CN111326516A - Non-volatile memory structure and manufacturing method thereof - Google Patents
Non-volatile memory structure and manufacturing method thereof Download PDFInfo
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Abstract
本发明公开一种非挥发性存储器结构及其制造方法,其中该非挥发性存储器结构包括基底、选择栅极、第一电荷存储层、控制栅极与第一介电层。在基底中具有沿着第一方向延伸的沟槽。选择栅极设置在沟槽中。第一电荷存储层设置在沟槽的侧壁上。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。控制栅极设置在沟槽中的选择栅极与第一电荷存储层上。控制栅极覆盖第一侧面与第二侧面。第一介电层设置在控制栅极与第一电荷存储层之间。
The invention discloses a non-volatile memory structure and a manufacturing method thereof, wherein the non-volatile memory structure includes a substrate, a selection gate, a first charge storage layer, a control gate and a first dielectric layer. There is a groove extending in the base along the first direction. The select gate is disposed in the trench. The first charge storage layer is disposed on the sidewalls of the trench. The first charge storage layer has a first side and a second side opposite to each other. The first side and the second side are arranged in the first direction. The control gate is disposed on the selection gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. The first dielectric layer is disposed between the control gate and the first charge storage layer.
Description
技术领域technical field
本发明涉及一种存储器结构及其制造方法,且特别是涉及一种非挥发性存储器结构及其制造方法。The present invention relates to a memory structure and a method of fabricating the same, and more particularly, to a non-volatile memory structure and a method of fabricating the same.
背景技术Background technique
由于非挥发性存储器(non-volatile memory)可进行多次数据的存入、读取与抹除等操作,且具有当电源供应中断时,所存储的数据不会消失、数据存取时间短以及低消耗功率等优点,所以已成为个人计算机和电子设备所广泛采用的一种存储器。然而,如何能够进一步地提升存储器元件的电性效能(electrical performance)为目前业界持续努力的目标。Because non-volatile memory (non-volatile memory) can perform operations such as storing, reading and erasing data for many times, and when the power supply is interrupted, the stored data will not disappear, the data access time is short, and It has the advantages of low power consumption and so on, so it has become a kind of memory widely used in personal computers and electronic equipment. However, how to further improve the electrical performance of the memory device is a goal that the industry continues to strive for.
发明内容SUMMARY OF THE INVENTION
本发明提供一种非挥发性存储器结构及其制造方法,其可有效地提升存储器元件的电性效能。The present invention provides a non-volatile memory structure and a manufacturing method thereof, which can effectively improve the electrical performance of the memory element.
本发明提出一种非挥发性存储器结构,包括基底、选择栅极、第一电荷存储层、控制栅极与第一介电层。在基底中具有沿着第一方向延伸的沟槽。选择栅极设置在沟槽中。第一电荷存储层设置在沟槽的侧壁上。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。控制栅极设置在沟槽中的选择栅极与第一电荷存储层上。控制栅极覆盖第一侧面与第二侧面。第一介电层设置在控制栅极与第一电荷存储层之间。The present invention provides a non-volatile memory structure including a substrate, a selection gate, a first charge storage layer, a control gate and a first dielectric layer. There is a trench in the substrate extending along the first direction. The select gate is disposed in the trench. The first charge storage layer is disposed on the sidewalls of the trench. The first charge storage layer has a first side surface and a second side surface opposite to each other. The first side surface and the second side surface are arranged in the first direction. The control gate is disposed on the select gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. The first dielectric layer is disposed between the control gate and the first charge storage layer.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,选择栅极、第一电荷存储层、控制栅极与基底可彼此电性绝缘。According to an embodiment of the present invention, in the above non-volatile memory structure, the select gate, the first charge storage layer, the control gate and the substrate can be electrically insulated from each other.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层例如是浮置栅极。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer is, for example, a floating gate.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层还可具有连接在第一侧面与第二侧面之间的第三侧面。控制栅极可覆盖第三侧面。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer may further have a third side surface connected between the first side surface and the second side surface. The control gate may cover the third side.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第二电荷存储层。第二电荷存储层设置在沟槽的另一侧壁上。第二电荷存储层可具有彼此相对的第四侧面与第五侧面。第四侧面与第五侧面可在第一方向上排列。控制栅极可覆盖第四侧面与第五侧面。第一介电层设置在控制栅极与第二电荷存储层之间。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a second charge storage layer. The second charge storage layer is disposed on the other sidewall of the trench. The second charge storage layer may have fourth and fifth sides opposite to each other. The fourth side surface and the fifth side surface may be arranged in the first direction. The control gate may cover the fourth side and the fifth side. The first dielectric layer is disposed between the control gate and the second charge storage layer.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层与第二电荷存储层可在第二方向上排列。第二方向可相交于第一方向。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer and the second charge storage layer may be arranged in the second direction. The second direction may intersect the first direction.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,第二电荷存储层还可具有连接在第四侧面与第五侧面之间的第六侧面。控制栅极可覆盖第六侧面。According to an embodiment of the present invention, in the above non-volatile memory structure, the second charge storage layer may further have a sixth side surface connected between the fourth side surface and the fifth side surface. The control gate may cover the sixth side surface.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第一掺杂区与第二掺杂区。第一掺杂区位于沟槽下方的基底中。第二掺杂区位于沟槽的一侧的基底中。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a first doped region and a second doped region. The first doped region is located in the substrate below the trench. The second doped region is located in the substrate on one side of the trench.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第三掺杂区。第三掺杂区位于沟槽的另一侧的基底中。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a third doped region. The third doped region is located in the substrate on the other side of the trench.
依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第二介电层与第三介电层。第二介电层设置在选择栅极与基底之间。第三介电层设置在第一电荷存储层与基底之间。According to an embodiment of the present invention, the above non-volatile memory structure may further include a second dielectric layer and a third dielectric layer. The second dielectric layer is disposed between the select gate and the substrate. The third dielectric layer is disposed between the first charge storage layer and the substrate.
本发明提出一种非挥发性存储器结构的制造方法,包括以下步骤。在基底中形成沿着第一方向延伸的沟槽。在沟槽中形成选择栅极。在沟槽的侧壁上形成第一电荷存储层。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。在沟槽中的选择栅极与第一电荷存储层上形成控制栅极。控制栅极覆盖第一侧面与第二侧面。在控制栅极与第一电荷存储层之间形成第一介电层。The present invention provides a method for manufacturing a non-volatile memory structure, which includes the following steps. A trench extending along the first direction is formed in the substrate. A select gate is formed in the trench. A first charge storage layer is formed on the sidewalls of the trench. The first charge storage layer has a first side surface and a second side surface opposite to each other. The first side surface and the second side surface are arranged in the first direction. A control gate is formed on the select gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. A first dielectric layer is formed between the control gate and the first charge storage layer.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,选择栅极、第一电荷存储层、控制栅极与基底可彼此电性绝缘。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the select gate, the first charge storage layer, the control gate and the substrate can be electrically insulated from each other.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层还可具有连接在第一侧面与第二侧面之间的第三侧面。控制栅极可覆盖第三侧面。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the first charge storage layer may further have a third side surface connected between the first side surface and the second side surface. The control gate may cover the third side.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层与第一介电层的形成方法可包括以下步骤。在沟槽中共形地形成电荷存储材料层。对电荷存储材料层进行回蚀刻制作工艺,而在沟槽的侧壁上形成电荷存储间隙壁。对电荷存储间隙壁进行图案化制作工艺,而形成第一电荷存储层。在形成第一电荷存储层之后,形成覆盖第一电荷存储层的第一介电层。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method for forming the first charge storage layer and the first dielectric layer may include the following steps. A layer of charge storage material is formed conformally in the trench. An etch-back fabrication process is performed on the charge storage material layer to form charge storage spacers on the sidewalls of the trenches. A patterned fabrication process is performed on the charge storage spacers to form a first charge storage layer. After forming the first charge storage layer, a first dielectric layer overlying the first charge storage layer is formed.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括在沟槽的另一侧壁上形成第二电荷存储层。第二电荷存储层可具有彼此相对的第四侧面与第五侧面。第四侧面与第五侧面可在第一方向上排列。控制栅极可覆盖第四侧面与第五侧面。第一介电层设置在控制栅极与第二电荷存储层之间。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method may further include forming a second charge storage layer on the other sidewall of the trench. The second charge storage layer may have fourth and fifth sides opposite to each other. The fourth side surface and the fifth side surface may be arranged in the first direction. The control gate may cover the fourth side and the fifth side. The first dielectric layer is disposed between the control gate and the second charge storage layer.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层与第二电荷存储层可在第二方向上排列。第二方向可相交于第一方向。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the first charge storage layer and the second charge storage layer may be arranged in the second direction. The second direction may intersect the first direction.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第二电荷存储层还可具有连接在第四侧面与第五侧面之间的第六侧面。控制栅极可覆盖第六侧面。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the second charge storage layer may further have a sixth side surface connected between the fourth side surface and the fifth side surface. The control gate may cover the sixth side surface.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括以下步骤。在沟槽下方的基底中形成第一掺杂区。在沟槽的一侧的基底中形成第二掺杂区。According to an embodiment of the present invention, the method for fabricating the above non-volatile memory structure may further include the following steps. A first doped region is formed in the substrate below the trench. A second doped region is formed in the substrate on one side of the trench.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括在沟槽的另一侧的基底中形成第三掺杂区。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method may further include forming a third doped region in the substrate on the other side of the trench.
依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括以下步骤。可在选择栅极与基底之间形成第二介电层。可在第一电荷存储层与基底之间形成第三介电层。According to an embodiment of the present invention, the method for fabricating the above non-volatile memory structure may further include the following steps. A second dielectric layer may be formed between the select gate and the substrate. A third dielectric layer may be formed between the first charge storage layer and the substrate.
基于上述,在本发明所提出的非挥发性存储器结构及其制造方法中,控制栅极设置在第一电荷存储层上且覆盖第一电荷存储层的第一侧面与第二侧面,且第一介电层设置在控制栅极与第一电荷存储层之间。由此,控制栅极与第一电荷存储层还可在第一电荷存储层的第一侧面与第二侧面进行耦合,进而可增加控制栅极与第一电荷存储层的耦合区域。如此一来,本发明所提出的非挥发性存储器结构可具有较高的耦合率(couplingratio),因此可有效地提升存储器元件的电性效能。Based on the above, in the non-volatile memory structure and the manufacturing method thereof proposed by the present invention, the control gate is disposed on the first charge storage layer and covers the first side and the second side of the first charge storage layer, and the first A dielectric layer is disposed between the control gate and the first charge storage layer. Therefore, the control gate and the first charge storage layer can also be coupled at the first side and the second side of the first charge storage layer, thereby increasing the coupling area between the control gate and the first charge storage layer. In this way, the non-volatile memory structure proposed by the present invention can have a higher coupling ratio, and thus can effectively improve the electrical performance of the memory device.
为让本发明的上述特征和优点能更明显易懂,下文特举实施例,并配合所附的附图作详细说明如下。In order to make the above-mentioned features and advantages of the present invention more obvious and easy to understand, the following embodiments are given and described in detail with the accompanying drawings as follows.
附图说明Description of drawings
图1A至图1J为本发明一实施例的非挥发性存储器结构的制造流程上视图;1A to 1J are top views of a manufacturing process of a non-volatile memory structure according to an embodiment of the present invention;
图2A至图2J分别为沿图1A至图1J中的I-I’剖面线的剖视图;Figures 2A to 2J are cross-sectional views along the section line I-I' in Figures 1A to 1J, respectively;
图3A至图3J分别为沿图1A至图1J中的II-II’剖面线的剖视图。3A to 3J are cross-sectional views taken along the line II-II' in FIGS. 1A to 1J, respectively.
符号说明Symbol Description
10:非挥发性存储器结构10: Non-volatile memory structure
100:基底100: base
102:隔离结构102: Isolation Structure
104:图案化硬掩模层104: Patterning the hard mask layer
106:沟槽106: Groove
108、128、130:掺杂区108, 128, 130: doped regions
110、110a、114、124:介电层110, 110a, 114, 124: Dielectric layers
112:选择栅极材料层112: Select the gate material layer
112a:选择栅极112a: select gate
116:电荷存储材料层116: charge storage material layer
118、120:电荷存储间隙壁118, 120: Charge storage spacers
118a、120a:电荷存储层118a, 120a: charge storage layer
122:图案化光致抗蚀剂层122: Patterned Photoresist Layer
126:控制栅极材料层126: Control gate material layer
126a:控制栅极126a: Control Gate
AA:主动(有源)区AA: Active (active) area
D1:第一方向D1: first direction
D2:第二方向D2: second direction
S1~S6:侧面S1~S6: Side
TS1、TS2:顶面TS1, TS2: Top surface
具体实施方式Detailed ways
图1A至图1J为本发明一实施例的非挥发性存储器结构的制造流程上视图。图2A至图2J为沿图1A至图1J中的I-I’剖面线的剖视图。图3A至图3J为沿图1A至图1J中的II-II’剖面线的剖视图。1A to 1J are top views of a manufacturing process of a non-volatile memory structure according to an embodiment of the present invention. 2A to 2J are cross-sectional views along the line I-I' in FIGS. 1A to 1J . 3A to 3J are cross-sectional views along the line II-II' in FIGS. 1A to 1J .
请参照图1A、图2A与图3A,可在基底100中形成隔离结构102,且可通过隔离结构102在基底100中定义出主动区AA。基底100可为半导体基底,如硅基底。隔离结构102的材料例如是氧化硅。隔离结构102例如是浅沟槽隔离结构(shallow trench isolation,STI),但本发明并不以此为限。隔离结构102的形成方法例如是进行浅沟槽隔离制作工艺。此外,主动区AA可在第一方向D1上排列,且可在第二方向D2上延伸。第二方向D2可相交于第一方向D1。在本实施例中,以第二方向D2垂直于第一方向D1为例来进行说明,但本发明并不以此为限。Referring to FIG. 1A , FIG. 2A and FIG. 3A , an
请参照图1B、图2B与图3B,在基底100上形成图案化硬掩模层104。图案化硬掩模层104的材料例如是氮化硅。图案化硬掩模层104的形成方法例如是组合使用沉积制作工艺、光刻制作工艺与蚀刻制作工艺。Referring to FIG. 1B , FIG. 2B and FIG. 3B , a patterned
接着,可利用图案化硬掩模层104作为掩模,移除部分基底100与部分隔离结构102,而在基底100中形成沿着第一方向D1延伸的沟槽106。部分基底100与部分隔离结构102的移除方法例如是干式蚀刻法。Next, part of the
然后,可在沟槽106下方的基底100中形成掺杂区108。掺杂区108可作为源极线(source line)使用。在本实施例中,掺杂区108是以N型掺杂区为例来进行说明,但本发明并不以此为限。在另一实施例中,掺杂区108也可为P型掺杂区。掺杂区108的形成方法例如是离子注入法。Then, doped
请参照图1C、图2C与图3C,可在沟槽106的表面上形成介电层110。介电层110的材料例如是氧化硅。介电层110的形成方法例如是热氧化法。Referring to FIGS. 1C , 2C and 3C , a
接下来,可形成填入沟槽106的选择栅极材料层112。选择栅极材料层112的材料例如是掺杂多晶硅等导体材料。选择栅极材料层112的形成方法例如是化学气相沉积法。Next, a select
请参照图1D、图2D与图3D,可对选择栅极材料层112进行回蚀刻制作工艺,以移除沟槽106外部的选择栅极材料层112,而在沟槽106中形成选择栅极112a。Referring to FIG. 1D , FIG. 2D and FIG. 3D , an etch-back process may be performed on the select
然后,可移除硬掩模层104。硬掩模层104的移除方法例如是湿式蚀刻法。再者,可移除未被选择栅极112a所覆盖的部分介电层110,而在选择栅极112a与基底100之间形成介电层110a。介电层110a可作为栅介电层。由此,选择栅极112a与基底100可彼此电性绝缘。部分介电层110的移除方法例如是湿式蚀刻法。在本实施例中,先移除硬掩模层104,再移除部分介电层110,但本发明并不以此为限。在另一实施例中,也可先移除部分介电层110,再移除硬掩模层104。Then, the
请参照图1E、图2E与图3E,可在沟槽106的表面上形成介电层114。此外,介电层114更可形成在基底100的顶面上与选择栅极112a的顶面上。介电层114可作为隧穿介电层。介电层114的材料例如是氧化硅。介电层114的形成方法例如是热氧化法或化学气相沉积法。在本实施例中,介电层114的形成方法是以热氧化法为例来进行说明。Referring to FIG. 1E , FIG. 2E and FIG. 3E , a
接着,可在沟槽106中共形地形成电荷存储材料层116。电荷存储材料层116的材料可为浮置栅极材料,如掺杂多晶硅或未经掺杂的多晶硅。Next, the charge
请参照图1F、图2F与图3F,可对电荷存储材料层116进行回蚀刻制作工艺。由此,可在沟槽106一侧壁上形成电荷存储间隙壁118,且可在沟槽106的另一侧壁上形成电荷存储间隙壁120。Referring to FIG. 1F , FIG. 2F and FIG. 3F , an etch-back fabrication process may be performed on the charge
请参照图1G、图2G与图3G,可在介电层114与电荷存储材料层116上形成图案化光致抗蚀剂层122。图案化光致抗蚀剂层122可具有暴露出部分电荷存储材料层118与部分电荷存储材料层120的开口122a。图案化光致抗蚀剂层122的形成方法例如是进行光刻制作工艺。Referring to FIGS. 1G , 2G and 3G , a patterned
请参照图1H、图2H与图3H,可通过图案化光致抗蚀剂层122作为掩模,移除部分电荷存储间隙壁118与部分电荷存储间隙壁120。由此,可对电荷存储间隙壁118与电荷存储间隙壁120进行图案化制作工艺,而在沟槽106的侧壁上形成电荷存储层118a,且在沟槽106的另一侧壁上形成电荷存储层120a。电荷存储层118a与电荷存储层120a可在第二方向D2上排列。电荷存储层118a与电荷存储层120a例如是浮置栅极。Referring to FIGS. 1H , 2H and 3H, a portion of the
电荷存储层118a具有彼此相对的侧面S1与侧面S2。侧面S1与侧面S2在第一方向D1上排列。此外,电荷存储层118a还可具有顶面TS1与连接在侧面S1与侧面S2之间的侧面S3。介电层114可设置在电荷存储层118a与基底100之间以及电荷存储层118a与选择栅极112a之间。因此,电荷存储层118a与基底100可通过介电层114而彼此电性绝缘,且电荷存储层118a与选择栅极112a可通过介电层114而彼此电性绝缘。The
电荷存储层120a可具有彼此相对的侧面S4与侧面S5。侧面S4与侧面S5可在第一方向D1上排列。此外,电荷存储层120a还可具有顶面TS2与连接在侧面S4与侧面S5之间的侧面S6。介电层114可设置在电荷存储层120a与基底100之间以及电荷存储层120a与选择栅极112a之间。由此,电荷存储层120a与基底100可彼此电性绝缘,且电荷存储层120a与选择栅极112a可彼此电性绝缘。The
然后,可移除图案化光致抗蚀剂层122。图案化光致抗蚀剂层122的移除方法例如是干式去光致抗蚀剂法(dry stripping)或湿式去光致抗蚀剂法(wet stripping)。Then, the patterned
请参照图1I、图2I与图3I,在形成电荷存储层118a之后,可形成覆盖电荷存储层118a的介电层124。介电层124的材料例如是氧化硅、氮化硅或其组合。介电层124可为多层结构或单层结构。举例来说,介电层124可为氧化硅层/氮化硅层/氧化硅层(ONO)的复合层。介电层124的形成方法例如是化学气相沉积法。介电层124可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3,且可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。Referring to FIGS. 1I, 2I and 3I, after the
接下来,可在沟槽106中形成控制栅极材料层126。控制栅极材料层126的材料例如是掺杂多晶硅等导体材料。控制栅极材料层126的形成方法例如是化学气相沉积法。Next, a control
请参照图1J、图2J与图3J,可移除沟槽106外部的部分控制栅极材料层126,而在沟槽106中的选择栅极112a、电荷存储层118a与电荷存储层120a上形成控制栅极126a。部分控制栅极材料层126的移除方法例如是化学机械研磨法(chemical mechanical polishing,CMP)。控制栅极126a可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3,且可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。介电层124可设置在控制栅极126a与电荷存储层118a之间、控制栅极126a与电荷存储层120a之间、控制栅极126a与选择栅极112a之间以及控制栅极126a与基底100之间。因此,控制栅极126a至少可通过介电层124而与电荷存储层118a、电荷存储层120a、选择栅极112a以及基底100彼此电性绝缘。Referring to FIGS. 1J , 2J and 3J , a portion of the control
然后,可在沟槽106的一侧的基底100中形成掺杂区128,且可在沟槽106的另一侧的基底100中形成掺杂区130。掺杂区128与掺杂区130分别可作为源极或漏极。在本实施例中,掺杂区128与掺杂区130是以N型掺杂区为例来进行说明,但本发明并不以此为限。在另一实施例中,掺杂区128与掺杂区130也可为P型掺杂区。掺杂区128与掺杂区130的形成方法例如是离子注入法。Then, doped
以下,通过图1J、图2J与图3J来说明本实施例的非挥发性存储器结构10。此外,虽然非挥发性存储器结构10的形成方法是以上述方法为例进行说明,但本发明并不以此为限。Hereinafter, the
请参照图1J、图2J与图3J,非挥发性存储器结构10包括基底100、选择栅极112a、电荷存储层118a、控制栅极126a与介电层124。在基底100中具有沿着第一方向D1延伸的沟槽106。选择栅极112a设置在沟槽106中。电荷存储层118a设置在沟槽106的侧壁上,且位于选择栅极112a上。电荷存储层118a具有彼此相对的侧面S1与侧面S2。侧面S1与侧面S2在第一方向D1上排列。电荷存储层118a还可具有顶面TS1与连接在侧面S1与侧面S2之间的侧面S3。电荷存储层118a例如是浮置栅极。控制栅极126a设置在沟槽106中的选择栅极112a与电荷存储层118a上。控制栅极126a可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3。介电层124设置在控制栅极126a与电荷存储层118a之间。1J , FIG. 2J and FIG. 3J , the
此外,非挥发性存储器结构10还可包括隔离结构102、掺杂区108、介电层110a、介电层114、电荷存储层120a、掺杂区128与掺杂区130中的至少一者。选择栅极112a、电荷存储层118a、电荷存储层120a、控制栅极126a与基底100可通过介电层110a、介电层114与介电层124而彼此电性绝缘。隔离结构102设置在基底100中。掺杂区108位于沟槽106下方的基底100中。介电层110a设置在选择栅极112a与基底100之间。介电层114设置在电荷存储层118a与基底100之间,且可设置在电荷存储层120a与基底100之间。电荷存储层120a设置在沟槽106的另一侧壁上。电荷存储层118a与电荷存储层120a可在第二方向D2上排列。第二方向D2可相交于第一方向D1。电荷存储层120a可具有彼此相对的侧面S4与侧面S5。侧面S4与侧面S5可在第一方向D1上排列。电荷存储层120a还可具有顶面TS2与连接在侧面S4与侧面S5之间的侧面S6。电荷存储层120a例如是浮置栅极。控制栅极126a可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。介电层124可设置在控制栅极126a与电荷存储层120a之间。掺杂区128位于沟槽106的一侧的基底100中。掺杂区130位于沟槽106的另一侧的基底100中。In addition, the
此外,非挥发性存储器结构10的各构件的材料、设置方式、导电型态、形成方法与功效已于上述实施例进行详尽地说明,在此不再重复说明。In addition, the materials, arrangement methods, conductive types, forming methods and functions of the components of the
基于上述实施例可知,在非挥发性存储器结构10及其制造方法中,控制栅极126a设置在电荷存储层118a上且覆盖电荷存储层118a的侧面S1与侧面S2,且介电层124设置在控制栅极126a与电荷存储层118a之间。由此,控制栅极126a与电荷存储层118a更可在电荷存储层118a的侧面S1与侧面S2进行耦合,进而可增加控制栅极126a与电荷存储层118a的耦合区域。如此一来,非挥发性存储器结构10可具有较高的耦合率,因此可有效地提升存储器元件的电性效能。Based on the above embodiments, in the
在一些实施例中,非挥发性存储器结构10还可包括电荷存储层120a。控制栅极126a设置在电荷存储层120a上且覆盖电荷存储层120a的侧面S4与侧面S5,且介电层124设置在控制栅极126a与电荷存储层120a之间。由此,控制栅极126a与电荷存储层120a还可在电荷存储层120a的侧面S4与侧面S5进行耦合,进而可增加控制栅极126a与电荷存储层120a的耦合区域。如此一来,非挥发性存储器结构10可具有较高的耦合率,因此可有效地提升存储器元件的电性效能。In some embodiments, the
此外,由于非挥发性存储器结构10具有垂直通道与埋入式的选择栅极112a,因此可防止短通道效应(short channel effect)与过度抹除现象(over-erase phenomenon),且可具有较高的存储单元密度(cell density)。In addition, since the
综上所述,在上述实施例的非挥发性存储器结构及其制造方法中,由于控制栅极与电荷存储层可具有较大的耦合区域,因此可使得非挥发性存储器结构具有较高的耦合率,进而可具有较佳的电性效能。To sum up, in the non-volatile memory structure and the manufacturing method thereof of the above-mentioned embodiments, since the control gate and the charge storage layer can have a larger coupling area, the non-volatile memory structure can have a high coupling rate, and thus can have better electrical performance.
虽然结合以上实施例公开了本发明,然而其并非用以限定本发明,任何所属技术领域中具有通常知识者,在不脱离本发明的精神和范围内,可作些许的更动与润饰,故本发明的保护范围应当以附上的权利要求所界定的为准。Although the present invention is disclosed in conjunction with the above embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, The scope of protection of the present invention should be defined by the appended claims.
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