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CN110327770A - A kind of composition and its preparation method except formaldehyde - Google Patents

A kind of composition and its preparation method except formaldehyde Download PDF

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Publication number
CN110327770A
CN110327770A CN201910465337.2A CN201910465337A CN110327770A CN 110327770 A CN110327770 A CN 110327770A CN 201910465337 A CN201910465337 A CN 201910465337A CN 110327770 A CN110327770 A CN 110327770A
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Prior art keywords
composition
formaldehyde
lignin
solution
tea polyphenols
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Inventor
孙立林
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Tianjin Qingrun Environmental Protection Technology Development Co Ltd
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Tianjin Qingrun Environmental Protection Technology Development Co Ltd
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Priority to CN201910465337.2A priority Critical patent/CN110327770A/en
Publication of CN110327770A publication Critical patent/CN110327770A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/82Solid phase processes with stationary reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The present invention provides a kind of compositions and its preparation method except formaldehyde.The composition for removing formaldehyde is mainly made of lignin, persimmon tannin and tea polyphenols that mass ratio is 5-7:14-18:2-6;Composition provided by the invention except formaldehyde can effectively remove formaldehyde, 90% formaldehyde can be removed in 48h, and low in cost.

Description

A kind of composition and its preparation method except formaldehyde
Technical field
The invention belongs to amenities technical field, in particular to a kind of composition and its preparation method except formaldehyde.
Background technique
Formaldehyde is colourless gas, also known as formaldehyde, has irritation to the skin and mucosa of human body, when concentration of formaldehyde is greater than 0.08m3When, it can cause to be envious, eye is itched, delays the symptoms such as discomfort, can induce a variety of diseases, even result in fetal anomaly, especially Its house just fitted up, often needing to be vented to can move in not a half year or more, or ask professional remove in formaldehyde mechanism decontamination chamber Formaldehyde, but somewhat expensive.
Summary of the invention
In order to solve the above technical problems, formaldehyde should be removed the present invention provides a kind of composition and its preparation method except formaldehyde Composition can be disposed in 48h 90% or more formaldehyde.
Specific technical solution of the present invention is as follows:
The present invention provides a kind of compositions except formaldehyde, should be mainly 5-7:14- by mass ratio except the composition of formaldehyde Lignin, persimmon tannin and the tea polyphenols composition of 18:2-6.
The present invention prepares composition using lignin, persimmon tannin and tea polyphenols, can play synergistic effect between each component, Formaldehyde is rapidly removed, and low-cost, meets the demand of users.
Further, it is made of except the composition of formaldehyde lignin, persimmon tannin and the tea polyphenols that mass ratio is 3:8:2.
Further, composition further includes myrtenol, bisabolene and honey, the lignin, persimmon tannin, tea Polyphenol and the myrtenol, bisabolene, honey mass ratio be 5-7:14-18:2-6:3-5:1-2:2-3.
The present invention passes through is added myrtenol, bisabolene and honey in the composition, acts synergistically between each ingredient, into The effect of composition removing formaldehyde is improved to one step, while having the effect of degerming.
Further, for lignin using preceding being ground, the diameter after grinding is 100-200 μm.
The present invention can further improve the effect of composition removing formaldehyde by the diameter of restriction lignin.
The present invention also provides a kind of formaldehyde scavengers, including composition and auxiliary material, wherein the quality of composition and auxiliary material Than for 40-50:5-7.
The formaldehyde scavenger be it is powdered, when use, can be placed on PARA FORMALDEHYDE PRILLS(91,95) in the room containing formaldehyde and be adsorbed Removal.
Further, it is the sodium bicarbonate of 2-4:6-10:3-5, fatty alcohol polyoxyethylene ether and ten that auxiliary material, which includes mass ratio, Dialkyl sulfonates.
The present invention can be improved the stability of composition by adding the above auxiliary material.
Further, composition the preparation method comprises the following steps: the persimmon tannin of definite quality ratio and tea polyphenols is taken to be placed in container It is interior, 20-30min is stirred under conditions of 70-75 DEG C, 400-500rpm after adding water, amount of water is that persimmon tannin and tea polyphenols are total Mixed solution is made in 3-5 times of quality, and mixed solution is continued to stir to mixed under conditions of 95-100 DEG C, 800-1000rpm The volume for closing solution is the 1/5-1/3 of original volume, adjusts pH to 5.5-5.8, concentrate is made, be down to room temperature, and regulation matter is added The lignin for measuring ratio stirs 10-12min under conditions of room temperature, 2000-3000rpm, and concentration, drying are to powder to get combination Object.
The composition that the present invention is prepared by above method can further extend the action time of composition.
Further, preparation method the following steps are included:
(1) persimmon tannin and tea polyphenols for taking definite quality ratio are placed in container, are added after water in 70-75 DEG C, 400- 20-30min is stirred under conditions of 500rpm, amount of water is 3-5 times of persimmon tannin and tea polyphenols gross mass, and it is molten to be made first Liquid;
(2) honey, myrtenol and bisabolene of definite quality ratio is taken to be placed in container, at normal temperature with The speed of 4000-6000rpm stirs 20-30min, and the second solution is made;
(3) the second solution is mixed with the first solution, and stirs 50-60min under conditions of 200-300rpm, be made the Three solution;
(4) continuing third solution under conditions of 95-100 DEG C, 800-1000rpm to stir to the volume of solution is substance Long-pending 1/5-1/3 adjusts pH to 5.5-5.8, and concentrate is made, and is down to room temperature, the lignin of definite quality ratio is added, in room 10-12min is stirred under conditions of temperature, 2000-3000rpm, concentration, drying are to powder to get composition.
It is long-acting that the present invention by above method achievees the purpose that composition.
Composition provided by the invention except formaldehyde can effectively remove formaldehyde, and 90% formaldehyde can be removed in 48h, and It is low in cost.
Specific embodiment
Embodiment 1
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 5g lignin, 18g persimmon tannin and 2g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 100 μm;
Wherein, composition the preparation method comprises the following steps: the persimmon tannin of definite quality ratio and tea polyphenols is taken to be placed in container, add 20min is stirred after water under conditions of 70 DEG C, 400rpm, amount of water is 3 times of persimmon tannin and tea polyphenols gross mass, is made mixed Solution is closed, mixed solution is continued to stir under conditions of 95 DEG C, 800rpm to the volume of mixed solution is the 1/5 of original volume, PH to 5.5 is adjusted, concentrate is made, is down to room temperature, the lignin of definite quality ratio is added, under conditions of room temperature, 2000rpm 10min is stirred, concentration, drying are to powder to get composition.
Embodiment 2
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g lignin, 16g persimmon tannin and 4g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 150 μm;
Wherein, composition the preparation method comprises the following steps: the persimmon tannin of definite quality ratio and tea polyphenols is taken to be placed in container, add 25min is stirred after water under conditions of 72 DEG C, 450rpm, amount of water is 4 times of persimmon tannin and tea polyphenols gross mass, is made mixed Solution is closed, mixed solution is continued to stir under conditions of 98 DEG C, 900rpm to the volume of mixed solution is the 1/4 of original volume, PH to 5.6 is adjusted, concentrate is made, is down to room temperature, the lignin of definite quality ratio is added, under conditions of room temperature, 2500rpm 11min is stirred, concentration, drying are to powder to get composition.
Embodiment 3
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 7g lignin, 14g persimmon tannin and 6g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 200 μm;
Wherein, composition the preparation method comprises the following steps: the persimmon tannin of definite quality ratio and tea polyphenols is taken to be placed in container, add 30min is stirred after water under conditions of 75 DEG C, 500rpm, amount of water is 5 times of persimmon tannin and tea polyphenols gross mass, is made mixed Solution is closed, mixed solution is continued to stir under conditions of 100 DEG C, 1000rpm to the volume of mixed solution is the 1/ of original volume 3, pH to 5.8 is adjusted, concentrate is made, is down to room temperature, the lignin of definite quality ratio is added, in room temperature, the condition of 3000rpm Lower stirring 12min, concentration, drying are to powder to get composition.
Embodiment 4
A kind of composition except formaldehyde, the composition includes 5g lignin, 18g persimmon tannin, 2g tea polyphenols, 3g hill gooseberry Enol, 2g bisabolene and 2g honey;
Wherein, for lignin using preceding being ground, the diameter after grinding is 100 μm;
Wherein, composition preparation method the following steps are included:
(1) persimmon tannin and tea polyphenols for taking definite quality ratio are placed in container, are added after water in 70 DEG C, the item of 400rpm 20min is stirred under part, amount of water is 3 times of persimmon tannin and tea polyphenols gross mass, and the first solution is made;
(2) honey, myrtenol and bisabolene of definite quality ratio is taken to be placed in container, at normal temperature with The speed of 4000rpm stirs 20min, and the second solution is made;
(3) the second solution is mixed with the first solution, and stirs 50min under conditions of 200rpm, third solution is made;
(4) continuing third solution under conditions of 95 DEG C, 800rpm to stir to the volume of solution is the 1/5 of original volume, PH to 5.5 is adjusted, concentrate is made, is down to room temperature, the lignin of definite quality ratio is added, under conditions of room temperature, 2000rpm 10min is stirred, concentration, drying are to powder to get composition.
Embodiment 5
A kind of composition except formaldehyde, the composition includes 6g lignin, 16g persimmon tannin, 4g tea polyphenols, 4g hill gooseberry Enol, 1.5g bisabolene and 2.5g honey;
Wherein, for lignin using preceding being ground, the diameter after grinding is 100 μm.
Wherein, composition preparation method the following steps are included:
(1) persimmon tannin and tea polyphenols for taking definite quality ratio are placed in container, are added after water in 72 DEG C, the item of 450rpm 25min is stirred under part, amount of water is 4 times of persimmon tannin and tea polyphenols gross mass, and the first solution is made;
(2) honey, myrtenol and bisabolene of definite quality ratio is taken to be placed in container, at normal temperature with The speed of 4500rpm stirs 25min, and the second solution is made;
(3) the second solution is mixed with the first solution, and stirs 55min under conditions of 250rpm, third solution is made;
(4) continuing third solution under conditions of 98 DEG C, 900rpm to stir to the volume of solution is the 1/4 of original volume, PH to 5.7 is adjusted, concentrate is made, is down to room temperature, the lignin of definite quality ratio is added, under conditions of room temperature, 2500rpm 11min is stirred, concentration, drying are to powder to get composition.
Embodiment 6
A kind of composition except formaldehyde, the composition includes 7g lignin, 14g persimmon tannin, 6g tea polyphenols, 5g hill gooseberry Enol, 1g bisabolene and 3g honey;
Wherein, for lignin using preceding being ground, the diameter after grinding is 100 μm.
Wherein, composition preparation method the following steps are included:
(1) persimmon tannin and tea polyphenols for taking definite quality ratio are placed in container, are added after water in 75 DEG C, the item of 500rpm 30min is stirred under part, amount of water is 5 times of persimmon tannin and tea polyphenols gross mass, and the first solution is made;
(2) honey, myrtenol and bisabolene of definite quality ratio is taken to be placed in container, at normal temperature with The speed of 6000rpm stirs 30min, and the second solution is made;
(3) the second solution is mixed with the first solution, and stirs 60min under conditions of 300rpm, third solution is made;
Third solution is continued to stir under conditions of 100 DEG C, 1000rpm to the volume of solution is the 1/3 of original volume, is adjusted Concentrate is made in whole pH to 5.8, is down to room temperature, and the lignin of definite quality ratio is added, stirs under conditions of room temperature, 3000rpm 12min is mixed, concentration, drying are to powder to get composition.
Embodiment 7
A kind of formaldehyde scavenger, the scavenger include 40g composition and 7g auxiliary material, in the embodiment ingredient of composition and Preparation method is same as Example 1, and auxiliary material includes 1g sodium bicarbonate, 4.5g fatty alcohol polyoxyethylene ether and 1.5g dodecyl sodium sulfonate Sodium.
Embodiment 8
A kind of formaldehyde scavenger, the scavenger include 45g composition and 6g auxiliary material, in the embodiment ingredient of composition and Preparation method is same as Example 2, and auxiliary material includes 1.5g sodium bicarbonate, 2.5g fatty alcohol polyoxyethylene ether and 2g dodecyl sodium sulfonate Sodium.
Embodiment 9
A kind of formaldehyde scavenger, the scavenger include 50g composition and 5g auxiliary material, in the embodiment ingredient of composition and Preparation method is same as Example 3, and auxiliary material includes 1g sodium bicarbonate, 3g fatty alcohol polyoxyethylene ether and 1g dodecyl sodium sulfate.
Reference examples 1
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g lignin, 16g tea tannin and 4g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 150 μm;
The preparation method of the composition is same as Example 2.
Reference examples 2
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g lignin, 16g hamameli tannin and 4g tea polyphenols Composition;
Wherein, for lignin using preceding being ground, the diameter after grinding is 150 μm;
The preparation method of the composition is same as Example 2.
Reference examples 3
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g cellulose, 16g persimmon tannin and 4g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 150 μm;
The preparation method of the composition is same as Example 2.
Reference examples 4
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g lignin, 16g persimmon tannin and 4g anthocyanidin group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 300 μm;
The preparation method of the composition is same as Example 2.
Reference examples 5
A kind of composition except formaldehyde, should be except the composition of formaldehyde be by 6g lignin, 16g persimmon tannin and 4g tea polyphenols group At;
Wherein, for lignin using preceding being ground, the diameter after grinding is 60 μm;
Wherein, composition the preparation method comprises the following steps: the persimmon tannin of definite quality ratio, tea polyphenols and lignin is taken to be placed in appearance In device, 25min is stirred under conditions of 72 DEG C, 450rpm after adding water, mixed solution is made, amount of water is that persimmon tannin and tea are more Mixed solution is concentrated under conditions of 98 DEG C, 900rpm, dries to powder to get composition by 4 times of phenol gross mass.
Test example 1 removes formaldehyde performance test
Formaldehyde is measured according to national standard QB-T2761-2006 " indoor air purification product clean-up effect measuring method ", by 33 A blank cabin is divided into blank group, test 1-3 group and control 1-7 group, every group of 3 blank cabins, tests 1-3 group and control 1-7 component Embodiment 3-5, the composition of reference examples 1-5 and the reality of Chinese patent CN101607174A are placed not under room temperature, air-proof condition Example 3, embodiment 5 are applied, each group usage amount is 100g, and the window that blank group opens two 1 square metre is aerated, respectively 48 The concentration of formaldehyde in each group blank cabin is detected after hour and half a year, and calculates formaldehyde removal rate, formaldehyde removal rate=(initial formaldehyde The final concentration of formaldehyde of concentration -)/initial concentration of formaldehyde × 100%, formaldehyde removal rate when being detected after half a year=(first at five months Concentration of formaldehyde at aldehyde concentration-six months)/five months when concentration of formaldehyde × 100%, each group of data is averaged, measurement result It is shown in Table 1.
The formaldehyde removal rate of 1. each group composition of table measures test result
As shown in Table 1, composition provided by the invention can effectively remove formaldehyde, the formaldehyde removal rate in 48h Up to 90% or more, and the removal rate of PARA FORMALDEHYDE PRILLS(91,95) is still not less than 47% after half a year, is higher than each control group significantly, when replacement is appointed One ingredient or when changing preparation method, except the effect of formaldehyde is remarkably decreased, it was demonstrated that in composition provided by the invention respectively at point it Between act synergistically, improve the effect except formaldehyde significantly, and low in cost.
The test of 2 bactericidal property of test example
1. preparing culture medium
1.1 preparation PBS buffer solution: the beaker of 1000ml is taken, 36g phosphoric acid dioxy potassium and 2.83g phosphoric acid hydrogen two are separately added into Sodium adds 1000ml distilled water and is stirred, and until completely dissolved, reuses sodium hydroxide solution and adjusts pH to 7.2-7.4, It is spare in 121 DEG C of pressuresteam sterilization 20min;
1.2 preparation Escherichia coli, staphylococcus aureus solid medium: beaker is taken, 10g tryptone, 5g chlorine is added Change sodium, 5g beef extract and 20g agar powder, add 1000ml distilled water and stir evenly, adjust pH value 7.2-7.4, dissolves by heating After be placed in high-pressure steam sterilizing pan, in 121 DEG C of sterilizing 30min.
2. antibacterial ring size is tested
2.1 prepare bacteria inhibition tablet: taking sterile filter paper to be divided into test 4-7 group, the filter paper difference of 4-7 group is tested after dry The composition of 20 μ l embodiment 3-6 is added dropwise, each group filter paper is lain against in sterilized petri dishes, then sterilized petri dishes are put into 37 DEG C Dry spare in incubator, every group is done 5 Duplicate Samples;
2.2 preparation control prints: it will be used as blank group after aseptic filter paper piece drying, 20 μ l is added dropwise in aseptic filter paper on piece and form sediment Powder solution, will be spare after filter paper drying;
2.3 inoculation experiments bacterium: dipping Escherichia coli and staphylococcus aureus solid medium with sterile cotton balls respectively, Wherein, the concentration of Escherichia coli and staphylococcus aureus solid medium is 5 × 105cfu/ml-5×106The range of cfu/ml It is interior, the sterile cotton for dipping Escherichia coli and staphylococcus aureus solid medium is placed in the table of nutrient agar plate Face is equably smeared 3 times, the pivotal plate after smearing, and the angle of plate rotation is 60 °, with sterile cotton on the side of culture medium flat plate Edge smears a circle, covers plate, and plate is dried 5min at room temperature;
2.4 iron side's bacteriostatic agent prints: bacteria inhibition tablet and control print are clamped respectively with sterile tweezers, is placed with the table in plate Face adjusts the distance between adjacent bacteria inhibition tablet or control print central point to 25-30mm, while adjusting each bacteria inhibition tablet and right The distance between piece and plate periphery are 15-20mm in the same old way, are then placed with bacteria inhibition tablet and control print with sterile tweezers In the surface of plate, then glass dish is covered, with insulating box culture, the temperature of insulating box is adjusted to 37 DEG C, and incubation time is 24 small When, observe test result, and with measure antibacterial ring size diameter, do 5 parallel tests, each group of data is averaged, the results are shown in Table 2。
Wherein, the diametrically-filter paper diameter of antibacterial ring size=outside, when measurement need to select uniformly, the suppression of integral asepsis growth Collarium measures, and diameter should be using the outer of antibacterial ring size as boundary;When inhibition zone diameter be greater than 7mm, be determined as by bacteriostasis, When inhibition zone diameter be less than or equal to 7mm, be determined as no bacteriostasis;The test method is referring to Chinese patent 201810385825.8 test method.
2. antibacterial ring size experimental result of table
As shown in Table 2, the present invention can be into one after providing addition myrtenol, bisabolene, honey in the composition Step plays bactericidal effect, it was demonstrated that acts synergistically between each ingredient in composition provided by the invention, has removal effect of formaldehyde While also have the effect of sterilization.
3 stability of embodiment
It each three groups of the formaldehyde scavenger of Example 7-9, places 2 years at room temperature, observes the face of each group formaldehyde scavenger Color, smell simultaneously carry out assay, as a result, it has been found that, after each group formaldehyde scavenger is placed 2 years, color and smell do not change, Assay is the results show that active constituent content is above 95%, it was demonstrated that after auxiliary material is added, improves the stabilization of formaldehyde scavenger Property.
To sum up, only the preferred embodiments of the invention, is not limited the scope of protection of the present invention with this, all according to the invention patent Equivalent changes and modifications made by range and description are all within the scope of the invention patent covers.

Claims (9)

1. a kind of composition except formaldehyde, which is characterized in that the composition except formaldehyde is mainly 5-7:14- by mass ratio Lignin, persimmon tannin and the tea polyphenols composition of 18:2-6.
2. removing the composition of formaldehyde as described in claim 1, which is characterized in that the composition except formaldehyde is by mass ratio Lignin, persimmon tannin and the tea polyphenols composition of 3:8:2.
3. as described in claim 1 remove formaldehyde composition, which is characterized in that the composition further include myrtenol, Bisabolene and honey, the lignin, persimmon tannin, tea polyphenols, water and the myrtenol, bisabolene, honey Mass ratio is 5-7:14-18:2-6:3-5:1-2:2-3.
4. removing the composition of formaldehyde as described in claim 1, which is characterized in that the lignin is ground using preceding being ground Diameter after mill is 100-200 μm.
5. a kind of formaldehyde scavenger, which is characterized in that including composition of any of claims 1 or 2 and auxiliary material, the composition Mass ratio with auxiliary material is 40-50:5-7.
6. formaldehyde scavenger as claimed in claim 5, which is characterized in that the auxiliary material includes that mass ratio is 2-4:6-10:3-5 Sodium bicarbonate, fatty alcohol polyoxyethylene ether and dodecyl sodium sulfate.
7. a kind of composition as claimed in claim 1 or 2, which is characterized in that the composition the preparation method comprises the following steps: taking regulation The persimmon tannin and tea polyphenols of mass ratio are placed in container, are stirred under conditions of 70-75 DEG C, 400-500rpm after adding water 20-30min, amount of water are 3-5 times of persimmon tannin and tea polyphenols gross mass, mixed solution are made, by mixed solution in 95- 100 DEG C, continue to stir to the volume of mixed solution under conditions of 800-1000rpm be original volume 1/5-1/3, adjustment pH is extremely Concentrate is made in 5.5-5.8, is down to room temperature, the lignin of definite quality ratio is added, in room temperature, the condition of 2000-3000rpm Lower stirring 10-12min, concentration, drying are to powder to get composition.
8. composition as claimed in claim 3, which is characterized in that the preparation method comprises the following steps:
(1) persimmon tannin and tea polyphenols for taking definite quality ratio are placed in container, are added after water in 70-75 DEG C, 400-500rpm Under conditions of stir 20-30min, amount of water is 3-5 times of persimmon tannin and tea polyphenols gross mass, obtained first solution;
(2) honey, myrtenol and bisabolene of definite quality ratio is taken to be placed in container, at normal temperature with 4000- The speed of 6000rpm stirs 20-30min, and the second solution is made;
(3) the second solution is mixed with the first solution, and stirs 50-60min under conditions of 200-300rpm, it is molten that third is made Liquid;
(4) continuing third solution under conditions of 95-100 DEG C, 800-1000rpm to stir to the volume of solution is original volume , adjust pH to 5.5-5.8, concentrate be made, is down to room temperature, the lignin of definite quality ratio is added, room temperature, 10-12min is stirred under conditions of 2000-3000rpm, concentration, drying are to powder to get composition.
9. the application of any of claims 1 or 2 except the composition of formaldehyde in the product that preparation has except effect of formaldehyde.
CN201910465337.2A 2019-05-30 2019-05-30 A kind of composition and its preparation method except formaldehyde Withdrawn CN110327770A (en)

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