CN110918028A - A device and method for preparing metal catalyst by using plasma - Google Patents
A device and method for preparing metal catalyst by using plasma Download PDFInfo
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- CN110918028A CN110918028A CN201911242257.7A CN201911242257A CN110918028A CN 110918028 A CN110918028 A CN 110918028A CN 201911242257 A CN201911242257 A CN 201911242257A CN 110918028 A CN110918028 A CN 110918028A
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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Abstract
本发明公开了一种利用等离子体制备金属催化剂的装置，包括反应室，所述反应室内设有金属板电极和多针电极，所述金属板电极和多针电极相对设置，所述金属板电极上压盖有电介质板。本发明产生均匀、大面积、高密度的等离子体，可以高效率、高质量的制取金属催化剂，且能有效防止电晕放电向火花放电的过渡，避免催化剂制备过程中的过度烧结，利于催化剂的制备。本发明设计简便、成本低廉、便于拆卸，还可应用于放电等离子体应用的其他领域。
The invention discloses a device for preparing metal catalyst by using plasma, comprising a reaction chamber, wherein a metal plate electrode and a multi-needle electrode are arranged in the reaction chamber, the metal plate electrode and the multi-needle electrode are arranged oppositely, and the metal plate electrode The upper gland has a dielectric plate. The invention generates uniform, large-area, high-density plasma, can prepare metal catalysts with high efficiency and high quality, and can effectively prevent the transition from corona discharge to spark discharge, avoid excessive sintering in the catalyst preparation process, and is beneficial to the catalyst preparation. The invention is simple in design, low in cost and easy to disassemble, and can also be applied to other fields of discharge plasma application.
Description
Technical Field
The invention relates to the field of catalyst preparation, in particular to a device and a method for preparing a metal catalyst by using plasma.
Background
The metal catalyst is widely applied to various industries in industrial production, such as petrochemical industry, synthetic ammonia industry, electroplating industry and the like, and for the metal catalyst, when the metal is uniformly dispersed on a carrier in a monatomic form, the metal catalyst is in an ideal state, and the preparation method of the metal catalyst comprises an immersion method, an atomic deposition method, a reduction method, a solid-phase melting method and the like, but the methods are usually complicated and time-consuming in the preparation process, and need to use a large amount of toxic and harmful reagents, so the method is not beneficial to environmental protection.
Disclosure of Invention
The invention provides a device and a method for preparing a metal catalyst by using plasma, wherein the prepared metal catalyst is uniformly dispersed on a carrier, and the device and the method are convenient to use, clean and environment-friendly.
An apparatus for preparing a metal catalyst using plasma, comprising: the device comprises a reaction chamber, wherein a metal plate electrode and a multi-needle electrode are arranged in the reaction chamber, the metal plate electrode and the multi-needle electrode are oppositely arranged, and a dielectric plate is pressed on the metal plate electrode in a pressing mode.
Further, the distance between the end part of the multi-needle electrode and the dielectric plate is 1-50 mm.
Furthermore, the curvature radius of the needles on the multi-needle electrode is 0.1-0.5 mm, and the density of the needles is 50-100 needles/dm2。
Further, the multi-needle electrode is made of stainless steel or other metals.
Further, the dielectric plate is quartz or ceramic, the area of the dielectric plate is not smaller than the metal plate electrode, and the thickness of the dielectric plate is 1-5 mm.
Further, the material of the reaction chamber is one of organic glass, quartz and stainless steel.
Further, still include electrode plate adjustment mechanism, electrode plate adjustment mechanism includes threaded rod, seal receptacle, packing ring and nut, the seal receptacle passes through the nut to be fixed on the reacting chamber, the metal plate electrode is fixed the tip of threaded rod, the threaded rod with seal receptacle threaded connection.
Further, the reaction chamber is provided with an air guide hole.
A method for preparing a metal catalyst using the above apparatus for preparing a metal catalyst using plasma, comprising the steps of:
step 1: completely immersing the catalyst support in a metal salt solution;
step 2: treating the catalyst carrier by adopting impregnation or ultrasonic impregnation;
and step 3: taking out the catalyst carrier and drying to obtain a catalyst to be treated;
and 4, step 4: uniformly placing the catalyst to be treated on the surface of the dielectric plate;
and 5: applying a high voltage to the multi-pin electrode and the metal plate electrode;
step 6: and corona discharge plasma is generated at the end part of the multi-needle electrode, and dielectric barrier discharge plasma is generated on one surface of the dielectric plate facing the multi-needle electrode, and the dielectric barrier discharge plasma all act on the surface of the catalyst to be treated to obtain a finished catalyst product.
Further, step 4 further comprises introducing a carrier gas from the gas guide hole.
The invention provides a device and a method for preparing a metal catalyst by using plasma, wherein the metal catalyst prepared by using the plasma is uniformly dispersed on a carrier, and the device and the method have the following advantages: firstly, the lower gas temperature of the plasma can avoid sintering and agglomeration of metal particles, inhibit the metal particles from diffusing into the carrier and enhance the interaction between the metal and the carrier; secondly, high-energy electrons in the plasma can be adsorbed on the surfaces of the metal particles, so that the metal particles are negatively charged and mutually repelled, and the dispersion degree of the metal particles is favorably improved; thirdly, high-energy particles in the plasma can rapidly decompose a catalyst precursor to rapidly nucleate metal ions; and fourthly, on a mesoscopic scale, the influence of relative contact behavior of the plasma can make the prepared metal catalyst structurally different from the catalyst prepared by the traditional method, so that the catalyst obtains better performance.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and those skilled in the art can also obtain other drawings according to the drawings without creative efforts.
FIG. 1 is a schematic structural diagram of an apparatus for preparing a metal catalyst by using plasma according to the present disclosure;
FIG. 2 is an enlarged partial cross-sectional view of an electrode plate adjustment mechanism according to the present invention;
FIG. 3 is a schematic view of a seal seat according to the present invention;
fig. 4 is a block diagram of a process for preparing a metal catalyst using plasma in the present invention.
In the figure: 1. a reaction chamber; 2. a metal plate electrode; 3. a multi-pin electrode; 4. a dielectric plate; 5. an air vent; 6. a catalyst to be treated; 7. an electrode plate adjusting mechanism; 71. a threaded rod; 72. a sealing seat; 721. a first cylinder; 722. a second cylinder; 73. a gasket; 74. a nut;
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in fig. 1, an apparatus for preparing a metal catalyst using plasma, comprising: the reaction chamber 1 is internally provided with a metal plate electrode 2 and a multi-needle electrode 3, the metal plate electrode 2 and the multi-needle electrode 3 are oppositely arranged, a dielectric plate 4 is pressed on the metal plate electrode 2, and the reaction chamber 1 is provided with an air guide hole 5.
The reaction chamber 1 is made of insulating materials such as organic glass and quartz or metal materials such as stainless steel, the reaction chamber 1 is fixed and sealed by the bases up and down, the upper base and the lower base are fixed by bolts, the bases are provided with air guide holes 5, the air guide holes 5 can also be arranged on the side wall of the reaction chamber 1, and carrier gas such as inert gas such as argon and the like or gas such as hydrogen and oxygen and the like which can participate in the reaction can be introduced according to requirements. The multi-pin electrode 3 and the metal plate electrode 2 are respectively connected with the positive electrode and the negative electrode of a power supply, and the power supply can be a pulse power supply, a direct current power supply or an alternating current power supply. The range of the power voltage is 1kV to 40kV, and if the power voltage is pulse discharge, the frequency range is 100Hz to 10000 Hz; the voltage range of the discharge is preferably 15kV to 30kV, and the preferred frequency range of the pulse discharge is 1000Hz to 7000 Hz; the low-frequency pulse discharge is adopted, so that the energy consumption can be effectively reduced, and the preparation efficiency of the catalyst is improved.
The multi-pin electrode 3 is formed by arranging a plurality of pin electrodes on a metal base plate and directing the plurality of pin electrodes toward the metal plate electrode 2, the curvature radius of the pins on the multi-pin electrode 3 is 0.1-0.5 mm, and the density of the pins is 50-100/dm2The multi-needle electrode 3 is made of stainless steel or other metals.
The dielectric plate 4 is made of quartz, ceramics or the like, the area of the dielectric plate 4 is not smaller than that of the metal plate electrode 2, and the thickness of the dielectric plate 4 is 1-5 mm. The catalyst 6 to be treated is placed on the dielectric plate 4, the dielectric plate 4 is pressed against the metal plate electrode 2, the dielectric plate 4 prevents the discharge breakdown of the multi-needle electrode 3, maintains the corona discharge state of the multi-needle electrode 3, and can form dielectric barrier discharge at one end of the dielectric plate 4, and the catalyst 6 to be treated is surface-treated together with the corona discharge formed by the multi-needle electrode 3.
Further, the distance between the end of the multi-pin electrode 3 and the dielectric plate 4 is 1 to 50 mm. In the distance range, the multi-needle electrode 3 carries out corona discharge to treat the catalyst 6 to be treated, and when the distance between the end part of the multi-needle electrode 3 and the dielectric plate 4 is 3-20 mm, the corona discharge treatment effect is better.
Further, as shown in fig. 2, the apparatus further comprises an electrode plate adjusting mechanism 7, the electrode plate adjusting mechanism 7 comprises a threaded rod 71, a sealing seat 72, a washer 73 and a nut 74, as shown in fig. 3, the sealing seat 72 comprises a first cylinder 721 and a second cylinder 722 coaxially and fixedly connected with the first cylinder, through threaded holes are arranged in the first cylinder 721 and the second cylinder 722 and are matched with the threaded rod 71, the first cylinder 721 is arranged in the reaction chamber 1, an opening is arranged at the top of the reaction chamber 1, the diameter of the opening is larger than that of the second cylinder 722 and smaller than that of the first cylinder 721, the second cylinder 722 extends out from the opening at the top of the reaction chamber 1, threads are arranged outside the second cylinder 722 and are matched with the nut 74, the sealing seat 72 is fixed on the reaction chamber 1 through the nut 74, the washer 73 ensures the sealing between the sealing seat 72 and the reaction chamber 1, the multi-needle electrode 2 and the metal plate electrode 3 are fixed at the end, the threaded rod 71 is in threaded connection with the sealing seat 72, and the distance between the multi-pin electrode 2 and the metal plate electrode 3 can be adjusted.
The reaction chamber and the base can be made of insulating materials such as organic glass and quartz, metal materials such as stainless steel can be adopted, and when the metal materials such as stainless steel are adopted, the sealing seat is made of insulating materials such as nylon.
By rotating the threaded rod 71, the distance between the multi-pin electrode 2 and the metal plate electrode 3 can be changed. The distance between the multi-needle electrode 2 and the metal plate electrode 3 is adjusted, so that the discharge intensity between the two electrodes can be changed. The closer the distance between the multi-pin electrode 2 and the metal plate electrode 3 is, the higher the intensity of corona discharge and dielectric barrier discharge is at the same peak voltage.
As shown in fig. 4, a method for preparing a metal catalyst using the above apparatus for preparing a metal catalyst using plasma, comprises the steps of:
step 1: completely immersing the catalyst support in a metal salt solution;
step 2: treating the catalyst carrier by adopting impregnation or ultrasonic impregnation;
and step 3: taking out the catalyst carrier and drying to obtain a catalyst 6 to be treated;
and 4, step 4: uniformly placing a catalyst 6 to be treated on the surface of the dielectric plate 4;
and 5: applying a high voltage to the multi-pin electrode 3 and the metal plate electrode 2;
step 6: corona discharge plasma is generated at the end part of the multi-needle electrode 3, and dielectric barrier discharge plasma is generated on one surface of the dielectric plate 4 facing the multi-needle electrode 3 and acts on the surface of the catalyst 6 to be treated, so that a catalyst finished product is obtained.
Further, step 4 includes introducing a carrier gas through the gas guide hole 5.
The method comprises the following specific implementation processes:
the multi-needle electrode 3 adopts a needle with a curvature radius of 0.3mm and has 75 needles/dm2Evenly distributed, adopt the quartz plate that thickness is 3mm as dielectric plate 4, adopt organic glass to make reaction chamber 1, add the organic glass base from top to bottom and seal with the bolt fastening, set up air guide hole 5 on the base.
Mixing gamma-Al2O3The method comprises the steps of completely immersing the catalyst in an aqueous solution of nickel sulfate and cobalt sulfate, carrying out ultrasonic immersion for 30min, then drying the catalyst in an oven at 80 ℃ for 30min to obtain a catalyst to be treated, uniformly placing the catalyst to be treated on a dielectric plate 4 in a reaction chamber 1, setting the peak voltage of a power supply to be 25kV and the discharge frequency to be 5000Hz, and adjusting the distance between a multi-needle electrode 3 and the dielectric plate 4 to enable the multi-needle electrode 3 to be in a corona discharge state and to uniformly act on the surface of the catalyst to be treated, wherein the distance between the end part of the multi-needle electrode 3 and the dielectric plate 4 is 12 mm. The catalyst to be treated is subjected to discharge treatment under the parameters, corona discharge plasma is generated at the end part of the multi-needle electrode 3, dielectric barrier discharge plasma is generated on one surface, facing the multi-needle electrode 3, of the dielectric plate 4, the plasmas generated from the two aspects act on the surface of the catalyst to be treated, and the catalyst is obtained after 5min of discharge treatmentAnd (5) preparing a finished product.
To verify the efficacy of the finished catalyst, a verification experiment was performed. The obtained catalyst finished product is used for simulating the catalytic modification of the thickened oil, and the experimental result shows that the experimental temperature is 200 ℃, the oil-water volume ratio is 3: 1, after the catalyst is added, compared with the kinematic viscosity of oil without the catalyst, the kinematic viscosity is reduced by 54 percent, the heat value is improved by 4.1 percent, and the yield of light oil after catalytic reaction reaches 87 percent.
The invention adopts the corona-dielectric barrier discharge plasma form, and can effectively avoid the conversion from corona discharge to spark discharge in the discharge form compared with the traditional needle-plate corona discharge; compared with the traditional dielectric barrier discharge, the discharge form can generate more stable and uniform plasma. The method can prepare the catalyst uniformly in a large area in the process of preparing the catalyst by the plasma, and can effectively prevent the catalyst from being excessively sintered; meanwhile, researches find that the catalyst prepared by the method has more uniform particle size distribution, has better performance in the applications of thickened oil modification, hydrogen preparation and the like, and has stronger practical value and application prospect.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111988903A (en) * | 2020-09-29 | 2020-11-24 | 大连理工大学 | A gas-phase packed bed discharge plasma generator |
| CN112945653A (en) * | 2021-04-06 | 2021-06-11 | 中国气象局沈阳大气环境研究所 | Electrostatic aerosol particle sampler |
| CN113318795A (en) * | 2021-06-24 | 2021-08-31 | 大连海事大学 | Device and method for preparing liquid metal catalyst by using plasma |
| CN113423167A (en) * | 2021-06-24 | 2021-09-21 | 大连海事大学 | Device and method for continuously generating large-volume plasma in liquid phase |
| CN114804150A (en) * | 2022-06-02 | 2022-07-29 | 大连海事大学 | Gas-liquid mixed phase discharge plasma ammonia production device and method |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004283742A (en) * | 2003-03-24 | 2004-10-14 | Canon Inc | Plasma treating device and plasma treating method |
| CN1647858A (en) * | 2004-12-01 | 2005-08-03 | 天津大学 | Method for Reducing Supported Metal Catalysts Using Low Temperature Plasma |
| CN103245655A (en) * | 2013-05-20 | 2013-08-14 | 大连理工大学 | Experimental apparatus for acquiring large-area uniform discharge plasmas |
| CN103482720A (en) * | 2013-08-29 | 2014-01-01 | 太原理工大学 | Dielectric barrier discharge water treatment device and method |
| CN103691428A (en) * | 2013-12-26 | 2014-04-02 | 大连大学 | Preparation method of carbon-supported noble metal catalyst |
| CN104645993A (en) * | 2015-02-05 | 2015-05-27 | 昆明理工大学 | Preparation method and application of carbon-based catalyst |
| CN204583165U (en) * | 2015-02-05 | 2015-08-26 | 昆明理工大学 | For the parallel plate type reaction of low temperature plasma device of catalyst surface modification |
| CN104891436A (en) * | 2015-05-22 | 2015-09-09 | 大连海事大学 | Liquid phase pulse discharge hydrogen production device and hydrogen production method |
| CN110317636A (en) * | 2019-07-29 | 2019-10-11 | 大连海事大学 | A kind of method and apparatus using discharge in water add in-place hydrogen upgrading heavy oil feedstock |
| CN110408421A (en) * | 2019-07-29 | 2019-11-05 | 大连海事大学 | A kind of method of utilizing liquid phase discharge to upgrade heavy oil raw material |
-
2019
- 2019-12-06 CN CN201911242257.7A patent/CN110918028A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004283742A (en) * | 2003-03-24 | 2004-10-14 | Canon Inc | Plasma treating device and plasma treating method |
| CN1647858A (en) * | 2004-12-01 | 2005-08-03 | 天津大学 | Method for Reducing Supported Metal Catalysts Using Low Temperature Plasma |
| CN103245655A (en) * | 2013-05-20 | 2013-08-14 | 大连理工大学 | Experimental apparatus for acquiring large-area uniform discharge plasmas |
| CN103482720A (en) * | 2013-08-29 | 2014-01-01 | 太原理工大学 | Dielectric barrier discharge water treatment device and method |
| CN103691428A (en) * | 2013-12-26 | 2014-04-02 | 大连大学 | Preparation method of carbon-supported noble metal catalyst |
| CN104645993A (en) * | 2015-02-05 | 2015-05-27 | 昆明理工大学 | Preparation method and application of carbon-based catalyst |
| CN204583165U (en) * | 2015-02-05 | 2015-08-26 | 昆明理工大学 | For the parallel plate type reaction of low temperature plasma device of catalyst surface modification |
| CN104891436A (en) * | 2015-05-22 | 2015-09-09 | 大连海事大学 | Liquid phase pulse discharge hydrogen production device and hydrogen production method |
| CN110317636A (en) * | 2019-07-29 | 2019-10-11 | 大连海事大学 | A kind of method and apparatus using discharge in water add in-place hydrogen upgrading heavy oil feedstock |
| CN110408421A (en) * | 2019-07-29 | 2019-11-05 | 大连海事大学 | A kind of method of utilizing liquid phase discharge to upgrade heavy oil raw material |
Non-Patent Citations (1)
| Title |
|---|
| 储伟: "《催化剂工程》", 30 September 2006, 四川大学出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111988903A (en) * | 2020-09-29 | 2020-11-24 | 大连理工大学 | A gas-phase packed bed discharge plasma generator |
| CN112945653A (en) * | 2021-04-06 | 2021-06-11 | 中国气象局沈阳大气环境研究所 | Electrostatic aerosol particle sampler |
| CN113318795A (en) * | 2021-06-24 | 2021-08-31 | 大连海事大学 | Device and method for preparing liquid metal catalyst by using plasma |
| CN113423167A (en) * | 2021-06-24 | 2021-09-21 | 大连海事大学 | Device and method for continuously generating large-volume plasma in liquid phase |
| CN113318795B (en) * | 2021-06-24 | 2023-07-14 | 大连海事大学 | Device and method for preparing liquid metal catalyst by plasma |
| CN114804150A (en) * | 2022-06-02 | 2022-07-29 | 大连海事大学 | Gas-liquid mixed phase discharge plasma ammonia production device and method |
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