CN109793696B

CN109793696B - Anti-dandruff plant composition and preparation method and application thereof

Info

Publication number: CN109793696B
Application number: CN201910225334.1A
Authority: CN
Inventors: 赵锴; 秦祚斌; 肖纪业; 刘世清; 徐丁巳; 黄杰明; 黄春明
Original assignee: Guangzhou Hanjinliang Cosmetic Co ltd
Current assignee: Guangzhou Hanjinliang Cosmetic Co ltd
Priority date: 2019-03-22
Filing date: 2019-03-22
Publication date: 2021-09-14
Anticipated expiration: 2039-03-22
Also published as: CN109793696A

Abstract

The invention discloses an anti-dandruff plant composition, and a preparation method and application thereof. The anti-dandruff plant composition comprises the following components in percentage by weight: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: 5-20 parts of garden balsam stem: 5-15: 3-10: 2-5: 3-8: 5-20: 5-15: 3-10: 2 to 5. The anti-dandruff plant composition is applied to shampoo, and the anti-dandruff plant composition accounts for 2-8% of the weight of the shampoo. The composition disclosed by the invention has the advantages that through reasonable screening and compounding of herbal extracts, each component generates an obvious synergistic effect, has strong antibacterial capability, has the effects of inhibiting scalp itching and removing dandruff, can be applied to various hair care products, and has a very good application prospect.

Description

Anti-dandruff plant composition and preparation method and application thereof

Technical Field

The invention relates to a hair care product, in particular to an anti-dandruff plant composition and a preparation method and application thereof.

Background

Dandruff is a very common scalp problem. On a global scale, consumers exceeding 1/3 are plagued by incomplete statistics. An important factor causing dandruff is the excessive proliferation of malassezia on scalp, most of the existing chemical antidandruff agents commonly used in shampoo products are broad-spectrum antibacterial agents, such as pyridone ethanolamine salt (OCT), ZPT, climbazole, magnesium pyrithione sulfate (MDS) and the like, the intermittent use can effectively inhibit the growth of bacteria and fungi, but the long-term use easily causes the problems of skin irritation, sensitization, toxicity and the like.

Along with the continuous development of society, the problem of environmental pollution in life is increasingly emphasized nowadays, and people are eagerly increasing for natural, organic, environment-friendly and green consumer products. In the daily necessities, the consumer's demand for shampoo products is also increasing, and on the one hand, there is a need for highly effective products against health stress caused by environmental pollution; on the other hand, the product is required to be mild in property, and can enable people and the environment to reach a harmonious and natural balance state. Therefore, the development of a mild plant anti-dandruff ingredient, and a product with anti-allergy properties, is more appreciated by consumers.

Disclosure of Invention

The invention aims to overcome the problems and provide an anti-allergic plant anti-dandruff composition.

In order to achieve the purpose, the technical scheme adopted by the invention is that the anti-dandruff plant composition is characterized by comprising the following components: fructus Cnidii, semen Camelliae Japonicae, rhizoma Zingiberis recens, herba Portulacae, herba Agastaches, flos Chrysanthemi Indici, radix et rhizoma Rhei, cortex Phellodendri and herba Speranskiae Tuberculatae.

According to related research reports, the common cnidium fruit has the effects of dispelling wind, relieving itching, clearing heat, drying dampness and resisting allergy.

The camellia seeds have the effects of cleaning, sterilizing, relieving itching and removing grease.

The ginger is warm in nature, contains main components such as gingerol, zingiberene, zingerone and gingerol, and also contains various amino acids such as glutamic acid, aspartic acid, serine and glycine, and has the effects of stimulating scalp blood vessels, strengthening scalp metabolism, enhancing local blood circulation, activating hair follicle tissues, promoting hair growth, inhibiting scalp itching, strengthening hairy roots, cleaning scalp, removing dandruff and the like.

The purslane contains rich SL3 fatty acid, vitamin A and other substances, and has the efficacies of clearing away heat and toxic material, promoting diuresis and removing dampness, dissipating blood and reducing swelling, removing dust and sterilizing, diminishing inflammation and relieving pain, stopping bleeding and cooling blood and the like.

Agastache rugosus: antifungal and antiviral effects.

Wild chrysanthemum flower, in compendium of materia Medica, "sweet in nature and slightly cold in nature, has the effects of dispelling wind-heat, calming liver and improving eyesight". Has antibacterial, antiviral, heat clearing away, antiinflammatory, active free radical scavenging, antioxidant, and skin aging preventing effects.

Rhubarb, radix et rhizoma Rhei, being bitter in taste and cold in nature, can cool blood and stop bleeding as well as astringe to stop bleeding. Clear away heat and toxic material, activate blood.

Cortex Phellodendri with effects of clearing heat, eliminating dampness, purging pathogenic fire, removing steam, removing toxic substance, and treating sore

Speranskia herb, herba speranskiae tuberculatae, for removing toxic substance and eliminating rash, treating eczema of scrotum, pyocutaneous disease and pyogenic infections, treating alopecia, and treating seborrheic alopecia

A large number of researches show that the 9-component compound achieves the synergistic effect, can effectively inhibit malassezia and remove dandruff, and has the effects of resisting allergy, deeply removing oil and controlling oil.

As a preferred embodiment of the anti-dandruff plant composition of the present invention, the weight ratio of the cnidium fruit, camellia seed, ginger, purslane, agastache rugosus, wild chrysanthemum flower, rhubarb, phellodendron bark and garden balsam stem is cnidium fruit: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: 5-20 parts of garden balsam stem: 5-15: 3-10: 2-5: 3-8: 5-20: 5-15: 3-10: 2 to 5.

The plant extracts are compounded according to the proportion, can mutually promote to achieve better malassezia inhibition and dandruff removal effects, and simultaneously has the effects of resisting allergy, deeply removing oil and controlling oil.

As a preferred embodiment of the anti-dandruff plant composition of the present invention, the weight ratio of the cnidium fruit, camellia seed, ginger, purslane, agastache rugosus, wild chrysanthemum flower, rhubarb, phellodendron bark and garden balsam stem is cnidium fruit: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem is 10: 8-12: 5-10: 3-4: 5-6: 10: 6-10: 5: 3.

especially, when the plant extracts are compounded according to the proportion, the effects of bacteriostasis, removing dandruff, removing oil and controlling oil are better.

As a preferred embodiment of the anti-dandruff plant composition of the present invention, the weight ratio of the cnidium fruit, camellia seed, ginger, purslane, agastache rugosus, wild chrysanthemum flower, rhubarb, phellodendron bark and garden balsam stem is cnidium fruit: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem is 10: 8: 10: 4: 6: 10: 8: 5: 3.

through a large amount of experimental researches of the inventor of the application, the effects of bacteria, dandruff removal, oil removal and oil control of the plant extract are optimal when the plant extract is compounded according to the proportion.

The invention also provides the application of the anti-dandruff plant composition in the preparation of hair care products. The application of any one of the compositions in the preparation of hair care products also belongs to the protection scope of the invention.

The invention also aims to provide a hair care product containing the anti-dandruff plant composition.

The fourth purpose of the invention is to provide shampoo containing the anti-dandruff plant composition, wherein the weight percentage of the anti-dandruff plant composition in the shampoo is 2-8%. The anti-dandruff effect of the anti-dandruff plant composition is increased along with the increase of the content of the anti-dandruff plant composition in shampoo, the anti-dandruff effect is obvious when the addition amount of the anti-dandruff plant composition is more than 2%, and the anti-dandruff effect is not obviously increased when the addition amount of the anti-dandruff plant composition is more than 8%, so that the anti-dandruff effect is obvious when the addition amount of the anti-dandruff plant composition is 2-8%.

As a preferred embodiment of the shampoo according to the invention, the anti-dandruff herbal composition is present in the shampoo in a percentage by weight of 4%.

The shampoo further comprises 0.5-10% of a conditioner, 1-6% of a thickening agent, 0.1-0.5% of an aromatic, 12-25% of a surfactant, 0.5-3% of a pearling agent, 0.5-6% of an ester-forming agent, 1-5% of a cosolvent, 0.1-0.2% of a preservative, 0.05-0.1% of a chelating agent and the balance of deionized water.

Preferably, the surfactant is at least one of sodium laureth sulfate, ammonium laureth sulfate, sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, coconut monoethanolamide, and cocamidopropyl betaine.

More preferably, the surfactant adopts the following components in percentage by weight: ammonium laureth sulfate, coconut monoethanolamide, and cocoamidopropyl betaine in a weight ratio of 10-14: 3-6: 1-3: 2 to 5.

Preferably, the conditioning agent is at least one of polyquaternium-10, polyquaternium-7, polyquaternium-39, polyquaternium-73, guar gum hydroxypropyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride and polydimethylsiloxane.

More preferably, the conditioner is polyquaternium-10, guar gum hydroxypropyl trimethyl ammonium chloride, and the mass ratio of the polydimethylsiloxane to the polydimethylsiloxane is 0.05-0.2: 0.1-0.2: 0.8 to 3.

Preferably, the thickener is at least one of carbomer 2020, acrylate copolymer, sodium hydroxy cellulose, hydroxyethyl cellulose, sodium carboxymethyl cellulose, cocamide DEA, NaCl.

More preferably, the thickener is cocamide DEA.

Preferably, the ester-forming agent is at least one of lanolin, shea butter, olive oil, linseed oil, camellia oil, jojoba oil PEG-150 esters, PEG-55 stearates, etc.

More preferably, the ester-forming agent is lanolin, jojoba oil PEG-150 esters and linseed oil in a weight ratio of 0.3-3: 0.1-3: 0.1 to 3.

Preferably, the pearling agent is one of ethylene glycol distearate and pearly luster slurry.

More preferably, ethylene glycol distearate.

Preferably, the cosolvent is at least one of ethoxydiglycol, glycerol, propylene glycol, 1, 3-butanediol, 1618 alcohol and dipropylene glycol.

More preferably, the cosolvent is glycerol and 1618 alcohol in a mass ratio of 1-3: 1 to 3.

Preferably, the chelating agent is one of EDTA-disodium, citric acid and sodium citrate.

More preferred chelating agent EDTA-disodium

Preferably, the preservative is at least one of caprylhydroxamic acid, p-hydroxyacetophenone, cason GG, glyceryl caprylate, German.

More preferably, the preservative is prepared by mixing p-hydroxyacetophenone and caprylyl hydroxamic acid in a mass ratio of 0.5-1: 0.2 to 1.

As a preferred embodiment of the shampoo provided by the invention, the shampoo comprises the following components in percentage by weight: 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium-ammonium salt, 0.1% of guar hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 4% of an anti-dandruff plant composition, 0.1% of a preservative, 0.05% of a chelating agent, 0.4% of an aromatic and the balance of deionized water.

When the shampoo is prepared from the components in proportion, the effects of bacteriostasis, dandruff removal, oil control and oil removal are optimal.

The invention has the beneficial effects that: the composition disclosed by the invention has the advantages that the traditional Chinese medicine components are reasonably selected for compounding, so that the components can play a role together to achieve the effects of removing dandruff and sterilizing, the scalp is well sterilized, the plant extract is not irritant to the scalp, the excessive oil secreted by the skin can be inhibited, the hair quality can be recovered to be normal, and the effect is better after long-term use. Can be applied to various hair care products, and has the advantages of safety, small side effect and good application prospect.

Drawings

FIG. 1 is a diagram showing the effect of the dandruff test in example 1 of the present invention.

Detailed Description

The invention is described in further detail below with reference to the drawings and specific examples, which are provided for illustration only and are not intended to limit the scope of the invention. The test methods used in the following examples are all conventional methods unless otherwise specified; the materials, reagents and the like used are, unless otherwise specified, commercially available reagents and materials.

The raw materials in the following examples are all commercially available general-purpose materials unless otherwise specified.

Example 1

As an example of an anti-dandruff botanical composition of the present invention, the anti-dandruff botanical composition comprises the following components: the medicine comprises the following components in parts by weight: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem is 10: 8: 10: 4: 6: 10: 8: 5: 3.

the preparation method of the anti-dandruff plant composition comprises the following steps: firstly, crushing medicinal materials including fructus cnidii, camellia seeds, ginger, purslane, agastache rugosus, wild chrysanthemum, rheum officinale, golden cypress and garden balsam stem into coarse powder according to the mass ratio, adding 10 times of deionized water, heating and refluxing for 2 times by small fire for 1 hour each time, filtering, combining the 2 times of filtrate, centrifuging, taking supernatant, keeping the vacuum degree of-0.1 to-0.08 MPa on a rotary evaporator at the temperature of 70 ℃, and concentrating under reduced pressure to 52ml to obtain 1mg/ml of anti-dandruff compound, and storing the anti-dandruff compound in a refrigerator at the temperature of 4 ℃ for later use.

The anti-dandruff plant composition is applied to shampoo, and the shampoo comprises the following components in percentage by weight: 4% of anti-dandruff plant composition, 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of cocoanut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium, 0.1% of guar gum hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 0.1% of preservative, 0.05% of chelating agent, 0.4% of aromatic and the balance of deionized water.

The preparation method of the shampoo comprises the following steps:

s1, pouring deionized water into a container, dispersing glycerol, polyquaternium-10 and guar gum hydroxypropyl trimethyl ammonium chloride into the deionized water while heating and stirring, heating the mixture in the container to 75 ℃, and keeping stirring at the temperature until the polyquaternium-10 is completely dissolved to obtain a mixture A;

s2, sequentially adding ammonium laureth sulfate, ammonium lauryl sulfate, coconut monoethanolamide, cocamidopropyl betaine and cocamide DEA into the mixture A while stirring, uniformly stirring to obtain a mixture B,

s3, adding a mixture of lanolin dissolved by heating, jojoba oil PEG-150 esters, ethylene glycol distearate, 1618 alcohol, linseed oil and polydimethylsiloxane oil into the mixture B to obtain a mixture C. The temperature of the mixture in the vessel was maintained at 75 ℃ throughout the stirring process;

s4, naturally cooling the mixture C to 40 ℃, sequentially adding the preservative and the essence, and uniformly stirring to obtain a shampoo base material D;

and S5, mixing the plant anti-dandruff compound with the shampoo base material D and uniformly stirring.

Example 2

The difference between the present example and example 1 is only that the anti-dandruff herbal composition is different, and the weight ratio of the cnidium fruit, the camellia seed, the ginger, the purslane, the wrinkled gianthyssop herb, the wild chrysanthemum flower, the rhubarb, the phellodendron bark and the garden balsam stem is: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem 5: 15: 10: 5: 8: 20: 15: 10: 5.

the antidandruff plant composition of the present invention is prepared in the same way as in example 1.

Example 3

The difference between the present example and example 1 is only that the anti-dandruff herbal composition is different, and the weight ratio of the cnidium fruit, the camellia seed, the ginger, the purslane, the wrinkled gianthyssop herb, the wild chrysanthemum flower, the rhubarb, the phellodendron bark and the garden balsam stem is: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: the garden balsam stem is 20: 5: 3: 2: 3: 5: 5: 3: 2.

Example 4

The difference between the present example and example 1 is only that the anti-dandruff herbal composition is different, and the weight ratio of the cnidium fruit, the camellia seed, the ginger, the purslane, the wrinkled gianthyssop herb, the wild chrysanthemum flower, the rhubarb, the phellodendron bark and the garden balsam stem is: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: the garden balsam stem is 10: 12: 6: 4: 6: 10: 10: 5: 3.

Example 5

The difference between the present example and example 1 is only that the anti-dandruff herbal composition is different, and the weight ratio of the cnidium fruit, the camellia seed, the ginger, the purslane, the wrinkled gianthyssop herb, the wild chrysanthemum flower, the rhubarb, the phellodendron bark and the garden balsam stem is: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: the garden balsam stem is 10: 10: 5: 3: 5: 10: 6: 5: 3.

Example 6

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage of 2%.

Example 7

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage ratio, and the anti-dandruff herbal composition is added in an amount of 5%.

Example 8

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage, and the anti-dandruff herbal composition is added in an amount of 6%.

Example 9

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage, and the anti-dandruff herbal composition is added in an amount of 8%.

Example 10

The shampoo of the embodiment is different from the shampoo of embodiment 1 only in that the components of the shampoo are different, and the shampoo of the embodiment comprises the following components in percentage by weight: 11% of ammonium laureth sulfate, 6% of ammonium lauryl sulfate, 2% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 2% of cocamide DEA, 100.1% of polyquaternium-ammonium salt, 0.1% of guar hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 1% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 6% of an anti-dandruff plant composition, 0.1% of a preservative, 0.05% of a chelating agent, 0.1% of an aromatic and the balance of deionized water.

The preparation method of the shampoo comprises the following steps:

Example 11

The shampoo of the embodiment is different from the shampoo of embodiment 1 only in that the components of the shampoo are different, and the shampoo of the embodiment comprises the following components in percentage by weight: 8% of sodium laureth sulfate, 2% of sodium dodecyl sulfate, 2% of cocamidopropyl betaine, 2% of carbomer 20200.5, 0.5% of acrylate copolymer, 70.1% of polyquaternium, 0.1% of behenyl trimethyl ammonium chloride, 0.3% of polydimethylsiloxane, 1.0% of lanolin, 0.3% of jojoba oil PEG-150 esters, 1.0% of camellia oil, 0.5% of pearlescent slurry, 0.5% of ethoxy diglycol, 0.5% of propylene glycol, 2% of an antidandruff plant composition, 0.1% of preservative, 0.05% of chelating agent, 0.4% of aromatic and the balance of deionized water.

The preparation method of the shampoo comprises the following steps:

s1, pouring deionized water into a container, dispersing ethoxy diglycol, polyquaternium-7 and behenyl trimethyl ammonium chloride into the deionized water while heating and stirring, heating the mixture in the container to 75 ℃, and keeping stirring at the temperature until the polyquaternium-7 is completely dissolved to obtain a mixture A;

s2, adding sodium laureth sulfate, sodium dodecyl sulfate, cocamidopropyl betaine, carbomer 2020 and acrylate copolymer into the mixture A while stirring, and uniformly stirring to obtain a mixture B,

s3, adding the mixture of lanolin, jojoba oil PEG-150 esters, nacreous slurry, propylene glycol and camellia oil which are heated and dissolved into the mixture B to obtain a mixture C. The temperature of the mixture in the vessel was maintained at 75 ℃ throughout the stirring process;

Example 12

The shampoo of the embodiment is different from the shampoo of embodiment 1 only in that the components of the shampoo are different, and the shampoo of the embodiment comprises the following components in percentage by weight: 13% of ammonium lauryl sulfate, 6% of sodium lauryl sulfate, 3% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 3% of sodium hydroxy cellulose, 3% of hydroxyethyl cellulose, 394% of polyquaternary ammonium salt, 732% of polyquaternary ammonium salt, 2% of behenyl trimethyl ammonium chloride, 2.0% of polydimethylsiloxane, 2% of shea butter, 2% of olive oil, 0.3% of jojoba oil PEG-150 esters, 1.7% of linseed oil, 3% of ethylene glycol distearate, 2% of glycerol, 3% of 1, 3-butanediol, 4% of an antidandruff plant composition, 0.2% of a preservative, 0.1% of a chelating agent, 0.5% of an aromatic and the balance of deionized water.

The preparation method of the shampoo comprises the following steps:

s1, pouring deionized water into a container, dispersing glycerol, polyquaternium-39, polyquaternium-73 and behenyl trimethyl ammonium chloride into the deionized water, heating while stirring, heating the mixture in the container to 75 ℃, maintaining the temperature, and continuously stirring until the polyquaternium-39 and the polyquaternium-73 are completely dissolved to obtain a mixture A;

s2, adding ammonium lauryl sulfate, sodium lauryl sulfate, coconut monoethanolamide, coconut oil amidopropyl betaine, sodium hydroxy cellulose and hydroxyethyl cellulose into the mixture A while stirring, and uniformly stirring to obtain a mixture B;

s3, adding the mixture of the shea butter, the olive oil, the jojoba oil PEG-150 esters, the ethylene glycol distearate, the 1, 3-butanediol, the linseed oil and the polydimethylsiloxane oil which are heated and dissolved into the mixture B to obtain a mixture C. The temperature of the mixture in the vessel was maintained at 75 ℃ throughout the stirring process;

Comparative example 1

The comparative example differs from example 1 only in that the anti-dandruff botanical composition of the comparative example comprises the following components: the traditional Chinese medicine composition comprises purslane, wrinkled gianthyssop herb, wild chrysanthemum flower, rhubarb, amur corktree bark and garden balsam stem, wherein the weight ratio of the purslane to the wrinkled gianthyssop herb to the wild chrysanthemum flower to the rhubarb to the amur corktree bark to the garden balsam stem is as follows: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem 4: 6: 10: 8: 5: 3.

the anti-dandruff plant composition of the comparative example is applied to shampoo, and the shampoo comprises the following components in percentage by weight: 4% of anti-dandruff plant composition, 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of cocoanut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium, 0.1% of guar gum hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 0.1% of preservative, 0.05% of chelating agent, 0.4% of aromatic and the balance of deionized water.

The anti-dandruff plant composition and shampoo of this comparative example were prepared in the same manner as in example 1.

Comparative example 2

This comparative example differs from example 1 only in that the anti-dandruff botanical composition of this comparative example comprises the following components: the medicine comprises the following components in parts by weight: fructus cnidii: camellia seeds: ginger: rhubarb: phellodendron bark: garden balsam stem is 10: 8: 10: 8: 5: 3.

Comparative example 3

The antidandruff plant composition of this comparative example comprises the following components: the traditional Chinese medicine composition comprises the following components in parts by weight: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower 10: 8: 10: 4: 6: 10.

Comparative example 4

The antidandruff plant composition of this comparative example comprises the following components: the medicine comprises the following components in parts by weight: fructus cnidii: ginkgo leaf: cacumen biotae: hundred steps: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: garden balsam stem is 10: 8: 10: 4: 6: 10: 8: 5: 3.

Comparative example 5

The antidandruff plant composition of this comparative example comprises the following components: the medicine comprises the following components in parts by weight: fructus cnidii: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: astragalus root: the preparation method comprises the following steps of (1) preparing broom cypress fruit: fructus xanthil 10: 8: 10: 4: 6: 10: 8: 5: 3.

Comparative example 6

The shampoo of the comparative example comprises the following components in percentage by weight: 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium-ammonium salt, 0.1% of guar hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of lanolin, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 1% of an antidandruff agent ZPT, 0.1% of a preservative, 0.05% of a chelating agent, 0.4% of an aromatic agent and the balance of deionized water.

The shampoo of this comparative example was prepared in the same manner as in example 1.

Comparative example 7

The shampoo of the comparative example is different in that the shampoo does not contain an antidandruff agent and comprises the following components in percentage by weight: 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium-ammonium salt, 0.1% of guar hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 0.1% of preservative, 0.05% of chelating agent, 0.4% of aromatic and the balance of deionized water.

The shampoo of this comparative example was prepared as in example 1.

Comparative example 8

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage, and the anti-dandruff herbal composition is added in an amount of 1.5%.

Comparative example 9

The difference between the present example and example 1 is that the anti-dandruff herbal composition is added to shampoo in a weight percentage, and the anti-dandruff herbal composition is added in an amount of 9%.

Example 12

The shampoo prepared in examples 1-12 and comparative examples 1-9 were tested for effectiveness.

(I) anti-dandruff effect

In the shampoo described in examples 1 to 12 and comparative examples 1 to 9, 1260 patients with mild, moderate and severe symptoms were selected according to the amount of dandruff and the degree of itching, the shampoo was used for washing hair once every 4 days by the "half-head test method", the amount of dandruff and the degree of itching were checked 4 days after washing hair, and the condition of washing hair was observed for 5 times. The effect is shown: no visible desquamation and no pruritus; the method has the following advantages: the hairy roots are occasionally tiny and desquamative, and have no pruritus; the improvement is as follows: a small amount of fine desquamation and itching feeling can be seen on the hair roots; and (4) invalidation: a large amount of fine desquamation and itching feeling. As shown in the chart 1, a test sheet is filled in to comprehensively evaluate the using effect as shown in the table 2, and the test sheet is filled in after trial to be scored. The using effect of each item in the scoring table is divided into 5 points in total: score 5 is the highest score, indicating very satisfactory; 4 points are better and relatively satisfactory; score 3 is acceptable; the following score of 3 is an unacceptable range, and the average score of each use effect is shown in table 1:

TABLE 1

As can be seen from table 1, the shampoos in examples 1 to 12 and comparative example 6 of the present invention have good anti-dandruff and anti-itching effects on mild, moderate and severe patients, and the anti-dandruff plant compositions in comparative examples 1 to 3 lack some components of cnidium fruit, camellia seed, ginger, purslane, wrinkled gianthyssop herb, wild chrysanthemum, rhubarb, phellodendron bark and garden balsam stem compared with example 1, and the anti-dandruff effect is significantly reduced compared with example 1; compared with the anti-dandruff plant composition in the comparative examples 4-5, the anti-dandruff plant composition adopts ginkgo leaf, cacumen biotae, stemona root, astragalus mongholicus, fructus kochiae and cocklebur fruit components to replace part of the components of the composition for compounding, and the results show that the effect is not as good as that of the composition, and the fructus cnidii, camellia seed, ginger, purslane, agastache rugosus, wild chrysanthemum flower, rheum officinale, golden cypress and garden balsam stem are compounded, so that the anti-dandruff plant composition has a synergistic function of anti-dandruff.

Comparative example 7 was conducted without the addition of an antidandruff ingredient. Of the 75 tested groups, the natural plant anti-dandruff group was found to be 2% more effective than the 1% ZPT group in terms of antipruritic effect. This is shown to be related to the ability of the plant to remove dandruff in the plant dandruff control and, in addition, in the severe patients group in comparative example 7, the effect was not as good as in the plant dandruff control, probably due to the drug resistance of some patients tested after long-term use of shampoo containing ZPT. Particularly, the user generally reflects that the ZPT group shampoo feels too strong degreasing force after washing, hair and scalp are dry and harsh, and obvious stimulation is exerted on eyes during washing, while the plant dandruff group shampoo does not have the feelings, which proves that the plant dandruff group shampoo is safer and milder than the ZPT group shampoo.

The results of comparative examples 8 to 9 show that the anti-dandruff effect is increased as the content of the anti-dandruff herbal composition in the shampoo is increased, the anti-dandruff effect is significant when the addition amount of the anti-dandruff herbal composition is greater than 2%, and the anti-dandruff effect is not significantly increased when the addition amount of the anti-dandruff herbal composition is greater than 8%, so that the anti-dandruff effect is significant when the addition amount of the anti-dandruff herbal composition is 2 to 8%.

Table 2 shows the average score of each use effect of the shampoos described in examples 1-12 and comparative examples 6-7

Group of	Oil control	Richness of foam	Irritation property	Cleaning of	Is compliant
						Examples1	4.95	4.98	5.00	4.97	4.97
Example 2	4.85	4.83	4.98	4.87	4.90
						Example 3	4.90	4.85	4.93	4.83	4.87
Example 4	4.95	4.92	4.99	4.95	4.92
						Example 5	4.94	4.93	4.99	4.95	4.93
Example 6	4.80	4.82	4.95	4.87	4.80
						Example 7	4.93	4.97	5.00	4.95	4.93
Example 8	4.95	4.97	5.00	4.95	4.97
						Example 9	4.93	4.97	4.99	4.98	4.91
Example 10	4.90	4.86	4.98	4.95	4.92
						Example 11	4.89	4.87	5.00	4.96	4.91
Example 12	4.91	4.78	5.00	4.96	4.92
						Comparative example 6	4.65	4.97	4.69	4.97	4.95
Comparative example 7	4.66	4.80	4.90	4.90	4.89

As can be seen from table 2, compared with comparative examples 6 to 7, the shampoos of examples 1 to 12 are non-irritant, have good cleanliness and flexibility, which shows that the shampoo of the present invention has a good conditioning effect on hair and a good oil control effect, and shows that the plant anti-dandruff shampoo containing the plant anti-dandruff antipruritic has a good oil control effect which is obviously superior to the shampoo containing no plant anti-dandruff agent, and the shampoo of example 1 is the best.

Secondly, the shampoos in examples 1-12 and comparative examples 1-9 are subjected to physicochemical detection, and the detection indexes are as follows:

(1) pH value detection

The shampoos described in examples 1 to 12 and comparative examples 1 to 9 were sampled and measured by a pH meter to have a pH of 6.0 to 6.5.

(2) Viscosity number detection

The shampoos described in examples 1 to 12 and comparative examples 1 to 9 were sampled and measured by a viscometer to obtain a viscosity number of 10000 to 16000.

(3) Stability detection

Sampling the shampoos described in examples 1-12 and comparative examples 1-9, packaging the shampoos in transparent cosmetic bottles, respectively placing the bottles under the experimental conditions of-15 ℃, 5 ℃, 25 ℃ and 48 ℃ of quartz lamp illumination, continuously testing the appearance, fragrance, pH value, viscosity and other items for 3 months, observing whether unfavorable phenomena such as bleeding, layering, separation, precipitation, discoloration, peculiar smell, demulsification and the like occur, and the detection result shows that the unfavorable results do not occur in the testing process, which indicates that the stability is good.

(4) Centrifugal assay

Sampling is carried out on the samples 1-12 in the examples and the samples 1-9 in the comparative examples, the samples are packaged in a centrifugal tube and are separated for 30min at 3000r/min, whether non-dispersed components appear or not is observed, and the detection result shows that the non-dispersed components do not appear, so that the mixing property is good.

(5) Stimulus hypersensitivity detection

The shampoo described in the embodiments 1-12 and the comparative examples 1-9 is sampled, a proper amount of the shampoo is applied to the necks of 60 volunteers 18-58 years old, and the phenomena of red swelling, rash, blistering and the like are observed for 30min, and the observation result shows that all the volunteers do not have the adverse symptoms within 30min, which indicates that the shampoo does not cause irritation and allergic problems to the skin.

(III) bacteriostatic test

Activated malassezia furfur is prepared into bacterial suspension (4X 105CFU/mL), 0.3mL of the bacterial suspension is smeared on a Leeming & Notman culture medium plate and placed for 10min, a plate cover is opened in a sterile ultra-clean workbench, and the plate is dried by sterile wind (about 20 min). 4 Oxford cups, 1 negative control (containing no test sample) Oxford cup, were placed on each plate, and the other three were dropped into 100. mu.L of the sample to be tested. Slightly pressing the oxford cup by using sterile forceps to enable the oxford cup to be tightly attached to the surface of the flat plate, covering the flat plate, placing the flat plate in a 30 ℃ constant-temperature incubator for inverted culture for 7 days, measuring the diameter of a bacteriostatic ring, calculating an average value, and performing comparison research. If the diameter of the inhibition zone is less than 8mm, the inhibition zone is invalid, otherwise, the inhibition zone is valid, and if the inhibition zone has the inhibition effect result in 3 times of repeated tests, the product is judged to be qualified. Negative control group has no bacteriostatic ring, otherwise test data is invalid. The results of the bacteriostatic experiments performed on the traditional Chinese medicines in table 3 are shown in table 3:

TABLE 3

As can be seen from Table 3, fructus Cnidii, camellia seeds, ginger, purslane, wrinkled gianthyssop herb, wild chrysanthemum flower, rhubarb, phellodendron bark and garden balsam stem have good antibacterial effects, the 9 traditional Chinese medicines are selected for compounding, antibacterial experiments are carried out on examples 1-12 and comparative examples 1-5, and the experimental results are shown in Table 4:

TABLE 4

Group of	Diameter of bacteriostatic circle (mm)
		Example 1	24.6±0.3
Example 2	20.3±0.5
		Example 3	21.0±0.2
Example 4	23.1±0.1
		Example 5	23.5±0.4
Example 6	21.8±0.6
		Example 7	22.5±0.4
Example 8	23.1±0.3
		Example 9	23.9±0.6
Example 10	23.0±0.4
		Example 11	21.6±0.2
Example 12	24.3±0.1
		Comparative example 1	15.8±0.5
Comparative example 2	14.9±0.7
		Comparative example 3	15.2±0.6
Comparative example 4	13.9±0.4
		Comparative example 5	14.7±0.3

As can be seen from table 4, the bacteriostatic effect of the embodiments 1 to 12 of the present invention is good, wherein when the mass ratio of cnidium fruit, camellia seed, ginger, purslane, wrinkled gianthyssop, wild chrysanthemum flower, rhubarb, phellodendron bark and speranskia herb is 10: 8: 10: 4: 6: 10: 8: 5: 3 hours, the diameter of the maximum inhibition zone is 24.6 mm. Compared with the composition of example 1, the anti-dandruff plant composition of comparative examples 1 to 3 lacks some components of cnidium fruit, camellia seed, ginger, purslane, wrinkled gianthyssop, wild chrysanthemum flower, rhubarb, phellodendron bark and garden balsam stem, and the antibacterial effect is inferior to that of example 1; compared with the example 1, the anti-dandruff plant composition in the comparative examples 4-5 adopts ginkgo leaf, cacumen biotae, stemona root, astragalus mongholicus, fructus kochiae and cocklebur fruit components to replace part of the components of the composition for compounding, and the results show that the antibacterial effect is not the same as that of the composition of the invention, and the fructus cnidii, camellia seed, ginger, purslane, wrinkled gianthyssop herb, wild chrysanthemum flower, rheum officinale, golden cypress and garden balsam stem are compounded, so that the composition has the synergistic antibacterial function.

(IV) antidandruff comparison test

Selecting 30 volunteers aged 18-30 years and suffering from dandruff, comparing the shampoo of example 1 with the shampoos of comparative examples 6-7 for removing dandruff, continuously using the shampoo for one month three times per week, weighing dandruff before and after use, counting average variance, and analyzing, wherein 10 persons in each group are selected. Wherein sample 1: example 1; sample 2: comparative example 6; sample 3 comparative example 7. The experimental results are shown in fig. 1:

as can be seen from FIG. 1, the application of the plant dandruff control composition has a very good effect on dandruff control.

The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims

1. The anti-dandruff plant composition is characterized in that the raw materials comprise the following components: fructus Cnidii, semen Camelliae Japonicae, rhizoma Zingiberis recens, herba Portulacae, herba Agastaches, flos Chrysanthemi Indici, radix et rhizoma Rhei, cortex Phellodendri and herba Speranskiae Tuberculatae; the weight ratio of the common cnidium fruit to the camellia seed to the ginger to the purslane to the agastache rugosus to the wild chrysanthemum flower to the rhubarb to the amur corktree bark to the garden balsam stem is as follows: camellia seeds: ginger: purslane: agastache rugosus: wild chrysanthemum flower: rhubarb: phellodendron bark: speranskia tuberculata = 10: 8: 10: 4: 6: 10: 8: 5: 3.

2. use of the antidandruff plant composition according to claim 1 for the preparation of a hair care product.

3. A hair care product comprising the antidandruff botanical composition according to claim 1.

4. A shampoo containing the anti-dandruff herbal composition according to claim 1, wherein the anti-dandruff herbal composition is present in the shampoo in an amount of 2 to 8% by weight.

5. The shampoo according to claim 4, wherein the anti-dandruff herbal composition is present in the shampoo in an amount of 4% by weight.

6. The shampoo according to claim 4 or 5, characterized by further comprising 0.5-10% of a conditioner, 1-6% of a thickener, 0.1-0.5% of an aromatic, 12-25% of a surfactant, 0.5-3% of a pearling agent, 0.5-6% of an ester-forming agent, 1-5% of a cosolvent, 0.1-0.2% of a preservative, 0.05-0.1% of a chelating agent and the balance of deionized water.

7. The shampoo according to claim 6, characterized by comprising the following components in percentage by weight: 12% of ammonium laureth sulfate, 5% of ammonium lauryl sulfate, 1% of coconut monoethanolamide, 3% of cocamidopropyl betaine, 1.5% of cocamide DEA, 100.1% of polyquaternium-ammonium salt, 0.1% of guar hydroxypropyl trimethyl ammonium chloride, 2.5% of polydimethylsiloxane, 0.2% of wool fat, 0.6% of jojoba oil PEG-150 esters, 0.3% of linseed oil, 1.4% of ethylene glycol distearate, 1.5% of glycerol, 2.0% of 1618 alcohol, 4% of an anti-dandruff plant composition, 0.1% of a preservative, 0.05% of a chelating agent, 0.4% of an aromatic and the balance of deionized water.