CN110174720A - Color reflectorized material of stealth seven and preparation method thereof - Google Patents
Color reflectorized material of stealth seven and preparation method thereof Download PDFInfo
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- CN110174720A CN110174720A CN201910596194.9A CN201910596194A CN110174720A CN 110174720 A CN110174720 A CN 110174720A CN 201910596194 A CN201910596194 A CN 201910596194A CN 110174720 A CN110174720 A CN 110174720A
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- 239000000463 material Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
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- 230000031700 light absorption Effects 0.000 claims abstract description 21
- 239000004744 fabric Substances 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 230000001105 regulatory effect Effects 0.000 claims abstract 4
- 238000004026 adhesive bonding Methods 0.000 claims abstract 2
- 238000009500 colour coating Methods 0.000 claims abstract 2
- 239000007800 oxidant agent Substances 0.000 claims abstract 2
- 230000001590 oxidative effect Effects 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims description 73
- 239000011324 bead Substances 0.000 claims description 34
- 238000000576 coating method Methods 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 239000002131 composite material Substances 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 229920005749 polyurethane resin Polymers 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 230000008033 biological extinction Effects 0.000 claims description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 7
- 239000002041 carbon nanotube Substances 0.000 claims description 7
- 239000002070 nanowire Substances 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 239000005083 Zinc sulfide Substances 0.000 claims description 5
- -1 polyparaphenylene Polymers 0.000 claims description 5
- 238000007711 solidification Methods 0.000 claims description 5
- 230000008023 solidification Effects 0.000 claims description 5
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 5
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002042 Silver nanowire Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000010985 leather Substances 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920001194 natural rubber Polymers 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 229920003051 synthetic elastomer Polymers 0.000 claims description 4
- 239000005061 synthetic rubber Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 3
- 239000006072 paste Substances 0.000 claims description 3
- 229920002627 poly(phosphazenes) Polymers 0.000 claims description 3
- 229920006267 polyester film Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 2
- 229920004933 Terylene® Polymers 0.000 claims description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 2
- 229920000547 conjugated polymer Polymers 0.000 claims description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 2
- 229910003472 fullerene Inorganic materials 0.000 claims description 2
- 238000003780 insertion Methods 0.000 claims description 2
- 230000037431 insertion Effects 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
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- 230000001143 conditioned effect Effects 0.000 abstract 1
- 230000011514 reflex Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 238000007738 vacuum evaporation Methods 0.000 description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000643 oven drying Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000000805 composite resin Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/003—Light absorbing elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of stealthy seven color reflectorized materials and preparation method thereof, and this reflectorized material is by reflective layer, refractive power regulating course, seven color coating, light-absorption layer, gluing oxidant layer and substrate layer composition.This seven color reflectorized materials show single color color in the sunlight, it is consistent with fabric color, it will not influence the associative perception of clothes, seven color effects are shown under conditioned reflex, obviously effect is had by visuality to improving in wearer's night or bad visibility environment, greatly improve clothes or textile dazzles cruel effect.
Description
Technical field
The present invention relates to reflectorized material technical fields, specially color reflectorized material of stealth seven and preparation method thereof.
Background technique
Reflectorized material generates strong reflecting effect under light source irradiation, has the purposes such as mark and warning, is also night
Walking provides safety guarantee.Reflectorized material is widely used in the fields such as life preserver, traffic police's dress ornament, and along with reflective material
The maturation of material manufacturing technique, the application field of reflective fabric are also constantly expanding.With in consumer clothes, reflectorized material is answered
With requirement of the people to the aesthetics of reflectorized material is also higher and higher.Based on reflectorized material monochrome currently on the market, seven is colored
Coloured silk variation it is also relatively simple, therefore limited to its reflective clothes, all kinds of business wears, easy dress, gym suit, fashionable dress, cap, gloves,
Application in the consumer clothes such as knapsack.
The plating of vacuum seven colour TV mainly generates the principle of color change with light refraction, controls difference with thicknesses of layers
The generation of color increases plated film mode that is gorgeous and promoting texture for product appearance.
107065051 B of CN disclose it is a kind of the invention discloses the color reflective single sided stretch fabrics of one kind seven, including base fabric,
The upper end of the base fabric is provided with elastic glue-line, and the upper end of elastic glue-line is provided with film layer, and the upper end of the film layer is set
It is equipped with composite layer, and the upper end of composite layer is provided with glass microballoon, the present invention utilizes the Zhu Mianchu for modulating good pattern in advance
It manages layer to be coated on glass microballoon, so that pattern is carried out inverse using glass microballoon and reflective layer, forms seven color reflective fabrics, and
And seven coloured picture cases on reflective fabric can be customized arbitrarily, improve the reflecting effect and color representation ability of reflective fabric, Er Qieji
It is provided with elastic glue-line between cloth and composite layer, so that making the surface of reflective fabric has micro- elastic force, further improves it
Touch feeling.
104880751 A of CN has opened the color reflective membrane of TRU seven, including is successively arranged PE release film, pearly-lustre from top to bottom
Seven color films, TPU hot melt film, wherein the color film of the pearly-lustre seven is injected in TPU hot melt film surface, the PE using glass microballoon
Release film is bonded on the color film of pearly-lustre seven by hot pressing mode
CN 105386330B discloses the manufacturing method of the color reflective leather of one kind seven, and TPU layer and seven color reflective membrane hot pressing are fitted in
Together.Enhance the binding strength of seven color reflective membranes and semi-finished product leather by TPU layer.
But the seven color product surface colors that the above way is made into generate color, and cross-color is relatively more, and lacks and dazzle extremely
Sense.We provide a kind of stealthy seven color reflectorized materials and preparation method thereof thus.
Summary of the invention
The purpose of the present invention is to provide a kind of stealthy seven color reflectorized materials, overcome the above deficiencies in the existing technologies
Place.
To achieve the above object, the invention provides the following technical scheme: a kind of stealthy seven color reflectorized material, including substrate
Layer, it is composite layer on substrate, is thereon colored light-absorption layer, is reflecting layer on colored light-absorption layer, reflecting layer is by being vaporized on glass
Seven color reflective layers on microballon, dioptric layer and glass bead layer composition, and seven color reflective layers are located at colored light-absorption layer and bead
Between, dioptric layer is in the gap between bead.Particularly colored light-absorption layer is made of adhesive and extinction composition,
Dioptric layer of the color reflectorized material of stealth seven mainly by the extinction composition of colored light-absorption layer and between bead gap changes light
Interference so that seven color reflecting layer show single color in the sunlight, seven color effects are shown in the state of retroreflecting.Stealth seven
Color reflectorized material is consistent with fabric color, will not influence the associative perception of clothes, and seven color reflecting effects are shown under the conditions of reflective, right
Obviously effect is had by visuality in raising wearer's night or bad visibility environment, greatly improves clothes or weaving
Product dazzle cruel effect.
The refractive index of glass microballoon used is 1.4 ~ 2.4 in the present invention, and partial size is greater than 97% in 50 ~ 125um, balling ratio,
The bead of preferred index 1.93 ~ 1.96.
The dioptric layer is made of high refractive index resin, and refractive power resin is between bead gap, Gao Zheguang
Index resin can be polyimides, polyparaphenylene's acetylene conjugated polymer, polythiaether, polysulfones, polyphosphazene, fullerene polymer,
One of polyphosphate is several.
Metal or non-metallic coatings are generally attached to glass by the mode of vacuum evaporation or magnetron sputtering by the reflective layer
The back side of pearl, coating material are vulcanization zinc coating or silica coating.
The colour light-absorption layer is made of adhesive and extinction composition, and adhesive is by acrylic resin, polyurethane tree
Rouge, epoxy resin, natural rubber, synthetic rubber, acrylic acid modified rubber, one or more of groups of acrylic acid modified polyurethane
At wherein it is preferred that polyurethane resin, epoxy resin or acrylic acid resin composition.The effect of extinction composition is to pass through light
Absorption seven color effects are masked out, the group of this composition becomes nano color paste and carbon nanotube, metal nanometer line such as 35nm
Silver nanowires, the composition of one or more of copper nano-wire, wherein carbon nanotube and nano wire have superpower absorbing ability.
Wherein resin and nano color paste and carbon nanotube, nano wire composition ratio can be 100:10 ~ 80:1 ~ 10.By nanometer before coating
Mill base and metal nanometer line stir evenly, and resin is then added.
The composite adhesive layer is by acrylic resin, polyurethane resin, natural rubber, synthetic rubber, and acrylic acid changes
Property rubber, one or more of compositions of acrylic acid modified polyurethane.
The substrate is one of terylene cloth, TC fabric, spandex face fabric, leather, TPU membrane and polyester film.
A kind of preparation method of stealthy seven color reflectorized materials, comprising the following steps:
1) it selects PET-PE composite membrane as film carrier, bead is uniformly adhered on film carrier, is by temperature by bead
The mode that heat sink drop is carried out in 120 DEG C ~ 170 DEG C of drying tunnel makes glass microballoon insertion film carrier depth Glass Bead Diameter
45% ~ 55%,
2) high refractive index refractive power resin is coated on exposed bead face, coating thickness is 5 ~ 20g/sqm, and heat drying obtains
The uniform coating accumulated in bead gap to one layer；
3) one layer of seven color reflective layer is plated on bead by way of vacuum or magnetron sputtering；
4) coating chromatic light-absorption layer, heating, drying solidification on seven color reflective layers；
4) composite adhesive layer, heating, drying are coated on colored light-absorption layer
5) substrate is carried out with adhesive layer compound
6) PETPE film carrier layer is removed, the color reflectorized material of the exposed stealth seven of bead is obtained.
Detailed description of the invention
Attached drawing 1 is the color reflectorized material structural schematic diagram of stealth seven；Wherein: 1. soot layer, 2. dioptric layer
3. seven color 4. 5. composite layer of colored light-absorption layer of reflected coat layer, 6. substrates.
Specific embodiment
It can further appreciate that a bright but of the invention protection is without being limited thereto by invention now given below embodiment.
Embodiment 1: being that the bead that 60 ~ 90um refractive index is 1.93 is uniformly adhered in PET/PE film carrier by diameter
On, wherein then PET is heated 2 minutes by 150 degree of baking ovens with a thickness of 100um and PE with a thickness of 30um and is embedded in glass microballoon
On film carrier；High refractive index refractive power resin polyimides are coated on exposed bead face, coating thickness is 5 ~ 20g/sqm, heating
It is dry, accumulate in it in bead gap；One layer of zinc sulfide layer is plated on bead by way of vacuum evaporation, it is thick
Degree is 20 ~ 200nm；Coating is inhaled by polyurethane resin, nano red mill base and the colored of carbon nanotube composition on zinc sulfide layer
Photosphere, wherein resin is polyurethane resin by Wanhua Chemical Group Co., Ltd., and red mill base is public purchased from U.S.'s Cabot
Department, carbon nanotube are purchased from Chengdu Organical Chemical Co., Ltd., Chinese Academy of Sciences, polyurethane: nano red mill base: carbon nanotube ratio
Example is 100:40:5, and coating thickness is 5 ~ 20g/sqm, by 60 degree of baking oven for drying solidification；Poly- ammonia is coated on colored light-absorption layer
Ester resin compounded layer, coating thickness 60g/sqm, by 80 degree of oven drying 2min, then with TC cloth in 4kgf, 80OC item
It is compound under part, it stands overnight, removing PETPE composite membrane obtains the color reflectorized material of the exposed stealth seven of bead.
Embodiment 2: being that the bead that 40 ~ 60um refractive index is 2.2 is uniformly adhered on PET/PE film carrier by diameter,
Wherein then PET is heated 2 minutes by 140 degree of baking ovens glass microballoon being embedded in film carrier with a thickness of 75um and PE with a thickness of 25um
On；High refractive index refractive power resin polythiaether is coated on exposed bead face, coating thickness is 5 ~ 20g/sqm, and heating is dry
It is dry, accumulate in it in bead gap；Layer of silicon dioxide layer is plated on bead by way of vacuum evaporation, it is thick
Degree is 20 ~ 100nm；Coating is by polyacrylic resin, the coloured silk of nanometer yellow mill base and copper nano-wire composition in silicon dioxide layer
Color light-absorption layer, wherein resin is polyacrylic resin by Changxing chemistry limited liability company, and yellow mill base is purchased from U.S.'s Cabot
Company, copper nano-wire are purchased from Nanjing Xian Feng Nono-material Science & Technology Ltd., and polyacrylic resin: nanometer yellow mill base: copper is received
Rice noodles ratio is 100:50:6, and coating thickness is 5 ~ 20g/sqm, by 60 degree of baking oven for drying solidification；It is applied on yellow light-absorption layer
Cloth polyurethane resin composite layer, coating thickness are then 60 ~ 100g/sqm exists by 80 degree of oven drying 2min with TPU membrane
5kgf, 110OIt is compound under the conditions of C, it stands overnight, removing PETPE composite membrane obtains the color reflectorized material of the exposed stealth seven of bead.
Embodiment 3: being that the bead that 90 ~ 125um refractive index is 1.5 is uniformly adhered in PET/PE film carrier by diameter
On, wherein then PET is heated 2 minutes by 160 degree of baking ovens glass microballoon being embedded in load with a thickness of 75um and PE with a thickness of 35um
On film；High refractive index refractive power resin polyphosphazene and polyphosphate mixture, coating thickness 5 are coated on exposed bead face
~ 20g/sqm, heat drying accumulate in it in bead gap；One is plated on bead by way of vacuum evaporation
Layer zinc sulfide layer, with a thickness of 20 ~ 100nm；Coating is by polyacrylic acid modified polyurethane resin, nanometer black on zinc sulfide layer
The colored light-absorption layer of mill base and copper nano-wire composition, wherein resin is polyacrylic acid modified polyurethane resin by the limited public affairs of Sartomer
Department, black color paste are purchased from Cabot Co., Ltd, the U.S., and silver nanowires is purchased from Nanjing Xian Feng Nono-material Science & Technology Ltd., polypropylene
Sour modified polyurethane resin: nanometer black color paste: silver nanowires ratio is 100:45:3, and coating thickness is 5 ~ 20g/sqm, is passed through
60 degree of baking oven for drying solidification；Polyurethane resin composite layer is coated on colored light-absorption layer, coating thickness is 60 ~ 100g/sqm, warp
80 degree of oven drying 2min are crossed, then with polyester film in 5kgf, 110OIt is compound under the conditions of C, it stands overnight, removing PETPE is compound
Film obtains the color reflectorized material of the exposed stealth seven of bead.
It above are only some specific embodiments of the present invention, but the design concept of the present invention is not limited to this, all utilizations
This design makes a non-material change to the present invention, and should all belong to behavior that violates the scope of protection of the present invention.
Claims (8)
1. a kind of stealthy seven color reflectorized material, including reflective layer, refractive power regulating course, seven color coating, light-absorption layer, gluing oxidant layer and base
Material layer composition, and refractive power regulating course is made of between bead gap high index resin；Particularly light-absorption layer is
It is made of adhesive and colored extinction composition.
2. the color reflectorized material of stealth seven as described in claim 1, it is characterised in that preparation method are as follows:
1) it selects PET-PE composite membrane as film carrier, bead is uniformly adhered on film carrier, is by temperature by bead
The mode that heat sink drop is carried out in 120 DEG C ~ 170 DEG C of drying tunnel makes glass microballoon insertion film carrier depth Glass Bead Diameter
45% ~ 55%,
2) high refractive index refractive power resin is coated on exposed bead face, coating thickness is 5 ~ 20g/sqm, and heat drying obtains
The uniform coating accumulated in bead gap to one layer；
3) one layer of seven color reflective layer is plated on bead by way of vacuum or magnetron sputtering；
4) coating chromatic light-absorption layer, heating, drying solidification on seven color reflective layers；
4) composite adhesive layer, heating, drying are coated on colored light-absorption layer
5) substrate is carried out with adhesive layer compound
6) PETPE film carrier layer is removed, the color reflectorized material of the exposed stealth seven of bead is obtained.
3. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that Glass Bead Diameter is 50 ~ 125 micro-
Rice, refractive index is about 1.4 ~ 2.4.
4. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that the high refraction as refractive power regulating course refers to
Number resins can be polyimides, polyparaphenylene's acetylene conjugated polymer, polythiaether, polysulfones, polyphosphazene, and fullerene polymer gathers
One or more of phosphate.
5. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that seven color reflective layers are by zinc sulphide or dioxy
SiClx composition.
6. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that light-absorption layer is combined by adhesive and extinction
Object composition, adhesive is by acrylic resin, polyurethane resin, natural rubber, synthetic rubber, acrylic acid modified rubber, acrylic acid
One or more of compositions of modified polyurethane；The group of extinction composition becomes nano color paste and carbon nanotube, metal nanometer line ratio
Such as 35nm silver nanowires, the composition of one or more of copper nano-wire.
7. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that the adhesive layer of composite layer is by propylene
Acid resin, polyurethane resin, natural rubber, synthetic rubber, acrylic acid modified rubber, one kind of acrylic acid modified polyurethane or several
Kind composition.
8. the color reflectorized material of stealth seven as claimed in claim 1 or 2, which is characterized in that substrate is terylene cloth, TC fabric, skin
One of leather, TPU membrane and polyester film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910596194.9A CN110174720A (en) | 2019-07-04 | 2019-07-04 | Color reflectorized material of stealth seven and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910596194.9A CN110174720A (en) | 2019-07-04 | 2019-07-04 | Color reflectorized material of stealth seven and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110174720A true CN110174720A (en) | 2019-08-27 |
Family
ID=67699699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910596194.9A Pending CN110174720A (en) | 2019-07-04 | 2019-07-04 | Color reflectorized material of stealth seven and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN110174720A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114836137A (en) * | 2022-04-27 | 2022-08-02 | 石狮市晓光服饰反光材料有限公司 | Colorful light-reflecting fabric and preparation method thereof |
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|---|---|---|---|---|
| JP2009150522A (en) * | 2007-12-21 | 2009-07-09 | Teikoku Sen I Co Ltd | Fire hose |
| CN102998727A (en) * | 2012-11-07 | 2013-03-27 | 苏州萃智新技术开发有限公司 | High-weather-resistance household washing permanent-color high-strength reflecting material with TC (terylene cotton) fabric as base |
| CN203630381U (en) * | 2013-12-02 | 2014-06-04 | 道明光学股份有限公司 | High-brightness colorful luminous product |
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Application publication date: 20190827 |