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CN109809922A - A kind of urea synergistic permeating agent - Google Patents

A kind of urea synergistic permeating agent Download PDF

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Publication number
CN109809922A
CN109809922A CN201910264922.6A CN201910264922A CN109809922A CN 109809922 A CN109809922 A CN 109809922A CN 201910264922 A CN201910264922 A CN 201910264922A CN 109809922 A CN109809922 A CN 109809922A
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CN
China
Prior art keywords
urea
synergistic
water
agent
permeating
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Application number
CN201910264922.6A
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Chinese (zh)
Inventor
徐延辉
耿玲
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Liaoning Expansion Agricultural Development Co Ltd
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Liaoning Expansion Agricultural Development Co Ltd
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Priority to CN201910264922.6A priority Critical patent/CN109809922A/en
Publication of CN109809922A publication Critical patent/CN109809922A/en
Withdrawn legal-status Critical Current

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Abstract

The invention discloses a kind of urea synergistic permeating agent, the urea synergistic permeating agent is made by the following method by sodium hydroxide, tertiary sodium phosphate, carbolic acid, ammonium nitrate, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, thickener and water: 1) sodium hydroxide, tertiary sodium phosphate, carbolic acid being put into reaction kettle after mixing and add water, prepares intermediate liquid;2) intermediate liquid obtained is walked before instilling in another reaction kettle into ammonium nitrate to be made, and obtains chelating agent;3) chelating agent obtained is walked before taking, it is chelated with other raw materials, area synergist is made, the urea synergistic permeating agent can penetrate into the inside of urea granules, decomposition release synchronous with urea, crop is continuously in the fertilizer efficiency period of urea and provides nutrition after application, is had effects that regulating crop growth, is promoted crop to the fertility for being absorbed and utilized, improving urea of fertilizer, and the urea synergistic permeating agent can be degradable, will not remain solid in the soil and pollute to soil.

Description

A kind of urea synergistic permeating agent
Technical field
The present invention relates to a kind of fertilizer synergist, especially one kind to penetrate into inside urea granules, improves urea fertilizer The fertilizer synergist of effect.
Background technique
Urea is also known as carbamide (carbamide), the organic compound being made of carbon, nitrogen, oxygen, hydrogen, is a kind of important Neutral fertilizer, urea be suitable for various soil and plant, be a kind of biggish chemical nitrogen fertilizer of current usage amount.But due to Plant growth also needs other a great number of elements, moderate-element and microelement other than nitrogen, only applies urea and is not able to satisfy Plant growth needs, also, when lacking moderate-element and microelement in soil, and will affect crop to macroelement fertilizer Effect is absorbed and utilized.Therefore, in order to improve the fertilizer efficiency of urea, the appearance Wrapped fertilizer synergy in urea granules is usually taken Agent, to supplement moderate-element and microelement necessary to plant growth, to achieve the purpose that improve urea efficiency.Existing skill Coating agent is made mostly based on coating, by moderate-element and microelement and urea film in area synergist in art, is solidificated in urine The surface of crude granule.Although coating urea synergy coating agent can make up that urea fertilizer nutrition is single, absorption rate is low etc. and lack Point, still, since this coating urea coating agent is wrapped around urea surface, after urea is administered in soil, coating Urea coating agent can be decomposed prior to urea, be only capable of at the initial stage of application being crop extra-nutrition, cannot be in the effective of urea efficiency Crop offer moderate-element is provided in the phase and microelement, the effect that urea synergy coating agent improves urea efficiency are limited. In addition, the degradation speed of coating is slower after the urea synergy coating agent of this coating is administered in soil together with urea, residual Solid matter in the soil is easy to pollute soil.
Summary of the invention
Technical problems to be solved by the inivention are: providing a kind of urea synergistic permeating agent, which can seep The inside for arriving urea granules thoroughly, decomposition release synchronous with urea, crop is continuously in the fertilizer efficiency period of urea and provides battalion after application It supports, has effects that regulating crop growth, promotes crop to the fertility for being absorbed and utilized, improving urea of fertilizer, and the urea increases Imitating bleeding agent can be degradable, will not remain solid in the soil and pollute to soil.
The technical solution adopted for solving the technical problem: a kind of urea synergistic permeating agent, the urea synergistic permeating agent by Sodium hydroxide, tertiary sodium phosphate, carbolic acid, ammonium nitrate, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, thickener and Water is made by the following method:
1) sodium hydroxide, tertiary sodium phosphate, carbolic acid are put into reaction kettle by the weight part ratio of 4:6:4 after mixing, to mixed The water that total weight of the mixture 29% is added in object is closed, is heated to 70-80 DEG C, reacts 2 hours, obtains intermediate liquid;
2) ammonium nitrate is added in another reaction kettle, closed reactor walks in obtained before at the uniform velocity instilling to closed reaction kettle Between liquid, intermediate liquid and ammonium nitrate weight part ratio are 5-7:8-12, and after instillation, reaction kettle is heated to 70-80 DEG C, it reacts 1.5-2 hours, obtains chelating agent;
3) chelating agent obtained is walked before taking, and white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex is added and stirs evenly, then Ammonium sulfate is added, aforementioned raw material is put into heating tank, is heated to 50-60 DEG C, keeps the temperature 2-3 hours, after being cooled to room temperature, adds Enter thickener, stir evenly, forms paste, obtain area synergist.
Preferably, in step 2, intermediate liquid and ammonium nitrate weight part ratio are 6:10
Preferably, in step 3), chelating agent, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, ammonium sulfate, thickening The weight part ratio of agent is 15-25:15-25:15-25:8-12:40-60:20-30.
Preferably, in step 3), chelating agent, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, ammonium sulfate, The weight part ratio of thickener is 20:20:20:10:50:25.
Preferably, in step 3), ammonium sulfate is added and then the coloring agent of 5 parts by weight is added.
Preferably, the thickener is gelatinized corn starch.
Preferably, the coloring agent is food grade dyes.
The utility model has the advantages that urea synergistic permeating agent of the invention due to use with sodium hydroxide, tertiary sodium phosphate, carbolic acid and Ammonium nitrate is that primary raw material is made the chelating agent with coordinate plant growth function, then by moderate-element with it is trace element chelated, The urea synergistic permeating agent of no harmful components is made, makes urea synergistic permeating agent of the invention when carrying out synergy processing to urea Urea granules deep can be penetrated into, decomposition release synchronous with urea, is continuously crop in the fertilizer efficiency period of urea and mentions after application For nutrition, also, have effects that regulating crop growth, promote crop to the fertility for being absorbed and utilized, improving urea of fertilizer, originally The urea synergistic permeating agent of invention can be degradable, will not remain and pollute in the soil to soil.Due to reasonably limiting The weight for having determined chelating agent, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, ammonium sulfate, thickener, makes Urea synergistic permeating agent nutrition of the invention is more balanced, promotes crop more preferable to the absorption of urea and utilizing status, fertilizer synergistic It acts on stronger.Due to joined coloring agent during chelating, when making synergy processing to urea, coloring agent can be used as infiltration Saturating depth indicator uses, and judges that the infiltration of urea synergistic permeating agent is imitated by the way that urea granules are checked dye level after broken Fruit and the requirement for whether reaching infiltration make to permeate urea using urea synergistic permeating agent of the invention when handling using more square Just, it is ensured that urea synergistic permeating agent fully penetrates into the deep of urea granules.Due to using the thickener as gelatinized corn starch, described Coloring agent is food grade dyes, keeps urea synergistic permeating agent of the invention more safe and reliable, can decompose completely after application, no It will form pollution residual, adverse effect will not be caused to soil.
Specific embodiment
Below with reference to embodiment, urea synergistic permeating agent of the invention is described in further detail.
Embodiment 1
A kind of urea synergistic permeating agent, the urea synergistic permeating agent is by sodium hydroxide, tertiary sodium phosphate, carbolic acid, ammonium nitrate, seven Water zinc sulphate, ferrous sulfate heptahydrate, four water, eight Boratex, thickener and water are made by the following method:
1) sodium hydroxide, tertiary sodium phosphate, carbolic acid are put into reaction kettle by the weight part ratio of 4:6:4 after mixing, to mixed The water that total weight of the mixture 29% is added in object is closed, is heated to 70-80 DEG C, reacts 2 hours, obtains intermediate liquid;
2) ammonium nitrate is added in another reaction kettle, closed reactor walks in obtained before at the uniform velocity instilling to closed reaction kettle Between liquid, intermediate liquid and ammonium nitrate weight part ratio are 5:12, after instillation, reaction kettle are heated to 70-80 DEG C, reaction 1.5-2 hours, obtain the chelating agent containing compound sodium nitrophenolate ingredient;
3) 15 parts by weight of chelating agent obtained are walked before taking, be added 15 parts by weight of white vitriol, 15 parts by weight of ferrous sulfate heptahydrate, Four water, eight Boratex, 12 parts by weight stir evenly, and add 60 parts by weight of ammonium sulfate, aforementioned raw material is put into heating tank, heating To 50-60 DEG C, 2-3 hours are kept the temperature, after being cooled to room temperature, 20 parts by weight of thickener is added, stir evenly, form paste, Obtain area synergist.
The thickener is sodium carboxymethyl cellulose solution.
Embodiment 2
A kind of urea synergistic permeating agent, the urea synergistic permeating agent is by sodium hydroxide, tertiary sodium phosphate, carbolic acid, ammonium nitrate, seven Water zinc sulphate, ferrous sulfate heptahydrate, four water, eight Boratex, coloring agent, thickener and water are made by the following method:
1) sodium hydroxide, tertiary sodium phosphate, carbolic acid are put into reaction kettle by the weight part ratio of 4:6:4 after mixing, to mixed The water that total weight of the mixture 29% is added in object is closed, is heated to 70-80 DEG C, reacts 2 hours, obtains intermediate liquid;
2) ammonium nitrate is added in another reaction kettle, closed reactor walks in obtained before at the uniform velocity instilling to closed reaction kettle Between liquid, intermediate liquid and ammonium nitrate weight part ratio are 6:10, after instillation, reaction kettle are heated to 70-80 DEG C, reaction 1.5-2 hours, obtain chelating agent;
3) 20 parts by weight of chelating agent obtained are walked before taking, be added 20 parts by weight of white vitriol, 20 parts by weight of ferrous sulfate heptahydrate, Four water, eight Boratex, 10 parts by weight stir evenly, and add 50 parts by weight of ammonium sulfate, and 5 parts by weight of coloring agent put aforementioned raw material Enter in heating tank, be heated to 50-60 DEG C, keep the temperature 2-3 hours, after being cooled to room temperature, 25 parts by weight of thickener is added, stirring is equal It is even, paste is formed, area synergist is obtained.
The coloring agent is food grade dyes.
The thickener is gelatinized corn starch.
Embodiment 3
A kind of urea synergistic permeating agent, the urea synergistic permeating agent is by sodium hydroxide, tertiary sodium phosphate, carbolic acid, ammonium nitrate, seven Water zinc sulphate, ferrous sulfate heptahydrate, four water, eight Boratex, coloring agent, thickener and water are made by the following method:
1) sodium hydroxide, tertiary sodium phosphate, carbolic acid are put into reaction kettle by the weight part ratio of 4:6:4 after mixing, to mixed The water that total weight of the mixture 29% is added in object is closed, is heated to 70-80 DEG C, reacts 2 hours, obtains intermediate liquid;
2) ammonium nitrate is added in another reaction kettle, closed reactor walks in obtained before at the uniform velocity instilling to closed reaction kettle Between liquid, intermediate liquid and ammonium nitrate weight part ratio are 7:8, after instillation, reaction kettle are heated to 70-80 DEG C, reaction 1.5-2 hours, obtain chelating agent;
3) 25 parts by weight of chelating agent obtained are walked before taking, be added 25 parts by weight of white vitriol, 25 parts by weight of ferrous sulfate heptahydrate, Four water, eight Boratex, 8 parts by weight stir evenly, and add 40 parts by weight of ammonium sulfate, and aforementioned raw material is put by 5 parts by weight of coloring agent In heating tank, 50-60 DEG C are heated to, keeps the temperature 2-3 hours, after being cooled to room temperature, 30 parts by weight of thickener are added, stirring is equal It is even, paste is formed, area synergist is obtained.
The coloring agent is food grade dyes.
The thickener is gelatinized corn starch.
Urea synergistic permeating agent is heated to 50 DEG C of formation hydratoids by the application method of urea synergistic permeating agent of the invention Body is sprayed in the agitator tank for filling urea, is stirred 3-5 minutes, obtains synergistic urea finished product, urea synergistic permeating agent after cooling Weight part ratio with urea is 3:1000.Or urea synergistic permeating agent paste is directly placed into the agitator tank for filling urea, It is stirred together with urea 10-15 minutes, after urea granules fully absorb urea synergistic permeating agent, obtains synergistic urea finished product, The weight part ratio of the agent of urea synergistic permeating and urea is 3:1000.
Following table is that urea synergistic permeating agent using effect of the invention compares, and table data are derived from 2018 in Liaoning Province Tieling The experimental plot in city, the town Bao Li, the Changtu County village Dong Weizi, wherein the urea of contrast groups application is common urea, the urine of experimental group application Element is with the processed urea of urea synergistic permeating agent, experimental group is identical as the other water of contrast groups, fertilizer and field management.
Experimental group average product (kg/acre) Contrast groups average product (kg/acre)
Corn 930 kilograms 900 kilograms
Soybean 245 kilograms 220 kilograms
Rice 690 kilograms 600 kilograms
Potato 2370 kilograms 2000 kilograms
The urea for applying urea synergistic permeating agent processing of the invention can significantly improve the fertilizer efficiency of urea, promote crop pair Fertilizer is absorbed and utilized, regulating crop growth, improves the disease resistance of crop, and effect of increasing production is obvious.Urea synergy of the invention Bleeding agent can be used for other crops such as vegetables, fruit tree, cotton, obvious effect of increasing production.

Claims (7)

1. a kind of urea synergistic permeating agent, it is characterized in that: the urea synergistic permeating agent is by sodium hydroxide, tertiary sodium phosphate, stone carbon Acid, ammonium nitrate, white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex, thickener and water are made by the following method:
1) sodium hydroxide, tertiary sodium phosphate, carbolic acid are put into reaction kettle by the weight part ratio of 4:6:4 after mixing, to mixed The water that total weight of the mixture 29% is added in object is closed, is heated to 70-80 DEG C, reacts 2 hours, obtains intermediate liquid;
2) ammonium nitrate is added in another reaction kettle, closed reactor walks in obtained before at the uniform velocity instilling to closed reaction kettle Between liquid, intermediate liquid and ammonium nitrate weight part ratio are 5-7:8-12, and after instillation, reaction kettle is heated to 70-80 DEG C, it reacts 1.5-2 hours, obtains chelating agent;
3) chelating agent obtained is walked before taking, and white vitriol, ferrous sulfate heptahydrate, four water, eight Boratex is added and stirs evenly, then Ammonium sulfate is added, aforementioned raw material is put into heating tank, is heated to 50-60 DEG C, keeps the temperature 2-3 hours, after being cooled to room temperature, adds Enter thickener, stir evenly, forms paste, obtain area synergist.
2. urea synergistic permeating agent according to claim 1, it is characterized in that: in step 2, intermediate liquid and ammonium nitrate Weight part ratio is 6:10.
3. urea synergistic permeating agent according to claim 2, it is characterized in that: in step 3), chelating agent, seven water sulfuric acid Zinc, ferrous sulfate heptahydrate, four water, eight Boratex, ammonium sulfate, thickener weight part ratio be 25:15-25 15-25:15-: 60:20-30 8-12:40-.
4. urea synergistic permeating agent according to claim 3, it is characterized in that: in step 3), chelating agent, seven water sulfuric acid Zinc, ferrous sulfate heptahydrate, four water, eight Boratex, ammonium sulfate, thickener weight part ratio be 20:20:20:10:50:25.
5. urea synergistic permeating agent according to claim 4, it is characterized in that: in step 3), be added ammonium sulfate and then The coloring agent of 5 parts by weight is added.
6. urea synergistic permeating agent according to any one of claims 1 to 5, it is characterized in that: the thickener is gelatinized corn starch.
7. urea synergistic permeating agent according to claim 6, it is characterized in that: the coloring agent is food grade dyes.
CN201910264922.6A 2019-04-03 2019-04-03 A kind of urea synergistic permeating agent Withdrawn CN109809922A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113603533A (en) * 2021-08-13 2021-11-05 辽宁拓展农业发展有限公司 Chelating solution for urea synergist and application

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09194279A (en) * 1996-01-12 1997-07-29 Nitto F C Kk Paste fertilizer and its production
CN105315088A (en) * 2015-12-07 2016-02-10 四川通丰科技有限公司 EDDHA chelated organic micro-fertilizer and preparation method thereof
CN106396916A (en) * 2016-08-31 2017-02-15 李明舵 Water-soluble biological organic fertilizer synergist as well as preparation method and application thereof
CN107226733A (en) * 2016-03-25 2017-10-03 辽宁津大肥业有限公司 New multicomponent element ecology chelation fertilizer and its manufacture method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09194279A (en) * 1996-01-12 1997-07-29 Nitto F C Kk Paste fertilizer and its production
CN105315088A (en) * 2015-12-07 2016-02-10 四川通丰科技有限公司 EDDHA chelated organic micro-fertilizer and preparation method thereof
CN107226733A (en) * 2016-03-25 2017-10-03 辽宁津大肥业有限公司 New multicomponent element ecology chelation fertilizer and its manufacture method
CN106396916A (en) * 2016-08-31 2017-02-15 李明舵 Water-soluble biological organic fertilizer synergist as well as preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113603533A (en) * 2021-08-13 2021-11-05 辽宁拓展农业发展有限公司 Chelating solution for urea synergist and application

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