the P-type layer region is replaced by the P-type layer. The P-type layer is embedded in the N-type layer, thereby cutting off the two-dimensional electron gas portion between the gate and the drain. The doping concentration of the N-type layer is 1×1019cm-3, which is close to the two-dimensional electron gas density (N two-dimensional electron gas). Although part of the 2D electron gas is replaced by the N-type layer and the P-type layer, the distance from the N-type layer to the P-type layer (LPN) of 0.01 μm is still suitable for achieving low channel resistance.

图7比较了VDS=10V和VGS=2、4、6、8和10V时FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管的漏极电流曲线。我们看到,EJ-高电子迁移率晶体管的电流几乎与FPC-高电子迁移率晶体管的。氮化镓基电子器件的输出特性主要取决于二维电子气的密度和沟道电流密度。FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管具有相似的沟道电流密度。对于EJ-高电子迁移率晶体管,使用高掺杂的N型层代替二维电子气区域的一部分。N型层的浓度接近二维电子气的密度,这导致了类似的导通电流。EJ-HMT的RON为15.37Ωmm,略高于FPC-高电子迁移率晶体管的14.98Ωmm。图8比较了FPC-高电子迁移率晶体管和EJ-高电子迁移率晶体管在VDS=1V时的传输特性曲线。两种结构的阈值电压均约为1.7V,并且阈值电压定义为IDS=0.01mA/mm。众所周知,氮化镓高电子迁移率晶体管结构的阈值电压主要由栅极电介质的厚度和栅电极下方的空间电荷决定。所提出的EJ-高电子迁移率晶体管结构对栅电介质的厚度和栅电极下方的空间电荷没有任何影响。因此,EJ-高电子迁移率晶体管不会改变结构转移特性。EJ-高电子迁移率晶体管结构采用高掺杂N型层代替二维电子气的一部分,栅极和漏极之间的电流密度略有降低。Fig. 7 compares the drain current curves of FPC-high electron mobility transistor and EJ-high electron mobility transistor at VDS=10V and VGS=2, 4, 6, 8 and 10V. We see that the current of the EJ-HEM transistor is almost the same as that of the FPC-HEM transistor. The output characteristics of GaN-based electronic devices mainly depend on the density of the two-dimensional electron gas and the channel current density. FPC-High Electron Mobility Transistor and EJ-High Electron Mobility Transistor have similar channel current densities. For EJ - High Electron Mobility Transistors, a highly doped N-type layer is used instead of part of the 2D electron gas region. The concentration of the N-type layer is close to the density of the two-dimensional electron gas, which leads to a similar on-current. The RON of EJ-HMT is 15.37Ωmm, which is slightly higher than 14.98Ωmm of FPC-high electron mobility transistor. FIG. 8 compares the transfer characteristic curves of FPC-high electron mobility transistor and EJ-high electron mobility transistor at VDS=1V. The threshold voltage of both structures is about 1.7 V, and the threshold voltage is defined as IDS = 0.01 mA/mm. It is well known that the threshold voltage of GaN high electron mobility transistor structures is mainly determined by the thickness of the gate dielectric and the space charge under the gate electrode. The proposed EJ-high electron mobility transistor structure does not have any effect on the thickness of the gate dielectric and the space charge under the gate electrode. Therefore, EJ-high electron mobility transistors do not change the structure transfer properties. The EJ-high electron mobility transistor structure uses a highly doped N-type layer to replace part of the two-dimensional electron gas, and the current density between the gate and drain is slightly reduced.

为了获得EJ-高电子迁移率晶体管的最佳Baliga品质因数(BFOM,定义为VBK2/RON),我们模拟了不同N型层掺杂浓度(NN+)的RON,并显示了相应的VBK和RON。图9给出获得的结果。可以看出,随着N型层的掺杂浓度增加,RON的值减小。随着N型层掺杂的增加,VBK的趋势先上升,后下降。当NN+设置为6×1018cm-3时,RON达到最大值。随着N型层的掺杂增加,RON值逐渐降低。当N型层的掺杂达到1×1019cm-3时,模拟的器件击穿电压达到最大值2050V,BFOM趋于最大值,并上升到2.734GW cm-2的值。结果,在NN+=1×1019cm-3处产生BFOM的峰。当NN+设置为1×1019cm-3时,可以对栅极到N型层(LGN)的距离进行优化。图10绘制了每个LGN的优化EJ-高电子迁移率晶体管以及不同LGN的相应VBK和RON。当LGN的长度设置为4um时,VBK保持最小1500V。随着LGN的增加,VBK在模拟过程中以准线性方式增加。当LGN的长度设置为13um时,VBK达到最大2050V。相应计算的RON的趋势保持在狭窄范围内,而优化的BFOM的趋势与优化的VBK的趋势一致。在LGN=13um时,我们的最大BFOM为2.734GWcm-2,而NN+=1.0×1019cm-3。To obtain the best Baliga figure of merit (BFOM, defined as VBK2/RON) for EJ-high electron mobility transistors, we simulated RON with different N-type layer doping concentrations (NN+) and showed the corresponding VBK and RON. Figure 9 presents the results obtained. It can be seen that as the doping concentration of the N-type layer increases, the value of RON decreases. With the increase of N-type layer doping, the trend of VBK first increases and then decreases. When NN+ is set to 6×1018cm-3, RON reaches the maximum value. As the doping of the N-type layer increases, the RON value gradually decreases. When the doping of the N-type layer reaches 1×1019cm-3, the simulated device breakdown voltage reaches the maximum value of 2050V, and the BFOM tends to the maximum value, and rises to the value of 2.734GW cm-2. As a result, a peak of BFOM was generated at NN+=1×1019 cm-3. When NN+ is set to 1×1019cm-3, the distance from the gate to the N-type layer (LGN) can be optimized. Figure 10 plots the optimized EJ-high electron mobility transistors for each LGN and the corresponding VBK and RON for different LGNs. When the length of LGN is set to 4um, VBK keeps minimum 1500V. As LGN increases, VBK increases in a quasi-linear manner during the simulation. When the length of LGN is set to 13um, VBK reaches a maximum of 2050V. The trend of the corresponding calculated RON remains within a narrow range, while the trend of the optimized BFOM is consistent with that of the optimized VBK. When LGN=13um, our maximum BFOM is 2.734GWcm-2, and NN+=1.0×1019cm-3.

图11给出了EJ-高电子迁移率晶体管每个WN以及相应的VBK和RON的优化。随着WN的上升,击穿电压也上升。当WN=1.5μm时,击穿电压达到饱和值2050V。随着WN的增加,N型层聚集了更多的二维电子气,RON逐渐增加。图12给出了每个HN以及相应的VBK和RON的优化EJ-高电子迁移率晶体管。N型器件条件下击穿电压和RON随着HN的增加而降低。Figure 11 presents the optimization of each WN and the corresponding VBK and RON of the EJ-high electron mobility transistor. As WN increases, the breakdown voltage also increases. When WN=1.5μm, the breakdown voltage reaches the saturation value of 2050V. With the increase of WN, the N-type layer gathers more 2D electron gas, and the RON gradually increases. Figure 12 presents the optimized EJ-high electron mobility transistors for each HN and the corresponding VBK and RON. The breakdown voltage and RON of N-type devices decreased with the increase of HN.

图12给出了针对每个HP以及相应的VBK和RON的优化EJ-高电子迁移率晶体管。随着HP的增加,击穿电压先上升然后下降。HP越大,HN越低,导致RON随着HP的增加而升高。当HP=31nm时,击穿电压达到最大值2050V。图13给出了每个NP以及相应的VBK和RON的优化EJ-高电子迁移率晶体管。随着NP的增加,击穿电压首先略微上升,然后下降。当增加NP时,RON保持上升。当增加P型层的掺杂浓度时,更多的N型层将被耗尽并且击穿电压波动被保持在电压裕度的小范围内。Figure 12 presents the optimized EJ-high electron mobility transistors for each HP and the corresponding VBK and RON. With the increase of HP, the breakdown voltage first increases and then decreases. The greater the HP, the lower the HN, resulting in an increase in RON with increasing HP. When HP=31nm, the breakdown voltage reaches the maximum value of 2050V. Figure 13 presents the optimized EJ-high electron mobility transistors for each NP and the corresponding VBK and RON. With the increase of NP, the breakdown voltage increases slightly at first and then decreases. When increasing NP, RON keeps rising. When increasing the doping concentration of the P-type layer, more N-type layer will be depleted and the breakdown voltage fluctuation is kept within a small range of voltage margin.

以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Anyone skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present invention. Should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be determined by the protection scope of the claims.

Claims (2)

1.内置PN结硅基高压增强型氮化镓晶体管,其特征在于,包括硅衬底、过渡层、缓冲层、势垒层,内置的N型层和P型层形成的嵌入结在势垒层和缓冲层中形成PN结,二维电子气的一部分替换为高掺杂N型层,同时P型层嵌入在N型层中;从下往上依次为硅衬底、过渡层、缓冲层、势垒层;所述势垒层为氮化铝镓势垒层,在氮化铝镓势垒层上形成二氧化硅作为蚀刻掩模,再蚀刻氮化铝镓阻挡层和氮化镓缓冲层,通过分子束外延的晶体生长技术使N型层和P型层重新生长,在P型层的顶部沉积二氧化硅掩模,形成N型层,作为通过等离子体增强化学气相沉积形成的钝化层,通过电感耦合等离子体蚀刻氮化硅和栅极凹槽,通过沉积氮化硅,作为栅极电介质,形成源电极和漏电极的纯电阻,形成的内置PN结位于栅极和漏极之间。1. Built-in PN junction silicon-based high-voltage enhancement-mode gallium nitride transistor, which is characterized in that it includes a silicon substrate, a transition layer, a buffer layer, and a barrier layer, and the embedded junction formed by the built-in N-type layer and P-type layer is in the barrier A PN junction is formed in the layer and the buffer layer, a part of the two-dimensional electron gas is replaced by a highly doped N-type layer, and the P-type layer is embedded in the N-type layer; from bottom to top are the silicon substrate, the transition layer, and the buffer layer , barrier layer; the barrier layer is an aluminum gallium nitride barrier layer, silicon dioxide is formed on the aluminum gallium nitride barrier layer as an etching mask, and then the aluminum gallium nitride barrier layer and the gallium nitride buffer layer are etched Layer, the N-type layer and P-type layer are regrown by molecular beam epitaxy crystal growth technology, and a silicon dioxide mask is deposited on top of the P-type layer to form an N-type layer as a passivation layer formed by plasma-enhanced chemical vapor deposition. Silicon nitride and gate grooves are etched by inductively coupled plasma, and silicon nitride is deposited as a gate dielectric to form a pure resistance of the source and drain electrodes, and the built-in PN junction formed is located at the gate and drain between. 2.内置PN结硅基高压增强型氮化镓晶体管制造方法,其特征在于,内置PN结硅基高压增强型氮化镓晶体管制造步骤如下:2. A method for manufacturing a silicon-based high-voltage enhancement mode gallium nitride transistor with a built-in PN junction, characterized in that the manufacturing steps of a silicon-based high-voltage enhancement mode gallium nitride transistor with a built-in PN junction are as follows: (a)在硅衬底上生长过渡层,然后通过金属有机化学气相沉积在过渡层上依次生长缓冲层和氮化铝镓势垒层;(a) A transition layer is grown on a silicon substrate, and then a buffer layer and an aluminum gallium nitride barrier layer are sequentially grown on the transition layer by metal-organic chemical vapor deposition; (b)通过使用等离子体增强化学气相沉积法形成二氧化硅作为蚀刻掩模;(b) forming silicon dioxide as an etch mask by using plasma-enhanced chemical vapor deposition; (c)用三氯化硼与氯气混合气体通过变压器耦合等离子体反应性离子蚀刻来蚀刻氮化铝镓阻挡层和氮化镓缓冲层;(c) Etching the AlGaN barrier layer and the GaN buffer layer by transformer-coupled plasma reactive ion etching with a mixture of boron trichloride and chlorine; (d)进行紫外线臭氧清洗和氟化氢加盐酸的湿法蚀刻相结合的方法,以减少蚀刻表面的杂质浓度,通过分子束外延的晶体生长技术使N型层和P型层重新生长;(d) A combination of ultraviolet ozone cleaning and wet etching of hydrogen fluoride and hydrochloric acid is used to reduce the concentration of impurities on the etched surface, and the N-type layer and P-type layer are re-grown by molecular beam epitaxy crystal growth technology; (e)使用等离子增强化学气相沉积法在P型层的顶部沉积二氧化硅掩模,并通过硅离子注入形成N型层,内置PN结位于栅极和漏极之间;(e) A silicon dioxide mask is deposited on top of the P-type layer using plasma-enhanced chemical vapor deposition, and an N-type layer is formed by silicon ion implantation, with a built-in PN junction between the gate and drain; (f)注入后,使用氢氟酸去除二氧化硅掩模,然后进行注入后退火,以激活注入的硅,并使用原位远程等离子体预处理技术去除样品表面上的自然氧化物,且表面损伤最小,并沉积氮化硅,作为通过等离子体增强化学气相沉积形成的钝化层;(f) After implantation, the silicon dioxide mask was removed using hydrofluoric acid, followed by a post-implantation anneal to activate the implanted silicon and remove the native oxide on the sample surface using an in-situ remote plasma pretreatment technique, and the surface Minimal damage and deposition of silicon nitride as a passivation layer via plasma enhanced chemical vapor deposition; (g)通过低功率电感耦合等离子体干法蚀刻,具体是通过电感耦合等离子体蚀刻氮化硅和栅极凹槽;(g) dry etching by low power inductively coupled plasma, specifically silicon nitride and gate grooves by inductively coupled plasma; (h)通过使用等离子体增强化学气相沉积的方式来沉积氮化硅,作为栅极电介质;(h) depositing silicon nitride as a gate dielectric by using plasma enhanced chemical vapor deposition; (i)形成栅电极,并形成源电极和漏电极的纯电阻。(i) Form the gate electrode, and form the pure resistance of the source and drain electrodes.
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