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CN109964943B - Herbicidal compositions comprising pyrimidinyloximes and their use - Google Patents

Herbicidal compositions comprising pyrimidinyloximes and their use Download PDF

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Publication number
CN109964943B
CN109964943B CN201910348129.4A CN201910348129A CN109964943B CN 109964943 B CN109964943 B CN 109964943B CN 201910348129 A CN201910348129 A CN 201910348129A CN 109964943 B CN109964943 B CN 109964943B
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polyoxyethylene ether
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actual control
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CN109964943A (en
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金涛
彭学岗
赵德
刘娜
张景远
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Jiangsu Qingyuan Nongguan Weed Control Co ltd
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Jiangsu Qingyuan Nongguan Weed Control Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing pyrimidine formyl oxime compounds and application thereof. The weeding composition comprises an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is

Description

Herbicidal compositions comprising pyrimidinyloximes and their use
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing pyrimidine formyl oxime compounds and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time. The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. For example, patent CN108586357A discloses a substituted pyrimidineformyl oxime derivative and its application as herbicide, and there is still a need to develop a herbicidal composition variety with high safety, broad herbicidal spectrum, synergistic effect and solving the problem of resistant weeds.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a weeding composition containing pyrimidyl formyl oxime compounds and application thereof. The composition can effectively prevent and kill off the problems of weeds such as veronica officinalis, alopecurus amurensis, chickweed, starwort, cleavers and shepherdspurse herb in crop fields, and has the characteristics of expanding the weed control spectrum, reducing the application amount, generating a synergistic effect, solving resistant weeds and the like.
A herbicidal composition comprising pyrimidinyloximes comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein,
the active ingredient A is
Figure BDA0002043059510000011
The active ingredient B is selected from one or more of the following compounds and salts/esters thereof:
(1) HPPD inhibitors: sulcotrione (CAS number: 99105-77-8), mesotrione (CAS number: 104206-82-8), topramezone (CAS number: 210631-68-8), tembotrione (CAS number: 335104-84-2), fluroxypyr (CAS number: 352010-68-5), benzofuranone (CAS number: 473278-76-1), bicyclosulfulone (CAS number: 156963-66-5), diconazole (CAS number: 1622908-18-2), ciclopirox (CAS number: 1855929-45-1), triazophorione (CAS number: 1911613-97-2), benzoxaflutole (CAS number: 1992017-55-6), fenzopyr pyrazole (CAS number: 365400-11-9), pyrazolate (CAS number: 58011-68-0), pyroxadim (CAS number: 82692-44-2), tolpyralate (CAS number: 1101132-67-5), fenquinolone (CAS number: 1342891-70-6), isoxazoleClethodim (CAS number: 141112-29-0), bifonazole (CAS number: 71561-11-0),
Figure BDA0002043059510000021
(2) (ii) a PDS inhibitor: flurtamone (CAS number: 61213-25-0), flurtamone (CAS number: 96525-23-4), diflufenican (CAS number: 83164-33-4), diflufenican (CAS number: 137641-05-5), beflubutamid (CAS number: 113614-08-7), norflurazon (CAS number: 27314-13-2), and fluridone (CAS number: 59756-60-4);
(3) a DOXP inhibitor: clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);
(4) ALS inhibitors: tribenuron-methyl (CAS number: 101200-48-0), thifensulfuron-methyl (CAS number: 79277-27-3), bensulfuron-methyl (CAS number: 83055-99-6), pyrazosulfuron-ethyl (CAS number: 93697-74-6), thiencarbazone-methyl (CAS number: 317815-83-1), halosulfuron-methyl (CAS number: 100784-20-1), propyrisulfuron (CAS number: 570415-88-2), metazosulfuron-methyl (CAS number: 868680-84-6), rimsulfuron-methyl (CAS number: 122931-48-0), ethoxysulfuron (CAS number: 126801-58-9), pyriminosulfuron-methyl (CAS number: 213464-77-8), flucarbazone-methyl (CAS number: 181274-17-9), mesosulfuron-methyl (CAS number: 208465-21-8), nicosulfuron (CAS number: 111991-09-4), Foramsulfuron (CAS number: 173159-57-4), flumetsulam (CAS number: 98967-40-9), triafamone (CAS number: 874195-61-6), penoxsulam (CAS number: 219714-96-2), cloransulam-methyl (CAS number: 147150-35-4), pyroxsulam (CAS number: 422556-08-9), imazamox (CAS number: 114311-32-9), imazapic (CAS number: 104098-48-8), imazethapyr (CAS number: 81385-77-5), imazapyr (CAS number: 81334-34-1), pyriminobac (CAS number: 147411-69-6), florasulam (CAS number: 145701-23-1), pyribenzoxim (CAS number: 135186-78-6), pyribenzoxim (CAS number: 168088-61-7), Tribenuron-methyl (CAS number: 145026-81-9), imazethapyr (CAS number: 81335-77-5), chlorsulfuron (CAS number: 64902-72-3), cinosulfuron (CAS number: 94593-91-6), cyclosulfamuron (CAS number: 136849-15-5), amidosulfuron (CAS number: 120923-37-7), triasulfuron (CAS number: 82097-50-5), iodosulfuron-methyl sodium salt (CAS number: 144550-36-7), flupyrsulfuron (CAS number: 144740-54-5), flucetosulfuron (CAS number: 412928-75-7), metsulfuron (CAS number: 74223-64-6), triflusulfuron (CAS number: 142469-14-5), sulfosulfuron (CAS number: 141776-32-1), pyrazosulfuron (CAS number: 122548-33-8), Bispyribac-sodium (CAS number: 125401-92-5), and sulfentrazone (CAS number: 139528-85-1);
(5) ACCase inhibitors: clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8), clethodim (CAS number: 99129-21-2), sethoxydim (CAS number: 74051-80-2), quizalofop-p-ethyl (CAS number: 100646-51-3), tralkoxydim (CAS number: 87820-88-0), fluazifop-p-butyl (CAS number: 69806-50-4), haloxyfop-R (CAS number: 72619-32-0), diclofop-p-methyl (CAS number: 51338-27-3), fenoxaprop-p-ethyl (CAS number: 113158-40-0), cyhalofop-butyl (CAS number: 122008-85-9), clethodim (CAS number: 139001-49-3), metamifop (CAS number: 256412-89-2), oxadiargyl (CAS number: 111479-05-1);
(6) PPO inhibitors: fluroxypyr ether (CAS number: 42874-03-3), fomesafen (CAS number: 72178-02-0), oxadiazon (CAS number: 19666-30-9), oxadiargyl (CAS number: 39807-15-3), sulfentrazone (CAS number: 122836-35-5), pyraclonil (CAS number: 158353-15-2), flumioxazin (CAS number: 103361-09-7), pentoxazone (CAS number: 110956-75-7), tiafenacil (CAS number: 1220411-29-9), saflufenacil (CAS number: 372137-35-4), pyraflufen (CAS number: 129630-19-9), carfentrazone (CAS number: 128621-72-7), butafenacil ester (CAS number: 134605-64-4), fluroxypyr ether ethyl ester (CAS number: 131086-42-5), Fluoroglycofen-ethyl (CAS No. 77501-60-1), fluoroglycofen-ethyl (CAS No. 50594-66-6), triflumimoxazin (CAS No. 1258836-72-4), and azinam-methyl (CAS No. 117337-19-6);
(7) PSII inhibitors: atrazine (CAS number: 1912-24-9), prometryn (CAS number: 7287-19-6), simetryn (CAS number: 1014-70-6), terbuthylazine (CAS number: 5915-41-3), terbutryn (CAS number: 886-50-0), ametryn (CAS number: 834-12-8), ipratropium (CAS number: 4147-51-7), fenflurazine (CAS number: 845-52-3), prometryn (CAS number: 1014-69-3), simazine (CAS number: 122-34-9), metribuzin (CAS number: 87-21064-9), ethiprole (CAS number: 64529-56-2), amicarbazone (CAS number: 129909-90-6), metribuzin (CAS number: 41394-05-2), cyanazine (CAS number: 21725-46-2), Chlortoluron (CAS number: 15545-48-9), isoproturon (CAS number: 34123-59-6), diuron (CAS number: 330-54-1), fluometuron (CAS number: 2164-17-2), linuron (CAS number: 330-55-2), buthiuron (CAS number: 34014-18-1), cypermethron (CAS number: 42609-52-9), chlortoluron (CAS number: 1746-81-2), bromuron (CAS number: 3060-89-7), endothel (CAS number: 555-37-3), pyridazinol (CAS number: 40020-01-7), hexazinone (CAS number: 51235-04-2), isoethazine (CAS number: 22936-75-0), prodrazine (CAS number: 1912-26-1), bromacil (CAS number: 314-40-9), Cyclinadine (CAS number: 2164-08-1), terbacil (CAS number: 5902-51-2), methabenzthiazuron (CAS number: 18691-97-9), cyclosulfamuron (CAS number: 1982-49-6), isoxaben (CAS number: 55861-78-4), metoxuron (CAS number: 19937-59-8), cumuron (CAS number: 1982-47-4), trifluoxazine (CAS number: 1258836-72-4), cyclopyromate (CAS number: 499231-24-2), propanil (CAS number: 709-98-8), pyridate (CAS number: 55512-33-9), betalain (CAS number: 13684-56-5), betanin (CAS number: 13684-63-4), bentazone (CAS number: 25057-89-0), bromoxynil octanoate (CAS number: 1689-99-2), Bromoxynil (CAS number: 1689-84-5), ioxynil (CAS number: 1689-83-4);
(8) microtubule assembly inhibitors: trifluralin (CAS number: 1582-09-8), butralin (CAS number: 33629-47-9), pendimethalin (CAS number: 40487-42-1), dithiopyr (CAS number: 97886-45-8), ethambucil (CAS number: 55283-68-6), oryzalin (CAS number: 19044-88-3), flumetsulam (CAS number: 1861-40-1), thiabendazole (CAS number: 117718-60-2), propaquilate (CAS number: 23950-58-5), dichlorvos (CAS number: 1861-32-1) and phorate (CAS number: 36335-67-8);
(9) microtubule combination inhibitors: diacyl-amine (CAS number: 16118-49-3);
(10) VLCFA inhibitors: acetochlor (CAS number: 34256-82-1), butachlor (CAS number: 23184-66-9), pretilachlor (CAS number: 51218-49-6), metolachlor (CAS number: 87392-12-9), mefenacet (CAS number: 73250-68-7), s-metolachlor (CAS number: 178961-20-1), flufenacet (CAS number: 142459-58-3), alachlor (CAS number: 15299-99-7), pyriflufen (CAS number: 447399-55-5), anilofol (CAS number: 64249-01-0), xylenol oxamine (CAS number: 87674-68-8), fentrazamide (CAS number: 158237-07-1), triafamone (CAS number: 212201-70-2), cafenstrole (CAS number: 125306-83-4), Mepiquat chloride (CAS number: 24151-93-7), propisochlor (CAS number: 86763-47-5), alachlor (CAS number: 15972-60-8), diflufenican (CAS number: 67129-08-2), propachlor (CAS number: 1918-16-7), dimethenamid (CAS number: 106700-29-2);
(11) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb (CAS number: 52888-80-9), molinate (CAS number: 2212-67-1), prosulfocarb (CAS number: 28249-77-6), benfuresate (CAS number: 68505-69-1), ethofumesate (CAS number: 26225-79-6), triallate (CAS number: 2303-17-5), dichlorfon (CAS number: 1929-77-7), butamolide (CAS number: 2008-41-5), dichlorfon (CAS number: 1134-23-2), pennisetum (CAS number: 61432-55-1) and penflun (CAS number: 85785-20-2);
(12) synthesis of hormones: quinclorac (CAS number: 84087-01-4), fluroxypyr (CAS number: 69377-81-7), fluroxypyr-meptyl (CAS number: 81406-37-3), fluroxypyr (CAS number: 943831-98-9), triclopyr (CAS number: 55335-06-3), clopyralid (CAS number: 1702-17-6), picloram (CAS number: 1918-02-1), aminopyralid (CAS number: 150114-71-9), dicamba (CAS number: 1918-00-9), fluroxypyr (CAS number: 1390661-72-9), 2-methyl-4-chlorophenoxyacetic acid (CAS number: 94-74-6), 2-methyl-4-chloro-phenothiolester (CAS number: 25319-90-8), MCPB (CAS number: 94-81-5), 2-methyl-4-chlorophenoxypropionic acid (CAS number: 93-65-2), sodium 2-methyl-4-chlorophenoxyacetate (CAS number: 3653-48-3), isooctyl 2-methyl-4-chlorophenoxyacetate (CAS number: 29450-45-1), butyl 2, 4-dichlorophenoxyacetate (CAS number: 94-80-4), isooctyl 2, 4-dichlorophenoxyacetate (CAS number: 25168-26-7), 2, 4-dichlorophenoxyacetic acid (CAS number: 94-75-7), chloroquinolinic acid (CAS number: 90717-03-6), 2-methyl-4 chlorodimethylammonium salt (CAS number: 2039-46-5), 2, 4-dichlorpropionic acid (CAS number: 120-36-5), 2, 4-D-butyric acid (CAS number: 94-82-6), benazolin (CAS number: 25059-80-7), aminocyclopyrachlor (CAS number: 858956-08-8);
(13) EPSPS inhibitors: glyphosate (CAS number: 1071-83-6), phosphinothricin (CAS number: 81591-81-3);
(14) a GS inhibitor: glufosinate-ammonium (CAS number: 77182-82-2), bialaphos (CAS number: 35597-43-4), and glufosinate-ammonium (CAS number: 35597-44-5);
(15) PSI inhibitors paraquat (CAS number: 1910-42-5), diquat (CAS number: 6385-62-2);
(16) DHP inhibitors: asulam (CAS number: 3337-71-1);
(17) cellulose synthesis inhibitors: triazinyl flumioxazin (CAS number: 131475-57-5), indexazin (CAS number: 950782-86-2);
(18) other herbicides: oxaziclomefone (CAS number: 153197-14-9), cinmethylin (CAS number: 87818-31-3), indanthrone (CAS number: 133220-30-1), quinclorac (CAS number: 130901-36-8), quintocet (CAS number: 1639426-14-4), prosulfuron (CAS number: 99485-76-4), imazalone (CAS number: 150-68-5), tetflupyrlomet (CAS number: 2053901-33-8).
In the context of the present specification, if the abbreviated forms of the common name of the active compounds are used, all customary derivatives, such as esters and salts, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are included in each case. If the generic name denotes esters or salts, all other customary derivatives, such as other esters and salts, free acids and neutral compounds, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are also included in each case. The chemical name given for a compound means at least one compound covered by the generic name, with compounds generally being preferred. In the case of sulfonamides, such as sulfonylureas, salts also include those formed by exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2 methyl 4 chloro sodium salt, potassium salt, dimethyl ammonium salt, isopropyl amine salt, etc., and 2 methyl 4 chloromethyl ester, ethyl ester, isooctyl ester, ethyl thioester, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolamine salt, isopropylamine salt, choline and the like, and 2,4-D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester and the like.
In the context of the present invention, the salts of the compounds are preferably in the form of the respective alkali metal, alkaline earth metal or ammonium salts, preferably in the form of the respective alkali metal salts, more preferably in the form of the respective sodium or potassium salts, most preferably in the form of the respective sodium salts.
A. The weight ratio of B is 1: 5000-10: 1 and 1: 4000-5: 1; preferably 1: 3000-1: 1 and 1: 2500-1: 5; more preferably 1: 2000-1: 10 and 1: 1500-1: 30; further preferably 1: 1000-1: 50 and 1: 800-1: 80; further preferred are 1:500 to 1:100, 1:300 to 1:150 and 1:250 to 1: 200.
The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
In addition, the composition of the present invention can be mixed with the following active substances, for example, known substances in "the world Wide Specification of New agricultural chemical products", the Chinese agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, Terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolac, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron, sulfo, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, Betalain, asulam, tefurazol, avenacalin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, dichloropetalum, ethiofen, prosulfocarb, cloquintocet, prosulfocarb, dichloropetalum, dichloropetalate, dichloropetal, 2-methyl-4-chloropropionate, 2-methyl-4-chlorobutyric acid, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloroamine salt, dicamba, woollen boom, varparvax, cypress, triclosan, dichlorfenamic acid, metoclopramide, diclofop-p-ethyl, haloxyfop-methyl, haloxyfop-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, cyhalofop-butyl, fenoxaprop-p-ethyl, cloroph-ethyl, haloxyfop-ethyl, trifoliate-ethyl, clomazone, paraquat, dixyl, asulam, flutolon, isoproturon, chlorothalofop-ethyl, cyhalofop-p-ethyl, propafen-ethyl, butyfen-ethyl, fluroxypyr, metalaxyl, propafen, propaferin, propafen, glyphosate, anilofos, glufosinate, sulfosate, piperaphos, bialaphos, bensulide, imazapyr, mepyrazine, varroa, amifostine, glufosinate, imazethapyr ammonium salt, imazethapyr, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxyfen, triclopyr, thiazopyr, flurazinone, aminopyralid, flurazone, diflufenzopyr, butoxyethyl triclopyr, ciodinate, sethoxydim, clethodim, thiacet, sethoxydim, clethodim, carfenflurazone, buthiazole, metribuzin, carfenflurazone, metamitron, fenflurazone, fenpyr, benzone, iodoxynil, bromoxynil, isoflurazone, isofluroxypyr, bensulam, isofluroxypyr, clomazone, ioxynil, dichlobenil, tolfenacet, pyraclonil, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluralin, bispyribac, pyribenzoxim, pyriminobac-methyl, pyrithiobac-methyl, bicyclosulfuron, mesotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketoxydipradox, isoxaflutole, fenoxasulfolane, Methiozolin, isopyrafen, pyraflufen, pyraflutole, pyrazotocide, pyraclonil, pyraclofenacetone, flumetsulcotrione, flumetsulam, fenflurazole, fentrazachlor, amicarbazone, fentrazachlor, pyrazachlor, pyraclonil, flumicloram, flumioxazone, fenflurazole, flumicloram, bexapyroxadim, flumicloram, bexadim, flumicloram, benfluroram, flumicl, Phthalidyl ether, Flumezin, pentachlorophenol (sodium), dinol, terbenol, terbutal, pendimethalin, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop-p-ethyl, tetrazolyl amine, fluridazin, oxamyl, bromamine, dimethenamid, pyridaben, pyridate, pyrirfalol, quinclorac, bentazone, pyridate, oxaziclorac, benazolin, clomazone, clomeptyl, isoprox, iprodione, propamocarb, cumylfen, indoxacarb, sodium chlorate, dalton, dalapon, trichloroacetic acid, monochloroacetone, hexachloroacetone, tetrafluoropropionic acid, pasture, bromophenol oxime, triazoxide, fentrazol, furamethon, fursulam, ethon, benfurazolin, pyrimethanil, clorac, clodinafop, clorac, cumquat, cumarone, clorac, Thidiazuron, alantin, hydroxybenone, metophenone, saflufenacil, dichlorophosphoric, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphridam, Ipfancarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurflurazone, Tripropindan, Sulglycapin, Sumbelanoline, Campandichlor, Cytopyrimidic acid, thiocyananilide, clethodim, fenclorim, cloquintocet, mequintocet, oxaziclomex, oxabetrinil, pyroxaglim, furazolidone, imazaquin, isoxadifen, dichlormid, halauxin, halauxifen, DOWF, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
The herbicidal composition further comprises at least one safener selected from the group consisting of:
a) dichlorophenyl pyrazoline-3-carboxylic acid (S1) compounds, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1 mefenpyr-diethyl, PM, p. 594-595), and related compounds described, for example, in WO91/07874 and PM (p. 594-595).
b) Dichlorophenyl pyrazole carboxylic acid derivatives, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2, 4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2, 4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylate (S1-4), ethyl 1- (2, 4-dichlorophenyl) -5-phenylpyrazole-3-carboxylate (S1-5), and related compounds as described in EP-A-333131 and EP-A-269806.
c) Triazole carboxylic acids (S1) and preferred compounds are, for example, fenchlorazole (fenchlorazole), i.e. ethyl 1- (2, 4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2, 4-triazole-3-carboxylate (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d) 5-benzyl-or 5-phenyl-2-isoxazoline-3-carboxylic acids or 5, 5-diphenyl-2-isoxazoline-3-carboxylic acids, preferred compounds being, for example, ethyl 5- (2, 4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds described in WO91/08202, or ethyl 5, 5-diphenyl-2-isoxazoline-3-carboxylate (S1-9, isoxadifen-ethyl)) or 5 described in the patent application (WO-A-95/07897), n-propyl 5-diphenyl-2-isoxazoline-3-carboxylate (S1-10) or ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylate (S1-11).
e) 8-Quinolinyloxyacetic acids (S2) of the class of compounds, preferably 1-methylhexan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-1, cloquintocet-mexyl), such as PM (p. 195-), (1, 3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinyloxy) acetate (S2-3), 1-allyloxypropan-2-yl (5-chloro-8-quinolinyloxy) acetate (S2-4), (ethyl 5-chloro-8-quinolinyloxy) acetate (S2-5), (methyl 5-chloro-8-quinolinyloxy) acetate (S2-6), allyl (5-chloro-8-quinolinyloxy) acetate (S2-7), 2- (2-propyleneiminoyloxy) -1-ethyl (5-chloro-8-quinolinyloxy) acetate (S2-8), 2-oxopropan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-9), and related compounds described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366.
f) (5-chloro-8-quinolinoxy) propanedioic acid-based compounds, preferred compounds are, for example, diethyl (5-chloro-8-quinolinoxy) malonate, (diallyl (5-chloro-8-quinolinoxy) malonate, (methylethyl (5-chloro-8-quinolinoxy) -malonate and related compounds described in EP-A-0582198.
g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acids, such as 2, 4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2-methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3, 6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).
h) Pyrimidines, such as fenclorim (PM, page 386-387) (═ 4, 6-dichloro-2-phenylpyrimidine),
i) dichloroacetamide-based active compounds, which are frequently used as pre-emergence safeners (soil-working safeners), for example "dichloroallylamine (dichlormid)" (PM, page 270-271) (═ N, N-diallyl-2, 2-dichloroacetamide), "AR-29148" (-3-dichloroacetyl-2, 2, 5-trimethyl-1, 3-oxazolidinone from Stauffer), "benoxacor" (PM, page 74-75) (-4-dichloroacetyl-3, 4-dihydro-3-methyl-2H-1, 4-benzoxazine), "APPG-1292" (-N-allyl-N [ (1, 3-dioxolan-2-yl) -methyl ] dichloroacetamide, from PPG Industries), "ADK-24" (═ N-allyl-N- [ (allylaminocarbonyl) -methyl ] -dichloroacetamide, from Sagro-Chem), "AAD-67" or "AMON 4660" (═ 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane, from nitrkemia or Monsanto), "diclonon" or "ABAS 145138" or "ala b 145138" (═ 3-dichloroacetyl-2, 5, 5-trimethyl-1, 3-diazabicyclo [4.3.0] nonane, from BASF), and "furilazol" or "AMON 13900" (see PM, 482-483) ((RS) -3-dichloroacetyl-5- (2-furyl) -2, 2-dimethyloxazolidinone),
j) dichloroacetone derivative-based active compounds, for example, "AMG 191" (CAS registry No. 96420-72-3) (═ 2-dichloromethyl-2-methyl-1, 3-dioxolane, available from Nitrokemia),
k) oxyimino compounds as active compounds, which are referred to as seed dressing materials, for example "oxabetrinil" (PM, page 689) (═ Z) -1, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile), which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), "fluoroxyfen" (PM, page 467 468) (═ 1- (4-chlorophenyl) -2,2, 2-trifluoro-1-ethanone O- (1, 3-dioxolan-2-ylmethyl) -oxime, which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), and "cyanohydrin" or "a-CGA-43089" (PM, page 983) ((Z) -cyanomethoxyimino (phenyl) acetonitrile), which is called safener in seed dressing, to prevent the damage of metolachlor (metolachlor),
l) Thiazolecarboxylic acid ester active compounds, which are known as seed dressing materials, for example "flurazon" (PM, p. 450. 451), (-2-chloro-4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester), which are known as safeners in seed dressing to prevent damage to alachlor (alachlor) and metolachlor,
m) active compounds of the naphthalenedicarboxylic acid derivative class, which are known as seed dressings, for example "naphthalic anhydride" (PM, pp 1009-1010) (═ 1, 8-naphthalic anhydride), which are known as safeners in corn seed dressings to prevent damage to thiocarbamate herbicides,
n) chromanoic acid derivatives such as "ACL 304415" (CAS registry No. 31541-57-8) (═ 2-84-carboxychroman-4-yl) acetic acid available from american cyanamid),
o) active compounds which, in addition to herbicidal action on harmful plants, also have safener action on plants, for example "penetryn (dimerate)" or "AMY-93" (PM, p.302-303) (═ S-1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "diuron (daimuron)" or "ASK 23" (PM, p.247) (═ 1- (1-methyl-1-phenylethyl) -3-p-tolylureｃA), "cumyluron (cumyluron)", "jc-940" ((3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) ureｃA, see JP- ｃA-60087254), "benzophenone (methoxyphenon)" or "ANK 049" (═ 3,3' -dimethyl-4-methoxy-benzophenone), "CSB" (═ 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS registry No. 54091-06-4, available from Kumiai).
The safener is preferably one or more of isoxadifen (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), mefenpyr (CAS: 135590-91-9), cloquintocet (CAS: 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8) and metacamifen (CAS: 129531-12-0).
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
The invention also provides an application of the weeding composition in weed control; and to provide a method of controlling unwanted plant growth comprising applying the herbicidal composition to a plant, part of a plant, plant seed, or area where a plant is growing.
In addition, the compositions according to the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces infested or susceptible to infestation by weeds.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described, achieving reduced use and being more environmentally friendly.
The synergistic herbicidal composition of the invention also has the following advantages:
(1) the composition of the invention is environment-friendly and is easy to degrade in the environment.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
A + sulcotrione (0.5+ 25: representing 0.5% A + 25% sulcotrione, the same applies hereinafter) dispersible oil suspension concentrate
A, sulcotrione, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 0.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + mesotrione (3+22.5)
A + mesotrione + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + topramezone (3+5)
A, topramezone, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + tembotrione (3+15)
A + tembotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + fluroxypyr (3+15) dispersible oil suspension
A, fluroxypyr, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + fursulcotrione (3+12)
A, benzofuranone, 6 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + bicyclosulfoncotrione (1.5+21)
A + benzobicyclon, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + carfentrazone-ethyl (3+5) dispersible oil suspending agent
A, carfentrazone-ethyl, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organic bentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
9, A + bicyclopyrone (3+15) dispersible oil suspension agent
A + cyflufenac + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.2% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + triazasulamone (3+22.5)
A + triazophone + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A + benzoxaflutole (3+15) dispersible oil suspension agent
A + benzoxaflutole + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + sulfonylopyrazole (3+5)
A + sulfonyloxapyrazole + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + pyrazolate (0.3+32.5) dispersible oil suspending agent
A, pyrazolate, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 5 percent of 100# solvent oil and methyl oleate
A + pyroxadim (0.3+30) dispersible oil suspending agent
A, the balance of the raw materials of A, the raw materials of
A + tolpyralate (1.5+25) dispersible oil suspension concentrate
A + tolpyrate + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A + fenquinotrione (1.5+25) dispersible oil suspension concentrate
A + fenquinotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A + isoxaflutole (3+15) dispersible oil suspension agent
A, isoxaflutole, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 5% 100# solvent oil and methyl oleate
A + benconazole (0.3+50) water dispersible granule
A + benzoprazole + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin
19.
Figure BDA0002043059510000131
Dispersible oil suspension
Figure BDA0002043059510000132
Calcium dodecyl benzene sulfonate, 6 percent fatty alcohol-polyoxyethylene ether, 5 percent castor oil-oxyethylene ether, 1.5 percent organobentonite, 1.5 percent fumed silica, 5 percent 100# solvent oil and methyl oleate
A + fluorochloridone (0.6+25) dispersible oil suspending agent
A, fluorochloridone, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 0.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + flurtamone (3+24) dispersible oil suspending agent
A + flurtamone + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + diflufenican (1.5+22)
A + diflufenican + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + fluopicolide (1.2+16.6)
A + fluopicolide, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + beflubutamid (1.2+17)
A + beflubutamid, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 5% 100# solvent oil and methyl oleate
25, A + norflurazon (0.3+36.7) water dispersible granule
A + norflurazon + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin
Wettable powder of A + fluazinone (0.2+44.4)
A, fluazinone, 10 percent of sodium lignosulfonate dispersant, 3 percent of sodium dodecyl sulfate, 10 percent of precipitated white carbon black and kaolin are complemented
Dispersible oil suspension agent of A + clomazone (0.5+36)
A, clomazone, 6 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 5 percent of 100# solvent oil and methyl oleate
A + bixlone (1.5+25) dispersible oil suspension
A + bixlone + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate
29, A + tribenuron-methyl (3+5) dispersible oil suspending agent
A, tribenuron-methyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + thifensulfuron methyl (3+5) dispersible oil suspending agent
A + thifensulfuron methyl + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + bensulfuron methyl (3+5) dispersible oil suspending agent
A + bensulfuron methyl + + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
32.A + pyrazosulfuron (3+5) dispersible oil suspending agent
A + pyrazosulfuron-ethyl, 5% calcium dodecylbenzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + thiencarbazone-methyl (3+6.5)
A, thiencarbazone-methyl, 5% calcium dodecyl benzene sulfonate, 8% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + halosulfuron-methyl (3+5) dispersible oil suspension agent
A + halosulfuron-methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
35, A + propyrisulfuron (3+14) dispersible oil suspending agent
A, propyrisulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
A + oxazine pyrazosulfuron (3+16.5) dispersible oil suspending agent
A + metazosulfuron-ethyl, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + rimsulfuron (3+4) dispersible oil suspension agent
A, rimsulfuron, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
38, A + ethoxysulfuron (3+4) dispersible oil suspending agent
A + ethoxysulfuron + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + orthosulfamuron (3+12.5) dispersible oil suspending agent
A, orthosulfamuron, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + flucarbazone-methyl (3+7) dispersible oil suspending agent
A, flucarbazone-sodium, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + mesosulfuron (3+2.5)
A + mesosulfuron-methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + nicosulfuron (3+10) dispersible oil suspending agent
A, nicosulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
A + foramsulfuron (3+7.5) dispersible oil suspension
A, foramsulfuron, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + flumetsulam (3+7.5) dispersible oil suspending agent
A, flumetsulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of white carbon black by a gas phase method, 5 percent of 100# solvent oil and methyl oleate
45.A + triafamone (3+6) dispersible oil suspending agent
A, triafamone, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2% of organic bentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
A + penoxsulam (3+5) dispersible oil suspending agent
A, penoxsulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + cloransulam-methyl (3+5.5) dispersible oil suspending agent
A + cloransulam-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + pyroxsulam (3+3) dispersible oil suspending agent
A, pyroxsulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + imazamox (3+8.5)
A + metopimox, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + mebendazole nicotinic acid (3+24)
A + mebendazole nicotinic acid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspending agent of A + imazethapyr (3+17.5)
A, imazethapyr, 6 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + imazapyr (0.6+50) water dispersible granules
A + imazapyr + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium lauryl sulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
53.A + pyriminobac-methyl (3+7.5) dispersible oil suspending agent
A, pyriminobac-sodium, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2% of organobentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + florasulam (3+1.5)
A, florasulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Aqueous suspension of A + pyriftalid (1.5+25)
A + pyriftalid + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.05% xanthan gum + 0.5% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
56.A + pyribenzoxim (3+12.5) dispersible oil suspending agent
A, pyribenzoxim, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
57, A + Tribensulfuron (3+11.5) dispersible oil suspending agent
A, tribenuron-methyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
58.A + imazethapyr (3+16.5) dispersible oil suspending agent
A + imazethapyr + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + chlorsulfuron (3+10) dispersible oil suspending agent
A + chlorsulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A + cinosulfuron (3+5) dispersible oil suspending agent
A, cinosulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2% of organobentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
61.A + cyclosulfamuron (3+3.5) dispersible oil suspending agent
A, cyclosulfamuron, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + amidosulfuron (3+5)
A, amidosulfuron, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
63.A + Ether tribenuron-methyl (3+4) dispersible oil suspending agent
A + tribenuron-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + iodosulfuron-methyl sodium salt (3+3.5)
A, iodometsulfuron-methyl sodium salt, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2% of organic bentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
65.A + fluazisulfuron (3+5) dispersible oil suspending agent
A, flazasulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2% of organobentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
66.A + Fluopyrsulfuron (3+5) dispersible oil suspending agent
A, flucetosulfuron, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + metsulfuron (3+1.5) dispersible oil suspending agent
A, metsulfuron-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
68.A + triflusulfuron-methyl (3+3.5) dispersible oil suspending agent
A, triflusulfuron-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension of A + sulfonylsulfuron (3+5)
A + sulfosulfuron, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A + azolopyrazolyl pyrazosulfuron (3+3.5) dispersible oil suspending agent
A + pyrazosulfuron-ethyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
71.A + bispyribac-sodium (3+5) dispersible oil suspending agent
A + bispyribac-sodium, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
72, A + metosulam (3+3.5) dispersible oil suspending agent
A, metosulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
73.A + clodinafop-propargyl (3+10) dispersible oil suspending agent
A, clodinafop-propargyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + pinoxaden (3+12.5)
A, pinoxaden, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
A + clethodim (3+15) dispersible oil suspending agent
A + clethodim + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
76.A + sethoxydim (3+37.5) dispersible oil suspending agent
A, sethoxydim, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 6 percent of 100# solvent oil and methyl oleate
77.A + quizalofop-p-ethyl (3+10) dispersible oil suspending agent
A, quizalofop-p-ethyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 6 percent of 100# solvent oil and methyl oleate
78.A + benzoxim (1.5+40) dispersible oil suspending agent
A + benzoximone + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 6% 100# solvent oil + methyl oleate
79.A + fluazifop-p-butyl (5+6.5) dispersible oil suspending agent
A, fluazifop-p-butyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 2 percent of organic bentonite, 1.5 percent of white carbon black by a gas phase method, 6 percent of 100# solvent oil and methyl oleate
80.A + high-efficiency haloxyfop (3+6.5) dispersible oil suspending agent
A + high-efficiency haloxyfop-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-oxyethylene ether, 2% organobentonite, 1.5% fumed silica, 6% 100# solvent oil and methyl oleate
Dispersible oil suspension of A + diclofop-methyl (0.5+25)
A, diclofop-p-ethyl, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 6 percent of 100# solvent oil and methyl oleate
82.A + fenoxaprop-p-ethyl (3+25) dispersible oil suspending agent
A, fenoxaprop-p-ethyl, 6 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
Dispersible oil suspension agent of A + cyhalofop-butyl (3+25)
A + cyhalofop-butyl, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica and methyl oleate
Dispersible oil suspension agent of A + clethodim (3+10)
A, clethodim, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
85.A + metamifop (3+25) dispersible oil suspending agent
A, metamifop, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
86.A + oxaoxalic acid (3+12.5) dispersible oil suspending agent
A, oxalic acid, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 10 percent of 100# solvent oil and methyl oleate
87, A + oxyfluorfen (3+30) dispersible oil suspending agent
A, oxyfluorfen, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.5 percent of organic bentonite, 2.5 percent of fumed silica, 20 percent of 100# solvent oil and methyl oleate
88.A + fomesafen (0.6+12.5) dispersible oil suspending agent
A, fomesafen, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 0.5 percent of fumed silica, 20 percent of 100# solvent oil and methyl oleate
89.A + oxadiazon (0.6+20) dispersible oil suspending agent
A, oxadiazon, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 5 percent of 100# solvent oil and methyl oleate
90.A + oxadiargyl (3+14) dispersible oil suspending agent
A, oxadiargyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 15 percent of 100# solvent oil and methyl oleate
Wettable powder of 91, A + sulfentrazone (1+30)
A, sulfentrazone, 12 percent of calcium lignosulfonate dispersant, 3 percent of sodium dodecyl sulfate, 10 percent of precipitated white carbon black and kaolin are complemented
92.A + pyraclonil (1.5+18) dispersible oil suspending agent
A, pyraclonil, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 5 percent of 100# solvent oil and methyl oleate
93.A + flumioxazin (3+15) dispersible oil suspending agent
A, flumioxazin, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.6 percent of organic bentonite, 15 percent of 100# solvent oil and methyl oleate
94.A + pentoxazone (0.6+13.3) dispersible oil suspending agent
A, pentoxazone, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organobentonite, 0.5% fumed silica, 5% 100# solvent oil and methyl oleate
95.A + tiafenacil (3+5.5) dispersible oil suspending agent
A, tiafenacil, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.0 percent of organic bentonite, 1.5 percent of fumed silica, 5 percent of 100# solvent oil and methyl oleate
96.A + saflufenacil (3+13) dispersible oil suspending agent
A, saflufenacil, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of white carbon black by a vapor phase method and methyl oleate
97, A + pyraflufen-ethyl (3+2) dispersible oil suspending agent
A, pyraflufen-ethyl, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.0 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
98.A + carfentrazone-ethyl (3+5) dispersible oil suspending agent
A + carfentrazone-ethyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organic bentonite + 1.5% fumed silica + methyl oleate
99.A + butafenacil (3+2) dispersible oil suspending agent
A + fluoropropylazoxystrobin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate
100, A + Meclofenacet ethyl ester (3+5) dispersible oil suspending agent
A, fluroxypyr-meptyl ester, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.0 percent of organic bentonite, 1.5 percent of fumed silica, 12 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + fluoroglycofen-ethyl (3+2.5)
A + fluoroglycofen-ethyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
102, A + acifluorfen (1+25) water dispersible granule
A + acifluorfen + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
A + triflumimoxazin (3+13.5) dispersible oil suspension concentrate
A + triflumimoxazin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + oxazine methyl oxalate (3+2.5)
A + oxazine methyl oxalate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate
Aqueous suspension of A + atrazine (0.3+37.5)
A + atrazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
106, A + prometryn (0.6+37.5) water suspension agent
A + prometryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
107, A + simetryn (0.6+31.3) water suspension agent
A + simetryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous A + terbuthylazine (0.5+25) suspension
A + terbuthylazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + terbutryn (0.3+30)
A + terbutryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + ametryn (0.3+40)
A + ametryn, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
Aqueous suspension of A + ipratron (0.3+50)
A + iprovalicarb + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + fenugreek (0.3+50) water suspension
A + fenfluramine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
113, A + dimethozin (0.6+37.5) water suspending agent
A + dimethomon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + simazine (0.3+31.3) aqueous suspension
A + simazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + metribuzin (0.6+22.5)
A + metribuzin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + ethiziclomazone (0.6+24) aqueous suspension
A + ethiflutole + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + amicarbazone (2+35)
A + amicarbazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + metamitron (0.1+32.4) water dispersible granule
A + metamitron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
Aqueous suspension of A + cyanazine (0.3+25)
A + cyanazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
120, A + chlortoluron (0.3+50) water dispersible granule
A + chlortoluron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin
Aqueous suspension of A + isoproturon (0.6+37.5)
A + isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + diuron (0.6+30) aqueous suspension
A + diuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + fluometuron (0.6+40)
A + fluometuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + linuron (0.6+50)
A + linuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + buthiuron (0.6+31.3)
A + buthiuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + Saprofron (0.6+50) aqueous suspension
A + Saposlon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
127, A + Lugluong (0.3+50) wettable powder
A + Luulong + 12% calcium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
Aqueous suspension of A + bromogluron (0.6+33.3)
A + bromogluron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + Conyza sativa (0.2+42.3)
A + dazomet + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous A + pyridazinol (0.6+24.6) suspension
A + pyridazinol + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
131, A + hexazinone (0.3+37.5) aqueous suspension
A + hexazinone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
132, A + isoamyl cleaned (0.3+41.7) water suspending agent
A + isoamyl detergent + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoaming agent + 3% ethylene glycol + water
Aqueous suspension of A + madazine (0.3+39)
A + oxamidinyl + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
134, A + herbicidal (0.1+20) suspension concentrate
A + weedicide + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
135, A + lenacil (0.6+40) water suspending agent
A + lenacil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + terbacil (0.1+20)
A + terbacil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + methabenzthiazuron (3+33)
A + methabenzthiazuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.5% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + cyclosulfamuron (0.1+20)
A + cyhaloron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + Isooxalong (0.3+33.4)
A + isoxolone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + metoxuron (0.1+22.2)
A + metoxuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
141, A + Subtilisuron (0.1+22.2) aqueous suspension
A + cumuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + trifluoxazine (1.5+25) aqueous suspension
A + trifluoxazine + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous A + cycloprozoomate (3+41.5) suspension
A + cycloprominate + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + propanil (0.1+25) aqueous suspension
A + propanil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
145, A + pyridate (0.6+45) aqueous suspension
A + pyridate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
146, A + Betaman (0.6+32) water suspension agent
A + Betam + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A + betanin (0.6+32)
A + betanin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
148, A + bentazone (0.6+45) aqueous suspension
A + bentazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
149, A + bromoxynil octanoate (3+30) aqueous suspension
A + bromoxynil octanoate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + bromoxynil (3+20) aqueous suspension
A + bromoxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
151, A + Iodobenzonitrile (3+20) aqueous suspension
A + ioxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Dispersible oil suspension of A + trifluralin (0.6+36)
A, trifluralin, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica and methyl oleate
153, A + butralin (0.1+10) dispersible oil suspending agent
A, butralin, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica and methyl oleate
154, A + pendimethalin (0.6+40) dispersible oil suspension
A, pendimethalin, 6 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 5 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica and methyl oleate
155, A + dithiopyr (1.2+33.4) dispersible oil suspending agent
A, dithiopyr, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica and methyl oleate
156, A + Fluben (0.3+35) water dispersible granule
A + ethylbutenafluoride + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
157, A + amisulalin (0.6+50) dispersible oil suspension
A, oryzalin, 5 percent of calcium dodecyl benzene sulfonate, 7 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica, 20 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + flumetsulam (acetopenetrol) (0.6+28.9)
A + flufenacet (acetobutyl-pentyl), 6% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 6% castor oil-oxyethylene ether, 1.5% organobentonite, 10% 100# solvent oil and methyl oleate
159, A + thiazopyr (0.6+33.3) dispersible oil suspension concentrate
A, fenthizamide, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 0.5 percent of fumed silica, 10 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + propyzamide (propyzamide) (0.6+33.3)
A + Naxyfen (propyzamide), 5% of calcium dodecyl benzene sulfonate, 9% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1% of organic bentonite, 0.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
161, A + chlorthal (0.3+50) wettable powder
A + chlorthal + 10% sodium lignosulfonate dispersant, 3% sodium dodecyl sulfate, 10% precipitated silica white and kaolin
Wettable powder of A + glyphosate (0.3+54.6)
A + phosphorus sodium herbicidum + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica white + kaolin
163, A + diacyl-chlor (0.6+30) dispersible oil suspending agent
A + diacyl-amine + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organic bentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
164.A + acetochlor (0.6+50) dispersible oil suspension
A + acetochlor + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 8% 100# solvent oil + methyl oleate
165, A + butachlor (0.6+30) dispersible oil suspending agent
A, butachlor, 6 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.2 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
Dispersible oil suspension agent of A + pretilachlor (1.5+37.5)
A, pretilachlor, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 0.5 percent of fumed silica and methyl oleate
167.A + metolachlor (0.6+50) dispersible oil suspension
A, metolachlor, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1 percent of fumed silica and methyl oleate
Dispersible oil suspension agent containing A + mefenacet (1.5+37.5)
A, mefenacet, 6 percent of calcium dodecyl benzene sulfonate, 4 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.2 percent of organic bentonite, 1 percent of fumed silica and methyl oleate
169, A + s-metolachlor (0.6+40) dispersible oil suspending agent
A + s-metolachlor + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + flufenacet (3+24)
A, flufenacet, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organobentonite, 1.0 percent of fumed silica, 20 percent of 100# solvent oil and methyl oleate
171, A + napropamide (0.6+50) dispersible oil suspending agent
A, napropamide, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.0 percent of organobentonite, 1.0 percent of fumed silica, 20 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + sulfonylpyraflufen (1.5+25)
A, the mixture of the sulphone pyraflufen-ethyl, 5 percent of calcium dodecyl benzene sulfonate, 4 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate
173.A + anilofos (1.5+25) dispersible oil suspension concentrate
A, anilofos, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 7 percent of castor oil-polyoxyethylene ether, 1.0 percent of organic bentonite, 1.0 percent of fumed silica, 12 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + dimethenamid (1+47)
A, xylenol oxamine, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.2 percent of organic bentonite, 8 percent of 100# solvent oil and methyl oleate
A + fentrazamide (3+33.5) dispersible oil suspension
A + tetrazolyl oxamide + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate
A + triazolam (3+41.5) dispersible oil suspension
A, triazolyl oxamide, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.6% organobentonite, 1.5% fumed silica, 8% 100# solvent oil and methyl oleate
177, A + cafenstrole (1.5+25) dispersible oil suspension
A, cafenstrole, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.6 percent of organobentonite, 1.5 percent of fumed silica, 8 percent of 100# solvent oil and methyl oleate
Dispersible oil suspension of A + piperazinophos (0.6+50)
A, piperophos, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.6 percent of organic bentonite, 1.5 percent of fumed silica, 8 percent of 100# solvent oil and methyl oleate
179.A + propisochlor (0.6+50) dispersible oil suspending agent
A + propisochlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 8% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + alachlor (0.6+50)
A, alachlor, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organic bentonite, 0.5 percent of fumed silica, 8 percent of 100# solvent oil and methyl oleate
181, A + metazachlor (0.6+25) dispersible oil suspending agent
A + metazachlor, 6% calcium dodecyl benzene sulfonate, 4% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 8% 100# solvent oil and methyl oleate
A + propachlor (0.2+25) dispersible oil suspending agent
A, toxoramine, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1 percent of organobentonite, 0.5 percent of fumed silica, 8 percent of 100# solvent oil and methyl oleate
183, A + dimethenamid (0.3+40) dispersible oil suspension agent
A + dimethenamid, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 8% 100# solvent oil and methyl oleate
184, A + prosulfocarb (0.1+22.2) dispersible oil suspending agent
A, bencarb, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1% of organic bentonite, 0.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
185.A + molinate (0.3+50) water dispersible granule
A + molinate + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
186, A + thiobencarb (0.3+50) water dispersible granule
A + thiobencarb + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
Dispersible oil suspension agent of A + benfuresate (0.2+31.1)
A + furbenclamide + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + methyl oleate
188, A + ethofumesate (0.3+26.7) dispersible oil suspending agent
A + ethofumesate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + methyl oleate
189, A + triallate (0.6+50) dispersible oil suspending agent
A + triallate + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate
190, A + molinate (0.1+19.4) dispersible oil suspending agent
A, metalaxyl, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.2 percent of organic bentonite, 12 percent of 100# solvent oil and methyl oleate are complemented
191, A + butachlor (1.5+25) dispersible oil suspending agent
A, buthoxylate, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of white carbon black by a gas phase method, 20 percent of 100# solvent oil and methyl oleate
192, A + Cyclomolinate (2+33) dispersible oil suspending agent
A + cyhalofop-butyl, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate
193, A + pipindone (0.1+11.1) dispersible oil suspension
A, propyzamide, 6 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organic bentonite, 12 percent of 100# solvent oil and methyl oleate
194, A + penflufen (0.1+22.2) dispersible oil suspending agent
A, penflufen, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate are complemented
195, A + Quinclorac (1+25) dispersible oil suspension
A, quinclorac, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate
196, A + fluroxypyr (3+33.5) dispersible oil suspension
A + fluroxypyr, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
197.A + fluroxypyr-meptyl (3+48) dispersible oil suspension concentrate
A + fluroxypyr meptyl + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
198, A + Fluorochloropyridine ester (3+1.5) dispersible oil suspending agent
A, fluroxypyridine fluoride ester, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2 percent of organic bentonite, 1.5 percent of white carbon black by gas phase method and methyl oleate
199, A + triclopyr (0.3+50) wettable powders
A + triclopyr + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
Dispersible oil suspension of A + clopyralid (3+30)
A + clopyralid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A + picloram (0.3+30)
A + picloram + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + aminopyralid (0.3+15)
A + picloram + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
203, A + dicamba (3+36) dispersible oil suspending agent
A + dicamba + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + Clinopyridyl ester (3+5)
A + chloropyridyl chloride ester, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + 2-methyl-4-chlorophenoxyacetic acid (0.6+30)
A + 2-methyl-4-chlorophenoxyacetic acid + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
A + 2-methyl-4-chloro-phenol ethyl thioester (0.6+36.8) dispersible oil suspension concentrate
A + 2-methyl-4-chloro-phenol ethyl thioester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension of A + MCPB (0.6+34.4)
A + MCPB + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
A + 2-methyl-4-chlorophenoxypropionic acid (0.6+32.1) dispersible oil suspending agent
A + 2-methyl-4-chlorophenoxypropionic acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
209.A + 2-methyl-4-chlorophenoxysodium acetate (0.6+33.3) dispersible oil suspension
A + 2-methyl-4-sodium chlorophenoxy acetate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.2% organobentonite + 10% 100# solvent oil + methyl oleate
A + 2-methyl-4-chlorophenoxyacetic acid isooctyl ester (0.6+47) dispersible oil suspending agent
A + 2-methyl-4-chlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 10% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A +2, 4-dichlorphenoxyacetic acid butyl ester (1.2+35)
A +2, 4-Dichlorophenoxyacetic acid butyl ester + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate
Dispersible oil suspension agent of A +2, 4-dichlorophenoxyacetic acid isooctyl ester (0.6+21)
A +2, 4-dichlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate
213, A +2, 4-dichlorophenoxyacetic acid (1.2+28) dispersible oil suspending agent
A +2, 4-dichlorophenoxyacetic acid + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate
214, A + chloromethylquinolinic acid (1.2+18) dispersible oil suspension
A + chloroquinolinic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + methyl oleate
215.A +2 methyl 4 chlorodimethylammonium salt (1.2+15) dispersible oil suspension concentrate
A +2 methyl-4-chlorodimethylammonium salt + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A +2, 4-dichlorprop (0.6+30)
A +2,4-D propionic acid + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
217, A +2,4-DB/2, 4-D butyric acid (0.6+30) dispersible oil suspending agent
A +2,4-DB/2, 4-D butyric acid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organic bentonite, 0.5% fumed silica, 20% 100# solvent oil and methyl oleate
218, A + benazolin (1.5+25) dispersible oil suspending agent
A, benazolin, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate
219, A + Cyclopropanepyrimidinic acid (3+25) dispersible oil suspension
A + cyclopropanepyrimidinic acid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Aqueous A + Glyphosate (0.3+37.5) suspension
A + glyphosate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + phosphinothricin (0.1+18) aqueous suspension
A + phosphinothricin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + glufosinate (0.6+30) aqueous suspension
A + glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + bialaphos (0.6+30) aqueous suspension
A + bialaphos + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A + refined glufosinate-ammonium (1.5+50) water suspension agent
A + glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
225.A + paraquat (1.5+50) aqueous suspension
A + paraquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
226, A + diquat (0.6+35) aqueous suspension
A + diquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
227, A + asulam (0.1+26.5) aqueous suspension
A + asulam + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
228, A + triazine flumioxazin (3+2.5) dispersible oil suspending agent
A, triazineonium flumioxazin, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2 percent of organic bentonite, 1.5 percent of fumed silica, 12 percent of 100# solvent oil and methyl oleate
229, A + indexazine flumioxazine (3+2.5) dispersible oil suspending agent
A + indenyloxazine-fluorchlor, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.8% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate
230, A + oxaziclomefone (3+8.5) dispersible oil suspending agent
A + oxaziclomefone + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
231, A + cinmethylin (6+10) dispersible oil suspension
A + cycloheptanethole, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate
232.A + indene clomazone (6+25) dispersible oil suspending agent
A + indanthrone, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A + quinclorac (1.2+20)
A + dichloroquinolinone, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 12% 100# solvent oil and methyl oleate
234, A + quintocet (6+20) dispersible oil suspending agent
A + quinclomazone + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
235, A + benzuron (0.6+20) dispersible oil suspending agent
A, benzuron, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica, 12 percent of 100# solvent oil and methyl oleate
236, A + meturon (0.6+20) dispersible oil suspending agent
A, meturon, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1 percent of fumed silica, 12 percent of 100# solvent oil and methyl oleate
A + tetflupyrolite (6+20) dispersible oil suspension concentrate
A + tetflupulolimet + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
The processing equipment of the aqueous suspending agent comprises: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the aqueous suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The processing equipment of the dispersible oil suspending agent comprises the following steps: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the dispersible oil suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.
The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.
The processing equipment of the wettable powder comprises: mechanical disintegrators, jet mills, coulter mixers.
The processing process of the wettable powder comprises the following steps: all the materials enter a coulter type mixer, and then are mechanically crushed and airflow crushed to obtain a finished product.
B) Test of drug efficacy
Spraying treatment of stems and leaves after seedling:
1) test conditions
1.1) test target
Grandma was collected from shouman shop, Henan province, Runan county, and David was collected from Huangdao district, Qingdao City, Shandong province. The weeds are cultured by a pot culture method, plastic nutrition bowls with the size of 180 х 140mm are placed in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which are just exposed to the white are uniformly placed on the surface of the soil, and then the enamel tray is covered with 0.5-1cm of soil according to the particle size of the seeds.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
The required active ingredient A is produced by the company, and the preparation method can be referred to patent CN 108586357A; the active ingredients B required by the method are diconazole, bicyclopyrone, topramezone and triazasulam which are all produced by the company, and others are purchased from a reagent company. The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning when the weeds are in a 3-4 leaf period, keeping 15 weeds in each pot, keeping 45 weeds in each treatment, and then continuously culturing until the weeds are in a proper leaf age (3-4 branches of the Veronica and 4-5 leaves of the Aleurea fragrans).
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf by using a 3WP-2000 model walking spray tower on the platform, wherein the liquid spraying amount is 450 kg/hectare. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is shown in 1.1), and the method is carried out according to 'herbicide in pesticide indoor bioassay test guidelines'. The application method is shown in 2.3.2), and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture.
4) Data investigation and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like. Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
The statistical results are shown in tables 1-237 below.
TABLE 1 evaluation of the actual control and combination of the effect of the compounded sulcotrione on Veronica
Figure BDA0002043059510000361
Table 2A evaluation of the actual control and combination of the effect of the compounded mesotrione on Veronica
Figure BDA0002043059510000362
TABLE 3A evaluation of the actual control and combination of topramezone on Veronica
Figure BDA0002043059510000363
Figure BDA0002043059510000371
TABLE 4 evaluation of the actual control and combination of the Potentilla species with respect to the Cyclofonone mixture
Figure BDA0002043059510000372
TABLE 5 evaluation of the actual control and combination of fluroxypyr mixed with clomazone on Veronica
Figure BDA0002043059510000373
TABLE 6 evaluation of the actual control and combination of Fusulcotrione mixture to Veronica
Figure BDA0002043059510000374
TABLE 7 evaluation of the actual control and combination of the effect of the compounded benzobicyclon to Veronica
Figure BDA0002043059510000375
TABLE 8A evaluation of the actual control and combination of the effect of the compounded amicarbazone on Veronica
Figure BDA0002043059510000376
Figure BDA0002043059510000381
TABLE 9 evaluation of the actual control and Combined Effect of Cycloflurtamone mixture on Veronica
Figure BDA0002043059510000382
TABLE 10 evaluation of the actual control and combination of the effect of compounded triazophone on Veronica
Figure BDA0002043059510000383
TABLE 11 evaluation of the actual control and combination of the effect of the compounded benzoxaflutole on Veronica
Figure BDA0002043059510000384
TABLE 12 evaluation of the actual control and combination of the effect of the compounded sulfonylopyrazole on Veronica
Figure BDA0002043059510000385
TABLE 13 evaluation of the actual control and combination of the compounded pyrazolate against Veronica
Figure BDA0002043059510000386
TABLE 14 evaluation of the actual control and Combined Effect of Mixed pyrifluzone on Veronica
Figure BDA0002043059510000387
Figure BDA0002043059510000391
TABLE 15 evaluation of the actual control and combination of tolpyralate combinations against Veronica
Figure BDA0002043059510000392
TABLE 16 evaluation of the actual control and combination of the blended fenquinotrione against Veronica
Figure BDA0002043059510000393
TABLE 17 evaluation of the actual control and combination of isoxaflutole versus Veronica
Figure BDA0002043059510000394
TABLE 18 evaluation of the actual control and Combined action of the blended benzoxadifen on Veronica
Figure BDA0002043059510000395
TABLE 19A compounding
Figure BDA0002043059510000396
Evaluation of actual control effect and combined action of Veronica officinalis
Figure BDA0002043059510000401
TABLE 20 evaluation of the actual control and Combined Effect of compounded flurochloridone on Veronica
Figure BDA0002043059510000402
TABLE 21 evaluation of the actual control and combination of effect of blended flurtamone on Veronica
Figure BDA0002043059510000403
TABLE 22 evaluation of the actual control and combination of diflufenican on Veronica
Figure BDA0002043059510000404
TABLE 23 evaluation of the actual control and combination of Veronica by compounding diflufenican
Figure BDA0002043059510000405
TABLE 24 evaluation of practical control and combination of beflubutamid-compounded versus veronica
Figure BDA0002043059510000411
TABLE 25 evaluation of the actual control and combination of norflurazon combinations on Veronica
Figure BDA0002043059510000412
TABLE 26 evaluation of the actual control and combination of the compounded fluridone to Veronica
Figure BDA0002043059510000413
TABLE 27 evaluation of the actual control and combination of clomazone to Veronica by compounding clomazone
Figure BDA0002043059510000414
TABLE 28 evaluation of the actual control and combination of the Bixlozone combinations against Veronica
Figure BDA0002043059510000415
TABLE 29 evaluation of the actual control and combination of the Mixed tribenuron-methyl to Veronica
Figure BDA0002043059510000421
TABLE 30 evaluation of the actual control and combination of thifensulfuron methyl compounded to Veronica
Figure BDA0002043059510000422
TABLE 31A evaluation of the actual control and combination of the blended bensulfuron methyl to Veronica
Figure BDA0002043059510000423
TABLE 32 evaluation of the actual control and combination of pyrazosulfuron ethyl
Figure BDA0002043059510000424
TABLE 33 evaluation of the actual control and combination of thidiazuron on Veronica
Figure BDA0002043059510000425
TABLE 34 evaluation of the actual control and combination of the compounded halosulfuron-methyl to Veronica
Figure BDA0002043059510000426
Figure BDA0002043059510000431
TABLE 35A evaluation of the actual control and combination of propyrisulfuron on Veronica
Figure BDA0002043059510000432
TABLE 36 evaluation of the actual control and combination of the effect of mixed oxazosulfuron on Veronica
Figure BDA0002043059510000433
TABLE 37 evaluation of the actual control and combination of the compounded rimsulfuron against Veronica
Figure BDA0002043059510000434
TABLE 38 evaluation of the actual control and combination of the Potentilla on with Ethoxysulfuron
Figure BDA0002043059510000435
TABLE 39A evaluation of the actual control and combination of the effect of the compounded orthosulfamuron on Veronica
Figure BDA0002043059510000441
TABLE 40 evaluation of the actual control and combination of Flucarbazone-sodium for compounded Veronica
Figure BDA0002043059510000442
TABLE 41 evaluation of the actual control and combination of the effect of the combination of Methylsulfuron on Veronica
Figure BDA0002043059510000443
TABLE 42 evaluation of the actual control and combination of flazasulfuron to Veronica
Figure BDA0002043059510000444
TABLE 43 evaluation of the actual control and combination of the effect of compounding foramsulfuron against Veronica
Figure BDA0002043059510000445
TABLE 44 evaluation of the actual control and combination of flumetsulam blended with Veronica
Figure BDA0002043059510000451
TABLE 45 evaluation of the actual control and combination of Veronica by compounding triafamone
Figure BDA0002043059510000452
TABLE 46 evaluation of the actual control and combination of penoxsulam compounded on Veronica
Figure BDA0002043059510000453
TABLE 47 evaluation of the actual control and combination of cloransulam-methyl on Veronica
Figure BDA0002043059510000454
TABLE 48 evaluation of the actual control and combination of the effect of the mixed pyroxsulam on Veronica
Figure BDA0002043059510000455
TABLE 49 evaluation of the actual control and combination of imazamox blends on Veronica
Figure BDA0002043059510000461
TABLE 50 evaluation of the actual control and combination of imazethapyr versus Veronica
Figure BDA0002043059510000462
TABLE 51 evaluation of the actual control and combination of imazethapyr versus Veronica
Figure BDA0002043059510000463
TABLE 52 evaluation of the actual control and combination of the effect of the mixed imazapyr on Veronica
Figure BDA0002043059510000464
TABLE 53 evaluation of the actual control and Combined Effect of blended pyriminobac-sodium on Veronica
Figure BDA0002043059510000465
TABLE 54 evaluation of the actual control and combination of florasulam on Veronica
Figure BDA0002043059510000471
TABLE 55 evaluation of the actual control and combination of cloransulam-methyl to Veronica
Figure BDA0002043059510000472
TABLE 56 evaluation of the actual control and combination of pyribenzoxim combinations against Veronica
Figure BDA0002043059510000473
TABLE 57A evaluation of the actual control and combination of the combination of clomazone to Veronica
Figure BDA0002043059510000474
TABLE 58 evaluation of the actual control and combination of imazethapyr blends on Veronica
Figure BDA0002043059510000475
TABLE 59 evaluation of the actual control and combination of the Mixed chlorsulfuron to Veronica
Figure BDA0002043059510000481
TABLE 60 evaluation of the actual control and combination of the effect of Etsulfuron on Veronica
Figure BDA0002043059510000482
TABLE 61A evaluation of the actual control and combination of thistle by Cyclopropanthesulfuron
Figure BDA0002043059510000483
TABLE 62 evaluation of the actual control and combination of the Mixed amidosulfuron to Veronica
Figure BDA0002043059510000484
TABLE 63 evaluation of the actual control and Combined Effect of Ether Trisulfuron on Veronica
Figure BDA0002043059510000485
TABLE 64A evaluation of the actual control and combination of the sodium iodosulfuron against Veronica
Figure BDA0002043059510000491
TABLE 65A evaluation of the actual control and combination of flazasulfuron on Veronica
Figure BDA0002043059510000492
TABLE 66 evaluation of the actual control and combination of Fluorosulfuron mixture to Veronica
Figure BDA0002043059510000493
TABLE 67A evaluation of the actual control and combination of thistle by the Mixed metsulfuron methyl
Figure BDA0002043059510000494
TABLE 68 evaluation of the actual control and combination of triflusulfuron-methyl
Figure BDA0002043059510000495
TABLE 69 evaluation of the actual control and combination of the effect of the Mixed sulfonylalosulfuron on Veronica
Figure BDA0002043059510000501
TABLE 70 evaluation of the actual control and combination of pyrazosulfuron ethyl
Figure BDA0002043059510000502
TABLE 71 evaluation of the actual control and combination of the compounded bispyribac-sodium to Veronica
Figure BDA0002043059510000503
TABLE 72 evaluation of the actual control and combination of Veronica by compounding fluazinam
Figure BDA0002043059510000504
TABLE 73 evaluation of the actual control and combination of the Polyethynyllum syntheticum compounded with Clodinium
Figure BDA0002043059510000505
TABLE 74 evaluation of actual control effect and combined action of pinoxaden mixed with pinoxaden on alopecurus
Figure BDA0002043059510000511
TABLE 75 evaluation of the actual control and Combined Effect of compounding clethodim on Myrtle
Figure BDA0002043059510000512
TABLE 76 evaluation of the actual control and combination of the mixed sethoxydim to the Physalis alkekengi
Figure BDA0002043059510000513
TABLE 77 evaluation of the actual control and combination of quizalofop-p-ethyl to Alhagi sparsifolia
Figure BDA0002043059510000514
TABLE 78 evaluation of the actual control and Combined Effect of compounding Oxidodim on Myrtacea
Figure BDA0002043059510000515
TABLE 79 evaluation of actual control and combination of fluazifop-p-butyl to Alygur foxtail
Figure BDA0002043059510000521
TABLE 80 evaluation of the actual control and joint action of highly effective haloxyfop-R-methyl mixed on the Aleurites communis
Figure BDA0002043059510000522
TABLE 81 evaluation of actual control and combination of Dioscorea zingiberensis C.H.Wright with mixed diclofop-methyl
Figure BDA0002043059510000523
TABLE 82 evaluation of the actual control and combination of fenoxaprop-p-ethyl on a Physalis alkekengi
Figure BDA0002043059510000524
TABLE 83 evaluation of actual control and combination of cyhalofop-butyl for Phyllanthus Amur
Figure BDA0002043059510000525
TABLE 84A evaluation of the actual control and combination of cycloxydim on a myrtle
Figure BDA0002043059510000526
Figure BDA0002043059510000531
TABLE 85 evaluation of the actual control and combination of metamifop to Alygur groundcherry
Figure BDA0002043059510000532
TABLE 86A evaluation of the actual prevention and combination of the Oxycoxalic acid mixture to the Phyllanthus Amarus
Figure BDA0002043059510000533
TABLE 87 evaluation of the actual control and combination of the compounded oxyfluorfen against Veronica
Figure BDA0002043059510000534
TABLE 88A evaluation of the actual control and combination of fomesafen sodium to Veronica
Figure BDA0002043059510000535
TABLE 89A evaluation of the actual control and combination of the blended oxadiazon to Veronica
Figure BDA0002043059510000536
TABLE 90A evaluation of the actual control and combination of oxadiargyl on Veronica
Figure BDA0002043059510000541
TABLE 91A evaluation of the actual control and combined action of the mixed sulfentrazone on Veronica
Figure BDA0002043059510000542
TABLE 92 evaluation of the actual control and combination of the effect of mixedpyraclonil on Veronica
Figure BDA0002043059510000543
TABLE 93 evaluation of the actual control and combination of the compounded flumioxazin against Veronica
Figure BDA0002043059510000544
TABLE 94 evaluation of the actual control and combination of the effect of the mixed pentoxazone on Veronica
Figure BDA0002043059510000545
TABLE 95 evaluation of the actual control and combination of Tiafenac blended with Veronica
Figure BDA0002043059510000551
TABLE 96A evaluation of the actual control and combination of saflufenacil against Veronica
Figure BDA0002043059510000552
TABLE 97 evaluation of the actual control and combination of pyriflufen-sodium to Veronica
Figure BDA0002043059510000553
TABLE 98A evaluation of the actual control and Combined Effect of Mixed Metronidazole on Veronica
Figure BDA0002043059510000554
TABLE 99A evaluation of the actual control and combination of butafenacil against Veronica
Figure BDA0002043059510000555
TABLE 100 evaluation of the actual control and combination of the compounded fluroxypyr ester on Veronica
Figure BDA0002043059510000561
TABLE 101 evaluation of the actual control and combination of acifluorfen acetate combinations against Veronica
Figure BDA0002043059510000562
TABLE 102 evaluation of the actual control and combination of acifluorfen-sodium to Veronica
Figure BDA0002043059510000563
TABLE 103A evaluation of the actual control and combination of triflumimoxazin against Veronica
Figure BDA0002043059510000564
TABLE 104 evaluation of the actual control and combination of the effect of clorazine methyl oxalate on Veronica
Figure BDA0002043059510000565
TABLE 105 evaluation of actual control and combination of atrazine compounded to Veronica
Figure BDA0002043059510000566
Figure BDA0002043059510000571
TABLE 106 evaluation of the actual control and combination of the compounded prometryn against Veronica
Figure BDA0002043059510000572
TABLE 107A evaluation of the actual control and combination of the effect of the mixed simetryn against Veronica
Figure BDA0002043059510000573
TABLE 108 evaluation of the actual control and combination of terbuthylazine compounding to Veronica
Figure BDA0002043059510000574
TABLE 109A evaluation of the actual control and combination of terbutryn against Veronica
Figure BDA0002043059510000575
TABLE 110 evaluation of the actual control and combination of the Mixed ametryn against Veronica
Figure BDA0002043059510000576
Figure BDA0002043059510000581
TABLE 111A evaluation of the actual control and combination of iprovalbumin against Veronica
Figure BDA0002043059510000582
TABLE 112 evaluation of the actual control and combination of the phytoncide mixture to Veronica
Figure BDA0002043059510000583
TABLE 113 evaluation of the actual control and combination of the blended diuron against Veronica
Figure BDA0002043059510000584
TABLE 114 evaluation of the actual control and combination of the compounded simazine against Veronica
Figure BDA0002043059510000585
TABLE 115A evaluation of the actual control and Combined Effect of Mixed metribuzin on Veronica
Figure BDA0002043059510000586
Figure BDA0002043059510000591
TABLE 116 evaluation of the actual control and Combined Effect of compounding ethifluzone on Veronica
Figure BDA0002043059510000592
TABLE 117A evaluation of the actual control and Combined Effect of the compounded amicarbazone on Veronica
Figure BDA0002043059510000593
TABLE 118 evaluation of the actual control and Combined Effect of Co-compounded metamitron on Veronica
Figure BDA0002043059510000594
TABLE 119 evaluation of actual control and combination of compounded cyanazine to Veronica
Figure BDA0002043059510000595
TABLE 120A evaluation of the actual control and combination of the effect of the Mixed chlorotoluron on Veronica
Figure BDA0002043059510000596
Figure BDA0002043059510000601
TABLE 121A evaluation of the actual control and combination of the combination of isoproturon compounded on Veronica
Figure BDA0002043059510000602
TABLE 122 evaluation of the actual control and combination of the compounded diuron versus Veronica
Figure BDA0002043059510000603
TABLE 123A evaluation of the actual control and combination of the effect of the compounded fluometuron on Veronica
Figure BDA0002043059510000604
TABLE 124 evaluation of the actual control and combination of the blended linuron on Veronica
Figure BDA0002043059510000605
TABLE 125A evaluation of the actual control and combination of the effect of the Mixed Thidiazuron on Veronica
Figure BDA0002043059510000606
Figure BDA0002043059510000611
TABLE 126 evaluation of the actual control and combination of Shaplon against Veronica
Figure BDA0002043059510000612
TABLE 127A evaluation of the actual control and combination of the Mixed Lukong versus Veronica
Figure BDA0002043059510000613
TABLE 128A evaluation of actual control and combined action of blended bromuron on Veronica
Figure BDA0002043059510000614
TABLE 129 evaluation of the actual control and combination of the compounded Caryopterina against Veronica
Figure BDA0002043059510000615
TABLE 130 evaluation of the actual control and combination of the effect of the compounded pyridazinols on Veronica
Figure BDA0002043059510000616
TABLE 131A evaluation of the actual control and Combined Effect of Cyclohexazinone on Veronica
Figure BDA0002043059510000621
TABLE 132A evaluation of the actual control and combination of isovaleryl
Figure BDA0002043059510000622
TABLE 133A evaluation of actual control and combination of Sunpora with mixed madder
Figure BDA0002043059510000623
TABLE 134 evaluation of the actual control and combination of the herbicidal combination against Veronica
Figure BDA0002043059510000624
TABLE 135A evaluation of the actual control and combination of lenacil to Veronica
Figure BDA0002043059510000625
TABLE 136A evaluation of the actual control and combination of terbacil against Veronica
Figure BDA0002043059510000631
TABLE 137A evaluation of the actual control and combination of the effect of the mixed methabenzthiazuron on Veronica
Figure BDA0002043059510000632
TABLE 138 evaluation of the actual control and combination of the effect of Cycloflururon on Veronica
Figure BDA0002043059510000633
TABLE 139A evaluation of the actual control and combination of isoxagon to Veronica
Figure BDA0002043059510000634
TABLE 140A evaluation of the actual control and combination of the effect of compounding metoxuron on Veronica
Figure BDA0002043059510000635
TABLE 141A evaluation of the actual control and combination of the blended subtillon against Veronica
Figure BDA0002043059510000641
TABLE 142A evaluation of the actual control and Combined Effect of compounded trifluoxazine on Veronica
Figure BDA0002043059510000642
TABLE 143A evaluation of the actual control and Combined action of the compounded cycloprominate on Veronica
Figure BDA0002043059510000643
TABLE 144A evaluation of the actual control and combination of propanil compounded against Veronica
Figure BDA0002043059510000644
TABLE 145 evaluation of the actual control and combination of the Mixed pyridate against Veronica
Figure BDA0002043059510000645
TABLE 146A evaluation of the actual control and combination of the combination of betaine-Ann to Veronica
Figure BDA0002043059510000651
TABLE 147A evaluation of the actual control and combination of the combed betanin against Veronica
Figure BDA0002043059510000652
TABLE 148 evaluation of the actual control and Combined Effect of the Mixed Mefenacet to Veronica
Figure BDA0002043059510000653
TABLE 149A evaluation of the actual control and Combined Effect of compounded bromoxynil octanoate on Veronica
Figure BDA0002043059510000654
TABLE 150 evaluation of the actual control and combination of bromoxynil with compounding to Veronica
Figure BDA0002043059510000655
TABLE 151A evaluation of the actual control and combination of the compounded iodobenzonitrile with Veronica
Figure BDA0002043059510000661
TABLE 152 evaluation of the actual control and combination of trifluralin combinations against Veronica
Figure BDA0002043059510000662
TABLE 153A evaluation of the actual control and combination of Seben-butralin against Veronica
Figure BDA0002043059510000663
TABLE 154 evaluation of the actual control and combination of pendimethalin compounded against Veronica
Figure BDA0002043059510000664
TABLE 155A evaluation of the actual control and combination of the effect of the co-formulated dithiopyr on Veronica
Figure BDA0002043059510000665
TABLE 156A evaluation of the actual control and combination of Fluoroxylum difluoride mixtures against Veronica
Figure BDA0002043059510000671
TABLE 157 evaluation of the actual control and combination of the effect of the combination of amisulalin compounds on Veronica
Figure BDA0002043059510000672
TABLE 158A evaluation of the actual control and combination of the effect of the compounded flumetsulam (acetopenalin) on Veronica
Figure BDA0002043059510000673
TABLE 159 evaluation of the actual control and Combined action of the mixed thiazopyr on Veronica
Figure BDA0002043059510000674
TABLE 160A evaluation of the actual control and combination of the effect of mixed lenacil (propyzamide) on Veronica
Figure BDA0002043059510000675
TABLE 161A evaluation of actual control and combination of chlorfenapyr against Veronica
Figure BDA0002043059510000676
Figure BDA0002043059510000681
TABLE 162 evaluation of the actual control and combination of the Potentilla treatments with the compounded glyphosate
Figure BDA0002043059510000682
TABLE 163A evaluation of the actual control and Combined Effect of the compounded diacyl-chlor on Veronica
Figure BDA0002043059510000683
TABLE 164 evaluation of the actual control and combination of acetochlor combinations against Veronica
Figure BDA0002043059510000684
TABLE 165A evaluation of the actual control and Combined Effect of butachlor compounded in Veronica
Figure BDA0002043059510000685
TABLE 166A evaluation of the actual control and combination of pretilachlor against Veronica
Figure BDA0002043059510000686
Figure BDA0002043059510000691
Evaluation of actual control effect and combined effect of table 167A mixed metolachlor on Veronica
Figure BDA0002043059510000692
TABLE 168A evaluation of the actual control and combination of the blended mefenacet to Veronica
Figure BDA0002043059510000693
TABLE 169A evaluation of the actual control and combined action of the mixed s-metolachlor on Veronica
Figure BDA0002043059510000694
TABLE 170A evaluation of the actual control and combination of flufenacet combinations against Veronica
Figure BDA0002043059510000695
TABLE 171 evaluation of the actual control and combination of the compounded fenazamide against Veronica
Figure BDA0002043059510000696
Figure BDA0002043059510000701
TABLE 172A evaluation of the actual control and Combined Effect of Mixed Sulforubin on Veronica
Figure BDA0002043059510000702
TABLE 173A evaluation of the actual control and combination of anilofos formulated to Veronica
Figure BDA0002043059510000703
TABLE 174A evaluation of the actual control and combination of the effect of compounded xylenol oxamine on Veronica
Figure BDA0002043059510000704
TABLE 175A evaluation of the actual control and combination of the compounded tetrazolamides on Veronica
Figure BDA0002043059510000705
TABLE 176A evaluation of the actual control and combination of the compounded mefenamic acid to Veronica
Figure BDA0002043059510000706
Figure BDA0002043059510000711
TABLE 177A evaluation of the actual control and combination of the mixed cafenstrole against Veronica
Figure BDA0002043059510000712
TABLE 178 evaluation of the actual control and Combined Effect of compounded paraquat on Veronica
Figure BDA0002043059510000713
TABLE 179A evaluation of the actual control and combination of the mixed propisochlor against Veronica
Figure BDA0002043059510000714
TABLE 180A evaluation of the actual control and combination of alachlor compounding to Veronica
Figure BDA0002043059510000715
TABLE 181A evaluation of the actual control and combination of diflufenican against Veronica
Figure BDA0002043059510000716
Figure BDA0002043059510000721
TABLE 182 evaluation of the actual control and combination of Veronica by Convolvula indica
Figure BDA0002043059510000722
TABLE 183A evaluation of the actual control and combination of the Mixed dimethenamid to Veronica
Figure BDA0002043059510000723
TABLE 184A evaluation of actual control and combined action of mixed prosulfocarb on Aleurites montana
Figure BDA0002043059510000724
TABLE 185A evaluation of the actual control and combined action of the blended grass-enemy on the Physalis alkekengi
Figure BDA0002043059510000725
TABLE 186 evaluation of actual control and joint action of mixed dicranostigma leptopodum on Aleurites montana
Figure BDA0002043059510000726
TABLE 187 evaluation of actual control and combination of Fulvuang mixture for Aleurites montana
Figure BDA0002043059510000731
TABLE 188A evaluation of the actual control and combination of the blended Oxyfluorfen to Alygur avender
Figure BDA0002043059510000732
TABLE 189 evaluation of actual control and combination of Dicamba mixed with brida for bride
Figure BDA0002043059510000733
TABLE 190A evaluation of actual control and combined action of mixed phytocide against Amur foxtail
Figure BDA0002043059510000734
Evaluation of actual prevention effect and combined effect of Table 191A mixed with butantze on physalis alkekengi
Figure BDA0002043059510000735
Evaluation of actual control effect and combined action of Table 192A mixed cyclophane-diphacinone on physalis alkekengi
Figure BDA0002043059510000741
TABLE 193 evaluation of actual control and combined action of pipindone mixture to Aleurites montana
Figure BDA0002043059510000742
Evaluation of actual control effect and combined effect of table 194A mixed pennyroyal on physalis alkekengi
Figure BDA0002043059510000743
TABLE 195A evaluation of the actual control and combination of the Quinclorac
Figure BDA0002043059510000744
TABLE 196A evaluation of the actual control and Combined Effect of the compounded Fluroxypyr on Veronica
Figure BDA0002043059510000745
TABLE 197A evaluation of the actual control and Combined Effect of the compounded fluroxypyr meptyl on Veronica
Figure BDA0002043059510000746
Figure BDA0002043059510000751
TABLE 198A evaluation of the actual control and combination of fluroxypyridine-mixed effect on Veronica
Figure BDA0002043059510000752
TABLE 199 evaluation of actual control and Combined Effect of triclopyr on Veronica
Figure BDA0002043059510000753
TABLE 200A evaluation of the actual control and combination of clopyralid on Veronica
Figure BDA0002043059510000754
TABLE 201 evaluation of the actual control and combination of Picloram combination against Veronica
Figure BDA0002043059510000755
TABLE 202A evaluation of the actual control and combination of the effect of the compounded aminopyralid on Veronica
Figure BDA0002043059510000756
Figure BDA0002043059510000761
TABLE 203A evaluation of the actual control and combination of dicamba mixed versus Veronica
Figure BDA0002043059510000762
TABLE 204A evaluation of the actual control and combination of chlorofluoropyridino esters against Veronica
Figure BDA0002043059510000763
TABLE 205 evaluation of the actual control and combination of 2-methyl-4-chlorophenoxyacetic acid compounded with Veronica
Figure BDA0002043059510000764
TABLE 206A evaluation of the actual control and combination of 2-methyl-4-chloro-phenol ethylthioester combination against Veronica
Figure BDA0002043059510000765
TABLE 207 evaluation of the actual control and Combined Effect of compounded MCPB on Veronica
Figure BDA0002043059510000766
Figure BDA0002043059510000771
TABLE 208 evaluation of the actual control and Combined Effect of 2-methyl-4-chlorophenoxypropionic acid compounded on Veronica
Figure BDA0002043059510000772
TABLE 209 evaluation of the actual control and combination of 2-methyl-4-chlorophenoxyacetic acid sodium salt compounded with Veronica
Figure BDA0002043059510000773
TABLE 210 evaluation of the actual control and combination of the effect of 2-methyl-4-chlorophenoxyacetic acid isooctyl ester compounded with Veronica
Figure BDA0002043059510000774
TABLE 211A evaluation of the actual control and combination of butyl 2, 4-dichlorophenoxyacetate incorporated in Veronica
Figure BDA0002043059510000775
TABLE 212 evaluation of the actual control and combination of 2, 4-Dichlorophenoxyacetic acid isooctyl ester to Veronica
Figure BDA0002043059510000776
TABLE 213A evaluation of the actual control and combination of 2, 4-dichlorophenoxyacetic acid versus Veronica
Figure BDA0002043059510000781
TABLE 214 evaluation of the actual control and combination of clodronic acid to Veronica
Figure BDA0002043059510000782
TABLE 215 evaluation of the actual control and combination of the effect of 2-methyl-4-chlorodimethylammonium salt compounded on Veronica
Figure BDA0002043059510000783
TABLE 216A evaluation of the actual control and combination of 2, 4-Dipropionic acid against Veronica
Figure BDA0002043059510000784
TABLE 217A evaluation of the actual control and combination of 2,4-DB/2, 4-Distillative acid against Veronica
Figure BDA0002043059510000785
TABLE 218 evaluation of the actual control and Combined action of the mixed benazolin against Veronica
Figure BDA0002043059510000791
TABLE 219 evaluation of the actual control and Combined Effect of Cyclopropirimidate on Veronica
Figure BDA0002043059510000792
TABLE 220A evaluation of the actual control and combination of glyphosate versus veronica
Figure BDA0002043059510000793
TABLE 221A evaluation of the actual control and combination of the effect of compounded phosphinothricin on Veronica
Figure BDA0002043059510000794
TABLE 222A evaluation of the actual control and combination of glufosinate-ammonium combinations on Veronica
Figure BDA0002043059510000795
TABLE 223 evaluation of actual control and combination of bialaphos with compounded bialaphos on Veronica
Figure BDA0002043059510000796
Figure BDA0002043059510000801
TABLE 224A evaluation of the actual control and combination of the compounded glufosinate-ammonium to Veronica
Figure BDA0002043059510000802
TABLE 225A evaluation of the actual control and combination of paraquat on Veronica
Figure BDA0002043059510000803
TABLE 226A evaluation of the actual control and Combined action of the blended diquat on Veronica
Figure BDA0002043059510000804
TABLE 227A evaluation of the actual control and combination of the compounded asulam to Veronica
Figure BDA0002043059510000805
TABLE 228 evaluation of the actual control and combination of the compounded triazineamic acid-fluoram against Veronica
Figure BDA0002043059510000806
Figure BDA0002043059510000811
TABLE 229A evaluation of the actual control and combination of the effect of the mixed indexazine flumioxazin on Veronica
Figure BDA0002043059510000812
TABLE 230A evaluation of the actual control and Combined Effect of Co-mingled oxaziclomefone on Veronica
Figure BDA0002043059510000813
TABLE 231 evaluation of the actual control and combination of the compounded cycloheptane ether of Table 231A on Veronica
Figure BDA0002043059510000814
TABLE 232A evaluation of the actual control and combination of the effect of compounded indanthrene on Veronica
Figure BDA0002043059510000815
TABLE 233A evaluation of the actual control and combination of cloquintocet-mefone mixture to Veronica
Figure BDA0002043059510000816
TABLE 234A evaluation of the actual control and combination of the effect of the compounded cloquintocet on Veronica
Figure BDA0002043059510000817
Figure BDA0002043059510000821
TABLE 235A evaluation of the actual control and combination of the effect of the compounded prosulfuron against Veronica
Figure BDA0002043059510000822
TABLE 236 evaluation of the actual control and combination of the Mixed Mesona-multocida to Veronica
Figure BDA0002043059510000823
TABLE 237A evaluation of the actual control and Combined Effect of the compounded tetflupyrlomet on Veronica
Figure BDA0002043059510000824
C) Demonstration of field
The herbicidal compositions prepared in examples 1 to 237 were used for field weed effect tests.
An exemplary popularization test was carried out in the test point of Huai' an, Jiangsu in 2018. The weeds in the field are mainly: speedwell, cleavers, shepherd's purse, chickweed, bull chickweed, and alopecurus.
The test method comprises the following steps:
treating stem and leaf by spraying water with a hand sprayer until the weeds are in 3-5 leaf stage30 kg/667 m2The stem and leaf are sprayed evenly.
The specific test agents and dosages are detailed in table 238, with a cell area of 50 square meters, repeated 4 times per treatment. The control effect was investigated 45 days after the application of the composition, as shown in Table 238.
Figure BDA0002043059510000831
Table 238 exemplary field Effect of the compounded compositions
Figure BDA0002043059510000832
Figure BDA0002043059510000841
Figure BDA0002043059510000851
Figure BDA0002043059510000861
Figure BDA0002043059510000871
Figure BDA0002043059510000881
Figure BDA0002043059510000891
Figure BDA0002043059510000901
Figure BDA0002043059510000911
Figure BDA0002043059510000921
Figure BDA0002043059510000931
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition is used for preventing and killing off the weeds such as speedwell, alopecurus, chickweed, starwort, cleavers, shepherd's purse, descurainia sophia, alopecurus japonicus and the like, has a surprising and unexpected synergistic effect, has more remarkable synergistic effect under low dosage, can reduce the dosage and the pollution to the environment, is reasonably compounded, reduces the agricultural cost, has high efficiency on ALS and ACCase inhibitor resistant weeds, and has good application prospect. Meanwhile, the herbicide composition shows good selectivity and excellent synergistic effect in wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and other plants through tests, and can be developed into herbicide mixtures with wide market value.

Claims (9)

1.A herbicidal composition comprising pyrimidinyloximes characterized in that the active ingredient consists of herbicidally effective amounts of A and B, wherein,
the active ingredient A is
Figure FDA0003021983120000011
The active ingredient B is selected from one of the following compounds and salts/esters thereof:
(1) HPPD inhibitors: sulcotrione, mesotrione, topramezone, tembotrione, flurtamone, benzofuranone, benzobicyclon, topramezoneBicyclopyrone, tembotrione, topramezone, pyrazoxate, tralkoxydim, tolpyralate, fenquinotrione, isoxaflutole, pyraclonil,
Figure FDA0003021983120000012
Wherein when B is selected from sulcotrione, the weight ratio of A, B is 1: 800-1: 150;
when B is selected from mesotrione or triazophone, the weight ratio of A, B is 1: 100-1: 10;
when B is selected from topramezone, topramezone or sulfonylopyrazole, the weight ratio of A, B is 1: 30-1: 5;
when B is selected from tembotrione, fluroxypyr, carfentrazone-ethyl or isoxaflutole
Figure FDA0003021983120000013
When the weight ratio of A, B is 1: 80-1: 10;
when B is selected from the group consisting of benzofuranone, A, B is in a weight ratio of 1: 50-1: 10;
when B is selected from the benzobicyclon, the weight ratio of A, B is 1: 200-1: 30;
when B is selected from pyrazolate, A, B is in a weight ratio of 1: 1500-1: 300;
when B is selected from the bicyclopyrone, the weight ratio of A, B is 1: 1500-1: 300;
when B is selected from tolpyralate or fenquinotrione, the weight ratio of A, B is 1: 250-1: 30;
when B is selected from the benzoxadiazole, the weight ratio of A, B is 1: 2500-1: 300.
2.A herbicidal composition comprising pyrimidineformyl oximes according to claim 1,
when B is selected from sulcotrione, A, B is in a weight ratio of 1: 600-1: 150;
when B is selected from mesotrione or triazophone, the weight ratio of A, B is 1: 92-1: 23;
when B is selected from topramezone, topramezone or sulfonylopyrazole, the weight ratio of A, B is 1: 20-1: 5;
when B is selected from tembotrione, fluroxypyr, carfentrazone-ethyl or isoxaflutole
Figure FDA0003021983120000021
When the weight ratio of A, B is 1: 60-1: 15;
when B is selected from the group consisting of benzofuranone, A, B is in a weight ratio of 1: 48-1: 12;
when B is selected from the group consisting of benzobicyclon, A, B is in a weight ratio of 1: 168-1: 42;
when B is selected from pyrazolate, A, B is in a weight ratio of 1: 1300-1: 325;
when B is selected from the bicyclopyrone, the weight ratio of A, B is 1: 1200-1: 300;
when B is selected from tolpyralate or fenquinotrione, the weight ratio of A, B is 1: 200-1: 50;
when B is selected from the benzoxadiazole, the weight ratio of A, B is 1: 2000-1: 500.
3. The herbicidal composition comprising pyrimidineformyl oximes according to claim 1 or 2, wherein A, B is contained in the herbicidal composition in an amount of 1 to 95% by mass.
4. The herbicidal composition comprising pyrimidyl formyl oximes according to claim 3, wherein the content of A, B in the herbicidal composition is 10-80% by weight of the total amount.
5.A herbicidal composition comprising pyrimidineformyl oximes according to claim 1 or 2, characterized in that it further comprises conventional adjuvants.
6.A herbicidal composition comprising pyrimidineformyl oximes according to claim 5, wherein the conventional adjuvants include carriers, surfactants.
7.A herbicidal composition comprising pyrimidineformyl oximes according to claim 1 or 2, characterized in that it further comprises at least one safener.
8.A herbicidal composition comprising pyrimidinylcarboxximes according to claim 7, wherein the safener is selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet, gibberellic acid, furilazole, metcamifen.
9.A herbicidal composition comprising pyrimidyl formyloxime compound as claimed in claim 1 or 2, wherein the specific formulation of said herbicidal composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.
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