CN107674578A - A kind of preparation method of radiation-proof fabric - Google Patents
A kind of preparation method of radiation-proof fabric Download PDFInfo
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- CN107674578A CN107674578A CN201710694461.7A CN201710694461A CN107674578A CN 107674578 A CN107674578 A CN 107674578A CN 201710694461 A CN201710694461 A CN 201710694461A CN 107674578 A CN107674578 A CN 107674578A
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- fabric
- radiation
- parts
- proof
- proof fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 115
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229920000914 Metallic fiber Polymers 0.000 claims abstract description 17
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 239000002105 nanoparticle Substances 0.000 claims abstract description 17
- 229910000077 silane Inorganic materials 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 238000009940 knitting Methods 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- ZHUWIYQJHBMTCY-UHFFFAOYSA-N 3-[ethoxy(2,2,2-triethoxyethoxy)silyl]propan-1-amine Chemical compound NCCC[SiH](OCC(OCC)(OCC)OCC)OCC ZHUWIYQJHBMTCY-UHFFFAOYSA-N 0.000 claims description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- YYAQTLYICNKRPF-UHFFFAOYSA-N aniline 3,5,5-trimethylcyclohex-2-en-1-one Chemical compound NC1=CC=CC=C1.CC1=CC(=O)CC(C)(C)C1 YYAQTLYICNKRPF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005543 nano-size silicon particle Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 claims 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 description 5
- 206010028980 Neoplasm Diseases 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical group CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- 206010000234 Abortion spontaneous Diseases 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- 208000032170 Congenital Abnormalities Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 206010021137 Hypovolaemia Diseases 0.000 description 1
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000036471 bradycardia Effects 0.000 description 1
- 208000006218 bradycardia Diseases 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 210000000748 cardiovascular system Anatomy 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 201000002364 leukopenia Diseases 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003176 neuroleptic agent Substances 0.000 description 1
- 230000000701 neuroleptic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 210000004994 reproductive system Anatomy 0.000 description 1
- 208000000995 spontaneous abortion Diseases 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/02—Layer formed of wires, e.g. mesh
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D177/00—Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/102—Oxide or hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of preparation method of radiation-proof fabric, at least two layers of the radiation-proof fabric：First layer is fabric substrate, and the composition of the second layer includes 5 10 parts of nano particles, 12 parts of adhesives, 35 parts of silane couplers, 10 20 parts of metallic fibers, 50 100 parts of resins.The radiation-proof fabric radiation proof efficiency of the present invention reaches more than 99%, and the second layer is very thin, general 0.03 0.05mm.The radiation-proof fabric manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and human body is not stimulated, and volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
Description
Technical field
The invention belongs to textile technology field, specifically relates to a kind of radiation-proof fabric.
Background technology
With the further development of electrical technology, radiate and be seen everywhere around us.The hand being either seen everywhere
Mechanical, electrical brain, printer, or household electrical appliance micro-wave oven, electric blanket, hair-dryer, can all there is certain radiation.Although household electrical appliance
Harm of the radiation for people without very big, but when the electric radiation of human body local environment exceedes certain intensity or produces certain
Cumulative effect when, can have the weaker old man of certain infringement, especially resistance, child, pregnant woman etc. to health.
The harm of radiation is a lot, such as：Children's intelligence can be caused incomplete；It is most likely the reason for causing children's cases with leukemia
One of；Cancer can be induced and accelerate the cancer cell multiplication of human body；The reproductive system of people is influenceed, is mainly shown as man's sperm matter
Amount reduces, and spontaneous abortion and fetal anomaly etc. occur for pregnant woman；The cardiovascular system of people is influenceed, palpitaition is shown as, hair loss, loses
Sleep, bradycardia, heartbeat oligemia, Neuroleptic Leukocytopenia, immunologic function decline etc..
Radiation-proof fabric in the market, usually with blending metallic fiber, conductive fiber, cost is high, not water-fastness,
Some people has allergic reaction, and therefore, searching is a kind of durable, and comfortable radiation-proof fabric is very important.
The content of the invention
It is an object of the invention to provide a kind of radiation-proof fabric and preparation method, to solve to propose in above-mentioned background technology
The problem of.
To achieve the above object, the present invention provides following technical scheme：
A kind of radiation-proof fabric, at least two layers of the radiation-proof fabric：First layer is fabric substrate；The composition of the second layer
Including 5-10 parts nano particle, 1-2 parts adhesive, 3-5 parts silane coupler, 10-20 parts metallic fiber, 50-100 part resins.
Preferably, described fabric substrate is knitting fabric, woven fabric, one kind in supatex fabric or wherein two
The combination of kind above fabric；It is knitted fabric or weft-knitted fabric to be knitted fabric；Woven fabric be plain cloth, twills or
Person's satin fabric.
Preferably, described nano particle is nano silicon, nano titanium oxide, nano ferriferrous oxide, nanometer
One or more than one kinds of mixtures in aluminum oxide.
Preferably, described adhesive is polyacrylate emulsion, polyurethane, one kind in methyl methacrylate or one
Kind thing mixed above.
Preferably, described silane coupler is 3- aminopropyl trimethoxysilanes, γ-(2,3- the third oxygen of epoxy) propyl group three
Ethoxysilane, γ-methacryloxypropyl trimethoxy silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy silicon
Any one in alkane, aniline isophorone and γ-aminopropyltriethoxy diethoxy silane or more than one mixture.
Preferably, described metallic fiber be silver plated fiber, plating aluminum fiber, Cu coated fibre, one kind in nickel plating fiber or
More than one mixture of person.
Preferably, described resin is in organic siliconresin, epoxy resin, polyamide, polyacrylics
One or more than one kinds of mixtures.
Preferably, a kind of preparation method of radiation-proof fabric, it is characterised in that：Comprise the following steps that：
Step 1, after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, it is low under oxygen atmosphere
The fabric that isothermal plasma is pre-processed；
Step 2, fabric face of the metallic fiber in step 1 is made into network；
Step 3,50-100 parts resin, 5-10 parts nano particle, 3-5 part silane couplers, 1000- are added in a kettle
3000 revs/min, stir 20-30 minutes；
Step 4, temperature is raised to 60-80 DEG C, adds 1-2 part adhesives, 500-1000 revs/min, stirring 20-30 divides
Clock；
Step 5,20-30 DEG C is cooled to, closes down stirring, the liquid prepared；
Step 6, by the solution of step 5 by spray, roll or roller coat in a manner of coated in step 2 fabric on；
Step 7, coated fabric is placed in 80-100 DEG C of baking oven and dried；
Step 8, after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, radiation-proof fabric radiation proof efficiency of the invention reaches more than 99%.
2nd, radiation-proof fabric manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic,
Human body is not stimulated, volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
3rd, mutual compatibility, synergy between various raw materials used in radiation-proof fabric of the invention, it is excellent to collectively constitute performance
Different product.
4th, the preparation of radiation-proof fabric of the invention is divided into two layers, substantially increases the radiation proof efficiency of fabric.
5th, technique is simplified, safe operation is simple, is easy to industrialized production.
6th, radiation-proof fabric of the invention can add the pigment of different colours according to demand, to prepare knitting for different color
Thing.
7th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of radiation-proof fabric, the radiation-proof fabric is at least formed by two layers：First layer is fabric
Matrix, the composition of the second layer include 5-10 parts nano particle, 1-2 parts adhesive, 3-5 parts silane coupler, 10-20 parts metal fibre
Dimension, 50-100 part resins.
Present invention also offers a kind of preparation method of radiation-proof fabric, comprise the following steps that：
(1) after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature
The fabric that plasma is pre-processed；
(2) fabric face of the metallic fiber in step (1) is made into network；
(3) 50-100 parts resin, 5-10 parts nano particle, 3-5 part silane couplers, 1000- are added in a kettle
3000 revs/min, stir 20-30 minutes；
(4) temperature is raised to 60-80 DEG C, is added 1-2 part adhesives, 500-1000 revs/min, is stirred 20-30 minutes；
(5) 20-30 DEG C is cooled to, closes down stirring, the liquid prepared；
(6) by the solution of (5) by spray, roll or roller coat in a manner of coated in step (2) fabric on；
(7) coated fabric is placed in 80-100 DEG C of baking oven and dried；
(8) after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Embodiment 1
The invention discloses a kind of radiation-proof fabric, the radiation-proof fabric is at least formed by two layers：First layer is fabric
Matrix, the composition of the second layer include 5 parts of nano particles, 1 part of adhesive, 3 parts of silane couplers, 10 parts of metallic fibers, 50 parts of trees
Fat.
Present invention also offers a kind of preparation method of radiation-proof fabric, comprise the following steps that：
(1) after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature
The fabric that plasma is pre-processed；
(2) fabric face of the metallic fiber in step (1) is made into network；
(3) 50 parts of resins, 5 parts of nano particles, 3 parts of silane couplers are added in a kettle, 1000 revs/min, are stirred
20 minutes；
(4) temperature is raised to 60 DEG C, is added 1 part of adhesive, 500 revs/min, is stirred 20 minutes；
(5) 20 DEG C are cooled to, closes down stirring, the liquid prepared；
(6) by the solution of (5) by spray, roll or roller coat in a manner of coated in step (2) fabric on；
(7) coated fabric is placed in 80 DEG C of baking ovens and dried；
(8) after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Embodiment 2
The invention discloses a kind of radiation-proof fabric, the radiation-proof fabric is at least formed by two layers：First layer is fabric
Matrix, the composition of the second layer include 8 parts of nano particles, 1.5 parts of adhesives, 4 parts of silane couplers, 15 parts of metallic fibers, 75 parts
Resin.
Present invention also offers a kind of preparation method of radiation-proof fabric, comprise the following steps that：
(1) after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature
The fabric that plasma is pre-processed；
(2) fabric face of the metallic fiber in step (1) is made into network；
(3) 75 parts of resins, 8 parts of nano particles, 4 parts of silane couplers are added in a kettle, 2000 revs/min, are stirred
25 minutes；
(4) temperature is raised to 70 DEG C, is added 1.5 parts of adhesives, 750 revs/min, is stirred 25 minutes；
(5) 25 DEG C are cooled to, closes down stirring, the liquid prepared；
(6) by the solution of (5) by spray, roll or roller coat in a manner of coated in step (2) fabric on；
(7) coated fabric is placed in 90 DEG C of baking ovens and dried；
(8) after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Embodiment 3
The invention discloses a kind of radiation-proof fabric, the radiation-proof fabric is at least formed by two layers：First layer is fabric
Matrix, the composition of the second layer include 10 parts of nano particles, 2 parts of adhesives, 5 parts of silane couplers, 20 parts of metallic fibers, 100 parts
Resin.
Present invention also offers a kind of preparation method of radiation-proof fabric, comprise the following steps that：
(1) after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature
The fabric that plasma is pre-processed；
(2) fabric face of the metallic fiber in step (1) is made into network；
(3) 100 parts of resins, 10 parts of nano particles, 5 parts of silane couplers are added in a kettle, 3000 revs/min, are stirred
Mix 30 minutes；
(4) temperature is raised to 80 DEG C, is added 2 parts of adhesives, 1000 revs/min, is stirred 30 minutes；
(5) 30 DEG C are cooled to, closes down stirring, the liquid prepared；
(6) by the solution of (5) by spray, roll or roller coat in a manner of coated in step (2) fabric on；
(7) coated fabric is placed in 100 DEG C of baking ovens and dried；
(8) after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Embodiment 4
The invention discloses a kind of radiation-proof fabric, the radiation-proof fabric is at least formed by two layers：First layer is fabric
Matrix, the composition of the second layer include 10 parts of nano particles, 2 parts of adhesives, 3 parts of silane couplers, 20 parts of metallic fibers, 80 parts of trees
Fat.
Present invention also offers a kind of preparation method of radiation-proof fabric, comprise the following steps that：
(1) after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature
The fabric that plasma is pre-processed；
(2) fabric face of the metallic fiber in step (1) is made into network；
(3) 80 parts of resins, 10 parts of nano particles, 3 parts of silane couplers are added in a kettle, 3000 revs/min, are stirred
30 minutes；
(4) temperature is raised to 80 DEG C, is added 2 parts of adhesives, 1000 revs/min, is stirred 20 minutes；
(5) 20 DEG C are cooled to, closes down stirring, the liquid prepared；
(6) by the solution of (5) by spray, roll or roller coat in a manner of coated in step (2) fabric on；
(7) coated fabric is placed in 100 DEG C of baking ovens and dried；
(8) after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
Test case
4 pieces of identical pure cotton cloths are made into 4 pieces of cloth with shielding property with the method for embodiment 1,2,3,4.Test is anti-
The result of radiation efficiency is as follows：
| Embodiment | Radiation proof efficiency (%) |
| 1 | 99 |
| 2 | 99.5 |
| 3 | 99.9 |
| 4 | 99.6 |
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
- A kind of 1. radiation-proof fabric, it is characterised in that：At least two layers of the radiation-proof fabric：First layer is fabric substrate；The Two layers of composition includes 5-10 parts nano particle, 1-2 parts adhesive, 3-5 parts silane coupler, 10-20 parts metallic fiber, 50- 100 parts of resins.
- 2. radiation-proof fabric according to claim 1, it is characterised in that：Described fabric substrate is knitting fabric, woven The combination of one kind or two of which above fabric in fabric, supatex fabric；It is knitted fabric or weft knitting to be knitted fabric Fabric；Woven fabric is plain cloth, twills or satin fabric.
- 3. radiation-proof fabric according to claim 1, it is characterised in that：Described nano particle be nano silicon, One or more than one kinds of mixtures in nano titanium oxide, nano ferriferrous oxide, nano aluminium oxide.
- 4. radiation-proof fabric according to claim 1, it is characterised in that：Described adhesive is polyacrylate emulsion, gathered One or more than one kinds of mixtures in urethane, methyl methacrylate.
- 5. radiation-proof fabric according to claim 1, it is characterised in that：Described silane coupler is 3- aminopropyl front threes TMOS, γ-(oxygen of 2,3- epoxies third) propyl-triethoxysilicane, γ-methacryloxypropyl trimethoxy silane, In N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, aniline isophorone and γ-aminopropyltriethoxy diethoxy silane Any one or more than one mixture.
- 6. radiation-proof fabric according to claim 1, it is characterised in that：Described metallic fiber is silver plated fiber, aluminized One or more than one kinds of mixtures in fiber, Cu coated fibre, nickel plating fiber.
- 7. radiation-proof fabric according to claim 1, it is characterised in that：Described resin is organic siliconresin, asphalt mixtures modified by epoxy resin One or more than one kinds of mixtures in fat, polyamide, polyacrylics.
- A kind of a kind of 8. preparation method of any described radiation-proof fabric in 1-7 using the claims, it is characterised in that： Comprise the following steps that：Step 1, after fabric face being cleaned into drying, it is placed in the device of low temperature plasma, under oxygen atmosphere, low temperature etc. The fabric that gas ions are pre-processed；Step 2, fabric face of the metallic fiber in step 1 is made into network；Step 3,50-100 parts resin, 5-10 parts nano particle, 3-5 part silane couplers, 1000-3000 are added in a kettle Rev/min, stir 20-30 minutes；Step 4, temperature is raised to 60-80 DEG C, is added 1-2 part adhesives, 500-1000 revs/min, is stirred 20-30 minutes；Step 5,20-30 DEG C is cooled to, closes down stirring, the liquid prepared；Step 6, by the solution of step 5 by spray, roll or roller coat in a manner of coated in step 2 fabric on；Step 7, coated fabric is placed in 80-100 DEG C of baking oven and dried；Step 8, after drying is completed, standing is cooled to room temperature, you can to obtain radiation-proof fabric.
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| CN109972405A (en) * | 2019-04-04 | 2019-07-05 | 六安市海洋羽毛有限公司 | A kind of processing method with shielding electromagnetic radiation and anti-static function natural feather |
| CN110130114A (en) * | 2019-04-25 | 2019-08-16 | 王兵兵 | A kind of biomass graphene fabric and preparation method thereof |
| CN110481104A (en) * | 2019-08-22 | 2019-11-22 | 深圳玛丝菲尔噢姆服饰有限公司 | A kind of summer radiation-proof ventilated composite material and preparation method thereof |
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Application publication date: 20180209 |