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CN109817656A - A kind of pixel defining layer and preparation method - Google Patents

A kind of pixel defining layer and preparation method Download PDF

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Publication number
CN109817656A
CN109817656A CN201711163186.2A CN201711163186A CN109817656A CN 109817656 A CN109817656 A CN 109817656A CN 201711163186 A CN201711163186 A CN 201711163186A CN 109817656 A CN109817656 A CN 109817656A
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pixel defining
defining layer
layer
boss
preparation
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CN201711163186.2A
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CN109817656B (en
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张东华
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TCL Corp
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TCL Corp
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Abstract

The present invention discloses a kind of pixel defining layer and preparation method, and method includes: to provide original pixel defining layer, and the pixel defining layer has the groove for defining luminescence unit;The mold with boss is provided, the boss of the mold and the groove of the pixel defining layer coincide;The boss level is divided into upper and bottom section, and the outer diameter of the upper part is greater than the outer diameter of lower part, forms one layer of hydrophobic material in the side of the upper part, forms one layer of hydrophilic material in the side of the lower part;The boss of the mold is bonded with the groove of the pixel defining layer, groove side surface upper part point layer containing hydrophobic material, lower pixel defining layer of the part containing hydrophilic materials is prepared.Hydrophilic and hydrophobic material is coated in the side of mold convexity by the present invention, is then transferred to pixel defining layer groove side by mold, the pixel defining layer structure that part is hydrophobic, lower part is hydrophilic in acquisition, so as to improve the uniformity of ink-jet printing ink.

Description

A kind of pixel defining layer and preparation method
Technical field
The present invention relates to field of display technology more particularly to a kind of pixel defining layers and preparation method.
Background technique
Inkjet printing technology can have been applied in light emitting diode (LED) display panel industry, needed in advance on substrate The preparation for completing pixel defining layer in print procedure, (reduces coffee ring, horse in order to which ink to be effectively printed upon to substrate Lang Geni stream influences), ink uniformity and resolution ratio are improved, pixel defining layer can be surface-treated, such as surface hydrophobe Performance improvement.
Summary of the invention
The purpose of the present invention is to provide a kind of pixel defining layer and preparation methods, it is intended to solve existing pixel defining layer Structure, the bad problem of uniformity after ink printed gets on.
Technical scheme is as follows:
A kind of preparation method of pixel defining layer, wherein comprising steps of
Original pixel defining layer is provided, the pixel defining layer has the groove for defining luminescence unit;
The mold with boss is provided, the boss of the mold and the groove of the pixel defining layer coincide;
The boss level is divided into upper and bottom section, and the outer diameter of the upper part is greater than the outer diameter of lower part, on described Partial side forms one layer of hydrophobic material, forms one layer of hydrophilic material in the side of the lower part;
The boss of the mold is bonded with the groove of the pixel defining layer, groove side surface upper part point is prepared containing hydrophobicity Material layer, lower pixel defining layer of the part containing hydrophilic materials.
The preparation method of the pixel defining layer, wherein the boss level is divided into upper and bottom section, it is described on Partial outer diameter is greater than the outer diameter of lower part, one layer of hydrophobic material is formed in the side of the upper part, in the lower part Side formed one layer of hydrophilic material method, comprising steps of
The boss is fully immersed in hydrophobic material solution, immersion depth is denoted as h1, forms one in the boss side surfaces Layer hydrophobic material;
The boss is immersed in cleaning solution after taking-up, immersion depth is denoted as h2;
The boss is immersed in hydrophilic material solution after taking-up, immersion depth is denoted as h3, wherein h3 >=h2 > 0 h1 >, H1>boss height, and h3<boss height form one layer of hydrophobic material in the side of the upper part, in the lower part Side forms one layer of hydrophilic material.
The preparation method of the pixel defining layer, wherein the hydrophobic material solution is dissolved in by hydrophobic material It is configured in one solvent;
The hydrophobic material is flexible polymer;
And/or first solvent is one of dimethylformamide and dimethyl sulfoxide or a variety of.
The preparation method of the pixel defining layer, wherein the flexible polymer is fluorine-containing polyolefin, fluorine-containing poly- One of epoxyalkane and polysiloxanes are a variety of.
The preparation method of the pixel defining layer, wherein the hydrophilic material solution is dissolved in by hydrophilic material It is configured in two solvents;
The hydrophilic material is rigid polymer;
And/or second solvent is one of dichlorotoleune, benzotrichloride and acetone or a variety of.
The preparation method of the pixel defining layer, wherein the rigid polymer is the polymerization containing alkyl in main chain One of polymer containing annular rigid structure in object and main chain is a variety of.
The rigid polymer is polyimides or bisphenol-a polycarbonate.
The preparation method of the pixel defining layer, wherein by the recessed of the boss of the mold and the pixel defining layer Slot fitting, and under the conditions of heating, ultrasonic vibration or ultraviolet irradiation, groove side surface upper part point is prepared containing hydrophobic material Layer, lower pixel defining layer of the part containing hydrophilic materials.
The preparation method of the pixel defining layer, wherein the pixel defining layer with a thickness of 3-5 μm.
The preparation method of the pixel defining layer, wherein the groove side hydrophobic material of the pixel defining layer covers Lid with a thickness of 1.5-2.5 μm.
A kind of pixel defining layer, wherein be prepared using the preparation method of pixel defining layer of the present invention.
The utility model has the advantages that the present invention is to be coated hydrophilic material on mold and hydrophobic material in the way of similar transfer In pixel defining layer groove side, so that obtaining groove side surface upper part point contains hydrophobic material, hydrophily material is contained in lower part The pixel defining layer of material, and then improve the uniformity after ink printed.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of original pixel defining layer provided by the invention.
Fig. 2 is the structural schematic diagram of pixel defining layer prepared by the present invention.
Fig. 3 is a kind of flow diagram of the preparation method of pixel defining layer provided by the invention.
Specific embodiment
The present invention provides a kind of pixel defining layer and preparation method, to make the purpose of the present invention, technical solution and effect more Add clear, clear, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used To explain the present invention, it is not intended to limit the present invention.
The present invention provides a kind of preparation method of pixel defining layer, wherein comprising steps of
100, original pixel defining layer is provided, the pixel defining layer has the groove for defining luminescence unit;
200, the mold with boss is provided, the boss of the mold and the groove of the pixel defining layer coincide;
300, the boss level is divided into upper and bottom section, and the outer diameter of the upper part is greater than the outer diameter of lower part, in institute The side for stating part forms one layer of hydrophobic material, forms one layer of hydrophilic material in the side of the lower part;
400, the boss of the mold is bonded with the groove of the pixel defining layer, groove side surface upper part point is prepared containing thin Water-based material layer, lower pixel defining layer of the part containing hydrophilic materials.
Above-mentioned steps are described in detail below by specific embodiment.
In step 100, the original pixel defining layer can be prepared by following steps: on the substrate got ready One layer of pixel defining layer is prepared using the method poured, with a thickness of 3-5 μm, as shown in Figure 1,1 is original pixel defining layer. The pixel defining layer is prepared as the prior art, and more specifically details are not described herein for preparation process.
Further, it before preparing the original pixel defining layer over the substrate, further comprises the steps of: to the lining Bottom starts the cleaning processing, specific cleaning process: cleaning solution is sprayed in substrate surface, after hairbrush is scrubbed, into high pressure It sprays in ultrapure water, rinses substrate surface, remove the raffinate of substrate surface, finally dried up.
In step 200, the mold has boss, and the boss and the groove of the pixel defining layer coincide.
In step 300, the boss level is divided into upper and bottom section, and the outer diameter of the upper part is greater than lower part Outer diameter, forms one layer of hydrophobic material in the side of the upper part, forms one layer of hydrophily material in the side of the lower part Material.Mold of the present invention plays the role of seal in similar transfer, by the way that hydrophobic material and hydrophilic material to be coated in Then the side of mold convexity is transferred to pixel defining layer groove side by mold, part is hydrophobic in acquisition, lower part is hydrophilic Pixel defining layer structure.
As one of specific embodiment, the boss level is divided into upper and bottom section, the upper part Outer diameter is greater than the outer diameter of lower part, one layer of hydrophobic material is formed in the side of the upper part, in the side of the lower part The method for forming one layer of hydrophilic material, comprising steps of
It secures the mold in positioning device, the mold can move up and down, and precision controlling is at 0.01 μm;
The boss is fully immersed in configured good hydrophobic material solution, immersion depth is denoted as h1,1-3min is stood, One layer of hydrophobic material is formed in the boss side surfaces.Wherein it is molten by hydrophobic material to be dissolved in first for the hydrophobic material solution It is configured in agent;The hydrophobic material is flexible polymer, such as can be fluorine-containing polyolefin, fluorine-containing polyalkylene oxide One of hydrocarbon and polysiloxanes etc. are a variety of;First solvent can be in dimethylformamide and dimethyl sulfoxide etc. It is one or more.Preferably, first solvent volume accounts for the 40%-70% of the hydrophobic material liquor capacity.
The boss is immersed in cleaning solution after taking-up, immersion depth is denoted as h2.The present invention is molten using the cleaning Liquid is to clean partially formed under boss one layer of hydrophobic material, and the cleaning solution can be (hydrophobic for hydrophobic solvent Class solvent can be hydrocarbon solvent, such as toluene, dimethylbenzene.) or clear water solution etc. it is without being limited thereto.
The boss is immersed in configured good hydrophilic material solution after taking-up, immersion depth is denoted as h3, wherein H1 > h3>=h2>0, h1>boss height, and h3<boss height stand 1-3min, form one layer in the side of the upper part Hydrophobic material forms one layer of hydrophilic material in the side of the lower part.Wherein the hydrophilic material solution is by hydrophilic Property material, which is dissolved in the second solvent, to be configured;The hydrophilic material is rigid polymer, and the rigid polymer is main chain In one of polymer containing annular rigid structure etc. or a variety of in polymer and main chain containing alkyl, such as can be Polyimides, bisphenol-a polycarbonate;Second solvent can for one of dichlorotoleune, benzotrichloride and acetone etc. or It is a variety of.Preferably, second solvent volume accounts for the 30%-70% of the hydrophilic material liquor capacity.
In step 400, as a wherein specific embodiment, by the boss of the mold and the pixel defining layer Groove fitting, and under the conditions ofs heating, ultrasonic vibration or ultraviolet irradiation etc., groove side surface upper part point material containing hydrophobicity is prepared The bed of material, lower pixel defining layer of the part containing hydrophilic materials.Preferably, the temperature of the heating is 100-150 DEG C, heating Time is 5-10min.Mold of the present invention plays the role of seal in similar transfer, by by hydrophobic material and hydrophily Material be coated in mold convexity side, pixel defining layer groove side is then transferred to by mold, in acquisition part it is hydrophobic, The hydrophilic pixel defining layer structure in lower part, so as to improve the uniformity of ink-jet printing ink.
The present invention provides a kind of pixel defining layer, wherein using the preparation method system of pixel defining layer of the present invention It is standby to form.As shown in Fig. 2, pixel defining layer of the present invention includes original pixel defining layer 1, wherein further include pixel circle The hydrophobic material layer 2 that the side surface upper part of the groove of given layer point is formed, the hydrophilic materials 3 that lower part is formed.
Present invention pixel defines the structure that part on layer is hydrophobic, lower part is hydrophilic, and this structure changes pixel defining layer Wetting characteristics, in groove (pixel region) depositing light-emitting unit (including the hole functional layer, luminescent layer defined to pixel defining layer With electronic work ergosphere) material when, the hydrophobic solution that can be avoided in upper part flows to adjacent pixel region, and lower part is hydrophilic to improve The surface tension of solution enables solution to be entirely paved in the pixel region that pixel defining layer defines, and improves film forming homogeneity, from And improve device luminous mass, prolong the service life.
Pixel defining layer of the present invention with a thickness of 3-5 μm, wherein the groove side hydrophobicity of the pixel defining layer Material covering with a thickness of 1.5-2.5 μm.In each layer structure of depositing light-emitting unit, the solution of every layer of structure can be dredged in upside Under the action of water, downside are hydrophilic, uniform film is formed.
The present invention also provides a kind of applications of pixel defining layer as described above, wherein is used for the pixel defining layer Prepare electroluminescent device.
Pixel defining layer is prepared using the above method in the present invention, and QLED device is then prepared by way of inkjet printing Part.As a wherein preferred embodiment, in the pixel defining layer groove, hole is sequentially depositing using the method for inkjet printing Implanted layer (HIL), hole transmission layer (HTL), quantum dot light emitting layer (QD), electron transfer layer (ETL) and back electrode.The present invention The pixel defining layer being prepared, since the groove side surface upper part of pixel defining layer is divided with hydrophobicity, lower part with hydrophilic Property, when preparing QLED device using inkjet printing methods, ink uniformity can be improved, keep prepared device performance more steady It is fixed, and simple process.
Below by embodiment, the present invention is described in detail.
Embodiment 1
The preparation step of the present embodiment pixel defining layer is as follows:
1, the method poured is used to deposit upper a layer thickness as 5 μm of pixel defining layer material (positivity light on ito glass substrate Photoresist);
2, as shown in Fig. 34, mold is then mounted on positioning device (can move up and down, precision is controllably 0.01 mold shape μm), mold decline is immersed in polysiloxanes and dimethyl formamide solution (hydrophobic material solution) for 5 μm, wherein diformazan It is 40% that base formamide volume, which accounts for total volume, stands 1min and takes out, and 3 μm of decline, which is put into clear water, to be cleaned up, and then takes out decline 3 μm are immersed in polyimides and dichlorotoleune solution (hydrophilic material solution), and wherein dichlorotoleune volume accounts for total volume and is 30%, it stands 1min and takes out, surface forms one layer of hydrophobic material on the boss of mold, and lower surface forms one layer Hydrophilic material, as shown in Figure 3,5 be hydrophobic material in Fig. 3, and 6 be hydrophilic material;
3, the boss for being coated with the mold of hydrophobe material is bonded with the groove of the pixel defining layer poured before, at 100 DEG C Lower heating 5min takes out mold, to obtain the upper pixel defining layer that part is hydrophobic, lower part is hydrophilic.
The preparation step of the present embodiment QLED device is as follows:
Upper hole injection layer (HIL), hole are successively deposited using inkjet printing technology in the above-mentioned pixel defining layer prepared Transport layer (HTL), quantum dot light emitting layer (QD), electron transfer layer (ETL) and back electrode.
Embodiment 2
The preparation step of the present embodiment pixel defining layer is as follows:
1, the method poured is used to deposit upper a layer thickness as 5 μm of pixel defining layer material (positivity light on ito glass substrate Photoresist);
2, as shown in Fig. 34, mold is then mounted on positioning device (can move up and down, precision is controllably 0.01 mold shape μm), mold decline is immersed in polysiloxanes and dimethyl formamide solution (hydrophobic material solution) for 5 μm, wherein diformazan It is 50% that base formamide volume, which accounts for total volume, stands 1min and takes out, and 3 μm of decline, which is put into clear water, to be cleaned up, and then takes out decline 3 μm are immersed in polyimides and dichlorotoleune solution (hydrophilic material solution), and wherein dichlorotoleune volume accounts for total volume and is 50%, it stands 1min and takes out, surface forms one layer of hydrophobic material on the boss of mold, and lower surface forms one layer Hydrophilic material, as shown in Figure 3,5 be hydrophobic material in Fig. 3, and 6 be hydrophilic material;
3, the boss for being coated with the mold of hydrophobe material is bonded with the groove of the pixel defining layer poured before, at 100 DEG C Lower heating 5min takes out mold, to obtain the upper pixel defining layer that part is hydrophobic, lower part is hydrophilic.
The preparation step of the present embodiment QLED device is as follows:
Upper hole injection layer (HIL), hole are successively deposited using inkjet printing technology in the above-mentioned pixel defining layer prepared Transport layer (HTL), quantum dot light emitting layer (QD), electron transfer layer (ETL) and back electrode.
Embodiment 3
The preparation step of the present embodiment pixel defining layer is as follows:
1, the method poured is used to deposit upper a layer thickness as 5 μm of pixel defining layer material (positivity light on ito glass substrate Photoresist);
2, as shown in Fig. 34, mold is then mounted on positioning device (can move up and down, precision is controllably 0.01 mold shape μm), mold decline is immersed in polysiloxanes and dimethyl formamide solution (hydrophobic material solution) for 5 μm, wherein diformazan It is 70% that base formamide volume, which accounts for total volume, stands 2min and takes out, and 3 μm of decline, which is put into clear water, to be cleaned up, and then takes out decline 3 μm are immersed in polyimides and dichlorotoleune solution (hydrophilic material solution), and wherein dichlorotoleune volume accounts for total volume and is 70%, it stands 3min and takes out, surface forms one layer of hydrophobic material on the boss of mold, and lower surface forms one layer Hydrophilic material, as shown in Figure 3,5 be hydrophobic material in Fig. 3, and 6 be hydrophilic material;
3, the boss for being coated with the mold of hydrophobe material is bonded with the groove of the pixel defining layer poured before, at 100 DEG C Lower heating 5min takes out mold, to obtain the upper pixel defining layer that part is hydrophobic, lower part is hydrophilic.
The preparation step of the present embodiment QLED device is as follows:
Upper hole injection layer (HIL), hole are successively deposited using inkjet printing technology in the above-mentioned pixel defining layer prepared Transport layer (HTL), quantum dot light emitting layer (QD), electron transfer layer (ETL) and back electrode.
In conclusion a kind of pixel defining layer provided by the invention and preparation method, mold of the present invention play similar Then the effect of seal in transfer passes through mould by the way that hydrophobic material and hydrophilic material to be coated in the side of mold convexity Have and is transferred to pixel defining layer groove side, the pixel defining layer structure that part is hydrophobic, lower part is hydrophilic in acquisition, so as to improve The uniformity of ink-jet printing ink.The pixel defining layer that upper part is hydrophobic, lower part is hydrophilic is prepared using the method for the present invention, Then QLED device is prepared by way of inkjet printing, simple process, prepared device performance is more stable.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention Protect range.

Claims (11)

1. a kind of preparation method of pixel defining layer, which is characterized in that comprising steps of original pixel defining layer is provided, it is described Pixel defining layer has the groove for defining luminescence unit;
The mold with boss is provided, the boss of the mold and the groove of the pixel defining layer coincide;
The boss level is divided into upper and bottom section, and the outer diameter of the upper part is greater than the outer diameter of lower part, on described Partial side forms one layer of hydrophobic material, forms one layer of hydrophilic material in the side of the lower part;
The boss of the mold is bonded with the groove of the pixel defining layer, groove side surface upper part point is prepared containing hydrophobicity Material layer, lower pixel defining layer of the part containing hydrophilic materials.
2. the preparation method of pixel defining layer according to claim 1, which is characterized in that the boss level is divided into top Divide and lower part, the outer diameter of the upper part are greater than the outer diameter of lower part, forms one layer of hydrophobicity in the side of the upper part Material, in the method that the side of the lower part forms one layer of hydrophilic material, comprising steps of
The boss is fully immersed in hydrophobic material solution, immersion depth is denoted as h1, forms one in the boss side surfaces Layer hydrophobic material;
The boss is immersed in cleaning solution after taking-up, immersion depth is denoted as h2;
The boss is immersed in hydrophilic material solution after taking-up, immersion depth is denoted as h3, wherein h3 >=h2 > 0 h1 >, H1>boss height, and h3<boss height form one layer of hydrophobic material in the side of the upper part, in the lower part Side forms one layer of hydrophilic material.
3. the preparation method of pixel defining layer according to claim 2, which is characterized in that the hydrophobic material solution by Hydrophobic material, which is dissolved in the first solvent, to be configured;
The hydrophobic material is flexible polymer;
And/or first solvent is one of dimethylformamide and dimethyl sulfoxide or a variety of.
4. the preparation method of pixel defining layer according to claim 3, which is characterized in that the flexible polymer is fluorine-containing One of polyolefin, fluorine-containing polyalkylene oxide and polysiloxanes or a variety of.
5. the preparation method of pixel defining layer according to claim 2, which is characterized in that the hydrophilic material solution by Hydrophilic material, which is dissolved in the second solvent, to be configured;
The hydrophilic material is rigid polymer;
And/or second solvent is one of dichlorotoleune, benzotrichloride and acetone or a variety of.
6. the preparation method of pixel defining layer according to claim 5, which is characterized in that the rigid polymer is main chain In one of polymer containing annular rigid structure or a variety of in polymer and main chain containing alkyl.
7. the preparation method of pixel defining layer according to claim 6, which is characterized in that the rigid polymer is polyamides Imines or bisphenol-a polycarbonate.
8. the preparation method of pixel defining layer according to claim 1, which is characterized in that the boss by the mold It is bonded with the groove of the pixel defining layer, groove side surface upper part point layer containing hydrophobic material is prepared, lower part is containing hydrophilic The step of pixel defining layer of property material layer include: the boss of the mold is bonded with the groove of the pixel defining layer, and Under the conditions of heating, ultrasonic vibration or ultraviolet irradiation, make the hydrophobic material and hydrophilic material transfer in the boss side surfaces On to the groove side, groove side surface upper part point layer containing hydrophobic material, lower pixel of the part containing hydrophilic materials are obtained Define layer.
9. the preparation method of pixel defining layer according to claim 1, which is characterized in that the thickness of the pixel defining layer It is 3-5 μm.
10. the preparation method of pixel defining layer according to claim 9, which is characterized in that the pixel defining layer it is recessed Slot side hydrophobic material covering with a thickness of 1.5-2.5 μm.
11. a kind of pixel defining layer, which is characterized in that using the system such as the described in any item pixel defining layers of claim 1-10 Preparation Method is prepared.
CN201711163186.2A 2017-11-21 2017-11-21 Pixel defining layer and preparation method thereof Active CN109817656B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1722366A (en) * 2004-06-01 2006-01-18 株式会社半导体能源研究所 Manufacturing method of semiconductor device
CN1815749A (en) * 2005-02-02 2006-08-09 大日本网目版制造株式会社 Substrate for organic el and method for manufacturing the same
CN101034667A (en) * 2006-03-10 2007-09-12 精工爱普生株式会社 Device fabrication by ink-jet printing materials into bank structures, and embossing tool
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