CN111012712A - A kind of saponin shampoo and its preparation method and application - Google Patents
A kind of saponin shampoo and its preparation method and application Download PDFInfo
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- CN111012712A CN111012712A CN201911411321.XA CN201911411321A CN111012712A CN 111012712 A CN111012712 A CN 111012712A CN 201911411321 A CN201911411321 A CN 201911411321A CN 111012712 A CN111012712 A CN 111012712A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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Abstract
The invention provides a saponin shampoo and a preparation method thereof. The saponin shampoo provided by the invention provides sufficient nutrition for scalp cells due to the addition of the saponin water extract. Meanwhile, the saponin shampoo provided by the invention is added with a plurality of substances such as a surfactant, a conditioner, citric acid, NaCl, a preservative and the like, so that the foaming, conditioning, pH regulation, thickening and preservative effects of the saponin shampoo are realized together, the foaming capacity and the decontamination performance of the saponin shampoo are effectively improved, and the combing performance, the gloss, the moisturizing effect and the hair comfort degree after shampooing are also obviously improved.
Description
Technical Field
The invention relates to the technical field of hair care products, and particularly relates to a saponin shampoo as well as a preparation method and application thereof.
Background
The shampoo is a hair care product with the functions of removing dandruff, treating hair oil, dyeing hair and the like. Among them, the main component is a surfactant. The surfactant has emulsifying, dispersing, foaming, solubilizing, cleaning, and moistening effects. The early shampoo is only a cleanser for hair and scalp, and along with the development of the formula and the process, the requirements of the shampoo product are more and more diversified. In recent years, people are pursuing greenization and nature return of washing and protecting products more and more favored by products containing Chinese herbal medicine components, so that the addition of harmful components can be effectively avoided by using some Chinese herbal medicines and plant extracts in the washing and protecting products, and the formula components of the products are closer to nature.
Fructus Gleditsiae Abnormalis, also called fructus Gleditsiae Abnormalis, is mature fruit of Gleditsia sinensis Lamarck of Gleditsia of Caesalpiniaceae, is rich in triterpene saponin, phenols, amino acids, etc., and can be used as natural raw material for medicine, food, cosmetic and washing product. The Chinese traditional custom of washing hair by boiling water with gleditschia horrida has the functions of killing various fungi on the scalp, inhibiting the generation of dandruff, promoting the blood circulation of the scalp and preventing alopecia and growing hair. However, when the saponin water is used alone for washing hair, the detergency and foaming performance are not enough, and the washed hair is poor in flexibility and easy to dry and frizzy.
Disclosure of Invention
In order to overcome the defect that the water of the Chinese honeylocust is used for washing hair independently in the prior art, the Chinese honeylocust shampoo and the preparation method thereof are provided.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides a saponin shampoo which comprises the following components in percentage by weight: 8 to 12 percent of saponin water extract, 18 to 30 percent of surfactant, 3.1 to 5.2 percent of conditioner, 0.01 to 0.02 percent of preservative, 0.4 to 0.8 percent of citric acid, 0.3 to 0.5 percent of NaCl and the balance of water;
the conditioner is polyquaternium-7, aloe water extract and cationic guar gum;
the concentration of the saponin water extract is 0.1g/mL, and the mass percent of the aloe water extract is 99%.
Preferably, the preparation method of the saponin aqueous extract comprises the following steps:
mixing the saponin powder with water, and sequentially soaking and ultrasonically extracting to obtain saponin water extract.
Preferably, the volume ratio of the mass of the saponin powder to the water is 1 g: 10 mL; the soaking time is 30-60 min.
Preferably, the temperature of the ultrasonic extraction is 40 ℃, and the time of the ultrasonic extraction is 50-60 min.
Preferably, the surfactant comprises one or more of sodium laureth sulfate, cocamidopropyl betaine and cocamidopropyl amide.
Preferably, the preservative comprises methylparaben or cason.
The invention also provides a preparation method of the saponin shampoo, which comprises the following steps:
carrying out first mixing on cationic guar gum, a surfactant, a saponin water extract and water to obtain a first mixed solution;
and secondly, mixing the first mixed solution, polyquaternium-7, aloe water extract, citric acid, NaCl and a preservative to obtain the saponin shampoo.
Preferably, the temperature of the first mixing is 70-80 ℃; the temperature of the second mixing is 35-40 ℃.
Preferably, the first mixing and the second mixing are independently performed under stirring conditions; the stirring speed is 200-500 r/min, and the stirring time is 2-4 h.
In order to achieve the purpose, the saponin shampoo provided by the invention comprises the following components in percentage by weight: 8 to 12 percent of saponin water extract, 18 to 30 percent of surfactant, 3.1 to 5.2 percent of conditioner, 0.01 to 0.02 percent of preservative, 0.4 to 0.8 percent of citric acid, 0.3 to 0.5 percent of NaCl and the balance of water; the conditioner is polyquaternium-7, aloe water extract and cationic guar gum; the concentration of the saponin water extract is 0.1g/mL, and the mass percent of the aloe water extract is 99%. Compared with the prior art, the saponin shampoo provided by the invention has the advantages that as the saponin extract is added, the saponin extract is rich in triterpene saponin, phenols, amino acid and other rich plant nutrients, so that sufficient nutrients are provided for scalp cells, and hair after shampooing is more smooth and glossy. Meanwhile, the saponin shampoo provided by the invention is added with a plurality of substances such as a surfactant, a conditioner, citric acid, NaCl, a preservative and the like, so that the foaming, conditioning, pH regulation, thickening and preservative effects of the saponin shampoo are realized together, the foaming capacity and the decontamination performance of the saponin shampoo are effectively improved, and the combing performance, the gloss, the moisturizing effect and the hair comfort degree after shampooing are also obviously improved.
Detailed Description
The invention provides a saponin shampoo which comprises the following components in percentage by weight: 8 to 12 percent of saponin water extract, 18 to 30 percent of surfactant, 3.1 to 5.2 percent of conditioner, 0.01 to 0.02 percent of preservative, 0.4 to 0.8 percent of citric acid, 0.3 to 0.5 percent of NaCl and the balance of water; the conditioner is polyquaternium-7, aloe water extract and cationic guar gum; the concentration of the saponin water extract is 0.1g/mL, and the mass percent of the aloe water extract is 99%.
According to the mass percentage, the saponin shampoo comprises 8-12% of saponin water extract, more preferably 8-10%, and the concentration of the saponin water extract is 0.05-0.20 g/mL, more preferably 0.1-0.2 g/mL.
In the present invention, the method for preparing the water extract of gleditsia sinensis lam preferably comprises the steps of: mixing the saponin powder with water, and sequentially soaking and ultrasonically extracting to obtain saponin water extract. In the present invention, the mass-to-water volume ratio of the saponin powder is preferably 1 g: (5-20) mL; more preferably 1 g: (5-10) mL.
The source of the saponin powder is not particularly required in the present invention, and may be obtained by using commercially available products well known to those skilled in the art or by preparing them, and in the specific embodiment of the present invention, it is preferable to obtain the saponin powder by preparing it. The preparation method of the saponin powder preferably comprises the following steps: washing appropriate amount of fructus Gleditsiae Abnormalis with deionized water, oven drying, pulverizing, and sieving to obtain the fructus Gleditsiae Abnormalis powder. The invention has no special requirement on the source of the saponin, and the saponin can be directly picked or purchased. The invention has no special requirements on the drying equipment, and the equipment well known by the technical personnel in the field can be adopted. Preferably in a dryer in the particular embodiment of the present invention. The present invention also does not require special equipment for said comminution, as is known to the skilled person. In the embodiment of the present invention, it is preferable to use a pulverizer. In the invention, the drying temperature is preferably 30-50 ℃, and the drying time is preferably 2-6 h; the crushing time is preferably 1-4 min.
In the invention, the sieving is preferably performed by using a 40-60-mesh sieve.
In the invention, the soaking temperature is preferably 20-40 ℃; the soaking time is preferably 30-60 min, and more preferably 50-60 min. In the invention, the ultrasonic extraction temperature is preferably 30-60 ℃, and more preferably 40-60 ℃; the time of ultrasonic extraction is preferably 50-60 min, and the frequency of ultrasonic extraction is preferably 40 KHz.
In the invention, after the ultrasonic extraction, the solid-liquid separation is carried out on the mixed material after the ultrasonic extraction to obtain the saponin aqueous extract. In the present invention, the solid-liquid separation is preferably a centrifugal treatment. The rotation speed of the centrifugal treatment is preferably 5000-8000 r/min, and the centrifugal time is preferably 3-5 min.
The saponin shampoo comprises 18-30% of surfactant, and more preferably 21-27% by mass. In the present invention, the surfactant preferably includes one or more of sodium laureth sulfate, cocamidopropyl betaine, and cocamide, and more preferably includes sodium laureth sulfate, cocamidopropyl betaine, and cocamide; when the surfactant comprises sodium laureth sulfate, cocamidopropyl betaine and cocamido diethanolamide, the saponin shampoo is used as a reference, the weight percentage of the sodium laureth sulfate is 12-18%, the weight percentage of the cocamidopropyl betaine is 2-4%, and the weight percentage of the cocamido diethanolamide is 4-8%. In the present invention, the source of the surfactant is not particularly limited, and a commercially available product known to those skilled in the art may be used.
According to the mass percentage, the saponin shampoo comprises 3.1-5.2% of conditioner, and more preferably 3.7-4.6%. In the present invention, the conditioning agent is preferably polyquaternium-7, aloe vera aqueous extract, and cationic guar gum; based on the saponin shampoo, the polyquaternium-7 accounts for 1-2 wt%, the aloe water extract accounts for 2-3 wt%, the cationic guar gum accounts for 0.1-0.2 wt%, and the aloe water extract accounts for 99 wt%. The source of the conditioning agent is not particularly required in the present invention, and commercially available products well known to those skilled in the art may be used.
The saponin shampoo comprises 0.01-0.02% of preservative by mass percent, and in the invention, the preservative preferably comprises methyl p-hydroxybenzoate or carbazone, and more preferably comprises methyl p-hydroxybenzoate. According to the mass percentage, the saponin shampoo also comprises 0.4-0.8% of citric acid, more preferably 0.4-0.6%, 0.3-0.5% of NaCl, more preferably 0.3-0.4%, and the balance of deionized water. In the present invention, there is no particular requirement for the source of the preservative, citric acid and NaCl, and commercially available products well known to those skilled in the art may be used.
In the invention, the saponin extract is rich in triterpene saponin, phenols, amino acid and other rich plant nutrients, provides sufficient nutrients for scalp cells, and enables hair to be more smooth and glossy after shampooing. Meanwhile, the saponin shampoo provided by the invention is added with a plurality of substances such as a surfactant, a conditioner, citric acid, NaCl, a preservative and the like, so that the foaming, conditioning, pH regulation, thickening and preservative effects of the saponin shampoo are realized together, the foaming capacity and the decontamination performance of the saponin shampoo are effectively improved, and the combing performance, the gloss, the moisturizing effect and the hair comfort degree after shampooing are also obviously improved.
The invention also provides a preparation method of the saponin shampoo, which comprises the following steps:
carrying out first mixing on cationic guar gum, a surfactant, a saponin water extract and water to obtain a first mixed solution;
and secondly, mixing the first mixed solution, polyquaternium-7, aloe water extract, citric acid, NaCl and a preservative to obtain the saponin shampoo.
According to the invention, cationic guar gum, a surfactant, a saponin water extract and water are subjected to first mixing to obtain a first mixed solution. In the present invention, the first mixing is preferably performed under stirring, and the stirring manner of the present invention does not require any special condition, and may be a stirring manner known to those skilled in the art, and specifically, mechanical stirring or magnetic stirring may be employed. In the invention, the stirring speed is preferably 200-400 r/min, and the stirring time is preferably 1-2 h.
In the invention, the temperature of the first mixing is preferably 70-80 ℃, and more preferably 75-80 ℃. The invention has no special requirement on the specific heating mode, and the heating mode known by the technical personnel can be adopted, and the heating mode can be specifically adopted by adopting a water bath or oil bath mode.
In the present invention, there is no particular requirement on the mixing order of the cationic guar gum, the surfactant, the saponin aqueous extract solution and the water, and the cationic guar gum, the surfactant, the saponin aqueous extract solution and the water are directly mixed and then heated.
Obtaining the first mixed solution; in the invention, the first mixed solution is preferably subjected to cooling treatment to obtain the first mixed solution at the second temperature. The invention has no special requirement on the temperature reduction treatment, and can adopt a temperature reduction mode which is well known by the technical personnel in the field, in particular, a natural cooling mode can be adopted.
In the present invention, the second temperature is preferably 35 to 40 ℃, and in the present invention, the second temperature is preferably the same as the second mixing temperature.
In the present invention, the second mixing is preferably performed under stirring. The stirring mode of the invention has no special requirement, and the stirring mode known to those skilled in the art can be adopted, and concretely, mechanical stirring or magnetic stirring can be adopted. In the invention, the stirring speed of the second mixing is preferably 400-500 r/min, and the stirring time is preferably 1-2 h.
The invention has no special requirement on the sequence of the second mixing, and the mixing can be carried out according to any mixing sequence.
After the second mixing is completed, the obtained mixed solution is preferably subjected to standing defoaming treatment, and the standing defoaming treatment is preferably performed at room temperature.
In the invention, the two-step mixing has the effects of better dissolving and dispersing the shampoo, not easily layering at higher temperature, normal temperature and lower temperature, and enabling the saponin shampoo product to obtain more ideal viscosity and pH value.
The invention also provides the application of the saponin shampoo, and after warm water is used for washing hair, a proper amount of saponin shampoo is uniformly smeared on hair.
Compared with the existing saponin liquid, the saponin shampoo provided by the invention is added with various substances such as a surfactant, a conditioner, citric acid, NaCl, a preservative and the like, so that the effects of foaming, conditioning, pH regulation, thickening and corrosion prevention of the saponin shampoo are realized together, and the foaming capacity and the decontamination performance of the saponin shampoo are effectively improved.
In order to better understand the present invention, the following examples are further provided to illustrate the present invention, but the present invention is not limited to the following examples.
Example 1
Washing appropriate amount of fructus Gleditsiae Abnormalis with deionized water, drying at 40 deg.C in a dryer, pulverizing in a pulverizer, and sieving with 40 mesh sieve to obtain fructus Gleditsiae Abnormalis powder. Mixing the raw materials in a ratio of 1 g: adding deionized water into the saponin powder according to the material-liquid ratio of 10mL (weight of the saponin powder: volume of the deionized water), soaking for 60 minutes at room temperature, performing ultrasonic treatment for 50 minutes at 40 ℃, performing solid-liquid separation by using a centrifugal machine, and reserving supernatant to obtain the saponin water extract.
15 percent of lauryl alcohol polyoxyethylene ether sodium sulfate, 10 percent of saponin water extract, 4 percent of cocamidopropyl betaine, 4 percent of coconut diethanolamide, 72 percent of polyquaternary ammonium salt, 2 percent of aloe water extract, 0.4 percent of citric acid, 0.3 percent of NaCl, 0.2 percent of cationic guar gum, 0.01 percent of methyl p-hydroxybenzoate and the balance of water; wherein the concentration of the saponin water extract is 0.1g/mL, and the mass percent of the aloe water extract is 99%.
Heating water to 75 ℃, sequentially adding sodium laureth sulfate, cocamidopropyl betaine, coconut oil diethanolamide, saponin water extract and cationic guar gum, and stirring until the mixture is transparent; cooling to 40 deg.C, adding polyquaternium-7, Aloe water extractive solution, citric acid, NaCl, and methyl p-hydroxybenzoate, stirring to disperse uniformly, making fructus Gleditsiae Abnormalis shampoo, standing, defoaming, and discharging.
Example 2
Washing appropriate amount of fructus Gleditsiae Abnormalis with deionized water, drying at 50 deg.C in a dryer, pulverizing in a pulverizer, and sieving with 40 mesh sieve to obtain fructus Gleditsiae Abnormalis powder. Mixing the raw materials in a ratio of 1 g: adding deionized water into the saponin powder at a material-liquid ratio of 5mL (weight of the saponin powder: volume of the deionized water), soaking for 60 minutes at room temperature, performing ultrasonic treatment for 60 minutes at 40 ℃, performing solid-liquid separation by using a centrifugal machine, and reserving supernatant to obtain saponin water extract.
Calculated by weight percentage, 18 percent of sodium lauryl polyoxyethylene ether sulfate, 8 percent of saponin water extract, 2 percent of cocamidopropyl betaine, 6 percent of coconut diethanolamide, 71 percent of polyquaternary ammonium salt, 3 percent of aloe water extract, 0.6 percent of citric acid, 0.4 percent of NaCl, 0.2 percent of cationic guar gum, 0.02 percent of methyl p-hydroxybenzoate and the balance of water; wherein the concentration of the saponin water extract is 0.2g/mL, and the mass percent of the aloe water extract is 99%.
Heating water to 80 ℃, sequentially adding sodium laureth sulfate, cocamidopropyl betaine, coconut oil diethanolamide, saponin water extract and cationic guar gum, and stirring until the mixture is transparent; cooling to 35 deg.C, adding polyquaternium-7, Aloe water extractive solution, citric acid, NaCl, and methyl p-hydroxybenzoate, stirring to disperse uniformly, making fructus Gleditsiae Abnormalis shampoo, standing, defoaming, and discharging.
Test example
Randomly selecting 40 people, half of men and women, and the age of 20-40 years, continuously using the saponin shampoo, the single saponin and the commercially available saponin shampoo of the embodiment 1 five times respectively, washing the hair once every two days according to the same method, and finally performing sensory comparison and scoring according to the hair washing effect of the product. The method adopts 10 points, 1 point is worst, 10 points are best, the comprehensive data is averaged, and the experimental results are shown in table 1.
TABLE 1 evaluation of efficacy of Saponin shampoo
As can be seen from table 1, the shampoo of the present invention significantly improved the shampoo performance of the saponin solution; compared with the commercially available saponin shampoo, the saponin shampoo disclosed by the invention is easier to clean, and the fineness of foam is not obviously different from that of the commercially available saponin shampoo; but the combing property, the luster, the moisturizing effect and the hair comfort degree are better than those of the commercially available saponin shampoo; the softness and the clean feeling after washing are not much different from those of the commercially available saponin shampoo, and the cleaning effect and the anti-dandruff and anti-itching effect are slightly worse than those of the commercially available saponin shampoo. The evaluation of the two methods is not very different, and the saponin shampoo has low cost, so the self-made shampoo containing the natural saponin extract has good application prospect.
The foregoing is merely a preferred embodiment of the invention and is not intended to limit the invention in any manner. It should be noted that, for those skilled in the art, without departing from the principle of the present invention, several improvements and modifications can be made, and these improvements and modifications should also be construed as the protection scope of the present invention.
Claims (10)
1. The saponin shampoo is characterized by comprising the following components in percentage by weight: 8 to 12 percent of saponin water extract, 18 to 30 percent of surfactant, 3.1 to 5.2 percent of conditioner, 0.01 to 0.02 percent of preservative, 0.4 to 0.8 percent of citric acid, 0.3 to 0.5 percent of NaCl and the balance of water;
the conditioner is polyquaternium-7, aloe water extract and cationic guar gum;
the concentration of the saponin water extract is 0.05-0.20 g/mL, and the mass percent of the aloe water extract is 99%.
2. The saponin shampoo of claim 1, wherein the saponin aqueous extract is prepared by a method comprising the steps of:
mixing the saponin powder with water, and sequentially soaking and ultrasonically extracting to obtain saponin water extract.
3. The saponin shampoo of claim 2, wherein the mass to water volume ratio of the saponin powder is 1 g: (5-20) mL; the soaking time is 30-60 min.
4. The saponin shampoo of claim 2, wherein the temperature of the ultrasonic extraction is 30-60 ℃ and the time of the ultrasonic extraction is 50-60 min.
5. The saponin shampoo of claim 1, wherein the surfactant comprises one or more of sodium laureth sulfate, cocamidopropyl betaine, and cocodiethanolamide.
6. The saponin shampoo of claim 1, wherein the preservative comprises methylparaben or cason.
7. The method for producing a saponin shampoo according to any one of claims 1 to 6 comprising the steps of:
carrying out first mixing on cationic guar gum, a surfactant, a saponin water extract and water to obtain a first mixed solution;
and secondly, mixing the first mixed solution, polyquaternium-7, aloe water extract, citric acid, NaCl and a preservative to obtain the saponin shampoo.
8. The method according to claim 7, wherein the temperature of the first mixing is 70 to 80 ℃; the temperature of the second mixing is 35-40 ℃.
9. The method of claim 7, wherein the first mixing and the second mixing are independently performed under stirring conditions;
the stirring speed is 200-500 r/min, and the stirring time is 2-4 h.
10. Use of a saponin shampoo according to any one of claims 1 to 6 or a saponin shampoo prepared by the method of any one of claims 7 to 9.
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| CN112494411A (en) * | 2021-01-28 | 2021-03-16 | 贵州华波日化有限公司 | Compound hair conditioner containing saponin and dendrobium nobile and preparation method thereof |
| CN113599322A (en) * | 2021-08-18 | 2021-11-05 | 中华全国供销合作总社南京野生植物综合利用研究所 | A shampoo formula containing Gleditsia sinensis saponin and its preparation method |
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| CN107308034A (en) * | 2017-05-26 | 2017-11-03 | 安徽肤彩生物科技有限公司 | A kind of special hand cleanser of women and infants |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112494411A (en) * | 2021-01-28 | 2021-03-16 | 贵州华波日化有限公司 | Compound hair conditioner containing saponin and dendrobium nobile and preparation method thereof |
| CN113599322A (en) * | 2021-08-18 | 2021-11-05 | 中华全国供销合作总社南京野生植物综合利用研究所 | A shampoo formula containing Gleditsia sinensis saponin and its preparation method |
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