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CN111326516A - Non-volatile memory structure and manufacturing method thereof - Google Patents

Non-volatile memory structure and manufacturing method thereof Download PDF

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CN111326516A
CN111326516A CN201811632865.4A CN201811632865A CN111326516A CN 111326516 A CN111326516 A CN 111326516A CN 201811632865 A CN201811632865 A CN 201811632865A CN 111326516 A CN111326516 A CN 111326516A
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charge storage
storage layer
volatile memory
memory structure
layer
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CN111326516B (en
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张哲玮
王俊扬
廖宏魁
刘振强
施咏尧
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Powerchip Technology Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/30Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/68Floating-gate IGFETs
    • H10D30/6891Floating-gate IGFETs characterised by the shapes, relative sizes or dispositions of the floating gate electrode
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
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Abstract

本发明公开一种非挥发性存储器结构及其制造方法,其中该非挥发性存储器结构包括基底、选择栅极、第一电荷存储层、控制栅极与第一介电层。在基底中具有沿着第一方向延伸的沟槽。选择栅极设置在沟槽中。第一电荷存储层设置在沟槽的侧壁上。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。控制栅极设置在沟槽中的选择栅极与第一电荷存储层上。控制栅极覆盖第一侧面与第二侧面。第一介电层设置在控制栅极与第一电荷存储层之间。

Figure 201811632865

The invention discloses a non-volatile memory structure and a manufacturing method thereof, wherein the non-volatile memory structure includes a substrate, a selection gate, a first charge storage layer, a control gate and a first dielectric layer. There is a groove extending in the base along the first direction. The select gate is disposed in the trench. The first charge storage layer is disposed on the sidewalls of the trench. The first charge storage layer has a first side and a second side opposite to each other. The first side and the second side are arranged in the first direction. The control gate is disposed on the selection gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. The first dielectric layer is disposed between the control gate and the first charge storage layer.

Figure 201811632865

Description

非挥发性存储器结构及其制造方法Non-volatile memory structure and method of making the same

技术领域technical field

本发明涉及一种存储器结构及其制造方法,且特别是涉及一种非挥发性存储器结构及其制造方法。The present invention relates to a memory structure and a method of fabricating the same, and more particularly, to a non-volatile memory structure and a method of fabricating the same.

背景技术Background technique

由于非挥发性存储器(non-volatile memory)可进行多次数据的存入、读取与抹除等操作,且具有当电源供应中断时,所存储的数据不会消失、数据存取时间短以及低消耗功率等优点,所以已成为个人计算机和电子设备所广泛采用的一种存储器。然而,如何能够进一步地提升存储器元件的电性效能(electrical performance)为目前业界持续努力的目标。Because non-volatile memory (non-volatile memory) can perform operations such as storing, reading and erasing data for many times, and when the power supply is interrupted, the stored data will not disappear, the data access time is short, and It has the advantages of low power consumption and so on, so it has become a kind of memory widely used in personal computers and electronic equipment. However, how to further improve the electrical performance of the memory device is a goal that the industry continues to strive for.

发明内容SUMMARY OF THE INVENTION

本发明提供一种非挥发性存储器结构及其制造方法,其可有效地提升存储器元件的电性效能。The present invention provides a non-volatile memory structure and a manufacturing method thereof, which can effectively improve the electrical performance of the memory element.

本发明提出一种非挥发性存储器结构,包括基底、选择栅极、第一电荷存储层、控制栅极与第一介电层。在基底中具有沿着第一方向延伸的沟槽。选择栅极设置在沟槽中。第一电荷存储层设置在沟槽的侧壁上。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。控制栅极设置在沟槽中的选择栅极与第一电荷存储层上。控制栅极覆盖第一侧面与第二侧面。第一介电层设置在控制栅极与第一电荷存储层之间。The present invention provides a non-volatile memory structure including a substrate, a selection gate, a first charge storage layer, a control gate and a first dielectric layer. There is a trench in the substrate extending along the first direction. The select gate is disposed in the trench. The first charge storage layer is disposed on the sidewalls of the trench. The first charge storage layer has a first side surface and a second side surface opposite to each other. The first side surface and the second side surface are arranged in the first direction. The control gate is disposed on the select gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. The first dielectric layer is disposed between the control gate and the first charge storage layer.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,选择栅极、第一电荷存储层、控制栅极与基底可彼此电性绝缘。According to an embodiment of the present invention, in the above non-volatile memory structure, the select gate, the first charge storage layer, the control gate and the substrate can be electrically insulated from each other.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层例如是浮置栅极。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer is, for example, a floating gate.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层还可具有连接在第一侧面与第二侧面之间的第三侧面。控制栅极可覆盖第三侧面。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer may further have a third side surface connected between the first side surface and the second side surface. The control gate may cover the third side.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第二电荷存储层。第二电荷存储层设置在沟槽的另一侧壁上。第二电荷存储层可具有彼此相对的第四侧面与第五侧面。第四侧面与第五侧面可在第一方向上排列。控制栅极可覆盖第四侧面与第五侧面。第一介电层设置在控制栅极与第二电荷存储层之间。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a second charge storage layer. The second charge storage layer is disposed on the other sidewall of the trench. The second charge storage layer may have fourth and fifth sides opposite to each other. The fourth side surface and the fifth side surface may be arranged in the first direction. The control gate may cover the fourth side and the fifth side. The first dielectric layer is disposed between the control gate and the second charge storage layer.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,第一电荷存储层与第二电荷存储层可在第二方向上排列。第二方向可相交于第一方向。According to an embodiment of the present invention, in the above non-volatile memory structure, the first charge storage layer and the second charge storage layer may be arranged in the second direction. The second direction may intersect the first direction.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,第二电荷存储层还可具有连接在第四侧面与第五侧面之间的第六侧面。控制栅极可覆盖第六侧面。According to an embodiment of the present invention, in the above non-volatile memory structure, the second charge storage layer may further have a sixth side surface connected between the fourth side surface and the fifth side surface. The control gate may cover the sixth side surface.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第一掺杂区与第二掺杂区。第一掺杂区位于沟槽下方的基底中。第二掺杂区位于沟槽的一侧的基底中。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a first doped region and a second doped region. The first doped region is located in the substrate below the trench. The second doped region is located in the substrate on one side of the trench.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第三掺杂区。第三掺杂区位于沟槽的另一侧的基底中。According to an embodiment of the present invention, the above-mentioned non-volatile memory structure may further include a third doped region. The third doped region is located in the substrate on the other side of the trench.

依照本发明的一实施例所述,在上述非挥发性存储器结构中,还可包括第二介电层与第三介电层。第二介电层设置在选择栅极与基底之间。第三介电层设置在第一电荷存储层与基底之间。According to an embodiment of the present invention, the above non-volatile memory structure may further include a second dielectric layer and a third dielectric layer. The second dielectric layer is disposed between the select gate and the substrate. The third dielectric layer is disposed between the first charge storage layer and the substrate.

本发明提出一种非挥发性存储器结构的制造方法,包括以下步骤。在基底中形成沿着第一方向延伸的沟槽。在沟槽中形成选择栅极。在沟槽的侧壁上形成第一电荷存储层。第一电荷存储层具有彼此相对的第一侧面与第二侧面。第一侧面与第二侧面在第一方向上排列。在沟槽中的选择栅极与第一电荷存储层上形成控制栅极。控制栅极覆盖第一侧面与第二侧面。在控制栅极与第一电荷存储层之间形成第一介电层。The present invention provides a method for manufacturing a non-volatile memory structure, which includes the following steps. A trench extending along the first direction is formed in the substrate. A select gate is formed in the trench. A first charge storage layer is formed on the sidewalls of the trench. The first charge storage layer has a first side surface and a second side surface opposite to each other. The first side surface and the second side surface are arranged in the first direction. A control gate is formed on the select gate and the first charge storage layer in the trench. The control gate covers the first side and the second side. A first dielectric layer is formed between the control gate and the first charge storage layer.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,选择栅极、第一电荷存储层、控制栅极与基底可彼此电性绝缘。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the select gate, the first charge storage layer, the control gate and the substrate can be electrically insulated from each other.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层还可具有连接在第一侧面与第二侧面之间的第三侧面。控制栅极可覆盖第三侧面。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the first charge storage layer may further have a third side surface connected between the first side surface and the second side surface. The control gate may cover the third side.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层与第一介电层的形成方法可包括以下步骤。在沟槽中共形地形成电荷存储材料层。对电荷存储材料层进行回蚀刻制作工艺,而在沟槽的侧壁上形成电荷存储间隙壁。对电荷存储间隙壁进行图案化制作工艺,而形成第一电荷存储层。在形成第一电荷存储层之后,形成覆盖第一电荷存储层的第一介电层。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method for forming the first charge storage layer and the first dielectric layer may include the following steps. A layer of charge storage material is formed conformally in the trench. An etch-back fabrication process is performed on the charge storage material layer to form charge storage spacers on the sidewalls of the trenches. A patterned fabrication process is performed on the charge storage spacers to form a first charge storage layer. After forming the first charge storage layer, a first dielectric layer overlying the first charge storage layer is formed.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括在沟槽的另一侧壁上形成第二电荷存储层。第二电荷存储层可具有彼此相对的第四侧面与第五侧面。第四侧面与第五侧面可在第一方向上排列。控制栅极可覆盖第四侧面与第五侧面。第一介电层设置在控制栅极与第二电荷存储层之间。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method may further include forming a second charge storage layer on the other sidewall of the trench. The second charge storage layer may have fourth and fifth sides opposite to each other. The fourth side surface and the fifth side surface may be arranged in the first direction. The control gate may cover the fourth side and the fifth side. The first dielectric layer is disposed between the control gate and the second charge storage layer.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第一电荷存储层与第二电荷存储层可在第二方向上排列。第二方向可相交于第一方向。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the first charge storage layer and the second charge storage layer may be arranged in the second direction. The second direction may intersect the first direction.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,第二电荷存储层还可具有连接在第四侧面与第五侧面之间的第六侧面。控制栅极可覆盖第六侧面。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the second charge storage layer may further have a sixth side surface connected between the fourth side surface and the fifth side surface. The control gate may cover the sixth side surface.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括以下步骤。在沟槽下方的基底中形成第一掺杂区。在沟槽的一侧的基底中形成第二掺杂区。According to an embodiment of the present invention, the method for fabricating the above non-volatile memory structure may further include the following steps. A first doped region is formed in the substrate below the trench. A second doped region is formed in the substrate on one side of the trench.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括在沟槽的另一侧的基底中形成第三掺杂区。According to an embodiment of the present invention, in the above-mentioned manufacturing method of the non-volatile memory structure, the method may further include forming a third doped region in the substrate on the other side of the trench.

依照本发明的一实施例所述,在上述非挥发性存储器结构的制造方法中,还可包括以下步骤。可在选择栅极与基底之间形成第二介电层。可在第一电荷存储层与基底之间形成第三介电层。According to an embodiment of the present invention, the method for fabricating the above non-volatile memory structure may further include the following steps. A second dielectric layer may be formed between the select gate and the substrate. A third dielectric layer may be formed between the first charge storage layer and the substrate.

基于上述,在本发明所提出的非挥发性存储器结构及其制造方法中,控制栅极设置在第一电荷存储层上且覆盖第一电荷存储层的第一侧面与第二侧面,且第一介电层设置在控制栅极与第一电荷存储层之间。由此,控制栅极与第一电荷存储层还可在第一电荷存储层的第一侧面与第二侧面进行耦合,进而可增加控制栅极与第一电荷存储层的耦合区域。如此一来,本发明所提出的非挥发性存储器结构可具有较高的耦合率(couplingratio),因此可有效地提升存储器元件的电性效能。Based on the above, in the non-volatile memory structure and the manufacturing method thereof proposed by the present invention, the control gate is disposed on the first charge storage layer and covers the first side and the second side of the first charge storage layer, and the first A dielectric layer is disposed between the control gate and the first charge storage layer. Therefore, the control gate and the first charge storage layer can also be coupled at the first side and the second side of the first charge storage layer, thereby increasing the coupling area between the control gate and the first charge storage layer. In this way, the non-volatile memory structure proposed by the present invention can have a higher coupling ratio, and thus can effectively improve the electrical performance of the memory device.

为让本发明的上述特征和优点能更明显易懂,下文特举实施例,并配合所附的附图作详细说明如下。In order to make the above-mentioned features and advantages of the present invention more obvious and easy to understand, the following embodiments are given and described in detail with the accompanying drawings as follows.

附图说明Description of drawings

图1A至图1J为本发明一实施例的非挥发性存储器结构的制造流程上视图;1A to 1J are top views of a manufacturing process of a non-volatile memory structure according to an embodiment of the present invention;

图2A至图2J分别为沿图1A至图1J中的I-I’剖面线的剖视图;Figures 2A to 2J are cross-sectional views along the section line I-I' in Figures 1A to 1J, respectively;

图3A至图3J分别为沿图1A至图1J中的II-II’剖面线的剖视图。3A to 3J are cross-sectional views taken along the line II-II' in FIGS. 1A to 1J, respectively.

符号说明Symbol Description

10:非挥发性存储器结构10: Non-volatile memory structure

100:基底100: base

102:隔离结构102: Isolation Structure

104:图案化硬掩模层104: Patterning the hard mask layer

106:沟槽106: Groove

108、128、130:掺杂区108, 128, 130: doped regions

110、110a、114、124:介电层110, 110a, 114, 124: Dielectric layers

112:选择栅极材料层112: Select the gate material layer

112a:选择栅极112a: select gate

116:电荷存储材料层116: charge storage material layer

118、120:电荷存储间隙壁118, 120: Charge storage spacers

118a、120a:电荷存储层118a, 120a: charge storage layer

122:图案化光致抗蚀剂层122: Patterned Photoresist Layer

126:控制栅极材料层126: Control gate material layer

126a:控制栅极126a: Control Gate

AA:主动(有源)区AA: Active (active) area

D1:第一方向D1: first direction

D2:第二方向D2: second direction

S1~S6:侧面S1~S6: Side

TS1、TS2:顶面TS1, TS2: Top surface

具体实施方式Detailed ways

图1A至图1J为本发明一实施例的非挥发性存储器结构的制造流程上视图。图2A至图2J为沿图1A至图1J中的I-I’剖面线的剖视图。图3A至图3J为沿图1A至图1J中的II-II’剖面线的剖视图。1A to 1J are top views of a manufacturing process of a non-volatile memory structure according to an embodiment of the present invention. 2A to 2J are cross-sectional views along the line I-I' in FIGS. 1A to 1J . 3A to 3J are cross-sectional views along the line II-II' in FIGS. 1A to 1J .

请参照图1A、图2A与图3A,可在基底100中形成隔离结构102,且可通过隔离结构102在基底100中定义出主动区AA。基底100可为半导体基底,如硅基底。隔离结构102的材料例如是氧化硅。隔离结构102例如是浅沟槽隔离结构(shallow trench isolation,STI),但本发明并不以此为限。隔离结构102的形成方法例如是进行浅沟槽隔离制作工艺。此外,主动区AA可在第一方向D1上排列,且可在第二方向D2上延伸。第二方向D2可相交于第一方向D1。在本实施例中,以第二方向D2垂直于第一方向D1为例来进行说明,但本发明并不以此为限。Referring to FIG. 1A , FIG. 2A and FIG. 3A , an isolation structure 102 may be formed in the substrate 100 , and an active area AA may be defined in the substrate 100 by the isolation structure 102 . The substrate 100 may be a semiconductor substrate, such as a silicon substrate. The material of the isolation structure 102 is, for example, silicon oxide. The isolation structure 102 is, for example, a shallow trench isolation (STI) structure, but the invention is not limited thereto. The formation method of the isolation structure 102 is, for example, performing a shallow trench isolation fabrication process. In addition, the active areas AA may be arranged in the first direction D1 and may extend in the second direction D2. The second direction D2 may intersect with the first direction D1. In this embodiment, the second direction D2 is perpendicular to the first direction D1 as an example for description, but the present invention is not limited to this.

请参照图1B、图2B与图3B,在基底100上形成图案化硬掩模层104。图案化硬掩模层104的材料例如是氮化硅。图案化硬掩模层104的形成方法例如是组合使用沉积制作工艺、光刻制作工艺与蚀刻制作工艺。Referring to FIG. 1B , FIG. 2B and FIG. 3B , a patterned hard mask layer 104 is formed on the substrate 100 . The material of the patterned hard mask layer 104 is, for example, silicon nitride. The formation method of the patterned hard mask layer 104 is, for example, a combination of deposition process, photolithography process and etching process.

接着,可利用图案化硬掩模层104作为掩模,移除部分基底100与部分隔离结构102,而在基底100中形成沿着第一方向D1延伸的沟槽106。部分基底100与部分隔离结构102的移除方法例如是干式蚀刻法。Next, part of the substrate 100 and part of the isolation structure 102 can be removed by using the patterned hard mask layer 104 as a mask, and a trench 106 extending along the first direction D1 is formed in the substrate 100 . A method for removing part of the substrate 100 and part of the isolation structure 102 is, for example, dry etching.

然后,可在沟槽106下方的基底100中形成掺杂区108。掺杂区108可作为源极线(source line)使用。在本实施例中,掺杂区108是以N型掺杂区为例来进行说明,但本发明并不以此为限。在另一实施例中,掺杂区108也可为P型掺杂区。掺杂区108的形成方法例如是离子注入法。Then, doped regions 108 may be formed in the substrate 100 below the trenches 106 . The doped regions 108 can be used as source lines. In this embodiment, the doped region 108 is described by taking an N-type doped region as an example, but the present invention is not limited thereto. In another embodiment, the doped region 108 can also be a P-type doped region. The method for forming the doped region 108 is, for example, an ion implantation method.

请参照图1C、图2C与图3C,可在沟槽106的表面上形成介电层110。介电层110的材料例如是氧化硅。介电层110的形成方法例如是热氧化法。Referring to FIGS. 1C , 2C and 3C , a dielectric layer 110 may be formed on the surface of the trench 106 . The material of the dielectric layer 110 is, for example, silicon oxide. The formation method of the dielectric layer 110 is, for example, a thermal oxidation method.

接下来,可形成填入沟槽106的选择栅极材料层112。选择栅极材料层112的材料例如是掺杂多晶硅等导体材料。选择栅极材料层112的形成方法例如是化学气相沉积法。Next, a select gate material layer 112 filling the trenches 106 may be formed. The material of the selection gate material layer 112 is, for example, a conductor material such as doped polysilicon. The formation method of the selection gate material layer 112 is, for example, a chemical vapor deposition method.

请参照图1D、图2D与图3D,可对选择栅极材料层112进行回蚀刻制作工艺,以移除沟槽106外部的选择栅极材料层112,而在沟槽106中形成选择栅极112a。Referring to FIG. 1D , FIG. 2D and FIG. 3D , an etch-back process may be performed on the select gate material layer 112 to remove the select gate material layer 112 outside the trench 106 and form a select gate in the trench 106 112a.

然后,可移除硬掩模层104。硬掩模层104的移除方法例如是湿式蚀刻法。再者,可移除未被选择栅极112a所覆盖的部分介电层110,而在选择栅极112a与基底100之间形成介电层110a。介电层110a可作为栅介电层。由此,选择栅极112a与基底100可彼此电性绝缘。部分介电层110的移除方法例如是湿式蚀刻法。在本实施例中,先移除硬掩模层104,再移除部分介电层110,但本发明并不以此为限。在另一实施例中,也可先移除部分介电层110,再移除硬掩模层104。Then, the hard mask layer 104 may be removed. The removal method of the hard mask layer 104 is, for example, a wet etching method. Furthermore, a portion of the dielectric layer 110 not covered by the select gate 112 a may be removed, and the dielectric layer 110 a may be formed between the select gate 112 a and the substrate 100 . The dielectric layer 110a may serve as a gate dielectric layer. Thus, the select gate 112a and the substrate 100 can be electrically insulated from each other. A method for removing part of the dielectric layer 110 is, for example, a wet etching method. In this embodiment, the hard mask layer 104 is removed first, and then part of the dielectric layer 110 is removed, but the invention is not limited to this. In another embodiment, part of the dielectric layer 110 may be removed first, and then the hard mask layer 104 may be removed.

请参照图1E、图2E与图3E,可在沟槽106的表面上形成介电层114。此外,介电层114更可形成在基底100的顶面上与选择栅极112a的顶面上。介电层114可作为隧穿介电层。介电层114的材料例如是氧化硅。介电层114的形成方法例如是热氧化法或化学气相沉积法。在本实施例中,介电层114的形成方法是以热氧化法为例来进行说明。Referring to FIG. 1E , FIG. 2E and FIG. 3E , a dielectric layer 114 may be formed on the surface of the trench 106 . In addition, the dielectric layer 114 may be further formed on the top surface of the substrate 100 and the top surface of the select gate 112a. The dielectric layer 114 may serve as a tunneling dielectric layer. The material of the dielectric layer 114 is, for example, silicon oxide. The formation method of the dielectric layer 114 is, for example, a thermal oxidation method or a chemical vapor deposition method. In this embodiment, the formation method of the dielectric layer 114 is described by taking the thermal oxidation method as an example.

接着,可在沟槽106中共形地形成电荷存储材料层116。电荷存储材料层116的材料可为浮置栅极材料,如掺杂多晶硅或未经掺杂的多晶硅。Next, the charge storage material layer 116 may be conformally formed in the trenches 106 . The material of the charge storage material layer 116 may be a floating gate material, such as doped polysilicon or undoped polysilicon.

请参照图1F、图2F与图3F,可对电荷存储材料层116进行回蚀刻制作工艺。由此,可在沟槽106一侧壁上形成电荷存储间隙壁118,且可在沟槽106的另一侧壁上形成电荷存储间隙壁120。Referring to FIG. 1F , FIG. 2F and FIG. 3F , an etch-back fabrication process may be performed on the charge storage material layer 116 . Thus, charge storage spacers 118 may be formed on one sidewall of trench 106 and charge storage spacers 120 may be formed on the other sidewall of trench 106 .

请参照图1G、图2G与图3G,可在介电层114与电荷存储材料层116上形成图案化光致抗蚀剂层122。图案化光致抗蚀剂层122可具有暴露出部分电荷存储材料层118与部分电荷存储材料层120的开口122a。图案化光致抗蚀剂层122的形成方法例如是进行光刻制作工艺。Referring to FIGS. 1G , 2G and 3G , a patterned photoresist layer 122 may be formed on the dielectric layer 114 and the charge storage material layer 116 . The patterned photoresist layer 122 may have openings 122a exposing portions of the charge storage material layer 118 and portions of the charge storage material layer 120 . The formation method of the patterned photoresist layer 122 is, for example, a photolithography process.

请参照图1H、图2H与图3H,可通过图案化光致抗蚀剂层122作为掩模,移除部分电荷存储间隙壁118与部分电荷存储间隙壁120。由此,可对电荷存储间隙壁118与电荷存储间隙壁120进行图案化制作工艺,而在沟槽106的侧壁上形成电荷存储层118a,且在沟槽106的另一侧壁上形成电荷存储层120a。电荷存储层118a与电荷存储层120a可在第二方向D2上排列。电荷存储层118a与电荷存储层120a例如是浮置栅极。Referring to FIGS. 1H , 2H and 3H, a portion of the charge storage spacer 118 and a portion of the charge storage spacer 120 may be removed by using the patterned photoresist layer 122 as a mask. Thus, a patterning process can be performed on the charge storage spacers 118 and the charge storage spacers 120 to form the charge storage layer 118 a on the sidewall of the trench 106 and the charge storage layer 118 a on the other sidewall of the trench 106 storage layer 120a. The charge storage layer 118a and the charge storage layer 120a may be arranged in the second direction D2. The charge storage layer 118a and the charge storage layer 120a are, for example, floating gates.

电荷存储层118a具有彼此相对的侧面S1与侧面S2。侧面S1与侧面S2在第一方向D1上排列。此外,电荷存储层118a还可具有顶面TS1与连接在侧面S1与侧面S2之间的侧面S3。介电层114可设置在电荷存储层118a与基底100之间以及电荷存储层118a与选择栅极112a之间。因此,电荷存储层118a与基底100可通过介电层114而彼此电性绝缘,且电荷存储层118a与选择栅极112a可通过介电层114而彼此电性绝缘。The charge storage layer 118a has a side surface S1 and a side surface S2 opposite to each other. The side surface S1 and the side surface S2 are arranged in the first direction D1. In addition, the charge storage layer 118a may further have a top surface TS1 and a side surface S3 connected between the side surface S1 and the side surface S2. The dielectric layer 114 may be disposed between the charge storage layer 118a and the substrate 100 and between the charge storage layer 118a and the select gate 112a. Therefore, the charge storage layer 118 a and the substrate 100 may be electrically insulated from each other by the dielectric layer 114 , and the charge storage layer 118 a and the select gate 112 a may be electrically insulated from each other by the dielectric layer 114 .

电荷存储层120a可具有彼此相对的侧面S4与侧面S5。侧面S4与侧面S5可在第一方向D1上排列。此外,电荷存储层120a还可具有顶面TS2与连接在侧面S4与侧面S5之间的侧面S6。介电层114可设置在电荷存储层120a与基底100之间以及电荷存储层120a与选择栅极112a之间。由此,电荷存储层120a与基底100可彼此电性绝缘,且电荷存储层120a与选择栅极112a可彼此电性绝缘。The charge storage layer 120a may have a side surface S4 and a side surface S5 opposite to each other. The side surface S4 and the side surface S5 may be arranged in the first direction D1. In addition, the charge storage layer 120a may further have a top surface TS2 and a side surface S6 connected between the side surface S4 and the side surface S5. The dielectric layer 114 may be disposed between the charge storage layer 120a and the substrate 100 and between the charge storage layer 120a and the selection gate 112a. Thus, the charge storage layer 120a and the substrate 100 may be electrically insulated from each other, and the charge storage layer 120a and the selection gate 112a may be electrically insulated from each other.

然后,可移除图案化光致抗蚀剂层122。图案化光致抗蚀剂层122的移除方法例如是干式去光致抗蚀剂法(dry stripping)或湿式去光致抗蚀剂法(wet stripping)。Then, the patterned photoresist layer 122 can be removed. The removal method of the patterned photoresist layer 122 is, for example, dry stripping or wet stripping.

请参照图1I、图2I与图3I,在形成电荷存储层118a之后,可形成覆盖电荷存储层118a的介电层124。介电层124的材料例如是氧化硅、氮化硅或其组合。介电层124可为多层结构或单层结构。举例来说,介电层124可为氧化硅层/氮化硅层/氧化硅层(ONO)的复合层。介电层124的形成方法例如是化学气相沉积法。介电层124可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3,且可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。Referring to FIGS. 1I, 2I and 3I, after the charge storage layer 118a is formed, a dielectric layer 124 covering the charge storage layer 118a may be formed. The material of the dielectric layer 124 is, for example, silicon oxide, silicon nitride, or a combination thereof. The dielectric layer 124 may be a multi-layer structure or a single-layer structure. For example, the dielectric layer 124 may be a composite layer of a silicon oxide layer/silicon nitride layer/silicon oxide layer (ONO). The formation method of the dielectric layer 124 is, for example, a chemical vapor deposition method. The dielectric layer 124 may cover the top surface TS1, the side surface S1, the side surface S2 and the side surface S3 of the charge storage layer 118a, and may cover the top surface TS2, the side surface S4, the side surface S5 and the side surface S6 of the charge storage layer 120a.

接下来,可在沟槽106中形成控制栅极材料层126。控制栅极材料层126的材料例如是掺杂多晶硅等导体材料。控制栅极材料层126的形成方法例如是化学气相沉积法。Next, a control gate material layer 126 may be formed in the trenches 106 . The material of the control gate material layer 126 is, for example, a conductor material such as doped polysilicon. The formation method of the control gate material layer 126 is, for example, a chemical vapor deposition method.

请参照图1J、图2J与图3J,可移除沟槽106外部的部分控制栅极材料层126,而在沟槽106中的选择栅极112a、电荷存储层118a与电荷存储层120a上形成控制栅极126a。部分控制栅极材料层126的移除方法例如是化学机械研磨法(chemical mechanical polishing,CMP)。控制栅极126a可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3,且可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。介电层124可设置在控制栅极126a与电荷存储层118a之间、控制栅极126a与电荷存储层120a之间、控制栅极126a与选择栅极112a之间以及控制栅极126a与基底100之间。因此,控制栅极126a至少可通过介电层124而与电荷存储层118a、电荷存储层120a、选择栅极112a以及基底100彼此电性绝缘。Referring to FIGS. 1J , 2J and 3J , a portion of the control gate material layer 126 outside the trench 106 may be removed and formed on the select gate 112 a , the charge storage layer 118 a and the charge storage layer 120 a in the trench 106 Control gate 126a. A method for removing part of the control gate material layer 126 is, for example, chemical mechanical polishing (CMP). The control gate 126a may cover the top surface TS1, the side surface S1, the side surface S2 and the side surface S3 of the charge storage layer 118a, and may cover the top surface TS2, the side surface S4, the side surface S5 and the side surface S6 of the charge storage layer 120a. Dielectric layer 124 may be disposed between control gate 126a and charge storage layer 118a, between control gate 126a and charge storage layer 120a, between control gate 126a and select gate 112a, and between control gate 126a and substrate 100 between. Therefore, the control gate 126a can be electrically insulated from the charge storage layer 118a, the charge storage layer 120a, the select gate 112a, and the substrate 100 at least through the dielectric layer 124 from each other.

然后,可在沟槽106的一侧的基底100中形成掺杂区128,且可在沟槽106的另一侧的基底100中形成掺杂区130。掺杂区128与掺杂区130分别可作为源极或漏极。在本实施例中,掺杂区128与掺杂区130是以N型掺杂区为例来进行说明,但本发明并不以此为限。在另一实施例中,掺杂区128与掺杂区130也可为P型掺杂区。掺杂区128与掺杂区130的形成方法例如是离子注入法。Then, doped regions 128 can be formed in the substrate 100 on one side of the trenches 106 and doped regions 130 can be formed in the substrate 100 on the other side of the trenches 106 . The doped region 128 and the doped region 130 can be used as a source electrode or a drain electrode, respectively. In this embodiment, the doped region 128 and the doped region 130 are described by taking the N-type doped region as an example, but the present invention is not limited thereto. In another embodiment, the doped regions 128 and 130 can also be P-type doped regions. The method for forming the doped region 128 and the doped region 130 is, for example, an ion implantation method.

以下,通过图1J、图2J与图3J来说明本实施例的非挥发性存储器结构10。此外,虽然非挥发性存储器结构10的形成方法是以上述方法为例进行说明,但本发明并不以此为限。Hereinafter, the non-volatile memory structure 10 of this embodiment will be described with reference to FIG. 1J , FIG. 2J and FIG. 3J . In addition, although the method for forming the non-volatile memory structure 10 is described by taking the above method as an example, the present invention is not limited thereto.

请参照图1J、图2J与图3J,非挥发性存储器结构10包括基底100、选择栅极112a、电荷存储层118a、控制栅极126a与介电层124。在基底100中具有沿着第一方向D1延伸的沟槽106。选择栅极112a设置在沟槽106中。电荷存储层118a设置在沟槽106的侧壁上,且位于选择栅极112a上。电荷存储层118a具有彼此相对的侧面S1与侧面S2。侧面S1与侧面S2在第一方向D1上排列。电荷存储层118a还可具有顶面TS1与连接在侧面S1与侧面S2之间的侧面S3。电荷存储层118a例如是浮置栅极。控制栅极126a设置在沟槽106中的选择栅极112a与电荷存储层118a上。控制栅极126a可覆盖电荷存储层118a的顶面TS1、侧面S1、侧面S2与侧面S3。介电层124设置在控制栅极126a与电荷存储层118a之间。1J , FIG. 2J and FIG. 3J , the non-volatile memory structure 10 includes a substrate 100 , a select gate 112 a , a charge storage layer 118 a , a control gate 126 a and a dielectric layer 124 . There are trenches 106 in the substrate 100 extending along the first direction D1. Select gate 112a is disposed in trench 106 . A charge storage layer 118a is disposed on the sidewalls of the trench 106 and on the select gate 112a. The charge storage layer 118a has a side surface S1 and a side surface S2 opposite to each other. The side surface S1 and the side surface S2 are arranged in the first direction D1. The charge storage layer 118a may also have a top surface TS1 and a side surface S3 connected between the side surface S1 and the side surface S2. The charge storage layer 118a is, for example, a floating gate. Control gate 126a is disposed in trench 106 on select gate 112a and charge storage layer 118a. The control gate 126a may cover the top surface TS1, the side surface S1, the side surface S2 and the side surface S3 of the charge storage layer 118a. A dielectric layer 124 is disposed between the control gate 126a and the charge storage layer 118a.

此外,非挥发性存储器结构10还可包括隔离结构102、掺杂区108、介电层110a、介电层114、电荷存储层120a、掺杂区128与掺杂区130中的至少一者。选择栅极112a、电荷存储层118a、电荷存储层120a、控制栅极126a与基底100可通过介电层110a、介电层114与介电层124而彼此电性绝缘。隔离结构102设置在基底100中。掺杂区108位于沟槽106下方的基底100中。介电层110a设置在选择栅极112a与基底100之间。介电层114设置在电荷存储层118a与基底100之间,且可设置在电荷存储层120a与基底100之间。电荷存储层120a设置在沟槽106的另一侧壁上。电荷存储层118a与电荷存储层120a可在第二方向D2上排列。第二方向D2可相交于第一方向D1。电荷存储层120a可具有彼此相对的侧面S4与侧面S5。侧面S4与侧面S5可在第一方向D1上排列。电荷存储层120a还可具有顶面TS2与连接在侧面S4与侧面S5之间的侧面S6。电荷存储层120a例如是浮置栅极。控制栅极126a可覆盖电荷存储层120a的顶面TS2、侧面S4、侧面S5与侧面S6。介电层124可设置在控制栅极126a与电荷存储层120a之间。掺杂区128位于沟槽106的一侧的基底100中。掺杂区130位于沟槽106的另一侧的基底100中。In addition, the non-volatile memory structure 10 may further include at least one of the isolation structure 102 , the doped region 108 , the dielectric layer 110 a , the dielectric layer 114 , the charge storage layer 120 a , the doped region 128 and the doped region 130 . The select gate 112a, the charge storage layer 118a, the charge storage layer 120a, the control gate 126a and the substrate 100 may be electrically insulated from each other by the dielectric layer 110a, the dielectric layer 114 and the dielectric layer 124. The isolation structure 102 is disposed in the substrate 100 . The doped regions 108 are located in the substrate 100 below the trenches 106 . The dielectric layer 110a is disposed between the select gate 112a and the substrate 100 . The dielectric layer 114 is disposed between the charge storage layer 118 a and the substrate 100 , and may be disposed between the charge storage layer 120 a and the substrate 100 . The charge storage layer 120a is disposed on the other sidewall of the trench 106 . The charge storage layer 118a and the charge storage layer 120a may be arranged in the second direction D2. The second direction D2 may intersect with the first direction D1. The charge storage layer 120a may have a side surface S4 and a side surface S5 opposite to each other. The side surface S4 and the side surface S5 may be arranged in the first direction D1. The charge storage layer 120a may also have a top surface TS2 and a side surface S6 connected between the side surface S4 and the side surface S5. The charge storage layer 120a is, for example, a floating gate. The control gate 126a may cover the top surface TS2, the side surface S4, the side surface S5 and the side surface S6 of the charge storage layer 120a. A dielectric layer 124 may be disposed between the control gate 126a and the charge storage layer 120a. A doped region 128 is located in the substrate 100 on one side of the trench 106 . The doped region 130 is located in the substrate 100 on the other side of the trench 106 .

此外,非挥发性存储器结构10的各构件的材料、设置方式、导电型态、形成方法与功效已于上述实施例进行详尽地说明,在此不再重复说明。In addition, the materials, arrangement methods, conductive types, forming methods and functions of the components of the non-volatile memory structure 10 have been described in detail in the above embodiments, and will not be repeated here.

基于上述实施例可知,在非挥发性存储器结构10及其制造方法中,控制栅极126a设置在电荷存储层118a上且覆盖电荷存储层118a的侧面S1与侧面S2,且介电层124设置在控制栅极126a与电荷存储层118a之间。由此,控制栅极126a与电荷存储层118a更可在电荷存储层118a的侧面S1与侧面S2进行耦合,进而可增加控制栅极126a与电荷存储层118a的耦合区域。如此一来,非挥发性存储器结构10可具有较高的耦合率,因此可有效地提升存储器元件的电性效能。Based on the above embodiments, in the non-volatile memory structure 10 and the manufacturing method thereof, the control gate 126a is disposed on the charge storage layer 118a and covers the side S1 and the side S2 of the charge storage layer 118a, and the dielectric layer 124 is disposed on the charge storage layer 118a. Between the control gate 126a and the charge storage layer 118a. Therefore, the control gate 126a and the charge storage layer 118a can be further coupled at the side S1 and the side S2 of the charge storage layer 118a, thereby increasing the coupling area between the control gate 126a and the charge storage layer 118a. In this way, the non-volatile memory structure 10 can have a higher coupling rate, and thus can effectively improve the electrical performance of the memory element.

在一些实施例中,非挥发性存储器结构10还可包括电荷存储层120a。控制栅极126a设置在电荷存储层120a上且覆盖电荷存储层120a的侧面S4与侧面S5,且介电层124设置在控制栅极126a与电荷存储层120a之间。由此,控制栅极126a与电荷存储层120a还可在电荷存储层120a的侧面S4与侧面S5进行耦合,进而可增加控制栅极126a与电荷存储层120a的耦合区域。如此一来,非挥发性存储器结构10可具有较高的耦合率,因此可有效地提升存储器元件的电性效能。In some embodiments, the non-volatile memory structure 10 may also include a charge storage layer 120a. The control gate 126a is disposed on the charge storage layer 120a and covers the side S4 and the side S5 of the charge storage layer 120a, and the dielectric layer 124 is disposed between the control gate 126a and the charge storage layer 120a. Therefore, the control gate 126a and the charge storage layer 120a can also be coupled at the side S4 and the side S5 of the charge storage layer 120a, thereby increasing the coupling area between the control gate 126a and the charge storage layer 120a. In this way, the non-volatile memory structure 10 can have a higher coupling rate, and thus can effectively improve the electrical performance of the memory element.

此外,由于非挥发性存储器结构10具有垂直通道与埋入式的选择栅极112a,因此可防止短通道效应(short channel effect)与过度抹除现象(over-erase phenomenon),且可具有较高的存储单元密度(cell density)。In addition, since the non-volatile memory structure 10 has the vertical channel and the buried select gate 112a, it can prevent short channel effect and over-erase phenomenon, and can have higher of the memory cell density.

综上所述,在上述实施例的非挥发性存储器结构及其制造方法中,由于控制栅极与电荷存储层可具有较大的耦合区域,因此可使得非挥发性存储器结构具有较高的耦合率,进而可具有较佳的电性效能。To sum up, in the non-volatile memory structure and the manufacturing method thereof of the above-mentioned embodiments, since the control gate and the charge storage layer can have a larger coupling area, the non-volatile memory structure can have a high coupling rate, and thus can have better electrical performance.

虽然结合以上实施例公开了本发明,然而其并非用以限定本发明,任何所属技术领域中具有通常知识者,在不脱离本发明的精神和范围内,可作些许的更动与润饰,故本发明的保护范围应当以附上的权利要求所界定的为准。Although the present invention is disclosed in conjunction with the above embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, The scope of protection of the present invention should be defined by the appended claims.

Claims (20)

1.一种非挥发性存储器结构,其特征在于,包括:1. A non-volatile memory structure, characterized in that, comprising: 基底,其中在所述基底中具有沿着第一方向延伸的沟槽;a substrate having grooves therein extending along a first direction; 选择栅极,设置在所述沟槽中;a select gate disposed in the trench; 第一电荷存储层,设置在所述沟槽的侧壁上,且具有彼此相对的第一侧面与第二侧面,其中所述第一侧面与所述第二侧面在所述第一方向上排列;a first charge storage layer, disposed on the sidewall of the trench, and having a first side surface and a second side surface opposite to each other, wherein the first side surface and the second side surface are arranged in the first direction ; 控制栅极,设置在所述沟槽中的所述选择栅极与所述第一电荷存储层上,且覆盖所述第一侧面与所述第二侧面;以及a control gate disposed on the select gate and the first charge storage layer in the trench and covering the first side and the second side; and 第一介电层,设置在所述控制栅极与所述第一电荷存储层之间。A first dielectric layer is disposed between the control gate and the first charge storage layer. 2.如权利要求1所述的非挥发性存储器结构,其中所述选择栅极、所述第一电荷存储层、所述控制栅极与所述基底彼此电性绝缘。2. The non-volatile memory structure of claim 1, wherein the select gate, the first charge storage layer, the control gate, and the substrate are electrically insulated from each other. 3.如权利要求1所述的非挥发性存储器结构,其中所述第一电荷存储层包括浮置栅极。3. The non-volatile memory structure of claim 1, wherein the first charge storage layer comprises a floating gate. 4.如权利要求1所述的非挥发性存储器结构,其中所述第一电荷存储层还具有连接在所述第一侧面与所述第二侧面之间的第三侧面,且所述控制栅极覆盖所述第三侧面。4. The non-volatile memory structure of claim 1, wherein the first charge storage layer further has a third side surface connected between the first side and the second side, and the control gate The pole covers the third side. 5.如权利要求1所述的非挥发性存储器结构,还包括:5. The non-volatile memory structure of claim 1, further comprising: 第二电荷存储层,设置在所述沟槽的另一侧壁上,且具有彼此相对的第四侧面与第五侧面,其中所述第四侧面与所述第五侧面在所述第一方向上排列,所述控制栅极覆盖所述第四侧面与所述第五侧面,且所述第一介电层设置在所述控制栅极与所述第二电荷存储层之间。The second charge storage layer is disposed on the other sidewall of the trench and has a fourth side surface and a fifth side surface opposite to each other, wherein the fourth side surface and the fifth side surface are on the first side Arranged upward, the control gate covers the fourth side surface and the fifth side surface, and the first dielectric layer is disposed between the control gate and the second charge storage layer. 6.如权利要求5所述的非挥发性存储器结构,其中所述第一电荷存储层与所述第二电荷存储层在第二方向上排列,且所述第二方向相交于所述第一方向。6. The non-volatile memory structure of claim 5, wherein the first charge storage layer and the second charge storage layer are aligned in a second direction, and the second direction intersects the first charge direction. 7.如权利要求5所述的非挥发性存储器结构,其中所述第二电荷存储层还具有连接在所述第四侧面与所述第五侧面之间的第六侧面,且所述控制栅极覆盖所述第六侧面。7. The non-volatile memory structure of claim 5, wherein the second charge storage layer further has a sixth side surface connected between the fourth side and the fifth side, and the control gate The pole covers the sixth side surface. 8.如权利要求1所述的非挥发性存储器结构,还包括:8. The non-volatile memory structure of claim 1, further comprising: 第一掺杂区,位于所述沟槽下方的所述基底中;以及a first doped region in the substrate below the trench; and 第二掺杂区,位于所述沟槽的一侧的所述基底中。A second doped region is located in the substrate on one side of the trench. 9.如权利要求8所述的非挥发性存储器结构,还包括:9. The non-volatile memory structure of claim 8, further comprising: 第三掺杂区,位于所述沟槽的另一侧的所述基底中。A third doped region is located in the substrate on the other side of the trench. 10.如权利要求1所述的非挥发性存储器结构,还包括:10. The non-volatile memory structure of claim 1, further comprising: 第二介电层,设置在所述选择栅极与所述基底之间;以及a second dielectric layer disposed between the select gate and the substrate; and 第三介电层,设置在所述第一电荷存储层与所述基底之间。A third dielectric layer is disposed between the first charge storage layer and the substrate. 11.一种非挥发性存储器结构的制造方法,包括:11. A method of fabricating a non-volatile memory structure, comprising: 在基底中形成沿着第一方向延伸的沟槽;forming trenches in the substrate extending along the first direction; 在所述沟槽中形成选择栅极;forming a select gate in the trench; 在所述沟槽的侧壁上形成第一电荷存储层,其中所述第一电荷存储层具有彼此相对的第一侧面与第二侧面,且所述第一侧面与所述第二侧面在所述第一方向上排列;A first charge storage layer is formed on the sidewall of the trench, wherein the first charge storage layer has a first side surface and a second side surface opposite to each other, and the first side surface and the second side surface are at each other. arranged in the first direction; 在所述沟槽中的所述选择栅极与所述第一电荷存储层上形成控制栅极,其中所述控制栅极覆盖所述第一侧面与所述第二侧面;以及forming a control gate on the select gate and the first charge storage layer in the trench, wherein the control gate covers the first side and the second side; and 在所述控制栅极与所述第一电荷存储层之间形成第一介电层。A first dielectric layer is formed between the control gate and the first charge storage layer. 12.如权利要求11所述的非挥发性存储器结构的制造方法,其中所述选择栅极、所述第一电荷存储层、所述控制栅极与所述基底彼此电性绝缘。12. The method for fabricating a non-volatile memory structure as claimed in claim 11, wherein the select gate, the first charge storage layer, the control gate and the substrate are electrically insulated from each other. 13.如权利要求11所述的非挥发性存储器结构的制造方法,其中所述第一电荷存储层还具有连接在所述第一侧面与所述第二侧面之间的第三侧面,且所述控制栅极覆盖所述第三侧面。13. The method of manufacturing a non-volatile memory structure according to claim 11, wherein the first charge storage layer further has a third side surface connected between the first side surface and the second side surface, and the The control gate covers the third side surface. 14.如权利要求11所述的非挥发性存储器结构的制造方法,其中所述第一电荷存储层与所述第一介电层的形成方法包括:14. The method for fabricating a non-volatile memory structure as claimed in claim 11, wherein the method for forming the first charge storage layer and the first dielectric layer comprises: 在所述沟槽中共形地形成电荷存储材料层;Conformally forming a layer of charge storage material in the trench; 对所述电荷存储材料层进行回蚀刻制作工艺,而在所述沟槽的侧壁上形成电荷存储间隙壁;performing an etch back fabrication process on the charge storage material layer to form charge storage spacers on the sidewalls of the trenches; 对所述电荷存储间隙壁进行图案化制作工艺,而形成所述第一电荷存储层;以及performing a patterning process on the charge storage spacers to form the first charge storage layer; and 在形成所述第一电荷存储层之后,形成覆盖所述第一电荷存储层的所述第一介电层。After forming the first charge storage layer, the first dielectric layer overlying the first charge storage layer is formed. 15.如权利要求11所述的非挥发性存储器结构的制造方法,还包括:15. The method of manufacturing a non-volatile memory structure of claim 11, further comprising: 在所述沟槽的另一侧壁上形成第二电荷存储层,其中所述第二电荷存储层具有彼此相对的第四侧面与第五侧面,所述第四侧面与所述第五侧面在所述第一方向上排列,所述控制栅极覆盖所述第四侧面与所述第五侧面,且所述第一介电层设置在所述控制栅极与所述第二电荷存储层之间。A second charge storage layer is formed on the other sidewall of the trench, wherein the second charge storage layer has a fourth side and a fifth side opposite to each other, and the fourth side and the fifth side are at Arranged in the first direction, the control gate covers the fourth side surface and the fifth side surface, and the first dielectric layer is disposed between the control gate and the second charge storage layer between. 16.如权利要求15所述的非挥发性存储器结构的制造方法,其中所述第一电荷存储层与所述第二电荷存储层在第二方向上排列,且所述第二方向相交于所述第一方向。16. The method of manufacturing a non-volatile memory structure according to claim 15, wherein the first charge storage layer and the second charge storage layer are arranged in a second direction, and the second direction intersects the the first direction. 17.如权利要求15所述的非挥发性存储器结构的制造方法,其中所述第二电荷存储层还具有连接在所述第四侧面与所述第五侧面之间的第六侧面,且所述控制栅极覆盖所述第六侧面。17. The method of manufacturing a non-volatile memory structure according to claim 15, wherein the second charge storage layer further has a sixth side surface connected between the fourth side surface and the fifth side surface, and the second charge storage layer further has a sixth side surface connected between the fourth side surface and the fifth side surface, and the The control gate covers the sixth side surface. 18.如权利要求11所述的非挥发性存储器结构的制造方法,还包括:18. The method of fabricating a non-volatile memory structure of claim 11, further comprising: 在所述沟槽下方的所述基底中形成第一掺杂区;以及forming a first doped region in the substrate below the trench; and 在所述沟槽的一侧的所述基底中形成第二掺杂区。A second doped region is formed in the substrate on one side of the trench. 19.如权利要求18所述的非挥发性存储器结构的制造方法,还包括:19. The method of fabricating a non-volatile memory structure of claim 18, further comprising: 在所述沟槽的另一侧的所述基底中形成第三掺杂区。A third doped region is formed in the substrate on the other side of the trench. 20.如权利要求11所述的非挥发性存储器结构的制造方法,还包括:20. The method of manufacturing a non-volatile memory structure of claim 11, further comprising: 在所述选择栅极与所述基底之间形成第二介电层;以及forming a second dielectric layer between the select gate and the substrate; and 在所述第一电荷存储层与所述基底之间形成第三介电层。A third dielectric layer is formed between the first charge storage layer and the substrate.
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