CN110130114A - A kind of biomass graphene fabric and preparation method thereof - Google Patents
A kind of biomass graphene fabric and preparation method thereof Download PDFInfo
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- CN110130114A CN110130114A CN201910337051.6A CN201910337051A CN110130114A CN 110130114 A CN110130114 A CN 110130114A CN 201910337051 A CN201910337051 A CN 201910337051A CN 110130114 A CN110130114 A CN 110130114A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/085—Metal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/087—Carbon fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
- D06N2211/106—Footwear
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The present invention discloses a kind of biomass graphene fabric and preparation method thereof, including surface covering and five piece of three winged satin fabric base being made of silver fiber warp thread and black alkene biomass fiber weft yarn, the surface covering includes the raw material of following parts by weight proportion: 33-65 parts of dialkyl polydimethylsiloxane, 18-25 parts of hydroxyl dimethyl silicone polymer, 22-26 parts of acrylic resin, 3-6 parts of methyl tributanoximo silane, 1-3 parts of TSL 8330, 1-2 parts of butyl titanate, 3-5 parts of hydroxypropyl acrylate, 17-20 parts of nano-titanium dioxide, 1, 2-4 parts of 3- dimethyl-2-imidazolinone, 2-3 parts and glycidyl methacrylate 2-6 parts of benzene sulfinic acid sodium salt, the biomass graphene fabric has outstanding antibacterial effect.
Description
Technical field
The present invention relates to a kind of biomass graphene fabrics and preparation method thereof.
Background technique
Fabric is exactly the material for making clothes.As one of clothes three elements, fabric can not only annotate clothes
Style and characteristic, and directly control the expression effect of the color of clothes, moulding.
Artificial leather is a kind of appearance, feel like leather and the plastic products that it can be replaced to use.Usually using fabric as base,
Coating synthetic resin and the addition of various plastics are made, and belong to one kind of fabric.China's artificial leather synthetic leather industry is new after the founding of the state
Emerging industry starts to walk to develop, is to develop one of industry earlier in plastics industry in the fifties end.By building for recent decades
If artificial leather synthetic leather industry has had comparable economic scale；With high-tech development both at home and abroad and advanced technologies equipment
Application, trade management, technical level, product specification have the qualitative leap of essence, and artificial leather synthetic leather has evolved into
For one of industry important in current consumption Products Industry, with entire processing industry synchronize march toward great powers in the world's ranks, be the world
On big producer, consumption big country, one of foreign trade big country.
Artificial leather application of dress material is very extensive, and current high-heeled shoes are generally formed using artificial leather facing material tailor, but mesh
Preceding artificial leather facing material does not have antibacterial effect, leads to bacterium easy to breed in high-heeled shoes.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of biomass graphene fabric with outstanding antibacterial effect
And preparation method thereof.
To solve the above problems, the present invention adopts the following technical scheme:
A kind of biomass graphene fabric, the raw material including following parts by weight proportion: including surface covering and by silver-colored fine
Five piece of three winged satin fabric base that warp thread and black alkene biomass fiber weft yarn are constituted is tieed up, the surface covering includes following weight
The raw material of number proportion: 33-65 parts of dialkyl polydimethylsiloxane, 18-25 parts of hydroxyl dimethyl silicone polymer, acrylic acid tree
22-26 parts of rouge, 3-6 parts of methyl tributanoximo silane, 1-3 parts of TSL 8330,1-2 parts of butyl titanate,
3-5 parts of hydroxypropyl acrylate, 17-20 parts of nano-titanium dioxide, 2-4 parts of 1,3- dimethyl-2-imidazolinone, benzene sulfinic acid sodium salt 2-
3 parts and glycidyl methacrylate 2-6 parts.
Further, fly including surface covering and be made of silver fiber warp thread and black alkene biomass fiber weft yarn five piece three
Satin fabric base, the surface covering include the raw material of following parts by weight proportion: 33 parts of dialkyl polydimethylsiloxane,
18 parts of hydroxyl dimethyl silicone polymer, 22 parts of acrylic resin, 3 parts of methyl tributanoximo silane, aminopropyl trimethoxy
1 part of silane, 1 part of butyl titanate, 3 parts of hydroxypropyl acrylate, 17 parts of nano-titanium dioxide, 1,3- dimethyl-2-imidazolinone 2
Part, 2 parts of benzene sulfinic acid sodium salt and 2 parts of glycidyl methacrylate.
Further, fly including surface covering and be made of silver fiber warp thread and black alkene biomass fiber weft yarn five piece three
Satin fabric base, the surface covering include the raw material of following parts by weight proportion: 65 parts of dialkyl polydimethylsiloxane,
25 parts of hydroxyl dimethyl silicone polymer, 26 parts of acrylic resin, 6 parts of methyl tributanoximo silane, aminopropyl trimethoxy
3 parts of silane, 2 parts of butyl titanate, 5 parts of hydroxypropyl acrylate, 20 parts of nano-titanium dioxide, 1,3- dimethyl-2-imidazolinone 4
Part, 3 parts of benzene sulfinic acid sodium salt and 6 parts of glycidyl methacrylate.
Further, fly including surface covering and be made of silver fiber warp thread and black alkene biomass fiber weft yarn five piece three
Satin fabric base, the surface covering include the raw material of following parts by weight proportion: 50 parts of dialkyl polydimethylsiloxane,
22 parts of hydroxyl dimethyl silicone polymer, 24 parts of acrylic resin, 4 parts of methyl tributanoximo silane, aminopropyl trimethoxy
2 parts of silane, 2 parts of butyl titanate, 4 parts of hydroxypropyl acrylate, 19 parts of nano-titanium dioxide, 1,3- dimethyl-2-imidazolinone 3
Part, 2 parts of benzene sulfinic acid sodium salt and 4 parts of glycidyl methacrylate.
Another technical problem to be solved by the present invention is that a kind of preparation method of biomass graphene fabric is provided, including with
Lower step:
1) it is interleaved silver fiber warp thread and black alkene biomass fiber weft yarn to obtain fabric, it is spare；
2) by 33-65 parts of dialkyl polydimethylsiloxane, 18-25 parts of hydroxyl dimethyl silicone polymer, acrylic resin
22-26 parts, 3-6 parts of methyl tributanoximo silane, 1-3 parts of TSL 8330,1-2 parts of butyl titanate, third
3-5 parts of olefin(e) acid hydroxypropyl acrylate, 17-20 parts of nano-titanium dioxide, 2-4 parts of 1,3- dimethyl-2-imidazolinone, benzene sulfinic acid sodium salt 2-3
Part is poured into reaction kettle together with glycidyl methacrylate 2-6 parts and carries out mixing processing, wherein the mixing
The mixing speed of stir process is 40-60r/min, and mixing time 1-2h obtains sizing material, spare；
3) sizing material made from step 2) is uniformly coated on fabric upper surface made from step 1) up to fabric.
The beneficial effects of the present invention are: by using five be made of silver fiber warp thread and black alkene biomass fiber weft yarn
Piece three winged satin fabrics can be contacted directly with foot as base, since silver fiber and graphene biomass fiber have
The sterilization of color and fungistatic effect can not only kill the bacterium in foot, while can prevent bacterium from breeding in shoe lining, have good
Good mould proof deodorizing effect, especially when wearing, in the environment of warm moist, silver ion has very high bioactivity, makes
The protein coagulating inside and outside bacterial cell membrane is obtained, to block the breathing and reproductive process of bacterial cell.
The characteristics of being the raw material of biomass graphene fabric below or effect:
Specific embodiment
Technical solution of the present invention is described below, it is clear that described embodiment is only present invention a part
Embodiment, instead of all the embodiments, to those skilled in the art, in the premise not made the creative labor
Under, other embodiments can also be obtained according to these embodiments.
Embodiment 1:
A kind of biomass graphene fabric, including surface covering and by silver fiber warp thread and black alkene biomass fiber weft yarn structure
At five piece of three winged satin fabric base, the surface covering includes the raw material of following parts by weight proportion: the poly- diformazan of dihydroxy
33 parts of radical siloxane, 18 parts of hydroxyl dimethyl silicone polymer, 22 parts of acrylic resin, 3 parts of methyl tributanoximo silane, amino
1 part of propyl trimethoxy silicane, 1 part of butyl titanate, 3 parts of hydroxypropyl acrylate, 17 parts of nano-titanium dioxide, 1,3- diformazan
2 parts of base -2- imidazolone, 2 parts of benzene sulfinic acid sodium salt and 2 parts of glycidyl methacrylate.
A kind of preparation method of biomass graphene fabric the following steps are included:
1) it is interleaved silver fiber warp thread and black alkene biomass fiber weft yarn to obtain fabric, it is spare；
2) by 33 parts of dialkyl polydimethylsiloxane, 18 parts of hydroxyl dimethyl silicone polymer, 22 parts of acrylic resin, first
3 parts of base tributanoximo silane, 1 part of butyl titanate, 3 parts of hydroxypropyl acrylate, is received 1 part of TSL 8330
17 parts of titanium dioxide of rice, 2 parts of 1,3- dimethyl-2-imidazolinone, 2 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate 2
Part, which is poured into together in reaction kettle, carries out mixing processing, wherein the mixing speed that processing is mixed is 40r/
Min, mixing time 1h obtain sizing material, spare；
3) sizing material made from step 2) is uniformly coated on fabric upper surface made from step 1) up to fabric.
Embodiment 2:
A kind of biomass graphene fabric, including surface covering and by silver fiber warp thread and black alkene biomass fiber weft yarn structure
At five piece of three winged satin fabric base, the surface covering includes the raw material of following parts by weight proportion: the poly- diformazan of dihydroxy
65 parts of radical siloxane, 25 parts of hydroxyl dimethyl silicone polymer, 26 parts of acrylic resin, 6 parts of methyl tributanoximo silane, amino
3 parts of propyl trimethoxy silicane, 2 parts of butyl titanate, 5 parts of hydroxypropyl acrylate, 20 parts of nano-titanium dioxide, 1,3- diformazan
4 parts of base -2- imidazolone, 3 parts of benzene sulfinic acid sodium salt and 6 parts of glycidyl methacrylate.
A kind of preparation method of biomass graphene fabric, comprising the following steps:
1) it is interleaved silver fiber warp thread and black alkene biomass fiber weft yarn to obtain fabric, it is spare；
2) by 65 parts of dialkyl polydimethylsiloxane, 25 parts of hydroxyl dimethyl silicone polymer, 26 parts of acrylic resin, first
6 parts of base tributanoximo silane, 2 parts of butyl titanate, 5 parts of hydroxypropyl acrylate, is received 3 parts of TSL 8330
20 parts of titanium dioxide of rice, 4 parts of 1,3- dimethyl-2-imidazolinone, 3 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate 6
Part, which is poured into together in reaction kettle, carries out mixing processing, wherein the mixing speed that processing is mixed is 60r/
Min, mixing time 2h obtain sizing material, spare；
3) sizing material made from step 2) is uniformly coated on fabric upper surface made from step 1) up to fabric.
Embodiment 3:
A kind of biomass graphene fabric, including surface covering and by silver fiber warp thread and black alkene biomass fiber weft yarn structure
At five piece of three winged satin fabric base, the surface covering includes the raw material of following parts by weight proportion: the poly- diformazan of dihydroxy
50 parts of radical siloxane, 22 parts of hydroxyl dimethyl silicone polymer, 24 parts of acrylic resin, 4 parts of methyl tributanoximo silane, amino
2 parts of propyl trimethoxy silicane, 2 parts of butyl titanate, 4 parts of hydroxypropyl acrylate, 19 parts of nano-titanium dioxide, 1,3- diformazan
3 parts of base -2- imidazolone, 2 parts of benzene sulfinic acid sodium salt and 4 parts of glycidyl methacrylate.
A kind of preparation method of biomass graphene fabric, comprising the following steps:
1) it is interleaved silver fiber warp thread and black alkene biomass fiber weft yarn to obtain fabric, it is spare；
2) by 50 parts of dialkyl polydimethylsiloxane, 22 parts of hydroxyl dimethyl silicone polymer, 24 parts of acrylic resin, first
4 parts of base tributanoximo silane, 2 parts of butyl titanate, 4 parts of hydroxypropyl acrylate, is received 2 parts of TSL 8330
19 parts of titanium dioxide of rice, 3 parts of 1,3- dimethyl-2-imidazolinone, 2 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate 4
Part, which is poured into together in reaction kettle, carries out mixing processing, wherein the mixing speed that processing is mixed is 50r/
Min, mixing time 1.5h obtain sizing material, spare；
3) sizing material made from step 2) is uniformly coated on fabric upper surface made from step 1) up to fabric.
Experimental example:
Experimental subjects: 120 triers, randomized are divided into 4 groups: experimental group 1, experimental group 2, experimental group 3 and control group, often
30 people of group.
Test method: the shoes that experimental group 1 is made using fabric made from embodiment 1；
The shoes that experimental group 2 is made using fabric made from embodiment 2；
The shoes that experimental group 3 is made using fabric made from embodiment 3；
Control group uses shoes on the market；
The use of the time is 14 days, then recycles at once and cut fabric, and using Bacteria Detection instrument M272969 to fabric
Medial surface (face directly contacted with foot) is detected.
4 groups of 14 days effects of user compare, and as a result see the table below:
By checking 3 groups of experiments, the RLU value that fabric produced by the present invention is surveyed is respectively less than 100, and RLU value is got over
Greatly, show that bacterium is more, see to find out that fabric produced by the present invention has outstanding sterilization antibacterial effect.
The beneficial effects of the present invention are: by using five be made of silver fiber warp thread and black alkene biomass fiber weft yarn
Piece three winged satin fabrics can be contacted directly with foot as base, since silver fiber and graphene biomass fiber have
The sterilization of color and fungistatic effect can not only kill the bacterium in foot, while can prevent bacterium from breeding in shoe lining, have good
Good mould proof deodorizing effect, especially when wearing, in the environment of warm moist, silver ion has very high bioactivity, makes
The protein coagulating inside and outside bacterial cell membrane is obtained, to block the breathing and reproductive process of bacterial cell.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of biomass graphene fabric, which is characterized in that including surface covering and by silver fiber warp thread and black alkene biomass
Five piece of three winged satin fabric base that fiber weft yarn is constituted, the surface covering include the raw material of following parts by weight proportion: two
33-65 parts of hydroxyl dimethyl silicone polymer, 18-25 parts of hydroxyl dimethyl silicone polymer, 22-26 parts of acrylic resin, methyl three
3-6 parts of butanone oximino silane, 1-3 parts of TSL 8330,1-2 parts of butyl titanate, hydroxypropyl acrylate 3-5
Part, 17-20 parts of nano-titanium dioxide, 2-4 parts of 1,3- dimethyl-2-imidazolinone, 2-3 parts of benzene sulfinic acid sodium salt and methacrylic acid
2-6 parts of ethylene oxidic ester.
2. a kind of biomass graphene fabric as described in claim 1, which is characterized in that including surface covering and by silver fiber
Five piece of three winged satin fabric base that warp thread and black alkene biomass fiber weft yarn are constituted, the surface covering includes following parts by weight
Number proportion raw materials: 33 parts of dialkyl polydimethylsiloxane, 18 parts of hydroxyl dimethyl silicone polymer, 22 parts of acrylic resin,
3 parts of methyl tributanoximo silane, 1 part of TSL 8330,1 part of butyl titanate, 3 parts of hydroxypropyl acrylate,
17 parts of nano-titanium dioxide, 2 parts of 1,3- dimethyl-2-imidazolinone, 2 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate
2 parts.
3. a kind of biomass graphene fabric as described in claim 1, which is characterized in that including surface covering and by silver fiber
Five piece of three winged satin fabric base that warp thread and black alkene biomass fiber weft yarn are constituted, the surface covering includes following parts by weight
Number proportion raw materials: 65 parts of dialkyl polydimethylsiloxane, 25 parts of hydroxyl dimethyl silicone polymer, 26 parts of acrylic resin,
6 parts of methyl tributanoximo silane, 3 parts of TSL 8330,2 parts of butyl titanate, 5 parts of hydroxypropyl acrylate,
20 parts of nano-titanium dioxide, 4 parts of 1,3- dimethyl-2-imidazolinone, 3 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate
6 parts.
4. a kind of biomass graphene fabric as described in claim 1, which is characterized in that including surface covering and by silver fiber
Five piece of three winged satin fabric base that warp thread and black alkene biomass fiber weft yarn are constituted, the surface covering includes following parts by weight
Number proportion raw materials: 50 parts of dialkyl polydimethylsiloxane, 22 parts of hydroxyl dimethyl silicone polymer, 24 parts of acrylic resin,
4 parts of methyl tributanoximo silane, 2 parts of TSL 8330,2 parts of butyl titanate, 4 parts of hydroxypropyl acrylate,
19 parts of nano-titanium dioxide, 3 parts of 1,3- dimethyl-2-imidazolinone, 2 parts of benzene sulfinic acid sodium salt and glycidyl methacrylate
4 parts.
5. a kind of preparation method of biomass graphene fabric, which comprises the following steps:
1) it is interleaved silver fiber warp thread and black alkene biomass fiber weft yarn to obtain fabric, it is spare；
2) by 33-65 parts of dialkyl polydimethylsiloxane, 18-25 parts of hydroxyl dimethyl silicone polymer, acrylic resin 22-26
Part, 3-6 parts of methyl tributanoximo silane, 1-3 parts of TSL 8330,1-2 parts of butyl titanate, acrylic acid hydroxyl
3-5 parts of propyl ester, 17-20 parts of nano-titanium dioxide, 2-4 parts of 1,3- dimethyl-2-imidazolinone, 2-3 parts of benzene sulfinic acid sodium salt and first
2-6 parts of base glycidyl acrylate are poured into reaction kettle together and carry out mixing processing, wherein at the mixing
The mixing speed of reason is 40-60r/min, and mixing time 1-2h obtains sizing material, spare；
3) sizing material made from step 2) is uniformly coated on fabric upper surface made from step 1) up to fabric.
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| CN207306097U (en) * | 2017-10-11 | 2018-05-04 | 青岛锦日盛家纺有限公司 | Novel and multifunctional socks |
| CN108385375A (en) * | 2018-03-20 | 2018-08-10 | 华南理工大学 | A kind of preparation method of super-hydrophobic antibiotic fabric |
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| CN105421088A (en) * | 2015-12-21 | 2016-03-23 | 常熟市金羽纤维制品厂 | Silver-fiber waterproof and moisture-permeable fabric |
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