CN111301185A - Methanol-water hybrid electric vehicle - Google Patents
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Abstract
本发明公开了一种甲醇水混合动力汽车,属于混合动力汽车技术领域,包括甲醇水重整装置、氢燃料电池、锂电池、电动机、汽车行走机构,氢燃料电池及锂电池分别与电动机电性连接,电动机与汽车行走机构传动连接。甲醇水重整装置包括用于为氢燃料电池提供氢气的重整反应器以及用于向重整反应器提供燃料的燃料箱。燃料箱与重整反应器通过管路连接,重整反应器与氢燃料电池通过管路连接,氢燃料电池与锂电池的充电线路电性连接,并且为锂电池提供充电。本发明通过采用锂电池及氢燃料电池作为电源驱动电动机,并且采用甲醇水重整装置为氢燃料电池提供燃料,从而提高混合动力汽车的可持续行驶里程,弥补了锂电池容量不足的缺陷。
The invention discloses a methanol-water hybrid vehicle, belonging to the technical field of hybrid vehicles, comprising a methanol-water reformer, a hydrogen fuel cell, a lithium battery, an electric motor, and an automobile running gear. connection, the motor is connected with the traveling mechanism of the automobile. The methanol water reformer includes a reforming reactor for supplying hydrogen to the hydrogen fuel cell and a fuel tank for supplying fuel to the reforming reactor. The fuel tank is connected with the reforming reactor through a pipeline, the reforming reactor is connected with the hydrogen fuel cell through a pipeline, and the hydrogen fuel cell is electrically connected with the charging circuit of the lithium battery, and provides charging for the lithium battery. The invention adopts lithium battery and hydrogen fuel cell as power source to drive motor, and adopts methanol water reformer to provide fuel for hydrogen fuel cell, thereby improving the sustainable driving mileage of hybrid electric vehicle and making up for the defect of insufficient capacity of lithium battery.
Description
技术领域technical field
本发明涉及混合动力汽车技术领域,特别涉及一种甲醇水混合动力汽车。The invention relates to the technical field of hybrid vehicles, in particular to a methanol-water hybrid vehicle.
背景技术Background technique
随着石油煤炭等化石能源的消耗,环境中的CO2浓度不断上升,由此引发的温室效应越来越显著。因此,世界各国对清洁可再生能源的关注越来越高。由于氢气在反应过程中无CO2、NOx等气体放出,所以被认为是未来的清洁能源。氢气可以由电解水、化石燃料重整反应等制得。尽管电解水所制备的氢气纯度高,但是制备成本高,催化剂昂贵,并且需要通入大量的电能。化石能源重整是指利用其中所储存的氢通过非均相的重整反应生成氢气的反应。相对于电解水制氢,化石能源重整制氢具有催化剂便宜、无需通电、产氢速率高的优点。With the consumption of fossil energy such as petroleum and coal, the concentration of CO2 in the environment continues to rise, and the resulting greenhouse effect becomes more and more significant. Therefore, countries around the world are paying more and more attention to clean and renewable energy. Since hydrogen does not emit CO 2 , NOx and other gases during the reaction, it is considered to be a clean energy in the future. Hydrogen can be produced from water electrolysis, fossil fuel reforming reactions, and the like. Although the hydrogen produced by electrolysis of water is of high purity, the production cost is high, the catalyst is expensive, and a large amount of electricity needs to be fed. Fossil energy reforming refers to a reaction in which hydrogen is generated by a heterogeneous reforming reaction using hydrogen stored therein. Compared with hydrogen production by electrolysis of water, hydrogen production from fossil energy reforming has the advantages of cheap catalyst, no need for electricity, and high hydrogen production rate.
此外,汽油汽车在行驶过程中以燃烧汽油为汽车提供动力来源,同时会排出COx和NOx以及pM2.5颗粒物等有害气体和物质。因此,为了减少汽油汽车对环境造成的污染,电动汽车迅速发展起来。电动汽车以锂电池里存储的电能为发动力提供动力,驱动汽车行驶。锂电池车具有零污染排放的优点,但是行驶里程低于汽油汽车。为了克服电动汽车的缺点,燃料电池汽车被开发出来。其中,氢燃料电池汽车以氢气为燃料,通过燃料电池将氢气转化为电能,从而为汽车提供能量。尽管氢燃料电池汽车无有害气体排除,且相对于锂电池汽车具有更长的行驶里程,但是氢燃料电池汽车需要配置高压的储氢灌。为了尽可能地提高储氢灌中存储氢气的量,其压力设置一般大于100MPa。这对于储氢灌材料的要求很高,无形中提高了燃料电池车的成本。并且,对于氢燃料电池车来讲,加氢站至关重要。然而,目前为止,国内城市中的加氢站数目还很稀少,拥有加氢站的城市屈指可数。因此,有必要设计效率更高的电动汽车,以克服目前电动汽车和氢燃料电池汽车的缺点和不足。In addition, gasoline vehicles use gasoline as a power source during driving, and at the same time emit COx, NOx, and pM2.5 particulate matter and other harmful gases and substances. Therefore, in order to reduce the pollution caused by gasoline vehicles to the environment, electric vehicles have developed rapidly. Electric vehicles use the electrical energy stored in lithium batteries to provide power to drive the car. Lithium battery vehicles have the advantage of zero pollution emissions, but the mileage is lower than gasoline vehicles. To overcome the shortcomings of electric vehicles, fuel cell vehicles were developed. Among them, hydrogen fuel cell vehicles use hydrogen as fuel, and the hydrogen is converted into electricity through fuel cells to provide energy for vehicles. Although hydrogen fuel cell vehicles do not emit harmful gases and have a longer mileage than lithium battery vehicles, hydrogen fuel cell vehicles need to be equipped with high-voltage hydrogen storage tanks. In order to increase the amount of hydrogen stored in the hydrogen storage tank as much as possible, the pressure setting is generally greater than 100MPa. This has high requirements for hydrogen storage filling materials, which virtually increases the cost of fuel cell vehicles. And, for hydrogen fuel cell vehicles, hydrogen refueling stations are very important. However, so far, the number of hydrogen refueling stations in domestic cities is still very few, and there are only a handful of cities with hydrogen refueling stations. Therefore, it is necessary to design more efficient electric vehicles to overcome the shortcomings and deficiencies of current electric vehicles and hydrogen fuel cell vehicles.
目前,国内的甲醇产量过剩,因此价格便宜。此外,甲醇水重整制氢技术成熟。同样体积的甲醇水和高压氢气,甲醇水通过重整反应获得的氢气是高压氢气的4倍,这意味着如果将甲醇水作为氢燃料电池的燃料来源,可以在燃料体积一定的情况下,增加氢燃料汽车的行驶里程。基于以上考虑,本发明提出一种新型混合动力汽车。所述混合动力汽车不消耗汽油,混合动力汽车在行驶过程中无CO2输出和其他有害气体和颗粒。这有助于城市空气质量的提高。此外,电动汽车以锂电池作为内置电源,通过锂电池的充放电为电动汽车提供动力。考虑到锂电池的容量有限,所以对于长时间行驶的汽车来讲不可避免地需要持续不断地充电。然而,在一些缺少充电桩的路线,电动汽车的使用受到限制。因此,本发明所述混合动力还包括甲醇水氢动力系统。所述混合动力汽车和汽油混合动力汽车的相同点在于可以拓宽电动汽车的使用里程和行驶范围,不同点在于汽油车在行驶过程中会排放大量CO2,并且油电混合动力汽车的发动机和变速箱之间的切换还存在不协调等问题,而本发明所述混合动力汽车以锂电池为直接动力来源,并不存在发电机和变速箱相互切换时存在的不协调的问题。At present, domestic methanol production is in excess, so the price is cheap. In addition, methanol-water reforming hydrogen production technology is mature. With the same volume of methanol water and high-pressure hydrogen, the hydrogen obtained by methanol water through the reforming reaction is 4 times that of high-pressure hydrogen, which means that if methanol water is used as the fuel source of hydrogen fuel cells, it can increase the fuel volume under the condition of a certain fuel volume. The mileage of a hydrogen car. Based on the above considerations, the present invention proposes a novel hybrid vehicle. The hybrid vehicle does not consume gasoline, and the hybrid vehicle does not output CO2 and other harmful gases and particles during driving. This contributes to the improvement of urban air quality. In addition, electric vehicles use lithium batteries as built-in power sources to provide power for electric vehicles through the charging and discharging of lithium batteries. Considering the limited capacity of lithium batteries, continuous charging is inevitable for long-running vehicles. However, the use of electric vehicles is limited on some routes that lack charging points. Therefore, the hybrid power system of the present invention also includes a methanol-water-hydrogen power system. The same point of the hybrid vehicle and the gasoline hybrid vehicle is that the mileage and driving range of the electric vehicle can be widened, and the difference is that the gasoline vehicle emits a large amount of CO 2 during driving, and the engine and transmission of the gasoline hybrid vehicle There are still problems such as incoordination in the switching between the boxes, while the hybrid vehicle of the present invention uses the lithium battery as the direct power source, and there is no inconsistency in the mutual switching between the generator and the gearbox.
发明内容SUMMARY OF THE INVENTION
本发明提供一种甲醇水混合动力汽车,解决现有纯电动汽车及油电混合汽车可持续行驶里程短的问题。The invention provides a methanol-water hybrid vehicle, which solves the problem of short sustainable driving mileage of existing pure electric vehicles and gasoline-electric hybrid vehicles.
为了解决上述技术问题,本发明的技术方案为:In order to solve the above-mentioned technical problems, the technical scheme of the present invention is:
一种甲醇水混合动力汽车,包括控制器、甲醇水重整装置、用于将甲醇水重整装置制得的氢气转化为化学能的氢燃料电池、锂电池、电动机以及汽车行走机构;A methanol-water hybrid vehicle, comprising a controller, a methanol-water reformer, a hydrogen fuel cell for converting the hydrogen produced by the methanol-water reformer into chemical energy, a lithium battery, an electric motor, and a vehicle running mechanism;
甲醇水重整装置与氢燃料电池通过管路连接,所述氢燃料电池及锂电池分别与电动机电性连接,所述电动机与汽车行走机构传动连接,并且为汽车行走机构提供动力;The methanol water reforming device is connected with the hydrogen fuel cell through pipelines, the hydrogen fuel cell and the lithium battery are respectively electrically connected with the electric motor, and the electric motor is connected with the traveling mechanism of the vehicle and provides power for the traveling mechanism of the vehicle;
所述甲醇水重整装置包括用于为氢燃料电池提供氢气的重整反应器、用于向重整反应器提供燃料的燃料箱、氢气提纯器;The methanol-water reforming device includes a reforming reactor for supplying hydrogen for the hydrogen fuel cell, a fuel tank for supplying fuel to the reforming reactor, and a hydrogen purifier;
所述燃料箱与重整反应器通过管路连接,所述重整反应器与氢燃料电池通过管路连接,氢气提纯器设置在重整反应器与氢燃料电池间的管路上;The fuel tank and the reforming reactor are connected through a pipeline, the reforming reactor and the hydrogen fuel cell are connected through a pipeline, and the hydrogen purifier is arranged on the pipeline between the reforming reactor and the hydrogen fuel cell;
重整反应器将甲醇水燃料转化为H2和少量CO等杂质,氢气提纯器将所生成的含杂质气体的H2进一步提纯和分离成高纯度的H2。经氢气提纯器提纯后的氢气可直接用于燃料电池的原料气;重整反应器生成的氢气通过分离生成高纯度的氢气,这部分氢气首先进入缓冲罐,然后进入氢燃料电池,氢燃料电池直接将氢气内的化学能部分转变为电能,其余部分转变为热能,所述热能在大功率电池中会使燃料电池发热;The reforming reactor converts methanol water fuel into impurities such as H 2 and a small amount of CO, and the hydrogen purifier further purifies and separates the generated H 2 containing impurities into high-purity H 2 . The hydrogen purified by the hydrogen purifier can be directly used as the feed gas of the fuel cell; the hydrogen generated by the reforming reactor is separated into high-purity hydrogen, and this part of the hydrogen first enters the buffer tank, and then enters the hydrogen fuel cell. Directly convert part of the chemical energy in the hydrogen into electrical energy, and the rest into thermal energy, which in a high-power battery will cause the fuel cell to generate heat;
所述氢燃料电池与锂电池的充电线路电性连接,并且为锂电池提供充电;控制器分别与氢燃料电池、锂电池及重整反应器电性连接,并且分别控制氢燃料电池、锂电池、燃料箱及重整反应器的工作。The hydrogen fuel cell is electrically connected with the charging circuit of the lithium battery, and provides charging for the lithium battery; the controller is electrically connected with the hydrogen fuel cell, the lithium battery and the reforming reactor, and controls the hydrogen fuel cell and the lithium battery respectively. , fuel tank and reforming reactor work.
其中,上述混合动力指的是动力源包括锂电池所存储的电能,以及甲醇水转化得到的电能;锂电池及电动机均可以采用已有商品化电动汽车或油电混合汽车所配置的电池及电动机,从而在已有商品化汽车上进行改造,节省制造成本。Among them, the above-mentioned hybrid power refers to the power source including the electric energy stored in the lithium battery and the electric energy obtained from the conversion of methanol water; the lithium battery and the electric motor can use the batteries and electric motors configured in the existing commercial electric vehicles or gasoline-electric hybrid vehicles. , so as to transform existing commercial vehicles and save manufacturing costs.
作为优选,所述锂电池设置有两路充电线路,另一路充电线路与通过外部电源进行充电的外部充电接口电性连接,锂电池可以通过氢燃料电池充电或者外部电源充电。Preferably, the lithium battery is provided with two charging circuits, and the other charging circuit is electrically connected to an external charging interface charged by an external power source, and the lithium battery can be charged by a hydrogen fuel cell or an external power source.
作为优选,所述燃料箱、重整反应器、氢燃料电池均可拆卸的设置在车体内部。Preferably, the fuel tank, the reforming reactor and the hydrogen fuel cell can be detachably arranged inside the vehicle body.
作为优选,所述氢燃料电池与锂电池相连的电路上设置有电控开关,所述电控开关与控制面板电性连接,并且通过控制面板控制电路的开闭。Preferably, an electric control switch is provided on the circuit connecting the hydrogen fuel cell and the lithium battery, the electric control switch is electrically connected with the control panel, and the opening and closing of the circuit is controlled by the control panel.
作为优选,所述控制面板设置在车体内部,一般设置在驾驶室,并且通过汽车驾驶内的仪表操作。Preferably, the control panel is arranged inside the vehicle body, generally arranged in the cab, and is operated through the instrument in the driving of the vehicle.
作为优选,所述重整反应器包括热交换系统、催化剂床层、加热系统和氢气分离净化系统,热交换系统、催化剂床层及氢气分离净化系统依次连接;重整反应器的反应温度一般为300~400℃,热交换系统用于甲醇水燃料的预热,反应生成的高温氢气与甲醇水燃料分别流入热交换系统并通过热交换对高温氢气进行降温,从而生成温度低于100℃的氢气,甲醇水燃料经过升温后形成蒸汽进入催化剂床层中反应,继而继续生成高温氢气,并输入到热交换系统中。Preferably, the reforming reactor includes a heat exchange system, a catalyst bed, a heating system and a hydrogen separation and purification system, and the heat exchange system, the catalyst bed and the hydrogen separation and purification system are connected in sequence; the reaction temperature of the reforming reactor is generally 300~400℃, the heat exchange system is used for the preheating of methanol water fuel, the high temperature hydrogen and methanol water fuel generated by the reaction flow into the heat exchange system respectively, and the high temperature hydrogen is cooled by heat exchange, thereby generating hydrogen with a temperature lower than 100℃ , the methanol water fuel is heated to form steam and enter the catalyst bed to react, and then continue to generate high-temperature hydrogen, which is input into the heat exchange system.
作为优选,所述氢燃料电池设置有用于与外部用电装置连接的外接线路,可通过外接线路向外部电器或电池充电,所述甲醇水重整装置设置有用于与外部装置连接的外部供气管路,可通过外部供气管路向外部装置提供高纯度氢气。Preferably, the hydrogen fuel cell is provided with an external circuit for connecting with an external electrical device, and the external electrical appliance or battery can be charged through the external circuit, and the methanol water reformer is provided with an external gas supply pipe for connecting with the external device High-purity hydrogen can be supplied to external devices through an external gas supply pipeline.
作为优选,所述氢燃料电池设置有散热装置,从而将氢燃料电池产生的热量散去,避免氢燃料电池温度过高,所述散热装置采用风冷或水冷。Preferably, the hydrogen fuel cell is provided with a heat dissipation device, so as to dissipate the heat generated by the hydrogen fuel cell and prevent the temperature of the hydrogen fuel cell from being too high, and the heat dissipation device adopts air cooling or water cooling.
上述的管路上均设置有与控制器电性连接的电控阀门,通过控制器控制不同电控阀门的开闭。The above-mentioned pipelines are all provided with electronically controlled valves that are electrically connected to the controller, and the opening and closing of different electronically controlled valves are controlled by the controller.
采用上述技术方案,通过采用锂电池及氢燃料电池作为电源驱动电动机,并且采用甲醇水重整装置为氢燃料电池提供燃料,从而提高混合动力汽车的可持续行驶里程,弥补了锂电池容量不足的缺陷。By adopting the above technical solution, by using lithium batteries and hydrogen fuel cells as power sources to drive motors, and using methanol-water reformer to provide fuel for hydrogen fuel cells, the sustainable driving range of hybrid electric vehicles is improved and the capacity of lithium batteries is insufficient. defect.
附图说明Description of drawings
图1为本发明实施例的连接示意图;Fig. 1 is the connection schematic diagram of the embodiment of the present invention;
图2为本发明实施例的部件设置位置示意图;FIG. 2 is a schematic diagram of a component setting position according to an embodiment of the present invention;
图3为本发明实施例中重整反应器的结构示意图。3 is a schematic structural diagram of a reforming reactor in an embodiment of the present invention.
图中,10、锂电池,20、氢燃料电池,21、外接线路,30、重整反应器,31、外部供气管路,40、燃料箱,50、控制器。In the figure, 10, lithium battery, 20, hydrogen fuel cell, 21, external circuit, 30, reforming reactor, 31, external gas supply pipeline, 40, fuel tank, 50, controller.
具体实施方式Detailed ways
下面结合附图对本发明的具体实施方式作进一步说明。在此需要说明的是,对于这些实施方式的说明用于帮助理解本发明,但并不构成对本发明的限定。此外,下面所描述的本发明各个实施方式中所涉及的技术特征只要彼此之间未构成冲突就可以相互组合。The specific embodiments of the present invention will be further described below with reference to the accompanying drawings. It should be noted here that the descriptions of these embodiments are used to help the understanding of the present invention, but do not constitute a limitation of the present invention. In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not conflict with each other.
如图1-3所示,本发明提供的一种甲醇水混合动力汽车,包括控制器50、甲醇水重整装置、用于将甲醇水重整装置制得的氢气转化为化学能的氢燃料电池20、锂电池10、电动机以及汽车行走机构;As shown in Figures 1-3, a methanol-water hybrid vehicle provided by the present invention includes a
甲醇水重整装置与氢燃料电池20通过管路连接,氢燃料电池20及锂电池10分别与电动机电性连接,电动机与汽车行走机构传动连接,并且为汽车行走机构提供动力;The methanol water reformer is connected with the
甲醇水重整装置包括用于为氢燃料电池20提供氢气的重整反应器30、用于向重整反应器30提供燃料的燃料箱40、氢气提纯器;The methanol water reformer includes a reforming
燃料箱40与重整反应器30通过管路连接,重整反应器30与氢燃料电池20通过管路连接,氢气提纯器设置在重整反应器30与氢燃料电池20间的管路上;The
重整反应器30将甲醇水燃料转化为H2和少量CO等杂质,氢气提纯器将所生成的含杂质气体的H2进一步提纯和分离成高纯度的H2。经氢气提纯器提纯后的氢气可直接用于燃料电池的原料气;重整反应器30生成的氢气通过分离生成高纯度的氢气,这部分氢气首先进入缓冲罐,然后进入氢燃料电池20,氢燃料电池20直接将氢气内的化学能部分转变为电能,其余部分转变为热能,热能在大功率电池中会使燃料电池发热;The reforming
氢燃料电池20与锂电池10的充电线路电性连接,并且为锂电池10提供充电;控制器50分别与氢燃料电池20、锂电池10及重整反应器30电性连接,并且分别控制氢燃料电池20、锂电池10、燃料箱40及重整反应器30的工作。The
其中,上述混合动力指的是动力源包括锂电池10所存储的电能,以及甲醇水转化得到的电能;锂电池10及电动机均可以采用已有商品化电动汽车或油电混合汽车所配置的电池及电动机,从而在已有商品化汽车上进行改造,节省制造成本。Among them, the above-mentioned hybrid power refers to the power source including the electric energy stored in the
进一步的,锂电池10设置有两路充电线路,另一路充电线路与通过外部电源进行充电的外部充电接口电性连接,锂电池10可以通过氢燃料电池20充电或者外部电源充电。Further, the
进一步的,燃料箱40、重整反应器30、氢燃料电池20均可拆卸的设置在车体内部。Further, the
进一步的,氢燃料电池20与锂电池10相连的电路上设置有电控开关,电控开关与控制面板电性连接,并且通过控制面板控制电路的开闭。Further, an electric control switch is provided on the circuit connecting the
进一步的,控制面板设置在车体内部,一般设置在驾驶室,并且通过汽车驾驶内的仪表操作。Further, the control panel is arranged inside the vehicle body, generally arranged in the cab, and is operated through the instrument in the driving of the vehicle.
进一步的,重整反应器30包括热交换系统、催化剂床层、加热系统和氢气分离净化系统,热交换系统、催化剂床层及氢气分离净化系统依次连接;重整反应器30的反应温度一般为300~400℃,热交换系统用于甲醇水燃料的预热,反应生成的高温氢气与甲醇水燃料分别流入热交换系统并通过热交换对高温氢气进行降温,从而生成温度低于100℃的氢气,甲醇水燃料经过升温后形成蒸汽进入催化剂床层中反应,继而继续生成高温氢气,并输入到热交换系统中。Further, the reforming
进一步的,氢燃料电池20设置有用于与外部用电装置连接的外接线路21,可通过外接线路21向外部电器或电池充电,甲醇水重整装置设置有用于与外部装置连接的外部供气管路31,可通过外部供气管路31向外部装置提供高纯度氢气。Further, the
进一步的,氢燃料电池20设置有散热装置,从而将氢燃料电池20产生的热量散去,避免氢燃料电池20温度过高,散热装置采用风冷或水冷。Further, the
上述的管路上均设置有与控制器50电性连接的电控阀门,通过控制器50控制不同电控阀门的开闭。The above-mentioned pipelines are all provided with electronically controlled valves that are electrically connected to the
工作原理为:The working principle is:
燃料箱40通过管路向重整反应器30提供甲醇水燃料,甲醇水燃料在重整反应器30中反应生成氢气,生成的氢气通过管路进入氢燃料电池20,氢气在氢燃料电池20中反应将化学能转变为电能,同时生成产物水,氢燃料电池20通过线路向锂电池10充电。燃料箱40向重整反应器30输送燃料,重整反应器30向氢燃料电池20输送氢气,以及氢燃料电池20向锂电池10充电均通过控制器50监测和控制。燃料箱40、重整反应器30、氢燃料电池20以及控制器50组成了混合动力汽车的甲醇水氢动力系统。甲醇水氢动力系统启动时,控制器50首先向重整制氢通过控制线路开启重整反应器30。当重整反应器30中的催化剂床层达到最佳反应温度时,控制器50通过控制线路向燃料箱40发出信号,启动电动机以及开启燃料箱40与重整反应器30间管路上的电控阀门,燃料箱40向重整反应器30输送甲醇水燃料。当燃料箱40向重整反应器30输送燃料时,应保证燃料箱40中有充足的燃料保证甲醇水可以不断向重整反应器30输送。为保证燃料箱40燃料的供应,燃料箱40内设置有液面感应器(未标注),当燃料箱40中甲醇水低于警戒线时,感应器向控制器50传递信号,控制器50发出加注甲醇水燃料的信号。如果燃料箱40中甲醇水低于警戒线,并且重整反应器30处于待机状态,那么控制器50将提醒加注燃料,并拒绝启动重整反应器30。The
甲醇水燃料在重整反应器30中反应首先生成较低纯度的氢气,其中包括CO和CO2。纯度较低的氢气通过重整反应器30中的钯膜过滤器过滤成高纯度的氢气(99.99%),一部分氢气被分流用于重整反应器30中加热系统的加热器的燃烧放热,加热器所释放的热量用于加热重整反应器30中的催化剂床层。另一部分高纯度氢气首先通过热交换系统的热量交换装置降低至60℃左右,然后通过管路输送到氢燃料电池20。氢燃料电池20在控制器50向重整反应器30发出启动预热信号后,启动预热。氢燃料电池20启动的信号是控制器50通过控制线路发出的。氢燃料电池20将高纯度的氢气在阳极氧化为H+,将空气中的氧气在阴极还原为O2-,同时线路中有电流通过。氢燃料电池20中产生的电流可以向锂电池10充电。由于氢燃料电池20在工作过程中有大量热放出,因此配备有散热装置(未标记)未标记,防止在反应过程中氢燃料电池20温度过高。The methanol-water fuel reacts in the reforming
氢燃料电池20产生的电通过线路向锂电池10充电,这一过程由控制器50监控完成。当锂电池10中的电量即将耗尽,控制器50监控到来自锂电池10的信号自动启动甲醇水氢动力系统,将甲醇水中存储的氢通过重整反应器30和氢燃料电池20逐级转化为氢气和电能,并向锂电池10充电。当锂电池10中的电量处于充满或充足的状态,控制器50不自动向甲醇水氢动力系统发出启动信号。但是,甲醇水氢动力系统可以另设有外接线路21,及外接充电连接线,可以向外接装置,一般为蓄电池或锂电池10充电。在这种情况下,甲醇水氢动力系统无法向锂电池10充电。The electricity generated by the
甲醇水氢动力系统中的重整反应器30除向氢燃料电池20提供高纯度氢气外,还可以通过外部供气管路31向其他装置或设备提供高纯度氢气,例如氢燃料电池20或燃烧装置,从而进一步扩展了甲醇水混合动力汽车的功能。当重整反应器30向外部提供氢气时,应保证甲醇水动力系统并未向锂电池10充电,即此时锂电池10应处于电量充足状态。重整反应器30向外部提供氢气的指示仍然从控制器50下达,此时通过控制器50上的操作屏幕或按钮下达启动重整反应器30预热和燃料箱40输送甲醇水燃料的通知。当控制器50启动制氢功能后,重整反应器30开始工作,其中的加热器在加热电偶和氢气燃烧放热的共同作用下将催化剂反应床层温度加热至反应温度。当催化剂床层温度达到反应温度时,控制器50自动启动电机将燃料箱40中的燃料输送至重整反应器30。重整反应器30将制备得到的高纯度氢气通过外部供气管路31向外部输送氢气,而不向氢燃料电池20输送氢气。氢燃料电池20处于待机或关闭状态,重整反应器30与氢燃料电池20连接的管路处于关闭状态。In addition to supplying high-purity hydrogen to the
图2给出了根据上述方案设计改造的一辆甲醇水混合动力汽车的动力结构。如图2所示,汽车的锂电池10放置在车头位置,靠近汽车的方向盘。控制器50也位于车头位置,其控制面板或按钮设置在方向盘位置(未标记)。氢燃料电池20、重整反应器30和燃料箱40位于车尾,其设置方式为:燃料箱40、重整反应器30和氢燃料电池20从下往上叠放,从而可以减少在车内的占地空间。氢燃料电池20的外接线路21和重整反应器30的外部供气管路31无需另外在汽车上开设孔道,可直接从汽车内部引出,如车门或后备箱,从而节省汽车的改造费用和成本。Figure 2 shows the power structure of a methanol-water hybrid vehicle designed and transformed according to the above scheme. As shown in FIG. 2 , the
图3公开了重整反应器30的一种结构,可参考申请号为201910722116.9的发明专利。重整反应器30由燃烧室、重整室和提纯室等构成。甲醇水燃料从两条进水管分别进入预热底座和重整室中的盘管(未标记)气化为气体,然后进入重整室中的反应列管生成纯度较低的氢气。纯度较低的氢气后进入提纯室生成高纯度的氢气(99.99%),其中一部分氢气回流至燃烧室(为燃烧室提供燃料),另一部分气体进过甲烷化反应器进一步将其中微量的CO或CO2转化为CH4,然后通入到氢燃料电池20。FIG. 3 discloses a structure of the reforming
以上结合附图对本发明的实施方式作了详细说明,但本发明不限于所描述的实施方式。对于本领域的技术人员而言,在不脱离本发明原理和精神的情况下,对这些实施方式进行多种变化、修改、替换和变型,仍落入本发明的保护范围内。The embodiments of the present invention have been described in detail above with reference to the accompanying drawings, but the present invention is not limited to the described embodiments. For those skilled in the art, without departing from the principle and spirit of the present invention, various changes, modifications, substitutions and alterations to these embodiments still fall within the protection scope of the present invention.
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