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CN110074129A - A kind of soluble concentrate of combination phoxim gamma cyhalothrin - Google Patents

A kind of soluble concentrate of combination phoxim gamma cyhalothrin Download PDF

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Publication number
CN110074129A
CN110074129A CN201910392394.2A CN201910392394A CN110074129A CN 110074129 A CN110074129 A CN 110074129A CN 201910392394 A CN201910392394 A CN 201910392394A CN 110074129 A CN110074129 A CN 110074129A
Authority
CN
China
Prior art keywords
phoxim
gamma cyhalothrin
combination
content
soluble concentrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910392394.2A
Other languages
Chinese (zh)
Inventor
钱趋程
陶天忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Rongcheng Chemical Co Ltd
Original Assignee
Nanjing Rongcheng Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Rongcheng Chemical Co Ltd filed Critical Nanjing Rongcheng Chemical Co Ltd
Priority to CN201910392394.2A priority Critical patent/CN110074129A/en
Publication of CN110074129A publication Critical patent/CN110074129A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of soluble concentrates of combination phoxim gamma cyhalothrin, the effective component formed including gamma cyhalothrin and phoxim, it further include PH regulator, emulsifier and stabilizer, solvent is supplied, gamma cyhalothrin mass fraction is 0.8%-1.1%, and phoxim content is 18%-22%, emulsifier content 11.2%-12.8%, pH adjusting agent content is 0.1%-0.25%, stabiliser content 2.6%-3.3%.The present invention solves the problems, such as penetrating odor, and the stability of product effective component is good, and drug effect is high, while production cost is low.

Description

A kind of soluble concentrate of combination phoxim gamma cyhalothrin
Technical field
The present invention relates to insecticide field, in particular to a kind of combination phoxim gamma cyhalothrin can solution Agent.
Background technique
Effective cypermethrin is a kind of pyrethroid insecticides, and bioactivity is higher, is the efficient different of cypermethrin Structure body has and tags and stomach poison function.
And the medicament insecticidal spectrum is wide, knocks down that speed is fast, and insecticidal activity is compared with cypermethrin height.Suitable for prevention and treatment cotton, vegetables, Pest and sanitary insect pest in the various plants such as fruit tree, tea tree, forest.
Phoxim be it is a kind of efficiently, less toxic organophosphorus insecticide, with tag with stomach toxicity based on, no systemic action, power of tagging By force, residual life, is short.
Health evil is prevented and treated in arbitrary site such as family, hotel, cinema, restaurant, office, school, street, afforestation squares On worm, medicament used at present, penetrating odor is bigger when use, has a certain impact to environment, people, animal, this shadow It rings up for solving.
Also, existing medicament is mostly with missible oil or wettable powder in market sale, only simplify by effective component It combines and is mixed by normal process, there are certain unstability, control efficiency needs to be further increased product, Meanwhile solvent effect on environment is big, filler has hardened influence to soil.
Summary of the invention
The present invention solves to solve the above problems, provide a kind of soluble concentrate of combination phoxim gamma cyhalothrin Penetrating odor problem, the stability of product effective component is good, and drug effect is high, while production cost is low.
Meanwhile this product is environmentally protective, it is low to the injury of humans and animals.
In order to achieve the above objectives, the technical solution adopted by the present invention is that: a kind of combination phoxim gamma cyhalothrin Soluble concentrate further includes PH regulator, emulsifier and stabilization including the effective component that gamma cyhalothrin and phoxim form Agent, solvent are supplied, and gamma cyhalothrin mass fraction is 0.8%-1.1%, and phoxim content is 18%-22%, emulsifier Content is 11.2%-12.8%, and pH adjusting agent content is 0.1%-0.25%, stabiliser content 2.6%-3.3%.
Further, solvent is benzyl acetate.
Further, emulsifier is 4- methoxyl group -2- (1- phenethyl)-phenol and isooctadecane base polyethylene oxide.
Further, 4- methoxyl group -2- (1- phenethyl)-phenol content is 7.8%-8.4%.
Further, isooctadecane base polyethylene oxide content is 3.4%-4.4%.
Further, stating pH adjusting agent is glacial acetic acid.
Further, stabilizer is epoxidized soybean oil.
Further, gamma cyhalothrin mass fraction is 1%, and phoxim content is 20%, the 4- that emulsifier is 8% Methoxyl group -2- (1- phenethyl)-phenol and 4% isooctadecane base polyethylene oxide, pH adjusting agent be 0.2% glacial acetic acid, surely Determine the epoxidized soybean oil that agent is 3%.
In conclusion the present invention has following advantages:
1, the combination of two kinds of effective components makes up the shortcoming of single dose, and can improve drug effect and inhibit drug resistance, also, The stabilization of effective component reduces unnecessary raw medicine and is excessively added;
2, product system stablizes guarantee drug effect without phytotoxicity, while being also avoided that the phenomenon of drug effect difference.
3, the application of pH adjusting agent plays a significant role effective component decomposition, further ensures the stabilization of product Property.
4, it is reduced environmental pollution using environmentally friendly solvent
Specific embodiment
The present invention will be further described below with reference to examples:
Embodiment 1:
A kind of soluble concentrate of combination phoxim gamma cyhalothrin, including gamma cyhalothrin and phoxim composition Effective component, specifically, gamma cyhalothrin mass fraction be 0.8%-1.1%, phoxim content be 18%-22%.
This soluble concentrate further includes PH regulator, emulsifier and stabilizer, and solvent is supplied.
Wherein, emulsifier content 11.2%-12.8% is 4- methoxyl group -2- (1- phenethyl)-phenol and isooctadecane Base polyethylene oxide, also, 4- methoxyl group -2- (1- phenethyl)-phenol content is 7.8%-8.4%, isooctadecane base polycyclic Oxidative ethane content is 3.4%-4.4%, this group of emulsifier combined effect comparative superiority can have preferable emulsifying effectiveness.
PH adjusting agent selection glacial acetic acid, content 0.1%-0.25%, while capable of guaranteeing effect of glacial acetic acid, significantly Reduce production cost.
Stabilizer selects epoxidized soybean oil, content 2.6%-3.3%, it can be ensured that the stabilization of effective component, and to ring Border influences small, nontoxicity.
And in the selection of solvent, benzyl acetate is selected, is environmentally friendly solvent, solubility property is more excellent, and small toxicity.
In the present embodiment, the specific mass fraction of each component are as follows:
Embodiment 2:
In the present embodiment, the specific mass fraction of each component are as follows:
Embodiment 3:
In the present embodiment, the specific mass fraction of each component are as follows:
Embodiment 4:
In the present embodiment, the specific mass fraction of each component are as follows:
Embodiment 5:
In the present embodiment, the specific mass fraction of each component are as follows:
Embodiment 6:
In the present embodiment, the specific mass fraction of each component are as follows:
According to the requirement of hygienic biocide effect on environment, authenticates and inquires by the investigation of early period, and product is tested, To verify the effect of this product.
At being grouped as following table 1.
Table 1: proportion screening
Obtain heat storage data such as table 2.
Table 2: heat storage data
Obtain cold storage data such as table 3.
Table 3: cold storage data
From the point of view of combined data, no matter cold storage data or heat storage data, No. 3 proportion data are qualified, also, ought not When adding pH adjusting agent glacial acetic acid, effective component is obviously decomposed, and stability and drug effect will receive strong influence.
The technical concepts and features of above embodiment only to illustrate the invention, its object is to allow be familiar with technique People cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention The equivalent transformation or modification that Spirit Essence is done, should be covered by the protection scope of the present invention.
For the ordinary skill in the art, above-mentioned term in the present invention specific can be understood with concrete condition Meaning.
Those skilled in the art will readily recognize that above-mentioned each preferred embodiment can be free under the premise of not conflicting Ground combination, superposition.
It should be appreciated that above-mentioned embodiment is merely exemplary, and not restrictive, without departing from of the invention basic In the case where principle, those skilled in the art can be directed to the various apparent or equivalent modification or replace that above-mentioned details is made It changes, is all included in scope of the presently claimed invention.

Claims (8)

1. a kind of soluble concentrate of combination phoxim gamma cyhalothrin, it is characterised in that: including gamma cyhalothrin and The effective component of phoxim composition, further includes PH regulator, emulsifier and stabilizer, solvent is supplied, the efficient cyhalothrin Ester mass fraction is 0.8%-1.1%, and the phoxim content is 18%-22%, and the emulsifier content is 11.2%- 12.8%, the pH adjusting agent content is 0.1%-0.25%, and the stabiliser content is 2.6%-3.3%.
2. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 1, it is characterised in that: described Solvent is benzyl acetate.
3. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 2, it is characterised in that: described Emulsifier is 4- methoxyl group -2- (1- phenethyl)-phenol and isooctadecane base polyethylene oxide.
4. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 3, it is characterised in that: described 4- methoxyl group -2- (1- phenethyl)-phenol content is 7.8%-8.4%.
5. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 3, it is characterised in that: described Isooctadecane base polyethylene oxide content is 3.4%-4.4%.
6. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 2, it is characterised in that: described PH adjusting agent is glacial acetic acid.
7. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 2, it is characterised in that: described Stabilizer is epoxidized soybean oil.
8. a kind of soluble concentrate of combination phoxim gamma cyhalothrin according to claim 2, it is characterised in that: described Gamma cyhalothrin mass fraction is 1%, and the phoxim content is 20%, the 4- methoxyl group -2- that the emulsifier is 8% (1- phenethyl)-phenol and 4% isooctadecane base polyethylene oxide, the pH adjusting agent be 0.2% glacial acetic acid, the stabilization The epoxidized soybean oil that agent is 3%.
CN201910392394.2A 2019-05-10 2019-05-10 A kind of soluble concentrate of combination phoxim gamma cyhalothrin Pending CN110074129A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910392394.2A CN110074129A (en) 2019-05-10 2019-05-10 A kind of soluble concentrate of combination phoxim gamma cyhalothrin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910392394.2A CN110074129A (en) 2019-05-10 2019-05-10 A kind of soluble concentrate of combination phoxim gamma cyhalothrin

Publications (1)

Publication Number Publication Date
CN110074129A true CN110074129A (en) 2019-08-02

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CN201910392394.2A Pending CN110074129A (en) 2019-05-10 2019-05-10 A kind of soluble concentrate of combination phoxim gamma cyhalothrin

Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101326907A (en) * 2008-01-26 2008-12-24 益阳市润慷宝化工有限公司 High-efficient cyhalothrin-phoxim emulsifiable solution and preparation thereof
CN101695304A (en) * 2009-10-15 2010-04-21 常华 Phoxim and high-efficient lambda-cyhalothrin compound pesticide preparation
CN102014617A (en) * 2008-04-08 2011-04-13 巴斯夫欧洲公司 Emulsifiable concentrate
CN104114022A (en) * 2012-02-27 2014-10-22 胡茨曼澳大利亚股份有限公司 Agrochemical emulsifiable concentrate formulation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101326907A (en) * 2008-01-26 2008-12-24 益阳市润慷宝化工有限公司 High-efficient cyhalothrin-phoxim emulsifiable solution and preparation thereof
CN102014617A (en) * 2008-04-08 2011-04-13 巴斯夫欧洲公司 Emulsifiable concentrate
CN101695304A (en) * 2009-10-15 2010-04-21 常华 Phoxim and high-efficient lambda-cyhalothrin compound pesticide preparation
CN104114022A (en) * 2012-02-27 2014-10-22 胡茨曼澳大利亚股份有限公司 Agrochemical emulsifiable concentrate formulation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张建伟: "一起旅客列车臭虫侵害应急处置", 《中国媒介生物学及控制杂志》 *

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Address after: No. 12 Gucheng Industrial Park, Gaochun Economic Development Zone, Nanjing City, Jiangsu Province, 210000

Applicant after: Nanjing Rongcheng Biotechnology Co., Ltd

Address before: No. 12 Gucheng Industrial Park, Gaochun Economic Development Zone, Nanjing City, Jiangsu Province, 210000

Applicant before: NANJING RONCH CHEMICAL Co.,Ltd.

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Application publication date: 20190802

RJ01 Rejection of invention patent application after publication