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CN111545949A - Solder and heat-insulating container welded by same - Google Patents

Solder and heat-insulating container welded by same Download PDF

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Publication number
CN111545949A
CN111545949A CN202010439595.6A CN202010439595A CN111545949A CN 111545949 A CN111545949 A CN 111545949A CN 202010439595 A CN202010439595 A CN 202010439595A CN 111545949 A CN111545949 A CN 111545949A
Authority
CN
China
Prior art keywords
welding
titanium
solder
container
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010439595.6A
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Chinese (zh)
Inventor
胡华成
彭利泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Novia Industry & Trade Co ltd
Original Assignee
Zhejiang Novia Industry & Trade Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Novia Industry & Trade Co ltd filed Critical Zhejiang Novia Industry & Trade Co ltd
Priority to CN202010439595.6A priority Critical patent/CN111545949A/en
Publication of CN111545949A publication Critical patent/CN111545949A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3006Ag as the principal constituent
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/22Drinking vessels or saucers used for table service
    • A47G19/2205Drinking glasses or vessels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • B23K35/0244Powders, particles or spheres; Preforms made therefrom

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)

Abstract

The invention relates to a solder and a heat-insulating container welded by the solder. The solder comprises, by weight, 40-80% of silver, 10-30% of copper and 5-30% of titanium. The heat preservation container comprises a titanium material inner container and a stainless steel shell; a welding cavity is reserved between the inner container and the shell after assembly, the welding flux is used for vacuum brazing welding, and the inner container and the shell are connected after welding. The titanium inner container and the stainless steel shell of the heat-insulating container can be welded and connected, the welding part has high tensile strength and good compactness, the quality of the heat-insulating container is ensured, and the service life of the heat-insulating container is prolonged.

Description

Solder and heat-insulating container welded by same
Technical Field
The invention relates to a heat-insulating container and a processing technology thereof, in particular to a solder and a heat-insulating container welded by the solder.
Background
At present, many people can fill water in a thermos cup and also can fill acidic drinks such as fruit juice, fruit tea, fruit powder granules, carbonated beverages and the like. The main material of the existing heat preservation container (especially the vacuum cup) is stainless steel, namely, the inner container and the outer shell of the vacuum cup are both made of stainless steel. The stainless steel has a high melting point and does not release undesirable substances due to high-temperature melting. However, stainless steel is most afraid of strong acid, and if drinks with strong acid are loaded for a long time, the inner container of the stainless steel is likely to be damaged. The damaged inner container of the stainless steel vacuum cup can cause the chromium, nickel and manganese elements contained in the stainless steel to migrate rapidly, and more heavy metals are likely to migrate in a short time. Moreover, the migration is often unrecognizable to the naked eye, which brings hidden dangers to the health of the user. Some people also like to soak the traditional Chinese medicine in a vacuum cup, so that the traditional Chinese medicine is convenient to carry and drink. However, a large amount of acidic substances are dissolved in the decocted traditional Chinese medicine, and the acidic substances are easy to react with chemical substances contained in the inner wall of the vacuum cup and are dissolved in the decoction, so that adverse effects are generated on the human body. The titanium vacuum cup has the advantages that strong acid and strong alkali resistance is not needed, the titanium vacuum cup is in contact with the traditional Chinese medicine, any chemical reaction is not generated, and the safety and the convenient carrying of the traditional Chinese medicine can be realized. No matter what the cup is, the cup can be filled with coffee, fruit juice, fruit tea, fruit powder granules, carbonated beverage and milk, no heavy metal is separated out, and the cup is not limited to what the cup wants to drink, and even people with metal allergy can use the cup without worry. Secondly, the method comprises the following steps: titanium is beneficial to the human body, and this light metal has the ability to regulate the body's natural electrical current through cell ionization. Titanium has special current characteristics, has beneficial physiological effect on human body, is chemically stable, cannot change or deteriorate with time, and is beneficial to physical and psychological health of human body. Therefore, the titanium product can achieve the effects of relaxing spirit, relaxing muscles and improving motor function. Thirdly, the method comprises the following steps: titanium oxide is an inorganic compound of titanium and oxygen and is generally used as food additives, paint, cosmetic additives and the like. Titanium oxide is classified into rutile type and anatase type according to its crystal structure. Among them, anatase type has a bactericidal effect. The titanium oxide thin film oxidized at the positive electrode has a temperature characteristic in the chemical synthesis treatment, and this characteristic causes the titanium oxide thin film to be anatase crystals and formed on the surface of titanium. The titanium surface is an oxide film, so that the iron rust taste of metal products is not felt, the peculiar smell of the beverage is not generated, and the taste can be fresh and cool. The mechanism of the photo-antibacterial action is that after the titanium oxide receives light, positive holes and negative electrons on the surface of the titanium oxide are released. This energy dissolves with oxygen contained in water to form active oxygen, and hydrogen and oxygen are produced by decomposing water. In this process, the beverage is further mellow in taste because the organic substances are sterilized and decomposed by the action of hydrogen and active oxygen, and also the foreign germs, sour taste, and the like are decomposed. Fourthly: titanium is known as biological metal, widely used for medical appliances and human body implantation, is a universally recognized healthy and nontoxic element in the world, has no influence on the vegetative nerve and gustatory nerve of people, and is resistant to strong acid and strong alkali. Therefore, the titanium vacuum cup is slightly expensive, but has obvious benefits for human bodies.
In order to solve the problems, the Chinese patent application publication (publication number: CN 110432727A) discloses a vacuum cup with outer steel and inner titanium and a vacuumizing process. It comprises the following steps: manufacturing a double-layer inner container, a titanium alloy inner container layer and a stainless steel inner container layer. Manufacturing a shell, comprising the following steps: a stainless steel layer: stainless steel pipe material, cutting pipe, water expanding, forming, rolling thread after products are complete, and forming the outer shell; and (5) stamping the outsole to form and vacuumizing holes. Manufacturing a finished cup body, comprising the following steps: the inner container shell is matched with a buckle for welding, and the outer bottom is welded (the upper air suction sheet is welded); placing glass cement after welding; the glass cement is heated and melted by vacuum equipment to reach a high vacuum state after being cooled. The vacuum interlayer sealing performance of the vacuum cup is greatly improved and the service life of the vacuum cup is prolonged by adopting the double-layer inner titanium alloy as the inner container, the stainless steel of the outermost shell, the 3-layer process and the hollow position vacuum layer in the inner container and the shell.
However, at present, the titanium material and the stainless steel have poor welding fastness, even the titanium material and the stainless steel cannot be welded together by adopting a common welding mode, and the quality of the heat preservation container of the titanium inner container and the stainless steel shell is poor.
Disclosure of Invention
The invention aims to provide a solder and a heat preservation container welded by the solder, which mainly solve the problems in the prior art, can realize the welding connection between a titanium inner container and a stainless steel shell of the heat preservation container, has high tensile strength and good compactness of the welding part, ensures the quality of the heat preservation container and prolongs the service life of the heat preservation container.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a solder for effecting a vacuum brazing weld between titanium and stainless steel, characterized by: the solder comprises, by weight, 40-80% of silver, 10-30% of copper and 5-30% of titanium.
The solder is characterized in that: the silver, the copper and the titanium are ground into powder according to the proportion, and the fineness of the powder is 300-800 meshes.
A heat-insulating container comprises a titanium material inner container and a stainless steel shell; the method is characterized in that: a welding cavity is reserved between the inner container and the shell after assembly, the welding flux is used for vacuum brazing welding, and the inner container and the shell are connected after welding.
The heat preservation container is characterized in that: the temperature of the vacuum brazing is 750-890 ℃.
The heat preservation container is characterized in that: the width of the welding cavity is 0.1-3.0 mm.
The heat preservation container is characterized in that: the vacuum brazing part adopts overlap welding or edge rolling welding.
The heat preservation container is characterized in that: the heat preservation time of the vacuum brazing is 50-70 min.
By the technical scheme, the invention has the advantages that:
the invention can realize the effective connection between the titanium inner container and the stainless steel shell of the heat-insulating container through the solder, the surface of the welding line close to the stainless steel forms nickel-silver-copper alloy (nickel comes from the stainless steel) through the solder, and the tensile strength of the side reaches about 50MPa-110 MPa. One side of the welding line close to the titanium liner is formed with a diffusion layer alloy of TiCu and TiCu2 through welding materials, and the tensile strength of the side reaches about 50MPa-110 MPa. The lowest mid-hardness of the weld is due to the strength of the solder not forming an alloy.
Drawings
FIG. 1 is a schematic view of the structure of the insulated container of the present invention.
FIG. 2 is a schematic view of the structure of a vacuum brazing portion of the heat insulating container of the present invention 1.
FIG. 3 is a schematic view of the structure of the vacuum brazing portion of the heat insulating container of the present invention 2.
FIG. 4 is another schematic view of the vacuum brazing site of the thermal container of the present invention.
FIG. 5 is a schematic view showing still another structure of the vacuum brazing portion of the heat insulating container of the present invention.
Detailed Description
The following detailed description and technical contents of the present invention are described with reference to the drawings, which are provided for reference and illustration purposes only and are not intended to limit the present invention.
Referring to fig. 1-3, the present invention discloses a thermal container. As shown in the figure: the titanium-based stainless steel water heater comprises a titanium material inner container 1 and a stainless steel shell 2; a welding containing cavity 3 is reserved between the inner container and the shell after assembly, vacuum brazing welding is carried out between the welding containing cavities 3 through a welding flux 4, and the inner container and the shell are connected after welding.
The invention provides a solder 4 which is beneficial to vacuum fiber welding between a titanium inner container 1 and a stainless steel shell 2. The solder comprises, by weight, 40-80% of silver, 10-30% of copper and 5-30% of titanium. During preparation, the silver, the copper and the titanium are ground into powder according to the proportion, the fineness of the powder is 300-800 meshes, and the powder is mixed to form the solder.
During welding, as shown in fig. 2 and 3, the width of a welding cavity reserved at the cup mouth is 0.1-3.0mm, and then the welding flux is adopted to carry out vacuum brazing by adopting the common vacuum brazing process steps. The temperature of the vacuum brazing is 750-890 ℃, the vacuum brazing part adopts overlap welding or edge rolling welding, and the heat preservation time of the vacuum brazing is 50-70 min.
Referring to fig. 3, 4 and 5, there are three structural schematic diagrams of the welding chambers that can be used in the present invention.
Example 1
A vacuum cup is provided with a titanium inner container and an SUS304 stainless steel shell, wherein a welding cavity is reserved between the inner container and the shell after assembly, the width of the welding cavity is 0.1mm, and vacuum brazing is carried out through welding flux. The solder is prepared by mixing 40% of 300-mesh silver powder, 30% of 800-mesh copper powder and 30% of 500-mesh titanium powder in percentage by weight.
The temperature of the vacuum brazing is 750 ℃, a lap welding structure (the inner container and the shell are jointed and welded together at the mouth part) is adopted, and the heat preservation time of the vacuum brazing is 50 min.
Example 2
A vacuum cup is provided with a titanium inner container and an SUS305 stainless steel shell, wherein a welding cavity is reserved between the inner container and the shell after assembly, the width of the welding cavity is 0.5mm, and vacuum brazing is carried out through welding flux. The solder is prepared by mixing 80% of silver powder of 800 meshes, 15% of copper powder of 800 meshes and 5% of titanium powder of 800 meshes according to weight percentage.
The temperature of the vacuum brazing is 890 ℃, a hemming structure (one opening of the inner container or the outer shell is welded after hemming and then matched with the opening) is adopted, and the heat preservation time of the vacuum brazing is 70 min.
Example 3
The inner container of the heat-insulating container is formed by compounding and connecting a titanium material and a SUS309 stainless steel material in a vacuum brazing mode, wherein the titanium material is arranged close to the inside and the stainless steel material is arranged close to the outside, and an unmodified or plastic shell can be arranged outside the compound inner container. The welding cavity (welding line) of the welding part of the composite liner is 3.0 mm. The solder is prepared by mixing 60 percent of 300-mesh silver powder, 10 percent of 300-mesh copper powder and 30 percent of 300-mesh titanium powder according to weight percentage.
The temperature of the vacuum brazing is 800 ℃, and the heat preservation time of the vacuum brazing is 70 min.
The above description is only a preferred embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent structural changes made by using the contents of the present specification and drawings are included in the scope of the present invention, and it is obvious that the present invention is also included in the claims.

Claims (7)

1. A solder for effecting a vacuum brazing weld between titanium and stainless steel, characterized by: the solder comprises, by weight, 40-80% of silver, 10-30% of copper and 5-30% of titanium.
2. The solder according to claim 1, wherein: the silver, the copper and the titanium are ground into powder according to the proportion, and the fineness of the powder is 300-800 meshes.
3. A heat-insulating container comprises a titanium material inner container and a stainless steel shell; the method is characterized in that: a welding cavity is reserved between the inner container and the shell after assembly, the welding flux of claim 1 or 2 is used for vacuum brazing welding, and the inner container and the shell are connected after welding.
4. The thermal container according to claim 3, characterized in that: the temperature of the vacuum brazing is 750-890 ℃.
5. The thermal container according to claim 3, characterized in that: the width of the welding cavity is 0.1-3.0 mm.
6. The thermal container according to claim 3, characterized in that: the vacuum brazing part adopts overlap welding or edge rolling welding.
7. The thermal container according to claim 4, characterized in that: the heat preservation time of the vacuum brazing is 50-70 min.
CN202010439595.6A 2020-05-22 2020-05-22 Solder and heat-insulating container welded by same Pending CN111545949A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010439595.6A CN111545949A (en) 2020-05-22 2020-05-22 Solder and heat-insulating container welded by same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010439595.6A CN111545949A (en) 2020-05-22 2020-05-22 Solder and heat-insulating container welded by same

Publications (1)

Publication Number Publication Date
CN111545949A true CN111545949A (en) 2020-08-18

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CN202010439595.6A Pending CN111545949A (en) 2020-05-22 2020-05-22 Solder and heat-insulating container welded by same

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101284336A (en) * 2008-05-30 2008-10-15 中国航空工业第一集团公司北京航空材料研究院 Argon arc welding-brazing hybrid welding method for connecting titanium alloy and steel
CN101298108A (en) * 2008-05-30 2008-11-05 中国航空工业第一集团公司北京航空材料研究院 Technique for vacuum brazing titanium alloy and steel
CN101362253A (en) * 2008-09-12 2009-02-11 北京工业大学 Joining method of TiNi shape memory alloy and stainless steel by instantaneous liquid phase diffusion welding
CN101695785A (en) * 2009-09-29 2010-04-21 陈亚 Vacuum welding method for titanium alloy and stainless steel
CN203124987U (en) * 2012-11-09 2013-08-14 航天材料及工艺研究所 Dissimilar metal welding structure of titanium alloy flange and stainless steel pipeline
CN107344655A (en) * 2017-07-31 2017-11-14 白明军 A kind of vacuum utensil structure of the outer steel of interior titanium
CN209437033U (en) * 2018-10-26 2019-09-27 浙江飞剑科技有限公司 A kind of vacuum heat-preserving titanium cup

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101284336A (en) * 2008-05-30 2008-10-15 中国航空工业第一集团公司北京航空材料研究院 Argon arc welding-brazing hybrid welding method for connecting titanium alloy and steel
CN101298108A (en) * 2008-05-30 2008-11-05 中国航空工业第一集团公司北京航空材料研究院 Technique for vacuum brazing titanium alloy and steel
CN101362253A (en) * 2008-09-12 2009-02-11 北京工业大学 Joining method of TiNi shape memory alloy and stainless steel by instantaneous liquid phase diffusion welding
CN101695785A (en) * 2009-09-29 2010-04-21 陈亚 Vacuum welding method for titanium alloy and stainless steel
CN203124987U (en) * 2012-11-09 2013-08-14 航天材料及工艺研究所 Dissimilar metal welding structure of titanium alloy flange and stainless steel pipeline
CN107344655A (en) * 2017-07-31 2017-11-14 白明军 A kind of vacuum utensil structure of the outer steel of interior titanium
CN209437033U (en) * 2018-10-26 2019-09-27 浙江飞剑科技有限公司 A kind of vacuum heat-preserving titanium cup

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Application publication date: 20200818

RJ01 Rejection of invention patent application after publication