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CN111500915A - Cutter material and preparation method thereof - Google Patents

Cutter material and preparation method thereof Download PDF

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Publication number
CN111500915A
CN111500915A CN202010374504.5A CN202010374504A CN111500915A CN 111500915 A CN111500915 A CN 111500915A CN 202010374504 A CN202010374504 A CN 202010374504A CN 111500915 A CN111500915 A CN 111500915A
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powder
carbide
tungsten
tool
tool material
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李云卿
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Jiangxi Zhongfu Cemented Carbide Co ltd
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Jiangxi Zhongfu Cemented Carbide Co ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/05Mixtures of metal powder with non-metallic powder
    • C22C1/051Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F2005/001Cutting tools, earth boring or grinding tool other than table ware

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)

Abstract

本发明涉及一种刀具材料及其制备方法,刀具材料包括如下重量百分比原料:50‑60%的碳化钨粉、10‑20%的钴粉、20‑30%的碳化物固溶体和2‑8%的碳化铌。方法包括:先按如下重量百分比称取各组分:55%的碳化钨粉、15%的钴粉、25%的碳化物固溶体、5%的碳化铌以及预设量的钨粉;加入酒精进行湿磨;过筛沉淀;干燥去酒精;再过筛;加入成型剂制粒;再过筛成型;压坯;烧结;最后进行机械加工。将刀具材料制成刀具后,在铣削加工极为粗糙的钢铁及合金材料的管道时,具有优良的铣削加工性能。并且,进给量较大,切削深度较大。相比传统的刀具材料制成的刀具,抗冲击、抗热震和抗边缘磨损的能力更强,切削的效果也更佳,大大提高了刀具的使用寿命以及切削效率。

Figure 202010374504

The invention relates to a cutting tool material and a preparation method thereof. The cutting tool material comprises the following raw materials by weight: 50-60% tungsten carbide powder, 10-20% cobalt powder, 20-30% carbide solid solution and 2-8% of niobium carbide. The method includes: firstly weighing each component according to the following weight percentages: 55% of tungsten carbide powder, 15% of cobalt powder, 25% of carbide solid solution, 5% of niobium carbide and preset amount of tungsten powder; adding alcohol to carry out Wet grinding; sieving and precipitation; drying to remove alcohol; sieving again; adding molding agent to granulate; sieving and molding again; compacting; sintering; After the tool material is made into a tool, it has excellent milling performance when milling extremely rough steel and alloy pipes. In addition, the feed rate is large, and the cutting depth is large. Compared with tools made of traditional tool materials, it has stronger impact resistance, thermal shock resistance and edge wear resistance, and better cutting effect, which greatly improves the service life of the tool and the cutting efficiency.

Figure 202010374504

Description

刀具材料及其制备方法Tool material and preparation method thereof

技术领域technical field

本发明涉及粉末冶金技术领域,具体涉及一种刀具材料及其制备方法。The invention relates to the technical field of powder metallurgy, in particular to a cutting tool material and a preparation method thereof.

背景技术Background technique

粉末冶金是制取金属粉末或用金属粉末作为原料,经过成形和烧结,制取金属材料、复合材料以及各种类型制品的工业技术。当下,粉末冶金技术已被广泛应用于交通、机械、电子、航空航天、武器、新能源、信息和核工业等领域。粉末冶金技术因其具备显著的节能、省材、产品性能优越、产品精度高且稳定性好等一系列优点,十分适合于大批量生产制造。另外,用铸造方法和机械加工方法无法直接制备的材料或复杂零件也可用粉末冶金技术制造。Powder metallurgy is an industrial technology for preparing metal powder or using metal powder as raw material, after forming and sintering, to prepare metal materials, composite materials and various types of products. At present, powder metallurgy technology has been widely used in transportation, machinery, electronics, aerospace, weapons, new energy, information and nuclear industries. Powder metallurgy technology is very suitable for mass production because of its significant energy saving, material saving, superior product performance, high product precision and good stability. In addition, materials or complex parts that cannot be directly prepared by casting methods and machining methods can also be manufactured by powder metallurgy technology.

高速钢和硬质合金是当前机械切削高速刀具中应用比较广泛的两种材料,据不完全统计,硬质合金刀具已占世界刀具消费总额的55%。硬质合金具有很高的硬度、强度、耐磨性和耐腐蚀性,被誉为“工业牙齿”。High-speed steel and cemented carbide are the two most widely used materials in the current mechanical cutting high-speed tools. According to incomplete statistics, cemented carbide tools have accounted for 55% of the world's total tool consumption. Cemented carbide has high hardness, strength, wear resistance and corrosion resistance, and is known as "industrial teeth".

目前,在对极为粗糙的钢铁及合金材料管道切削时,切削效率较慢。At present, when cutting extremely rough steel and alloy pipes, the cutting efficiency is relatively slow.

发明内容SUMMARY OF THE INVENTION

为解决在对极为粗糙的钢铁及合金材料管道切削时,切削效率较慢的问题,本发明提供一种刀具材料及其制备方法。In order to solve the problem of slow cutting efficiency when cutting extremely rough steel and alloy pipes, the present invention provides a cutting tool material and a preparation method thereof.

为实现本发明目的提供的一种刀具材料,包括如下重量百分比原料:50-60%的碳化钨粉、10-20%的钴粉、20-30%的碳化物固溶体和2-8%的碳化铌。A tool material provided for the purpose of the present invention comprises the following raw materials by weight: 50-60% of tungsten carbide powder, 10-20% of cobalt powder, 20-30% of carbide solid solution and 2-8% of carbide niobium.

在其中一个具体实施例中,刀具材料还包括预设量的钨粉,以将碳化钨粉中碳的质量百分比调至5.9%±0.02%。In one specific embodiment, the tool material further includes a preset amount of tungsten powder, so as to adjust the mass percentage of carbon in the tungsten carbide powder to 5.9%±0.02%.

在其中一个具体实施例中,碳化物固溶体包括如下重量百分比原料:5.75%的钽和7.35%的钛,其余为钨粉和碳。In one specific embodiment, the carbide solid solution includes the following raw materials by weight: 5.75% tantalum and 7.35% titanium, and the balance is tungsten powder and carbon.

在其中一个具体实施例中,碳化钨和钨粉的粒度均为3-4微米;钴粉的粒度为1-2微米。In one specific embodiment, the particle size of the tungsten carbide and the tungsten powder are both 3-4 microns; the particle size of the cobalt powder is 1-2 microns.

本发明还提供了一种刀具材料的制备方法,包括以下操作步骤:The present invention also provides a preparation method of cutting tool material, comprising the following operation steps:

先按如下重量百分比称取各组分:55%的碳化钨粉、15%的钴粉、25%的碳化物固溶体、5%的碳化铌以及预设量的钨粉;加入酒精进行湿磨;过筛沉淀;干燥去酒精;再过筛;加入成型剂制粒;再过筛成型;压坯;烧结;最后进行机械加工。First weigh each component according to the following weight percentages: 55% tungsten carbide powder, 15% cobalt powder, 25% carbide solid solution, 5% niobium carbide and a preset amount of tungsten powder; add alcohol for wet grinding; Precipitation by sieving; drying to remove alcohol; sieving again; adding molding agent for granulation; sieving and molding again; compacting; sintering;

在其中一个具体实施例中,在进行机械加工之后,对刀具材料进行涂层处理。In one embodiment, the tool material is coated after machining.

本发明的有益效果为:本发明提出的一种刀具材料,将刀具材料制成刀具后,在铣削加工极为粗糙的钢铁及合金材料的管道时,具有优良的加工性能。并且,进给量较大,切削深度较大。相比传统的刀具材料制成的刀具,抗冲击、抗热震和抗边缘磨损的能力更强,切削的效果也更佳,大大提高了刀具的使用寿命以及切削效率。The beneficial effects of the present invention are as follows: the tool material proposed by the present invention has excellent machining performance when milling extremely rough steel and alloy pipes after the tool material is made into a tool. In addition, the feed rate is large, and the cutting depth is large. Compared with tools made of traditional tool materials, it has stronger impact resistance, thermal shock resistance and edge wear resistance, and the cutting effect is also better, which greatly improves the service life of the tool and the cutting efficiency.

附图说明Description of drawings

为了更清楚地说明本发明具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述中所需要使用的附图作简单地介绍。在所有附图中,类似的元件或部分一般由类似的附图标记标识。附图中,各元件或部分并不一定按照实际的比例绘制。In order to illustrate the specific embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that are required to be used in the description of the specific embodiments or the prior art. Similar elements or parts are generally identified by similar reference numerals throughout the drawings. In the drawings, each element or section is not necessarily drawn to actual scale.

图1是本发明一种刀具材料的制备方法一具体实施例的工艺流程图。FIG. 1 is a process flow diagram of a specific embodiment of a method for preparing a tool material of the present invention.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments.

所述实施例的示例在附图中示出,其中自始至终相同或类似的符号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,旨在用于解释本发明,而不能理解为对本发明的限制。Examples of such embodiments are illustrated in the accompanying drawings, wherein the same or similar symbols refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary, and are intended to explain the present invention and should not be construed as limiting the present invention.

本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明或简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "upper", "lower", "front", "rear", "left" ", "right", "vertical", "horizontal", "top", "bottom", "in", "outer", "clockwise", "counterclockwise", "axial", "radial" The orientation or positional relationship indicated by , "circumferential direction", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention or simplifying the description, rather than indicating or implying that the indicated device or element must have a specific Orientation, construction and operation in a particular orientation, and therefore should not be construed as limiting the invention.

此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。In addition, the terms "first" and "second" are only used for descriptive purposes, and should not be construed as indicating or implying relative importance or implying the number of indicated technical features. Thus, a feature defined as "first" or "second" may expressly or implicitly include one or more of that feature. In the description of the present invention, "plurality" means two or more, unless otherwise expressly and specifically defined.

在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”、“衔接”、“铰接”等术语应做广义理解,例如可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接连接,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise expressly specified and limited, the terms "installation", "connection", "connection", "fixation", "joint", "hinging" and other terms should be understood in a broad sense, for example, it may be a fixed connection , it can be detachable connection, or integrated; it can be mechanical connection or electrical connection; it can be direct connection or indirect connection through an intermediate medium, it can be the internal connection of two elements or the mutual connection of two elements role relationship. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood according to specific situations.

刀具材料包括包括如下重量百分比原料:50-60%的碳化钨粉、10-20%的钴粉、20-30%的碳化物固溶体和2-8%的碳化铌。将刀具材料制成刀具后,在铣削加工极为粗糙的钢铁及合金材料的管道时,具有优良的铣削加工性能。并且,进给量较大,切削深度较大。相比传统的刀具材料制成的刀具,抗冲击、抗热震和抗边缘磨损的能力更强,切削的效果也更佳,大大提高了刀具的使用寿命以及切削效率。刀具材料还包括预设量的钨粉,以将碳化钨粉中碳的质量百分比调至5.9%±0.02%。其中,碳化物固溶体包括如下重量百分比原料:5.75%的钽和7.35%的钛,其余为钨粉和碳。碳化钨和钨粉的粒度均为3-4微米,钴粉的粒度为1-2微米。由刀具材料制得的刀具孔隙度≤A02/B02/C00,密度为11.5-12g/m3,硬度(HRA)为89.5-90.5,抗弯强度为1900-2000N/mm2The tool material includes the following raw materials by weight: 50-60% tungsten carbide powder, 10-20% cobalt powder, 20-30% carbide solid solution and 2-8% niobium carbide. After the tool material is made into a tool, it has excellent milling performance when milling extremely rough steel and alloy pipes. In addition, the feed rate is large, and the cutting depth is large. Compared with tools made of traditional tool materials, it has stronger impact resistance, thermal shock resistance and edge wear resistance, and better cutting effect, which greatly improves the service life of the tool and the cutting efficiency. The tool material also includes a preset amount of tungsten powder to adjust the mass percentage of carbon in the tungsten carbide powder to 5.9%±0.02%. Wherein, the carbide solid solution includes the following raw materials by weight: 5.75% tantalum and 7.35% titanium, and the rest are tungsten powder and carbon. The particle size of tungsten carbide and tungsten powder is 3-4 microns, and the particle size of cobalt powder is 1-2 microns. The porosity of the tool made from the tool material is ≤A02/B02/C00, the density is 11.5-12 g/m 3 , the hardness (HRA) is 89.5-90.5, and the bending strength is 1900-2000 N/mm 2 .

参照图1,本发明还提供一种刀具材料的制备方法,包括以下操作步骤:1, the present invention also provides a method for preparing a cutting tool material, comprising the following steps:

先按如下重量百分比称取各组分:55%的碳化钨粉、15%的钴粉、25%的碳化物固溶体、5%的碳化铌以及预设量的钨粉,然后,加入酒精进行湿磨。之后,过筛沉淀,再干燥去酒精,再过筛。然后,对Co、C、Ta和Ni等元素进行检验。检验合格后,加入成型剂制粒。再过筛成型,压坯。对压坯进行形状、密度和单个刀具质量等进行检验和鉴定。检验合格后,进行装舟进炉,再将成型剂排除完毕后,进行烧结,最后进行机械加工。在进行机械加工之后,对刀具材料进行涂层处理。在烧结之后,进行刀具的表面处理。使用刀具材料经刀具材料的制备方法制成的刀具,在对石油管道进行扒皮或打毛刺时,切削效率更高,使用寿命能够提高10-15倍。并且,切削后的粗糙度更为光亮,有效地节省了修刀时间,提高了生产效率,改善加工质量。First weigh the components according to the following weight percentages: 55% tungsten carbide powder, 15% cobalt powder, 25% carbide solid solution, 5% niobium carbide and a preset amount of tungsten powder, then add alcohol to wet grind. After that, the precipitate is sieved, dried to remove alcohol, and sieved again. Then, elements such as Co, C, Ta, and Ni are examined. After passing the inspection, add the molding agent for granulation. Then sieve to form, compact. The compacts are inspected and qualified for shape, density and individual tool quality. After passing the inspection, it is loaded into a boat into the furnace, and after the molding agent is removed, it is sintered and finally machined. After machining, the tool material is coated. After sintering, the surface treatment of the tool is carried out. The tool made of the tool material by the tool material preparation method has higher cutting efficiency when peeling or burring the oil pipeline, and the service life can be increased by 10-15 times. In addition, the roughness after cutting is brighter, which effectively saves tool repair time, improves production efficiency, and improves processing quality.

最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围,其均应涵盖在本发明的权利要求和说明书的范围当中。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, but not to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions described in the foregoing embodiments can still be modified, or some or all of the technical features thereof can be equivalently replaced; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the embodiments of the present invention. The scope of the invention should be included in the scope of the claims and description of the present invention.

Claims (6)

1. The cutter material is characterized by comprising the following raw materials in percentage by weight: 50-60% of tungsten carbide powder, 10-20% of cobalt powder, 20-30% of carbide solid solution and 2-8% of niobium carbide.
2. The tool material according to claim 1, further comprising a predetermined amount of tungsten powder to adjust the mass percentage of carbon in the tungsten carbide powder to 5.9% ± 0.02%.
3. The tool material of claim 2 wherein the carbide solid solution comprises, in weight percent, 5.75% tantalum and 7.35% titanium, with the balance being the tungsten powder and the carbon.
4. The tool material of claim 2, wherein the tungsten carbide and the tungsten powder each have a particle size of 3 to 4 microns; the particle size of the cobalt powder is 1-2 microns.
5. The preparation method of the cutter material is characterized by comprising the following operation steps of:
firstly, weighing the following components in percentage by weight: 55% of tungsten carbide powder, 15% of cobalt powder, 25% of carbide solid solution, 5% of niobium carbide and a preset amount of tungsten powder; adding alcohol for wet grinding; sieving and precipitating; drying to remove alcohol; sieving again; adding a forming agent for granulation; sieving and forming; pressing into a blank; sintering; and finally, machining.
6. The method of manufacturing a tool material according to claim 5, wherein the tool material is subjected to a coating treatment after the machining.
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WO1998003691A1 (en) * 1996-07-19 1998-01-29 Sandvik Ab (Publ) Cemented carbide insert for turning, milling and drilling
CN106929734A (en) * 2015-12-30 2017-07-07 成都工具研究所有限公司 For aperture knife tool guide pad Hardmetal materials and preparation method thereof
CN108950341A (en) * 2018-07-04 2018-12-07 株洲锐利工具有限公司 hard alloy and preparation method
CN109763054A (en) * 2019-03-21 2019-05-17 陕西理工大学 A kind of multi-component hybrid carbide cemented carbide and its preparation method and application

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998003691A1 (en) * 1996-07-19 1998-01-29 Sandvik Ab (Publ) Cemented carbide insert for turning, milling and drilling
CN106929734A (en) * 2015-12-30 2017-07-07 成都工具研究所有限公司 For aperture knife tool guide pad Hardmetal materials and preparation method thereof
CN108950341A (en) * 2018-07-04 2018-12-07 株洲锐利工具有限公司 hard alloy and preparation method
CN109763054A (en) * 2019-03-21 2019-05-17 陕西理工大学 A kind of multi-component hybrid carbide cemented carbide and its preparation method and application

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