CN111631220A - Pesticide composition and application thereof - Google Patents
Pesticide composition and application thereof Download PDFInfo
- Publication number
- CN111631220A CN111631220A CN202010538759.0A CN202010538759A CN111631220A CN 111631220 A CN111631220 A CN 111631220A CN 202010538759 A CN202010538759 A CN 202010538759A CN 111631220 A CN111631220 A CN 111631220A
- Authority
- CN
- China
- Prior art keywords
- dinotefuran
- chlorantraniliprole
- oligosaccharin
- amino
- pesticide composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000000575 pesticide Substances 0.000 title claims abstract description 55
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 claims abstract description 80
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000005886 Chlorantraniliprole Substances 0.000 claims abstract description 73
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 33
- 239000004480 active ingredient Substances 0.000 claims abstract description 23
- 230000002195 synergetic effect Effects 0.000 claims abstract description 15
- 241000218641 Pinaceae Species 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 claims description 30
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 28
- 235000018782 Dacrydium cupressinum Nutrition 0.000 claims description 26
- 235000013697 Pinus resinosa Nutrition 0.000 claims description 26
- 241000534656 Pinus resinosa Species 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 241000238631 Hexapoda Species 0.000 claims description 20
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- 230000000361 pesticidal effect Effects 0.000 claims description 16
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 15
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 claims description 15
- 229920001732 Lignosulfonate Polymers 0.000 claims description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 15
- 229960000458 allantoin Drugs 0.000 claims description 15
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 15
- 235000010413 sodium alginate Nutrition 0.000 claims description 15
- 239000000661 sodium alginate Substances 0.000 claims description 15
- 229940005550 sodium alginate Drugs 0.000 claims description 15
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 15
- 240000007263 Pinus koraiensis Species 0.000 claims description 12
- 235000011615 Pinus koraiensis Nutrition 0.000 claims description 12
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 235000011613 Pinus brutia Nutrition 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
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- 239000000725 suspension Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
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- 239000000600 sorbitol Substances 0.000 claims description 4
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 3
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- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 3
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- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 claims description 3
- 239000001685 glycyrrhizic acid Substances 0.000 claims description 3
- 229960004949 glycyrrhizic acid Drugs 0.000 claims description 3
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 claims description 3
- 235000019410 glycyrrhizin Nutrition 0.000 claims description 3
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims description 3
- 229920013747 hydroxypolyethylene Polymers 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
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- 229960003885 sodium benzoate Drugs 0.000 claims description 3
- 229940074404 sodium succinate Drugs 0.000 claims description 3
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 3
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The invention discloses a pesticide composition and application thereof, wherein the pesticide composition contains active ingredients of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin in a weight ratio of 1 (0.1-99) to 0.05-50. Compared with the single use of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin or the compound use of two of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin, the pesticide composition has better control effect on forestry pests. In addition, the application ratios of chlorantraniliprole, dinotefuran dextroisomer and amino-oligosaccharin have the synergistic effect in a wide range, so that the composition has a very remarkable control effect on the mixed occurrence of different types of strobilus pests of Pinaceae plants, and is high in action speed, high in medicament utilization rate, cost-saving and high in safety.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a pesticide composition and application thereof.
Background
In recent years, the harm of the strobilus pests of the Pinaceae plants is increasingly serious, and the pest threatens the economy and the ecology of forest areas seriously. The Korean pine is a national II-level key protection tree species, not only is a precious timber tree species, but also is one of main afforestation and greening tree species, and is also an important economic tree species. In recent years, strobilus Pini pests of Pinaceae plants are rampant, which seriously affect the under-forest renewal of Korean pine seedlings and the healthy development of Korean pine seed industry. Investigation shows that in some severe occurrence areas, the damage rate of strobilus of Pinaceae plants is as high as more than 70%, and some strobilus of Pinaceae plants are almost no longer harvested. The strobilus Pini as a plant of Pinaceae not only greatly reduces the yield and quality of red pine seeds and causes huge direct economic loss, but also seriously threatens the natural renewal of the red pine forest and influences the exertion of forest ecological benefits. Wherein, the Pinus massoniana guenee, the Abies fir tip striped rice borer, the Hemocarpus orbiculatus Chilo moth and the Pinus densiflora tip striped rice borer are main pests of the Pinus koraiensis cones.
At present, chemical control, biological control and forest control measures are mainly adopted for controlling strobilus pests of Pinaceae plants. The chemical control adopts tebufenozide, fipronil, abamectin, imidacloprid and beta-cypermethrin for spraying, the control effect is poor, the trunk pesticide injection technology of imidacloprid and thiacloprid is used for controlling Korean pine, a strong pesticide injection method is used for controlling Korean pine, the biological control adopts the functions of spraying bacillus thuringiensis for controlling and releasing parasitic natural enemies, or oligosaccharide is used for assisting in controlling the functions of growth, development, reproduction, insect pest prevention and the like of plants, and the method for forestation under canopy is adopted for the nutritive forest control. The above methods have poor or single effect, or are time-consuming and labor-consuming. Therefore, the development of a pesticide product and a method which can comprehensively control a plurality of mixed insect pests and have outstanding control effect is needed.
Disclosure of Invention
The invention aims to provide a pesticide composition and application thereof aiming at overcoming the technical defects in the prior art, and aims to solve the technical problem that the control effect of conventional pesticides on pine cone pests needs to be improved in the prior art.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
the pesticide composition contains active ingredients, wherein the active ingredients comprise chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin, and the weight ratio of the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin in the active ingredients is 1: 0.1-99: 0.05-50.
Preferably, in the active ingredients, the weight ratio of chlorantraniliprole to dinotefuran dextroenantiomer to amino-oligosaccharin is 1: 1-10: 0.5-5.
Preferably, the weight percentage of the active ingredient in the pesticide composition is 5-60%.
Preferably, an adjuvant is contained in the pesticide composition, and is selected from one or several of the following components: synergistic humectant, dispersing humectant, thickener, defoaming agent, preservative and water.
Preferably, in the pesticide composition: the weight percentage of the synergistic humectant is 0.01 percent to 10 percent; the weight percentage of the dispersing wetting agent is 0.1 to 20 percent; the weight percentage of the thickening agent is 0.01 percent to 1 percent; the weight percentage of the defoaming agent is 0.01 percent to 1 percent; the weight percentage of the preservative is 0.01 percent to 1 percent; the weight percentage of the water is 40-95%.
Preferably, the synergistic humectant is selected from one or several of the following components: glycyrrhizic acid, allantoin, sorbitol, urea; the dispersion wetting agent is selected from one or more of the following components: fatty alcohol-polyoxyethylene ether, polyoxyethylene polyoxypropylene ether block copolymer, alkyl naphthalene sulfonate formaldehyde condensate, polycarboxylate, lignosulfonate, alkylphenol polyoxyethylene ether formaldehyde condensate, phosphate, sodium succinate, sodium dodecyl sulfate and hydroxy polyethylene oxide block copolymer; the thickening agent is selected from one or more of the following components: sodium alginate, dextrin, arabic gum, gelatin, xanthan gum, carboxymethyl cellulose, methyl cellulose, and magnesium aluminum silicate; the preservative is selected from one or several of the following components: 1-2 benzisothiazolin-3-one, kaempferol, formaldehyde, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate; the defoaming agent is selected from one or several of the following components: silicone oil, organic silicone compounds, ester-ether compounds, C8-C12 fatty alcohol compounds, C10-C20 fatty acid compounds.
Preferably, the pesticide composition is in the form of a suspension.
On the basis of the technical scheme, the invention further provides application of the pesticide composition in preventing and treating the pine cone plant fruit pests.
Preferably, the Pinaceae plant includes Pinus koraiensis, Pinus densiflora, Pinus thunbergii, Pinus sylvestris, Pinus massoniana, and spruce.
On the basis of the technical scheme, the invention further provides the application of the pesticide composition in preventing and controlling the red pine cone pests; wherein the red pine cone insect pests include Pinus massoniana guenee, Abies fir tip spotted borer, Pinus densiflora guenee and Spodoptera frugiperda.
The invention provides a pesticide composition and application thereof. According to the technical scheme, chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin are compounded in a specific ratio, so that red pine cone insect pests caused by pinkeye, fir tip pinkeye, red pine tip pinkeye, carpesia cunea and the like can be effectively prevented and treated. Compared with the single chlorantraniliprole, the dinotefuran dextroenantiomer or the amino-oligosaccharin and the compound use of any two of the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin, the pesticide composition disclosed by the invention has a more remarkable control effect by compounding the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin, the synergistic effect is realized in the use ratio of the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin in a wider range, the comprehensive control can be performed on the mixed occurrence of various insect pests, and the control effect is remarkable. The pesticide composition provided by the invention can be used for simultaneously preventing and treating red pine cone insect pests caused by pinkeye, fir tip spotted borer, red pine tip spotted borer, carposina niponensis koidzumi and the like, has a broad-spectrum insecticidal effect, and has an improved effect on preventing and treating each kind of red pine cone insect pests compared with the existing pesticide products.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Detailed Description
Hereinafter, specific embodiments of the present invention will be described in detail. Well-known structures or functions may not be described in detail in the following embodiments in order to avoid unnecessarily obscuring the details. Approximating language, as used herein in the following examples, may be applied to identify quantitative representations that could permissibly vary in number without resulting in a change in the basic function. Unless defined otherwise, technical and scientific terms used in the following examples have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
First aspect of the invention: the pesticide composition contains an active ingredient and an auxiliary agent, wherein the active ingredient comprises chlorantraniliprole, a dinotefuran dextroenantiomer and amino-oligosaccharin, and the weight ratio of the chlorantraniliprole to the dinotefuran dextroenantiomer to the amino-oligosaccharin is 1: (0.1-99): (0.05-50).
The active ingredients of the pesticide composition are chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin which are combined and used according to a proportion, so that red pine cone insect pests caused by pinkeye, fir tip spotted borer, red pine tip spotted borer, carpesia cunea and the like can be effectively prevented and treated. Compared with the single chlorantraniliprole, the dinotefuran dextroenantiomer or the amino-oligosaccharin and the compound use of any two of the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin, the pesticide composition disclosed by the invention has a more remarkable control effect by compounding the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin, the synergistic effect is realized in the use ratio of the chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin in a wider range, the comprehensive control can be performed on the mixed occurrence of various insect pests, and the control effect is remarkable. The pesticide composition provided by the invention can be used for simultaneously preventing and treating red pine cone insect pests caused by pinkeye, fir tip spotted borer, red pine tip spotted borer, carposina niponensis koidzumi and the like, has a broad-spectrum insecticidal effect, and has an improved effect on preventing and treating each kind of red pine cone insect pests compared with the existing pesticide products.
In the present invention, chlorantraniliprole is 3-bromo-N- [ 4-chloro-2-methyl-6- (methylcarbamoyl) benzene]-1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide, formula: c18H14N5O2BrCl2Relative molecular weight: 483.15, having the English name of Chloratraniniprole, the CAS number of 500008-45-7, and the structural formula shown in formula (1):
dinotefuran is a tradename for (RS) 1-methyl-2-nitro-3- (3-tetrahydrofuromethyl) guanidine, molecular formula: c7H14N4O3Relative molecular weight: 202.2, having the name dinotefuran and the CAS number of 165252-70-0, and the structural formula shown in formula (2):
the dinotefuran dextro enantiomer serving as an active ingredient in the pesticide composition is a dinotefuran dextro enantiomer, and the insecticidal activity of the dinotefuran mainly comes from the dinotefuran dextro enantiomer, namely (R) 1-methyl-2-nitro-3- (3-tetrahydrofuryl methyl) guanidine, and the molecular formula, the relative molecular weight, the English name and the CAS number of the dinotefuran dextro enantiomer are the same as that of dinotefuran.
The amino-oligosaccharin is [ (1, 4) -2-amino-2-deoxy- β -D-glucose]nTrade name of (2), molecular formula: (C)6H11NO4)n·H2O (n is more than or equal to 2 and less than or equal to 20), the relative molecular weight is n × 161+18(n is less than or equal to 20), the English name is oligosaccharins, the CAS number is 9012-76-4, and the structural formula is shown as a formula (3):
according to the invention, in order to further enhance the synergistic effect of compounding chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin, preferably, the weight ratio of the chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin can be 1: (1-10): (0.5-5). Under the preferable condition within the proportion range, the three components have the most outstanding synergistic effect, can obtain excellent control effect with lower application dosage of the composition, and can obviously improve the control effect of various red pine cone pests.
According to the first aspect of the invention, the pesticide composition is characterized in that the content of the pesticide active ingredient in the pesticide preparation is 5-60% by weight based on the total amount of the composition.
According to the first aspect of the present invention, the pesticidal composition may further contain a composition adjuvant. The adjuvant comprises one or more selected from a synergistic humectant, a dispersing humectant, a thickener, a defoamer, a preservative and water. Based on the total amount of the composition, the weight content of the synergistic humectant in the pesticide preparation is 0.01-10%, the weight content of the dispersion humectant in the pesticide preparation is 0.1-20%, the weight content of the thickener in the pesticide preparation is 0.01-1%, the weight content of the defoamer in the pesticide preparation is 0.01-1%, the weight content of the preservative in the pesticide preparation is 0.01-1%, and the weight content of the water in the pesticide preparation is 40-95%. The amount of the adjuvant is not particularly limited, and may be selected from conventional amounts according to different formulations of the pesticide composition, which are well known to those skilled in the art.
According to the first aspect of the present invention, the adjuvant in the pesticidal composition may be formulated as needed with ingredients commonly used in the art, and the adjuvant includes one or more selected from the group consisting of a booster humectant, a dispersion wetting agent, a thickener, an antifoaming agent, a preservative and water.
According to the first aspect of the present invention, the ingredients of the adjuvant in the pesticidal composition are not particularly limited, and those commonly used in the art, for example: the synergistic humectant is at least one selected from glycyrrhizic acid, allantoin, sorbitol and urea, the dispersing humectant is at least one selected from fatty alcohol-polyoxyethylene ether, polyoxyethylene polyoxypropylene ether block copolymer, alkyl naphthalene sulfonate formaldehyde condensate, polycarboxylate, lignosulfonate, alkylphenol polyoxyethylene ether formaldehyde condensate, phosphate esters, sodium succinate sulfonate, sodium lauryl sulfate and hydroxy polyethylene oxide block copolymer, the thickener is at least one selected from sodium alginate, dextrin, Arabic gum, gelatin, xanthan gum, carboxymethyl cellulose, methyl cellulose and magnesium aluminum silicate, the preservative is at least one selected from 1-2 benzisothiazolin-3-one (BIT), kaempferon, formaldehyde, benzoic acid, sodium benzoate, sorbic acid and potassium sorbate, and the defoaming agent is at least one selected from silicone oil, sorbitol and urea, At least one of organic silicone compounds, ester-ether compounds, C8-C12 fatty alcohol compounds and C10-C20 fatty acid compounds.
The pesticidal composition of the present invention may be provided in the form of a finished product, i.e., the components of the composition have been mixed, or each component may be provided in the form of a separate formulation which is directly tank-mixed at the time of use.
In the present invention, the formulation prepared from the pesticidal composition is a suspension.
In the present invention, there is no special requirement for the preparation method of the suspending agent, and various methods known in the art can be adopted, and are not described herein again.
It will be understood by those skilled in the art that the various dosage forms of the present invention may be diluted for use as desired in practice.
In a second aspect of the invention, the invention also provides the application of the pesticide composition in the control of the conifer cone insect pests.
In the invention, the pesticide composition and the preparation thereof have no special limitation on the types of the plants in the Pinaceae which can be controlled, and the plants in the Pinaceae can be one or more of Korean pine, red pine, black pine, Chinese red pine and spruce.
In the invention, the pesticide composition and the preparation thereof have no special limitation on the type of insect pest caused by red pine cone insect pest which can be controlled, and optionally, the insect pest can be one or more of insect pests caused by pinkeye, fir tip spotted borer, red pine tip spotted borer and pink boll-worm moth.
For example, the pesticide composition can be applied to red pine, treats insect pests caused by pinkeye, fir tip pinkeye, red pine tip pinkeye and carposina niponensis which are mixed on the red pine, improves the health condition of the red pine, and effectively reduces the phenomena of malformation or drying shrinkage, incapability of setting and the like caused by damage of carposina niponensis.
The dosage of the pesticide composition per mu of land is not particularly limited, and may be specifically adjusted according to the dosage per mu of active ingredient, the active ingredient content of the preparation and the degree of closure of the Korean pine, for example, the total application amount of the active ingredient per mu of land may be 1-100 g.
The present invention will be described in further detail with reference to examples, but the present invention is not limited thereto.
In the following examples, chlorantraniliprole was purchased from Shandong Weifang Runfeng chemical Co., Ltd, dinotefuran dextro enantiomer was purchased from China university of agriculture academic institute, amino-oligosaccharins were purchased from Shannan Zhengchang agricultural Co., Ltd, oligosaccharins were purchased from Hainan Zhengchang agricultural Co., Ltd, avermectins were purchased from Hebei Xinbai agricultural science Co., Ltd, lignosulfonate, sodium lauryl sulfate, allantoin were purchased from Koenlai chemical Co., Ltd, sodium alginate was purchased from Beijing reagent factory, magnesium aluminum silicate was purchased from Hunan Penta Gaoxin Material Co., Ltd, silicone antifoaming agent was purchased from Mai Gaoxin Gao Material (China) Ltd, and 1-2 benzisothiazolin-3-one (BIT) was purchased from Shanghai continuous Biotechnology Ltd.
Example 1
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:9:2)
1 wt% of chlorantraniliprole, 9 wt% of dinotefuran dextroenantiomer, 2 wt% of amino-oligosaccharin, 3 wt% of lignosulfonate, 1 wt% of sodium dodecyl sulfate, 4 wt% of allantoin, 0.15 wt% of sodium alginate, 0.6 wt% of magnesium aluminum silicate, 0.3 wt% of an organic silicon defoamer, 0.2 wt% of 1-2 benzisothiazolin-3-one (BIT), and water added to 100 wt%.
Example 2
24% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:9:2)
Chlorantraniliprole 2 wt%, dinotefuran dextroenantiomer 18 wt%, amino-oligosaccharin 4 wt%, lignosulfonate 4 wt%, sodium dodecyl sulfate 1.5 wt%, allantoin 4 wt%, sodium alginate 0.15 wt%, magnesium aluminum silicate 0.6 wt%, silicone defoamer 0.3 wt%, 1-2 benzisothiazolin-3-one (BIT)0.2 wt%, water added to 100 wt%.
Example 3
48% chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin is 1:9:2)
4% by weight of chlorantraniliprole, 36% by weight of dinotefuran dextroenantiomer, 4% by weight of amino-oligosaccharin, 5% by weight of lignosulfonate, 2% by weight of sodium dodecyl sulfate, 4% by weight of allantoin, 0.15% by weight of sodium alginate, 0.6% by weight of magnesium aluminum silicate, 0.3% by weight of an organosilicon defoamer, 0.2% by weight of 1-2 benzisothiazolin-3-one (BIT), and water added to 100% by weight.
Example 4
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:6:5)
1 wt% of chlorantraniliprole, 6 wt% of dinotefuran dextroenantiomer, 5 wt% of amino-oligosaccharin, 3 wt% of lignosulfonate, 1 wt% of sodium dodecyl sulfate, 4 wt% of allantoin, 0.15 wt% of sodium alginate, 0.6 wt% of magnesium aluminum silicate, 0.3 wt% of an organic silicon defoamer, 0.2 wt% of 1-2 benzisothiazolin-3-one (BIT), and water added to 100 wt%.
Example 5
12% chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin is 1:1:1)
3% by weight of chlorantraniliprole, 3% by weight of dinotefuran dextroenantiomer, 3% by weight of amino-oligosaccharin, 3% by weight of lignosulfonate, 1% by weight of sodium dodecyl sulfate, 4% by weight of allantoin, 0.15% by weight of sodium alginate, 0.6% by weight of magnesium aluminum silicate, 0.3% by weight of silicone defoamer, 0.2% by weight of 1-2 benzisothiazolin-3-one (BIT), and water added to 100% by weight.
Example 6
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:98.95:0.05)
1% by weight of chlorantraniliprole, 98.95% by weight of dinotefuran dextroenantiomer, 0.05% by weight of amino-oligosaccharin, 3% by weight of lignosulfonate, 1% by weight of sodium dodecyl sulfate, 4% by weight of allantoin, 0.15% by weight of sodium alginate, 0.6% by weight of magnesium aluminum silicate, 0.3% by weight of an organosilicon defoamer, 0.2% by weight of 1-2 benzisothiazolin-3-one (BIT), and water added to 100% by weight.
Example 7
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, the dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:0.1:0.05)
10.43% chlorantraniliprole, 1.04% dinotefuran dextroenantiomer, 0.52% amino-oligosaccharin, 3% lignosulfonate, 1% sodium dodecyl sulfate, 4% allantoin, 0.15% sodium alginate, 0.6% magnesium aluminum silicate, 0.3% silicone defoamer, 0.2% 1-2 benzisothiazolin-3-one (BIT), and water added to 100% by weight.
Example 8
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:0.1:0.1)
10% by weight of chlorantraniliprole, 1% by weight of dinotefuran dextroenantiomer, 1% by weight of amino-oligosaccharin, 3% by weight of lignosulfonate, 1% by weight of sodium dodecyl sulfate, 4% by weight of allantoin, 0.15% by weight of sodium alginate, 0.6% by weight of magnesium aluminum silicate, 0.3% by weight of an organosilicon defoamer, 0.2% by weight of 1-2 benzisothiazolin-3-one (BIT), and water added to 100% by weight.
Example 9
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:99:50)
0.08 percent of chlorantraniliprole, 7.92 percent of dinotefuran dextroenantiomer, 4 percent of amino-oligosaccharin, 3 percent of lignosulfonate, 1 percent of sodium dodecyl sulfate, 4 percent of allantoin, 0.15 percent of sodium alginate, 0.6 percent of magnesium aluminum silicate, 0.3 percent of organic silicon defoamer, 0.2 percent of 1-2 benzisothiazolin-3-one (BIT) and water added to 100 percent by weight.
Example 10
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:9:50)
0.2 wt% of chlorantraniliprole, 1.8 wt% of dinotefuran dextroenantiomer, 10 wt% of amino-oligosaccharin, 3 wt% of lignosulfonate, 1 wt% of sodium dodecyl sulfate, 4 wt% of allantoin, 0.15 wt% of sodium alginate, 0.6 wt% of magnesium aluminum silicate, 0.3 wt% of an organic silicon defoamer, 0.2 wt% of 1-2 benzisothiazolin-3-one (BIT), and water added to 100 wt%.
Example 11
12% Chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin suspending agent (the weight ratio of the Chlorantraniliprole, dinotefuran dextroenantiomer and the amino-oligosaccharin is 1:69:50)
0.1 wt% of chlorantraniliprole, 6.9 wt% of dinotefuran dextroenantiomer, 5 wt% of amino-oligosaccharin, 3 wt% of lignosulfonate, 1 wt% of sodium dodecyl sulfate, 4 wt% of allantoin, 0.15 wt% of sodium alginate, 0.6 wt% of magnesium aluminum silicate, 0.3 wt% of an organic silicon defoamer, 0.2 wt% of 1-2 benzisothiazolin-3-one (BIT), and water added to 100 wt%.
Comparative example 1
12% Chlorantraniliprole suspension
The dinotefuran dextro enantiomer and the amino-oligosaccharin in example 1 were replaced by chlorantraniliprole with the same weight, and other components were unchanged.
Comparative example 2
12% dinotefuran dextro enantiomer suspending agent
Chlorantraniliprole and the amino-oligosaccharin in the example 1 are replaced by dinotefuran dextro enantiomer with the same weight, and other components are not changed.
Comparative example 3
12% oligosaccharin suspension
The dextro-enantiomer of chlorantraniliprole and dinotefuran in example 1 was replaced by the same weight of amino-oligosaccharin, and the other ingredients were unchanged.
Comparative example 4
12% chlorantraniliprole-dinotefuran dextro enantiomer suspending agent
The amino-oligosaccharin in example 1 was replaced with chlorantraniliprole of the same weight, and the other ingredients were not changed.
Comparative example 5
12% chlorantraniliprole-amino oligosaccharin suspending agent
The dextro enantiomer of dinotefuran in example 1 was replaced with the same amount by chlorantraniliprole, and the other ingredients were unchanged.
Comparative example 6
12% dinotefuran dextro enantiomer amino-oligosaccharin suspending agent
The chlorantraniliprole in example 1 was replaced by the same weight of dinotefuran dextro enantiomer, and the other ingredients were unchanged.
Comparative example 7
12% chlorantraniliprole, dinotefuran dextro enantiomer and oligosaccharin suspending agent
The amino-oligosaccharin in example 1 was replaced with an oligosaccharin of the same weight, and the other ingredients were not changed.
Comparative example 8
12% chlorantraniliprole imidacloprid amino-oligosaccharin suspending agent
The dextro enantiomer of dinotefuran in example 1 was replaced with the same weight of propamocarb imidacloprid, and the other ingredients were unchanged.
Comparative example 9
12% avermectin-dinotefuran dextro enantiomer-amino oligosaccharin suspending agent
The chlorantraniliprole in the embodiment 1 is replaced by avermectin with the same weight, and other components are not changed.
Test example 1
Several pinus densiflora with a breast diameter of 25cm were selected, and the suspending agents prepared in examples 1 to 11 and comparative examples 1 to 9 were diluted to 100ml each of a suspension with 1 wt% of active ingredient for use. Selecting 50 fir tip snout moth's larva and red pine tip snout moth's larva with approximately the same size, respectively dispersedly placing on the insect-free trees with good growth state selected in advance, then injecting the liquid medicine into the trees by a punching liquid injection mode, and then recording the death number of the target insects in 24h, 48h and 72h respectively. Each drug solution was subjected to 3 of the above tests and a blank test set (i.e. pest culture only, not administration to trees) was performed. The mortality in percent (%) was calculated for each treatment according to formula (I).
After 1 day, the control effect of the suspending agent on the fir tip striped rice borer and the red pine tip striped rice borer is more than 95%, as shown in table 1. The action speed is high.
TABLE 1
Test example 2
Several Korean pine having a breast diameter of 20cm were selected, and the suspending agents prepared in examples 1 to 11 and comparative examples 1 to 9 were diluted to 100ml each of a suspension having an active ingredient of 1% by weight for use. Selecting 50 approximately consistent pine cone tip spotted borers and carposina niponensis walsingham in size, dispersedly placing the trees in a pre-selected insect-free tree with good growth state respectively, injecting liquid medicine into the trees in a punching liquid injection mode, and recording the death number of target insects in 24 hours, 48 hours and 72 hours respectively. Each drug solution was subjected to 3 of the above tests and a blank test set (i.e. pest culture only, not administration to trees) was performed. The mortality in percent (%) was calculated for each treatment according to formula (I).
After 1 day, the control effect of the suspending agent on the pinkeye and the plutella xylostella is over 95 percent, and the action speed is high. As shown in table 2:
TABLE 2
Test example 3
The test examples of the present invention test the control effect of the pine trematoda borer in examples 1 to 11 and comparative examples 1 to 9. Before the test, a certain amount of distilled water was added, stirred uniformly, and the concentrations of the active ingredients of examples 1 to 11 and comparative examples 1 to 9 were adjusted to 1% by weight, respectively, for future use.
The pintail pyralid medinalis: the tree is a tree trap collected from pure red pine forest in Changbai mountain of Jilin. And selecting 3-instar larva individual bodies with consistent sizes.
Wood section: the wood segments are selected from healthy Korean pine in Changbai mountain of Jilin, with diameter at breast height of 0.12m, cut into small segments with length of 0.35m, and sealed with peppery seal at two ends to prevent water loss.
And (3) test treatment: the method comprises the following steps of (1) inserting the pinkeye into a wood segment 3 days before a test, prying the phloem of the wood segment by using a knife, chiseling a pit with the length of 10mm, the width of 5mm and the depth of 5mm on the pried wood, placing the pinkeye into the pit, folding the phloem, sealing and numbering. 30 heads of larva of the pinkeye are connected to each wood segment. After 3 days, 25ml of each of the diluted examples 1-8 and comparative examples 1-9 is directly sprayed on the surface of the wood section inoculated with the longicorn to ensure that the whole wood section is wetted thoroughly. Each treatment was repeated 3 times for a total of 90 daily cows. And (3) opening the access ports on days 3, 5 and 7, recording the survival conditions of the pinkeye, picking out the dead pinkeye, then sealing the access ports, and observing the prevention and treatment effect calculated by the formula (II), wherein the results are shown in the table 3.
TABLE 3
Note: the blank provides basic data for other examples and comparative examples.
As can be seen from comparison of the data of examples 1 to 11 with those of comparative examples 1 to 9 according to tables 1, 2 and 3, the pesticidal composition provided by the present invention can achieve excellent control effects on various pine plant pests, compared to the use of chlorantraniliprole, dinotefuran dextroenantiomer or amino-oligosaccharin alone, or the use of a combination of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin, or the use of a combination of two of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin with another component; comparing the data of examples 1-3 with those of examples 4-11, it can be seen that under the condition that the content of the dextro enantiomer of dinotefuran is 0.1-10 parts by weight and the content of the amino-oligosaccharin is 0.5-5 parts by weight relative to 1 part by weight of chlorantraniliprole which is preferred in the invention, more excellent control effect can be obtained, so that the health of crops can be effectively improved, the dosage can be reduced, the cost can be saved, the residue can be reduced, and the pollution to the environment can be reduced; comparing the data of example 7 with those of examples 9 to 12, it can be seen that the active ingredient and the adjuvant are contained in the preferred pesticidal composition of the present invention, wherein the adjuvant is contained in an amount of 0.01 to 10% by weight of the synergistic humectant in the pesticidal formulation, 0.1 to 20% by weight of the dispersion humectant in the pesticidal formulation, 0.01 to 1% by weight of the thickener in the pesticidal formulation, 0.01 to 1% by weight of the antifoaming agent in the pesticidal formulation, 0.01 to 1% by weight of the preservative in the pesticidal formulation, and 40 to 95% by weight of water in the pesticidal formulation, based on the total amount of the composition, without affecting the use effect of the pesticidal composition.
The embodiments of the present invention have been described in detail, but the description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention. Any modification, equivalent replacement, and improvement made within the scope of the application of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. The pesticide composition contains active ingredients, and is characterized in that the active ingredients comprise chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin, and the weight ratio of the chlorantraniliprole to the dinotefuran dextroenantiomer to the amino-oligosaccharin in the active ingredients is 1: 0.1-99: 0.05-50.
2. The pesticide composition as claimed in claim 1, wherein the weight ratio of chlorantraniliprole, dinotefuran dextroenantiomer and amino-oligosaccharin in the active ingredients is 1: 1-10: 0.5-5.
3. The pesticide composition as claimed in claim 1, wherein the active ingredient is present in the pesticide composition in an amount of 5 to 60% by weight.
4. The pesticide composition as set forth in claim 1, wherein an adjuvant is contained in the pesticide composition, and the adjuvant is selected from one or more of the following components: synergistic humectant, dispersing humectant, thickener, defoaming agent, preservative and water.
5. The pesticide composition as set forth in claim 4, wherein in the pesticide composition: the weight percentage of the synergistic humectant is 0.01 percent to 10 percent; the weight percentage of the dispersing wetting agent is 0.1 to 20 percent; the weight percentage of the thickening agent is 0.01 percent to 1 percent; the weight percentage of the defoaming agent is 0.01 percent to 1 percent; the weight percentage of the preservative is 0.01 percent to 1 percent; the weight percentage of the water is 40-95%.
6. The pesticide composition as set forth in claim 4, wherein the synergistic humectant is selected from one or more of the following components: glycyrrhizic acid, allantoin, sorbitol, urea; the dispersion wetting agent is selected from one or more of the following components: fatty alcohol-polyoxyethylene ether, polyoxyethylene polyoxypropylene ether block copolymer, alkyl naphthalene sulfonate formaldehyde condensate, polycarboxylate, lignosulfonate, alkylphenol polyoxyethylene ether formaldehyde condensate, phosphate, sodium succinate, sodium dodecyl sulfate and hydroxy polyethylene oxide block copolymer; the thickening agent is selected from one or more of the following components: sodium alginate, dextrin, arabic gum, gelatin, xanthan gum, carboxymethyl cellulose, methyl cellulose, and magnesium aluminum silicate; the preservative is selected from one or several of the following components: 1-2 benzisothiazolin-3-one, kaempferol, formaldehyde, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate; the defoaming agent is selected from one or several of the following components: silicone oil, organic silicone compounds, ester-ether compounds, C8-C12 fatty alcohol compounds, C10-C20 fatty acid compounds.
7. The pesticide composition as set forth in claim 1, wherein the pesticide composition is in the form of a suspension.
8. Use of the pesticidal composition of any one of claims 1 to 7 for controlling strobilus Pini.
9. The use of claim 8, wherein said Pinaceae plant comprises Pinus koraiensis, Pinus densiflora, Pinus thunbergii, Pinus sylvestris, Pinus massoniana, spruce.
10. The use of the pesticidal composition of any one of claims 1 to 7 for controlling pine cone pests; wherein the red pine cone insect pests include Pinus massoniana guenee, Abies fir tip spotted borer, Pinus densiflora guenee and Spodoptera frugiperda.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114698643A (en) * | 2022-03-23 | 2022-07-05 | 河南农王实业有限公司 | A kind of agricultural composition comprising clothianidin |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN102217639A (en) * | 2011-04-21 | 2011-10-19 | 青岛海利尔药业有限公司 | Insecticidal composition containing dinotefuran and chlorantraniliprole |
| CN103004855A (en) * | 2012-11-26 | 2013-04-03 | 海南正业中农高科股份有限公司 | Composition containing oligosaccharide and anabasine insecticide components |
| CN103651382A (en) * | 2013-12-03 | 2014-03-26 | 海南正业中农高科股份有限公司 | Insecticidal composition containing chitosan oligosaccharide and applications |
-
2020
- 2020-06-13 CN CN202010538759.0A patent/CN111631220A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN102217639A (en) * | 2011-04-21 | 2011-10-19 | 青岛海利尔药业有限公司 | Insecticidal composition containing dinotefuran and chlorantraniliprole |
| CN103004855A (en) * | 2012-11-26 | 2013-04-03 | 海南正业中农高科股份有限公司 | Composition containing oligosaccharide and anabasine insecticide components |
| CN103651382A (en) * | 2013-12-03 | 2014-03-26 | 海南正业中农高科股份有限公司 | Insecticidal composition containing chitosan oligosaccharide and applications |
Non-Patent Citations (1)
| Title |
|---|
| 张金平: "手性单体新烟碱类农药可降低对蜜蜂毒性", 《农药市场信息》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114698643A (en) * | 2022-03-23 | 2022-07-05 | 河南农王实业有限公司 | A kind of agricultural composition comprising clothianidin |
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