CN110129954A - Antistatic knitting fabric of one kind and preparation method thereof - Google Patents
Antistatic knitting fabric of one kind and preparation method thereof Download PDFInfo
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- CN110129954A CN110129954A CN201910399675.0A CN201910399675A CN110129954A CN 110129954 A CN110129954 A CN 110129954A CN 201910399675 A CN201910399675 A CN 201910399675A CN 110129954 A CN110129954 A CN 110129954A
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- Prior art keywords
- antistatic
- fiber
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- conductive composite
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-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a kind of antistatic knitting fabrics, contain the following parts by weight: 90~160 parts of graphene conductive composite fibres, 22~38 parts of tencels, 10~20 parts of copper ammonia fiber, 32~55 portions of cottons, 10~15 parts of antistatic agents, graphene conductive composite fibre include 0.5~1.5 part of graphene, 80~140 parts of spandex matrix fibers；The preparation method of graphene conductive composite fibre: S1, pretreatment, it is S2, dry-mixed, S3, granulation is blended, S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 210~220 DEG C, winding speed is set as 1400~2600m/min, nascent conductive fiber is obtained, S5, drafting forming: drawing-off being carried out to nascent conductive fiber, drawing temperature is 95~125 DEG C, drafting multiple is 3~6 times, finally obtains graphene conductive composite fibre.Antistatic knitting fabric of the invention has comfortable soft, ventilative nice and cool, the advantage that antistatic property is lasting, efficient.
Description
Technical field
The present invention relates to fabric processing technique field, in particular to a kind of antistatic knitting fabric and preparation method thereof.
Background technique
Fabric is the material for making clothes, can not only annotate the style of clothes as one of clothes three elements
And characteristic, and it is directly related to the expression effect of clothing color, moulding.With being gradually increased for people's living standard, people
The requirement of more and more functional and style aspects is proposed to fabric, therefore conventional fabric can no longer meet market
Demand.
Functional fiber specifically includes that modified fibre, such as in the modified acquisition anti-pilling, antistatic property, parent of feed stage
Aqueous, anti-flammability etc.；Functional topical finishing generally comprises: comfort finishing, be embodied in ventilative, moisture-inhibiting, it is slim and graceful, smooth, prevent it is quiet
The arrangement of electricity etc..Wholesomeness arranges, and embodies its antistatic deodorization；Protective arrange, be embodied in fire-retardant, uvioresistant,
Radiation protection etc.；Health arranges, and is embodied in beauty pro-skin, far infrared；Easily keeping property arranges, and is embodied in crease-resistant, mothproof function
It arranges；The feature of environmental protection arranges, and is embodied in ring close friend, green non-pollution.
Existing notification number is the Chinese invention patent of CN105133165B, discloses a kind of system of antistatic high temperature resistant fabric
Preparation Method, comprising the following steps: Step 1: using highly dense knitted fabric as base fabric, using special antistatic high temperature resistant coating to it
It is coated；It sufficiently stirs evenly, prepares Step 2: a certain proportion of butanone, polyurethane, promotor and phosphate are added to the container
Fire retardant glue sprays fire retardant glue to the curtain base fabric front and back sides of coated antistatic high temperature resistant coating；Step 3: step 2 is handled
Base fabric afterwards is washed, dries, is baked, and antistatic high temperature resistant fabric is made.
Although by preparing anti-static coatings in prior art, and being formed in scrim surfaces by way of coating anti-
Electrostatic coating, to play anti-static effect, but the antistatic performance of anti-static coating can be with the use of fabric, washing gradually
Decaying, therefore other than coating anti-static coating, the antistatic property of face liber itself is also improved, can just reach hold in this way
Long efficient anti-static effect.
Summary of the invention
The purpose of the present invention is to provide a kind of antistatic knitting fabrics and preparation method thereof, and manufactured fabric has comfortable
Softness is breathed freely nice and cool, the advantage that antistatic property is lasting, efficient.
To achieve the above object, the present invention provides the following technical scheme that a kind of antistatic knitting fabric, includes following heavy
Measure the component of part:
90~160 parts of graphene conductive composite fibres, 22~38 parts of tencels, 10~20 parts of copper ammonia fiber, 32~55 portions of cottons, 10~
15 parts of antistatic agents.
By using above-mentioned technical proposal, graphene conductive composite fibre is a kind of by graphene and particular kind of fiber
In conjunction with tencel can significantly improve fiber and fabric antistatic property using the antistatic property that graphene is excellent.Phase
For traditional inorganic, organic antistatic agents, graphene is green safe, more suitable for human skin, the work with pro-skin foster skin
With；On the other hand, graphene conductive is high, in conjunction with general carbon fiber, the electric conductivity of fiber can be improved, and then increase fabric
Permanent antistatic performance.
Tencel is a kind of highly-flexible fiber of silk that can match in excellence or beauty, and has hygroscopicity more better than cotton, frivolous easy to wash easily dry,
There is good biocidal property, bacteria breed can be effectively reduced, manufactured fabric has good washing dimensional stability, washing contracting
Water rate is small, bright color, is a kind of natural mercerising fabric.
The fibre section of copper ammonia fiber is rounded, no skin-core structure, and fiber can bear high elongation, monofilament obtained compared with
Carefully, the feel and pliability of fabric can be improved；On the other hand, the sucting wet air permeability of copper ammonia fiber is good, drapability is high, and has
Preferable antistatic property can be further improved the antistatic property of fabric.
Cotton fiber softness skin-friendly is good, moisture absorbing and sweat releasing and abundant raw materials are cheap, can be further improved the dress of fabric
Comfort level, while the processing cost of fabric can also be reduced.
Antistatic agent is added in fabric antistatic finish process, antistatic agent can be adsorbed, infiltrate into face liber
Inside, to further increase the antistatic property of fabric.
The present invention is further arranged to, and the graphene conductive composite fibre includes 0.5~1.5 part of graphene, 80~140
Part matrix fiber.
By using above-mentioned technical proposal, graphene and matrix fiber are organically combined, so that fiber has the spy of graphene
Property and function, to assign antistatic, the antistatic property of fabric persistent high efficiency.
The present invention is further arranged to, and described matrix fiber is in spandex.
By using above-mentioned technical proposal, elastomeric polyurethane fiber is excellent, and intensity is high, and line density is thinner, chemically-resistant degradation, acid and alkali-resistance
Property, sweat proof, dry cleaning resistance and wearability it is preferable, spandex since molecular structure is closer and amino acid molecular structure, pro-skin relax
Adaptive is good.
The present invention is further arranged to, and the preparation method of the graphene conductive composite fibre includes the following steps:
The preparation method of the graphene conductive composite fibre, includes the following steps:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 70~95 DEG C, drying time
For 6~12h；
It is S2, dry-mixed: graphene, matrix fiber are put into high-speed mixer, 250~320rpm of revolving speed is adjusted, mixes 1~3min,
850~950rpm of revolving speed is adjusted again, continuess to mix 1~2min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 200~215 DEG C, and revolving speed is 90~150rpm, and the melt blending time is 25~30min, and melt blended material squeezes out cooling, warp
Pelletizing obtains conducting fibre master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 210~220 DEG C, volume
It is set as 1400~2600m/min around speed, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 95~125 DEG C, and drafting multiple is 3~6 times,
Finally obtain graphene conductive composite fibre.
It is by using above-mentioned technical proposal, the graphene after vacuum drying, matrix fiber progress is dry-mixed, graphite can be made
Alkene is uniformly mixed with matrix fiber, obtains conducting base fibre blend, then carry out melt blending by twin-screw blender, from
And so that graphene and matrix fiber is carried out depth integration, graphene can evenly spread to fibrous inside, improve graphene with
The fastness that fiber combines；Again by carrying out melt spinning to graphene fiber master batch, it is higher nascent conductive fine to obtain dispersion degree
Dimension, then the degree of orientation and crystallinity inside nascent conductive fiber are improved by drafting forming, to further increase fiber
Intensity and elongation.
The present invention is further arranged to, and the antistatic agent is organosilicon quaternary ammonium salt antistatic agent.
By using above-mentioned technical proposal, organosilicon quaternary ammonium salt is the good antistatic agent of a kind of comprehensive performance, and arrangement is knitted
Such antistatic agent does not need high temperature baking when object, just can produce lasting antistatic effect after general drying, knitting after arrangement
Object not only has excellent antistatic property, but also is also equipped with good moisture absorption absorption of perspiration, flexibility, resilience, static electricity resistance,
And pollution resistance.
The present invention is further arranged to, the preparation method of the antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, obtain conductive hybrid yarn
Line；
S2, mercerising: scribbled in S1 step is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the mercerized yarn that S2 step is obtained carries out warping on sectional warper, and speed of beaming is 150~
170m/min, beaming speed are 105~130m/min；
S4, face weave: warp thread and weft yarn that S3 step obtains are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 7%~15% walks S4
Rapid fabric is impregnated in antistatic agent solution, and bath raio is (1:4)~(1:6), and dip time is 40~60min, after dipping
It is dried at 70~85 DEG C, 30~35min of drying time；
S6, final finishing: the fabric of S5 step is subjected to final finishing.
It is blended to obtain conductive hybrid yarn by using above-mentioned technical proposal, so that yarn is had the composite attribute of multifilament
And function, to provide the antistatic property of high-efficient and lasting for fabric；Mercerising improve fiber especially cotton fiber intensity and
Lustrous surface, so that the colourability of fiber further increases；Antistatic and final finishing is carried out to fabric, so that fabric antistatic property
Energy, wrinkle resistance, feel etc. have further promotion.
The present invention is further arranged to, and the number of conductive hybrid yarn is 30~50 in the S1 step.
By using above-mentioned technical proposal, the conductive hybrid yarn in the count range have preferably hang down it is pliable and strong
Degree, can be improved the weavability and fabric hand feel of fabric.
The present invention is further arranged to, and the finishing process in the S6 step includes dyeing and finishing, washing, sizing, preshrunk work
Sequence.
By using above-mentioned technical proposal, washing can be removed the loose colour of web surface and impurity, and pass through and be formed, is pre-
Contracting can effectively reduce the washing contraction distortion in the subsequent use process of fabric.
In conclusion the invention has the following advantages:
1. the graphene conductive composite fibre in the present invention, by by graphene, spandex matrix fiber in twin-screw blender
It is blended and is granulated, form conducting fibre master batch, then conducting fibre master batch is formed into graphene conductive composite fibre by melt spinning,
Obtain graphene in conjunction with high degree of dispersion in molecular level with fiber, to obtain almost permanent property antistatic property；
It is high using copper ammonia fiber sucting wet air permeability, drapability is good 2. add copper ammonia fiber in the fabric in the present invention, and have compared with
The characteristics of antistatic property got well, achieve the effect that further increase fabric snugness of fit and antistatic property；
3. the fabric in the present invention passes through the antistatic finish of organosilicon quaternary ammonium salt antistatic agent finishing fluid, so that antistatic agent is inhaled
Attached and infiltration is into face liber, to achieve the effect that further increase fabric antistatic property.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Embodiment
Embodiment 1:
A kind of antistatic knitting fabric, contains the following parts by weight:
90 parts of graphene conductive composite fibres, 22 parts of tencels, 10 parts of copper ammonia fiber, 32 portions of cottons, 10 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 0.5 part of graphene, 80 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: 0.5 part of graphene, 80 parts of matrix fibers are put into vacuum drying oven drying, drying temperature is 70 DEG C, dry
Time is 6h；
It is S2, dry-mixed: graphene, the matrix fiber after drying are put into high-speed mixer, revolving speed 250rpm is adjusted, mixes 1min,
Revolving speed 850rpm is adjusted again, continuess to mix 1min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 200 DEG C, revolving speed 90rpm, and the melt blending time is 25min, and melt blended material squeezes out cooling, obtains conductive fibre through pelletizing
Tie up master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 210 DEG C, winding speed
It is set as 1400m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 95 DEG C, and drafting multiple is 3 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 30 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 150m/min, beaming on sectional warper
Speed is 105m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 7%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:4, and dip time is 40 minutes, is dried at 70 DEG C after dipping, is dried
Time is 30min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Embodiment 2:
A kind of antistatic knitting fabric, contains the following parts by weight:
110 parts of graphene conductive composite fibres, 26 parts of tencels, 12 parts of copper ammonia fiber, 38 portions of cottons, 11 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 0.7 part of graphene, 90 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 75 DEG C, and drying time is
7h；
It is S2, dry-mixed: graphene, matrix fiber being put into high-speed mixer, revolving speed 270rpm is adjusted, mixes 1min, then adjust and turn
Fast 870rpm, continuess to mix 1min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 205 DEG C, revolving speed 100rpm, and the melt blending time is 26min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Fiber master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 212 DEG C, winding speed
It is set as 1600m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 105 DEG C, and drafting multiple is 4 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 30 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 155m/min, beaming on sectional warper
Speed is 110m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 9%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:4, and dip time is 45 minutes, is dried at 75 DEG C after dipping, is dried
Time is 31min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Embodiment 3:
A kind of antistatic knitting fabric, contains the following parts by weight:
130 parts of graphene conductive composite fibres, 30 parts of tencels, 14 parts of copper ammonia fiber, 40 portions of cottons, 12 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 0.9 part of graphene, 100 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 80 DEG C, and drying time is
8h；
It is S2, dry-mixed: graphene, matrix fiber being put into high-speed mixer, revolving speed 280rpm is adjusted, mixes 2min, then adjust and turn
Fast 890rpm, continuess to mix 1.5min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 210 DEG C, revolving speed 110rpm, and the melt blending time is 27min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Fiber master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 214 DEG C, winding speed
It is set as 1800m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 110 DEG C, and drafting multiple is 5 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 40 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 160m/min, beaming on sectional warper
Speed is 115m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 11%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:5, and dip time is 50 minutes, is dried at 75 DEG C after dipping, is dried
Time is 32min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Embodiment 4:
A kind of antistatic knitting fabric, contains the following parts by weight:
140 parts of graphene conductive composite fibres, 34 parts of tencels, 16 parts of copper ammonia fiber, 50 portions of cottons, 13 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 1.1 parts of graphene, 120 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 85 DEG C, and drying time is
9h；
It is S2, dry-mixed: graphene, matrix fiber being put into high-speed mixer, revolving speed 290rpm is adjusted, mixes 2min, then adjust and turn
Fast 910rpm, continuess to mix 1.5min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 215 DEG C, revolving speed 120rpm, and the melt blending time is 28min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Fiber master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 216 DEG C, winding speed
It is set as 2000m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 115 DEG C, and drafting multiple is 5 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 40 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 165m/min, beaming on sectional warper
Speed is 120m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 13%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:5, and dip time is 55 minutes, is dried at 80 DEG C after dipping, is dried
Time is 33min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Embodiment 5:
A kind of antistatic knitting fabric, contains the following parts by weight:
150 parts of graphene conductive composite fibres, 36 parts of tencels, 18 parts of copper ammonia fiber, 53 portions of cottons, 14 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 1.3 parts of graphene, 140 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 90 DEG C, and drying time is
10h；
It is S2, dry-mixed: graphene, matrix fiber being put into high-speed mixer, revolving speed 300rpm is adjusted, mixes 3min, then adjust and turn
Fast 930rpm, continuess to mix 2min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 215 DEG C, revolving speed 130rpm, and the melt blending time is 29min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Fiber master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 218 DEG C, winding speed
It is set as 2200m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 120 DEG C, and drafting multiple is 6 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 50 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 170m/min, beaming on sectional warper
Speed is 125m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 15%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:6, and dip time is 60 minutes, is dried at 80 DEG C after dipping, is dried
Time is 34min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Embodiment 6:
A kind of antistatic knitting fabric, contains the following parts by weight:
160 parts of graphene conductive composite fibres, 38 parts of tencels, 20 parts of copper ammonia fiber, 55 portions of cottons, 15 parts of antistatic agents；Wherein, stone
Black alkene electrically conductive composite fibre includes 1.5 parts of graphene, 150 parts of matrix fiber.
The preparation step of graphene conductive composite fibre is as follows:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 95 DEG C, and drying time is
12h；
It is S2, dry-mixed: graphene, matrix fiber being put into high-speed mixer, revolving speed 320rpm is adjusted, mixes 3min, then adjust and turn
Fast 950rpm, continuess to mix 2min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 215 DEG C, revolving speed 150rpm, and the melt blending time is 30min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Fiber master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 220 DEG C, winding speed
It is set as 2600m/min, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 125 DEG C, and drafting multiple is 6 times, is finally obtained
Graphene conductive composite fibre.
The preparation method of antistatic knitting fabric, comprising the following steps:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, it is mixed to obtain 50 conductions
Yarn；
S2, mercerising: conductive hybrid yarn is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the yarn after mercerising is subjected to warping, speed of beaming 170m/min, beaming on sectional warper
Speed is 130m/min；
S4, face weave: warp thread and weft yarn are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 15%, by the face of S4 step
Material is impregnated in antistatic agent solution, bath raio 1:6, and dip time is 60 minutes, is dried at 85 DEG C after dipping, is dried
Time is 35min；
S6, final finishing: the fabric of S5 step is subjected to dyeing and finishing, washing, sizing, preshrunk final finishing.
Performance detection
The consistent sample fabric of 5 block specifications is respectively prepared according to the method for Examples 1 to 6, and is tried according to the following terms Indexs measure
Sample fabric, the test result of sample fabric as made from the same embodiment are averaged, and test result is as shown in table 1:
Antistatic property according to GB/T 24249-2009 standard testing fabric surface resistivity；
The indices test result of sample fabric made from 1 the above various embodiments of table
| Test item | Feel and pliability | Grammes per square metre g/m2 | Surface resistivity/Ω |
| Embodiment 1 | Comfortable feel is soft | 128 | 7.6×108 |
| Embodiment 2 | Comfortable feel is soft | 130 | 7.1×108 |
| Embodiment 3 | Comfortable feel is soft | 132 | 8.2×108 |
| Embodiment 4 | Comfortable feel is soft | 129 | 8.1×108 |
| Embodiment 5 | Comfortable feel is soft | 131 | 7.9×108 |
| Embodiment 6 | Comfortable feel is soft | 130 | 8.5×108 |
As can be seen from Table 1, the comfortable feel and pliability of 1-6 of embodiment of the present invention sample fabric are preferable, and embodiment 1~
The grammes per square metre of 6 sample fabrics is relatively low, and illustrates that fabric of the invention is slim and graceful, is more suitable dress；It is real in terms of antistatic property
The surface resistivity for applying 1~6 fabric of example reaches 7.0 × 108More than, illustrate multiple using graphene conductive in fabric of the invention
Condensating fiber and cuprammonium antistatic fibre, and by the final finishing of antistatic agent finishing fluid, can achieve significantly improve fabric resist it is quiet
The effect of electrical property.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (8)
1. a kind of antistatic knitting fabric, it is characterised in that: contain the following parts by weight:
90~160 parts of graphene conductive composite fibres, 22~38 parts of tencels, 10~20 parts of copper ammonia fiber, 32~55 portions of cottons, 10~
15 parts of antistatic agents.
2. a kind of antistatic knitting fabric according to claim 1, it is characterised in that: the graphene conductive composite fibre
Including 0.5~1.5 part of graphene, 80~140 parts of matrix fibers.
3. a kind of antistatic knitting fabric according to claim 2, it is characterised in that: described matrix fiber is spandex.
4. a kind of antistatic knitting fabric according to claim 2, it is characterised in that: the graphene conductive composite fibre
Preparation method, include the following steps:
S1, pretreatment: graphene, matrix fiber are dried in vacuum drying oven, and drying temperature is 70~95 DEG C, drying time
For 6~12h；
It is S2, dry-mixed: graphene, matrix fiber are put into high-speed mixer, 250~320rpm of revolving speed is adjusted, mixes 1~3min,
850~950rpm of revolving speed is adjusted again, continuess to mix 1~2min, obtains conducting base fiber premix；
S3, granulation is blended: conducting base fiber premix investment twin-screw blender is subjected to blending granulation, melt blending temperature
Degree is 200~215 DEG C, and revolving speed is 90~150rpm, and the melt blending time is 25~30min, and melt blended material squeezes out cooling, warp
Pelletizing obtains conducting fibre master batch；
S4, melt spinning: using melt spinning machine to conducting fibre master batch melt spinning, spinning temperature is 210~220 DEG C, volume
It is set as 1400~2600m/min around speed, obtains nascent conductive fiber；
S5, drafting forming: carrying out drawing-off to nascent conductive fiber, and drawing temperature is 95~125 DEG C, and drafting multiple is 3~6 times,
Finally obtain graphene conductive composite fibre.
5. a kind of antistatic knitting fabric according to claim 1, it is characterised in that: the antistatic agent is organosilicon season
Ammonium salt antistatic agent.
6. according to claim 1~5 it is described in any item it is antistatic knitting fabrics preparation methods, which is characterized in that including with
Lower step:
S1, scribbled: the progress of graphene conductive composite fibre, tencel, copper ammonia fiber and cotton is blended, obtain conductive hybrid yarn
Line；
S2, mercerising: scribbled in S1 step is subjected to mercerization finish on mercerizing machine；
S3, warping weaving: the mercerized yarn that S2 step is obtained carries out warping, speed of beaming 150- on sectional warper
170m/min, beaming speed are 105-130m/min；
S4, face weave: warp thread and weft yarn that S3 step obtains are weaved；
S5, antistatic finish: the machine silicon quaternary ammonium salt antistatic agent solution that configuration quality percentage concentration is 7%~15%, by S4 step
Fabric be impregnated in antistatic agent solution, bath raio is (1:4)~(1:6), and dip time is 40~60min, 70 after dipping
It is dried at~85 DEG C, drying time is 30~35min；
S6, final finishing: the fabric of S5 step is subjected to final finishing.
7. the preparation method of the antistatic knitting fabric of one kind according to claim 6, it is characterised in that: in the S1 step
Conductive hybrid yarn number be 30~50.
8. the preparation method of the antistatic knitting fabric of one kind according to claim 6, it is characterised in that: in the S6 step
Finishing process include dyeing and finishing, washing, sizing, shrinking processes.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112273750A (en) * | 2020-09-25 | 2021-01-29 | 上海燕莎服饰有限公司 | Double-faced woolen overcoat and manufacturing method thereof |
| CN112853521A (en) * | 2020-12-30 | 2021-05-28 | 杭州东南纺织有限公司 | Production method of anti-static POY (polyester pre-oriented yarn) |
| CN113818251A (en) * | 2021-09-22 | 2021-12-21 | 浙江迪亚服饰有限公司 | Down jacket fabric with anti-static function and manufacturing process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103498212A (en) * | 2013-09-23 | 2014-01-08 | 绍兴文理学院 | Toughening type conductive polylactic acid fiber and preparation method and application thereof |
| CN105463598A (en) * | 2015-11-16 | 2016-04-06 | 四川大学 | Graphite-enhanced ultrafine synthetic leather fiber |
| CN103882601B (en) * | 2014-04-01 | 2016-04-27 | 晋江万兴隆染织实业有限公司 | A kind of preparation method of antibacterial antistatic color-woven fabric |
| CN106065498A (en) * | 2016-06-04 | 2016-11-02 | 江苏启弘新材料科技有限公司 | The preparation method of antistatic fibre based on point discharge effect |
| CN108677307A (en) * | 2018-08-09 | 2018-10-19 | 魏桥纺织股份有限公司 | A kind of graphene modified fibre scribbled, fabric and its production technology |
| CN109082727A (en) * | 2018-07-12 | 2018-12-25 | 山东佳星环保科技有限公司 | A kind of preparation method for the polyester blended fabric that graphene is modified |
-
2019
- 2019-05-14 CN CN201910399675.0A patent/CN110129954A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103498212A (en) * | 2013-09-23 | 2014-01-08 | 绍兴文理学院 | Toughening type conductive polylactic acid fiber and preparation method and application thereof |
| CN103882601B (en) * | 2014-04-01 | 2016-04-27 | 晋江万兴隆染织实业有限公司 | A kind of preparation method of antibacterial antistatic color-woven fabric |
| CN105463598A (en) * | 2015-11-16 | 2016-04-06 | 四川大学 | Graphite-enhanced ultrafine synthetic leather fiber |
| CN106065498A (en) * | 2016-06-04 | 2016-11-02 | 江苏启弘新材料科技有限公司 | The preparation method of antistatic fibre based on point discharge effect |
| CN109082727A (en) * | 2018-07-12 | 2018-12-25 | 山东佳星环保科技有限公司 | A kind of preparation method for the polyester blended fabric that graphene is modified |
| CN108677307A (en) * | 2018-08-09 | 2018-10-19 | 魏桥纺织股份有限公司 | A kind of graphene modified fibre scribbled, fabric and its production technology |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112273750A (en) * | 2020-09-25 | 2021-01-29 | 上海燕莎服饰有限公司 | Double-faced woolen overcoat and manufacturing method thereof |
| CN112853521A (en) * | 2020-12-30 | 2021-05-28 | 杭州东南纺织有限公司 | Production method of anti-static POY (polyester pre-oriented yarn) |
| CN112853521B (en) * | 2020-12-30 | 2022-04-26 | 杭州东南纺织有限公司 | Production method of anti-static POY (polyester pre-oriented yarn) |
| CN113818251A (en) * | 2021-09-22 | 2021-12-21 | 浙江迪亚服饰有限公司 | Down jacket fabric with anti-static function and manufacturing process thereof |
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