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CN110160041B - CFB boiler pollutant coupling control method and CFB boiler pollutant coupling control system - Google Patents

CFB boiler pollutant coupling control method and CFB boiler pollutant coupling control system Download PDF

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CN110160041B
CN110160041B CN201910473238.9A CN201910473238A CN110160041B CN 110160041 B CN110160041 B CN 110160041B CN 201910473238 A CN201910473238 A CN 201910473238A CN 110160041 B CN110160041 B CN 110160041B
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sulfur dioxide
cfb boiler
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limestone
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邬万竹
李影平
辛胜伟
王虎
胡昌华
张鹏
陶世健
谢国威
顾从阳
段守保
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China Energy Investment Corp Ltd
Shenhua Guoneng Group Corp Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
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    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
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Abstract

本发明提供了CFB锅炉污染物耦合控制方法及CFB锅炉污染物耦合控制系统。该方法包括以下步骤:S1,在CFB锅炉运行过程中,建立不同污染物的排放浓度之间的函数关系,污染物包括二氧化硫和氮氧化物;S2,将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值;S3,将氧量和石灰石加入量控制在最优值。通过获取CFB锅炉SO2排放浓度与NOx排放浓度的定量耦合关系,给出污染物控制浓度及石灰石加入量的最佳建议值,使得CFB锅炉SO2排放浓度与NOx排放浓度均达到整体最优值,指导CFB污染物控制运行操作,减少运行人员操作强度,降低炉内脱硫钙硫比。

Figure 201910473238

The invention provides a CFB boiler pollutant coupling control method and a CFB boiler pollutant coupling control system. The method includes the following steps: S1, during the operation of the CFB boiler, establish a functional relationship between the emission concentrations of different pollutants, and the pollutants include sulfur dioxide and nitrogen oxides; S2, apply the functional relationship to the amount of oxygen and the amount of limestone added In the relationship with the pollutant emission concentration, the oxygen amount and the limestone addition amount when the pollutant emission concentration is the lowest are obtained and recorded as the optimal value; S3, the oxygen amount and the limestone addition amount are controlled at the optimal value. By obtaining the quantitative coupling relationship between the SO 2 emission concentration and NO x emission concentration of the CFB boiler, the optimal recommended values of the pollutant control concentration and the amount of limestone added are given, so that the SO 2 emission concentration and NO x emission concentration of the CFB boiler both reach the overall maximum. The figure of merit can guide the operation of CFB pollutant control, reduce the operation intensity of operators, and reduce the calcium-sulfur ratio of desulfurization in the furnace.

Figure 201910473238

Description

CFB锅炉污染物耦合控制方法及CFB锅炉污染物耦合控制系统CFB boiler pollutant coupling control method and CFB boiler pollutant coupling control system

技术领域technical field

本发明涉及CFB锅炉领域,具体而言,涉及一种CFB锅炉污染物耦合控制方法及CFB锅炉污染物耦合控制系统。The invention relates to the field of CFB boilers, in particular to a CFB boiler pollutant coupling control method and a CFB boiler pollutant coupling control system.

背景技术Background technique

目前CFB锅炉发电机组常采用炉内脱硫控制SO2排放,即通过石灰石加入系统自动和手动控制石灰石的给料机频率调整石灰石加入量,并通过增减钙硫摩尔比来调整SO2排放量。CFB机组炉内脱硝方面,则采用控制运行氧量、床温、分级配风等运行措施来降低NOx排放浓度。At present, CFB boiler and generator sets often use in-furnace desulfurization to control SO 2 emissions, that is, the limestone feeder frequency is automatically and manually controlled by the limestone adding system to adjust the limestone addition amount, and the calcium-sulfur molar ratio is adjusted to adjust SO 2 emissions. In terms of denitrification in the furnace of the CFB unit, operating measures such as controlling the operating oxygen amount, bed temperature, and graded air distribution are adopted to reduce the NOx emission concentration.

然而,由于CFB炉内脱硫加入的石灰石对于NOx的生成有一定的催化作用,同时运行氧量的增加也会促进脱硫反应的进行,导致在降低SO2排放浓度同时增加了NOx排放量。因此,在实际运行中发现,随着机组SO2排放逐步降低,NOx排放逐步升高,二者排放浓度呈现“此消彼长”的效果,如图1所示。上述问题给控制CFB污染物的运行操作带来较大的困难。However, since the limestone added to the desulfurization in the CFB furnace has a certain catalytic effect on the formation of NOx , and the increase in the amount of operating oxygen will also promote the desulfurization reaction, resulting in a decrease in the concentration of SO2 emissions and an increase in the amount of NOx emissions. Therefore, in actual operation, it is found that as the SO 2 emission of the unit gradually decreases, the NO x emission gradually increases, and the emission concentrations of the two show the effect of “one trade off and one trade off from the other”, as shown in Figure 1. The above problems bring great difficulties to the operation of controlling CFB pollutants.

发明内容SUMMARY OF THE INVENTION

本发明的主要目的在于提供一种CFB锅炉污染物耦合控制方法及CFB锅炉污染物耦合控制系统,以解决现有技术中对CFB污染物的控制操作困难的问题。The main purpose of the present invention is to provide a CFB boiler pollutant coupling control method and a CFB boiler pollutant coupling control system, so as to solve the problem of difficulty in controlling and operating CFB pollutants in the prior art.

为了实现上述目的,根据本发明的一个方面,提供了一种CFB锅炉污染物耦合控制方法,包括以下步骤:S1,在CFB锅炉运行过程中,建立不同污染物的排放浓度之间的函数关系,污染物包括二氧化硫和氮氧化物;S2,将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值;S3,将氧量和石灰石加入量控制在最优值。In order to achieve the above object, according to one aspect of the present invention, a method for coupling pollutants of a CFB boiler is provided, comprising the following steps: S1, during the operation of the CFB boiler, establishing a functional relationship between the emission concentrations of different pollutants, The pollutants include sulfur dioxide and nitrogen oxides; S2, the functional relationship is applied to the relationship between the amount of oxygen, the amount of limestone added and the pollutant emission concentration, and the oxygen amount and the amount of limestone added when the pollutant emission concentration is the lowest is obtained and recorded as the optimal value; S3, the amount of oxygen and limestone added to the optimal value.

进一步地,建立函数关系的步骤包括:S11,建立第一函数关系式C(NOx)+K×C(SO2)=M,其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度;S12,将同一负荷下不同时间点的二氧化硫排放浓度和氮氧化物排放浓度应用于函数关系式中,以得到K和M。Further, the step of establishing the functional relationship includes: S11, establishing a first functional relationship C(NO x )+K×C(SO 2 )=M, wherein C(NO x ) is the nitrogen oxide emission concentration, C( SO 2 ) is the sulfur dioxide emission concentration; S12, the sulfur dioxide emission concentration and nitrogen oxide emission concentration at different time points under the same load are applied to the functional relationship to obtain K and M.

进一步地,步骤S11包括:测量CFB锅炉在不同负荷下的二氧化硫排放浓度和氮氧化物排放浓度,并绘制关系曲线;分别对各关系曲线进行数据拟合,得到多个二氧化硫排放浓度与氮氧化物排放浓度的函数关系式;根据各函数关系式之间的规律,得到第一函数关系式。Further, step S11 includes: measuring the sulfur dioxide emission concentration and nitrogen oxide emission concentration of the CFB boiler under different loads, and drawing a relationship curve; respectively, performing data fitting on each relationship curve to obtain a plurality of sulfur dioxide emission concentrations and nitrogen oxides. The functional relationship of the emission concentration; according to the law between the functional relationships, the first functional relationship is obtained.

进一步地,得到氧量和石灰石加入量的最优值的步骤包括:S21,根据二氧化硫排放浓度与氮氧化物排放浓度之间的关系建立约束条件,并将约束条件应用于函数关系中,以得到二氧化硫排放浓度的最优值;S22,将二氧化硫排放浓度的最优值应用于氧量、石灰石加入量与二氧化硫排放浓度的关系中,以得到氧量的最优值以及石灰石加入量的最优值。Further, the step of obtaining the optimal value of the oxygen amount and the amount of limestone added includes: S21, establishing a constraint condition according to the relationship between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration, and applying the constraint condition to the functional relationship to obtain The optimal value of sulfur dioxide emission concentration; S22, the optimal value of sulfur dioxide emission concentration is applied to the relationship between oxygen amount, limestone addition amount and sulfur dioxide emission concentration, so as to obtain the optimal value of oxygen amount and the optimal value of limestone addition amount .

进一步地,约束条件为:控制氮氧化物的排放浓度为100~150mg/Nm3Further, the constraint condition is: control the emission concentration of nitrogen oxides to be 100-150 mg/Nm 3 .

根据本发明的另一方面,提供了一种CFB锅炉污染物耦合控制系统,与CFB锅炉发电机组电连接,CFB锅炉发电机组包括CFB锅炉、与CFB锅炉连通的污染物排放管线以及石灰石输送系统,上述污染物耦合控制系统还包括:采集单元,与污染物排放管线连通,用于采集污染物的浓度,污染物包括二氧化硫和氮氧化物;第一计算单元,与采集单元电连接,用于建立不同污染物的排放浓度之间的函数关系;第二计算单元,与第一计算单元电连接,用于将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值;控制单元,分别与CFB锅炉、石灰石输送系统以及第二计算单元电连接,用于将氧量和石灰石加入量控制在最优值。According to another aspect of the present invention, a CFB boiler pollutant coupling control system is provided, which is electrically connected to the CFB boiler generator set, and the CFB boiler generator set includes a CFB boiler, a pollutant discharge pipeline communicated with the CFB boiler, and a limestone conveying system, The above-mentioned pollutant coupling control system further includes: a collection unit, connected with the pollutant discharge pipeline, for collecting the concentration of pollutants, and the pollutants include sulfur dioxide and nitrogen oxides; a first calculation unit, electrically connected with the collection unit, for establishing the functional relationship between the emission concentrations of different pollutants; the second calculation unit, electrically connected to the first calculation unit, is used for applying the functional relationship to the relationship between the oxygen amount, the amount of limestone added and the pollutant emission concentration to obtain the pollutant emission concentration The oxygen amount and the limestone addition amount when the emission concentration is the lowest shall be recorded as the optimal value; the control unit is electrically connected to the CFB boiler, the limestone conveying system and the second calculation unit respectively, and is used to control the oxygen amount and the limestone addition amount to the optimal value. value.

进一步地,第一计算单元包括:数据拟合模块,与采集单元电连接,用于建立第一函数关系式C(NOx)+K×C(SO2)=M,其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度;第一计算模块,与数据拟合模块,电连接,用于将同一负荷下不同时间点的二氧化硫排放浓度和氮氧化物排放浓度应用于函数关系式中,以得到K和M。Further, the first calculation unit includes: a data fitting module, electrically connected to the acquisition unit, for establishing a first functional relationship C(NO x )+K×C(SO 2 )=M, where C(NO x ) ) is the emission concentration of nitrogen oxides, and C(SO 2 ) is the emission concentration of sulfur dioxide; the first calculation module is electrically connected to the data fitting module, and is used to calculate the emission concentration of sulfur dioxide and nitrogen oxides at different time points under the same load The concentration is applied to the functional relationship to obtain K and M.

进一步地,第二计算单元包括:第二计算模块,与第一计算模块电连接,用于根据二氧化硫排放浓度与氮氧化物排放浓度之间的关系建立约束条件,并将约束条件应用于函数关系中,以得到二氧化硫排放浓度的最优值;第三计算模块,与第二计算模块电连接,用于将二氧化硫排放浓度的最优值应用于氧量、石灰石加入量与二氧化硫排放浓度的关系中,以得到氧量的最优值以及石灰石加入量的最优值。Further, the second calculation unit includes: a second calculation module, electrically connected to the first calculation module, for establishing a constraint condition according to the relationship between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration, and applying the constraint condition to the functional relationship in order to obtain the optimal value of the sulfur dioxide emission concentration; the third calculation module, electrically connected with the second calculation module, is used for applying the optimal value of the sulfur dioxide emission concentration to the relationship between the oxygen amount, the amount of limestone added and the sulfur dioxide emission concentration , in order to obtain the optimal value of oxygen and the optimal value of limestone addition.

应用本发明的技术方案,提供了一种CFB锅炉污染物耦合控制方法,通过获取CFB锅炉SO2排放浓度与NOx排放浓度的定量耦合关系,给出污染物控制浓度及石灰石加入量的最佳建议值,使得CFB锅炉SO2排放浓度与NOx排放浓度均达到整体最优值,指导CFB污染物控制运行操作,减少运行人员操作强度,降低炉内脱硫钙硫比,提高电厂运行经济性。By applying the technical solution of the present invention, a coupling control method for pollutants of a CFB boiler is provided. By obtaining the quantitative coupling relationship between the SO 2 emission concentration and the NO x emission concentration of the CFB boiler, the optimal control concentration of pollutants and the amount of limestone added are given. The proposed value makes the SO 2 emission concentration and NO x emission concentration of the CFB boiler reach the overall optimal value, which guides the operation of CFB pollutant control, reduces the operation intensity of operators, reduces the calcium-sulfur ratio of desulfurization in the furnace, and improves the operation economy of the power plant.

附图说明Description of drawings

构成本发明的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings forming a part of the present invention are used to provide further understanding of the present invention, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention, and do not constitute an improper limitation of the present invention. In the attached image:

图1示出了现有技术中CFB锅炉污染物排放浓度随氧量变化的关系示意图;Fig. 1 shows the schematic diagram of the relationship between CFB boiler pollutant emission concentration and oxygen amount in the prior art;

图2示出了本发明实施方式所提供的CFB锅炉污染物耦合控制方法的流程示意图;FIG. 2 shows a schematic flowchart of a method for coupling pollutants in a CFB boiler provided by an embodiment of the present invention;

图3示出了本发明实施方式所提供的CFB锅炉污染物耦合控制方法中氮氧化物排放浓度与二氧化硫排放浓度的关系示意图;3 shows a schematic diagram of the relationship between the nitrogen oxide emission concentration and the sulfur dioxide emission concentration in the CFB boiler pollutant coupling control method provided by the embodiment of the present invention;

图4示出了本发明实施方式所提供的一种具有第一函数关系式的CFB锅炉污染物耦合控制方法的流程示意图;4 shows a schematic flowchart of a method for coupling pollutants in a CFB boiler with a first functional relationship provided by an embodiment of the present invention;

图5示出了现有技术中SO2排放浓度与石灰石加入量存在的定量关系示意图;Fig. 5 shows the quantitative relationship schematic diagram of SO emission concentration and limestone addition in the prior art ;

图6示出了本发明实施方式所提供的一种CFB锅炉污染物耦合控制系统的实施过程流程示意图。FIG. 6 shows a schematic flowchart of an implementation process of a CFB boiler pollutant coupling control system provided by an embodiment of the present invention.

具体实施方式Detailed ways

需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that the embodiments of the present invention and the features of the embodiments may be combined with each other under the condition of no conflict. The present invention will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.

为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to make those skilled in the art better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only Embodiments are part of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

需要说明的是,本发明的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本发明的实施例。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。It should be noted that the terms "first", "second" and the like in the description and claims of the present invention and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific sequence or sequence. It is to be understood that the data so used are interchangeable under appropriate circumstances for the embodiments of the invention described herein. Furthermore, the terms "comprising" and "having" and any variations thereof, are intended to cover non-exclusive inclusion, for example, a process, method, system, product or device comprising a series of steps or units is not necessarily limited to those expressly listed Rather, those steps or units may include other steps or units not expressly listed or inherent to these processes, methods, products or devices.

正如背景技术所介绍的,现有技术中由于CFB炉内脱硫加入的石灰石对于NOx的生成有一定的催化作用,同时运行氧量的增加也会促进脱硫反应的进行,导致在降低SO2排放浓度同时增加了NOx排放量,上述问题给控制CFB污染物的运行操作带来较大的困难。As described in the background art, in the prior art, limestone added for desulfurization in the CFB furnace has a certain catalytic effect on the formation of NO x , and at the same time, the increase in the amount of operating oxygen will also promote the desulfurization reaction, resulting in the reduction of SO 2 emissions. The concentration also increases NOx emissions, and the above problems bring greater difficulties to the operation of controlling CFB pollutants.

为了解决如上技术问题,本发明提出了一种CFB锅炉污染物耦合控制方法,如图2所示,包括以下步骤:S1,在CFB锅炉运行过程中,建立不同污染物的排放浓度之间的函数关系,污染物包括二氧化硫和氮氧化物;S2,将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值;S3,将氧量和石灰石加入量控制在最优值。In order to solve the above technical problems, the present invention proposes a coupling control method for pollutants of a CFB boiler, as shown in FIG. 2, including the following steps: S1, during the operation of the CFB boiler, establish a function between the emission concentrations of different pollutants The pollutants include sulfur dioxide and nitrogen oxides; S2, the functional relationship is applied to the relationship between the amount of oxygen, the amount of limestone added and the pollutant emission concentration, and the oxygen amount and the amount of limestone added when the pollutant emission concentration is the lowest is obtained and recorded as Optimal value; S3, control the amount of oxygen and limestone added to the optimal value.

本发明的上述CFB锅炉污染物耦合控制方法中,通过获取CFB锅炉SO2排放浓度与NOx排放浓度的定量耦合关系,给出污染物控制浓度及石灰石加入量的最佳建议值,使得CFB锅炉SO2排放浓度与NOx排放浓度均达到整体最优值,指导CFB污染物控制运行操作,减少运行人员操作强度,降低炉内脱硫钙硫比,提高电厂运行经济性。In the above-mentioned CFB boiler pollutant coupling control method of the present invention, by obtaining the quantitative coupling relationship between the SO 2 emission concentration and the NO x emission concentration of the CFB boiler, the optimal recommended value of the pollutant control concentration and the amount of limestone added is given, so that the CFB boiler can Both SO 2 emission concentration and NO x emission concentration reach the overall optimal value, which guides the operation of CFB pollutant control operation, reduces the operation intensity of operators, reduces the calcium-sulfur ratio of desulfurization in the furnace, and improves the operation economy of the power plant.

下面将更详细地描述根据本发明提供的CFB锅炉污染物耦合控制方法的示例性实施方式。然而,这些示例性实施方式可以由多种不同的形式来实施,并且不应当被解释为只限于这里所阐述的实施方式。应当理解的是,提供这些实施方式是为了使得本申请的公开彻底且完整,并且将这些示例性实施方式的构思充分传达给本领域普通技术人员。Exemplary embodiments of the CFB boiler pollutant coupling control method provided according to the present invention will be described in more detail below. These exemplary embodiments may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. It should be understood that these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of these exemplary embodiments to those skilled in the art.

申请人在多个CFB电厂的现场试验的过程中,分析多组SO2与NOx排放浓度变化趋势,发现二者之间有较强的负相关性,且两者的数值存在着一定的定量关系。如图1所示,SO2与NOx排放浓度二者数值变化相互耦合,趋势相反,且变化幅度存在一定的比例关系。In the process of field tests of multiple CFB power plants, the applicant analyzed the variation trends of SO 2 and NO x emission concentrations in multiple groups, and found that there is a strong negative correlation between the two, and the values of the two have a certain quantification. relation. As shown in Figure 1, the numerical changes of SO 2 and NO x emission concentrations are coupled with each other, with opposite trends, and there is a certain proportional relationship between the changes.

然后通过在300MW CFB锅炉发电机组上,经过对不同负荷下现场多组的数据分析,得出污染物排放浓度呈现一定关系,如图3所示。通过整理数据,拟合出二者的函数关系为:Then, through the data analysis of multiple groups under different loads on the 300MW CFB boiler generator set, it is concluded that the pollutant emission concentration has a certain relationship, as shown in Figure 3. By arranging the data, the functional relationship between the two is fitted as:

151MW负荷:151MW load:

C(NOx)=-0.142C(SO2)+142.17;C(NOx)=-0.142C(SO 2 )+142.17;

192MW负荷:192MW load:

C(NOx)=-0.122C(SO2)+132.17;C(NOx)=-0.122C(SO 2 )+132.17;

其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度;Among them, C(NO x ) is the emission concentration of nitrogen oxides, and C(SO 2 ) is the emission concentration of sulfur dioxide;

可以看出,在不同的负荷工况下,当氧量、石灰石加入量等因素变化时,虽然两者的浓度都在变化,但总存在着一个比例系数K使得NOx浓度与比例折算后的SO2浓度之和等于一个常数M,比例系数K及常数M随负荷略有变化,变化幅度不大,即有如下关系:It can be seen that under different load conditions, when the oxygen content, the amount of limestone added and other factors change, although the concentrations of both are changing, there is always a proportional coefficient K that makes the NOx concentration and the SO after the ratio converted. 2 The sum of the concentrations is equal to a constant M, the proportional coefficient K and the constant M change slightly with the load, and the change range is not large, that is, the relationship is as follows:

C(NOx)+K×C(SO2)=M,其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度。C(NO x )+K×C(SO 2 )=M, wherein C(NO x ) is the emission concentration of nitrogen oxides, and C(SO 2 ) is the emission concentration of sulfur dioxide.

因此,在上述步骤S1中,如图4所示,建立上述函数关系的步骤可以包括:S11,建立第一函数关系式C(NOx)+K×C(SO2)=M,其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度;S12,将同一负荷下不同时间点的二氧化硫排放浓度和氮氧化物排放浓度应用于函数关系式中,以得到K和M。Therefore, in the above step S1, as shown in FIG. 4, the step of establishing the above functional relationship may include: S11, establishing a first functional relationship formula C(NO x )+K×C(SO 2 )=M, where C (NO x ) is the nitrogen oxide emission concentration, C(SO 2 ) is the sulfur dioxide emission concentration; S12, the sulfur dioxide emission concentration and nitrogen oxide emission concentration at different time points under the same load are applied to the functional relationship to obtain K and M.

在一种优选的实施方式中,上述步骤S11包括:测量CFB锅炉在不同负荷下的二氧化硫排放浓度和氮氧化物排放浓度,并绘制关系曲线;分别对各关系曲线进行数据拟合,得到多个二氧化硫排放浓度与氮氧化物排放浓度的函数关系式;根据各函数关系式之间的规律,得到第一函数关系式。In a preferred embodiment, the above step S11 includes: measuring the sulfur dioxide emission concentration and nitrogen oxide emission concentration of the CFB boiler under different loads, and drawing a relationship curve; The functional relationship between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration; the first functional relationship is obtained according to the law between the functional relationships.

在上述步骤S1之后,执行步骤S2:将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值。After the above step S1, step S2 is performed: the functional relationship is applied to the relationship between the oxygen amount, the amount of limestone added and the pollutant discharge concentration, and the oxygen amount and the amount of limestone added when the pollutant discharge concentration is the lowest is obtained and recorded as the optimal value .

可以在不同煤种燃烧条件下,利用一段时间的SO2排放浓度与NOx排放浓度进行数据,输入电厂DCS中,通过计算拟合求解出K与M的值,将K、M应用于氧量、石灰石加入量与污染物排放浓度的关系中,即可得出运行氧量及石灰石加入量的最优值。同时,定量的描述SO2排放浓度与NOx排放浓度相互关系,可以为现场调整污染物浓度操作提供参考依据,使SO2排放浓度与NOx排放浓度同时达到较为理想的数值。Under different coal combustion conditions, the data of SO 2 emission concentration and NO x emission concentration can be used for a period of time, input into the DCS of the power plant, and the values of K and M can be solved by calculation and fitting, and K and M can be applied to the amount of oxygen. , the relationship between the amount of limestone added and the pollutant emission concentration, the optimal value of the amount of operating oxygen and the amount of limestone added can be obtained. At the same time, quantitative description of the relationship between SO 2 emission concentration and NO x emission concentration can provide a reference for on-site adjustment of pollutant concentration operations, so that SO 2 emission concentration and NO x emission concentration can reach ideal values at the same time.

在一种优选的实施方式中,如图4所示,得到上述氧量和上述石灰石加入量的最优值的步骤包括:S21,根据二氧化硫排放浓度与氮氧化物排放浓度之间的关系建立约束条件,并将约束条件应用于函数关系中,以得到二氧化硫排放浓度的最优值;S22,将二氧化硫排放浓度的最优值应用于氧量、石灰石加入量与二氧化硫排放浓度的关系中,以得到氧量的最优值以及石灰石加入量的最优值。In a preferred embodiment, as shown in FIG. 4 , the step of obtaining the optimal value of the above-mentioned oxygen amount and the above-mentioned limestone addition amount includes: S21, establishing a constraint according to the relationship between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration S22, apply the optimal value of sulfur dioxide emission concentration to the relationship between oxygen amount, limestone addition amount and sulfur dioxide emission concentration to obtain the optimal value of sulfur dioxide emission concentration; The optimum value of oxygen and the optimum amount of limestone added.

循环流化床中,石灰石首先吸热分解为CaO和CO2,继而CaO与SO2进行反应,实现炉内脱硫,反应公式如下:In the circulating fluidized bed, the limestone is first endothermically decomposed into CaO and CO 2 , and then CaO reacts with SO 2 to achieve desulfurization in the furnace. The reaction formula is as follows:

CaCO3→CaO+CO2CaCO 3 →CaO+CO 2 ;

CaO+1/2O2+SO2→CaSO4CaO+1/2O 2 +SO 2 →CaSO 4 .

在CFB电厂中,一般通过控制石灰石的给料机频率来调整炉膛内石灰石加入量来控制SO2排放浓度,SO2排放浓度与石灰石加入量存在特定的定量关系,如图5所示;另一方面,石灰石脱硫反应的进行需要耗氧,氧量在一定范围内提高有利于脱硫反应的进行,从而降低SO2排放,SO2排放浓度与氧量也存在着定量关系,如图1。In CFB power plants, the amount of limestone added in the furnace is generally adjusted by controlling the frequency of the limestone feeder to control the SO 2 emission concentration. There is a specific quantitative relationship between the SO 2 emission concentration and the amount of limestone added, as shown in Figure 5; another On the one hand, the limestone desulfurization reaction requires oxygen consumption, and the increase of the oxygen content within a certain range is beneficial to the desulfurization reaction, thereby reducing the SO 2 emission. There is also a quantitative relationship between the SO 2 emission concentration and the oxygen amount, as shown in Figure 1.

在CFB电厂实际运行中,为控制NOX达标排放或配合SNCR脱硝系统使NOX达到超低排放,同时兼顾燃烧效果与运行经济性,可以将炉膛出口NOX控制在100mg/Nm3~150mg/Nm3范围内作为上述约束条件,具体数值C(NOx)各电厂可根据现场实际运行工况进行选择确定。再将C(NOx)代入本发明确定的函数关系中,就可得到该种运行工况下SO2排放浓度最优目标值C(SO2),从而得出石灰石加入量的最佳建议目标值。同时也对运行氧量控制值得出定量的优化建议。进而达到减少石灰石加入量,优化运行氧量,提高电厂运行经济性的效果。In the actual operation of the CFB power plant, in order to control the NOx emission up to the standard or cooperate with the SNCR denitrification system to achieve ultra-low NOx emissions, while taking into account the combustion effect and operating economy, the NOx at the furnace outlet can be controlled at 100mg/ Nm3 ~ 150mg/ Within the range of Nm 3 as the above constraint, the specific value C(NO x ) can be selected and determined by each power plant according to the actual operating conditions on site. Substitute C(NO x ) into the functional relationship determined by the present invention, the optimal target value C(SO 2 ) of SO 2 emission concentration under this operating condition can be obtained, thereby obtaining the optimal recommended target of limestone addition amount value. At the same time, quantitative optimization suggestions are made for the operating oxygen control value. And then achieve the effect of reducing the amount of limestone added, optimizing the amount of oxygen in operation, and improving the operation economy of the power plant.

根据本发明的另一方面,还提供了一种CFB锅炉污染物耦合控制系统,与CFB锅炉发电机组电连接,该CFB锅炉发电机组包括CFB锅炉、与CFB锅炉连通的污染物排放管线以及石灰石输送系统,上述污染物耦合控制系统还包括采集单元、第一计算单元、第二计算单元和控制单元。According to another aspect of the present invention, a CFB boiler pollutant coupling control system is also provided, which is electrically connected to the CFB boiler generator set, and the CFB boiler generator set includes a CFB boiler, a pollutant discharge pipeline communicated with the CFB boiler, and a limestone conveying system. The above-mentioned pollutant coupling control system further includes a collection unit, a first calculation unit, a second calculation unit and a control unit.

其中,上述采集单元与污染物排放管线连通,用于采集污染物的浓度,污染物包括二氧化硫和氮氧化物;上述第一计算单元与采集单元电连接,用于建立不同污染物的排放浓度之间的函数关系;上述第二计算单元与第一计算单元电连接,用于将函数关系应用于氧量、石灰石加入量与污染物排放浓度的关系中,得到污染物排放浓度最低时的氧量和石灰石加入量并记为最优值;上述控制单元分别与CFB锅炉、石灰石输送系统以及第二计算单元电连接,用于将氧量和石灰石加入量控制在最优值。Wherein, the above-mentioned collection unit is connected with the pollutant discharge pipeline, and is used to collect the concentration of pollutants, and the pollutants include sulfur dioxide and nitrogen oxides; the above-mentioned first calculation unit is electrically connected with the collection unit, and is used to establish a relationship between the discharge concentrations of different pollutants. The functional relationship between the above-mentioned second calculation unit and the first calculation unit is electrically connected to apply the functional relationship to the relationship between the amount of oxygen, the amount of limestone added and the pollutant discharge concentration to obtain the oxygen amount when the pollutant discharge concentration is the lowest and the amount of limestone added and recorded as the optimal value; the above control units are respectively electrically connected to the CFB boiler, the limestone conveying system and the second calculation unit to control the oxygen amount and the added amount of limestone to the optimal value.

本发明的上述CFB锅炉污染物耦合控制系统中,通过CFB锅炉SO2排放浓度与NOx排放浓度的定量耦合关系,给出污染物控制浓度及石灰石加入量的最佳建议值,使得CFB锅炉SO2排放浓度与NOx排放浓度均达到整体最优值,指导CFB污染物控制运行操作,减少运行人员操作强度,降低炉内脱硫钙硫比,提高电厂运行经济性。In the above-mentioned CFB boiler pollutant coupling control system of the present invention, through the quantitative coupling relationship between the CFB boiler SO 2 emission concentration and NO x emission concentration, the optimal recommended value of the pollutant control concentration and the amount of limestone added is given, so that the CFB boiler SO 2. Both the emission concentration and NOx emission concentration reach the overall optimal value, which guides the operation of CFB pollutant control, reduces the operation intensity of operators, reduces the calcium-sulfur ratio of desulfurization in the furnace, and improves the operation economy of the power plant.

优选地,上述第一计算单元包括数据拟合模块和第一计算模块,数据拟合模块与采集单元电连接,用于建立第一函数关系式C(NOx)+K×C(SO2)=M,其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度;第一计算模块与数据拟合模块,电连接,用于将同一负荷下不同时间点的二氧化硫排放浓度和氮氧化物排放浓度应用于函数关系式中,以得到K和M。Preferably, the above-mentioned first calculation unit includes a data fitting module and a first calculation module, and the data fitting module is electrically connected to the acquisition unit for establishing the first functional relationship C(NO x )+K×C(SO 2 ) =M, where C(NO x ) is the emission concentration of nitrogen oxides, and C(SO 2 ) is the emission concentration of sulfur dioxide; the first calculation module and the data fitting module are electrically connected to The sulfur dioxide emission concentration and nitrogen oxide emission concentration are applied in the functional relationship to obtain K and M.

优选地,上述第二计算单元包括第二计算模块和第三计算模块,第二计算模块与第一计算模块电连接,用于根据二氧化硫排放浓度与氮氧化物排放浓度之间的关系建立约束条件,并将约束条件应用于函数关系中,以得到二氧化硫排放浓度的最优值;第三计算模块与第二计算模块电连接,用于将二氧化硫排放浓度的最优值应用于氧量、石灰石加入量与二氧化硫排放浓度的关系中,以得到氧量的最优值以及石灰石加入量的最优值。Preferably, the above-mentioned second calculation unit includes a second calculation module and a third calculation module, the second calculation module is electrically connected to the first calculation module, and is used for establishing a constraint condition according to the relationship between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration , and apply the constraint conditions to the functional relationship to obtain the optimal value of the sulfur dioxide emission concentration; the third calculation module is electrically connected to the second calculation module, and is used to apply the optimal value of the sulfur dioxide emission concentration to the amount of oxygen, the addition of limestone In order to obtain the optimal value of oxygen amount and the optimal value of limestone addition amount in the relationship between the amount and sulfur dioxide emission concentration.

本发明的上述CFB锅炉污染物耦合控制系统还可以利用现有CFB锅炉发电机组中的DCS控制系统,如图6所示,在其中新增数据拟合计算模块,其通用公式为:The above-mentioned CFB boiler pollutant coupling control system of the present invention can also utilize the DCS control system in the existing CFB boiler generator set, as shown in Figure 6, in which a new data fitting calculation module is added, and its general formula is:

C(NOx)+K×C(SO2)=M (1)C(NO x )+K×C(SO 2 )=M (1)

其中,C(NOx)为氮氧化物排放浓度,C(SO2)为二氧化硫排放浓度,其数值可以从电厂现有的污染物测量系统中实时取值,通过代入不同时间的多组C(NOx)、C(SO2)数值,进行数据拟合计算,可以得到K、M具体数值,公式(1)也就随之确定下来,以K、M具体数值为K1、M1为例,这样就得到了适用于该段时间内的NOx与SO2的排放浓度耦合关系式:Among them, C(NO x ) is the emission concentration of nitrogen oxides, and C(SO 2 ) is the emission concentration of sulfur dioxide. Its value can be obtained in real time from the existing pollutant measurement system of the power plant. By substituting multiple groups of C ( NO x ), C(SO 2 ) values, perform data fitting calculation, the specific values of K and M can be obtained, and formula (1) is determined accordingly. Take the specific values of K and M as K 1 and M 1 as an example , so the coupling relationship between the emission concentration of NO x and SO 2 for this period of time is obtained:

C(NOx)+K1×C(SO2)=M1(2)C(NOx)+K 1 ×C(SO 2 )=M 1 (2)

利用关系式(2),可以得出当前浓度、石灰石加入量的最优控制建议值,再显示在DCS画面中,或者输入自动控制系统中,实现CFB机组污染物的最佳耦合控制。Using the relational formula (2), the optimal control recommendation value of the current concentration and limestone addition amount can be obtained, and then displayed on the DCS screen or input into the automatic control system to realize the optimal coupling control of the pollutants of the CFB unit.

从以上的描述中,可以看出,本发明上述的实施例实现了如下技术效果:From the above description, it can be seen that the above-mentioned embodiments of the present invention achieve the following technical effects:

通过获取CFB锅炉SO2排放浓度与NOx排放浓度的定量耦合关系,给出污染物控制浓度及石灰石加入量的最佳建议值,使得CFB锅炉SO2排放浓度与NOx排放浓度均达到整体最优值,指导CFB污染物控制运行操作,减少运行人员操作强度,降低炉内脱硫钙硫比,提高电厂运行经济性。By obtaining the quantitative coupling relationship between the SO 2 emission concentration and NO x emission concentration of the CFB boiler, the optimal recommended values of the pollutant control concentration and the amount of limestone added are given, so that the SO 2 emission concentration and NO x emission concentration of the CFB boiler both reach the overall maximum. The figure of merit can guide the operation of CFB pollutant control, reduce the operation intensity of operators, reduce the calcium-sulfur ratio of desulfurization in the furnace, and improve the operation economy of the power plant.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (8)

1. A pollutant coupling control method for a CFB boiler is characterized by comprising the following steps:
s1, establishing a functional relation between emission concentrations of sulfur dioxide and nitrogen oxides in pollutants during operation of the CFB boiler, wherein the pollutants comprise the sulfur dioxide and the nitrogen oxides;
s2, applying the functional relation to the relation among oxygen quantity, limestone adding quantity and pollutant emission concentration to obtain the oxygen quantity and the limestone adding quantity when the pollutant emission concentration is lowest and recording as optimal values;
and S3, controlling the oxygen amount and the limestone addition amount at the optimal value, and mutually coupling the numerical changes of the emission concentrations of the sulfur dioxide and the nitrogen oxide in the functional relation, wherein the numerical changes have opposite trends, and the change amplitudes have a certain proportional relation.
2. The CFB boiler contaminant coupling control method of claim 1, wherein the step of establishing said functional relationship comprises:
s11, establishing a first functional relation C (NO)x)+K×C(SO2) Wherein, C (NO)x) For the nitrogen oxide emission concentration, C (SO)2) The sulfur dioxide emission concentration;
s12, the sulfur dioxide emission concentration and the nitrogen oxide emission concentration at different time points under the same load are applied to the functional relation to obtain K and M.
3. The CFB boiler contaminant coupling control method of claim 2, wherein said step S11 includes:
measuring the sulfur dioxide emission concentration and the nitrogen oxide emission concentration of the CFB boiler under different loads, and drawing a relation curve;
respectively carrying out data fitting on each relation curve to obtain a plurality of functional relation formulas of the sulfur dioxide emission concentration and the nitrogen oxide emission concentration;
and obtaining the first functional relation according to the rule among the functional relations.
4. A CFB boiler contaminant coupling control method according to any one of claims 1 to 3, wherein the step of obtaining optimal values of said oxygen amount and said limestone addition amount comprises:
s21, establishing a constraint condition according to the relation between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration, and applying the constraint condition to the functional relation to obtain the optimal value of the sulfur dioxide emission concentration;
and S22, applying the optimal value of the sulfur dioxide emission concentration to the relation among oxygen quantity, limestone adding quantity and the sulfur dioxide emission concentration to obtain the optimal value of the oxygen quantity and the optimal value of the limestone adding quantity.
5. The CFB boiler contaminant coupling control method of claim 4, wherein the constraints are: controlling the emission concentration of the nitrogen oxide to be 100-150 mg/Nm3
6. A CFB boiler contaminant coupling control system electrically connected to a CFB boiler generator set, the CFB boiler generator set including a CFB boiler, a contaminant discharge line in communication with the CFB boiler, and a limestone conveyance system, the contaminant coupling control system further comprising:
a collection unit in communication with the pollutant discharge line for collecting a concentration of the pollutant, the pollutant including sulfur dioxide and nitrogen oxides;
the first calculation unit is electrically connected with the acquisition unit and is used for establishing a functional relation between the emission concentrations of the sulfur dioxide and the nitrogen oxide;
the second calculation unit is electrically connected with the first calculation unit and is used for applying the functional relation to the relation among oxygen quantity, limestone adding amount and pollutant emission concentration to obtain the oxygen quantity and the limestone adding amount when the pollutant emission concentration is lowest and recording the oxygen quantity and the limestone adding amount as optimal values;
and the control unit is respectively and electrically connected with the CFB boiler, the limestone conveying system and the second calculation unit and is used for controlling the oxygen amount and the limestone adding amount to be in the optimal value, the numerical changes of the emission concentrations of the sulfur dioxide and the nitrogen oxide in the functional relation are mutually coupled, the trends are opposite, and the change amplitudes have certain proportional relation.
7. The CFB boiler contaminant coupling control system of claim 6, wherein the first calculation unit comprises:
a data fitting module electrically connected with the acquisition unit and used for establishing a first functional relation C (NO)x)+K×C(SO2) Wherein, C (NO)x) For the nitrogen oxide emission concentration, C (SO)2) The sulfur dioxide emission concentration;
and the first calculation module is electrically connected with the data fitting module and is used for applying the sulfur dioxide emission concentration and the nitrogen oxide emission concentration at different time points under the same load to the functional relation to obtain K and M.
8. The CFB boiler contaminant coupling control system of claim 7, wherein the second calculation unit comprises:
the second calculation module is electrically connected with the first calculation module and used for establishing a constraint condition according to the relation between the sulfur dioxide emission concentration and the nitrogen oxide emission concentration and applying the constraint condition to the functional relation so as to obtain the optimal value of the sulfur dioxide emission concentration;
and the third calculation module is electrically connected with the second calculation module and is used for applying the optimal value of the sulfur dioxide emission concentration to the relation among oxygen quantity, limestone addition and the sulfur dioxide emission concentration so as to obtain the optimal value of the oxygen quantity and the optimal value of the limestone addition.
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