CN110241628A - A kind of anti-soda acid functional fabric of flame-retardant and anti-static and preparation method thereof - Google Patents
A kind of anti-soda acid functional fabric of flame-retardant and anti-static and preparation method thereof Download PDFInfo
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- CN110241628A CN110241628A CN201910433701.7A CN201910433701A CN110241628A CN 110241628 A CN110241628 A CN 110241628A CN 201910433701 A CN201910433701 A CN 201910433701A CN 110241628 A CN110241628 A CN 110241628A
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- soda acid
- preparation
- base fabric
- fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 48
- 239000002253 acid Substances 0.000 title claims abstract description 40
- 239000003063 flame retardant Substances 0.000 title claims abstract description 31
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 28
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000002105 nanoparticle Substances 0.000 claims abstract description 11
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000006184 cosolvent Substances 0.000 claims abstract description 8
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 12
- 229920006231 aramid fiber Polymers 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 7
- 238000004026 adhesive bonding Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 238000009941 weaving Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 6
- 239000004753 textile Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 241000700605 Viruses Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B9/00—Solvent-treatment of textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
- D06N2201/0272—Aromatic polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/041—Conductive
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/046—Anti-static
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/126—Permeability to liquids, absorption
- D06N2209/128—Non-permeable
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- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
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- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses anti-soda acid functional fabric of a kind of flame-retardant and anti-static and preparation method thereof, which is to be sequentially prepared anti-soda acid layer in scrim surfaces and waterproof and oilproof layer obtains;Wherein base fabric is made of using fire resistance fibre and conductive fiber, the raw material of anti-soda acid layer includes: methyl acrylate, octadecyl acrylate, surfactant, polytetrafluoroethylene (PTFE), nanoparticle, silica, cosolvent and water, and the raw material of waterproof and oilproof layer is PK591 finishing agent.Fabric of the invention not only has permanent fire-retardant, anti-static function, also has the function of good anti-soda acid.
Description
Technical field
The invention belongs to function protecting field of fabric producing technology, and in particular to a kind of flame-retardant and anti-static anti-soda acid functionality face
Material and preparation method thereof.
Background technique
Functional protective textile refers to textile other than with itself use value, also has antibacterial, fire-retardant, anti-
The other functions such as mould, anti-soda acid, water and oil repellant, antiultraviolet, antistatic.With the continuous development of industrial technology, people are in work
Make and will inevitably face in living the threat of fire, electrostatic, strong acid, highly basic and virus etc., functionality protection is spun
Fabric is threatened and is widely used in relevant special industry precisely in order to resisting these.In recent years, with functional textile
Product are continually developed, gradually developed to by original simple function it is multi-functional compound, by simple auxiliary agent arrangement develop to
Processing is modified to fiber, technique and technology are all being constantly progressive.
Fire-retardant, antistatic, anti-soda acid multifunctional fabric, which is that special industry is required, a kind of to gather multi -function in integral whole
Composite functional fabric, the function protecting fabric of simple function has been unable to satisfy demand currently on the market.It is mostly anti-soda acid fabric
By doing the extraordinary final finishing of water and oil repellant and anti-soda acid on the basis of common dyeing fabric, but general acid-proof alkaline agent uses
It will affect its flame retardant effect on inflaming retarding fabric surface, it is therefore desirable to if considered on the basis of guaranteeing fire-retardant and antistatic effect
Further realize anti-soda acid effect.
Summary of the invention
The object of the present invention is to provide anti-soda acid functional fabrics of a kind of flame-retardant and anti-static and preparation method thereof, not only have
Permanent fire-retardant, anti-static function also has the function of good anti-soda acid.
A kind of anti-soda acid functional fabric of flame-retardant and anti-static successively includes base fabric, anti-soda acid layer and waterproof and oilproof layer;
The raw material of the base fabric includes fire resistance fibre and conductive fiber;
The raw material of the anti-soda acid layer includes: methyl acrylate, octadecyl acrylate, surfactant, polytetrafluoroethylene (PTFE), nanometer
Particle, silica, cosolvent and water;
The raw material of the waterproof and oilproof layer includes: PK591 finishing agent.
The preparation method of the above-mentioned anti-soda acid functional fabric of flame-retardant and anti-static, comprising the following steps:
Step 1, blended using aramid fiber 1313, Fanglun l414 fiber and flame retardant polyester fiber, and looping electrically conductive filament, weaving
Base fabric is made;
Step 2, in parts by weight, 50-70 parts of methyl acrylate, 30-60 parts of octadecyl acrylate, surfactant 10-20 are taken
Divide, 5-10 parts of polytetrafluoroethylene (PTFE), 5-10 parts of nanoparticle, 3-5 parts of silica, 30-40 parts of cosolvent, 80-120 parts of water, mixes
It closes, anti-soda acid gluing is made, is then applied directly to scrim surfaces, dry;
Step 3, by step 2, treated that base fabric is placed in the finishing fluid of the finishing agent containing PK591 pads;
Step 4, by step 3 treated base fabric drying, sizing to get.
Further, in step 1 each raw material of base fabric mass percent are as follows: aramid fiber 1313 70-80%, Fanglun l414
Fiber 5-10%, flame retardant polyester fiber 10-20%, electrically conductive filament 1-3%, the sum of mass percent of all raw materials are 100%.
Further, in step 2 nanoparticle be nano aluminium oxide, nano-titanium oxide and nano zircite composition.
Further, drying condition is 120-150 DEG C, 1min in step 2.
Further, the concentration of PK591 finishing agent is 35-45g/L, pick-up 65-75% in finishing fluid in step 3.
Further, drying condition is 120-140 DEG C, 1.5-2min in step 4, and styling condition is 180-200 DEG C and bakes
1.6-2.1min。
The present invention uses fire resistance fibre for primary raw material, and mixes electrically conductive filament and base fabric is made, and has fabric permanent
Fire-retardant, anti-static function;By being sequentially prepared anti-soda acid layer and waterproof and oilproof layer in base fabric outer surface, on the one hand can be formed has
The film layer of anti-soda acid effect effectively plays the effect of anti-soda acid, and on the other hand outermost waterproof and oilproof layer can further drop
The surface energy of bottom surface material achievees the effect that refusing acid refuses alkali.
Specific embodiment
Technical solution of the present invention is further described combined with specific embodiments below.
Embodiment 1
The preparation method of the anti-soda acid functional fabric of flame-retardant and anti-static, comprising the following steps:
Step 1, blended using aramid fiber 1313, Fanglun l414 fiber and flame retardant polyester fiber, and looping electrically conductive filament, weaving
Base fabric, the mass percent of each raw material are as follows: aramid fiber 1313 70%, Fanglun l414 fiber 10%, flame retardant polyester fiber is made
18%, electrically conductive filament 2%;
Step 2, in parts by weight, 50 parts of methyl acrylate, 40 parts of octadecyl acrylate, surfactant 12 is taken to divide, polytetrafluoro
7 parts of ethylene, 6 parts of nanoparticle, 4 parts of silica, 32 parts of cosolvent, 90 parts of water, mixing, are made anti-soda acid gluing, then will
It is applied directly to scrim surfaces, and anti-soda acid layer is made in 120-150 DEG C of drying 1min;
Step 3, it will pad, roll in the finishing fluid of step 2 treated base fabric is placed in concentration is 35-45g/L PK591 finishing agent
Remaining rate is 65-75%;
Step 4, step 3 treated base fabric is baked into sizing 1.6- through 120-140 DEG C 1.5-2min, 180-200 DEG C of drying
2.1min to get.
Wherein, in step 2 nanoparticle be nano aluminium oxide, nano-titanium oxide and nano zircite composition, three
Dosage be 1:1:0.5.
Embodiment 2
The preparation method of the anti-soda acid functional fabric of flame-retardant and anti-static, comprising the following steps:
Step 1, blended using aramid fiber 1313, Fanglun l414 fiber and flame retardant polyester fiber, and looping electrically conductive filament, weaving
Be made base fabric, the mass percent of each raw material are as follows: aramid fiber 1313 75%, Fanglun l414 fiber 7%, flame retardant polyester fiber 16%,
Electrically conductive filament 2%;
Step 2, in parts by weight, 60 parts of methyl acrylate, 50 parts of octadecyl acrylate, surfactant 17 is taken to divide, polytetrafluoro
8 parts of ethylene, 7 parts of nanoparticle, 3 parts of silica, 37 parts of cosolvent, 80 parts of water, mixing, are made anti-soda acid gluing, then will
It is applied directly to scrim surfaces, and anti-soda acid layer is made in 120-150 DEG C of drying 1min;
Step 3, it will pad, roll in the finishing fluid of step 2 treated base fabric is placed in concentration is 35-45g/L PK591 finishing agent
Remaining rate is 65-75%;
Step 4, step 3 treated base fabric is baked into sizing 1.6- through 120-140 DEG C 1.5-2min, 180-200 DEG C of drying
2.1min to get.
Wherein, in step 2 nanoparticle be nano aluminium oxide, nano-titanium oxide and nano zircite composition, three
Dosage be 2:1:1.
Embodiment 3
The preparation method of the anti-soda acid functional fabric of flame-retardant and anti-static, comprising the following steps:
Step 1, blended using aramid fiber 1313, Fanglun l414 fiber and flame retardant polyester fiber, and looping electrically conductive filament, weaving
Be made base fabric, the mass percent of each raw material are as follows: aramid fiber 1313 80%, Fanglun l414 fiber 7%, flame retardant polyester fiber 10%,
Electrically conductive filament 3%;
Step 2, in parts by weight, 60 parts of methyl acrylate, 50 parts of octadecyl acrylate, surfactant 17 is taken to divide, polytetrafluoro
6 parts of ethylene, 7 parts of nanoparticle, 3 parts of silica, 36 parts of cosolvent, 100 parts of water, mixing, are made anti-soda acid gluing, then will
It is applied directly to scrim surfaces, and anti-soda acid layer is made in 120-150 DEG C of drying 1min;
Step 3, it will pad, roll in the finishing fluid of step 2 treated base fabric is placed in concentration is 35-45g/L PK591 finishing agent
Remaining rate is 65-75%;
Step 4, step 3 treated base fabric is baked into sizing 1.6- through 120-140 DEG C 1.5-2min, 180-200 DEG C of drying
2.1min to get.
Wherein, in step 2 nanoparticle be nano aluminium oxide, nano-titanium oxide and nano zircite composition, three
Dosage be 1:1:0.5.
The fabric flame retardant property that the present invention obtains meets GB/T17591-2006 flame-retardant textile standard, and char length≤
150mm, after flame time≤5s, duration of fire resistance≤5s.
The fabric antistatic performance that the present invention obtains meets GB12014-2009 antistatic clothing standard, and point-to-point resistance is 1
×105-1×107Ω。
The anti-acid-base property of the fabric that the present invention obtains can meet GB24540-2009 protective clothes acid-base class chemical protection clothes
Standard, strong acid-base resistance, acid and alkali-resistance time of break-through are long, and resistance to acid fracturing is high, wash resistant.
Claims (7)
1. a kind of anti-soda acid functional fabric of flame-retardant and anti-static, it is characterised in that: successively include that base fabric, anti-soda acid layer and waterproof are anti-
Oil reservoir;
The raw material of the base fabric includes fire resistance fibre and conductive fiber;
The raw material of the anti-soda acid layer includes: methyl acrylate, octadecyl acrylate, surfactant, polytetrafluoroethylene (PTFE), nanometer
Particle, silica, cosolvent and water;
The raw material of the waterproof and oilproof layer includes: PK591 finishing agent.
2. the preparation method of the anti-soda acid functional fabric of flame-retardant and anti-static described in claim 1, it is characterised in that: including following
Step:
Step 1, blended using aramid fiber 1313, Fanglun l414 fiber and flame retardant polyester fiber, and looping electrically conductive filament, weaving
Base fabric is made;
Step 2, in parts by weight, 50-70 parts of methyl acrylate, 30-60 parts of octadecyl acrylate, surfactant 10-20 are taken
Divide, 5-10 parts of polytetrafluoroethylene (PTFE), 5-10 parts of nanoparticle, 3-5 parts of silica, 30-40 parts of cosolvent, 80-120 parts of water, mixes
It closes, anti-soda acid gluing is made, is then applied directly to scrim surfaces, dry;
Step 3, by step 2, treated that base fabric is placed in the finishing fluid of the finishing agent containing PK591 pads;
Step 4, by step 3 treated base fabric drying, sizing to get.
3. preparation method according to claim 2, it is characterised in that: the mass percent of each raw material of base fabric in step 1 are as follows:
Aramid fiber 1313 70-80%, Fanglun l414 fiber 5-10%, flame retardant polyester fiber 10-20%, electrically conductive filament 1-3%, all raw materials
The sum of mass percent be 100%.
4. preparation method according to claim 2, it is characterised in that: nanoparticle is nano aluminium oxide, nanometer in step 2
The composition of titanium oxide and nano zircite.
5. preparation method according to claim 2, it is characterised in that: drying condition is 120-150 DEG C, 1min in step 2.
6. preparation method according to claim 2, it is characterised in that: in step 3 in finishing fluid PK591 finishing agent it is dense
Degree is 35-45g/L, pick-up 65-75%.
7. preparation method according to claim 2, it is characterised in that: drying condition is 120-140 DEG C, 1.5- in step 4
2min, styling condition are 180-200 DEG C and bake 1.6-2.1min.
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Effective date of registration: 20190902 Address after: 215000 No. 12 Linjiang Road, Suzhou Industrial Park, Suzhou City, Jiangsu Province Applicant after: Diya Kang (Suzhou) Co., Ltd. high-grade fabrics Address before: Room 101, No. 40, Shangcheng B District, Jiulongcang Times, Wuxi City, Jiangsu Province Applicant before: Zhou Shunxing |
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Application publication date: 20190917 |